KR102556399B1 - High resistance adhesives using ionic compounds and products using them - Google Patents

Abstract

The present invention relates to high-resistance adhesives and paints using ionic compounds, and products to which they are applied, and more particularly, to devices (products) that use electricity in low-humidity environments such as winter or clean rooms. It improves the generation of static electricity by electric field or frictional force, and aims to create a pleasant environment by attenuating the electric field by high resistance and imparting antibacterial, anti-mildew, and flame retardancy.
To this end, in the present invention, an ionic compound was used as a main additive and mixed with a water-soluble adhesive and paint to impart adhesiveness.

Description

High resistance adhesive composition using ionic compounds and products applied thereto {High resistance adhesives using ionic compounds and products using them}

An object of the present invention is to impart antistatic properties, antibacterial properties, antifungal properties (antifungal), and flame retardant properties by using the properties of ionic compounds.

Chemistry is broadly classified into physical chemistry, organic chemistry, inorganic chemistry, and analytical chemistry, but since the late 20th century, as interdisciplinary research and application in each specific field has expanded, the boundaries have largely disappeared. In the 21st century, polymer chemistry is included in the above fields to be divided into core areas and multidisciplinary areas such as agriculture, environment, geochemistry, biochemistry, and material/nanochemistry. Here, ionic compounds belong to inorganic chemistry as compounds not dealt with in organic chemistry, and are compounds composed of sequential arrangements of ions having opposite charges. It has inherent resistance, antibacterial properties, antimicrobial properties, and flame retardant properties, so that antistatic function, antibacterial and antimicrobial functions against bacteria or mold strains such as Escherichia coli, and flame retardant function by digestion during ignition are also exhibited.

An ionic compound, which is a subject of the present invention, is a compound composed of ions having opposite charges by electrostatic force through ionic bonding, and the compound is electrically neutral. When H ₂ O enters this compound, it dissolves and dissociates into cations and anions.

According to the above principle, antistatic function, antibacterial, anti-mildew, and flame retardant functions are exhibited in a complex manner.

As the technology behind the invention, first, water-soluble adhesives focused on improving adhesion and workability, but polymeric substances such as adhesives are mostly insulating materials and are widely used in various construction and electrical/electronic parts. Static electricity accumulates on the plastic surface, causing an electrification phenomenon. This electrification phenomenon adsorbs dust or dirt and can lead to production failure and disasters in the industrial field. Conventional technologies for preventing electrification of plastics include adding conductive fillers, antistatic agents, surfactants, and conductive polymers. known to be the most efficient. However, among the products commercialized in the past, surface resistance is high, and antistatic performance is remarkably deteriorated, or the price of additives is high for general use. Table 1 shows applicable fields according to surface resistance.

surface resistance phenomenon Characteristics and Applications >10 ¹³ charge accumulated Isolation 10 ¹³ ~ 10 ¹² battleship Prevention of interference in static state 10 ¹² ~ 10 ¹⁰ charged but attenuated Debris protection in dynamic conditions 10 ¹⁰ ~ 10 ⁸ hardly ever fight Antistatic I (with antistatic performance) 10 ⁸ to 10 ⁵ hardly ever fight Antistatic II (partial electromagnetic wave shielding) <10 ⁵ do not charge electromagnetic wave shield, electromagnetic wave blocking

In the case of antibacterial and anti-mildew, fine dust, bacteria, mold, etc. in indoor air not only cause allergic diseases or respiratory diseases, but also sometimes cause pulmonary tuberculosis or infectious diseases. To prevent this, in the previous method of imparting antibacterial function, organic antimicrobial agents with excellent initial antibacterial inhibition or inorganic antimicrobial agents with excellent thermal stability were used in plastics, but they exhibit high antibacterial performance against Escherichia coli, but against fungi The anti-fog properties are declining.

Therefore, it is expected that the ionic compound component of the present invention has (+) and (-) ionic properties at the same time to exhibit antistatic (including electric field attenuation), antibacterial and antifog, and flame retardant effects.

