KR20220083958A - A composition which exhibits a composite or selective effect of adhesion strengthening, freeze protection, antimicrobial, antifungal, antistatic, corrosion prevention performance depending on the mixing ratio of additive materials, type of additive material, and an application II - Google Patents

Abstract

The present invention relates to a composition and application products using the same, which complexly or selectively/selectively exhibit anti-freezing, antibacterial/mildew, electromagnetic wave absorption, electromagnetic wave blocking, flame retardant, and corrosion prevention performance according to the type of additive material and the mixing ratio of the additive material, The product manufactured by the composition and manufacturing method of the present invention has a property of lowering the freezing point and increasing the boiling point among the components of the composition, generally causing product and construction damage due to heat in sub-zero weather, but the present invention is Excellent in preventing loss of adhesion due to its antibacterial properties, antibacterial/mildew suppressing various types of bacteria, electromagnetic wave (electric field) blocking and extinction due to electrical properties, removal of fine dust attached to the product surface by antistatic properties, air quality purification, electromagnetic wave There is a desensitizing effect, and plastics are mostly composed of organic materials, so they are more susceptible to fire than concrete or metal panels because they are easily combustible. Another feature is that it is a complementary product with a wall, floor, and ceiling, and in the case of a plastering product, which is one of the composition products of the present invention, it prevents various types of bacteria and mold, electromagnetic wave shielding, prevention of heat during construction, and prevention of ignition by semi-incombustibility. It is characterized in that it is a product that contributes to In particular, in the present invention, it is one of the very important characteristics that the health and convenience of workers and the comfort after construction are promoted in the manufacturing method and process for producing the product having environmental and human compatibility of the present invention.

Description

A composition that exhibits complex, selective and selective performance of strengthening adhesion, anti-freezing, anti-bacterial/mildew, anti-static, flame-retardant, and anti-corrosion performance according to the type of additive and the mixing ratio of additives, and application products using the same II {A composition which exhibits a composite or selective effect of adhesion strengthening, freeze protection, antimicrobial, antifungal, antistatic, corrosion prevention performance depending on the mixing ratio of additive materials, type of additive material, and an application II}

The present invention relates to a composition that exhibits complex, selective, and selective performance of strengthening adhesion, anti-freezing, anti-bacterial, anti-mild, anti-static, flame-retardant, anti-corrosion, humidity control, and rust prevention according to the type of additive and the mixing ratio of the additive, and a composition using the same Through the application, it has the following adhesive strength, anti-freeze, antibacterial/mildew (mixed and used depending on the context in the sense of mildew), flame-retardant, anti-corrosion, humidity control, and anti-rust performance in combination or selectively/selectively. It is generated in general residential environments, offices, factories, electric/electronic products, transportation means, etc. using electric, electric/electronic parts (products) and communication parts (products) and means, motors (rotors), etc. It is intended to reduce adverse effects such as bacteria, static electricity (electrostatic and electromagnetic waves), fire, etc. (packaging) and electronic product cases (eg, mobile phone cases), etc. to strengthen adhesion according to complex and selective/selective functions, anti-freeze, antibacterial/mildew, antistatic. It is to give functionality to adhesives and finishing materials, shielding materials, and resin compounds used for flame retardant abnormal (flame retardant), corrosion prevention, humidity control, and rust prevention.

Therefore, the fields to which the present invention having complex and each selection/selective function can be applied are as follows.

① In cold weather, when building, construction, construction, chemical, material, etc. industrial sites, product manufacturing, interior, etc., and before construction and drying, the material (product or construction material) freezes or freezes during distribution and storage, and the adhesive ability is reduced. Fields that need to prevent falling, ② Areas where it is necessary to prevent damage from freezing in sub-zero weather for various water-soluble products, ③ Areas with poor ventilation or high humidity such as beaches and rivers, and poor insulation In a place where the temperature difference between the outside air and the inside temperature occurs, the humid air attaches to the wall, causing dewdrops or condensation. Areas (places) or fields that need to suppress the occurrence and growth of bacteria and mold generated by pollution, ④ Used (plastic) as a new lightweight material for various industries such as construction, electricity, electronics and automobiles In case of fire caused by the use of foam, flame retardant with reinforced flame retardant properties (hereinafter referred to as flame retardant. Flame retardancy is generally known to correspond to flame retardant class 3) in consideration of safety in case of fire, and fields and various plastics that require almost non-combustibility. , papers, etc. are mostly composed of organic and pulp materials, so they are used for products with easy-to-combust properties, in areas requiring flame retardant properties, ⑤ in areas where it is difficult to remove fine dust (dust) adhering to the product surface due to insulation, and dust Fields that do not adhere to the surface of the product and cause defects, ⑥ Dust charged in the air can cause fatal injuries to the human body if it enters through the respiratory system (environment), ⑦ Electrical/electronic products or communication means , electric wires, electric lights, electric heaters, transformers, ballasts, distribution boards, repeaters, etc. due to the electrostatic properties (electromagnetic waves) generated from exposure to the human body may be adversely affected, and adverse effects caused by malfunction of electronic control devices due to static electricity Absorbing and diffusing electromagnetic waves (each or both of electric and magnetic fields) existing in space in fields requiring reduction, especially in electrification (electromagnetic waves) Because it is large enough, it is necessary to protect the human body and control devices from unnecessary/unnecessary electromagnetic environment, and it collects and removes electromagnetic waves scattered in the space by accumulating and removing them as slight heat in the resistive layer to prevent electromagnetic waves (electric fields) and static electricity. Industrial obstacles caused by electromagnetic waves, fields that need to reduce electromagnetic wave pollution, ⑧ In addition, the phenomenon of deterioration of properties and performance as a metal by combining with elements of a given environment such as metal to form a non-metal oxide is called metal corrosion, that is, due to the presence of an aqueous solution on the metal surface Corrosion caused by the action of a solution is wet corrosion, and the process of wet corrosion is generally due to electrochemical action. It can be applied to various fields such as prevention, bacteria and mold control, and removal of static electricity due to neutralization of charged environment or dust, such as air quality purification and charged dust removal, flame retardant (flame retardant) performance, corrosion prevention area, humidity control in space, rust prevention, etc. It relates to compositions and products (technology).

The present invention is based on clear evidence by establishing a scientific independent theory based on the inventor's experience and thought, and securing engineering data through repeated tests and measurements, as well as prior investigations on possible background technologies after thoroughly examining the phenomenon. The invention has been implemented.

The present invention is based on the strengthening of adhesion and anti-freezing function according to the type of additive and the mixing ratio of the additive, and it is equipped with antibacterial/mildew, antistatic, flame retardant, anti-corrosion, humidity control, and rust-preventive performance in a complex or selective manner. to make it possible; Water-soluble products can be manufactured even in cold weather (most water-soluble products are frozen in cold weather, that is, products are frozen at 0 ~ -5℃ or lower), and construction (work) is possible by preventing freezing, but there is no risk of damage to the construction product after construction ( For example, if paper glue is applied to the wallpaper, in cold weather, the applied paper glue freezes more easily than when it is packaged in a cloth, so there may be a problem with the wallpaper falling off the wall due to poor adhesion), storability (preservability), It reduces the adverse effects of various bacteria and fungi in a humid environment, reduces or eliminates static electricity caused by electromagnetic waves and static electricity emitted from various electrical and electronic products, and reduces the damage to human life caused by toxic gases and smoke in case of fire. "In accordance with the type of additive and the mixing ratio of additives, it is intended to select and select one or more of the properties such as flame retardancy (flame retardancy) for combustion gases and flames, which are direct factors, strengthening adhesion, freezing prevention, antibacterial, It relates to a composition that exhibits antistatic, flame-retardant, anti-corrosion, humidity control, and rust-preventing properties in a complex, selective and selective manner, and application products using the same. (For reference, Arabic numerals and units must be spaced for correct notation, but in the present invention, some are spaced and some are attached. For example, numbers and ℃ (degrees Centigrade), hr (hour), min (minute), sec (second), %(percent), weight %(weight %), g(gram), kg(kilogram), L(liter), ㏀(kiloohm), MeV(megaelectron volt), eV(electron volt), meV( millielectron volt), Ω/□ (ohm per square), Ω-cm (ohm-centimeter), μm, mm, cm, km (length units), g/cm3 (density unit), V/m (Volt per meter) ), %RH (% relative humidity), N/25mm (newton per 25 millimeter), cps (centi poise), GHz (frequency unit), rpm (revolution per minute), M/T (metric ton), etc. It is marked with a space (name) for easy viewing or attached, and dB (decibel) and atm (atmosphere) are marked with a space.

The materials, techniques, and problems that have been invented in the past, and the sources, current status, actual conditions, etc. of the functions pursued in the present invention are as follows.

(1) Adhesive strength and anti-freezing: Adhesives manufactured with water have serious problems due to freezing during construction, distribution and storage in cold weather. As a product containing water, there is, for example, a powder paste that is used by dissolving it in water as a way to prevent freezing among paints (paint), adhesives, and paper glue (or named wheat paste). This powdered paste (starch powder, corn powder, etc.) has strengths in that it does not freeze during distribution and by reducing its weight, but it does not completely unravel during operation, or in the case of powdered paste on sale, the solid content of adhesive strength is liquid paste (coating). As a paste, field workers call it wheat paste), so the adhesive strength is lowered, and there may be parts where the glue may partially aggregate. to be. This also requires the use of water, so if the coating material is coated with grass and applied to the wall in cold weather, there is a risk that the wallpaper may come off due to freezing before drying. ) to reduce the amount of water used in the city, which is the same as grass that is distributed (sold) with water. there may be Therefore, no matter how cheap the price of the painting pool is, when painting a large area, it can be an economic burden and a disadvantage in work. And, above all, adhesive strength is the basic. The present invention is intended to be invented for the purpose of improving adhesion in the same adhesive material rather than the conventional concept of strengthening adhesion according to the type of polymer.

(2) Antibacterial and anti-mildew properties (anti-fungal properties): In order to give antiseptic effect against bacteria and fungi to high molecular substances, which are prey of bacteria, active response to chemicals and moisture generated by moisture, etc. It was necessary to develop a product with antibacterial and anti-mildew functions that can remove it, and there are laws and regulations to minimize damage to the human body. According to the report, about 30% of all defects are in the finishing process, and 60% of repairs for finishing defects are due to mold (Table 1). Looking at the photos of mold fungus on the apartment wall (see Example 18) and mold fungus on the country house (refer to Example 18), a significant amount of mold is occurring, especially in places such as country houses in a humid environment. It can be seen that more and more mold bacteria are generated in

fault type number of cases defect rate mold fungus 127 61.3 exhilaration 37 17.8 dent, contamination 31 14.9 Etc 12 6.0 total 207 100%

(Source: Citing data from S Construction) As a solution to this, inorganic antibacterial agents and organic antibacterial agents are used to manufacture products with antibacterial effects. Antibacterial products are manufactured by adding organic or inorganic antibacterial agents to polymers (polyethylene, polypropylene, polyvinyl, epoxy, etc.) and tiles. Since an expensive antibacterial agent (company C) must be added, there is a problem of cost burden (disability to generalize) to apply in the case of large-area construction. Accordingly, the present invention is based on the scientific principle and experimental data first mentioned by the present inventors that substances added to impart functionality simultaneously inhibit bacteria and fungi, thereby exhibiting antibacterial and anti-mildew performance to inhibit Escherichia coli, Pseudomonas aeruginosa, mold, etc. Based on the description, it will be explained in the description and claims.

(3) Electromagnetic wave absorption and blocking: Electromagnetic wave is an inevitable problem that cannot be separated from civilized society. As the information society rapidly advances, the use of electric and electronic products increases significantly, and the problem of unnecessary and unnecessary electromagnetic waves from these devices is rising. It is known that there is a possibility that it could be caused. In addition, the fact that electromagnetic waves, which is called the fourth pollution following environmental pollution such as air pollution, water pollution, and noise pollution, cannot be felt even with the five senses (senses) adds to the severity, and also adds to the severity of malfunctions of peripheral devices and various diseases. There is a warning that it may cause Therefore, related technology development and products are being developed to cope with this, and expensive products (37,500 won/20g for S company E product in Naver search as of June 16, 2018 at the time of the first filing of the present invention) are mainly As a product applied for manufacturing electrical/electronic parts and for electromagnetic shielding, it has been found that it is difficult to apply due to high cost (price) when applying (work) over a large area.

(4) Antistatic property: Electric shock, that is, static electricity, electric shock caused by static electricity is remarkably weak, and it does not die from electric shock, but the work efficiency is reduced due to the static shock, the contact with the machine, or the stress caused by the fear. It causes secondary obstacles such as machine malfunctions, and damage to electronic parts (products). When the static electricity of the human body is a problem among the electrification phenomenon, which is one of the fields (products) to which the present invention is applied, the resistance of the human body is several kΩ to several thousand kΩ, so it can be regarded as a conductor electrically, but the human body is separated from the earth due to the shoes. In the insulated state, a type of capacitor is formed between the earth and the ground, and the static electricity on the conductor not only increases the capacitance, but also discharges the entire charge at one place, so it becomes a large discharge energy provider. In addition, there are two cases of electric shock to the human body, which occurs when a human body charged with static electricity is discharged in proximity to the ground or another charged object, and when a charged object approaches the human body and discharge occurs. In other words, it is known that it is difficult to prevent the generation of static electricity accumulated in a charged object because it is not only a shock to the human body, but also static electricity caused by instantaneous discharge is generated by friction and contact between substances. In order to prevent such an electrostatic disturbance, it is necessary to remove, neutralize, and leak the generated electric charge. As the information society rapidly advances, the use of electrical and electronic parts (products) increases significantly, and it is difficult to solve the malfunction of various products or the noise phenomenon of electrical and electronic devices and communication devices due to the electromagnetic fields generated from these devices. . In the meantime, countermeasures against this include grounding or shielding (shielding) in addition to using an inductor capacitor or an electronic component manufactured using ferrite. The shield, which is known to be the most effective among countermeasures, uses metal as an exterior material for general electrical and electronic products to exhibit high attenuation characteristics over a wide frequency band. There was an inevitable problem that had to be solved. Materials such as plastics are mostly used as insulating materials in various electrical and electronic parts (products), but these insulating properties cause static electricity to accumulate on the surface of plastics and cause electrification. This charging phenomenon adsorbs dust or dirt and leads to production disturbances and disasters in the industrial field, or it can cause product defects in semiconductors, electronic parts (products), fibers, films, etc. It may also cause malfunction. And when looking at the disturbance caused by static electricity (electric field among electromagnetic waves) and indirectly affecting the human body, there are currently few cathode ray tube type TVs, but the same phenomenon occurs with fluorescent lamps. Positive static electricity of ~10,000V flows. While this static electricity is discharged toward the earth, it attracts negative ions in the air, and as a result, the negative ions are neutralized and removed. At this time, since negative ions in the air are consumed, it becomes a cationic environment in which positive ions are relatively large in the indoor air. Therefore, in the living body, the intake of cations during respiration takes precedence. The composition of this cation is hydrogen ion (H ⁺ ), and when the concentration of hydrogen ions increases, body fluids including blood become acidic. Table 2 shows the actions of anions and cations. In particular, hydroxide ions (OH ^- ) formed by dissociation of water (H ₂ O) molecules are strong bases and are easily oxidized. Since the hydroxide ions are reduced in this way, the hydrogen ion concentration is relatively high, and in particular, positive static electricity leads to acidity of the body fluid. It is known that positive static electricity also increases free radicals in the body and acidifies the living body, so metabolism is disturbed and cell function is weakened. Therefore, static electricity and electromagnetic waves may disturb the mechanism of the living body. In other words, those lacking electrons are positively charged, so they are cations, and those with too many electrons are negatively charged, so they are called negative ions. Anions, called vitamins of air, exist together with cations in the atmosphere, such as carbon dioxide, oxygen, nitrogen, and hydrogen. People with weak constitutions in an atmosphere with a lot of positive ions are more likely to develop chronic diseases and exacerbate chronic diseases. Conversely, if there are a lot of negative ions, the cells become active, and the resistance to disease becomes stronger and the body can become a healthy weak alkaline constitution. Phenomenon that the human body can feel is the refreshing feeling of walking outside after a storm has passed, the feeling of standing in a waterfall, and the feeling of being in a pine forest. This may be because a large amount of negatively charged oxygen ions (negative ions) were generated by the ionization phenomenon (Leonard phenomenon) in which the surrounding air had a negative charge. Therefore, the reason you feel refreshed with negative ions is probably because of the abundance of negative ions that purify minute pollutants in the air. When the water of the waterfall falls and violently collides with the surrounding rocks, the water droplets are split into very small clusters (particles). If you measure the amount of ions in the air, you can see that negative ions are very abundant in forests or near waterfalls. When you come into contact with this nature, you feel refreshed. Positive ions are abundantly present in buildings, concrete, cities polluted with exhaust gas from automobiles and factories, cigarette smoke, OA (Office automation) office equipment, and electrical/electronic products such as computers. The phenomenon that nature generates negative ions is called the Leonard phenomenon, after the Nobel Prize-winning physicist Dr. Willib Leonard. Table 3 below shows the amount of negative ions generated by region based on waterfalls in the Americas, a Leonard phenomenon.

division Action negative ions Promote the supply of oxygen to cells and tissues cation Delays the delivery of oxygen, resulting in oxygen starvation

by region Anion generation [ions/cc] waterfall 50,000 Mountains 5,000 Country 1,500 Office 50

In addition, dust is charged as a kind of colloidal material, and if an ionic environment is created, it sticks to the colloid and removes the charge that the colloid has. It is said that charged dust, rather than uncharged dust, attaches to the respiratory system of the human body and does not fall off easily, causing respiratory disorders. Therefore, this anionic environment acts to neutralize the cationic dust. Denis L. Henshaw, Ph.D. reported an experiment showing that charged fine dust and charged air pollutants, such as radon, bacteria, and viruses, gather by electric charges existing in space. In the experiment, carcinogens were present in excess around the electric field. Based on this, it was explained that people who live near power lines have an increased risk of getting cancer. Using radon decay, aerosol was used to show the selective accumulation of aerosol on the surface of the electric field of power lines. Also, from the Uracil point of view, very low-energy electrons form uracil (a basic substance that is one of the components of ribonucleic acid). There is a lot of interest in whether it can destroy, how much radiation (alpha, beta, and gamma rays or heavy ions) can damage living cells, and the secondary particles that are generated as a result of the primary invasion of radiation. In particular, electrons with energies of several tens of electron volts (eV) were the subject of intense interest. In fact, it is said that about 40,000 electrons are generated when an energy of 1 MeV is applied. A large number of secondary particles quickly lose energy and attach to the water molecules in the cell as they solvate. Then, studies showing that lower electron energies of 20 eV or less, electrons in the 3-20 eV range cause significant detrimental damage to genes, including destruction of single-stranded and double-stranded DNA (Boudaiffa et al. Science). , Vol. 287, p. 1658, 2000). In the study of lower-energy secondary electrons, Tilmann Maerk of University Innsbruck and University Claude Bernard Lyon and colleagues scatter less than 1 eV electrons from a gaseous uracil molecular beam. Uracil is one of the base units of RNA molecules, and uracil is a crucial component in the cell. According to the study, scientists say that uracil is broken into pieces by electrons with an energy of only a few meV. It is said that it is not the kinetic energy of electrons that causes this decomposition, but the effect of the charge of electrons that changes the internal potential energy environment of uracil. An invention that minimizes the effect of electric charge, which is the source, is required by identifying the root cause through such scientific research and literature research, but a solution has not been secured because there are still many unsatisfactory parts or lack of a clear theory. In order to minimize the effect of charging, an antistatic composition in which at least one conductive material selected from the group consisting of conductive polymer, conductive carbon, and graphite, a polymer, a solvent, etc. are mixed is used, but in the case of a solvent, the volatility Therefore, caution is required for indoor use.

(5) Flame-retardant (flame-retardant): Flame-retardant material is almost identical to or very similar to that of flame-retardant material, so it is called flame-retardant. As a flame retardant material, when manufacturing a flame retardant composition with various polymers, generally flame retardant materials containing halogen-based, antimony-based, inorganic, phosphorus-based and nitrogen-phosphorus-based materials are added. The use of specialty products is gradually expanding. Polymers are mostly composed of organic substances and thus have a property of being easily combusted. Flame retardant materials are substances added to suppress or alleviate combustion by physically and chemically modifying these properties. In general, flame-retardant materials are classified according to usage methods and components, and are divided into additive type and reactive type according to usage methods. The additive type is organic and inorganic, and the reactive type is a flame retardant material containing active radicals such as -OH, -H, and -COOH. ), bromine-based, chlorine-based, etc., inorganic types are typically divided into antimony-based and metal hydroxide-based (aluminum hydroxide, magnesium hydroxide). In particular, among organic flame-retardant materials, brominated flame-retardant materials are widely used in various plastic products due to their excellent flame-retardant properties. First, the previous flame-retardant materials will be explained, and the superiority will be explained through comparative evaluation later, and then the semi-non-flammable materials will be explained. The characteristics of flame retardant materials that are mainly used are as follows. ① First of all, among halogen-based flame retardant materials and halogen compounds, flame retardancy is excellent in the order of I>Br>Cl>F, but iodine compounds are expensive and C-I bonding strength is weak, so they are easily decomposed at processing temperature, and fluorine compounds have large C-F bonding energy It is not used because it is inefficient, and although bromine-based is more expensive than chlorine-based, it has an excellent flame retardant effect, so it is widely used in general-purpose and en-pla resins. Representative examples of bromine-based flame retardant materials include tribromophenoxyethane, tetrabromobisphenol A (TBBA), and otabromodiphenyl ether (OBDPE), among which TBBA is the most used. Brominated flame-retardant materials generally use antimony compounds (antimony trioxide, antimony pentoxide, etc.) as a flame retardant auxiliary material (synergist), and the reaction mechanism is as follows.

<General reaction mechanism of halogen-based flame retardant materials>

HO + HX → HOH + X → inhibitory reaction

X + RH → HX + R → regeneration reaction

↓ Stop the chain reaction

XO + OH → HX + O2 → Reduce the concentration of active O, OH and stop the chain reaction

→ Flame retardant effect

X + O → XO + X → Non-combustible gas generated during decomposition → O2 blocking

O + OX → O2 + X

<Reaction mechanism of halogen + antimony flame retardant material>

Sb2O3 + 2HBr → 2SbOBr + H2O

5SBOBr → Sb4O5O4Br + SbBr↑

4Sb4O5Br2 → 5Sb8O4Cl + SbBr↑

3Sb8O4Br → 4Sb2Cl3 + SbBr3↑

Chlorine-based flame retardant materials include chlorinated paraffin, chlorinated polyethylene, and substituted chlorine-based flame retardant materials. In the case of chlorine-based paraffin and polyethylene, the price is low, but thermal stability is weak, and in the case of a substituted group flame-retardant material, the price is high.

Examples of inorganic flame retardant materials include aluminum hydroxide, magnesium hydroxide, antimony oxide and boron-containing compounds. Unlike organic flame-retardant materials, inorganic flame-retardant materials are decomposed without volatilization by heat to release non-flammable gases such as H2O, CO2, SO2, etc., and most have endothermic properties. In the gaseous state, it dilutes the combustible gas, prevents the access of oxygen by coating the plastic surface, and at the same time has the effect of reducing the plastic cooling and the generation of thermal decomposition products through the endothermic reaction on the solid surface. In addition, in the case of a boron compound, there is an effect of blocking oxygen and heat by forming a glassy protective layer on the solid surface. Aluminum hydroxide is the cheapest among inorganic flame-retardant materials, but it can only be used in plastics with a low decomposition temperature of 200℃ or less. The reaction mechanism of inorganic flame retardant materials is as follows.

