KR102577808B1 - Wastewater treatment method using mixed treatment of dyeing wastewater and heterogeneous wastewater - Google Patents
Wastewater treatment method using mixed treatment of dyeing wastewater and heterogeneous wastewater Download PDFInfo
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- 239000002351 wastewater Substances 0.000 title claims abstract description 161
- 238000004043 dyeing Methods 0.000 title claims abstract description 91
- 238000011282 treatment Methods 0.000 title claims abstract description 88
- 238000004065 wastewater treatment Methods 0.000 title claims abstract description 37
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 30
- 239000000701 coagulant Substances 0.000 claims abstract description 17
- 238000006386 neutralization reaction Methods 0.000 claims abstract description 16
- 238000005345 coagulation Methods 0.000 claims abstract description 10
- 230000015271 coagulation Effects 0.000 claims abstract description 10
- 238000001556 precipitation Methods 0.000 claims abstract description 9
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 claims description 44
- 238000004062 sedimentation Methods 0.000 claims description 34
- 239000010802 sludge Substances 0.000 claims description 32
- 239000006228 supernatant Substances 0.000 claims description 28
- 230000005484 gravity Effects 0.000 claims description 22
- 238000002156 mixing Methods 0.000 claims description 13
- 239000005416 organic matter Substances 0.000 claims description 11
- 238000011221 initial treatment Methods 0.000 claims description 10
- 238000003756 stirring Methods 0.000 claims description 10
- 238000005273 aeration Methods 0.000 claims description 9
- 238000006243 chemical reaction Methods 0.000 claims description 8
- 238000005189 flocculation Methods 0.000 claims description 6
- 230000016615 flocculation Effects 0.000 claims description 6
- 239000010842 industrial wastewater Substances 0.000 claims description 6
- 238000007599 discharging Methods 0.000 claims description 5
- 230000001376 precipitating effect Effects 0.000 claims description 5
- 239000004576 sand Substances 0.000 claims description 4
- 239000002699 waste material Substances 0.000 claims description 4
- 230000003311 flocculating effect Effects 0.000 claims description 3
- 229920000642 polymer Polymers 0.000 claims description 3
- 230000003472 neutralizing effect Effects 0.000 claims description 2
- 239000010840 domestic wastewater Substances 0.000 claims 1
- 239000000356 contaminant Substances 0.000 abstract description 18
- 238000000034 method Methods 0.000 description 31
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 12
- 239000000126 substance Substances 0.000 description 12
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 9
- 230000003647 oxidation Effects 0.000 description 8
- 238000007254 oxidation reaction Methods 0.000 description 8
- 244000005700 microbiome Species 0.000 description 7
- XEEYBQQBJWHFJM-UHFFFAOYSA-N iron Substances [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 6
- 150000002505 iron Chemical class 0.000 description 6
- 239000013049 sediment Substances 0.000 description 5
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 4
- 230000000694 effects Effects 0.000 description 4
- 239000012266 salt solution Substances 0.000 description 4
- 239000002253 acid Substances 0.000 description 3
- 239000007788 liquid Substances 0.000 description 3
- 239000002244 precipitate Substances 0.000 description 3
- 238000004064 recycling Methods 0.000 description 3
- 235000011121 sodium hydroxide Nutrition 0.000 description 3
- 239000007787 solid Substances 0.000 description 3
- 230000002378 acidificating effect Effects 0.000 description 2
- 238000001816 cooling Methods 0.000 description 2
- 238000000354 decomposition reaction Methods 0.000 description 2
- 230000018044 dehydration Effects 0.000 description 2
- 238000006297 dehydration reaction Methods 0.000 description 2
- 238000010586 diagram Methods 0.000 description 2
- 238000005868 electrolysis reaction Methods 0.000 description 2
- 239000003344 environmental pollutant Substances 0.000 description 2
- AFEXUNWJRCURNJ-UHFFFAOYSA-M iron(3+);oxygen(2-);chloride Chemical compound [O-2].[Cl-].[Fe+3] AFEXUNWJRCURNJ-UHFFFAOYSA-M 0.000 description 2
- 231100000719 pollutant Toxicity 0.000 description 2
- CBENFWSGALASAD-UHFFFAOYSA-N Ozone Chemical compound [O-][O+]=O CBENFWSGALASAD-UHFFFAOYSA-N 0.000 description 1
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 1
- 239000003518 caustics Substances 0.000 description 1
- 238000004042 decolorization Methods 0.000 description 1
- 235000013601 eggs Nutrition 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 239000004744 fabric Substances 0.000 description 1
- 159000000014 iron salts Chemical class 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 230000001590 oxidative effect Effects 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 230000001699 photocatalysis Effects 0.000 description 1
- 238000003672 processing method Methods 0.000 description 1
- 238000009210 therapy by ultrasound Methods 0.000 description 1
Classifications
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- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F9/00—Multistage treatment of water, waste water or sewage
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- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/008—Control or steering systems not provided for elsewhere in subclass C02F
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- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/52—Treatment of water, waste water, or sewage by flocculation or precipitation of suspended impurities
- C02F1/54—Treatment of water, waste water, or sewage by flocculation or precipitation of suspended impurities using organic material
- C02F1/56—Macromolecular compounds
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- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/66—Treatment of water, waste water, or sewage by neutralisation; pH adjustment
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F11/00—Treatment of sludge; Devices therefor
- C02F11/12—Treatment of sludge; Devices therefor by de-watering, drying or thickening
- C02F11/121—Treatment of sludge; Devices therefor by de-watering, drying or thickening by mechanical de-watering
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- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F3/00—Biological treatment of water, waste water, or sewage
- C02F3/02—Aerobic processes
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- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2103/00—Nature of the water, waste water, sewage or sludge to be treated
- C02F2103/34—Nature of the water, waste water, sewage or sludge to be treated from industrial activities not provided for in groups C02F2103/12 - C02F2103/32
- C02F2103/36—Nature of the water, waste water, sewage or sludge to be treated from industrial activities not provided for in groups C02F2103/12 - C02F2103/32 from the manufacture of organic compounds
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- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2209/00—Controlling or monitoring parameters in water treatment
- C02F2209/06—Controlling or monitoring parameters in water treatment pH
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- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Hydrology & Water Resources (AREA)
- Environmental & Geological Engineering (AREA)
- Water Supply & Treatment (AREA)
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
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Abstract
Description
본 발명은 염색폐수와 이업종폐수의 혼합처리를 이용한 폐수 처리방법에 관한 것으로, 보다 상세하게는 이업종폐수에 균질화된 염색폐수를 중화조에서 혼합하여 교반한 후, FeSO4와 Ca(OH)2를 주입하여 pH 9 ~ 10으로 반응시킨 혼합 처리수에 응집제를 투입하여 응집 및 침전시키는 것에 의해, 염색폐수 내에 포함된 난분해성 오염물질을 가장 효율적이고 빠르게 제거할 수 있는 염색폐수와 이업종폐수의 혼합처리를 이용한 폐수 처리방법에 관한 것이다.The present invention relates to a wastewater treatment method using mixed treatment of dyeing wastewater and wastewater from a different industry. More specifically, the dyeing wastewater homogenized with wastewater from a different industry is mixed in a neutralization tank, stirred, and then FeSO 4 and Ca(OH) Dyeing wastewater and wastewater from other industries can most efficiently and quickly remove non-decomposable contaminants contained in dyeing wastewater by adding coagulant to coagulate and precipitate the mixed treated water that has been injected and reacted to pH 9 ~ 10. It relates to a wastewater treatment method using mixed treatment.