An object of the present invention is to impart antistatic properties, antibacterial and antiseptic properties, and flame retardant properties by using the properties of ionic compounds.

Static electricity is generated by electrification, and instantaneous discharge damages products or facilitates dust adhesion, so antistatic properties are required. Therefore, it is important to prevent separation of static electricity (charge) to prevent static electricity. Charge separation means movement under the action of an external force, and materials with high dielectric constant are used to reduce the electric field caused by charge separation, or materials with good conductivity are used to prevent charging by increasing the speed of charges. However, materials that are easily absorbed by charge should be used. Currently, antistatic treatment is performed using surfactants or conductive polymers as widely used antistatic agents, but films treated with commercially available surfactant coating solutions have a high surface resistance of 10 ⁹ ~10 ¹² Ω/□ In the case of using a conductive polymer alone, it has been an obstacle to generalization due to expensive raw material prices so far.

And looking at the known antibacterial mechanisms, ① a mechanism is known to inhibit the growth of microorganisms due to the formation of ions-S by reacting with -SH groups of cysteine, one of the amino acids constituting proteins, and ions, and ② substances of microorganisms. The mechanism of inducing the generation of active oxygen in metabolism to act as an antibacterial, ③ the mechanism of inactivation by releasing ions in the membrane of microorganisms by ions, and the mechanism of preventing cell division by reacting with bases present in microorganisms are known. (Source: Korean J. Microbiol. Biotechnol. Vol. 39, No. 1, 18 (2011). In addition to the strains mentioned above, it is known that there are about 300 types of fungi that occur in general living environments, which are a type of microorganisms. Among them, the most harmful mold to humans is black mold, and mold spores can easily float in the air, and when the indoor temperature where people live is 20 ~ 30 ℃, which is optimal for mold growth, mold in a spore state rapidly grows. Characteristic of propagation by spreading spores.Generally, fungi start basic growth at 80~90%RH and vigorously grow at 90%RH or higher.In addition, molds are characterized by carbon and nitrogen, which are the main components of building polymers. It is often propagated as a nutrient, various soap ingredients used in the bathroom are rich in nutrients that mold likes, and various dead skin cells generated from humans are also said to be nutrients of mold. E. coli is known as the cause of food poisoning, and lives with these bacteria in daily life.To prevent these bacteria, research and development have been conducted to suppress them using antibiotics or metal-based antibacterial substances.

However, in the present invention, it is intended to exert antibacterial ability by using ionic materials in addition to the above materials. The ionic material is non-toxic and harmless to the human body, and is expected to exert an antibacterial effect by suppressing the metabolic function of microorganisms. In addition, it is expected to have antibacterial and antibacterial effects by affecting the reproductive function of microorganisms due to the electrical characteristics of ions.