<Flame-retardant mechanism of inorganic flame-retardant material>

2Al(OH) ₃ → Al ₂ O ₃ + 3H ₂ O - 298KJ/mol

Mg(OH) ₂ → MgO + H ₂ O - 328 cal/mol

The phosphorus compound serves to block oxygen and heat by generating char by esterification and dehydrogenation of polyphosphoric acid produced by thermal decomposition during combustion. Phosphorus-based flame retardant materials include red, phosphoric acid esters, and phosphine oxide. In the case of red, the compound material is red because its own color is red, and its use is limited due to color problems. Phosphate ester-based flame retardant materials include triaryl phosphate, alkyldiaryl phosphate, and trialkyl phosphate in the form of monomers, and resorcinaol bisdiphnyl phosphate in the form of oligomers. Nitrogen-phosphorus flame-retardant materials include melamine-phosphate and melamine-polyphosphate. Nitrogen-phosphorus flame-retardant materials are intumescent thick char layer due to the thermal polycondensation catalysis of polyphosphoric acid generated during combustion and nitrogen sources (N2, NH3, etc.) It forms a barrier to the diffusion of heat and oxygen. However, there is a disadvantage in that physical properties and price competitiveness are lacking due to the large amount of use. And antimony, tin, zinc, and selenium are heavy metals used to add flame retardancy to wallpaper and are used to improve the functionality of wallpaper. In particular, antimony has a toxicity similar to arsenic, and when exposed it has been reported to cause pneumonia, osteoporosis, and cancer. (Source: KANALYTICAL SCIENCE & TECHNOLOGY, Vol. 21, No. 2, 135-142, 2008 )

In addition, semi-incombustible materials have less fire risk than combustible materials and have the ability to suppress the occurrence of fire. It refers to materials that do not work, and in the Building Act, they are classified into three categories according to their performance: non-combustible materials, semi-non-combustible materials, and flame-retardant materials. (Source: Interior Terminology Dictionary, Architectural Glossary) After heating at ℃ for 10 min, there should be no cracks, holes, and melting (including all melting and disappearing of the core material in the case of a composite material), etc., harmful to fire that penetrates the specimen, and there is no residual flame (less than 30 sec) (time units, Second is an abbreviation of second), and the average stopping time of a rat left in the combustion gas of the material must be 9min or more. Table 4 compares the standards for non-combustible materials, semi-non-combustible materials, and flame-retardant materials disclosed and generally known.

division non-combustible material Semi-incombustible material flame retardant material Justice Materials with non-combustible properties (Article 2 of the Enforcement Decree of the Building Act) Materials with properties comparable to non-combustible materials (Building Act Enforcement Decree Article 2) Materials that are resistant to fire (Article 2 of the Enforcement Decree of the Building Act) standard When heating at 750°C for 20 minutes, the temperature does not rise above 50°C, and there must be no residual flame for more than 30 sec after heating at 305°C for 10 minutes. When heating at 305°C for 10 minutes, there should be no remarkably harmful deformation such as melting or cracking, and there should be no residual flame for more than 30 sec after heating is finished. When heating at 235℃ for 6min, there should be no harmful deformation, etc., and there should be no residual flame for more than 30 sec after heating is finished. test standard Korean Industrial Standard KSF2271 (Class 1 Flame Retardant), Article 6 of the Rules for Standards for Evacuation of Buildings and Fire Protection Structures Korean Industrial Standard KSF2271 (flame retardant class 2), Article 7 of the Rules for Standards for Evacuation of Buildings and Fire Protection Structures Article 5 of the Korean Industrial Standard KSF2271 (Flame Retardant Class 3), Rules for Standards for Evacuation of Buildings, Fire Protection Structures, etc. oilseed Concrete, stone, brick, glass, glass wool, cement board, gypsum cement board, etc. Gypsum board, pulp cement board, etc. Flame-retardant plate, flame-retardant plastic plate, etc.

(Source: http://cafe.naver.com/linecontra/89348) In order to have an excellent flame retardant effect, flame retardant (or flame retardant) products that are not flame retardant due to increasing the use of flame retardants or using medium to expensive flame retardants The price of the product is 2-6 times higher than that of the product. In the distribution market, based on flame-retardant wallpaper products, assuming that general wallpaper is about 2,000 to 2500 won (as a standard), silk wallpaper is about 6,000 won, and flame-retardant wallpaper is sold at a high price of 12,000 won. The reality is that it is more difficult to apply the flame retardant material to the cheap plastering pool.

(6) Anti-corrosion: Concrete has superior durability compared to other materials and it gradually loses durability in a natural environment, so it is impossible to permanently preserve and maintain the structure. I never do that. However, due to the neutralization of the concrete surrounding the rebar, corrosion such as cracks occurs. The neutralization of concrete is a phenomenon that occurs by reacting with carbon dioxide in the air and alkali of concrete. This action proceeds from the surface of the concrete to the inside, and the rate of progress depends on the humidity in the air, the permeability of the concrete, and the strength of the concrete. In general, it is reported that concrete progresses about 12mm in 10 years and 25mm in 50 years. A similar process occurs with sulfur dioxide in air. Therefore, in areas with severe pollution, the combined action of carbon dioxide and sulfur dioxide occurs, so the neutralization action is faster. When the concrete surrounding the reinforcement is neutralized, the reinforcement begins to corrode. It was said that the corrosive action of rebar is accelerated in neutralized concrete. (Source: The main culprit of concrete corrosion, Korea Research Institute of Technology)

Hardened concrete is a hydration product of cement and contains calcium hydroxide (Ca(OH) ₂ ) and exhibits strong alkalinity (pH 12-13). It is said that carbon dioxide or acid rain in the air chemically reacts with calcium hydroxide in the concrete to gradually turn into calcium carbonate (CaCO ₃ ) and lose the alkalinity of the concrete. This phenomenon is also called "concrete neutralization" or "concrete carbonation".

Ca(OH) ₂ +CO ₂ →CaCO ₃ +H ₂ O[CaCO ₃ ↑ → neutralization ↑]

At a pH of 11 or higher inside the concrete, a passivation film is formed on the surface of the reinforcing bar, so it does not rust even in the presence of oxygen. it expands In other words, when the concrete is neutralized (pH 8.5~10), the reinforcing bars corrode and expansion pressure is generated. When this expansion pressure exceeds the concrete stress, cracks occur and water and carbon dioxide penetrate into the cracks, leading to rapid deterioration. proceeds To determine neutralization, when an alcohol solution of 1% phenolphthalein is sprayed on concrete, the alkaline part appears reddish purple, so the part that does not change color is judged to be neutralized. (Source: [Naver Knowledge Encyclopedia] Concrete Neutralization - Concrete Neutralization seonghwa), Geospatial Information System Glossary, 2016. 1. 3., Gumi Seogwan) In addition, the phenomenon in which metal harmonizes with the components of a given environment to form a non-metal oxide, which deteriorates the properties and performance of a metal is called metal corrosion. Corrosion caused by the action of a solution due to the presence of an aqueous solution on the surface is called wet corrosion. In general, the wet corrosion process is usually caused by an electrochemical or chemical action. this is required

(7) Insect control: The main components of spray insecticides are phthalthrin and pyrethroid compounds used in pesticides, etc. This component has lower toxicity than organochlorine and organophosphorus insecticides, so it is widely used. It is known that respiratory disorders such as inflammation and pulmonary fibrosis may occur. Imidacloprid, an ant extermination ingredient, is a colorless, odorless, transparent gel that is said to disappear when sprayed on corners and crevices of a house. It is a kind of pesticide that has raised concerns that it may disturb the ecosystem.

(8) Elimination of dust generation: Among the dusts with frequent fire and explosion accidents, not only damage to human life and property due to the occurrence of sugar, corn, and flour dust, but also dust (Source: (Fire Explosion Risk Assessment of Food Dust 2015)) It is known to cause respiratory diseases, nervous system-related disorders, and nausea. As the recognition criteria for occupational respiratory diseases, wood dust, grain dust, flour, animal hair dust, antibiotics, chromium or its compounds, TDI·MDI· There are asthma caused by exposure to diisocyanate, such as HDI, reactive dyes, nickel, cobalt, formaldehyde, aluminum, acid anhydride, etc. or asthma and rhinitis aggravated by the work environment. 」 Article 37 (5) and Regulation 「Enforcement Decree of Industrial Accident Compensation Insurance Act」 Article 34 (3) and attached Table 3, Item 4)

(9) Humidity control: As the quality of life increases along with industrial development, interest in indoor air quality is also increasing. Environmental diseases such as hypersensitivity atopic dermatitis and allergic rhinitis are on the rise while living in a polluted residential environment. Misoperation of precision instruments due to the proliferation of viruses such as colds and the accumulation of static electricity may occur. Therefore, a dehumidifier or humidifier is used to maintain proper humidity. In this case, energy consumption is high and when used for a long period of time, mold, mites, or various bacteria grow inside the dehumidifier or humidifier. (Source: Textile Coloration and Finishing Vol.27, No.3, 210~218)

(10) In order to solve these problems, the prior art and its problems are as follows. ① Republic of Korea Patent Application No. 10-2000-0068297, layer separation caused by the use of a high-density radio wave absorber and manufacturing into a commercial product using a high-density material was difficult, ② Republic of Korea Patent No. 10-0591003, There was a disadvantage in that the long-term adhesion properties were deteriorated due to the absence of a sexual material, and ③ Korean Patent Nos. 10-0526673 and 10-0522267 did not have specific techniques for conductive carbon black and adhesives used as main materials. ④ And 10-0056008, one of the patents applied by the present inventor, is a composition patent that mixes the already prepared paste with the PVA adhesive sold (manufactured) as a subject, and the step of composing and manufacturing a mixed composition product between finished products There are several challenges in Excluding the difficulties of lowering economic feasibility due to the use of already manufactured products, there are the difficulties of volatilization and drying, difficulties of uniform dispersion due to mixing between products with high viscosity, etc. It is a technology that has unresolved problems such as consumer distrust about the corrosive concerns of metals. Therefore, the above technology is fundamental because it does not consider the ease of operation, economic feasibility, types and efficacy of materials used, action, long-term reliability and storability as a product, adhesion, etc., which are inevitably required in the method of manufacturing a functional polymer material. I have a problem.

The present invention has been devised to overcome the problems of the above technology, and the mixing ratio of additive materials to provide anti-freezing properties to strengthen adhesion and suppress the problem of freezing in cold weather in water-soluble adhesive materials, paints, polymers, etc. , Its main purpose is to provide a composition with anti-yawning properties by the type of additive and application products using the same.

Another object of the present invention is to provide a composition having an antibacterial and anti-mold function against a polymer (polymer), which is frequently encountered in real life, which is a prey of bacteria or mold, and an application product using the same.

Another object of the present invention is to remove static electricity by antistatic and to provide electric field absorption, blocking and electromagnetic wave shielding performance, and a composition having suitable electrical and magnetic properties depending on the mixing ratio of the additive material and the type of additive material, and a composition using the same Its purpose is to provide application products.

As described above, another object of the present invention is to provide a composition that enables flame retardancy (flame retardancy) or more properties for combustion gases and flames, which are a direct factor in casualties due to toxic gases and smoke in case of fire, and application products using the same. It also aims to provide an environment-friendly composition instead of insecticide for the purpose of neutralizing concrete and inhibiting metal corrosion caused by it, and other insect repellent, humidity control, and rust prevention purposes to prevent corrosion, insect repellent, humidity control , to provide a composition that enables rust-preventing properties and an application product using the composition.

And another important object of the present invention is to provide a manufacturing method as well as an applied product manufactured and a construction method.

In order to achieve the above object, adhesion strength according to the type of additive material of the present invention and the mixing ratio of the additive material (ratio and content are terms with the same meaning and were mixed depending on the context), anti-freezing, anti-bacterial/mildew, anti-static , developed a composition that exhibits complex, selective and selective performance, such as flame retardancy, corrosion prevention, humidity control, and rust prevention, and application products using the same.

The purpose of the present invention is the compounding ratio of additive substances and the performance to be selectively and selectively exhibited according to the type of additive, ① adhesive strength and temperature change at freezing, ② antibacterial and anti-mildness, ③ surface resistance 10 depending on the content difference Electromagnetic wave blocking at ³ ∼10 ⁶⁽⁵⁾ Ω/□, antistatic performance at 10 ⁶⁽⁵⁾ ∼10 ⁹ Ω/□, ① electromagnetic wave absorption and electromagnetic wave blocking according to the type of additive, ② flame retardant (flame retardant) and semi-incombustible , ③ Corrosion prevention performance ④ Adhesive strength ⑤ Humidity control, rust prevention, etc. are selectively and selectively exhibited, and one of the developed compositions and applied products is an example of application of 1.5 to 2 degrees stronger than existing wallpaper, -16.9℃ Does not freeze at ^-19.3 ℃, but can be painted after thawing It is characterized by static reduction, flame-retardant effect, flame-retardant doubling when used with flame-retardant wallpaper, and humidity control function. .

In addition, another important invention of the present invention is characterized in that it is possible to manufacture by a traditional (conventional) manufacturing method, and provides a production method in consideration of the improvement of the working environment and productivity of the worker.

In addition, applicable products that can be applied (manufactured) include strong adhesion, anti-freeze, antibacterial function, mold suppression, anti-static, flame-retardant function, humidity control, and rust-preventive function for painting, paint (coating), and fire protection such as cabinets and desks. Furniture, partitions, curtains and vertical blinds that require flame retardancy, film sheets, paper wallpaper (manufactured with paper materials such as laminated wallpaper) that require flame retardancy, anti-mildness, humidity control, and rust prevention properties, silk wallpaper, PVC flooring, etc. It is characterized in that it can be provided (manufactured) into various applications and products such as flooring materials such as flooring, clothing, and boards.

In the same way as above, depending on the type of additive and the mixing ratio of the additive, the adhesive strength, freeze prevention, antibacterial/mildew, antistatic, electromagnetic wave absorption, electromagnetic wave blocking, flame retardant, corrosion prevention, humidity control, decay prevention, rust prevention performance, etc. The composition and application products using it have been developed, and the complex or selection/selection performance according to the type of additive material, which is the subject (main purpose) of the present invention, and the compounding ratio of the additive material, are described in more detail in the specific content and claims.

As described above, a composition that exhibits complex, selective and selective performance of adhesive strength, anti-freezing, anti-bacterial, anti-mild, anti-static, flame-retardant, anti-corrosion, humidity control, rust prevention, etc. The applied products used lower the freezing point to prevent damage to adhesive strength by preventing freezing in cold weather, to ensure product stability (preservability) and stability after construction (work), inhibit various bacteria, and Suppression of electromagnetic waves generated in the military, etc. that use electricity, removal of fine dust and static electricity on the surface of products by antistatic properties, suppression of ignition in case of fire, and suppression of adverse effects of various water-soluble products with anti-corrosion performance due to alkali, human It has the effect of contributing to providing a comfortable environment and life for Therefore, the present invention provides the above-mentioned functions in an unfavorable environment, -reinforcement of adhesion, antifreeze, antibacterial/mildew, electromagnetic wave absorption, electromagnetic wave blocking, antistatic, flame retardant or flame retardant, corrosion prevention, humidity control, rust prevention function, etc.- For example, when applied to housing (spaces where people live, such as houses, apartments, offices, workplaces, and educational places) and housing and packaging of electrical and electronic products due to shielding (electromagnetic wave absorption and blocking) properties, comfortable living and living, in workplaces, and products Improves the quality of electronic components and products by removing electrical noise, etc., and is protected from foreign substances. It can be applied to products for painting, packing, and housing. This is so good that when bonding PVC (Polyvinyl chloride) conductive tiles, static electricity generated from the human body, equipment, and the human body during work escapes through the PVC conductive tile through the conductive adhesive and the grounding terminal of the present invention, thereby exhibiting antistatic properties Another feature is that it becomes an intermediate (complementary) product so as to become an antistatic floor that , Prevents various types of bacteria and fungi, prevents freezing, prevents ignition/flame prevention and action with flame retardancy, and helps prevent corrosion of rebar in concrete and neutralization of concrete by alkali.

In other words, the present invention has the ability to strengthen adhesion by the unique characteristics and mechanism of the composition, the freezing point is lowered, so that it does not freeze like antifreeze in cold weather, and the antibacterial ability against anionic and cationic bacteria by the anion and cationic properties of the composition. , electrical properties that can exhibit antistatic performance reduce the electric field through self-resistance heat extinction and grounding among electromagnetic waves, furthermore, block and absorb electromagnetic waves, and suppress the occurrence of fire and smoke due to flame retardant and flame retardant properties, humidity control and It also has insect repelling abilities. As described above, such a performance exhibits a function of compounding or selecting/selecting functions according to the type of additive material and the mixing ratio of the additive material of the present invention as described above.

1 is a photograph taken of a company A clean room with a conductive tile construction with the composition of the present invention, and the result of the measurement of the surface and ground resistance, and the mechanism thereof.
2 is a photograph and measurement result of a surface resistance report obtained by requesting a test researcher for a specimen produced using conductive carbon and an adhesive as the composition of the present invention.
Figure 3 is a real photograph of a nonwoven fabric made of an adhesive product, which is one of the compositions of the present invention.
Figure 4 is a picture taken on-site to construct an apartment with the composition product of the present invention.
5 is a conductive carbon (graphite) structure used in the present invention.
6 is a photograph and measurement results of surface resistance and half-life test results obtained by requesting a specimen manufactured with the composition of the present invention to a test researcher B.
7 is an electric field measurement result with E-tester equipment before and after box inner treatment (construction) with the composition of the present invention.
8 is an electric field measurement result with E-tester equipment before and after box inner treatment (construction) with the composition of the present invention.
9 is an electric field measurement result with a TriField meter device before and after construction with the composition of the present invention;
10 is a schematic diagram for explaining the theory of a metal sphere.
11 is a photograph of the electric field measurement result with HI-3604 before construction with the composition of the present invention (video captured as a photograph).
12 is a composition of the present invention in the frequency counter before construction, the light on state vs. A photo of the difference in electric field generation when the light is off (capture the video as a photo).
Figure 13 is a photograph of the electric field measurement result with HI-3604 after construction with the composition of the present invention (video captured as a photograph).
14 is a frequency counter after construction with the composition of the present invention, the light on state vs. A photo of the difference in electric field generation when the light is off (capture the video as a photo).
Figure 15 is the result of measuring the electric field with a GIGA SOLUTIONS meter before and after construction of an apartment in which the interior walls of the apartment are coated using laminated wallpaper as one of the compositions of the present invention.
16 is a schematic diagram of shielding according to the difference in received power by a shielding agent with respect to the incident power used in the present invention.
17 is an electromagnetic wave shielding system used in the present invention.
18 is a Soft-1 scanning electron microscope (SEM) photographing result of the present invention.
19 is a measurement result of the shielding rate of the sheet manufactured by the present invention.
20 is a three-roll mill according to the present invention, the composition aggregation state in two passes or less photographing results.
Figure 21 is a three roll mill according to the present invention, the composition in good condition when three or more passes are taken.
22 is a captured photograph of a surface resistance report received by requesting a test researcher for the composition product of the present invention.
23 is a measurement equipment Network Analyzer Mod. MS46322A, Specification 10MHz~20GHz, Tell Cell DC~5GHz, showing the state of the equipment before measuring the electromagnetic wave absorption rate.
24 is a measurement equipment Network Analyzer Mod. Using MS46322A, specifications 10MHz to 20GHz, Tell Cell DC to 5GHz, the sample is mounted for measuring the electromagnetic wave absorption rate.
25 is a captured photograph of an antibacterial test report evaluated by requesting a test researcher for a sample prepared according to the present invention.
26 is a photograph of a fungal strain experiment (video) capture for a general acrylic primer and an acrylic primer according to the present invention.
27 is a photograph of a fungal strain experiment (video) capture for an adhesive according to the present invention and a general adhesive.
28 is a result of a mold inhibition experiment with bread in a dry composition according to the present invention.
29 is a photograph of mold fungus growing on the outer wall of the apartment.
30 is a photograph of mold fungus generated on the living room wall of a country house.
31 is a photograph of a captured antibacterial test report evaluated by requesting a test researcher for a sample prepared according to the present invention.
Figure 32 is a sample taken after the flame test for PS foam (polystyrene foam).
33 is a representative schematic view of a foam prepared by the present invention.
34 is a schematic view of a foam with multiple flame retardant layers produced by the present invention.
35 is a schematic view of a foam having an antistatic flame retardant layer prepared by the present invention.
36 is a schematic view of wallpaper with double-sided flame retardant layers without foam according to the present invention.
37 is a schematic view of wallpaper with a flame retardant layer on one side, not a foam, according to the present invention.
38 is a photograph taken after a flame test for the laminated wallpaper prepared by the present invention and the existing (general) glued laminated wallpaper.
39 is a photograph of occurrence of dew condensation.
40 is a picture taken to prevent condensation according to the present invention.
41 is a change in freezing point according to the weight ratio of ethylene glycol.
42 is a diagram for explaining the phenomenon of lowering the freezing point.
43 is a freezing test result (progress), photographed photos of two types of common grass and the present invention.
44 is a photograph of the state of the general water-based paint and the water-based paint according to the present invention after freezing and then thawing.
45 is a photograph taken after bonding a wooden flooring material with the composition of the present invention.
Figure 46 is a photograph taken after injecting and culturing mold fungi into the dobae grass of the present invention and the commercially available dobae grass (S company).
Figure 47 is a flame test for both sides or one side coated and uncoated of general wallpaper and silk wallpaper with the composition of the present invention, photograph 1/2.
Figure 48 is a flame test of the composition of the present invention, coated on both sides or one side of normal wallpaper and silk wallpaper and not coated, photograph 2/2.
49 is a comparative adhesive strength test after completely freezing and thawing in two types of dobae grass and general dobae grass among the compositions of the present invention.
Figure 50 is a photograph of the appearance of the thawed state after completely freezing the dobae grass and the general dobae grass of the present invention.
51 is a result of testing (photographing) the corrosion state of the screw surface after immersing the screw in the plastering pool of the present invention and the general plastering pool and leaving it for a long time.
52 is a photograph of a captured surface resistance measurement result after application with the plastering finishing material composition of the present invention.
53 is a photograph of the process and results of evaluating the degree of corrosion over a long period of time in the present invention.
54 is a photograph of a captured surface resistance measurement result after application with another plastering finishing material composition of the present invention.
55 is an electric field measurement result with E-tester equipment after box interior plastering (construction) with the plastering finishing material composition of the present invention.
56 is a captured photograph of the far-infrared emissivity measurement result evaluated by requesting the testing researcher for the plaster finishing material of the present invention.
57 is a photograph taken of the ocher plaster finishing material composition prepared according to the present invention.
58 is an electric field measurement result with E-tester equipment after box interior plastering (construction) with the loess plaster finishing material of the present invention.
59 is an ant extermination experiment in the composition according to the present invention.
60 is a photograph of a fire generation mechanism and actual ignition scene due to static electricity at a gas station.
Figure 61 is a photograph of the bottle and product state immediately after opening 9 months after storage (sealing) of wheat grass prepared with the composition of the present invention for 9 months.
62 is an abbreviation of GHS (Globally Harmonized System of Classification and Labeling of Chemicals, classification, labeling and material safety data sheet) warning display for ^┌ quality labeling by industrial product quality control _┘ .
63 is a photograph of a product packaging display according to the present invention.
64 is an interior according to the present invention, reducing harmful elements after painting

Hereinafter, the present invention will be described in more detail as follows.

