CN107265785A - Paper-making industry advanced waste treatment system and its processing method - Google Patents

Paper-making industry advanced waste treatment system and its processing method Download PDF

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Publication number
CN107265785A
CN107265785A CN201710672059.9A CN201710672059A CN107265785A CN 107265785 A CN107265785 A CN 107265785A CN 201710672059 A CN201710672059 A CN 201710672059A CN 107265785 A CN107265785 A CN 107265785A
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CN
China
Prior art keywords
water
chemicals dosing
dosing plant
clear water
sterilization pool
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201710672059.9A
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Chinese (zh)
Inventor
马冠
范俊峰
胡林阁
何花鲜
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Dengzhou City Huaxin Paper Co Ltd
Original Assignee
Dengzhou City Huaxin Paper Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Dengzhou City Huaxin Paper Co Ltd filed Critical Dengzhou City Huaxin Paper Co Ltd
Priority to CN201710672059.9A priority Critical patent/CN107265785A/en
Publication of CN107265785A publication Critical patent/CN107265785A/en
Pending legal-status Critical Current

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Classifications

    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F9/00Multistage treatment of water, waste water or sewage
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/001Processes for the treatment of water whereby the filtration technique is of importance
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/50Treatment of water, waste water, or sewage by addition or application of a germicide or by oligodynamic treatment
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/52Treatment of water, waste water, or sewage by flocculation or precipitation of suspended impurities
    • C02F1/5236Treatment of water, waste water, or sewage by flocculation or precipitation of suspended impurities using inorganic agents
    • C02F1/5245Treatment of water, waste water, or sewage by flocculation or precipitation of suspended impurities using inorganic agents using basic salts, e.g. of aluminium and iron
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F2001/007Processes including a sedimentation step
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2103/00Nature of the water, waste water, sewage or sludge to be treated
    • C02F2103/26Nature of the water, waste water, sewage or sludge to be treated from the processing of plants or parts thereof
    • C02F2103/28Nature of the water, waste water, sewage or sludge to be treated from the processing of plants or parts thereof from the paper or cellulose industry
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2301/00General aspects of water treatment
    • C02F2301/08Multistage treatments, e.g. repetition of the same process step under different conditions
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2303/00Specific treatment goals
    • C02F2303/04Disinfection
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F3/00Biological treatment of water, waste water, or sewage
    • C02F3/34Biological treatment of water, waste water, or sewage characterised by the microorganisms used
    • C02F3/342Biological treatment of water, waste water, or sewage characterised by the microorganisms used characterised by the enzymes used

Abstract

The invention discloses a kind of paper-making industry advanced waste treatment system, including the coagulating basin connected successively by pipeline, sedimentation basin, sand filter, sterilization pool and clear water reserviors, the coagulating basin upper end is provided with the first chemicals dosing plant, the sedimentation basin upper end is provided with the second chemicals dosing plant, and the sterilization pool upper end is provided with the 3rd chemicals dosing plant.Processing method is as follows:Discharge of wastewater after biochemical treatment is into coagulating basin, coagulant is added to be reacted, reacted waste water, which is sequentially entered, carries out separation of solid and liquid in sedimentation basin and sand filter, supernatant enters in sterilization pool the processing that carries out disinfection, and the clear water emitted from sterilization pool, which is entered in clear water reserviors, carries out the clear water after stewing process standing through pumping to recycle-water point progress cycling and reutilization.The paper-making industry advanced waste treatment system and its processing method of the present invention, the waste water after deep treatment can also meet the requirement of production process quality of reused water while wastewater discharge standard is met.