In addition, there is a flame retardant property as another property pursued in the present invention. Currently, flame retardants containing halogen-based, antimony-based, inorganic-based, phosphorus-based, and nitrogen-phosphorus-based flame retardants as main components are used in the manufacture of building materials and polymer (plastic) flame retardant resins. Most of the polymer materials are composed of organic materials, so they are easily combustible. In order to impart flame retardant properties to polymers, the above-listed flame retardants are said to exhibit flame retardant properties by the following mechanism. ① Halogen-based flame retardant; Halogen-based flame retardants act in the gaseous phase, and -OH, -H, which are active radicals that play a role in propulsion of combustion, are captured by HX, a halogen compound, in the combustion process to exert their flame retardant effect. HX also has the effect of diluting combustible gas and blocking oxygen by generating incombustible gas. In addition, halogen-containing flame retardants show a flame retardant effect even in the solid phase, and HX acts as an oxidation catalyst for combustible materials, and the oxidized materials form a ring structure, resulting in the production of carbon compounds, which block oxygen and latent heat. It serves to help keep combustible materials below the combustion zone. ② phosphorus-based flame retardant; It has an excellent flame retardant effect in solid phase reactions, and is particularly effective in plastics containing a large amount of oxygen. First, polyphosphoric acid is produced by thermal decomposition, which is esterified and dehydrogenated to produce charcoal, and it is known that the charcoal thus produced blocks oxygen and heat. It is non-toxic and thermally stable, but when in contact with water, it is highly toxic and releases phosphine gas, which is explosive in confined spaces, so care is required. ③ Inorganic flame retardant; There are aluminum hydroxide, antimony oxide, magnesium hydroxide, etc. It is not volatilized by heat and decomposes to release incombustible gases such as water, carbon dioxide, sulfur dioxide, and hydrogen chloride. Most of the endothermic reactions, in the gas phase, flammable gases are diluted and applied to the plastic surface to prevent access of oxygen and at the same time, an endothermic reaction on the solid surface. Through this, it has the effect of reducing the formation of plastic cooling and thermal decomposition products. ④ flame retardant enhancer; ⓐ silicone-based additives; It is known that when 1 to 5% of silicone-based additives are added to thermoplastic or thermosetting polymers, there is a synergistic effect on flame retardancy. Silicone-based additives reduce heat emission, emission of toxic gases such as carbon monoxide and smoke. It is said that the amount of heat released is reduced when silicone-based additives are added to polystyrene. ⓑ P/Br compounds; As a result of application to PC/PBT (2:1), it is said that there was an excellent flame retardant effect. In order for each plastic to exhibit flame retardancy of UL94 V-0, 12~13% of flame retardant is required, but in the case of P/Br compound, 6~ It is known that flame retardancy can be imparted with only 7% of the flame retardant. © Zinc borate; When zinc borate and aluminum trihydrate are added to hard PVC, smoke generation can be significantly reduced. In this case, it is said that the maximum smoke generation density can be lowered from 563 to 285. ⑤ chlorine-based flame retardant; There are chlorinated paraffin, chlorinated polyethylene, and aliphatic chlorine-based flame retardants. In the case of chlorine-based paraffin and polyethylene, the price is low, but thermal stability is weak. In the case of aliphatic flame retardants, the price competitiveness is low and the flame retardant efficiency is low compared to brominated flame retardants. (Source; http://eunsungfc.com/main.htm) Among the flame retardants, brominated and chlorinated flame retardants are emerging as a necessity to develop new eco-friendly flame retardants due to the emission of toxic gases, and therefore, the present invention exhibits the above effects in combination. While doing so, it is human body-friendly and makes it possible to create a pleasant indoor environment.

The present invention relates to a high-resistance adhesive and paint using an ionic compound, and to a product applying the same, and an object of the present invention is to create a comfortable environment by imparting antistatic and electric field attenuation, antibacterial, anti-fog, and flame retardant properties due to high resistance.

To this end, acrylic emulsion-based adhesives (Acrylic emulsion), epoxy emulsion-based adhesives (epoxy emulsion), polyvinyl acetate and emulsion-based adhesives (Poly Vinyl Acetate and emulsion), and urethane-based adhesives (Urethane) are used as water-soluble adhesives with a solid content of 5 to 59% by weight , Silicone adhesive, EVA (Ethylene Vinyl Acetate) adhesive, resorcinol adhesive (Resorcinol), α-olefin adhesive (α-Olefin), vinyl chloride resin adhesive (Polyvinyl chloride), isocyanate adhesive ( Isocyanate), a composition (I) in which 10 to 95% by weight of a phenolic resin adhesive (Phenolic) is mixed alone or two or more,

Rice, wheat, bran, corn, potato, 15 to 40% by weight of solids grass made of grains such as dextrin alone or 5 to 95% by weight of a mixture of two or more compositions (II),

Composition (III) obtained by mixing 10 to 95% by weight of composition (II) with composition (I) at a ratio of 1: 0.2 to 10;

As a solvent, non-toxic water or alcohol is used in an amount of 0 to 50% by weight,