염색폐수는 폐수 내에 생물학적으로 처리하기 어려운 난분해성의 오염물질이 많이 포함되어 있다. 따라서, 이러한 난분해성 오염물질을 사전에 제거하거나 미생물이 분해 및 흡수할 수 있도록 유기물의 긴 분자사슬을 끊어주는 1차 처리를 실시한 후 2차로 미생물을 이용하여 잔존하는 유기물을 생물학적인 처리방법으로 처리하는 방법을 주로 사용하고 있으며, 염색폐수의 1차 처리기술로서는 오존산화, 전기분해, 마이크로파 조사, 플라즈마 이용분해, 광촉매 산화 등의 다양한 방법들이 있다.Dyeing wastewater contains many non-degradable contaminants that are difficult to biologically treat. Therefore, after performing primary treatment to remove these non-degradable contaminants in advance or breaking the long molecular chains of organic matter so that microorganisms can decompose and absorb them, the remaining organic matter is secondarily treated using a biological treatment method using microorganisms. The primary treatment technology for dyeing wastewater includes various methods such as ozone oxidation, electrolysis, microwave irradiation, plasma decomposition, and photocatalytic oxidation.
이러한 방법들은 에너지가 많이 소요되면서도 염색폐수의 성상에 따라 처리효율이 크게 차이나 단일 물질이 포함되어 있는 염색폐수 처리에는 사용가치가 있으나, 복합물질로 조성된 염색폐수 처리에는 효율이 떨어진다. 따라서, 대부분의 염색업체에서는 염색방법이나 원단의 종류에 따라 사용되는 염색방법이 달라져서 염색업체에서 배출되는 대부분의 염색폐수는 단일 염색폐수가 거의 없는 실정으로 전기분해 등의 처리방법은 주 처리방법이 아니고 일부에서 보조처리 방법으로 많이 사용되고 있다.Although these methods require a lot of energy, their treatment efficiency varies greatly depending on the properties of the dyeing wastewater. Although they are valuable for treating dyeing wastewater containing a single substance, they are less efficient in treating dyeing wastewater composed of complex substances. Therefore, in most dyeing companies, the dyeing method used varies depending on the dyeing method or type of fabric. As most of the dyeing wastewater discharged from dyeing companies is rarely single dyeing wastewater, treatment methods such as electrolysis are the main treatment methods. No, it is widely used as an auxiliary processing method in some areas.
다른 방법으로는 여러 단계의 생물학적처리 즉 호기성처리, 혐기성처리를 연속 반복하거나 또는 호기성처리, 호기성처리와 같이 동일 방법을 수차례 반복시켜 난분해성의 오염물질과 염색폐수 내의 유기물을 미생물로 분해시켜 정화하는 방법도 있으나, 이러한 방법들은 자연의 미생물을 이용하는 친환경적인 처리방법으로는 가장 좋은 대안이라 할 수 있다. 하지만, 이러한 방법들은 난분해성 유기물에 대한 분해속도가 늦어서 처리에 필요한 부지면적이 커야 하고 색도제거가 어려운 문제가 있다.Another method is to continuously repeat several stages of biological treatment, such as aerobic treatment and anaerobic treatment, or repeat the same method several times, such as aerobic treatment and aerobic treatment, to decompose non-degradable pollutants and organic matter in dyeing wastewater into microorganisms and purify them. There are other methods, but these methods can be said to be the best alternative as an eco-friendly treatment method using natural microorganisms. However, these methods have the problem that the decomposition rate for non-decomposable organic substances is slow, so the site area required for treatment is large, and color removal is difficult.
한편, 유입되는 염색폐수에 황산이나 염산 등의 산화물질을 투입하여 pH를 3 ~ 3.5 정도로 강 산성화시키고 과산화수소와 철염을 투입하여 과산화수소가 분해되면서 발생하는 OH- 라디칼기가 염색폐수의 색도를 낮추고, 강 산성분위기에서 철염에서 용출된 Fe가 난분해성의 오염물질과 반응하여 난분해성의 오염물질 철염산화슬러지로 침전되면 침전된 철염산화슬러지는 응집시켜 고액분리조에서 고액으로 분리시킨 후 고형물은 탈수기로 탈수시켜 탈수 케이크로 외부 처리하고, 난분해성 물질이 제거되어진 1차처리수는 다시 폭기조, 침전조를 거치면서 1차처리수 내에 잔존하는 유기물을 미생물을 이용하여 분해 제거하는 처리방법인 염색폐수 펜톤 산화방법이 대한민국공개 특허 제10-1996-0031353호(특허등록 제10-0145467호)에 기재되어 있다.Meanwhile, oxidizing substances such as sulfuric acid or hydrochloric acid are added to the incoming dyeing wastewater to strongly acidify the pH to about 3 to 3.5, and hydrogen peroxide and iron salt are added to reduce the color of the dyeing wastewater. In an acidic atmosphere, Fe eluted from iron salt reacts with non-decomposable contaminants and precipitates into iron chloride oxide sludge, a non-decomposable contaminant. The precipitated iron chloride oxide sludge is coagulated and separated into solid and liquid in a solid-liquid separator, and the solid is dehydrated in a dehydrator. The Fenton oxidation method for dyeing wastewater is a treatment method in which organic matter remaining in the primary treatment water is decomposed and removed using microorganisms while the primary treatment water from which non-biodegradable substances have been removed passes through an aeration tank and a sedimentation tank. This is described in Korean Patent Publication No. 10-1996-0031353 (Patent Registration No. 10-0145467).
위의 염색폐수 펜톤 산화방법은 처리효율은 좋으나 색도제거를 위한 과산화수소의 투입과 전체 염색폐수를 펜톤산화 조건인 강산성화시키기 위해 투입하는 황산과 펜톤산화 처리 후에 1차처리수를 다시 중화시키기 위하여 가성소다 등의 산 및 알칼리 약품을 대량 투입하게 되어 많은 약품비가 소요되고, 특히 투입되는 철염과 산 및 알칼리 약품이 전부 슬러지화 되어 탈수케이크 발생량이 많아지는 문제점이 있다.The Fenton oxidation method for dyeing wastewater has good treatment efficiency, but it requires the addition of hydrogen peroxide to remove color, sulfuric acid added to strongly acidify the entire dyeing wastewater under Fenton oxidation conditions, and caustic acid to neutralize the primary treatment water again after the Fenton oxidation treatment. A large amount of acid and alkaline chemicals such as soda are injected, resulting in high chemical costs. In particular, there is a problem in that all the iron salts and acid and alkaline chemicals added are converted into sludge, resulting in an increase in the amount of dehydrated cake.
본 발명의 목적은 이업종폐수에 균질화된 염색폐수를 중화조에서 혼합하여 교반한 후, FeSO4와 Ca(OH)2를 주입하여 pH 9 ~ 10으로 반응시킨 혼합 처리수에 응집제를 투입하여 응집 및 침전시키는 것에 의해, 염색폐수 내에 포함된 난분해성 오염물질을 가장 효율적이고 빠르게 제거할 수 있는 염색폐수와 이업종폐수의 혼합처리를 이용한 폐수 처리방법을 제공하는 것이다.The purpose of the present invention is to mix and stir dyeing wastewater homogenized with wastewater from different industries in a neutralization tank, then inject FeSO 4 and Ca(OH) 2 and add a coagulant to the mixed treated water to react to pH 9 to 10 to flocculate it. To provide a wastewater treatment method using mixed treatment of dyeing wastewater and wastewater from other industries, which can most efficiently and quickly remove non-degradable contaminants contained in dyeing wastewater by precipitation.
상기 과제를 해결하기 위한 본 발명의 실시예에 따른 염색폐수와 이업종폐수의 혼합처리를 이용한 폐수 처리방법은 (a) 이업종폐수에 Ca(OH)2 및 FeSO4를 주입하여 반응시키는 단계; (b) 상기 반응시킨 이업종폐수에 균질화된 염색폐수를 중화조 내에서 서로 혼합하여 교반한 후, FeSO4와 Ca(OH)2를 주입하여 pH 9 ~ 10으로 반응시키는 단계; (c) 상기 pH 9 ~ 10으로 반응시킨 혼합 처리수에 응집제를 투입하여 응집 및 침전시키는 단계; (d) 상기 응집 및 침전시킨 혼합 처리수에 황산(H2SO4)을 주입하여 pH 6 ~ 8로 중화 처리하는 단계; 및 (e) 상기 중화 처리된 혼합 처리수를 폭기조로 유입시켜 생물학적 처리로 유기물을 분해 처리한 후, 침전시켜 상등액을 방류하는 단계;를 포함하는 것을 특징으로 한다.To solve the above problem, a wastewater treatment method using mixed treatment of dyeing wastewater and wastewater from a different industry according to an embodiment of the present invention includes the steps of (a) injecting Ca(OH) 2 and FeSO 4 into the wastewater from a different industry and reacting it; (b) mixing and stirring the dyeing wastewater homogenized with the reacted wastewater from a different industry in a neutralization tank, then injecting FeSO 4 and Ca(OH) 2 to react to pH 9 to 10; (c) adding a coagulant to the mixed treated water reacted at pH 9 to 10 to cause coagulation and precipitation; (d) neutralizing the coagulated and precipitated mixed water to pH 6 to 8 by injecting sulfuric acid (H 2 SO 4 ); and (e) introducing the neutralized mixed treatment water into an aeration tank, decomposing organic matter through biological treatment, and then precipitating it and discharging the supernatant.