There may be a plurality of preferred embodiments of the present invention, and the following will be described in detail below based on the consideration of the phenomena of the above-mentioned problems, the principles of solutions and methods, and the like, and through these preferred examples and drawings, the object, features, It will be possible to better understand through detailed descriptions of the status quo and all, selection/selection performance, effects, etc. In addition, it will be possible to understand the content of the present invention more specifically through tests and measurements.

And like reference numbers in each drawing refer to like components.

The present invention relates to a composition that exhibits integrally, selectively, and selectively anti-freezing, anti-bacterial/mildew, anti-static, flame-retardant, corrosion prevention, humidity control performance, rust prevention, etc. It relates to the application products used, etc.

In order to realize the above object, in order to realize the composition and application products using the composition with substances that exhibit adhesion strengthening, anti-freezing, anti-bacterial/mildew, anti-static, flame-retardant, anti-corrosion, humidity control performance, rust prevention, etc.;

First, as materials that provide adhesion and appearance, Acrylic, Epoxy, Polyvinyl Alcohol, Polyvinyl Acetate, Silicone, Polyurethane, Ethylenevinyl Acetate, Polyvinyl Chloride, Vinyl Acetate Acrylic Copolymer, Acrylic Copolymer with a solid content of 1 to 100% by weight. Gum Rosin, 2-Ethyl Hexyl Acrylate Monomer, 2-Ethylhexyl 2-Propenoate, 2-Hexyl. Resin, Solution or Acid, Primer, Emulsion, Monomer, Copolymer of 2-EHAM, 2-Ethyl Hexyl Acryl Acid, Butyl Acrylate Monomer, N-Butyl Ester, Butyl 2-Propenoic Chloroprene Rubber, Acid, n-Butylacrylate, Vinyl Acetate Monomer , Resorcinol, α-Olefin, Isocyanate, Phenolic, Thermosoftening Plastic [PVC (Polyvinyl chloride), Cellulose, polyester, PVC sol, PP (Polypropylene), ABS (Acrylonitrile Butadiene Styrene), PMMA (Polymethlmethacrylate), PE (Polyethylene), PET (Polyethylene Terephthalate), PBT (Polybuthylene Terephthalate), PPS (Polyphenylene Sulfide), PC (PolyCabonate), Nylon, LDPE (Low Density Polyethylene), HDPE (High Density Polyethylene), Polystyrene any one or a mixture of two or more], Thermosetting Plastic ( Grains such as Phenol, Urea, Melamine, Polyurethane, Unsaturated Polyester, Silicon Resin alone or in combination of two or more), Starch, Rice, Wheat, Bran, Corn, Potato, Dextrin, Modified starch, Glutinous Rice, Nori, Gelidium amansii LAMOUROUX Algae, grains such as dextrin, materials manufactured alone or in a mixture of two or more, such as modified starch, powdered grass (using powdered grass, such as German company H, Korea company E, K company, Y company), and Solids 1-100% of preservative-free wheatgrass; Characterized by including the use of 1 to 99% by weight alone or in a mixture of two or more,

Adhesive strength strengthening, freezing prevention, antibacterial/mildew, antistatic, flame retardant, corrosion prevention, humidity control, insect repellent, antirust performance, etc., which are one of the main purposes of the present invention Nitrogen, Sodium Chloride, Magnesium Chloride, Calcium Chloride (European, African, Asian, North American, South American) belonging to metal chlorides of hydrated nH ₂ O (n = 0 to 99) with a solid content of 1 to 100% by weight. Acids and Oceania acids, especially domestic and Asian acids, which are easy to secure, were mainly used), etc., prepared in the form of a powder or an aqueous solution thereof, and contained in an amount of 0 to 50% by weight, or containing these substances alone or in a mixture composition of two or more; Solid content 1-100 wt% Salt is edible salt with sodium chloride as the main ingredient, sea salt and industrial salt material used as chemicals, East Sea, West Sea, South Sea, Mediterranean Coast, Pacific Ocean, Atlantic Ocean, Indian Ocean, Arctic Ocean, Antarctic Ocean, Dead Sea, Black Sea, etc. (Europe, Africa, Asian, North American, South American, Oceania) Salt salt produced in Asia, Europe and West Sea such as USA, Australia (Australia), China, Philippines and Vietnam or Africa, America , produced in salt mines (rock salt) on six continents such as Tibet - The salt of the present invention is largely classified into sea salt and refined salt. Sea salt is a thick, translucent hexagonal crystal made by drawing seawater to a salt farm and evaporating harmful ingredients along with moisture with wind and sunlight. On the other hand, refined salt is a crystal of sodium chloride obtained by electrolyzing seawater to remove impurities and heavy metals with an ion resin film. In Korea, it is produced a lot in the west coast or south coast where the water depth is not deep and the tidal difference is large. Sinan-gun, Jeollanam-do accounts for 65% of the domestic solar salt production and more than half of the salt farm area, and its quality is also excellent in the world. In addition, salt containing sulfur produced in the vicinity of Baengnyeongdo is considered a commodity. Cheonil Salt Farms in Korea usually consist of a reservoir, an evaporation pond, and a crystallization pond. At high tide, the sluice gate is opened to make concentrated brine in the evaporation pond and send it to the crystallization area to obtain salt crystals. When the wind is strong, the crystals are small, and when the temperature is low, the salt tastes bitter and the quality of salt decreases. The sea salt produced in Korea is alkaline and its salinity is about 88%. Sea salt has a lot of minerals and moisture such as Ca, Mg, Zn, K, and Fe, so it is good for pickling vegetables or fish, and is mainly used for making kimchi, soy sauce, and soybean paste. While it contains a lot of minerals that are good for the body, but also contains some toxic substances, it must be removed and consumed. In addition, sea salt has high hygroscopicity due to various minerals and has anti-corruption effect by sterilizing power beyond antibacterial. or 0 to 50% by weight of a mixture of two or more; Magnesium Chloride 15~19%, Magnesium Sulfate 6~9%, Potassium Chloride 2~4%, Sodium Chloride 2~6%, Magnesium Bromide 0.2~0.4%, etc. Solid content 1~69% by weight bittern, or 100g of these or 0 to 50% by weight of 5 to 90% concentration by heating; Where bacteria-inhibiting power is further required, 0-50% by weight of purified salt is included instead of sea salt to secure antibacterial and anti-mildew effects, especially by treating at a high temperature of 100°C or higher to eradicate all bacteria of the additive material itself; When manufacturing a product, 0-5 wt% of an acid (pH <4) of 1-100 wt% of solid content (purity) is mixed with some products to remove not only the compatibility of the adhesive material, but also the adhesive and self-retained bacteria of the composition. ; Among the above-mentioned calcium chloride and sodium chloride of hydrous nH ₂ O (n = 0 to 99) having a solid content of 1 to 100% by weight, these are treated with an acid, etc. 0 to 50% by weight alone or two or more of the substances; As an ionic compound with a solid content of 5 to 100% by weight - In the ionic compound used in the present invention, a metal cation and a non-metal anion are coupled by electrostatic attraction, and the sum of charges is electrically neutral. - The cationic metal element having a valence of +2 or higher may be one or more from the group consisting of Co, Cu, Ni, Mn, Zn, Fe, Al, Be, Mg, Ca, Ba, and the like, and the anion element is a fluoride anion, a bromide Anion, iodide anion, sulfide anion, chloride anion, ammonium anion, hydroxide anion, sulfate anion, carbonate anion, nitrate anion, phosphate anion, permanganate anion, acetate ion, hydrogen carbonate anion, borate anion, chromate anion, dichromate anion, halogen anion , hydrochloric acid anion, organic acid anion, etc. may be mentioned, and may further include an ammonium salt in consideration of equipment corrosion and solution stability, and in the form of anhydride, hydrate, aqueous solution Substance alone or 0 to 50% by weight of two or more, or 5 to 100% by weight of solid content The ionic compound uses a +1 cation metal and a -1 valent or -2 valent anion, and the cationic metal element belonging to this is Li, and one or more selected from the group consisting of Na, K, and the like, and the anion element is a fluoride anion, a bromide anion, an iodide anion, a sulfide anion, a chloride anion, an ammonium anion, a hydroxide anion, a sulfate anion, a carbonate anion, a nitrate anion , phosphate anion, permanganate anion, acetate ion, hydrogen carbonate anion, boric acid anion, chromate anion, dichromate anion, halogen anion, hydrochloric acid anion, organic acid anion, etc. It contained at least one selected from the group consisting of, anhydride form, hydrate form , containing 0 to 50% by weight of one or two or more of these substances in the form of an aqueous solution; 5 to 100% by weight of the solid content of the ionic compounds in the form of an anhydride, hydrate, or aqueous solution, alone or 1 to 50% by weight of two or more thereof; 1 to 100% by weight of solids produced by mixing two or more of the ionic compounds 0 to 50% by weight of alkaline white basic material, 0.1 to 50% by weight of solids Conductive Polymer (Polythiophene, PEDOT-PSS, Polyaniline, Polypyrrole) 0 to 50% by weight of either used or so; Characterized by including the use of 0 to 99% by weight alone or in a mixture of two or more,

Adhesive strength, antistatic, antibacterial/mildew, flame retardant abnormality, increase in weight, impact reinforcement and dispersion, cold resistance, viscosity increase, shortening of drying (curing) time, anti-corruption, rust prevention, for plastering, 0.0001~7,000㎛ spherical and plate shape, needle shape As a hydrous aluminum silicate mineral containing alkali metal or alkaline earth metal with various shapes such as (a porous structure in which Si tetrahedrons are combined in a three-dimensional network and WmZnO _2n2 O composition formula, W is Na, Ca, Ba, Sr, , Z=Si+Al, quartz SiO ₂ , Zeolite in which a part of Si in the three-dimensional network structure of infinitely connected diamond tetrahedral structure is substituted by Al, siliceous porous material, lightweight foamed ceramic, Silica, Perlite, Titanium Dioxide, Clay , talc, Aluminum Hydroxide, Kaolin, Magnesium Hydroxide, Calcium Carbonate, Diatomite, Loess, Bentonite, Quartz sand, Gypsum, Lime, cement, Terra alba, Pozzolan, Diatom, Pulp or water (H ₂ O) dispersed solid content 1∼100 0 to 99% by weight of Pulp alone or two or more; Ammonium Dodecylbenzenesulfona, Polyoxyethylenenonylphenyl Ether, Polyoxyethyleneoctylphenyl Ether, Sodium Dodecylsulfonate, Sodium Dioctylsulfosuccinate, Sodium Dodecylbenzenesulfonate, Ammonium Dodecylbenzenesulfonate among anionic, cationic, and amphoteric surfactants , Phosphate Ester, Ammonium, Soda-based organic/inorganic dispersant, Silicon dispersant, Acrylic dispersant, etc. Sodium Polycarboxyl Acid; Octylalcohol, Cyclohexane, Polydimethylsiloxan, Other Higher Alcohols or Ethylene Glycol, Span Other Nonionic Active Agents, Silicon Antifoaming Agents; It is characterized in that it contains 0 to 55% by weight of each of at least one type,

For thickening and initial adhesion, cellulose type, alkali swellable type, ester type, urethane compound type, bento type, airgel type, acrylic type, etc. i.e., for example, gum arabic, jintan gum, tara gum, guar Gum, agar, kerazinan (carrageenan), sodium alginate, powdered cellulose, cellulose, methylcellulose, HEC, CMC, MC, SD, BT, EHEC, MEHEC, LBG, tararind, arabic, soybean polysaccharide, curdran , gellan, glucomannan, soda alginate, pectin, carbomer, Hisel, gelatin, polycarboxylic acid, carboxyvinyl polymer, metal ethyl cellulose, potassium alginate, ritextose, sodium carboxymethyl starch, casein, starch; It is characterized in that it contains 0 to 55% by weight of each of at least one type,

For cold-resistant adhesive properties, Dioctyl Phthalate, Dibutyl Phthalate, Ester, etc. are used, preferably Alkyl Ester; It is characterized in that it contains 0 to 20% by weight alone or two or more,

For better antibacterial, anti-mildew and anti-corruption effects after manufacturing or installation, solid content 1-100 wt% sodium carboxymethylcellulose (CMC), chlorine-treated 5 Chloro 2 methyl 4 isothiazolin 3 one and non-chlorinated 2 Methyl 4 Organic nitrogen sulfide mixed with isotiazolin 3 one, solid content (purity) 1-100% by weight Hydrochloric acid, sulfuric acid, citric acid, glacial acetic acid, malic acid oxalic acid, etc., each or two or more of strong acids (pH <4), sodium benzoate, borax 0 to 3% by weight of the mixture, preferably 0 to 2% by weight, may include 3-lodo-2 propynl butyl carbamate (product name: MX-3 Advanced Plus, manufacturer: CONNELL FAMILY INC.), C ₁₁ H ₁₉ NOS (TK-800), UNICOOL-K14 (manufacturer: UCC), NP-40; Characterized by including the use of 0 to 5% by weight alone or in a mixture of two or more, preferably, when using an acidity of 1 to 99 (solid content = acidity)% acid (pH <4) Substance (hereinafter referred to as anti-corruption material) 1: It is characterized in that it contains 0 to 5% by weight in a ratio of 0.1 to 50,

Electromagnetic wave absorption and electromagnetic wave blocking, electromagnetic wave shielding (those that exhibit both electromagnetic wave absorption and electromagnetic wave blocking at the same time are called shielding), antistatic. Iron powder, Copper powder, Cobalt powder, Tin powder, Aluminum powder with various shapes such as spherical shape, plate shape, needle shape, etc. of 0.0001~7,000㎛ for antibacterial and anti-mildew, flame retardant, corrosion prevention, electrical conduction, heat conduction (adhesion) electrode usage characteristics , Magnesium powder, Titanium powder, Silicon powder, Nickel powder, Zinc powder, Manganese powder. Soft ferrite such as Silver powder, Ag coated Cu, Ni coated Cu, Indium tin oxide, solder ball (Free lead Tin-Bismuth), silver chloride, Antimony tin oxide, Stainless Steel, Mn (or Mg, Ni, etc.)-Zn ferrite And hard ferrite such as Ba (or Sr, etc.) ferrite, conductive carbon powder and fiber, solid content 1.0-80.0 wt% Conductive carbon sol alone or a mixture of 2 or more types 0-97.5 wt%, or these metal materials with carboxylic acid It is also characterized in that it can have a feature that can be manufactured into a product having a color by a composition prepared by surface-modifying using a fatty acid or a silane-based material, and composition of 0 to 90.0% by weight of a surface-modified metal material and an additive material thereof. with

The solvent for dispersion is; Content 1∼99.9 wt% Methanol, Ethanol, Butanol, Dichloromethane, Ethylacetate, Hexane, Diethylehter, Acetonitrile, Benznene, Dibasic Ester, 1-METHOXY-2-PROPANOL, BC, Diethylene Glycol Monoethyl Ether Acetate, Toluene, Alcohol, H2O, etc cast; It is characterized in that it contains 0 to 97% by weight alone or two or more types,

The materials for the above purpose do not matter much in the order of mixing, but it is preferable to mix compositions in approximately the order of the resin and the adhesive material, the solvent, the performance-imparting additive material, and the like, and it is characterized by including at least one material.

Therefore, the main purpose of the present invention is the performance of complex or selective/selective performance according to the type of additive material and the mixing ratio of the additive material, first, by the difference in the content of the mixing ratio, ① adhesion strength and temperature change at freezing, ② antibacterial and anti-mildness, ③ Electromagnetic wave blocking at surface resistance 10 ³ ∼10 ⁶⁽⁵⁾ Ω/□, antistatic performance at 10 ⁶⁽⁵⁾ ∼10 ⁹ Ω/□, ① electromagnetic wave absorption and electromagnetic wave blocking according to the type of additive, ② flame retardant (flame retardant) and semi-incombustible, ③ anti-corrosion performance, ④ adhesion strength, ⑤ humidity control, anti-rust, etc.

In addition, wet mixing is a high-pressure disperser, high-shear mixer (in-line mixer, homomixer), premixer (stirrer), homodisperse, homogenizer, (impeller) high-speed stirrer, paste mixer, corotatory mixer, etc. in a reaction tank or mixing vessel. , commonly used mixers and stirring devices (mixing containers), feed/aggregate/cement/mortar/concrete blenders (eg, types of powder mixers manufactured by Daekwang Construction Machinery, etc.), existing (current) crucible heating type or extrusion steam A method for producing a composition, characterized in that it is formulated in a production method under the conditions of -15 to 350° C., 1 to 600 min, and 1 to 20,000 rpm, using single or multiple methods such as a formula, an extrusion heating device, and a production device developed in the present invention, and In addition to the traditional and current manufacturing methods in which an operator improves and packs the composition that comes out through the mixing vessel discharge valve after the composition is manufactured by the above manufacturing method, raw material input and packaging transfer using automation equipment, inline/outline PLC control It is characterized in that it can be manufactured by a manufacturing method (applicable to dry mixing manufacturing) that can be packaged at a desired weight by automatic weighing by establishing a fully automatic production line such as an unmanned system. Furthermore, in dry mixing, a feed/aggregate/cement/mortar/concrete blender was mainly used at room temperature below 65%RH for mixing between two or more types of powder and powder, but preferably humidity when mixing in a mixing container Mixing at 0 to 65% RH, temperature -10 to 190° C., removing moisture from the powder composition, and sealingly packaging. Or, it is characterized in that the mixed composition is formed into a resin (hereinafter referred to as a resin compound pellet) that is pelletized at a processing temperature of 150 to 350° C. using an extruder, and to make it also It is characterized in that the product is manufactured at a processing temperature of 60 to 450°C in an injection machine or press equipped with a mold of the shape of (to be produced).

And another most important feature of the present invention is that it provides a production method in consideration of the improvement of the worker's working environment and productivity in addition. Looking at the dobae grass (wheat grass), which is one of the manufacturing compositions of the present invention, it is known that the previous or current dobae grass production lines can threaten the health of workers by the dust generated from the raw material input household. As a way to solve this, work clothes and a mask are provided as a way to minimize the exposure of workers, and as a method to fundamentally solve the present invention, the raw material input is made through the absorption pipeline or is currently open (open, outside without a lid) It is also an important feature to cover the exposed manufacturing container with a lid and to provide a raw material input port for adding flour to a part of the lid to fundamentally block the health of workers and the threat of explosion caused by dust caused by dust generated during input.

In the case of mixing a material that imparts the functionality of the present invention to the previously prepared adhesive such as PVA, the composition and mixing are carried out under the conditions of -10 to 70° C., 0.5 to 30 min, 0.01 to 100,000 rpm, and 0.5 to 5 atm, and then packaging do,

On the other hand, it is a manufacturing method that puts water and flour in a container and stirs it while heating it with a heat source to produce an adhesive composition and material, or to increase the production amount. ), a mixing solution (mixed liquid solution) is first prepared under the conditions of 0~70℃, 0.5~30min, 0.01~100,000rpm, 0.5~5 atm, and this mixing solution is placed in a larger container than the previous container (mixer). , Preferably, it is transferred to a container twice or more, and as a means for breaking the transferred mixing solution, it is 50 to 120 ° C, 0.1 to 5 atm. Oil, steam, water, gas, electricity, etc., which are made of viscous composition, adhesive material, or wheat paste while slowly stirring and heating, or heated to 70-500°C by 0.01-10 min instantaneous heating method, heat-conducting tube or heat-conducting sheet, extrusion It was manufactured by passing it through a screw line, a drum, etc. The container used here is preferably corrosion-resistant stainless steel, cast iron, carbon steel, etc., but inexpensive plastic materials were used for general metals and packaging. The manufactured high-temperature adhesive composition and material are immediately packaged at the same time as the prepared composition and material are discharged through the above-mentioned example tube, extrusion screw line, etc. , containers, preferably drums) were passed through or contained and then packaged. In particular, when a drum is used as a cooling device, a knife or bar type is installed on one side of the drum so that if agglomerated adhesive material occurs, the agglomeration is resolved, and it is transported and packaged through the tube. In this case, it is passed through a mesh such as a mesh to prevent the agglomerated adhesive composition and material or mixing solution from passing to the next step process, and when it is closed in another container, one or more packaging pipes are installed at the bottom of the container. As another example, in the present invention, in a method that costs little, if it is manufactured by using an onion net in front of the mixing liquid transfer pipe, it is possible to simply eliminate the agglomeration going to the next step process. It is also a feature belonging to another example.

In the same way as above, depending on the type of additive, the mixing ratio of the additive, and the manufacturing method, the adhesive strength is strengthened, freeze prevention, antibacterial/mildew, electromagnetic wave absorption, electromagnetic wave blocking, antistatic, flame retardant, corrosion prevention, humidity control, insect repellent, rust prevention performance We have developed a composition that exhibits complex, selective, and selective effects, and application products using the same.

15-55 wt% of each mixture of 1 to 65 wt% of Acrylic Emulsion, Polyvinyl Acetate, and Polyvinyl Chloride, 65-84 wt% of H ₂ O, 1-10 wt% of 0thers Composition to 2-EHAM: BAM = 2~3:1 ratio of 30~99 wt%, CaCO ₃ 10~50 wt%, H ₂ O 10~60 wt%, others 0.01~5 wt% Mixed composition or acrylic copolymer 45~55 wt%, CaCO ₃ 30-40%, H ₂ O 10-20 wt%, Gum Rosin 5-10 wt%, 0thers 1-70 wt% Acrylic sealant or silicon sealant alone or in 1 to 90 wt% of 1 to 2 or more in the composition 0 to 90% by weight of two or more types; - Others are substances corresponding to the above-mentioned electromagnetic wave shielding, weight increase, impact reinforcement and beauty, dispersion, cold resistance, viscosity increase, dispersant, etc. - 0~20 wt% of calcium chloride powder, 0~ 20% by weight, conductive carbon powder and fiber 0 to 30% by weight, solids 1 to 80% by weight 0 to 80% by weight of conductive carbon sol Adhesive that exhibits the main function of electromagnetic wave blocking and antistatic performance by composition alone or in a mixture As a result of the evaluation as follows, the adhesive properties and workability were good as well as excellent electrical properties. Test standard ANSI/ESD STM 11.11-2015, test environment 23℃, 50%RH, Resistance Meter (Manufacturer Trek) Model As a result of measuring with 152, it was 10 ⁴ to 10 ⁶ Ω/□ that satisfies the cleanroom SPEC. The result of measuring the surface resistance after the antistatic tile construction with the composition of the present invention was photographed and shown in FIG. 1 . As a result of measuring the surface resistance after on-site construction, it was found to be 10 ⁵ Ω/□ at a humidity of 45%RH, and it was confirmed that the antistatic tile constructed with the composition of the present invention satisfies the cleanroom construction SPEC. 1 is a scene of drying a company A clean room with the composition of the present invention, first drying in order to check the conductivity of the present invention, and measuring the resistance is shown in the center of FIG. 1, and is shown at the bottom of FIG. Given that, when the antistatic tile is adhered with an adhesive having electrical characteristics for the (clean room) floor construction to reduce static electricity, static electricity generated from the human body or equipment during work passes through the antistatic tile, the adhesive of the present invention, and the grounding terminal It is exhibited as another feature to become an anti-static floor (clean room) that escapes through and exhibits anti-static (static-static) properties. And the surface resistance meter used after construction is Wolfgang Warmbier's Surface Resistance Meter SRMⓡ110/Made in EURO.