Description

Paper-making industry advanced waste treatment system and its processing method
Technical field:
The present invention relates to a kind of paper-making industry advanced waste treatment system, more particularly to a kind of place that advanced treating is carried out to waste water Reason method, belongs to pulp and paper technology field.
Background technology:
With the water-saving and environmental protection requirement and the project verification requirement of new environmental protection project of paper-making industry, with the increase of quantity of circulating water, enter The sewage quantity of Sewage Disposal is being gradually reduced, but the concentration of Pollutants in Wastewater accordingly increases, and according to calculating and predicting, is saved After the water project implementation, inlet COD concentration can rise to 2300mg/l or so by original 2000mg/l.According to of the prior art Sewage treatment process and treatment facility, it is difficult to reach the effluent quality formulated before the project implementation, to qualified discharge and improvement reclaimed water Water quality brings certain difficulty.The subject matter that existing sewage disposal device is present has:1. pretreating effect is poor, the pond of preliminary sedimentation tank Hold it is larger, because can not spoil disposal in time, precipitating sludge residence time in pond is longer, causes organic contamination in anaerobic acidification, waste water The increase of thing content, increases follow-up biochemical treatment load;2. treatment process is lacked before oxygen consumption aeration, water quality, water can not be adjusted, Cellulose and hemicellulose are difficult to degrade in waste water, and very big processing pressure is brought to follow-up biochemical process.
Waste water is after biochemical treatment, and the pollutant in water is mainly the solubilised state organic pollution for being difficult to biochemical degradation, The solid particulate matter that free microorganism flco and part is not removed is also remained in waste water, it is necessary to further in-depth processing.
The content of the invention:
The technical problems to be solved by the invention are:A kind of paper-making industry advanced waste treatment system and its processing method are provided, it is right Further depths reason is carried out in the waste water after biochemical treatment, water supply standard is reached.
The present invention is for the technical solution adopted for solving the technical problem:
A kind of paper-making industry advanced waste treatment system, including connected successively by pipeline coagulating basin, sedimentation basin, sand filter, sterilization Pond and clear water reserviors, the coagulating basin upper end are provided with the first chemicals dosing plant, and the sedimentation basin upper end is provided with the second chemicals dosing plant, The sterilization pool upper end is provided with the 3rd chemicals dosing plant.
Paper-making industry advanced waste treatment system recited above carries out the processing method of advanced treating to waste water, its specific step It is rapid as follows:
1. the discharge of wastewater after biochemical treatment adds appropriate mix by the first chemicals dosing plant into coagulating basin into coagulating basin Solidifying agent, regulation waste water pH value is 6.0~9.0;
2. the waste water emitted from coagulating basin is entered in sedimentation basin, is added by the second chemicals dosing plant to sedimentation basin appropriate Decolorising agent, stands after stirring, and carries out separation of solid and liquid;
3. the waste water emitted from sedimentation basin is entered in sand filter, crosses the suspended material filtered to remove in waste water;
4. the discharge of wastewater emitted from sand filter is added suitable into sterilization pool by the 3rd chemicals dosing plant into sterilization pool The disinfectant of amount, carry out disinfection processing;
5. the clear water emitted from sterilization pool, which is entered, carries out stewing process in clear water reserviors;
6. the clear water in clear water reserviors carries out cycling and reutilization through pumping to recycle-water point.
Described coagulant is industrial aluminum sulphate, and described decolorising agent is lipase, and described disinfectant is titanium dioxide Chlorine.
The present invention using coagulant sedimentation carry out waste water advanced treating, be simple and convenient to operate with process, efficiency high, The characteristics of small investment.Its general principle is:In the presence of coagulant, by compressing microparticle surfaces electric double layer, reduction interface ζ The electrochemical process such as current potential, charge neutrality, and bridging, net such as catch, adsorbed at the physical and chemical process, by the suspension in waste water, glue Body and the other materials that can be flocculated are condensed into " floc sedimentation ";The waste water after flocculation is subjected to separation of solid and liquid after being precipitated again through sedimentation basin, " floc sedimentation " sinks to sedimentation basin bottom and as mud, top outflow is then colourity and the relatively low clear water of turbidity.It was verified that mixed Solidifying removal of the precipitation method to suspension and colourity has preferable effect, while can also remove the COD of partial solubility.
Suspended impurity in water removal of the invention of being made a return journey using sand filter, is to ensure that the most terminal ring of water treatment system effluent quality Section.
Conventional sterilization process has liquid chlorine, chlorine dioxide, ozone and disinfection by ultraviolet light.Ozone and ultraviolet have good Disinfection Effect, but its equipment is expensive, and operating cost is higher, applies in general to require stricter place.Compared with liquid chlorine disinfection, Chlorine dioxide antiseptic effect is good, offers medicine simple and convenient, is not influenceed by pH.Through Integrated comparative, present invention determine that using titanium dioxide The disinfection way of chlorine.Chlorine dioxide is a kind of strong oxidizer, can rapidly be reacted with the organic matter in water after putting into water, make difficult life The organic matter of thing degraded is decomposed into small molecule or is directly oxidized, so as to reduce the content of water pollutant, removes waste water color Degree, while chlorine dioxide or a kind of very excellent disinfectant, have well for the coliform in water and various algae Killing effect, the natural organic matter, Bu Huiyu such as humic acid (HA) or fulvic acid (FA) in chlorine dioxide energy direct oxidation water It forms the chloride such as haloform, can substantially reduce after sterilization the chlorine disinfection by-product such as haloform (THMS) in water.
Clear water after processed by the invention rises to reuse water spot through pumping, it is impossible to the direct outer row of reuse, carries out farmland Pour.
After advanced treating of the present invention, its effect is as follows(Referring to following table):
Waste water after deep treatment of the present invention can also meet production process recycle-water while wastewater discharge standard is met The requirement of water quality.
Brief description of the drawings:
Fig. 1 is the structured flowchart of the paper-making industry advanced waste treatment system of the present invention.
Embodiment:
The present invention is made further explanation and description with specific embodiment below in conjunction with the accompanying drawings:
Embodiment 1:Referring to Fig. 1, a kind of paper-making industry advanced waste treatment system, including the coagulating basin 1, heavy connected successively by pipeline Shallow lake pond 2, sand filter 3, sterilization pool 4 and clear water reserviors 5, are provided with the first chemicals dosing plant 6, in sedimentation basin upper end in the upper end of coagulating basin 1 The second chemicals dosing plant 7 is provided with, the upper end of sterilization pool 4 is provided with the 3rd chemicals dosing plant 8.
Embodiment 2:Paper-making industry advanced waste treatment system described in embodiment 1 carries out the processing side of advanced treating to waste water Method, it is comprised the following steps that:
1. the discharge of wastewater after biochemical treatment is added in right amount into coagulating basin 1 by the first chemicals dosing plant 6 into coagulating basin 1 Coagulant, regulation waste water pH value is 6.0~9.0;
2. the waste water emitted from coagulating basin 1 is entered in sedimentation basin 2, is added by the second chemicals dosing plant 7 to sedimentation basin 2 Appropriate decolorising agent, stands after stirring, and carries out separation of solid and liquid;
3. the waste water emitted from sedimentation basin 2 is entered in sand filter 3, crosses the suspended material filtered to remove in waste water;
4. the discharge of wastewater emitted from sand filter 3 is added into sterilization pool 4 by the 3rd chemicals dosing plant 8 into sterilization pool 4 Enter appropriate disinfectant, carry out disinfection processing;
5. the clear water emitted from sterilization pool 4, which is entered, carries out stewing process in clear water reserviors 5;
6. the clear water in clear water reserviors 5 carries out cycling and reutilization through pumping to recycle-water point.
Wherein:Described coagulant is industrial aluminum sulphate, and described decolorising agent is lipase, and described disinfectant is two Chlorine monoxid.
Waste water after deep treatment of the present invention can also meet production process and return while wastewater discharge standard is met With the requirement of water water quality.