상기 (a) 단계는, (a-1) 이업종폐수 전용관로 및 이업종폐수 집수조를 통하여 반응조 내로 이업종폐수를 유입시키는 단계; (a-2) 상기 반응조 내로 유입된 상기 이업종폐수에 Ca(OH)2를 주입하여 pH를 11 ~ 12로 조절하는 단계; 및 (a-3) 상기 pH 11 ~ 12로 조절된 이업종폐수에 FeSO4를 주입하여 pH 3 ~ 5에서 반응시키는 단계;를 포함한다.The step (a) includes (a-1) introducing wastewater from a different industry into the reaction tank through a pipe dedicated to wastewater from a different industry and a collection tank for wastewater from a different industry; (a-2) adjusting the pH to 11 to 12 by injecting Ca(OH) 2 into the wastewater from other industries flowing into the reaction tank; And (a-3) injecting FeSO 4 into the industrial wastewater adjusted to pH 11 to 12 and reacting at pH 3 to 5.
상기 (b) 단계에서, 상기 균질화된 염색폐수는 전용 폐수관로를 통하여 유입되는 염색폐수 중 침사조를 이용하여 모래 성분을 침전시켜 제거하고, 상기 염색폐수에 혼입되어 유입되는 폐기물을 스크린조를 통해 분리 제거하고, 상기 스크린조를 통과한 염색폐수를 균등조 및 유량조정조에서 균질하게 혼합하여 유입부하를 설정 값으로 유지시킨 것이 이용된다.In step (b), the homogenized dyeing wastewater is removed by precipitating the sand component of the dyeing wastewater flowing in through a dedicated wastewater pipe using a silt tank, and the waste mixed in the dyeing wastewater is filtered through a screen tank. The dyeing wastewater that has been separated and removed and passed through the screen tank is mixed homogeneously in an equalization tank and a flow rate adjustment tank to maintain the inflow load at the set value.
상기 응집제는 폴리머인 것이 바람직하다.The coagulant is preferably a polymer.
상기 (c) 단계는, (c-1) 상기 pH 9 ~ 10으로 반응시킨 혼합 처리수를 응집조 내로 유입시킨 후, 응집제를 투입하여 응집하는 단계; 및 (c-2) 상기 응집제에 의해 응집된 혼합 처리수를 1차 침전조로 유입하여 중력 침강시켜 상등액과 슬러지로 분리시키는 단계;를 포함한다.The step (c) includes (c-1) introducing the mixed treated water reacted to pH 9 to 10 into a flocculation tank and flocculating it by adding a coagulant; and (c-2) flowing the mixed treated water flocculated by the coagulant into a primary sedimentation tank and allowing it to gravity settle to separate it into a supernatant and sludge.
상기 (c-2) 단계에서, 상기 1차 침전조에서 중력 침강시켜 분리된 상등액은 1차 처리수조에 유입시켜 황산(H2SO4)으로 중화시키고, 상기 슬러지는 1차 슬러지 저장조에 저장한다.In step (c-2), the supernatant separated by gravity settling in the primary sedimentation tank is introduced into the primary treatment tank to be neutralized with sulfuric acid (H 2 SO 4 ), and the sludge is stored in the primary sludge storage tank.
상기 (e) 단계는, (e-1) 상기 중화 처리된 혼합 처리수를 폭기조로 유입시켜 생물학적 처리로 유기물을 분해 처리한 후, 2차 침전조에서 중력 침강시켜 상등액과 슬러지로 분리시키는 단계; 및 (e-2) 상기 2차 침전조에서 중력 침강시켜 분리된 상등액을 방류조로 유입시킨 후, 상기 상등액의 유량을 유량계로 측정하고, pH를 조절하여 종말처리장으로 배출하는 단계;를 포함한다.The step (e) includes (e-1) introducing the neutralized mixed treatment water into an aeration tank, decomposing organic matter through biological treatment, and then separating it into a supernatant and sludge by gravity settling it in a secondary sedimentation tank; and (e-2) flowing the supernatant separated by gravity sedimentation in the secondary sedimentation tank into the discharge tank, measuring the flow rate of the supernatant with a flow meter, adjusting the pH, and discharging it to the terminal treatment plant.
상기 (e-1) 단계에서, 상기 2차 침전조에서 중력 침강시켜 분리된 상등액은 드레인 배관을 통하여 유량조정조로 재 유입시킨다.In step (e-1), the supernatant separated by gravity settling in the secondary sedimentation tank is re-introduced into the flow control tank through the drain pipe.
상기 (e-1) 단계에서, 상기 2차 침전조에서 중력 침강시켜 분리된 상등액은 방류조로 유입시켜 종말처리장으로 배출하고, 상기 슬러지는 2차 슬러지 저장조에 저장한다.In step (e-1), the supernatant separated by gravity settling in the secondary sedimentation tank is introduced into a discharge tank and discharged to a terminal treatment plant, and the sludge is stored in a secondary sludge storage tank.
상기 1차 및 2차 슬러지 저장조에 저장된 슬러지는 혼합 탱크로 각각 이송시킨 후, 탈수 처리하고 케이크 저장설비를 통하여 케이크 처리 후 방출된다.The sludge stored in the primary and secondary sludge storage tanks is transferred to a mixing tank, dehydrated, and discharged after cake treatment through a cake storage facility.
본 발명에 따른 염색폐수와 이업종폐수의 혼합처리를 이용한 폐수 처리방법은이업종폐수에 균질화된 염색폐수를 중화조에서 혼합하여 교반한 후, FeSO4와 Ca(OH)2를 주입하여 pH 9 ~ 10으로 반응시킨 혼합 처리수에 응집제를 투입하여 응집 및 침전시키는 것에 의해, 염색폐수 내에 포함된 난분해성 오염물질을 가장 효율적이고 빠르게 제거할 수 있게 된다.The wastewater treatment method using the mixed treatment of dyeing wastewater and wastewater from a different industry according to the present invention involves mixing homogenized dyeing wastewater with wastewater from a different industry in a neutralization tank, stirring the mixture, and then injecting FeSO 4 and Ca(OH) 2 to pH 9. By adding a coagulant to the mixed treated water reacted at ~10 to cause coagulation and precipitation, it is possible to most efficiently and quickly remove non-degradable contaminants contained in dyeing wastewater.
아울러, 본 발명에 따른 염색폐수와 이업종폐수의 혼합처리를 이용한 폐수 처리방법은 2차 침전조에서 중력 침강시켜 분리된 상등액을 드레인 배관을 통하여 중화조로 재 유입시키는 것에 의해, 침전물 내의 난분해성 오염물질과 반응하고 있던 Fe2+ 성분이 황산에 용해된 후 황산과 결합하여 다시 철염 용액으로 재생되어 재사용할 수 있으므로, FeSO4의 사용 비용을 절감시킬 수 있게 된다.In addition, the wastewater treatment method using mixed treatment of dyeing wastewater and wastewater from other industries according to the present invention involves gravity settling in a secondary sedimentation tank and re-introducing the separated supernatant into the neutralization tank through a drain pipe, thereby removing non-decomposable contaminants in the sediment. The Fe 2+ component reacting with is dissolved in sulfuric acid and then combined with sulfuric acid to be regenerated into an iron salt solution and reused, thereby reducing the cost of using FeSO 4 .