In these compositions, solid content of 5 to 80% by weight of ionic compound I - In the ionic compound used in the present invention, metal cations and non-metal anions are bound by electrostatic attraction, and the sum of charges is electrically neutral. - + The divalent or higher cation metal element may include one or more from the group consisting of Co, Cu, Ni, Mn, Zn, Fe, Al, Be, Mg, Ca, Ba, etc., and the anion element may be fluoride anion, bromide anion, Iodide anion, sulfide anion, chloride anion, ammonium anion, hydroxide anion, sulfate anion, carbonate anion, nitrate anion, phosphate anion, permanganate anion, acetate ion, hydrogencarbonate anion, borate anion, chromate anion, dichromate anion, halogen anion, hydrochloric acid and at least one selected from the group consisting of anions, organic acid anions, and the like. Ammonium salts may be additionally included in consideration of corrosion of equipment and solution stability, and 2 to 50% by weight of these materials alone or two or more in the form of hydrates or aqueous solutions are used. Ionic Compound II with a solid content of 5 to 80% by weight uses a +monovalent cation metal and a -monovalent or -divalent anion, and the cationic metal element belonging thereto is one or more selected from the group consisting of Li, Na, K, etc. The anion element may be fluoride anion, bromide anion, iodide anion, sulfide anion, chloride anion, ammonium anion, hydroxide anion, sulfate anion, carbonate anion, nitrate anion, phosphate anion, permanganate anion, acetate ion, hydrogen carbonate It contains at least one selected from the group consisting of anion, boric acid anion, chromic acid anion, dichromate anion, halogen anion, hydrochloric acid anion, organic acid anion, etc., and 2 to 50% by weight of these substances alone or two or more in the form of a hydrate or an aqueous solution 0.1 to 50% by weight of a solid conductive polymer (Conductive Polymer; Polythiophene, PEDOT-PSS, Polyaniline, Polypyrrole), 100% solid silica and alumina, and an adhesive composition containing 2 to 50% by weight of these materials alone or a mixture of two or more

Anti-static, anti-bacterial, anti-mildew, flame retardant composition prepared by mixing at a stirring speed of 30 to 20,000 rpm and a stirring time of 5 minutes to 3 hours, and applied to various products such as adhesives, paints, wallpaper, furniture, flooring, curtains, and blinds. It is characterized by doing.

As described above, the high-resistance adhesive and paint using the ionic compound of the present invention, and products applied thereto, are transparent or translucent, yet exhibit antistatic performance and electric field attenuation effect, and at the same time have antibacterial properties, anti-mildew properties, and flame retardant properties. It is characterized by a combination of functions.

1 is a surface resistance measurement result for a sheet manufactured by the present invention.
Figure 2 is the surface resistance measurement results for the sheet produced by the present invention.
Figure 3 is an electric field measurement result (E-tester) after coating with a conventional adhesive.
4 is an electric field measurement result (E-tester) after coating with an adhesive prepared according to the present invention.
Figure 5 is an antibacterial test result for the sheet produced by the present invention.
FIG. 6 sequentially shows pictures taken as motion pictures of a combustion test for a conventional wallpaper and a wallpaper coated with the adhesive of the present invention.
Figure 7 is sequentially shown following Figure 6.

The present invention is a water-soluble adhesive material having a solid content of 5 to 59% by weight, such as acrylic emulsion or epoxy emulsion adhesive, polyvinyl acetate and emulsion adhesive (Poly Vinyl Acetate and emulsion), urethane adhesive ( Urethane), silicone adhesive (Silicone), EVA (Ethylene Vinyl Acetate) adhesive, resorcinol adhesive (Resorcinol), α-olefin adhesive (α-Olefin), polyvinyl chloride adhesive, isocyanate adhesive (Isocyanate), 10 to 95% by weight of a phenolic resin adhesive (Phenolic) alone or a mixture of two or more (I), 15 to 40% by weight of solids made of grains such as rice, wheat, bran, corn, potato, and dextrin Composition (II) obtained by mixing % pools alone or 5 to 95% by weight of two or more, composition (III) obtained by mixing 10 to 95% by weight of composition (II) with composition (I) at a ratio of 1: 0.2 to 10, and these In the composition, solid content 5-80% by weight ionic compound I 2-50%, solid content 5-80% ionic compound II 2-50% by weight, solid content 0.1-50% by weight Conductive polymer (Polythiophene, PEDOT) -PSS, Polyaniline, Polypyrrole), 100% solid silica and alumina, a composition in which an adhesive composition mixed with 2 to 50% by weight of these materials alone or two or more is mixed at a stirring speed of 30 to 20,000 rpm and a stirring time of 5 minutes to 3 hours manufactured.