Claims (3)

1. a kind of paper-making industry advanced waste treatment system, it is characterised in that:The paper-making industry advanced waste treatment system include according to The secondary coagulating basin connected by pipeline(1), sedimentation basin(2), sand filter(3), sterilization pool(4)And clear water reserviors(5), the coagulating basin (1)Upper end is provided with the first chemicals dosing plant(6), the sedimentation basin upper end is provided with the second chemicals dosing plant(7), the sterilization pool (4)Upper end is provided with the 3rd chemicals dosing plant(8).
2. the paper-making industry advanced waste treatment system described in claim 1 carries out the processing method of advanced treating to waste water, it has Body step is as follows:
1. the discharge of wastewater after biochemical treatment is to coagulating basin(1)In, pass through the first chemicals dosing plant(6)To coagulating basin(1)In plus Enter appropriate coagulant, regulation waste water pH value is 6.0~9.0;
2. from coagulating basin(1)In the waste water that emits enter sedimentation basin(2)In, pass through the second chemicals dosing plant(7)To precipitation Pond(2)Appropriate decolorising agent is added, is stood after stirring, separation of solid and liquid is carried out;
3. from sedimentation basin(2)In the waste water that emits enter sand filter(3)In, cross the suspended material filtered to remove in waste water;
4. from sand filter(3)In the discharge of wastewater that emits to sterilization pool(4)In, pass through the 3rd chemicals dosing plant(8)To sterilization Pond(4)Middle to add appropriate disinfectant, carry out disinfection processing;
5. from sterilization pool(4)In the clear water that emits enter clear water reserviors(5)Middle carry out stewing process;
6. clear water reserviors(5)In clear water through pumping to recycle-water point carry out cycling and reutilization.
3. processing method according to claim 2, it is characterised in that:Described coagulant is industrial aluminum sulphate, described Decolorising agent is lipase, and described disinfectant is chlorine dioxide.
CN201710672059.9A 2017-08-08 2017-08-08 Paper-making industry advanced waste treatment system and its processing method Pending CN107265785A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201710672059.9A CN107265785A (en) 2017-08-08 2017-08-08 Paper-making industry advanced waste treatment system and its processing method

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Application Number Priority Date Filing Date Title
CN201710672059.9A CN107265785A (en) 2017-08-08 2017-08-08 Paper-making industry advanced waste treatment system and its processing method

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Publication Number Publication Date
CN107265785A true CN107265785A (en) 2017-10-20

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108658339A (en) * 2018-06-20 2018-10-16 南京海洛阿姆生物科技有限公司 A kind of purifier and application method of the sterilizing deodorization of municipal sewage pond

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101337752A (en) * 2008-06-26 2009-01-07 中冶华天工程技术有限公司 Advanced treatment process for paper-making waste water
CN204211569U (en) * 2014-10-30 2015-03-18 苏州科环环保科技有限公司 A kind of paper waste advanced treatment apparatus
CN106396252A (en) * 2016-08-29 2017-02-15 浙江远大纸业有限公司 Papermaking sewage depth biochemical treatment method

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101337752A (en) * 2008-06-26 2009-01-07 中冶华天工程技术有限公司 Advanced treatment process for paper-making waste water
CN204211569U (en) * 2014-10-30 2015-03-18 苏州科环环保科技有限公司 A kind of paper waste advanced treatment apparatus
CN106396252A (en) * 2016-08-29 2017-02-15 浙江远大纸业有限公司 Papermaking sewage depth biochemical treatment method

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108658339A (en) * 2018-06-20 2018-10-16 南京海洛阿姆生物科技有限公司 A kind of purifier and application method of the sterilizing deodorization of municipal sewage pond

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Application publication date: 20171020