이 결과, 본 발명에 따른 염색폐수와 이업종폐수의 혼합처리를 이용한 폐수 처리방법은 황산, 과산화수소 및 가성소다의 투입량이 줄고 FeSO4의 재활용을 통한 전체적인 약품사용량이 줄어서 슬러지의 발생량을 최소화할 수 있으므로 폐수 처리 비용 절감을 통한 경제성 확보가 가능해질 수 있게 된다.As a result, the wastewater treatment method using the mixed treatment of dyeing wastewater and wastewater from other industries according to the present invention can minimize the amount of sludge generated by reducing the input amount of sulfuric acid, hydrogen peroxide, and caustic soda and reducing the overall chemical usage through recycling of FeSO 4 . Therefore, it becomes possible to secure economic feasibility by reducing wastewater treatment costs.
도 1은 본 발명의 실시예에 따른 염색폐수와 이업종폐수의 혼합처리를 이용한 폐수 처리방법을 나타낸 공정 순서도.
도 2는 본 발명의 실시예에 따른 염색폐수와 이업종폐수의 혼합처리를 이용한 폐수 처리방법을 나타낸 공정 모식도.Figure 1 is a process flow chart showing a wastewater treatment method using mixed treatment of dyeing wastewater and wastewater from different industries according to an embodiment of the present invention.
Figure 2 is a process schematic diagram showing a wastewater treatment method using mixed treatment of dyeing wastewater and wastewater from different industries according to an embodiment of the present invention.
이하, 첨부된 도면을 참조하여 본 발명의 실시예를 더욱 상세히 설명하기로 한다. 그러나 본 발명은 이하에서 개시되는 실시예에 한정되는 것이 아니라 서로 다른 다양한 형태로 구현될 것이며, 단지 본 실시예들은 본 발명의 개시가 완전하도록 하며, 통상의 지식을 가진 자에게 발명의 범주를 완전하게 알려주기 위해 제공되는 것이다. 도면상에서 동일 부호는 동일한 요소를 지칭한다.Hereinafter, embodiments of the present invention will be described in more detail with reference to the attached drawings. However, the present invention is not limited to the embodiments disclosed below and will be implemented in various different forms. These embodiments only serve to ensure that the disclosure of the present invention is complete and to those skilled in the art to fully convey the scope of the invention. This is provided to inform you. In the drawings, like symbols refer to like elements.
본 명세서에서의 구성부들에 대한 구분은 각 구성부가 담당하는 주기능별로 구분한 것에 불과함을 명확히 하고자 한다. 즉, 이하에서 설명할 2개 이상의 구성부가 하나의 구성부로 합쳐지거나 또는 하나의 구성부가 보다 세분화된 기능별로 2개 이상으로 분화되어 구비될 수도 있다. 그리고 이하에서 설명할 구성부 각각은 자신이 담당하는 주기능 이외에도 다른 구성부가 담당하는 기능 중 일부 또는 전부의 기능을 추가적으로 수행할 수도 있으며, 구성부 각각이 담당하는 주기능 중 일부 기능이 다른 구성부에 의해 전담되어 수행될 수도 있음은 물론이다. 따라서, 본 명세서를 통해 설명되는 각 구성부들의 존재 여부는 기능적으로 해석되어야 할 것이다.It is intended to be clear that the division of components in this specification is merely a division according to the main function each component is responsible for. That is, two or more components, which will be described below, may be combined into one component, or one component may be divided into two or more components for more detailed functions. In addition to the main functions it is responsible for, each of the components described below may additionally perform some or all of the functions handled by other components, and some of the main functions handled by each component may be performed by other components. Of course, it can also be carried out exclusively by . Therefore, the presence or absence of each component described throughout this specification should be interpreted functionally.
이하 본 발명에 따른 염색폐수와 이업종폐수의 혼합처리를 이용한 폐수 처리방법을 첨부된 도면을 참고로 하여 상세히 기술되는 실시예들에 의해 그 특징들을 이해할 수 있을 것이다.Hereinafter, the characteristics of the wastewater treatment method using the mixed treatment of dyeing wastewater and wastewater from other industries according to the present invention will be described in detail with reference to the attached drawings.
도 1은 본 발명의 실시예에 따른 염색폐수와 이업종폐수의 혼합처리를 이용한 폐수 처리방법을 나타낸 공정 순서도이고, 도 2는 본 발명의 실시예에 따른 염색폐수와 이업종폐수의 혼합처리를 이용한 폐수 처리방법을 나타낸 공정 모식도이다.Figure 1 is a process flow chart showing a wastewater treatment method using mixed treatment of dyeing wastewater and wastewater from a different industry according to an embodiment of the present invention, and Figure 2 is a process flow chart showing a mixed treatment of dyeing wastewater and wastewater from a different industry according to an embodiment of the present invention. This is a process schematic diagram showing the wastewater treatment method used.
도 1 및 도 2를 참조하면, 본 발명의 실시예에 따른 염색폐수와 이업종폐수의 혼합처리를 이용한 폐수 처리방법은 이업종폐수 처리 단계(S110), 이업종폐수와 염색폐수 혼합 처리 단계(S120), 응집 및 침전 처리 단계(S130), 중화 처리 단계(S140) 및 생물학적 처리 단계(S150)를 포함한다.Referring to Figures 1 and 2, the wastewater treatment method using mixed treatment of dyeing wastewater and other industry wastewater according to an embodiment of the present invention includes a second industry wastewater treatment step (S110), a second industry wastewater and dyeing wastewater mixing treatment step ( S120), flocculation and precipitation treatment step (S130), neutralization treatment step (S140), and biological treatment step (S150).
이업종폐수 처리Wastewater treatment for different industries
이업종폐수 처리 단계(S110)에서는 이업종폐수에 Ca(OH)2 및 FeSO4를 주입하여 반응시킨다.In the second-industry wastewater treatment step (S110), Ca(OH) 2 and FeSO 4 are injected into the second-industry wastewater to react.
이러한 이업종폐수 처리 단계(S110)는 이업종폐수 전용관로(110) 및 이업종폐수 집수조(112)를 통하여 반응조(114) 내로 이업종폐수를 유입시키는 과정과, 반응조(114) 내로 유입된 이업종폐수에 Ca(OH)2를 주입하여 pH 11 ~ 12로 조절하는 과정과, pH 11 ~ 12로 조절된 이업종폐수에 FeSO4를 주입하여 pH 3 ~ 5에서 반응시키는 과정을 포함한다.This second-industry wastewater treatment step (S110) is a process of introducing the second-industry wastewater into the reaction tank 114 through the second-industry wastewater exclusive pipe 110 and the second-industry wastewater collection tank 112, and the process of introducing the second-industry wastewater into the reaction tank 114. It includes the process of injecting Ca(OH) 2 into industrial wastewater to adjust pH to 11 to 12, and the process of injecting FeSO 4 into industrial wastewater adjusted to pH 11 to 12 and reacting at pH 3 to 5.
이업종폐수와 염색폐수 혼합 처리Mixed treatment of wastewater from different industries and dyeing wastewater
이업종폐수와 염색폐수 혼합 처리 단계(S120)에서는 반응시킨 이업종폐수에 균질화된 염색폐수를 중화조(120) 내에서 서로 혼합하여 교반한 후, FeSO4와 Ca(OH)2를 주입하여 pH 9 ~ 10으로 반응시킨다.In the mixing treatment step (S120) of wastewater from a different industry and dyeing wastewater, the homogenized dyeing wastewater and the reacted wastewater from a different industry are mixed and stirred in a neutralization tank (120), and then FeSO 4 and Ca(OH) 2 are injected to adjust the pH. React with steps 9 to 10.