The ionic compound I may include one or more from the group consisting of +2-valent or higher cation metal elements Co, Cu, Ni, Mn, Zn, Fe, Al, Be, Mg, Ca, Ba, etc., and the anion element is fluorinated anion, bromide anion, iodide anion, sulfide anion, chloride anion, ammonium anion, hydroxide anion, sulfate anion, carbonate anion, nitrate anion, phosphate anion, permanganate anion, acetate ion, hydrogencarbonate anion, borate anion, chromate anion, dichromate anion , At least one selected from the group consisting of halogen anion, hydrochloric acid anion, organic acid anion, etc. was used, and the ionic compound II used a +monovalent cation metal and a -monovalent or -divalent anion, a cationic metal belonging thereto and at least one selected from the group consisting of elements Li, Na, K, etc., and the anion element is fluoride anion, bromide anion, iodide anion, sulfide anion, chloride anion, ammonium anion, hydroxide anion, sulfate anion, carbonate anion , nitrate anion, phosphate anion, permanganate anion, acetate ion, hydrogen carbonate anion, borate anion, chromic acid anion, dichromate anion, halogen anion, hydrochloric acid anion, organic acid anion, etc. .

As the solvent, 0 to 50% by weight of non-toxic water or alcohol was used.

The present invention prepared as described above has a surface resistance of 10 ^{4 to 9} Ω/□, and exhibits functions of attenuating electromagnetic waves generated from fluorescent lamps and light bulbs, as well as antibacterial, anti-mildew, and flame retardant functions.

Hereinafter, surface resistance, antibacterial, antifog, and flame retardant performance will be described based on examples of the object pursued in the present invention according to the solid content and content among the materials listed above.

The adhesive having the electromagnetic wave attenuation function of the present invention contains 19% by weight of solid content, 57% by weight of water-soluble adhesive material, 50% by weight of solid content, 13% by weight of ionic compound I, 20% by weight of solid content, 15% by weight of ionic compound II, and 15% by weight of water. It was prepared by mixing at a stirring speed of 500 rpm and mixing for 1 hour. The surface resistance of the prepared adhesive is measured as a result of measurement under measurement conditions 20.4±2℃, 23±2%RH, test equipment Surface Resistance Meter SRM ^ⓡ 110 (serial No. 20148096), D ₁ =17cm, D ₂ =17cm. As shown in Fig. 1, it was 10 ⁷ Ω/□.

In the same manner as in Example 1, the adhesive having the electromagnetic wave attenuation function of the present invention was prepared by adding 23 wt% of solids to 66 wt% of water-soluble adhesive material, 50 wt% of solids to 14 wt% of ionic compound I and 20 wt% of solids to 20 wt% of ionic compound II. The surface resistance of the adhesive prepared by adding weight% was measured at 19.9 ± 2 ℃, 25 ± 2% RH, test equipment Surface Resistance Meter SRM ^ⓡ 110 (serial No. 20148096), D ₁ = 17cm, D ₂ = 17cm As a result of the measurement, it was 10 ⁷ Ω/□, and is shown in FIG. 2 .

For the purpose of visually checking the degree of electric field attenuation generated by the lamp after application with the adhesive of the present invention, a test on the case of applying wallpaper without applying to a wooden box (FIG. 3) and the case of applying wallpaper after application (FIG. 4) was carried out. Measurement conditions 19.9 ± 2 ℃, 25 ± 2% RH, test equipment was measured using an E-Tester manufactured by Pulse. As shown in Figures 3 and 4, the box without the adhesive of the present invention shows 130V / m, but the box coated with the present invention was measured to be attenuated to 0V / m.