And FIG. 2 is an evaluation by request of Test Researcher A, and after manufacturing 2 to 30% by weight of carbon sol in the PVA, ANSI/ESD STM 11.11-2015, test environment 23℃, 50%RH, Resistance Meter (Manufacturer Trek) As a result of measurement with Model 152, the surface resistance was 1.05×10 ⁴ ∼1.23×10 ⁴ Ω/□, indicating that the adhesive had electromagnetic wave blocking properties.

And, for evaluation of the adhesive strength of the composition adhesive of the present invention, which is one of the most important characteristics, adhesive strength evaluation was performed at room temperature 23°C and low temperature 10°C, respectively, for 2hr, 4hr, 24hr, and 168hr after bonding. It was carried out at ℃, 45%RH, and the open time before bonding was 20 min. After unification, the results are shown in Table 5.

Item composition 1 composition 2 composition 3 25℃ 10℃ 25℃ 10℃ 25℃ 10℃ 90° peel
Adhesive strength (Kg _f /25mm) after 2hrs 1.2 0.9 2.1 1.6 2.9 2.5 after 4hrs 2.6 2.0 3.4 3.0 4.4 4.1 after 24hr 7.6 5.8 7.9 7.1 77 7.4 after 168hr 9.7 7.8 10.7 9.9 11.9 12.8

As can be seen from Table 5, it can be seen that the adhesive according to the present invention has good adhesion. [Adhesive strength test method]

(1) Room temperature (23℃) adhesive strength

① Apply adhesive to flat cement, plywood, and plastic plates with a spatula.

② After leaving the open time for 10 to 60 min, the tile specimen was pressed and attached to a flat plate, especially a plastic plate.

③ After 2 hr, 4 hr, 24 hr, and 168 hr of drying time at room temperature, respectively, the specimen was peeled at 90° and measured.

(2) Cold-resistant adhesive strength

① In a thermostat at 10℃, the adhesive was applied on a flat plate with a spatula.

② After leaving the open time for 10 to 60 min, the tile specimen was pressed and attached to a flat plate, especially a plastic plate.

③ After 2 hr, 4 hr, 24 hr, 168 hr, and 168 hr, respectively, in a thermostat at 10° C., peeled at 90° and measured.

After preparing 2 to 30% by weight of carbon sol with a solid content of 1 to 80% by weight in an acrylic emulsion with a solid content of 1 to 65% by weight, gravure printing on 80 rolls on a paper medium to paint the real paper medium. 3 is shown. And the actual construction scene of the apartment with a product made of carbon sol in acrylic emulsion as the main adhesive is shown in FIG. 4 . As described above, the composition of the present invention is an example showing the diversity of application fields by being characterized in that it can be used with various application products and actual construction. And as a result of measuring the surface resistance by requesting the construction product to the K Test Research Institute, it was 2.5×10 ⁶ Ω/□, which is shown in FIG. 4 .

In addition, the Republic of Korea Patent Application Nos. 10-0526673 and 10-0522267 mentioned in the technology that is the background of the invention above, mainly in "There is no specific technology for the conductive carbon black (conducting carbon) used and the adhesive." First, carbon It can be said that it is a living material that has been used for a long time. Carbon black is one of the materials that have been used in various ways ranging from ink, ink, rubber reinforcing agent, etc., and activated carbon is used as a deodorant, solvent recovery, and catalyst. Here, carbon is produced by thermal decomposition or incomplete combustion of hydrocarbons. The manufacturing method is divided into pyrolysis method and incomplete combustion method. Depending on the manufacturing method, it has a variety of uses due to its high surface area and unique surface. About 85% of carbon consumption is for rubber, and about 11% is used for printing ink and conductive carbon. Carbon is a structure in which layers of a carbon hexagonal net of graphite-like structure are overlapped and connected in a chain shape. In the case of graphite, there are three lines per atom. The layer lattice of the graphite structure with weak van der waals force between layers and strong covalent bonds within the layers is anisotropic in physical properties, and the dotted line shown in FIG. (pi bonds, π bonds) are responsible for the conduction of electricity through graphite. A pi bond is a chemical bond caused by the overlapping of electron orbitals of each atom adjacent to each other in a molecule. Unlike a sigma bond, a pi bond is centered on the x-axis or y-axis, so the electron density on the z-axis connecting both atomic nuclei is zero. The pi bond is named from the Greek letter (π) meaning p orbital. And the valence electron is the outermost electron of an atom, and plays the biggest role in determining molecular bonds and chemical properties. A carbon atom in the neutral state has 4 valence electrons. 3 out of 4 valence electrons of carbon are used, and there is one free electron that does not participate in bonding in carbon having a graphite (carbon) structure. By these free electrons, graphite becomes a conductor and such conductive graphite (carbon) - One of CNT, graphene, modified graphite or xGnP - is one of the main functional materials used in the present invention. The microstructure is needle-like, plate-like, or cubic, and a particle size of 0.0001 to 25 μm was used.

division CNT Graphene (modified) graphite or xGnP rescue 6 carbons are hexagonal and tubular A thin film composed of 6 carbons in a hexagon and 1 atom thick Single-layer graphene forms multiple layers difference Numerous studies have been done as it is known as the best thermally conductive material, but when the shape is changed, the properties change. Thus, graphene appeared as an alternative material. No change in electrical properties even when stretched or bent.
The characteristic of graphene is that the effective mass of internal electrons is 0, so there is an effect that electrons move at the speed of light in graphene. Therefore, the conductivity is high As single-layer graphene is piled up, the more the stacks are, the higher the conductivity is due to the decrease in resistance due to the collapse of the symmetry due to the overlapping of the band gap. band gap 0~1.9eV 0eV 0eV electrical conductivity 0.17~2.0-5Ω-cm ~10-6Ω-cm 104~10-7Ω-cm same
weight
compare Appearance: Fiber(1D)
Density: 1.33g/cm3 Density: 2.2g/cm3 Appearance: small and bulky
Plate-shaped thin film (3D)
Density: 1.9~2.0g/cm3 dispersion time
Properties Multi-layer structure during mechanical dispersion (modified graphite) → The layer is broken and the number of layers is reduced to become graphene, improving mechanical properties

Another one of the mixing ratios of the present invention is 10 to 35% by weight of starch, 70 to 100% by weight of solid content, 0 to 40% of chloride, 1 to 100% by weight of solid salt, 5 to 40% by weight of salt, and 30 to 95% by weight of water. The composition is heated/mixed at 70-350° C., 1-60 min. A pool with a viscosity of 1,000 to 500,000 cps (using Brookfield RV DV-II + PRO) was prepared under the conditions of 1 to 20,000 rpm. In the case of construction using the prepared glue, it was additionally mixed with water 10 to 0.3 times and applied (eg, wallpaper). At this time, as a result of measuring the surface resistance of the prepared and used glue after drying, it was confirmed that it had antistatic properties and electromagnetic wave blocking properties in the range of 10 ⁵ to 10 ⁹ Ω/□ at 45%RH. The measuring instrument used at this time was Wolfgang Warmbier's Surface Resistance Meter SRMⓡ110/Made in EURO to evaluate the resistance. As shown in FIG. 6, the test conditions, applied voltage 500V, 60 sec, 20°C, 65%RH, and the test equipment is 5.1 as a result of measurement according to TOA SME-8511, D ₁ =1.96 cm, D ₂ =2.41 cm ×10 ⁷ Ω/□ (half-life 1.5 sec) and 4.3×10 ⁸ Ω/□ (half-life 2.1 sec) resistance values were obtained.

In particular, one of the mixing ratios of the present invention is 60 to 83% by weight of solid content 20% by weight adhesive material, 48% by weight solid content, 11% by weight chloride, 25% by weight solid content 6% by weight of salt solution, and other adhesives containing H ₂ O And the result of measuring the degree of reduction of the electric field after manufacturing a coating material and coating each of the four boxes with wallpaper using the general paper glue (referring to the existing or currently commercially available paper glue) and the wallpaper glue of the present invention is shown in FIG. 7 shown in As shown in FIG. 7 , it was confirmed that the measured value of PULSE's E-tester before construction was 575V/m, but after construction, it was confirmed that the place where the internal construction was performed at 0V/m is going to 0 due to the attenuation of the electric field. If the manufacturing adhesive material has three or less sides, such as a box, when the coating layer of the present invention is grounded to the ground terminal using a conductive material, the electric field (static electricity) accumulated in the coating layer (surface) escapes through the ground terminal. In case of coating (painting) on more than 4 sides, the electric field is reduced by the phenomenon that the electric field is reduced to zero (0) like the inside of a metal.

Under the same conditions as in Fig. 8, the measured value of PULSE's E-tester before painting was 346V/m, but after painting, it was 11V/m. In the sample (Fig. 9), the measuring instrument ALPHA LAB. As a result of measuring using a TriField meter (ELF-1kHz), it was over 1,000V/m, which is an area that could not be measured due to excessive generation of electromagnetic waves before coating, but it was measured at 20V/m after coating.

“The electric charge inside the conductor does not move, and the electric field inside the conductor is zero. The absence of an electric field in a conductor is not because the electric field cannot penetrate the metal, but because the free electrons in the conductor stop moving and can 'stop' only when the internal electric field is zero. As the charged metal spheres exert a pushing force, the electrons move as far apart as possible from each other, and the electrons are uniformly distributed on the surface of the sphere. If you place a positive charge exactly in the center of the sphere, you will not receive any force. The electrons on the left side of the sphere pull the charge to the left, while the electrons on the right side of the sphere pull the charge to the right with an equal force. The force acting on the charge is zero. Therefore, the electric field is also zero. If the conductor is not spherical, the charge distribution is not uniform, but - if it is a cube - most of the charge is concentrated at the edges. It is the same principle as the concentration of electric charge and force at a sharp point, but the distribution of electrons on the faces and edges is made so that the electric field becomes zero anywhere in the cube. If there is an electric field inside the conductor, the free electrons inside the conductor will start to move. Until equilibrium is reached, the positions of all electrons move until the electric field inside the conductor is zero. Therefore, regardless of its shape, the interior of a metal has zero electric field. In the initial state, assuming that there is an electric charge and an electric field in the conductor, the presence of an electric field means that there is a movement of the electric charge. The electric charges in the conductor start to move under the influence of the electric field, and the movement of the electric charges moves in the direction that makes the electric field within it zero and continues until it becomes zero, i.e., there are no more electric charges moving. . If the electric field in the conductor does not become zero, the charges move under a force until the electric field becomes zero. This movement causes all the charges to gather on the surface of the conductor and is forced outward, where it can no longer move. This is the metal sphere theory (the theory first mentioned by the inventor) (see Figure 10), and is why the electric field on the surface of a conductor is always perpendicular to the surface. The inside moves continuously to become a (-) ion environment. Based on this theory, the present inventor thinks that electronic components are put in a shielding bag such as an aluminum bag, etc. , it is judged that this also used the principle of the metal sphere.”

11, 12, 13, and 14, a commonly used Donggeun fluorescent lamp is installed at a height of 2.3 m equal to or similar to the height of an apartment from the floor to the ceiling, and is located at a position 1.0 m away from the floor, which is the height of a child. The electromagnetic wave measuring instrument HI-3604 was connected to the frequency counter (FC-1022), and the HI-3604 was displayed as an analog waveform, and pictures were sequentially captured after shooting a video. The electric field observed by the measuring instrument before construction (painting) was 90-100V/m, and it was found that a considerable amount of the electric field was generated even when the light was off. An actual measurement result showing that it is not is obtained, and it is shown by shooting and capturing a video.

And the apartment in which they actually reside was mass-produced and manufactured in a pool manufacturing plant in the same proportion (content) as the composition of the present invention, and the interior of the apartment was painted. In the apartment rooms 1, 2, 3, living room, kitchen, etc., the degree of electric field generation before and after painting was measured and shown in FIG. to /m, Zone 2 from 160V/m pre-padding to 99V/m after coating, Zone 3 from 258V/m before coating to 73V/m after coating, Zone 4 to 69V/m before coating The electromagnetic wave environment was improved with an electric field of 48V/m after coating, and the attenuation ratio fell in the area where the difference in the attenuation rate was mainly absorbed by the ceiling. It could be seen that the electromagnetic wave attenuation environment was improved as the

In Example 3, a composition (composition 1) in which 3.5 to 12% by weight of salt in an antistatic material is mixed with an adhesive material with a solid content of 3 to 65% by weight, and 5 to 10% by weight of seawater (collected in July in the East Sea) are mixed The result of measuring the surface resistance and half-life of the composition (composition 2) and the composition (composition 3) prepared by mixing 6-30 wt% of Mn-Zn ferrite (soft-1) in the metal powder is shown, as shown in Table 7 together. The composition containing salt and the composition containing seawater were as low as 10 ⁶ ∼ 10 ⁷ Ω/□, and the composition containing ferrite, an insulator, had a high resistance value, but ferrite absorbs a magnetic field rather than an electric field, and It is a composition that dissipates heat and shields it.

An antibacterial test, which is another object of the present invention, was performed on the compositions, and the results are shown in Table 8. According to the results of the antibacterial test, - In Japan, children's products should be 70% or less. This is because the high antibacterial activity can eradicate all bacteria and may have a rather bad effect, but in Korea, antibacterial activity of 90% or more is preferred. - As a result of measuring the antibacterial rate against E. coli strain by KS K 0693-95, composition 1 and composition 2 obtained more than 90% antibacterial value, and composition 3 obtained more than about 30% antibacterial value. Salt, which is the main material in the present invention, does not give a chance for various germs, bacteria or microorganisms to reproduce, and has properties that do not change even after a long time. Salt dissolves well in water, so it penetrates and mixes well with other substances. Salt leads the metabolism in the human body by decomposing food and excreting wastes. The biggest cause of harm to human health may be poor metabolism. It is said that when the metabolism of pushing out the old in the cell and accepting the new is not done smoothly, the blood becomes acidic and the immunity is weakened, increasing the risk of disease. Intake of salt before and after surgery is said to speed up wound healing, which would prove that salt plays an important role. Ringer's solution is also Na ⁺ 130, K ⁺ 4, Ca ²⁺ 3, Cl ^- 109 ratio, similar to the human body ≒ seawater ratio. Salt quickly restores dead or destroyed cells. As described above, due to the beneficial action of salt (salt), it has lower antibacterial activity than herbicides, but salt (according to the present invention) is a beneficial substance to the human body. In the antibacterial experiment of the present invention, the bacterial solution was shaken and incubated at 25°C for 24 hours, and the number of bacteria was measured (the number of times 150 times/min). ATCC25922 was used.

Item unit of measure composition 1 composition 2 composition 3 Assessment Methods surface resistivity Ω/□ 2.1x10 ⁵ 1.3 x 10 ⁷ 6.4 x 10 ¹¹ KS M 3015-1997
(or ASTM D257) half life sec 0.5 0.8 20 KS K 0555-2000, method A

composition Test analysis result (number of bacteria/ml) antibacterial immediately after contact after 24 hours (increase rate) Blank 120,000 3,180,000 -2,550.0 % (26.5 times) composition 1 120,000 897 99.6% composition 2 120,000 2,378 98,9% composition 3 120,000 57,875 51.8%

Materials that provide adhesion and appearance include Acrylic, Epoxy, Polyvinyl Alcohol, Polyvinyl Acetate, Silicone, Polyurethane, Ethylenevinyl Acetate, Polyvinyl Chloride, Vinyl Acetate Acrylic Copolymer, Acrylic Copolymer with a solid content of 1 to 100% by weight. Gum Rosin, 2-Ethyl Hexyl Acrylate Monomer, 2-Ethylhexyl 2-Propenoate, 2-Hexyl. Resin, Solution or Acid, Primer, Emulsion, Monomer, Copolymer of 2-EHAM, 2-Ethyl Hexyl Acryl Acid, Butyl Acrylate Monomer, N-Butyl Ester, Butyl 2-Propenoic Chloroprene Rubber, Acid, n-Butylacrylate, Vinyl Acetate Monomer , Resorcinol, α-Olefin, Isocyanate, Phenolic, Thermosoftening Plastic [PVC (Polyviny chloride), polyester, PVC sol, PP (Polypropylene), ABS (Acrylonitrile Butadiene Styrene), PMMA (Polymethlmethacrylate), PE (Polyethylene), PET ( Polyethylene Terephthalate), PBT (Polybuthylene Terephthalate), PPS (Polyphenylene Sulfide), PC (PolyCabonate), Nylon, LDPE (Low Density Polyethylene), HDPE (High Density Polyethylene), Polystyrene any one or a mixture of two or more], Thermosetting Plastic (Phenol) , Urea, Melamine, Polyurethane, Unsaturated Polyester, Silicon Resin alone or a mixture of two or more), Starch, Rice, Wheat, Bran, Corn, Potato, Dextrin, Modified starch, Grains such as Glutinous Rice, Nori, Gelidium amansii Seaweed such as LAMOUROUX , of grains such as dextrin, substances manufactured from modified starch, etc., powdered grass (Germany H company, Korea E company, K company, Y company, etc. are used); Use 1 to 99% by weight alone or in a mixture of two or more,

The metallic materials used are 0.0001∼7,000㎛ spherical, with various shapes such as plate shape, needle shape, Iron powder, Copper powder, Cobalt powder, Tin powder, Aluminum powder, Magnesium powder, Titanium powder, Silicon powder, Nickel powder, Zinc powder, Manganese powder. Soft ferrite such as Silver powder, Ag coated Cu, Ni coated Cu, Indium tin oxide, solder ball (Free lead Tin-Bismuth), silver chloride, Antimony tin oxide, Stainless Steel, Mn (or Mg, Ni, etc.)-Zn ferrite And hard ferrite such as Ba (or Sr, etc.) ferrite was used. - In the previous invention to prevent the charging phenomenon, conductive fillers or surfactants were added, but these materials cause loss of mechanical properties of polymer resins or interface The polymer added with the activator has a surface resistance of 10 ⁹ Ω/□ or more and has a disadvantage in that the antistatic performance is poor when used alone. - Therefore, spherical and flake-shaped (or plate-shaped) metal materials with a particle diameter of 0.001-25㎛ are surface-modified using carboxylic acid-based, fatty acid, and silane-based materials, and 3.5-90.0% by weight of the surface-modified metal material is added to the polymer. As a result of evaluating the electric and magnetic field characteristics in the state of dispersing and dispersing the crystalline metal material on the surface (manufactured in the form of a sheet for measurement), it exhibits amorphous properties and acts as a broadband electric and magnetic field shielding agent. The surface resistance is measured as 10 ^-3 ∼10 ¹³ Ω/□, and it can be used in a wide range from conductors to insulators depending on the metal material and content used. The shielding effect is defined as the ratio of the received power received through the specimen to the incident power. For a constant incident power, the difference in the received power when the material to be tested is installed on the measuring jig and when it is not, that is, insertion loss. By measuring the shielding effect can be measured. The theoretical shielding effect was calculated by Schelkunoff et al. by dividing the signal transmitting and receiving parts by an infinitely large shielding surface, and considering the reflection, absorption and transmission processes of electromagnetic waves perpendicular to the shielding surface. The shielding ratio (%) calculation was shown by the shielding effective value (dB) obtained in the following Figures 16, 17, and Table 9.

dB Shielding rate (%) 20 90 40 99 60 99.9 90 99.99 100 99.999

Shielding Effectiveness(dB) = 20 log V1/V2Shielding effectiveness(SE) is as follows.

SE(dB) = A + R + B

A: absorption loss

R: reflection loss

B: multiple internal reflection loss

*Where A(dB) is

t: thickness of barrier f(MHz): frequency(MHz)

σ: conductivity (relative to Cu=1)

μ: magnetic permeability (relative to vacuum or Cu=1)

A is proportional to the shield thickness (t) and the conductivity (σ) and permeability (μ). The measurement error of the shielding test varies depending on the signal generator, spectrum analyzer, RF (Radio Frequency) switch, step attenuator, and measurement repeatability, but the total error range of this system is less than 5%.

Through the above experiment, - Mn-Zn ferrite (Soft-1, Table 10, Fig. 18) of the metal material is used to absorb the magnetic field and then convert it into heat to remove it - Depending on the additive material and the mixing ratio The absorption area and absorption power of the magnetic field are different, and the greater the content of the metal material with respect to the magnetic field, the better the shielding effect. A magnetic field absorbing composition was prepared by mixing 5 to 30% by weight of soft ferrite with a polymer material based on the total weight. It was found that the prepared composition sheet acts as an amorphous material by adding it in a powder state, and thus the area capable of shielding electromagnetic waves is broadened. It can be seen that FIG. 19 shows a shielding rate of 20 to 45% in the entire area of the 10 to 1000 MHz band (measurement standard: D4935-99 Standard Test method for Measuring the Electromagnetic Shielding Effectiveness of Planar Materials), which is the measurement area.

Measurement Method Symbol Unit Soft-1 Soft-2 Soft-3 Soft-4 Surface Area (BET) m2/g 1.4 0.9 0.8 1.6 Moment Saturation EMU/g 73 60 59 83 Average Particle
Diameter (Fisher) μm 3.2 4.4 3.6 3.7 Moisture % 0.02 0.02 0.00 0.01 Initial Permeability μ _i 120 800 350 2500 Saturation Flux Density
at Filed Density B _s
H Gauss
Oersteds 3400
10 3000
10 2700
10 5000
10 Residual Flux Density Br Gauss 2500 1800 1500 1000 Coercive Force H _c Oersteds 1.5 0.2 32 0.3 Curie Temperature T _c ℃ >200 >160 >120 >190 Resistivity ρ Ω-cm <106 <105 <104 <102 Sintering Density g/cm3 5.1 5.0 4.8 4.7

And the Republic of Korea Patent Application No. 10-2000-0068297, which was mentioned in the technology that is the background of the invention, solves "the problem of difficulty in manufacturing a commercial product due to the occurrence of layer separation due to the use of a high-density radio wave absorber and high viscosity" Here's how to do it: Layer separation occurs when high-density powder and polymer have poor miscibility. As a solution to this problem, hydrophilic powder was modified using a surface treatment agent for hydrophobic treatment, for example, a carboxylic acid-based, fatty acid, and silane-based surface treatment agent. In addition, the composition, which is difficult to disperse due to high viscosity, was dispersed using a thress roll mill (three-roll mill or three-roll mill). When the number of powder passes was less than 2 times, agglomerated parts were present (FIG. 20), but a composition suitable for application could be prepared by passing 3 to 10 times or adding a solvent during the pass (FIG. 21). The experimental photos were taken and shown in FIGS. 20 and 21 .