이와 같이, 본 발명에서는 이업종폐수 및 염색폐수 내에 포함된 난분해성 오염물질을 가장 효율적이면서 신속하게 제거하기 위해 FeSO4와 Ca(OH)2를 사용하였다. FeSO4는 강한 산성조건 외에도 강한 알칼리 조건에서도 반응효율이 높다는 점을 이용하여 이업종폐수 및 염색폐수에 Ca(OH)2를 투입하여 강알칼리 상태를 조성한 후 이업종폐수 및 염색폐수에 포함된 난분해성 오염물질을 FeSO4와 반응시켜 중력 침강으로 침전 제거시키는 방법을 사용한 것이다.As such, in the present invention, FeSO 4 and Ca(OH) 2 were used to most efficiently and quickly remove non-decomposable contaminants contained in wastewater from other industries and dyeing wastewater. Taking advantage of the fact that FeSO 4 has a high reaction efficiency not only under strong acidic conditions but also under strong alkaline conditions, Ca(OH) 2 is added to the wastewater from other industries and dyeing wastewater to create a strong alkaline state, and then the non-decomposable wastewater contained in the wastewater from other industries and dyeing wastewater is created. A method of reacting contaminants with FeSO 4 and removing them by gravity sedimentation was used.
다시 말해, 이업종폐수 및 염색폐수에 Ca(OH)2를 투입하여 강알칼리 상태를 조성한 후 이업종폐수 및 염색폐수에 포함된 난분해해성 오염물질을 FeSO4와 반응시키게 되면, FeSO4 내의 Fe2+ 성분이 강 알칼리의 환원 분위기로 인해 SO4 2- 기와 분리된 후 이업종폐수 및 염색폐수 내의 난분해성 오염물질과 빠르게 결합하면서 플럭이 형성되어 입자가 커지게 된다. 이에 따라, 후속되는 응집 및 침전 처리 단계(S130)에서 빠르게 응집 및 침전이 이루어지게 되어 난분해성 오염물질이 포함된 침전물을 손쉽게 제어하는 것이 가능하다.In other words, when Ca(OH) 2 is added to the wastewater of other industries and dyeing wastewater to create a strong alkaline state, and then the non-decomposable contaminants contained in the wastewater of other industries and dyeing wastewater are reacted with FeSO 4 , Fe 2 in FeSO 4 After the + component is separated from the SO 4 2- group due to the strong alkaline reducing atmosphere, it quickly combines with non-decomposable contaminants in wastewater from other industries and dyeing wastewater, forming flocs and causing the particles to become larger. Accordingly, coagulation and sedimentation occur quickly in the subsequent coagulation and sedimentation treatment step (S130), making it possible to easily control sediment containing non-decomposable contaminants.
이에 따라, 본 발명은, 종래의 펜톤산화 방법과 달리, 알카리성인 염색폐수를 펜톤산화 조건인 pH 3 ~ 3.5를 맞추기 위해 다량의 황산 또는 염산을 투입하고 색도처리를 위한 OH- 라디칼기를 생성하기 위해 과산화수소를 투입할 필요가 없으므로 약품사용량을 현저히 감소시킬 수 있게 된다.Accordingly, in the present invention, unlike the conventional Fenton oxidation method, a large amount of sulfuric acid or hydrochloric acid is added to alkaline dyeing wastewater to adjust the pH of 3 to 3.5, which is the Fenton oxidation condition, and to generate OH - radical groups for color treatment. Since there is no need to add hydrogen peroxide, the amount of chemical used can be significantly reduced.
여기서, 균질화된 염색폐수는 전용 폐수관로(130)를 통하여 유입되는 염색폐수 중 침사조(132)를 이용하여 모래 성분을 침전시켜 제거하고, 염색폐수에 혼입되어 유입되는 폐기물을 스크린조(134)를 통해 분리 제거하고, 스크린조(134)를 통과한 염색폐수를 균등조(136) 및 유량조정조(138)에서 균질하게 혼합하여 유입부하를 설정 값으로 유지시킨 것이 이용된다.Here, the homogenized dyeing wastewater is removed by precipitating the sand component of the dyeing wastewater flowing in through the dedicated wastewater pipe 130 using the silt tank 132, and the waste mixed in the dyeing wastewater and flowing in is filtered into the screen tank 134. The dyeing wastewater that has passed through the screen tank 134 is separated and mixed homogeneously in the equalization tank 136 and the flow rate adjustment tank 138 to maintain the inflow load at the set value.
이와 같이, 전용 폐수관로(130)를 통하여 유입되는 염색폐수는 불균질한 염색폐수가 유입되므로 침사조(132)를 이용하여 모래 성분을 침전시켜 제거한 후, 스크린조(134)를 통해 불균질한 염색폐수에 혼입되어 있는 조대폐기물을 분리 제거하게 된다.In this way, since the dyeing wastewater flowing in through the dedicated wastewater pipe 130 is heterogeneous dyeing wastewater, the sand component is precipitated and removed using the silt tank 132, and then the heterogeneous dyeing wastewater is removed through the screen tank 134. Coarse waste mixed in dyeing wastewater is separated and removed.
이후, 스크린조(134)를 통과한 불균질한 염색폐수를 유량계(135)를 이용하여 일정량을 균등조(136) 및 유량조정조(138) 내에 순차적으로 유입시키게 된다. 이때, 균등조(136) 및 유량조정조(138)는 유입되는 염색폐수의 성상이 각 시간마다 상이하므로, 유입되는 불균질한 염색폐수를 균질하게 섞어 유입부하를 일정하게 유지시키게 된다.Thereafter, a certain amount of the heterogeneous dyeing wastewater that has passed through the screen tank 134 is sequentially introduced into the equalization tank 136 and the flow rate adjustment tank 138 using the flow meter 135. At this time, since the properties of the dyeing wastewater flowing into the equalizing tank 136 and the flow adjusting tank 138 are different at each time, the inflow load is kept constant by homogeneously mixing the heterogeneous dyeing wastewater flowing in.
특히, 본 단계(S120)에서는 이업종폐수와 균질화된 염색폐수를 중화조(120)에서 혼합하여 교반한 후, FeSO4와 Ca(OH)2를 주입하여 pH 9 ~ 10으로 반응시키게 된다.In particular, in this step (S120), the wastewater from different industries and the homogenized dyeing wastewater are mixed and stirred in the neutralization tank 120, and then FeSO 4 and Ca(OH) 2 are injected to react to pH 9 to 10.
이때, 교반은 1,500 ~ 3,000rpm의 속도로 10 ~ 120분 동안 실시하는 것이 바람직하다. 교반 속도가 1,500rpm 미만이거나, 교반 시간이 10분 미만일 경우에는 이업종폐수와 균질화된 염색폐수 내에 FeSO4와 Ca(OH)2가 균질하게 혼합되지 못하여 pH 조절에 어려움이 따를 수 있고, 교반 속도가 3,000rpm을 초과하거나, 교반 시간이 120분을 초과할 경우에는 더 이상의 효과 없이 제조 비용만을 상승시키는 요인으로 작용할 수 있으므로, 경제적이지 못하다.At this time, stirring is preferably performed for 10 to 120 minutes at a speed of 1,500 to 3,000 rpm. If the stirring speed is less than 1,500 rpm or the stirring time is less than 10 minutes, FeSO 4 and Ca(OH) 2 may not be mixed homogeneously in the wastewater from other industries and the homogenized dyeing wastewater, which may lead to difficulties in adjusting pH. If it exceeds 3,000 rpm or the stirring time exceeds 120 minutes, it may act as a factor that only increases manufacturing costs without any further effect, making it uneconomical.