In order to verify the antibacterial effect of the adhesive prepared in Example 2, which is another object of the present invention, a strain test was conducted on Escherichia coli and the like by requesting a test institute. In this experiment, the antibacterial activity value of Staphyococcus aureus ATCC 658P was 2.55 in the test standard JIS Z 2801-2010, standard film sterilized PP film, and 0.1mL of inoculum solution, and 3.1 for E. coli (Escherichia coli ATCC 8739). As shown in Figure 5 antibacterial results. It was confirmed that the ionic compound used in the present invention had antibacterial performance, as the bacteria were destroyed by more than 99%.

In addition, as a result of the experiment using bread to test whether or not to suppress mold, it was confirmed that there is also an anti-mildew effect as shown in FIG. 6.

The adhesives prepared by Examples 1 and 2 had flame retardant properties. In the adhesive used in the present invention, ionic compounds I and II can be mixed not only in a liquid state but also in a solid powder form, and an adhesive having a flame retardant action, which is another object of the present invention, was also possible. When the ionic compound comes into contact with a flame, it is possible to exhibit a flame retardant action by being a material having a flame retardant effect due to the inherent properties of the material itself.

To determine the correlation between flame retardancy and surface resistance. As a result of measurement using the measurement conditions 19.9℃, 25% RH, test equipment Surface Resistance Meter SRMⓡ110, surface resistance 10 ^9~11 Ω/ when less than 3% by weight of ionic compound I and less than 3% by weight of ionic compound II Antistatic properties and ignition delay were poor with □, and antistatic properties and ignition delay were excellent at 18% by weight of ionic compound I and 3% by weight of ionic compound II at 10 ^{4 ~ 5} Ω / □, but the adhesive strength was slightly lowered. there was Therefore, 3 to 18% by weight of ionic compound I and 3 to 10% by weight of ionic compound II are mixed. In particular, it is preferable to apply 4 to 12% by weight of ionic compound I and 4 to 7% by weight of ionic compound II. will do

Based on Example 1, the prepared adhesive was applied to the surface of the paper wallpaper, and an ignition test was performed. In FIGS. 7 and 8, the uncoated paper wallpaper and the paper wallpaper coated with the adhesive of the present invention were ignited under the same conditions. As a result, the paper wallpaper was completely burned down, but the one according to the present invention was turned off immediately after ignition. Therefore, the excellent flame retardancy of the present invention could be confirmed.

Claims (5)