Acrylic, Epoxy, Polyvinyl Alcohol, Polyvinyl Acetate, Silicone, Polyurethane, Ethylenevinyl Acetate, Polyvinyl Chloride, Vinyl Acetate Acrylic Copolymer, Acrylic Copolymer with a solid content of 1 to 100% by weight. Gum Rosin, 2-Ethyl Hexyl Acrylate Monomer, 2-Ethylhexyl 2-Propenoate, 2-Hexyl. Resin, Solution or Acid, Primer, Emulsion, Monomer, Copolymer of 2-EHAM, 2-Ethyl Hexyl Acryl Acid, Butyl Acrylate Monomer, N-Butyl Ester, Butyl 2-Propenoic Chloroprene Rubber, Acid, n-Butylacrylate, Vinyl Acetate Monomer , Resorcinol, α-Olefin, Isocyanate, Phenolic, Thermosoftening Plastic, Thermosetting Plastic, Starch, Rice, Wheat, Bran, Corn, Potato, Dextrin, Modified starch, Grains such as Glutinous Rice, Nori, Gelidium amansii Seaweed such as LAMOUROUX, Dextrin substances manufactured from grains, modified starch, etc., powdered grass (Germany H company, Korea E company, K company, Y company, etc. powdered grass, etc. are used) and 1-100% solids wheat grass without preservatives; of 1 to 99% by weight alone or a mixture of two or more,

Use 0-50 wt% of metal chloride powder or aqueous solution thereof of aqueous nH ₂ O (n=0-99) having a solid content of 1-100 wt%, or use 0-50 wt% of these materials alone or a mixture of two or more ; Solid content of 1-100% by weight Salt is edible salt containing sodium chloride as the main ingredient, sea salt and industrial substances used as chemicals, and rock salt alone or 0-50% by weight of a mixture of two or more; 0-50 wt% of bittern or 100 g of these heated and concentrated 5 to 90% is used; Use 0-50% by weight of purified salt instead of sea salt to secure antibacterial and anti-mildew effects, especially by treating at a high temperature of 100°C or higher to eradicate all bacteria in the additive material itself; When manufacturing a product, 0-5 wt% of an acid (pH <4) of 1-100 wt% of solid content (purity) is mixed with some products to remove not only the compatibility of the adhesive material, but also the adhesive and self-retained bacteria of the composition. ; Among the above-mentioned calcium chloride and sodium chloride of hydrous nH ₂ O (n=0 to 99) having a solid content of 1 to 100% by weight, they are treated with an acid and a chemical reaction between heterogeneous aqueous solutions, etc. Among the lowered ones, 0-50 wt% of these materials alone or two or more are used; In addition, 5 to 100% by weight of solid content ionic compounds are used alone or 0 to 50% by weight of two or more of the ionic compounds in anhydrous form, hydrate form, or aqueous solution form; Solids 0.1-50% by weight Conductive Polymer 0-50% by weight, either used; Use 0 to 99% by weight alone or in a mixture of two or more,

solvent; Content 1∼99.9 wt% Methanol, Ethanol, Butanol, Dichloromethane, Ethylacetate, Hexane, Diethylehter, Acetonitrile, Benznene, Dibasic Ester, 1-METHOXY-2-PROPANOL, BC, Diethylene Glycol Monoethyl Ether Acetate, Toluene, Alcohol, H ₂ O , etc; Used alone or in a mixture of 0 to 97% by weight of two or more,

Iron powder, Copper powder, Cobalt powder, Tin powder, Aluminum powder, Magnesium powder, Titanium powder, Silicon powder, Nickel powder, Zinc having various shapes such as 0.0001~7,000㎛ spherical shape, plate shape, needle shape, etc. in the above single or mixed adhesive composition powder, Manganese powder. Soft ferrite such as Silver powder, Ag coated Cu, Ni coated Cu, Indium tin oxide, solder ball (Free lead Tin-Bismuth), silver chloride, Antimony tin oxide, Stainless Steel, Mn (or Mg, Ni, etc.)-Zn ferrite And 0 to 99% by weight of one or more of hard ferrites such as Ba (or Sr) ferrite alone or in a mixture composition to absorb electromagnetic waves, block electromagnetic waves, antistatic, antibacterial/mildew, flame retardant, freeze prevention, corrosion prevention, humidity As a result of manufacturing and evaluating an adhesive exhibiting control and rust prevention performance, it is shown in FIG. 22 that it has 10 ⁴ to 6 Ω/□.

The samples prepared according to Examples 1, 2, and 3 are mainly for the purpose of reducing the electric field among electromagnetic waves, and the purpose of this Example and Examples 4 and 5 is to absorb and remove electromagnetic waves from the viewpoint of the magnetic field.

Measurements are performed using the instrument Network Analyzer Mod. Using MS46322A, specification 10MHz~20GHz, Tell Cell DC~5GHz, the following test sequence was carried out. ① Install the equipment as shown in FIG. 23 before measuring the absorption rate of the measurement sample. ② Adjust the height of the sample mount and the antenna to the same height. ③ Turn on the power of the measuring equipment and preheat for 30 minutes and set up the equipment necessary for measurement. ④ When calibration is performed, the value of the measuring device is fixed at 0 dB. ⑤ If it is not fixed to 0 dB, check the height of the sample mount and antenna and set it to 0 dB. ⑥ When the calibration of the measuring equipment is finished, the sample is mounted on the sample mounting table and fixed as shown in FIG. 24 . ⑦ At this time, be careful not to move the sample holder. ⑧ After checking whether the value at 0 dB has changed in the measuring device, write it in the data sheet and save it.

Through the above procedure, the test method IEEE-SDT-1128-1998, the test environment temperature 23 ℃, humidity 44%RH, the absorption rate measurement results for six main several frequencies are shown in Table 11. As shown in Table 11, it can be seen that the product (measurement sample) manufactured using the metal powder exhibits an effect on the magnetic field.

(Unit: dB) Frequency [GHz] antistatic
paper grass 3~10% of conductive carbon in antistatic coating pool frequency [MHz] General coating paste + Ni powder 5~30% Antistatic coating paste + Ni powder 20~30%% Antistatic coating paste + Ni powder 25~35% General paper paste + Ni powder 30~50% One - 0.47 - 0.06 200 - 0.12 - 0.12 - 0.12 - 0.15 2 - 0.40 - 0.40 400 - 0.75 - 0.80 - 0.80 - 0.86 3 - 0.40 - 1.02 600 - 4.31 - 4.33 - 4.31 - 6.05 786 - 4.43 - 5.20 - 6.32 - 9.63 4 - 0.41 - 1.66 800 - 1.54 - 1.56 - 1.54 - 1.87 5 - 0.42 - 1.14 966 - 7.50 - 9.82 - 11.40 - 19.89 1000 - 1.19 - 1.19 - 1.20 - 2.24

Acrylic, Epoxy, Polyvinyl Alcohol, Polyvinyl Acetate, Silicone, Polyurethane, Ethylenevinyl Acetate, Polyvinyl Chloride, Vinyl Acetate Acrylic Copolymer, Acrylic Copolymer with a solid content of 1 to 100% by weight. Gum Rosin, 2-Ethyl Hexyl Acrylate Monomer, 2-Ethylhexyl 2-Propenoate, 2-Hexyl. Resin, Solution or Acid, Primer, Emulsion, Monomer, Copolymer of 2-EHAM, 2-Ethyl Hexyl Acryl Acid, Butyl Acrylate Monomer, N-Butyl Ester, Butyl 2-Propenoic Chloroprene Rubber, Acid, n-Butylacrylate, Vinyl Acetate Monomer , Resorcinol, α-Olefin, Isocyanate, Phenolic, Thermosoftening Plastic, Thermosetting Plastic, Starch, Rice, Wheat, Bran, Corn, Potato, Dextrin, Modified starch, Grains such as Glutinous Rice, Nori, Gelidium amansii Seaweed such as LAMOUROUX, Dextrin 1~99% by weight of materials manufactured from grains, modified starch, etc., powdered grass (using powdered paste such as German company H, Korea company E, company K, company Y, etc.) do,

Sodium Chloride, Magnesium Chloride, Calcium Chloride, etc. belonging to metal chlorides of hydrated nH ₂ O (n = 0 to 99) having a solid content of 1 to 100% by weight or in the form of an aqueous solution thereof are prepared and used in an amount of 0 to 50% by weight, or a substance thereof 0 to 50% by weight of the composition alone or in a mixture of two or more; Solid content 1-100% by weight Salt is used alone or 0-50% by weight of edible salt containing sodium chloride as the main component, sea salt and industrial salt materials used as chemicals, rock salt, and refined salt; Magnesium Chloride 15~19%, Magnesium Sulfate 6~9%, Potassium Chloride 2~4%, Sodium Chloride 2~6%, Magnesium Bromide 0.2~0.4%, etc. Solid content 1~69% by weight bittern, or 100g of these 0 to 50% by weight of 5 to 90% concentration by heating; Mixing 0-5% by weight of an acid (pH<4) of 1-100% by weight of solid content (purity) to remove not only the miscibility of the adhesive material but also the adhesive and self-retaining bacteria of the composition; Among the above-mentioned calcium chloride and sodium chloride of hydrous nH ₂ O (n=0 to 99) having a solid content of 1 to 100% by weight, they are treated with an acid and a chemical reaction between heterogeneous aqueous solutions, etc. Among the lowered ones, 0-50 wt% of these materials alone or two or more are used;

In addition, 5 to 100% by weight of the solid content of the ionic compound is used alone or 0 to 50% by weight of two or more of the ionic compound in the form of an anhydride, hydrate, or aqueous solution; Solids 0.1-50% by weight Conductive Polymer 0-50% by weight, either used; Use 0 to 99% by weight alone or in a mixture of two or more,

0.0001~7,000㎛ Hydrous aluminum silicate mineral containing alkali metal or alkaline earth metal with various shapes such as spherical and plate-like, needle-like, zeolite substituted with Al, siliceous porous material, lightweight foamed ceramic, Silica, Perlite, Titanium Dioxide, Clay, talc, Aluminum Hydroxide, Kaolin, Magnesium Hydroxide, Calcium Carbonate, Diatomite, Loess, Bentonite, Quartz sand, Gypsum, Lime, cement, Terra alba, Pozzolan, Diatom, Pupl or water (H ₂ O) dispersed solids 1 to 100% by weight Pupl or the like is used alone or 0 to 99% by weight of two or more; Among anionic, cationic and amphoteric surfactants, Ammonium Dodecylbenzenesulfona, Polyoxyethylenenonylphenyl Ether, Polyoxyethyleneoctylphenyl Ether, Sodium Dodecylsulfonate, Sodium Dioctylsulfosuccinate, Sodium Dodecylbenzenesulfonate, Ammonium Dodecylbenzenesulfonate, Ammonium Dodecylbenzenesulfonate, Sodium Alkylaryl Esterlic Dispersant, Soda-based dispersant, Soda-based dispersant, Sodium Alkylaryl Esterlic, Phosphate dispersant Sodium Polycarboxyl Acid; Octylalcohol, Cyclohexane, Polydimethylsiloxan, other higher alcohols or Ethylene Glycol, spandex, other nonionic active agents, silicone defoaming agents; It is characterized in that it contains 0 to 55% by weight of each of at least one type, and cellulose type, alkali swellable type, ester type, urethane compound type, bento type, airgel type, acrylic type, etc. That is, for example, gum arabic, jintan Gum, tara gum, guar gum, agar, kerazinan (carrageenan), sodium alginate, powdered cellulose, cellulose, methylcellulose, HEC, CMC, MC, SD, BT, EHEC, MEHEC, LBG, tararind, arabic , Soybean polysaccharide, curdlan, gellan, glucomannan, soda alginate, pectin, carbomer, high cell, gelatin, polycarboxylic acid, carboxyvinyl polymer, metal ethyl cellulose, potassium alginate, ritexrose, sodium carboxymethyl starch, casein, starch among them; It is characterized in that it contains 0 to 55% by weight of each of at least one type, Dioctyl Phthalate-based, Dibutyl Phthalate-based, Ester-based, etc. are used, preferably Alkyl Ester; It is characterized in that it contains the use of 0-20% by weight alone or two or more,

Solid content 1-100 wt% Sodium carboxymethylcellulose (CMC), chlorinated 5 Chloro 2 methyl 4 isothiazolin 3 one and unchlorinated 2 Methyl 4 isotiazolin 3 one organic nitrogen sulfide, strong acids (pH <4) ), hydrochloric acid, sulfuric acid, citric acid, glacial acetic acid, malic acid oxalic acid, sodium benzoate, and borax each or a mixture of two or more types 0 to 3% by weight, preferably 0 to 2% by weight, 3-lodo-2 propynl butyl carbamate (product name: MX-3 Advanced Plus, manufacturer: CONNELL FAMILY INC.), C ₁₁ H ₁₉ NOS (TK-800), UNICOOL-K14 (manufacturer: UCC), NP-40; It is characterized in that it comprises the use of 0 to 5% by weight alone or in a mixture of two or more,

0.0001~7,000㎛ Iron powder, Copper powder, Cobalt powder, Tin powder, Aluminum powder, Magnesium powder, Titanium powder, Silicon powder, Nickel powder, Zinc powder, Manganese powder with various shapes such as spherical, plate, and needle shape. Soft ferrite such as Silver powder, Ag coated Cu, Ni coated Cu, Indium tin oxide, solder ball (Free lead Tin-Bismuth), silver chloride, Antimony tin oxide, Stainless Steel, Mn (or Mg, Ni, etc.)-Zn ferrite And hard ferrite such as Ba (or Sr, etc.) ferrite, conductive carbon powder and fiber, solid content 1.0-80.0 wt% Conductive carbon sol alone or a mixture of 2 or more types 0-97.5 wt%, or these metal materials with carboxylic acid It is also characterized in that it can have a feature that can be manufactured into a product having a color by a composition prepared by surface-modifying using a fatty acid or a silane-based material, and composition of 0 to 90.0% by weight of a surface-modified metal material and an additive material thereof. with

Content 1∼99.9 wt% Methanol, Ethanol, Butanol, Dichloromethane, Ethylacetate, Hexane, Diethylehter, Acetonitrile, Benznene, Dibasic Ester, 1-METHOXY-2-PROPANOL, BC, Diethylene Glycol Monoethyl Ether Acetate, Toluene, Alcohol, H ₂ O , etc; In order to identify the antibacterial and anti-mold properties, which is another object of the present invention, the specimen prepared by the composition, characterized in that it is mixed alone or in 0-97.0% by weight of two or more types, evaluated by requesting the test researcher B, - of the present invention It is possible to simultaneously exhibit antibacterial and anti-mildew performance by simultaneously inhibiting E. coli, Pseudomonas aeruginosa, Staphylococcus aureus, etc. or mold bacteria added to impart functionality; 「E. coli, Pseudomonas aeruginosa, and Staphylococcus aureus belonging to the (-)charge strain, etc., and fungi belonging to the (+)charge strain. Fungi and (+)charge are the scientific principles first mentioned by the present inventor that they adsorb (collect) E. coli, which is a (-)charge strain, respectively, and penetrate the cell wall and kill them”. +) Charge Ag carrier zeolite is a product made by mixing and sold as an antibacterial product that inhibits E. coli. Therefore, the result of each evaluation according to the principle by the present inventor - that is, the result of the antibacterial test (shown in Fig. 25) is the test standard KS K 0693:2001, nonionic surfactant Tweea 80, Staphylococcus aureus ( Staphyococcus aureus ATCC 6538P) showed excellent antibacterial performance, with 99.9% reduction in bacteriostatic bacteria and 99.9% in Klebsiella pneum oniae 4352.

26 is a comparison of the results of an acrylic (acrylic primer, acrylic emulsion)-based adhesive with an adhesive in which the composition material of the present invention is not added and an adhesive in which 3.5% of the refined salt composition additive of the present invention is added as an anti-military test. As shown in Figure 26, it can be seen that there is a mold inhibitory effect. The experiment is the result of measuring the fungal strain after culturing for one week in a constant temperature and humidity chamber (experimental device). The results of comparative evaluation of the acrylic primer (acrylic emulsion) adhesive used for construction and the acrylic adhesive prepared by the present invention were captured after simultaneous shooting. Although it was confirmed that a large amount of mold is generated in the acrylic adhesive system, which is used for waterproofing or adhesion purposes, even now when the present invention is applied for a patent, it can be seen that the product of the present invention has anti-fungal properties. 27 is a result of comparative evaluation in the same method by applying the same composition ratio of the present invention to the PVA-based adhesive, and the same result as that of the acrylic adhesive was obtained. 28 is a method for additionally evaluating the superiority of the present invention, and is a result of an experiment with bread, which is highly resistant to mold. For the evaluation of the experiment, the experiment was conducted in the state that moisture was always kept on the bread for 4 days. The portion of the bread which was not in contact with the noodles prepared by the above composition had more mold than the portion of the bread that was in contact with the present invention. It was found that the anti-mildew effect was very good, as the composition of the present invention contained no or almost no mold. And, in fact, Fig. 29 is a photograph of mold occurring on the apartment wall, and Fig. 30 is a photograph of mold bacteria occurring on the wall of a country house exposed to a humid environment.

40 to 85% by weight of water, 50 to 100% by weight of solids, 3 to 30% by weight of chlorides, and 2 to 30% by weight of salt, 78% by weight of solids, into 12-30% by weight of starch, which is one of the mixing ratios of the present invention, and heated (50-350° C., 1-150 min. After boiling while stirring or extruding at 1-100,00 rpm), it was prepared in a gel state. In general, the solid content was 3 to 35 wt% higher than that of commercially available grass, but the viscosity was 80,000 to 200,000 cps (viscometer, when using Brookfield RVDV-II + PRO), which was somewhat lower or the same. General grass (commercial grass) solids ca. 15-20% by weight, in order to meet 120,000-240,000cps, the content of water was reduced during manufacturing to prepare a non-freezing pool.

The composition of the present invention has the effect of lowering the freezing point depending on the content of the added chloride - in particular, paper grass (wheat grass), water-soluble EVA, water-soluble acrylic, etc. - It was invented for the first time in the present invention, and therefore the freezing point lowering phenomenon like antifreeze for automobiles It was not easy to freeze. That is, it is characterized by lowering the freezing point and preventing the phenomenon of freezing, and the viscosity in commercially available starch paste (wheat paste) with a solid content of 15 to 21% by weight is about 140,000cps (measured by Brookfield RV DV-II + PRO). In order to lower the viscosity (to facilitate construction (painting)), water is additionally added and used. In winter, a small amount of water should be used compared to summer due to the freezing (hyp) phenomenon of water, but adhesion according to the present invention The composition can be used in all weather without the above concerns, so it can be used as it is at the additional water mixing ratio of the previous plastering company. Another strength is that it is possible to secure an economic advantage by securing the quantity according to the forecasting of the use of wallpapering grass (wheat grass) and reducing the cost of construction materials.

The motive of the present invention starts from the fact that seawater does not freeze well in winter. In order to confirm the above principle, the following test was first performed. Water begins to freeze past 0°C and freezes completely when it reaches -1.0°C, but a mixture of 0.24 g of salt and 19.76 g of water begins to freeze at -0.45°C and partially freezes at -1.0°C (salt 1.12 wt%). A mixture of 0.62 g of salt and 19.38 g of water was not frozen at -1.0°C at all, but slightly frozen at -2.0°C, and more unfrozen water remained than the previous brine (1.12% by weight of salt) (3.1% by weight of salt). As described above, as the concentration of salt increases, it is confirmed that the freezing point is lowered and thus does not freeze well, and applied to the present invention to invent a new product. When this invention is applied to a product with a high freezing point such as a water-soluble product, it lowers the freezing point like an antifreeze (a liquid used to prevent the freezing of cooling water for automobile engines), thereby reducing the original product's inherent adhesion and coating power due to freezing prevention. It prevents the loss of adhesion and coating power by maintaining its original performance.

Therefore, the present invention prevents the phenomenon of the adhesive material from freezing before drying when constructing structures, interiors, etc., such as building materials and construction in a cold environment. Innovative technology applicable to fields that can prevent

Another object relates to the antibacterial properties, and the antibacterial experiments in which the compositions prepared in Examples 1, 4, 5, 7, 8, 9 were evaluated by requesting the C Test Research Institute were tested according to the test standard JIS Z 2801-2010, standard film sterilized. The antibacterial activity of Staphyococcus aureus ATCC 6538P was 2.5 in PP film, 0.1 mL of the inoculum solution, and the antibacterial activity was 3.1 in Escherichia coli ATCC 8739, confirming that the antibacterial performance was excellent. The antibacterial activity value of Staphyococcus aureus ATCC 6538P was 2.5, the initial strain of 5.6*?* ⁴ in the blank, the number of bacteria after 24 hours of incubation of 2.1×10 ⁴ , and the number of bacteria after culturing for 24 hours in the present invention was 62. when Escherichia coli ATCC 8739; In Blank, the initial strain was 4.6×10 ⁴ , the number of bacteria after culturing for 24 hours was 5.0×10 ⁴ , and in the present invention, the number of bacteria was <0.63 after culturing for 24 hours, indicating an antibacterial activity value of 3.1. The experimental results are shown in FIG. 31, and it can be confirmed that the antibacterial performance is excellent.

As one of the compositions of the invention important in the present invention, the composition of dobae grass (wheat grass); According to Examples 1, 4, 5, 7, 8, and 9, starch as one of the above compositions (grade 1, grade 2, grade 3, each alone or a mixture of two or more compositions) 10-40 wt%, water 30-95 45 to 350 including one or more 30 to 100% by weight of solid content, 30 to 100% by weight of calcium chloride, 3 to 40% by weight of calcium chloride, 20 to 99% by weight of solids, and 3 to 40% by weight of salt components (sun salt, rock salt, refined salt, etc. alone or mixed) ℃, 3-60 min. 1 to 20,000 rpm, 0.5 to 5 atm, the mixing ratio of the liquid coating composition containing preservative-free (no formaldehyde in preservatives), etc., packaged after production while stirring, and its manufacturing method; Among the above compositions, as one of the compositions of the invention, which is important in the present invention, the composition of the coating grass: 10 to 40 wt% of starch (1st grade, 2nd grade, 3rd grade, each alone or mixed composition of two or more), 30 water 45 to 350° C., including at least one 30 to 100% by weight of solids, 30 to 100% by weight of calcium chloride, 3 to 40% by weight of calcium chloride, 20 to 99% by weight of solids, and 3 to 40% by weight of salt components (sun salt, rock salt, refined salt, etc.) to 95% by weight; 3 to 60 min. 1 to 20,000 rpm, 0.5 to 5 atm, the mixing ratio of the liquid coating composition containing preservatives (no formaldehyde in the preservatives), etc., packaged after manufacturing, and its manufacturing method; Another composition, starch (1st grade, 2nd grade, 3rd grade, each alone or mixed composition of two or more) 15 to 30% by weight of calcium chloride solution in 15 to 90% by weight of water and 45 to 50% by weight %, solid content 20-35 wt% Salt component (solar salt, rock salt, refined salt, etc. alone or mixed use) 5-40 wt% of one or more solutions, and anti-corruption material (solid content (acidity) 1 to 99 wt% acid substance ( pH <4)) at 45 to 350° C., 3 to 60 min. 1 to 20,000 rpm while stirring, the mixing ratio of the packaged liquid paste composition and its manufacturing method; Another composition, starch (1st grade, 2nd grade, 3rd grade, each alone or mixed composition of two or more), 15 to 90% by weight of water, 15 to 30% by weight of calcium chloride solution %, 20 to 5% by weight of solid content Salt component (solar salt, rock salt, refined salt, etc. alone or mixed use) 5 to 40% by weight of two or more solutions, and anti-corruption substances (solids (acidity) 1 to 99% by weight acid substances ( pH <4) and the anti-corruption material mentioned in Example 1 in a ratio of 1: 1 to 50) 45 to 350° C., 3 to 60 min. 1 to 20,000 rpm while stirring, the mixing ratio of the packaged liquid paste composition and its manufacturing method; Another composition, starch (1st grade, 2nd grade, 3rd grade, each alone or mixed composition of two or more) 15 to 90% by weight of water, 15 to 30% by weight of calcium chloride solution %, solid content 20-100 wt% Salt component (solar salt, rock salt, refined salt, etc. alone or mixed use) 5-40 wt% of two or more solutions, solid content 1-100 wt% sodium carboxymethylcellulose (CMC), chlorine treatment Organic nitrogen sulfide, acids (pH <4), citric acid, glacial acetic acid, malic acid oxalic acid, sodium benzoate, and borax in which 5 Chloro 2 methyl 4 isothiazolin 3 one and unchlorinated 2 Methyl 4 isotiazolin 3 one are mixed together or Solid content (acidity) of 2 or more 1~99 wt% Hydrochloric acid 1: 1~20 ratio 0~3 wt%, 3-lodo-2 propynl butyl carbamate (MX-3), C ₁₁ H ₁₉ NOS (TK- 800), UNICOOL-K14 (manufacturer: UCC), among NP-40; 45 to 350° C., 3 to 60 min. 1 to 20,000 rpm while stirring, the mixing ratio of the packaged liquid paste composition and its manufacturing method; The biggest feature of the present invention is that different compositions (prescriptions) and compounding and classification of substances to be blended in the composition are different in order to improve the long-term storage (aka, long-term storage) of the products formulated and manufactured according to the season. one of them

Filming of those not surface-coated on PS foam (left) and coated with the composition of the present invention (right) with the composition products of the present invention according to Examples 1, 4, 5, 7, 8, 9, and 11 After capture results are shown in FIG. 32 . When the sample before and after coating the PS foam was lit, as a result, the right side completely melted and the PS foam in the area where there was a flame melted and disappeared, but the sample coated on the surface did not melt due to the flame retardant properties of the composition of the present invention Cotton is the result of confirming the flame retardant (flame retardant) characteristics of the present invention as a photograph showing that it remains.