아울러, 교반시, 25 ~ 45KHz의 주파수 및 10 ~ 20W의 출력 전압 조건으로 초음파 처리를 함께 실시하는 것이 보다 바람직한데, 이는 이업종폐수와 균질화된 염색폐수 내의 난분해성 오염물질과의 결합을 극대화하기 위함이다. 초음파 인가시, 주파수가 25KHz 미만이거나, 출력 전압이 10W 미만일 경우에는 초음파의 인가에 따른 캐비테이션(cavitation) 효과가 미미하여 초음파 인가 효과를 제대로 발휘하기 어렵고, 초음파의 주파수가 45KHz를 초과하거나, 또는 출력 전압이 20W를 초과할 경우에는 더 이상의 효과 상승 없이 과도한 초음파 인가로 인해 경제성이 좋지 않을 우려가 있으므로, 바람직하지 못하다.In addition, when stirring, it is more desirable to perform ultrasonic treatment at a frequency of 25 to 45 KHz and an output voltage of 10 to 20 W, to maximize the combination of non-degradable contaminants in the wastewater from different industries and the homogenized dyeing wastewater. It is for this purpose. When applying ultrasonic waves, if the frequency is less than 25 KHz or the output voltage is less than 10 W, the cavitation effect caused by the application of ultrasonic waves is minimal, making it difficult to properly demonstrate the effect of applying ultrasonic waves. If the frequency of ultrasonic waves exceeds 45 KHz, or the output voltage is If it exceeds 20W, it is not desirable because there is a risk of poor economic efficiency due to excessive application of ultrasonic waves without further increase in effectiveness.
응집 및 침전 처리Flocculation and sedimentation treatment
응집 및 침전 처리 단계(S130)에서는 pH 9 ~ 10으로 반응시킨 혼합 처리수에 응집제를 투입하여 응집 및 침전시킨다. 여기서, 응집제로는 폴리머를 이용하는 것이 바람직하다.In the coagulation and precipitation treatment step (S130), a coagulant is added to the mixed treatment water reacted to pH 9 to 10 to cause coagulation and precipitation. Here, it is preferable to use a polymer as a coagulant.
이러한 응집 및 침전 처리 단계(S130)는 pH 9 ~ 10으로 반응시킨 혼합 처리수를 응집조(140) 내로 유입시킨 후, 응집제를 투입하여 응집하는 과정과, 응집제에 의해 응집된 혼합 처리수를 1차 침전조(142)로 유입하여 중력 침강시켜 상등액과 슬러지로 분리시키는 과정을 포함한다.This coagulation and sedimentation treatment step (S130) is a process of introducing mixed treated water reacted to pH 9 to 10 into the flocculation tank 140, flocculating it by adding a coagulant, and mixing the mixed treated water flocculated by the coagulant into 1 It includes the process of flowing into the secondary settling tank 142 and separating it into supernatant and sludge by gravity settling.
이때, 1차 침전조(142)에서 중력 침강시켜 분리된 상등액은 1차 처리수조(146)에 유입시켜 황산(H2SO4)으로 중화시키고, 슬러지는 1차 슬러지 저장조(144)에 저장한다. 여기서, 1차 처리수조(146)는 냉각탑(148)에 의해 일정한 온도로 냉각이 이루어지게 된다.At this time, the supernatant separated by gravity settling in the primary sedimentation tank 142 is introduced into the primary treatment tank 146 to be neutralized with sulfuric acid (H 2 SO 4 ), and the sludge is stored in the primary sludge storage tank 144. Here, the primary treatment water tank 146 is cooled to a constant temperature by the cooling tower 148.
중화 처리neutralization treatment
중화 처리 단계(S140)에서는 응집 및 침전시킨 혼합 처리수에 황산(H2SO4)을 주입하여 pH 6 ~ 8로 중화 처리한다.In the neutralization treatment step (S140), sulfuric acid (H 2 SO 4 ) is injected into the coagulated and precipitated mixed treatment water to neutralize it to pH 6 to 8.
이와 같이, 응집 및 침전시킨 혼합 처리수에 황산(H2SO4)을 주입하여 pH 6 ~ 8로 중화 처리하게 되면, 침전물 내에 난분해성 오염물질과 반응하고 있던 Fe2+ 성분이 황산에 용해된 후 황산과 결합하여 다시 철염 용액으로 재생되어 재사용할 수 있으므로, FeSO4의 사용 비용을 절감시킬 수 있게 된다.In this way, when sulfuric acid (H 2 SO 4 ) is injected into the coagulated and precipitated mixed treatment water to neutralize it to pH 6 to 8, the Fe 2+ component reacting with the non-decomposable contaminants in the sediment is dissolved in sulfuric acid. After combining with sulfuric acid, it can be regenerated into an iron salt solution and reused, thereby reducing the cost of using FeSO 4 .
생물학적 처리biological treatment
생물학적 처리 단계(S150)에서는 중화 처리된 혼합 처리수를 폭기조(150)로 유입시켜 생물학적 처리로 유기물을 분해 처리한 후, 침전시켜 상등액을 방류한다.In the biological treatment step (S150), the neutralized mixed treatment water is introduced into the aeration tank 150 to decompose organic matter through biological treatment, and then precipitated and the supernatant is discharged.
이와 같이, 황산(H2SO4)을 주입하는 것에 의해 pH 6 ~ 8로 중화 처리된 혼합 처리수는 폭기조(150)에서 장시간 체류하면서 공기에 의해 호기조건이 되어 호기성 미생물의 활동이 활발해지면서 중화 처리된 혼합 처리수 내의 유기물이 미생물에 의해 분해되는 것이다.In this way, the mixed treatment water, which has been neutralized to pH 6 to 8 by injecting sulfuric acid (H 2 SO 4 ), stays in the aeration tank 150 for a long time and is neutralized as the activity of aerobic microorganisms becomes active due to aerobic conditions caused by air. Organic matter in the treated mixed water is decomposed by microorganisms.
이러한 생물학적 처리 단계(S150)는 중화 처리된 혼합 처리수를 폭기조(150)로 유입시켜 생물학적 처리로 유기물을 분해 처리한 후, 2차 침전조(152)에서 중력 침강시켜 상등액과 슬러지로 분리시키는 과정과, 2차 침전조(152)에서 중력 침강시켜 분리된 상등액을 방류조(156)로 유입시킨 후, 상등액의 유량을 유량계(155)로 측정하고, pH를 조절하여 종말처리장으로 배출하는 과정을 포함한다.In this biological treatment step (S150), the neutralized mixed treatment water is introduced into the aeration tank 150 to decompose organic matter through biological treatment, and then separated into supernatant and sludge by gravity settling in the secondary sedimentation tank 152. , It includes the process of flowing the supernatant separated by gravity sedimentation in the secondary sedimentation tank 152 into the discharge tank 156, measuring the flow rate of the supernatant with the flow meter 155, adjusting the pH, and discharging it to the terminal treatment plant. .
아울러, 2차 침전조(152)에서 중력 침강시켜 분리된 상등액은 드레인 배관(158)을 통하여 유량조정조(138)로 재 유입시키게 된다. 이에 따라, 유량조정조(138)에는 이업종폐수와 균질화된 염색폐수와 더불어, 드레인 배관(158)을 통하여 폐수처리 과정에서 발생된 폐수가 재 유입되어 혼합되고, 유량조정조(138)를 통하여 유량부하가 일정하게 유지된다.In addition, the supernatant separated by gravity settling in the secondary settling tank 152 is re-introduced into the flow adjustment tank 138 through the drain pipe 158. Accordingly, in the flow adjustment tank 138, wastewater generated during the wastewater treatment process is re-introduced and mixed together with wastewater from other industries and homogenized dyeing wastewater through the drain pipe 158, and the flow rate load is adjusted through the flow adjustment tank 138. remains constant.
이와 같이, 본 발명에서는 2차 침전조(152)에서 중력 침강시켜 분리된 상등액을 드레인 배관을 통하여 유량조정조(138)로 재 유입시키는 것에 의해, 침전물 내의 난분해성 오염물질과 반응하고 있던 Fe2+ 성분이 황산에 용해된 후 황산과 결합하여 다시 철염 용액으로 재생되어 재사용할 수 있으므로, FeSO4의 사용 비용을 절감시킬 수 있게 된다.As such, in the present invention, the supernatant separated by gravity sedimentation in the secondary sedimentation tank 152 is re-introduced into the flow rate adjustment tank 138 through the drain pipe, thereby removing the Fe 2+ component that was reacting with the non-decomposable contaminants in the sediment. After being dissolved in sulfuric acid, it combines with sulfuric acid and is regenerated into an iron salt solution so that it can be reused, thereby reducing the cost of using FeSO 4 .