Regarding the composition (III) in which the composition (I) containing the water-soluble adhesive and the composition (II) containing the grass made of grain were mixed in a weight ratio of 1: 0.2 to 10,
3 to 18% by weight of ionic compound I, which combines metal cations with +2 or higher valence and non-metal anions, and is added in the form of an aqueous solution;
3 to 10% by weight of Ionic Compound II, which is a combination of +1 or more valent metal cations and -1 or -2 valent anions, added in the form of an aqueous solution;
It is prepared by mixing 0.1 to 50% by weight of a conductive polymer,
The water-soluble adhesive includes acrylic emulsion, epoxy emulsion, polyvinyl acetate and emulsion, urethane, silicone adhesive, EVA (Ethylene Vinyl Acetate)-based adhesive, resorcinol-based adhesive (Resorcinol), α-olefin-based adhesive (α-Olefin), vinyl chloride resin-based adhesive (Polyvinyl chloride), isocyanate-based adhesive (Isocyanate), phenol resin-based adhesive (Phenolic ) alone or in combination,
Grasses made from the above grains include rice, wheat, bran, corn, potato, dextrin alone or two or more,
The +2 or higher valent metal cation of the ionic compound I is at least one selected from the group consisting of Co, Cu, Ni, Mn, Zn, Fe, Al, Be, Mg, Ca, and Ba, and the non-metal anion is fluorinated anion, bromide anion, iodide anion, sulfide anion, chloride anion, ammonium anion, hydroxide anion, sulfate anion, carbonate anion, nitrate anion, phosphate anion, permanganate anion, acetate ion, hydrogencarbonate anion, borate anion, chromate anion, dichromate anion , At least one selected from the group consisting of halogen anions, hydrochloric acid anions, and organic acid anions,
In the ionic compound II, the metal cation having a valence of +1 or more is at least one selected from the group consisting of Li, Na, and K, and the -1 or -2 valent anion is a fluoride anion, a bromide anion, an iodide anion, a sulfide anion, Chloride anion, ammonium anion, hydroxide anion, sulfate anion, carbonate anion, nitrate anion, phosphate anion, permanganate anion, acetate ion, hydrogencarbonate anion, borate anion, chromic acid anion, dichromate anion, halogen anion, hydrochloric acid anion, and organic acid anion At least one selected from the group,
The conductive polymer is characterized in that it contains Polythiophene, PEDOT-PSS, Polyaniline, Polypyrrole alone or two or more
High-resistance adhesive composition using an ionic compound.
According to claim 1,
The ionic compound I includes Ca as a cation and chloride anion as an anion,
The ionic compound II is characterized in that it contains Na as a cation and chloride anion as an anion
High-resistance adhesive composition using an ionic compound.
Regarding the composition (III) in which the composition (I) containing the water-soluble adhesive and the composition (II) containing the grass made of grain were mixed in a weight ratio of 1: 0.2 to 10,
3 to 18% by weight of ionic compound I, which combines metal cations with +2 or higher valence and non-metal anions, and is added in the form of an aqueous solution;
3 to 10% by weight of Ionic Compound II, which is a combination of +1 or more valent metal cations and -1 or -2 valent anions, added in the form of an aqueous solution;
It is prepared by mixing 0.1 to 50% by weight of conductive polymer at a stirring speed of 30 to 20,000 rpm and a stirring time of 5 minutes to 3 hours,
The water-soluble adhesive includes acrylic emulsion, epoxy emulsion, polyvinyl acetate and emulsion, urethane, silicone adhesive, EVA (Ethylene Vinyl Acetate)-based adhesive, resorcinol-based adhesive (Resorcinol), α-olefin-based adhesive (α-Olefin), vinyl chloride resin-based adhesive (Polyvinyl chloride), isocyanate-based adhesive (Isocyanate), phenol resin-based adhesive (Phenolic ) alone or in combination,
Grasses made from the above grains include rice, wheat, bran, corn, potato, dextrin alone or two or more,
The +2 or higher valent metal cation of the ionic compound I is at least one selected from the group consisting of Co, Cu, Ni, Mn, Zn, Fe, Al, Be, Mg, Ca, and Ba, and the non-metal anion is fluorinated anion, bromide anion, iodide anion, sulfide anion, chloride anion, ammonium anion, hydroxide anion, sulfate anion, carbonate anion, nitrate anion, phosphate anion, permanganate anion, acetate ion, hydrogencarbonate anion, borate anion, chromate anion, dichromate anion , At least one selected from the group consisting of halogen anions, hydrochloric acid anions, and organic acid anions,
In the ionic compound II, the metal cation having a valence of +1 or more is at least one selected from the group consisting of Li, Na, and K, and the -1 or -2 valent anion is a fluoride anion, a bromide anion, an iodide anion, a sulfide anion, Chloride anion, ammonium anion, hydroxide anion, sulfate anion, carbonate anion, nitrate anion, phosphate anion, permanganate anion, acetate ion, hydrogencarbonate anion, borate anion, chromic acid anion, dichromate anion, halogen anion, hydrochloric acid anion, and organic acid anion At least one selected from the group,
The conductive polymer is characterized in that it contains Polythiophene, PEDOT-PSS, Polyaniline, Polypyrrole alone or two or more
Method for producing a high-resistance adhesive composition using an ionic compound.
A product to which the high-resistance adhesive composition of claim 1 or 2 is applied.
According to claim 4,
The product is a product applied with a high resistance adhesive composition, characterized in that any one of paint, wallpaper, furniture, flooring, curtains, blinds.

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