One of the compositions according to Examples 1, 4, 5, 7, 8, 9, and 11 is first coated with 0.01 to 10,000 μm on one side or both sides, and the adhesive material of the composition and the adhesive material used for the composition are aqueous Or a method for protecting a functional part coated with the composition of the present invention by coating one or both sides with an adhesive material such as oil or varnish and a paint with an additional 0.01 to 10,000 μm, and their application products, including wood and Application products that can be manufactured by coating adhesives and paints prepared according to the present invention to those easily prone to fire can be variously applied to various fields. Applicable application products include products featuring furniture, curtains, verticals, wallpaper, flooring, blinds, and clothing, and the product structure is a base material layer (or printing layer, embossing layer) 10 and plastic foam 30 ( Depending on the product, it may be a sheet other than plastic foam. Papers, plastics, etc. belong to this, and these are named sheets.) Between, for example, the compositions of Examples 1, 4, 5, 7, 8, 9, and 11 A flame retardant layer 20 made of is formed, an aluminum foil layer 40 is formed at the bottom of the plastic foam 30 , and an adhesive layer 50 and a release paper 60 are formed on the lower surface thereof. The flame retardant layer 20 suppresses or delays ignition in case of fire. The structure for this is shown in FIG. 33 and not shown in the figure, but in the case of a product constructed in a different environment, the base material layer 10 / flame retardant layer 20 / plastic foam 30 / nonwoven fabric such as polyester long fiber nonwoven fabric It is composed of plastic/plastic foam (30)/aluminum layer (40)/adhesive layer (50)/release paper (60) to form a structure that prevents distortion of the product, or if the installer directly uses an adhesive, aluminum foil Without the layer 40 and the adhesive layer 50, the release paper 60 to the composition of the present invention or the above-listed adhesive (coating) materials that are not included can be prepared and dried after coating.

In Example 13, only one side of the plastic foam 30 is flame-retardant, but FIG. 34 is a case in which the plastic foam 30 is manufactured by forming the flame-retardant layer 20 on both sides of the plastic foam 30, and the plastic foam 30 is In the case of the constituted product, when both surfaces of the plastic foam 30 are flame-retardant, the flame-retardant effect is further improved. Although schematically illustrated in the present invention, a person skilled in the art may additionally consist of a plurality or a plurality of layers or may be manufactured without a constituent layer. For example, when wallpaper is installed on the plastic foam 30 , it may be manufactured as shown in FIG. 35 without the base material layer 10 . Here, the coating layer was made to exist with the adhesive (coating) material described in Example 13, except for the case where the upper release paper part was attached. 36 and 37, when manufactured in the same configuration as the actual wallpaper or paper wallpaper, not foam, it has electromagnetic wave absorption or electromagnetic wave blocking, antistatic, antibacterial/mildew, flame retardant abnormality, antifreeze, anticorrosion performance, and the like.

In the case of the flame retardant layer, it is also possible to remove the attached dust or to shield the electromagnetic wave by the antistatic function. It can be said that the electrical properties are improved according to the additive material and the blending amount of the composition. Taking carbon black as an additive, for example, when the mixing ratio is 3 wt% of carbon black to 20 wt% of solid content, the surface resistance is 10 ⁶ to 10 ⁸ Ω/□, and when the mixture is 6 wt%, the surface resistance is 10 ⁵ to 10 ⁶ Ω/ When □, 10% by weight, the surface resistance is 10 ⁴ ∼ 10 ⁵ Ω/□, and the conductive properties are improved, and the ability to exhibit electromagnetic wave blocking properties from antistatic properties is also improved. And the difference in additive material is that when PEDOT, a conductive polymer, is added instead of carbon black, the surface resistance is 10 ⁷ ∼ 10 ⁸ Ω/□, antistatic performance, and when Ag powder is added, 10 ^-5 ∼10 ^-1 With Ω-cm, electromagnetic shielding performance can also be exhibited, and it can also be applied as an electrode material.

With the composition product of the present invention according to Examples 1, 4, 5, 7, 8, 9, 10, 11, to form one layer on the back side of the silk wallpaper or to permeate into the stratum of the back side (rear side or back side) of the silk wallpaper It is a product manufactured with a structure that has been turned off, and has a product structure characterized by complex selection and selection of two or more functions among electromagnetic wave absorption, electromagnetic wave blocking, antistatic, antibacterial/mildew, flame retardant abnormality, and corrosion prevention performance. In particular, it imparts flame retardancy to the silk wallpaper of As a painting method that maximizes the flame-retardant properties by applying a composition product to the back side, allowing it to permeate the wallpaper for 15 to 100,000 sec, and installing it on the wall, it features a product manufacturing method, structure, and construction method that can be applied to product groups such as laminated wallpaper. do.

One of the additive materials of the present invention - mentioned in Example 1 - was prepared by adding chloride and salt, and then flame retardant performance according to surface resistance and thickness (after applying the composition on paper wallpaper, respectively, ignition was tested. ) was tested. At this time, water-based EVA was used as the adhesive material, and the surface resistance of the water-based EVA adhesive prepared by mixing 7.90% by weight and 12.18% by weight among various mixing ratios (measurement conditions: 19.5℃, humidity 45%) was KS M 3015- According to 1997 or ASTM D257 evaluation method, it was 10 ⁵ to 10 ⁸ Ω/□, and the half-life according to KS K 0555-2000, method A was 0.5 to 0.7 sec. Coat paper wallpaper with a paint brush with a width of 50 mm, and surface resistance and flame retardancy by ratio (content) Table 12 shows the results of measurement and evaluation of coating thickness or not)

division chloride ratio(%) 0% 7.89 7.90 9.81 9.82 12.18 13.89 13.92 16.21 salt ratio(%) 0% 2.94 6.22 Sheet resistance (width 50 mm paint brush) 2 coats 10 ¹¹ 10 ⁸ 10 ⁷ 10 ⁷ 10 ⁷ 10 ⁶ 10 ⁶ 10 ⁶ 10 ⁵ 1 coat 10 ¹² 10 ⁹ 10 ⁸ 10 ⁷ 10 ⁸ flame retardant N.G. N.G~△ O.K. O.K. △ O.K. O.K. O.K. O.K. Coating thickness (㎛) 2 coats (including base 229mm) 341 440 829 375 391 349 403 485 one side coating 56 150 300 73 81 60 87 129

From the above results, when the chloride content is 8% by weight or more, it is possible to secure within the surface resistance pursued in the present invention, and the higher the chloride ratio, the more flame retardant properties can be realized even when the coating thickness is thin. It can be seen that the required surface resistance and flame retardant effect can be realized by increasing the coating thickness. In this case, instead of the adhesive EVA material, Acrylic, Epoxy, Polyvinyl Alcohol, Polyvinyl Acetate, Silicone, Polyurethane, Ethylenevinyl Acetate, Polyvinyl Chloride, Vinyl Acetate Acrylic Copolymer, Acrylic Copolymer. Gum Rosin, 2-Ethyl Hexyl Acrylate Monomer, 2-Ethylhexyl 2-Propenoate, 2-Hexyl. Resin, Solution or Acid, Primer, Emulsion, Monomer, Copolymer of 2-EHAM, 2-Ethyl Hexyl Acryl Acid, Butyl Acrylate Monomer, N-Butyl Ester, Butyl 2-Propenoic Chloroprene Rubber, Acid, n-Butylacrylate, Vinyl Acetate Monomer , Resorcinol, α-Olefin, Isocyanate, and Phenolic substances were used alone or in a mixture of two or more substances to obtain the same results.

Another object of the present invention is to prepare a heat-resistant polymer material through molecular structure change, a reactive flame-retardant material in which a flame-retardant component is chemically combined in a polymer structure, and an addition type in which a flame-retardant material is physically added to a polymer material. There are methods to improve heat resistance by coating or painting flame retardant materials or other flame retardant materials, or by changing product design. Therefore, flame-retardant materials can generally be divided into reactive and additive types, and in reactive flame-retardant materials, the flame retardant component is chemically bonded to the polymer material to maintain the flame-retardant effect, and the additive-type flame-retardant material is physically dispersed in the polymer material. And if there is some compatibility with the material to be used, it acts as a plasticizer or as a filler. Unlike reactive flame-retardant materials, additive-type flame-retardant materials may bloom on the surface of polymer materials depending on their structure and external conditions, so caution is required in use. In the case of a combination type flame retardant material, it exhibits a flame retardant synergistic or inhibitory effect depending on the combination type. Additive-type flame-retardant materials can be classified into the following 4 types according to their flame-retardant behavior. First, it is a substance that can block the emission of incombustible gas or combustible gas and oxygen, and is related to the decomposition and ignition behavior of macro scale. For example, there are a halogenated compound that suppresses the generation of highly reactive radicals in a gas phase reaction and a phosphorus compound that inhibits a decomposition reaction through char formation in a solid phase reaction. Second, as a method of reducing the heat of combustion, there is a phosphorus-based compound that is related to the macro-scale combustion stage and inhibits the decomposition reaction through the formation of charcoal. Third, it is a method of maintaining the physical shape of a material through oxygen and heat blocking, which is related to macro-scale decomposition, and there are fillers, glass fiber reinforcement, and phosphorus-based compounds. Fourth, as a method of increasing the specific heat or thermal conductivity of a substance, there is a hydrate as a method related to the macro-scale heating process. Therefore, the flame retardant principle; ① Increase the degree of crosslinking of the polymer and increase the ignition point by adding a filler, ② Al(OH) ₃ or Mg(OH) ₂ blocks combustion by generating water during combustion, ③ Phosphorus or boron compound char on the polymer surface during combustion It blocks oxygen by coating it with a film, and ④ Halogen compounds cool the combustion process by taking the heat of vaporization during combustion. In case of ①, the physical strength is lowered, in case of ②, aluminum hydroxide is used in large amounts and has the disadvantage of being decomposed at a temperature below 200℃, and in case of ③ and ④, harmful substances such as dioxins are generated. As flame retardant materials that can overcome the regulated boron and halogen-based materials, chloride-based materials, salt and seawater, and white carbon as additional flame-retardant materials were also possible. In the case of products requiring a black color, if conductive carbon is additionally mixed, better results can be obtained in terms of antistatic and electromagnetic wave blocking. ⓐ Carbon: Using the theory that phosphorus-based flame-retardant material acts as a flame-retardant material by blocking oxygen and generating charcoal during combustion, it can be flame-retardant if the polymer material is coated with charcoal (carbon, charcoal), and carbon can also act as a deodorant. can The problem is that black carbon can be used in fields limited to color problems, but there is also white carbon, so it can be used in various areas. ⓑ If the heat transfer rate is good, if the local heat is dispersed quickly, the flame retardancy will be good. First, since the flame retardant synergistic effect linked with ⓐ, thermal conductivity and electrical conductivity are in a proportional relationship. ⓒ Na-based or Ca-based materials, which are analyzed by photoelectron spectroscopy at the Kyushu Institute of Technology to check the calcium oxide film, which cannot be observed with an electron microscope, and ignite as such a film has a protective action to block oxygen. The mechanism by which the temperature rises was revealed. And ⓓ NaCl is not deliquescent, but salts containing Mg ions or Ca ions are deliquescent. Although this is the reason why the antistatic performance of polymers made from seawater is better. Although it is a kind of chloride-based material and chloride-based material such as CaCl ₂ or MgCl ₂ , it is a deliquescent electrolyte by abundant minerals such as sea salt.

Comparative evaluation results for the compositions, flame retardant and flame retardant properties according to Examples 1, 2, 3, 4, 5, 7, 8, 9, and 11 are shown in Table 13, and the test conditions are sample size 5 mm, heat source methyl alcohol (using alcohol lamp), flame length 5cm and flame contact length 1cm Through the above results, for comparative evaluation in the present invention, the result of conducting a flame retardancy test on a specimen prepared using other flame-retardant materials and the additive material of the present invention; Nitrogen-phosphorus flame retardant materials can achieve UL standard V-0 flame retardancy when the flame retardant content is 40% or more compared to the total content. Compared to the material, the amount of flame retardant material used was large. Halogen-based flame retardant material exhibited V-0 grade flame retardancy with only 20% content, and showed the best flame retardancy. In addition, there was no dripping phenomenon in flame-retardant specimens prepared using nitrogen-phosphorus and inorganic flame-retardant materials when heated continuously for 2 minutes without checking the turn-off time, but dripping occurred when halogen-based flame-retardant materials were used. As a result of comparative evaluation of the adhesive material prepared by adding the composition additive of the present invention and other flame-retardant materials, it can be seen that the product of the present invention is equal to or superior to other flame-retardant specimens. Among the additives used to exhibit flame retardancy, which is another function of the present invention, the possibility of exhibiting a function similar to that of the previous flame-retardant material was revealed through physical and chemical consideration, and an additional environmental risk test was conducted. 2271 (flame retardant class 2~3 standards) and export UL-94 (V-0, V-1 standards) standard specimens (220mm × construction thickness (max. 15mm)) were manufactured to evaluate environmental hazards. did The gas hazard test, which is an objective evaluation index for environmental risk, was performed with the adhesive and coating material of the present invention.

As shown in Table 14, the weight loss of the specimen after the test was 2.5 g and 2.3 g, respectively, and the mouse action stop time was also measured as a value higher than 9 sec, which is the judgment standard, so the adhesive and coating material of the present invention has excellent flame retardancy was able to confirm

Item Specimen Specification T1(sec) T2(sec) Judgment Nitrogen-Phosphorus Flame Retardant

50 5mm×5mm One One V-0 40 One One 30 One 1-2 Inorganic flame retardant

60 One One 50 One 1-2 40 One 5 Halogen-based flame retardant

40 One One 30 One One 20 One One Addition of flame retardant material


30 One One 20 One One 10 One One 8 One 1-2 Addition of 2 kinds of chloride system

30 One One 20 One One 10 One One 8 One 1-2

Test name Gas toxicity test Criteria test specimen number One 2 -
Size (mm) 220 220 Thickness (mm) 4.0 4.0 Weight (g) 371.4 368.2 Weight loss after test (g) 2.0 1.8 mouse
(mouse) pedigree sex ICR, female ICR, female average weight 20.4 20.4 test box temperature
(℃) Early 31.3 31.2 best 32.1 32.0 average mouse stop time 11min 51sec 10min 54sec Standard Deviation 0min 7sec 0min 4sec mouse stop time 9min 44sec 10min 50sec 9min or more Judgment fitness fitness -

[Surface test]◎ Related standards: KS F 2271.

◎ Test method: After heating a 220 mm wide and 220 mm long specimen with a sub-heat source, it is continuously heated for 6 min by a main and sub-heat source, and the related weight loss, temperature time area and smoke coefficient per unit area, residual flame, melting, cracking, Measure the strain.

◎ Judgment Criteria:

― Weight loss: less

― Temperature time area: Do not exceed the standard temperature curve within 3 min after the start of the test.

― Smoke coefficient per unit area: 350 or less.

― Afterflame time: less than 30 sec.

― No melting, cracking (less than 1/10 of the thickness) or deformation.

[Gas toxicity test]

◎ Related standards: KS F 2271.

◎ Test method: Measure the average behavioral stop time of 8 female ICR (Institute of Cancer Research) mice in smoke generated by heating a 220 mm wide and 220 mm long specimen.

◎ Judgment Criteria: Average action stop time is 9min or more.

Examples 1, 2, 3, 4, 5, 7, 8, 9, 11, solid content 33% by weight, adhesive material 60% by weight, anti-condensation and humidity control material 3% by weight, solid content 47-100 As a result of measuring the surface resistance using a composition containing 5 to 20% by weight of chloride, 25 to 100% by weight of solid content, 3 to 20% by weight of salt, and 5 to 30% by weight of additional water, 10 ⁶ to 10 at 40%RH It was confirmed that there was an antistatic property at ⁸ Ω/□. Next, the results of flame retardancy measurement through D Test Research Institute are as follows.

KS M 2150 (liquefied petroleum gas) is used for the fuel used in the flame retardant test of the present invention, and the length of the burner flame is 45 mm for the micro burner and 65 mm for the McKell burner, and the tip of the flame is the lower end of the center of the specimen. The burner was installed so as to be in contact with the Specimens are cut into pieces of 35 cm in width and 25 cm in length, which are arbitrarily cut from the object to be measured over 2 m 2 , and cut three at a time. The specimen is dried for 24 hours in a constant temperature dryer at 50 ° C. After being put in a desiccator with silica gel for 2 hours, It was carried out at a temperature of 16°C and a humidity of 34%RH. After coating 120 μm of the composition adhesive and coating material (EVA base) prepared according to the present invention on the coating substrate plywood, the flame-retardant performance test as described above was performed on three specimens, respectively. As a result, the carbonization area is for specimen ① 28.4 cm ² , specimen ② 27.6 cm ² , specimen ③ 31.3 cm ² , and the carbonization length is for specimen ① 7.1 cm, specimen ② 6.7 cm, specimen ③ 8.1 cm, afterflame time is 0 sec for specimen ① , specimen② 0 sec, specimen ③ 0 sec, and remaining time are indicated for specimen ① 0 sec, specimen ② 0 sec, and specimen ③ 0 sec. In addition, after coating 120 μm of the composition adhesive and coating material (PVA base) prepared according to the present invention on the plywood as a coating base, the flame-retardant performance test as described above was performed on three specimens, respectively. As a result, the carbonization area is for specimen ① 38.7cm ² , specimen ② 40.3cm ² 2 , specimen ③ 30.8cm ² , and the carbonization length is for specimen ① 8.9cm, specimen ② 9.5cm, specimen ③ 7.5cm, and afterflame time is specimen ① 0 sec, test object② 0 sec, test object③ 0 sec, and remaining time are indicated for test object① 0 sec, test object② 0 sec, and test object③ 0 sec. At this time, the carbonization length was set as the maximum length in the carbonized part of the specimen, and the heating was performed for 2 min for each specimen. It was found that the adhesive and coating composition had good flame retardant properties.

[Flame proof test]

◎ Carbonized area: The area carbonized by the flame.

◎ Carbonization Length: Length carbonized by flame.

◎ After-flame time: The time from when the flame of the burner is removed until the state of burning with the flame stops.

◎ Remaining time: The time from when the flame of the burner is removed until the state of combustion ceases without raising the flame (excluding the time during which after-flame is generated).

◎ Judgment criteria: The flame retardant performance of thick fabric corresponding to the specimen (coated on paper wallpaper) of the present invention is based on after-flame time within 5 sec, after-life time within 20 sec, carbonization area within 40 cm2, and carbonization length within 20 cm.

38 is a photograph taken of a specimen after a flame test for non-coated and coated paper wallpaper with the composition of the present invention. In the case of non-coated laminated wallpaper, the specimen was completely burned as soon as a flame was applied (left side of the photo). turned off within ∼2 sec. Therefore, it was found that the composition of the present invention has very excellent flame retardancy or flame retardancy.

Therefore, as the adhesive and coating composition using the chloride of the present invention and application products using the same, such as an adhesive for painting, a paint for painting (coating agent), etc. , film sheet, laminated wallpaper and silk wallpaper that require flame retardancy and anti-mildness properties, flooring materials such as PVC flooring or flooring, and clothing are manufactured by coating the front or both sides. A coating layer made of chloride and salts (sun salt, rock salt, refined salt, etc.), bittern, conductive carbon black, metal material, ceramic (the material mentioned in Example 1), etc. used in the present invention is a method of preventing direct exposure to the outside. , As previously described, on one and both sides of the coating substrate (product), first, the adhesion and coating materials using the chloride and salts, bittern water, conductive carbon black, metal materials, ceramics, etc. mentioned in the present invention are applied 1 to 10 times to 0.01 ~10,000 μm coating, one or both sides of the coating layer are coated with 0.01 to 10,000 μm of water-based as well as oil-based, varnish, and adhesive paints in one of the adhesive materials listed in the present invention or one of the adhesives used in the composition Treatment to prevent direct exposure of the primary coating layer pursued in the present invention to the outside, or, in particular, furniture, curtains, It was confirmed in the present invention that it can be used without restrictions in various fields by additionally coating water-based or oil-based adhesives, varnishes, and adhesive paints when applied to vertical areas. Above all, it is another feature of the present invention that it is applied to products such as upholstered furniture that are subject to the Fire Protection Act and becomes a product that exhibits flame retardancy (flame retardancy) among various functions.

Condensation phenomenon; Although the general paint shows dew formation as shown in FIG. 39, FIG. 40 shows that the present invention does not show dew formation on the surface due to hygroscopicity due to the added ceramic and chloride. And through this function, one of the objects of another invention of the present invention is a flame retardant (flame retardant) synergistic action and method as follows. It appears that the composition of the present invention has excellent flame retardancy properties than the composition without additives of the present invention.

According to Korean Patent Application No. 10-2006-0019024, when exposed to a high humidity environment due to its high water absorption, it may have adverse effects such as contamination of the coated surface due to the generation of humidity on the coated surface. As a way to overcome this, the present invention has provided the following solution. When the additive material of the present invention is used alone or in combination among the composition additives, the additive material specified in Example 1 is used as the additive material of the present invention in the adhesive material and paint (or paint) with a solid content of 35% by weight in the weight ratio of the total composition. The ratio (content) is preferably at least one type and within 30%, and the above problems no longer occur, thereby exhibiting the function of preventing dew condensation while exhibiting the function of more than flame retardant. In order to realize the purpose of preventing condensation above, even when calcium chloride in chloride is used alone instead of ceramics such as siliceous porous material, lightweight foamed ceramic, and clay as a composition participating material, in terms of using an aqueous solution of calcium chloride that is theoretically soluble as much as possible. When the composition is made so as not to exceed 30% in the weight ratio of the composition, the above-described problems do not occur any more, so that the antistatic function can be additionally exhibited.

However, considering the wet environment in case of rain due to climatic change, the content of calcium chloride (in general commercially available anhydrous CaCl ₂ in anhydrous CaCl ₂ 6H ₂ O) is 25 wt. % or less is more preferable. In the case of use with salt, in the above composition, the ratio of calcium chloride to salt (sea salt or refined salt, sawmill salt, processed salt, rock salt, industrial slat material, etc.) is 1: 0.5 to 10. It becomes possible to further promote antibacterial/mildew function, partial antistatic function, antistatic and flame retardant function by calcium chloride, freeze prevention, and anti-condensation prevention.