따라서, 본 발명은, 종래와 달리, 황산, 과산화수소 및 가성소다의 투입량이 줄고 FeSO4의 재활용을 통한 전체적인 약품사용량이 줄어서 슬러지의 발생량을 최소화할 수 있으므로 폐수 처리 비용 절감을 통한 경제성 확보가 가능해질 수 있게 된다.Therefore, unlike the prior art, the present invention can minimize the amount of sludge generated by reducing the input amount of sulfuric acid, hydrogen peroxide, and caustic soda and reducing the overall chemical usage through recycling of FeSO 4 , making it possible to secure economic feasibility by reducing wastewater treatment costs. It becomes possible.
아울러, 2차 침전조(152)에서 중력 침강시켜 분리된 상등액은 방류조(156)로 유입시켜 종말처리장으로 배출하고, 슬러지는 2차 슬러지 저장조(154)에 저장한다. 이와 같이, 방류조(156)는 2차 침전조(152)에서 고액 분리된 상등액을 유량계(155)를 이용하여 유량을 측정한 후, pH를 조절하여 종말처리장으로 배출시키게 된다.In addition, the supernatant separated by gravity settling in the secondary sedimentation tank 152 flows into the discharge tank 156 and is discharged to the terminal treatment plant, and the sludge is stored in the secondary sludge storage tank 154. In this way, the discharge tank 156 measures the flow rate of the supernatant separated from solid and liquid in the secondary sedimentation tank 152 using the flow meter 155, adjusts the pH, and discharges it to the terminal treatment plant.
여기서, 1차 및 2차 슬러지 저장조(144, 154)에 저장된 슬러지는 혼합 탱크(160)로 각각 이송시킨 후, 탈수 설비(162)를 통하여 탈수 처리하고 케이크 저장설비(164)를 통하여 케이크 처리 후 방출된다.Here, the sludge stored in the primary and secondary sludge storage tanks 144 and 154 is transferred to the mixing tank 160, then dehydrated through the dehydration facility 162 and cake treated through the cake storage facility 164. It is released.
지금까지 설명한 바와 같이, 본 발명의 실시예에 따른 염색폐수와 이업종폐수의 혼합처리를 이용한 폐수 처리방법은 이업종폐수에 균질화된 염색폐수를 중화조에서 혼합하여 교반한 후, FeSO4와 Ca(OH)2를 주입하여 pH 9 ~ 10으로 반응시킨 혼합 처리수에 응집제를 투입하여 응집 및 침전시키는 것에 의해, 염색폐수 내에 포함된 난분해성 오염물질을 가장 효율적이고 빠르게 제거할 수 있게 된다.As explained so far, the wastewater treatment method using a mixed treatment of dyeing wastewater and wastewater from a different industry according to an embodiment of the present invention mixes dyeing wastewater homogenized with wastewater from a different industry in a neutralization tank, stirs it, and then mixes FeSO 4 and Ca By injecting (OH) 2 and adding a coagulant to the mixed treatment water, which has reacted to pH 9 to 10, to coagulate and precipitate, non-decomposable contaminants contained in dyeing wastewater can be removed most efficiently and quickly.
아울러, 본 발명의 실시예에 따른 염색폐수와 이업종폐수의 혼합처리를 이용한 폐수 처리방법은 2차 침전조에서 중력 침강시켜 분리된 상등액을 드레인 배관을 통하여 중화조로 재 유입시키는 것에 의해, 침전물 내의 난분해성 오염물질과 반응하고 있던 Fe2+ 성분이 황산에 용해된 후 황산과 결합하여 다시 철염 용액으로 재생되어 재사용할 수 있으므로, FeSO4의 사용 비용을 절감시킬 수 있게 된다.In addition, the wastewater treatment method using mixed treatment of dyeing wastewater and wastewater from other industries according to an embodiment of the present invention re-introduces the supernatant separated by gravity sedimentation in the secondary sedimentation tank into the neutralization tank through the drain pipe, thereby removing the eggs in the sediment. The Fe 2+ component reacting with decomposable pollutants is dissolved in sulfuric acid and then combined with sulfuric acid to be regenerated into an iron salt solution and reused, thereby reducing the cost of using FeSO 4 .
이 결과, 본 발명의 실시예에 따른 염색폐수와 이업종폐수의 혼합처리를 이용한 폐수 처리방법은 황산, 과산화수소 및 가성소다의 투입량이 줄고 FeSO4의 재활용을 통한 전체적인 약품사용량이 줄어서 슬러지의 발생량을 최소화할 수 있으므로 폐수 처리 비용 절감을 통한 경제성 확보가 가능해질 수 있게 된다.As a result, the wastewater treatment method using mixed treatment of dyeing wastewater and wastewater from other industries according to the embodiment of the present invention reduces the input amount of sulfuric acid, hydrogen peroxide, and caustic soda, and reduces the overall chemical usage through recycling of FeSO 4 , thereby reducing the amount of sludge generated. Because it can be minimized, it becomes possible to secure economic feasibility by reducing wastewater treatment costs.
이상과 같이 본 발명의 실시예에 대하여 상세히 설명하였으나, 본 발명의 권리범위는 이에 한정되지 않으며, 본 발명의 실시예와 실질적으로 균등의 범위에 있는 것까지 본 발명의 권리범위가 미친다.Although the embodiments of the present invention have been described in detail as described above, the scope of the rights of the present invention is not limited thereto, and the scope of the rights of the present invention extends to the scope substantially equivalent to the embodiments of the present invention.
S110 : 이업종폐수 처리 단계
S120 : 이업종폐수와 염색폐수 혼합 처리 단계
S130 : 응집 및 침전 처리 단계 S140 : 중화 처리 단계
S150 : 생물학적 처리 단계 110 : 이업종폐수 전용관로
112 : 이업종폐수 집수조 114 : 반응조
120 : 중화조 130 : 전용 폐수관로
132 : 침사조 134 : 스크린조
136 : 균등조 138 : 유량조정조
140 : 응집조 142 : 1차 침전조
144 : 1차 슬러지 저장조 146 : 1차 처리수조
148 : 냉각탑 150 : 폭기조
152 : 2차 침전조 154 : 슬러지 저장조
156 : 방류조 158 : 드레인 배관
160 : 혼합 탱크 162 : 탈수 설비
164 : 케이크 저장설비S110: Industrial wastewater treatment step
S120: Mixing treatment step of wastewater from other industries and dyeing wastewater
S130: Coagulation and precipitation treatment step S140: Neutralization treatment step
S150: Biological treatment step 110: Pipe dedicated to wastewater from other industries
112: Industrial wastewater collection tank 114: Reaction tank
120: Neutralization tank 130: Exclusive wastewater pipe
132: Silt tank 134: Screen tank
136: equalization tank 138: flow adjustment tank
140: flocculation tank 142: primary sedimentation tank
144: primary sludge storage tank 146: primary treatment tank
148: cooling tower 150: aeration tank
152: secondary sedimentation tank 154: sludge storage tank
156: Discharge tank 158: Drain piping
160: mixing tank 162: dehydration facility
164: Cake storage facility
Claims (10)
(b) 상기 반응시킨 이업종폐수에 균질화된 염색폐수를 중화조 내에서 서로 혼합하여 교반한 후, FeSO4와 Ca(OH)2를 주입하여 pH 9 ~ 10으로 반응시키는 단계;
(c) 상기 pH 9 ~ 10으로 반응시킨 혼합 처리수에 응집제를 투입하여 응집 및 침전시키는 단계;
(d) 상기 응집 및 침전시킨 혼합 처리수에 황산(H2SO4)을 주입하여 pH 6 ~ 8로 중화 처리하는 단계; 및
(e) 상기 중화 처리된 혼합 처리수를 폭기조로 유입시켜 생물학적 처리로 유기물을 분해 처리한 후, 침전시켜 상등액을 방류하는 단계;를 포함하며,
상기 (a) 단계에서, 상기 이업종폐수는 생활 오폐수이고,
상기 (a) 단계는, (a-1) 이업종폐수 전용관로 및 이업종폐수 집수조를 통하여 반응조 내로 이업종폐수를 유입시키는 단계; (a-2) 상기 반응조 내로 유입된 상기 이업종폐수에 Ca(OH)2를 주입하여 pH를 11 ~ 12로 조절하는 단계; 및 (a-3) 상기 pH 11 ~ 12로 조절된 이업종폐수에 FeSO4를 주입하여 pH 3 ~ 5에서 반응시키는 단계;를 포함하는 것을 특징으로 하는 염색폐수와 이업종폐수의 혼합처리를 이용한 폐수 처리방법.(a) reacting by injecting Ca(OH) 2 and FeSO 4 into wastewater from other industries;
(b) mixing and stirring the dyeing wastewater homogenized with the reacted wastewater from a different industry in a neutralization tank, then injecting FeSO 4 and Ca(OH) 2 to react to pH 9 to 10;
(c) adding a coagulant to the mixed treated water reacted to pH 9 to 10 to cause coagulation and precipitation;
(d) neutralizing the coagulated and precipitated mixed water to pH 6 to 8 by injecting sulfuric acid (H 2 SO 4 ); and
(e) introducing the neutralized mixed treatment water into an aeration tank to decompose organic matter through biological treatment, then precipitating it and discharging the supernatant;
In step (a), the industrial wastewater is domestic wastewater,
The step (a) includes (a-1) introducing wastewater from a different industry into the reaction tank through a pipe dedicated to wastewater from a different industry and a collection tank for wastewater from a different industry; (a-2) adjusting the pH to 11 to 12 by injecting Ca(OH) 2 into the wastewater from other industries flowing into the reaction tank; and (a-3) injecting FeSO 4 into the wastewater from a different industry adjusted to pH 11 to 12 and reacting it at pH 3 to 5. Using mixed treatment of dyeing wastewater and wastewater from a different industry, comprising: Wastewater treatment method.
상기 (b) 단계에서,
상기 균질화된 염색폐수는
전용 폐수관로를 통하여 유입되는 염색폐수 중 침사조를 이용하여 모래 성분을 침전시켜 제거하고,
상기 염색폐수에 혼입되어 유입되는 폐기물을 스크린조를 통해 분리 제거하고,
상기 스크린조를 통과한 염색폐수를 균등조 및 유량조정조에서 균질하게 혼합하여 유입부하를 설정 값으로 유지시킨 것이 이용되는 것을 특징으로 하는 염색폐수와 이업종폐수의 혼합처리를 이용한 폐수 처리방법.According to paragraph 1,
In step (b) above,
The homogenized dyeing wastewater is
The sand component of the dyeing wastewater flowing in through the dedicated wastewater pipe is removed by precipitating it using a silt tank.
Waste mixed in the dyeing wastewater is separated and removed through a screen tank,
A wastewater treatment method using mixed treatment of dyeing wastewater and wastewater from other industries, characterized in that the dyeing wastewater that has passed through the screen tank is mixed homogeneously in an equalization tank and a flow rate adjustment tank to maintain the inflow load at a set value.
상기 응집제는
폴리머인 것을 특징으로 하는 염색폐수와 이업종폐수의 혼합처리를 이용한 폐수 처리방법.According to paragraph 1,
The coagulant is
A wastewater treatment method using mixed treatment of dyeing wastewater and wastewater from other industries, which is characterized as being polymer.
상기 (c) 단계는,
(c-1) 상기 pH 9 ~ 10으로 반응시킨 혼합 처리수를 응집조 내로 유입시킨 후, 응집제를 투입하여 응집하는 단계; 및
(c-2) 상기 응집제에 의해 응집된 혼합 처리수를 1차 침전조로 유입하여 중력 침강시켜 상등액과 슬러지로 분리시키는 것을 특징으로 하는 염색폐수와 이업종폐수의 혼합처리를 이용한 폐수 처리방법.According to paragraph 1,
In step (c),
(c-1) introducing the mixed treated water reacted to pH 9 to 10 into a flocculation tank and flocculating it by adding a coagulant; and
(c-2) A wastewater treatment method using mixed treatment of dyeing wastewater and wastewater from other industries, characterized in that the mixed treated water coagulated by the coagulant is introduced into the primary sedimentation tank and subjected to gravity sedimentation to separate it into supernatant and sludge.
상기 (c-2) 단계에서,
상기 1차 침전조에서 중력 침강시켜 분리된 상등액은 1차 처리수조에 유입시켜 황산(H2SO4)으로 중화시키고, 상기 슬러지는 1차 슬러지 저장조에 저장하는 것을 특징으로 하는 염색폐수와 이업종폐수의 혼합처리를 이용한 폐수 처리방법.According to clause 5,
In step (c-2),
The supernatant separated by gravity settling in the primary sedimentation tank is introduced into the primary treatment tank and neutralized with sulfuric acid (H 2 SO 4 ), and the sludge is stored in the primary sludge storage tank. Dyeing wastewater and wastewater from other industries Wastewater treatment method using mixed treatment.
상기 (e) 단계는,
(e-1) 상기 중화 처리된 혼합 처리수를 폭기조로 유입시켜 생물학적 처리로 유기물을 분해 처리한 후, 2차 침전조에서 중력 침강시켜 상등액과 슬러지로 분리시키는 단계; 및
(e-2) 상기 2차 침전조에서 중력 침강시켜 분리된 상등액을 방류조로 유입시킨 후, 상기 상등액의 유량을 유량계로 측정하고, pH를 조절하여 종말처리장으로 배출하는 단계;
를 포함하는 것을 특징으로 하는 염색폐수와 이업종폐수의 혼합처리를 이용한 폐수 처리방법.According to paragraph 1,
In step (e),
(e-1) introducing the neutralized mixed treatment water into an aeration tank to decompose organic matter through biological treatment, and then separating it into a supernatant and sludge by gravity settling it in a secondary sedimentation tank; and
(e-2) flowing the supernatant separated by gravity sedimentation in the secondary sedimentation tank into the discharge tank, measuring the flow rate of the supernatant with a flow meter, adjusting the pH, and discharging it to the terminal treatment plant;
A wastewater treatment method using mixed treatment of dyeing wastewater and wastewater from other industries, comprising:
상기 (e-1) 단계에서,
상기 2차 침전조에서 중력 침강시켜 분리된 상등액은 드레인 배관을 통하여 유량조정조로 재 유입시키는 것을 특징으로 하는 염색폐수와 이업종폐수의 혼합처리를 이용한 폐수 처리방법.In clause 7,
In step (e-1) above,
A wastewater treatment method using mixed treatment of dyeing wastewater and wastewater from other industries, characterized in that the supernatant separated by gravity settling in the secondary sedimentation tank is re-introduced into the flow rate adjustment tank through a drain pipe.
상기 (e-1) 단계에서, 상기 2차 침전조에서 중력 침강시켜 분리된 상등액은 방류조로 유입시켜 종말처리장으로 배출하고, 상기 슬러지는 2차 슬러지 저장조에 저장하는 것을 특징으로 하는 염색폐수와 이업종폐수의 혼합처리를 이용한 폐수 처리방법.In clause 7,
In the step (e-1), the supernatant separated by gravity settling in the secondary sedimentation tank is introduced into a discharge tank and discharged to a terminal treatment plant, and the sludge is stored in a secondary sludge storage tank. Wastewater treatment method using wastewater mixing treatment.
1차 또는 2차 슬러지 저장조에 저장된 슬러지는
혼합 탱크로 각각 이송시킨 후, 탈수 처리하고 케이크 저장설비를 통하여 케이크 처리 후 방출되는 것을 특징으로 하는 염색폐수와 이업종폐수의 혼합처리를 이용한 폐수 처리방법.According to clause 6 or 9,
Sludge stored in the primary or secondary sludge storage tank is
A wastewater treatment method using mixed treatment of dyeing wastewater and wastewater from other industries, characterized in that each is transferred to a mixing tank, dehydrated, and discharged after cake treatment through a cake storage facility.
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