Conductive carbon black compensated for the shortcomings of color through the use of conductive polymers such as PEDOT, white carbon, chloride, salt, and bittern. By using conductive carbon black at the same addition ratio, it was possible to double the electromagnetic wave shielding (electromagnetic wave reduction) beyond the flame retardant properties through char formation and the antistatic performance by conductivity. In particular, the bittern used in the present invention is also called high salt old water. It can be obtained as a by-product when producing salt, and can be obtained by using the deliquescent action when storing salt. The composition consists of 15-19% magnesium chloride, 6-9% magnesium sulfate, 2-4% potassium chloride, 2-6% sodium chloride, 0.2-0.4% magnesium bromide, and the like. It has been used as a coagulant when making tofu since ancient times, but research on bittern has been conducted since World War I, and now it is used as an important resource for inorganic pharmaceuticals. The bittern water treatment industry is a sector such as potassium industry and potassium fertilizer manufacturing industry, and there is also research to manufacture magnesium hydroxide or metallic magnesium using bittern water. The bittern is used directly for tofu production and magnesia cement, and in addition, it has been used in small amounts for rice cleaning, etc., but has been used since ancient times. A material containing 3 to 35% magnesium, 0.1 to 7% calcium chloride, 2 to 27% sodium chloride, 0.01 to 1% magnesium bromide, etc. was used, and 20% by weight of a polymer, which is one of the mixing ratios of Example 1, 50 wt% adhesive material The degree of attenuation of the electric field before and after internal treatment (construction) of the box is measured using an adhesive and coating material containing 50% by weight of weight, 50% by weight of chloride, 25% by weight of solids, 7% by weight of bittern, and 38% by weight of water. measured. It was also confirmed that the measured value of PULSE's E-tester before construction was 136V/m, but after construction, it was 0V/m, and it was also confirmed that the place where the internal construction was performed was going to 0 due to the attenuation of the electric field.

As mentioned in Examples 1, 4, 5, 7, 8, 9, 11, 17, 19, the present invention also relates to an anti-freezing adhesive and coating composition (product), wherein in cold weather, a water-soluble paste, adhesive or paint, etc. The product relates to a composition product and its application products that can be used in all weathers by lowering the freezing point to reduce the adverse effects of freezing during transportation and construction, etc.

In order to realize this, the present invention first secured specific data through the following considerations, solution principles, and tests in order to confirm the principle of lowering a certain point.

As a solid substance that dissolves well in water and can lower the freezing point, there are chloride, nitrate, and ammonium salt. For example, magnesium chloride has less ionized water than calcium chloride, but has the same effect of lowering the freezing point at the same number of moles, so magnesium chloride is more effective than calcium chloride and better than sodium chloride for the same weight. On the other hand, liquid substances, alcohols, glycols, etc. have the same effect. In the case of methyl alcohol, the mass of 1 mole is 32 g, and the freezing point reduction is slightly less than the freezing point reduction mole number of salt 24.25, so the freezing point lowering effect is large. Ethylene glycol is used as an automobile antifreeze, which has a molar mass of 62 and is half that of salt. And freezing point depression is the freezing point depression constant In the case of water, the freezing point depression constant per mole is 1.86 °C/m. Using the principle of lowering the freezing point as described above, it became the motivation (motiv) of the present invention. As shown in FIG. 41, the freezing temperature of pure ethylene glycol is -12 °C, but the freezing temperature (freezing point) of a liquid in which ethylene glycol and water are mixed depends on the mixing ratio. When water is mixed, the hydrogen bonding of ethylene glycol is disrupted and the freezing point is lowered. The freezing point of a liquid in which the amount of ethylene glycol is 70% and water 30% is reduced to about -50℃. Antifreeze with a 1:1 ratio of water and ethylene glycol is about -35 to -40℃, so it is a good example of an antifreeze that can be used in the winter environment of Korea. (Source: Naver Cast, Today's Science, Chemistry Walk , Antifreeze, Prof. Yeo-Hyung Yeo) Also, the principle of lowering the freezing point is that ordinary water starts to freeze from 0℃, but the composition of the present invention, contrary to caustic soda, the higher the content, the lower the freezing point occurs, so it freezes even at a temperature lower than 0℃. The theoretical principle for this is shown in FIG. 42 with reference to the Naver Knowledge Window, rsy7979. If the plane is divided into three places with a red line, the leftmost part is solid state, the upper middle part is liquid state, and the lower right part is gaseous state. And the red line between the solid and liquid states is the solidification point = melting point line, and the solidification point = melting point line of the solution rather than water moves in parallel to the left, that is, since the x-axis is the axis representing temperature, moving in parallel to the left means that the freezing point = melting point. This means that the temperature is lowered. Therefore, the freezing point of the composition of the present invention is lower than that of ordinary water, and there is an advantage in product storage, distribution, and construction in cold weather due to the prevention of freezing.

Products containing water such as water-soluble adhesives, paints, and glue have a problem of freezing (freezing phenomenon) in sub-zero weather. In addition, the increase in material cost compared to summer due to the use of less water than summer during winter construction (painting), and the occurrence of freezing (freezing) in winter when the wall of the apartment veranda with a lower temperature than the apartment room or living room is painted with water-soluble paint In most cases, the builder is unable to construct. In addition, special attention (management) is required as there are cases in which adhesiveness is lowered or the product must be discarded due to agglomeration/separation due to freezing (freezing) during winter movement (product movement stage for distribution or construction) and warehouse storage. In the case of products manufactured with water in circulation, when thawed after freezing, water and adhesive components are separated, resulting in agglomeration or significantly lower viscosity. In order to solve these problems and to prevent the freezing phenomenon by lowering the freezing point, the results of the freezing test are as follows.

As a major part of the present invention, current water-soluble adhesive and coating products always had a problem due to freezing in sub-zero weather in winter. The freezing phenomenon was confirmed as shown, and a comparative freezing (freezing) evaluation experiment was conducted with the present invention. As a result of evaluating whether the products currently distributed on the market and the dobae grass manufactured according to the present invention (the grass manufactured by the S company dobae grass production line) were frozen together in the freezer (Fig. 39 upper part), the distribution products containing water were After about -11°C for 2 hours, freezing began at the time of the first evaluation, and after leaving the freezer for 24 hours, it became a hard lump of ice, but the product of the present invention (see FIG. 43) did not freeze at -11.8 to -15.6°C for 24 hours, and subsequent evaluation At -16.5℃, 12hr evaluation, only the surface showed a slight degree of freezing, but when it was thawed at 16℃ for 4hr (I left it in the indoor atmosphere), the product of the present invention was restored to its original state, --19.3℃ 50hr In the additional freezing test, the product of the present invention completely turned into a lump of ice, but upon thawing, it maintained its original state and adhesive strength. -, When products distributed in the market (current products sold) are completely frozen and thawed, agglomeration occurs due to the separation of the water and flour components, which are the solutions used in manufacturing, and the inherent adhesive function of adhesives such as starch is significantly reduced. phenomenon occurred. Then, for the adhesion test, glue was applied to the paper wallpaper and dried, followed by peeling by hand. The products distributed easily fell off, and even some wallpapers that were glued on by themselves fell off, but the adhesive strength of the present invention did not change, and there was no problem with the adhesive strength (adhesion) enough that the paper wallpaper itself was torn when peeled (when), so adhesives and paints The intrinsic properties were maintained. The experimental results for this will be described in more detail in the following examples.

In addition to the starch coating paste, EVA composed of water-based EVA paint (experiment conducted with N company water-based paint) and the same proportions and materials as those of Examples 1, 2, 3, 4, 5, 7, 8, 9, 11 A freeze test was carried out with a product made with a paint invention composition, and it was completely frozen in the freezer and then thawed, and if you look at the condition, the appearance color of the EVA paint in circulation has changed. The composition EVA paint of the present invention did not change the appearance color before and after freezing. In the painting experiment, the distribution paint that was frozen and then thawed was not applied, but there was no problem in the present invention. 44 shows the state before and after thawing, looking at the principle and test results; The paint has an effect of lowering the freezing point of paints or adhesives containing additives according to the present invention compared to paints that do not contain any additives such as the present invention among water-soluble paints (including adhesives currently on sale). Previous water-soluble paints and adhesives start to freeze after 0°C, but according to the present invention, when one type of additive is mixed, that is, 3% by weight, about -2 to -3°C, 6% by weight -3 to 4°C, 10 wt% -7~-8℃, 15wt% -10~-12℃, 20wt% -13~-15℃, 29wt% -20~-22℃, solid content in the same content ratio when two types are mixed It was confirmed that the adhesive prepared by mixing two types of additive materials with a difference of 2:1 was lower than the freezing point temperature of the above ratio by -2 to -7°C. According to the present invention, even if the paint or adhesive containing the additive material is frozen, the adhesive strength is restored to its original state after thawing, so there is no problem in adhesive strength. was separated like an island, resulting in almost loss of coating power and adhesion. Therefore, when the materials of the present invention are mixed, the freezing point is lowered and the adhesive strength is restored when thawed after freezing. However, it is one of the very important features that it is a product that is easy to install regardless of the season, which was first invented by solving the fundamental problem of the previous adhesive with the antifreeze effect as described above by the present invention.

As in Examples 1, 4, 5, 7, 8, 9, 11, 17, and 19, each of a chloride and a salt was dissolved in H ₂ O to form a solution - Chloride was a solution with a solid content of 20 to 50% by weight, and salt had a solid content of 20 -33% by weight solution - Otherwise, in the case of preparing dobae grass by putting it in a mixing container for preparing dobae grass in a powder state, water was first added, CaCl ₂ powder, salt powder was added and stirred to dissolve, and then starch was added. Preferably, CaCl ₂ is first added and dissolved, and then salt is added and dissolved. This is because if you add salt to a chloride solution in a heated state using the heat generated when CaCl ₂ is melted and dissolve it, the melting time will be shorter and it will dissolve better. It was thought to be advantageous for The manufacturing method was prepared in the same manner as in Example 1.

The same physical properties and the same performance were realized even when the dobae grass of the present invention was prepared by adding salt and CaCl ₂ powder in the same formulation as the method of making the dobae grass. That is, first, H ₂ O (refined pure water is most advantageous, but usually groundwater, tap water), salt, CaCl ₂ , and starch are added to the mixing container in this order, and among the manufacturing conditions of Example 1, 30-350° C. 1-100 min, or to prepare a paper grass under 1 to 10,000 rpm manufacturing conditions; First, salt, CaCl ₂ powder, H ₂ O are put and dissolved, and then starch is added to prepare it. The solubility, dispersibility, and miscibility of the additive material of the present invention are very excellent, making it easy to mass-produce and easy to manufacture in various ways. Being possible is yet another of the best features of the present invention.

In addition, it is preferable to boil water in advance for sterilization of bacteria that may be included in the water, and then use it. At this time, the mixing conditions are 200-600 kg _of H ₂ O with CaCl ₂ powder (Australian, Vietnamese, South American, North American, European, African, Among Asian products, from Japan, Vietnam, India, the Philippines, etc. In particular, one or a mixture of one or two or more of deicing agents, edible, low corrosive, reagent grade, and dehumidifying, such as domestic Chinese products, 15 to 100 kg, salt (in the present invention) The salt used is sea salt or rock salt, and one or more of the low corrosive properties, such as deicing agent, edible, playground/tennis, are mixed, and among Australian, Vietnamese, South American, North American, European, African, and Asian Made in Japan, Vietnam, India, Philippines, etc. In particular, one or a mixture of one or more of deicing agents, edible, low corrosive, and dehumidifying agents such as domestic Chinese products, or products made in Asia such as domestic, Chinese or Vietnamese products are used. 5 to 100 kg, starch (1 or 2 or more of grades 1, 2, and 3 were mixed and used.) 20 to 160 kg were added, 1 to 100 min at 30 to 350 ° C, 1 to 10,000 rpm, It is one of the characteristics of the present invention to prepare a porcelain grass while stirring under 0.5-5 atm, but mainly under atmospheric pressure.

Examples 4, 5, 7, 9, 11, 17, 19, 21 for further starch miscibility in the prepared paper grass, an acid with a pH < 4 or less at a solid content of 1 to 100% by weight, as mentioned in Example 1 One anti-rotting agent was prepared by adding 0 to 5% by weight, respectively, based on 100% by weight of the total composition. Preferably, 0 to 5% by weight of strong acid in 90 to 99.999% by weight of the prepared paper paste, 3-lodo-2 propynl butyl carbamate as the main ingredient (product name: MX-3 Advanced Plus, manufacturer: CONNELL) FAMILY INC.), C ₁₁ H ₁₉ NOS (TK-800), UNICOOL-K14 (manufacturer: UCC), NP-40; By adding 0 to 5% by weight alone or in a mixture of two or more, the anti-mildew effect was maximized. With this composition, the shelf life can be maintained for more than one year. In this case, the preservation and storage properties can be maintained for more than 1 year mainly in summer and long-term storage composition. In this case, it was prepared by mixing in the case of pre-production mainly for summer and long-term storage, but even without mixing the above substances, compared to commercially available paper plants - although there may be differences depending on the season - the period is 2 to 50 times without changing the physical properties It is one of the most excellent features of the present invention that long-term storage properties are maintained.

And when the prepared composition is stored/distributed/marketed in an insulating box such as Styrofoam or the composition in a frozen state, at least twice or more than the above period, in particular, the frozen composition maintains a semi-permanent storage period. This is compared to the composition of the present invention that loses adhesiveness due to the separation of the solute and the solvent due to the separation of the solute and solvent when the composition of the present invention is mostly water-soluble adhesive or when the paper is frozen, in the present invention, the composition is restored to its original state when thawed and the adhesive force is maintained as it is. By - see Example 20 above - As an adhesive composition, it is one of the greatest inventions of the present invention that has not been implemented in any composition so far.

One of the compositions of the present invention according to Examples 1, 4, 5, 7, 8, 9, 11, 17, 19, 21, 22, starch strong flour and wheat flour or corn, potato 15-35 wt%, water 15-85 20 to 49% by weight of solids CaCl 2 3 to 35% by weight CaCl ₂ 3 to 35% by weight, 10 to 35% by weight of solids 1 to 30% by weight of salt, and 0 to 5% by weight of other strong acids or dispersants 1-350° C. , 1 to 600 min. 1 to 20,000 rpm 0.5 to 5 atm A liquid coating composition prepared while stirring, and its manufacturing method, and the liquid composition is diluted 1-1,000 times and then spray-dried and then subdivided, or completely dried and then pulverized to form a powder paste, this powder When the paste is added with water and stirred again, it becomes a liquid coating paste, and the coating work becomes possible. The powdered grass produced in this way increases the manufacturing cost due to the additional process for manufacturing the powdered grass, but it can be stored for a long time due to the powder state and has the effect of reducing distribution costs due to weight loss.

Unlike the sol-gel (or sol-powder) manufacturing method of the above embodiment, the sol-powder manufacturing method strengthens adhesion according to the type of additive material and the mixing ratio of the additive material, freeze prevention, antibacterial/mildew, electromagnetic wave absorption, electromagnetic wave blocking, charging Powdered paste that exhibits the properties of prevention, flame retardancy, corrosion prevention, and decay prevention in a complex, selective and selective manner is manufactured, so that it has excellent long-term storage properties.

45 is a photograph taken after bonding a wooden floor tile (flooring material) using the composition adhesive prepared in Examples 1, 2, and 3, and is constructed and dried to a level as good as the adhesive for conductive antistatic tile of Example 2; No peeling occurred after

In this example, the composition of the products prepared according to Examples 1, 4, 5, 7, 8, 9, 11, 17, 19, 21, 22, and 23, and the commercially purchased preservative S company containing the Figure 46 shows the results of artificially putting a fungal strain into the product (injection) and performing a culture experiment for one week. As shown in the figure, the spread of mold did not occur in the paper grass prepared according to the composition of the present invention, and the spread of fungus was severe in the commercial paper grass containing preservatives, etc. Therefore, it was found that the paper grass containing the functional composition material in the present invention had an excellent (good) anti-mild effect than the paper grass containing preservatives as it prevented the spread of mold.

As mentioned in Examples 12, 16, and 17, the properties regarding flame retardancy, flame retardancy, and non-flammability are as follows. Flame retardancy is a property that prevents flame combustion from occurring when ignited through chemical or physical treatment of combustible materials, flame retardancy is a property that makes the combustion rate relatively slower than combustible materials, and nonflammability is a property that does not burn even at high temperatures like metal or inorganic materials say that with In other words, flame-retardant burns when exposed to a flame, but does not burn by igniting itself when the flame is removed, and does not spread or expand fire beyond the standard carbonized area by receiving the flame directly. It was made to have (self-turning off). Although flame retardant has a flame retardant effect under weak combustion conditions, it can be said that there is no significant difference from general combustible materials under high temperature or strong combustion conditions. (Source: Doosan Encyclopedia) When classified into flame retardant grades, flame retardant grade 1 is a non-combustible material that does not burn, flame retardant grade 2 is a semi-incombustible material that does not burn easily, and flame retardant grade 3 is called a flame retardant material. Materials that are difficult to burn with Therefore, flame-retardant material refers to a material that does not burn well even when ignited, and it is a material that burns in a flame but does not burn well. There should be no damage. When a flame is ignited, some toxic gas is generated, and there is no burning phenomenon. Flame-retardant board, flame-retardant fiber board, and flame-retardant plastic board are among the flame-retardant materials. According to the Enforcement Decree of the Building Act, it is specified as a 'material with non-combustible performance', and as a result of testing as stipulated by the Korean Industrial Standards Act under the Industrial Standardization Act stipulated by the Ordinance of the Ministry of Construction, In order to evaluate whether it has a flame retardant property corresponding to such a flame retardant class 3, the wallpapering glue and the general wallpapering glue prepared by Examples 1, 4, 7, 8, 9, 11, 17, 19, 21, 22, 23 It was applied on paper and silk wallpaper with a flame test. Figures 47 and 48 show that general wallpaper and silk wallpaper are coated on both sides or one side with the composition of the present invention, and a commercially available wallpapering paste made of water and starch for painting, or a general wallpapering paste containing a fungicide therein ( Because it is not coated with the composition of the present invention, it is described as “not coated”) by capturing a video taken during the flame test and showing it as a photograph. 「The first on the right of the captured photo (paper wallpaper); It was not coated with the paper glue of the present invention, and the second from the right (paper wallpaper); Both sides were coated with the paper paste of the present invention, and the last additional experimental video capture photo (paper wallpaper); Only the back (one side) is applied. And if you look at the captured picture of the same screen, the first on the left (silk wallpaper); Not coated with silk wallpaper, the second from the left (silk wallpaper): only the back side (one side) is applied, and the third from the left (in the captured photo, the center is silk wallpaper) ; It was applied on both sides.” As it was shown in the test, the laminated wallpaper coated with general paper paste had less flame than silk wallpaper, but it burned completely. It burned while in this psalm, and burned and extinguished when the flame was removed from the psalm. As shown in FIGS. 47 and 48, the silk wallpaper applied had the same results as the laminated wallpaper, but the uncoated silk wallpaper burned better than the laminated wallpaper while generating dark smoke. It can be seen that this product needs flame-retardant properties because it is coated on one side (or both sides) of the paper with PVC, a chemical substance, and the silk wallpaper with a printed layer is good for harmful smoke and combustion due to the combustion of PVC. Therefore, the composition product of the present invention is characterized in that it has very excellent flame retardant properties.

Following Example 20, in order to secure the superiority of the present invention by freezing, a more detailed TEST was additionally performed. The results of the freezing test on the dobae grass and the general dobae grass among the compositions of the present invention are shown in the upper part of FIG. 49 . The paper grass of the present invention did not freeze after 24 hours at -11.8 to -15.6°C, but the general paper grass was completely frozen like ice. So, the present invention was further frozen (frozen) by lowering the temperature further at -16.5 ° C for 12 hours, but only the surface was frozen. As such, it was found that the composition according to the composition of the present invention becomes antifreeze like antifreeze that does not freeze well at low temperatures, and therefore, for specific evaluation, the temperature -16 ℃ (fixed), depending on the content of the additive of the present invention, To evaluate the degree of change in the product state depending on the change in freezing time and the time after freezing and thawing, surface resistance and adhesiveness, which are the main items of the present invention, were additionally measured. 11% chloride and 6% salt to total weight No freezing at -16℃ 8hrs after freezing, surface resistance 14.8℃ 36%RH 10 ⁶ Ω/□, 17.2℃ 27%RH 10 ⁶ ∼10 ⁷ Ω/□, 14.7℃ 33 Based on %RH 10 ⁷ Ω/□, it was completely frozen after freezing at -16℃ for 8hrs at 3% salt, only the surface was thawed at 2hrs of thawing, and half melted at 3hrs of thawing, and the surface resistance of this sample was 14.8℃36 %RH 10 ⁸ Ω/□, 17.2℃ 27%RH 10 ⁸ ∼10 ⁹ Ω/□, 14.7℃ 33%RH 10 ⁹ Ω/□; It was completely frozen in 6% salt at -16℃ after 8hrs freezing, half-melted at 2hrs of thawing, and slushed at 3hrs of thawing, and the surface resistance of this sample was 14.8℃ 36%RH 10 ⁸ Ω/□, 17.2℃ 27 %RH 10 ⁸ Ω/□, 14.7℃ 33%RH 10 ⁸ ∼10 ⁹ Ω/□; In 3% chloride and 3% salt, it was completely frozen at -16℃ 8hrs after freezing, half-melted at 2hrs of thawing, and slushed at 3hrs of thawing. The surface resistance of this sample was 14.8℃ 36%RH 10 ⁷ Ω/□, 17.2℃ 27%RH 10 ⁷ ∼10 ⁸ Ω/□, 14.7℃ 33%RH 10 ⁸ Ω/□; After freezing at -16℃ for 8hrs at -16℃ with 6% chloride and 6% salt, it was frozen about 3/4 of the way, slushed at 2hrs of thawing and completely thawed at 3hrs, and the surface resistance of this sample was 14.8℃ 36%RH 10 ⁷ Ω/□, 17.2°C 27%RH 10 ⁷ ∼10 ⁸ Ω/□, 14.7°C 33%RH 10 ⁸ Ω/□; In 6% chloride and 6% salt, it was frozen 4/5 after 8.5 hrs of freezing, slush was slightly more molten at 1 hr of thawing, and completely thawed at 2 hrs of thawing. The surface resistance of this sample was 14.7℃ 33%RH 10 ⁸ Ω/□; In 8% chloride and 3% salt, after freezing at -16℃ for 8.5hrs, it was frozen 9/10, more than half melted in 1hr of thawing, and completely thawed in 2hrs of thawing, and the surface resistance of this sample was 14.7℃ 33%RH 10 ⁷ ∼10 ⁸ Ω/□; In 9% chloride and 3% salt, it was frozen 4/5 after 8.5 hrs freezing at -16℃, slightly more frozen than slush at 1hr of thawing, completely thawed at 2hrs of thawing, and the surface resistance of this sample was 14.7℃ 33% RH 10 ⁷ ∼10 ⁸ Ω/□; After freezing at -16℃ 8.5hrs in 7% chloride and 4% salt, it was frozen 9/10, half-melted at 1hr of thawing, and thawed 9/10 at 2hrs of thawing, and the surface resistance of this sample was 14.7℃ 33% RH 10 ⁸ ∼10 ⁹ Ω/□; In 7% chloride and 5% salt, it was frozen 4/5 after freezing at -16℃ 8.5hrs, slightly more molten than slush at 1hr of thawing, completely thawed at 2hrs of thawing, and the surface resistance of this sample was 14.7℃ 33% RH 10 ⁸ ∼10 ⁸ Ω/□; In 7% chloride and 4% salt, it was frozen 4/5 after 8.5 hours at -16℃, slightly more molten than slush at 1hr of thawing, completely thawed at 2hr of thawing, and the surface resistance of this sample was 14.7℃ 33% RH 10 ⁸ Ω/□; In 6% chloride and 6% salt, it was completely frozen at -16℃ 11hrs after freezing, slushed at 1hr of thawing, completely thawed at 2hrs of thawing, and the surface resistance of this sample was 17.2℃ 27%RH 10 ⁸ Ω/□, 14.7 ℃ 33%RH 10 ⁸ Ω/□; In 5% chloride and 3% salt, it was completely frozen at -16℃ 11hrs after freezing, only the surface was thawed at 1hr of thawing, half melted at 2hrs of thawing, and slushed at 3hrs of thawing, and the surface resistance of this sample was 17.2℃ 27%RH 10 ⁹ Ω/□, 14.7℃ 33%RH 10 ⁸ ∼10 ⁹ Ω/□; -16℃ at 6% chloride, 3% salt Completely frozen after 11hrs freezing, only the surface melts in 1hr of thawing, slush in 2hrs of thawing It was completely thawed at 3hr of thawing, and the surface resistance of this sample was 17.2°C 27%RH 10 ⁸ ∼ 10 ⁹ Ω/□, 14.7°C 33%RH 10 ⁸ Ω/□; In 7% chloride and 3% salt, it was completely frozen at -16℃ 11hrs after freezing, slushed at 1hr thawed, slushed at 2hrs thawed, completely thawed at 3hrs thaw, and the surface resistance of this sample was 17.2℃ 27% RH 10 ⁸ Ω/□, 14.7°C 33%RH 10 ⁸ Ω/□; In the above composition, after complete thawing, there was no problem in the adhesion of those with a surface resistance of 10 ⁹ Ω/□, which is sought in the present invention. However, if the waiting time for construction after freezing is taken into account, more preferably, a composition with a surface resistance of 10 ⁸ Ω/□ is most preferably thawed at 2 hours after thawing. However, it is a feature of the present invention that all TEST preparations can be manufactured as anti-freezing composition products because there is no defect in adhesive strength after thawing.

In another evaluation experiment, the results of evaluating the adhesion strength by thawing each of the completely frozen paper plants, applying the paste to the paper wallpaper, and attaching them to the wall are shown in the lower part of FIG. 49 . First, after thawing, normal (existing) paper plants were separated from water and starch, but the present invention was externally restored to its original state (refer to FIG. 50). After freezing, thawing, coating, and drying 2 hours later, peeling test was performed. The upper layer was coated by diluting the grass by adding water (manufactured paper paste 1: water 1 ratio (weight) added) to the grass, and the lower one was coated with the paper grass manufactured in the manufacturing plant after freezing and thawing. It was painted without adding water. The left side of the continuous photo of Figure 49 is that the general paper grass #1 is frozen and thawed at -11.8 ° C for 24 hours, and the center is the general paper grass #2, frozen at -11.8 ° C for 24 hours and coated after thawing, and the right side is the main According to the invention, it was completely frozen at -19.3℃ for 50hrs and thawed twice, and then coated. As shown in the results, it can be seen that the wallpaper coated on the wall simply fell off due to loss of adhesion in the general paper paste or fell even with a slight peeling force, but it can be seen that the paper paste of the present invention has no problem in adhesion even when frozen like ice. As shown in the peel test, the paper part between the wall and the wallpaper does not fall, but the paper part is torn, indicating that the adhesive strength is good.

These are the test progress results to determine the degree of corrosion to metals such as screws in the wallpapering pools according to the present invention and the two types of mating pools #1 and #2 sold in the general market (see FIG. 51). According to the present invention, purchase the papering grass manufactured in the papering pool manufacturing plant and two different general papering pools, soak the screws, leave them for a long time (at room temperature for 30 days) until the grass is completely dry (30 days at room temperature), and then observe the appearance of the screws is a result The screws placed in the general paper pool are corroded and oxidized, but the level of corrosion of the screws cannot be known in the paper glue factory (C, S, M company mass production line, own production line) line according to the present invention. There was no change in the color of the screw surface.

Powdery paste (Germany H company, Korea E company, K company, Y company, etc. powder paste is used) 100 parts by weight of dried solid chloride 0-100 parts by weight, dried salt (sodium like the material described in Example 1) Edible salt whose main ingredient is Chloride, sea salt and industrial substances used as chemicals, from Europe, Africa, and Asia produced in the East Sea, West Sea, South Sea, Mediterranean Sea Pacific, Atlantic Ocean, Indian Ocean, Northern Sea, Antarctic Sea, Dead Sea, Black Sea, etc. , North America, South America, and Oceania, especially in the United States, Australia (Australia), China, and the Philippines, such as Asia, Europe, and the West Sea, or salt mines on 6 continents such as Africa, America, and Tibet. Alone or mixed of two or more) 1 to 100 parts by weight of the powder alone or in a mixture of two kinds, the mixing ratio of chloride 1: salt is prepared in a ratio of 0.1 to 5, and by the manufacturing method mentioned in Example 1, - The present invention is As the first powdered paste manufacturing method invented - a composition that exhibits antistatic, antibacterial and anti-mildew, flame retardant abnormality, freeze prevention, and humidity control performance in a complex manner, and powdered paste was manufactured through it. The pool is a solid powder and there is no H ₂ O, so it is advantageous for long-term storage and distribution. Examples 1, 4, 5, 7, 8, 9, 11, 17, 19, 21, 22, 23, and 27 have the same characteristics as the liquid porcelain paste of the present invention, but long-term storage by solid standing and distribution by light weight advantageous to

In addition, powdered grass manufactured with grains such as starch, rice, wheat, bran, corn, potato, dextrin, modified starch, glutinous rice, seaweed such as nori, Gelidium amansii LAMOUROUX, grains such as dextrin, modified starch, etc. or German company H , Korea E company, K company, Y company, etc. 1 to 100 parts by weight of powdered grass, 0 to 100 parts by weight of the solid chloride mentioned in Example 1, dried sea salt or rock salt, refined salt powder alone or two or more 01 to 100 Mix by weight, and here 0.0001~7,000㎛ spherical and plate-like, needle-like Zeolite, siliceous porous material, Silica, Perlite, Clay, talc, Aluminum Hydroxide, Kaolin, Magnesium Hydroxide, Calcium Carbonate, Diatomite, Loess, Bentonite, Quartz sand , Gypsum, Lime, cement, Terra alba, Pozzolan, Diatom, Pulp, etc. alone or in an amount of 0-100 parts by weight of two or more were used to prepare a powdery or solid-type plastering finishing material. In contrast, a photograph of surface resistance measurement is shown in FIG. 52, and as shown, the measured value was 10 ⁶ Ω/□, which was a level capable of exhibiting electromagnetic wave blocking or antistatic properties.

It was confirmed in Example 28 that the functional additive material of the present invention was not more corrosive than general coating pastes or adhesives due to its compatibility with the adhesive and chemical action. In order to infer and clarify more clear reasons and principles, a long-term test was conducted. Therefore, in the present invention, Figure 53 is a test for evaluating the degree of corrosion over a long period of time - currently in progress for about 300 days - (a) The evaluation was carried out by putting a clip and a nail in the container on the start date of the experiment. The middle two are by the present invention, and the two containers on the left contain water in order to determine the effect of water because the water-soluble adhesive material contains water. In addition, after one day, the experiment was carried out by inserting clips and nails. As shown in Fig. 53 (b), in the clip placed in water, corrosion was occurring before 24 hr elapsed, and the degree of corrosion was gradually diffused, but the composition of the present invention also caused very little corrosion due to water. it can be seen that there is This resulted as in Example 28 due to the generation of a material (calcium hydroxide) that prevents corrosion of iron while the composition of the present invention goes through the mixing process during the manufacturing process, and this material is also in the atmosphere when neutralizing and painting concrete It can increase the durability of the building by first reacting with the polluting gas to form a block. The present invention mentioned in the above and examples is more than the contents invented in Patent Application No. 10-0118954 ~ Application No. 10-0162120, etc. applied by the present inventor "Supplementation, further improvement, further improvement, new development (invention)" Addition, improvement of the manufacturing method, and characteristics of the invention were identified and shown in detail by securing specific data for "new invention, the source of efficacy of the invention, etc." In the present invention, the previous patent invented by the present inventor did not solve the mechanism for corrosion, but in the present invention, an excellent mechanism for corrosion resolution was secured compared to the conventional water-soluble adhesive. This is because it is possible to explain academically and theoretically that the added functional materials can not only reduce corrosion as well as increase the durability of buildings as they lead to new salts in a water-solution state. From the left of (a), the composition of the present invention in the center, in which the yellow container solution and the purple container solution are mixed, shows the formation of new salts, and these salts play a role in preventing corrosion, in particular, corrosion of iron. Substances for this are only called salts.

In Example 29, if the plastering thickness exceeds 10mm, cracks may occur in the plastered part, and the construction was preferably less than 2mmm smoothly. Acrylic, Epoxy, Polyvinyl Alcohol, Polyvinyl Acetate, Silicone, Polyurethane, Ethylenevinyl Acetate, Polyvinyl Chloride, Vinyl Acetate Acrylic Copolymer, Acrylic Copolymer with a solid content of 1 to 100% by weight. Gum Rosin, 2-Ethyl Hexyl Acrylate Monomer, 2-Ethylhexyl 2-Propenoate, 2-Hexyl. Resin, Solution or Acid, Primer, Emulsion, Monomer, Copolymer of 2-EHAM, 2-Ethyl Hexyl Acryl Acid, Butyl Acrylate Monomer, N-Butyl Ester, Butyl 2-Propenoic Chloroprene Rubber, Acid, n-Butylacrylate, Vinyl Acetate Monomer , Resorcinol, α-Olefin, Isocyanate, Phenolic, Thermosoftening Plastic, Thermosetting Plastic, Starch, Rice, Wheat, Bran, Corn, Potato, Dextrin, Modified starch, Grains such as Glutinous Rice, Nori, Gelidium amansii Seaweed such as LAMOUROUX, Dextrin A single or a mixture of two or more of substances manufactured with 15 to 50% by weight of solid content, such as grains, modified starch, etc. Sodium Chloride, Magnesium Chloride, Calcium Chloride (European, African, Asian, North American) belonging to a metal chloride of hydrous nH ₂ O (n = 0 to 99) with a solid content of 1 to 100% by weight and used in ~99% by weight Acids, South American products, Oceania products, especially domestic products that are easy to secure, and products made in China were mainly used), etc., in the form of powder or an aqueous solution thereof, in an amount of 0-50% by weight, alone or in a mixture composition of two or more; Solid content 1-100% by weight Salt is edible salt whose main ingredient is sodium chloride, sea salt and industrial substances used as chemicals, East Sea, West Sea, South Sea, Mediterranean Sea, Pacific Ocean, Atlantic Ocean, Indian Ocean, Northern Sea, Antarctic Sea, Dead Sea, Black Sea, etc. Produced in Europe, Africa, Asia, North America, South America, Oceania, especially in the United States, Australia (Australia), China, and Asia such as the Philippines, Europe, West Sea, etc. 6 such as Africa, America and Tibet 0-50% by weight of products produced in salt mines on the continent alone or in a mixture of two or more, Magnesium Chloride 15-19%, Magnesium Sulfate 6-9%, Potassium Chloride 2-4%, Sodium Chloride 2-6%, Use 0-50% by weight of 1 to 69% by weight of solid content consisting of 0.2 to 0.4% of Magnesium Bromide, or 5 to 90% of boiling water by heating 100 g of these, or using these chlorides among Calcium Chloride and Sodium Chloride. And among those whose corrosiveness is lowered by low-corrosion salt production or low-chlorination system by treatment with a chemical reaction between heterogeneous aqueous solutions, 0-50 wt% of these materials alone or two or more are used, or solid content of 5-100 wt% ionic compound In the ionic compound used in the present invention, a metal cation and a non-metal anion are coupled by electrostatic attraction, and the sum of the charges is electrically neutral. , Zn, Fe, Al, Be, Mg, Ca, Ba, etc. may be mentioned at least one anion, and the anion element is a fluoride anion, a bromide anion, an iodide anion, a sulfide anion, a chloride anion, an ammonium anion, a hydroxide anion , sulfate anion, carbonate anion, nitrate anion, phosphate anion, permanganate anion, acetate ion, hydrogen carbonate anion, borate anion, chromate anion, dichromate anion, halo and one or more selected from the group consisting of gen anion, hydrochloric acid anion, organic acid anion, etc., and may additionally include an ammonium salt in consideration of equipment corrosion and solution stability, in anhydrous form, hydrate form, aqueous solution form These substances alone or two or more are used in an amount of 0 to 50% by weight, or solid content of 5 to 100% by weight The ionic compound uses a +1 cation metal and a -1 valent or a -2 valent anion, and the cationic metal element belonging to this is Li , Na, K, and the like, and the anion element is a fluoride anion, a bromide anion, an iodide anion, a sulfide anion, a chloride anion, an ammonium anion, a hydroxide anion, a sulfate anion, a carbonate anion, nitric acid Anion, phosphate anion, permanganate anion, acetate ion, hydrogen carbonate anion, boric acid anion, chromate anion, dichromate anion, halogen anion, hydrochloric acid anion, organic acid anion, etc. It contained at least one selected from the group consisting of, anhydride form, hydrate As a hydrous aluminum silicate mineral containing an alkali metal or alkaline earth metal having various shapes such as 0.0001 to 7,000 μm spherical and plate-like, needle-like, or 0 to 50% by weight of two or more of these substances alone or in the form of an aqueous solution ( A porous structure in which Si,Al)O ₄ tetrahedra are combined in a three-dimensional network and WmZnO _2n2 O composition formula, W is Na, Ca, Ba, Sr, Z=Si+Al, quartz SiO ₂ , diamond-shaped tetrahedral structure is infinitely connected Zeolite, in which a part of Si in a three-dimensional network is replaced by Al, siliceous porous material, lightweight foamed ceramic, Silica, Perlite, Titanium Dioxide, Clay, talc, Aluminum Hydroxide, Kaolin, Magnesium Hydroxide, Calcium Carbonate, Diatomite, Loess , Bentonite, Quartz sand, Gypsum, Lime, cement, Terra a lba, Pozzolan, Diatom, Pulp or water (H ₂ O) dispersed solid content 1-100 wt% Pulp alone or 1 to 99 wt% of two or more are used to protect the interior and exterior walls, ceilings, floors, etc. of buildings Thus, a surface finishing material for plastering to increase the durability of the structure was manufactured. The plastering material of the present invention is a material that is strongly formed without cracking after drying or curing by application, and it is preferable to mainly use it as a finishing material for interior decoration. Its strength is that it can achieve fire prevention and insulation over semi-non-combustible by mixing it with other materials without background treatment, and that it can form patterns in various shapes due to various finishing methods.

As one example of the various composition ratios of Example 31, one side and a square box are plastered with a plastering finishing material prepared by mixing 30g of the present invention, 50% by weight of solid content pulp, and 500g of white clay containing sand After that, resistance and electromagnetic wave attenuation were measured. 54 is a Surface Resistance Meter SRMⓡ110/Made in EURO of Wolfgang Warmbier, a surface resistance meter, and the resistance 10 ⁶ Ω/□ was obtained in a test environment of 21° C. and 38% RH, and FIG. The inside of the box was plastered. The same electromagnetic wave generation environment was created for the one coated with the general plastering paste (non-functional plastering paste) and the one plastered with the composition of the present invention, and the results were measured using a measuring device E-tester (manufacturer: Pulse) at the same time, and the results are as follows. . The electromagnetic environment was improved from 1,848V/m in electric field to 0V/m in case of general coating. In addition, plaster, lime, water, sand, etc. were the main ingredients for plaster, and gypsum was the main ingredient and dolomite. It is a gypsum plaster mixed with clay, the adhesive of the present invention (grass, etc.), and a glue material, and has been developed as a plastering material for walls and ceilings. Therefore, by mixing the functional additive material described in Example 30 alone or by mixing two or more types, a cosmetic product that exhibits electromagnetic wave blocking, antistatic, antibacterial/mildew, semi-incombustible abnormality, freezing prevention, and humidity control performance pursued in the present invention The performance improves as the plaster is applied 1 to 10 times thinly, not only for one-time plastering, but also for initial plastering, chaebol plastering, and finishing plastering. For example, the use of the coating paste of the present invention improves adhesion and suppresses the occurrence of plaster cracks due to quick drying, and the pulp used also reduces cracks by dispersing and reducing cracks. The advantage is that it increases the thickness of the plaster, increases the strength of sand, and implements the unique color of the added ceramic, that is, in the case of loess, it is suitable for country houses and detached houses due to the color of ocher and various colors. Here, hydraulic hardening, which is cured by evaporating water, and hydraulic hardening, which is hardened by reaction with gas in the atmosphere, are one or two examples, respectively. Also, all the materials that are mixed below have various shapes such as spherical, plate-shaped, needle-shaped, etc. as mentioned above, as mentioned above. If you change this to a mesh unit, materials with 3 mesh or more are used. The loess plaster is 30 to 99% by weight of loess, 2 to 50% by weight of pulp, 1 to 80% by weight of the present invention-produced coating paste (25 to 32% by weight of solid content), preferably 80% by weight, 16% by weight, 4% by weight. And, with a composition ratio of 1-50 wt% gypsum, 10-90 wt% loess, 5-30 wt% sand, and 1-50 wt% pulp, it is a hydraulic product that is hardened by evaporation of water, and limestone 1~ 45% by weight, 5-30% by weight of silica sand, 5 to 90% by weight of loess soil, pulp (I decided to use rice bran or rice husk, etc. for all of the above-mentioned compositions instead of pulp), 0-15% by weight of calcium chloride, 1-20% by weight of salt Weight%, nickel powder 1-90% by weight The composition is a hard product and has electromagnetic wave absorption, electromagnetic wave blocking, antistatic, antibacterial/mildew-proof, semi-incombustible abnormality, and anti-freezing performance. Humidity control performance, etc.

And additionally, the effect of far-infrared rays on the loess composition in the composition was measured. As a result of measuring at 40℃ compared to the black body by FT-IR Spectrometer Method, the far-infrared emissivity (5-20㎛) was about 0.902 and the radiant energy was 3.64×10²㎛. The main components of loess of the present invention are kaolinite Al ₂ O _3· 2SiO _2· 2H ₂ O and halloysite Al ₂ O _3· SiO _2· 4H ₂ O, which is a material composed of an excess of Al and Si. Therefore, it is known that materials containing a lot of Al and Si materials have high far-infrared emissivity at high temperatures. 56 shows the measurement results commissioned and evaluated by Test Researcher D. In addition, as mentioned, loess used in the composition exhibits its unique characteristic ocher color, thereby exhibiting the effect as a beautiful exterior product (see Fig. 57), and emitting far-infrared rays, a kind of human-friendly wavelength in loess products of the present invention. It has a radiation function and has (+) and (-) ionic properties, so it has an inhibitory effect on (-) and (+) strains. In addition, loess also exhibits the effect of having semi-incombustibility more than flame retardant by acting as an inorganic flame retardant. As a result of testing the loess-added sample in the present invention in accordance with KS K 0693-2001, a test result was obtained showing an antibacterial effect of 99.9% against Staphylococcus aureus and Pneumococcus, respectively. As shown in FIG. 58, the square box was plastered with the loess plaster composition, and electromagnetic waves were measured using a measuring instrument GIGA SOLUTIONS/Made in Germany. As a result, it was found that the attenuation of the electric field was evident at 8V/m.

Among the above examples and the mixed composition, 0.001 to 100mm carbon fiber or hair, animal hair, or rice bran is used as a substitute for pulp to improve strength and suppress cracking, and improve coating thickness with one plastering (fiber such as pulp has a synergistic effect ) to shorten the construction period. In particular, the carbon fiber exhibits electrical properties as well as (+) charges. -Like silver carrier antibacterial agent- Not only antibacterial effect, but also one stone eight trillions due to electromagnetic wave shielding effect (It can be dispersed into fibers in the above-mentioned and listed water-soluble substances, so it has fiber-like mechanical strength, anti-cracking, antibacterial, anti-mildew, Effect of electromagnetic wave and antistatic, antifreeze, flame retardant (flame retardant) effect, and humidity control.

In Patent No. 1187976, the liquid loess wallpaper composition contains 70 to 90 wt% of loess sediment having a moisture content of 85 to 95% and 60 to 79 wt% of a loess mixture composed of 10 to 30 wt% of diatomaceous earth; 1 to 10% by weight of mulberry powder; Sodium carboxymethylcellulose (CMC) 0.5 to 3% by weight, propylene glycol (PG) 5 to 10% by weight, terrapin oil 1 to 5% by weight, water 72 to 88.5% by weight of a liquid aqueous solution containing 20 to 30% by weight; comprising; The liquid aqueous solution was a liquid loess wallpaper composition characterized in that 5 to 10 wt% of modified starch was further added for quick drying, and in Patent No. 1138128, propylene glycol and terrapin oil were added to the water in the water tank and stirred, , preparing a liquid aqueous solution by adding and stirring sodium carboxymethylcellulose, mixing mulberry powder in the previously prepared aqueous solution, mixing the ocher mixture consisting of loess sediment and diatomaceous earth with the mulberry powder mixture; It relates to a method for preparing a liquid loess wallpaper composition for applying, characterized in that it includes a liquid grinding step of grinding a mixture of the liquid aqueous solution, mulberry powder, loess sediment and diatomaceous earth, and the liquid aqueous solution is 82 to 88.5% by weight of water, Propylene glycol (PG) 5-10% by weight, terrapin oil 1-5% by weight, carboxymethylcellulose sodium (CMC) 0.5-3% by weight of sodium carboxymethyl cellulose (CMC) in the aqueous solution in which the alpha (α) starch is additionally included Sodium Chloride, Magnesium Chloride, Calcium _Chloride (European, African, Asian, North American, 0-50% by weight of powder or aqueous solution thereof, such as South American, Oceania, especially easily obtained domestic and Chinese), alone or a mixture composition of two or more thereof; 1~100% by weight Salt is edible salt with sodium chloride as its main ingredient, sea salt and industrial substances used as chemicals, East Sea, West Sea, South Sea, Mediterranean Sea Pacific, Atlantic Ocean, Indian Ocean, Northern Sea, Antarctic Sea, Dead Sea, Black Sea, etc. Salt produced in Europe, Africa, Asia, North America, South America, Oceania, especially in Asia such as the United States, Australia (Australia), China and the Philippines, Europe, and the West Sea, or 6 continents such as Africa, America, and Tibet 0-50% by weight alone or in a mixture of two or more products produced in the salt mines of Use 0-50 wt% of 1 to 69% by weight of solid content consisting of bromide 0.2 to 0.4%, or 5 to 90% concentration of 5 to 90% by heating 100 g of these, or Calcium Chloride, Sodium Chloride, Among those whose corrosiveness is lowered by the generation of low-corrosive salts or by the low-chlorination system by treatment with a chemical reaction between heterogeneous aqueous solutions, 0 to 50% by weight of these materials alone or two or more thereof are used, or as an ionic compound with a solid content of 5 to 100% by weight. - In an ionic compound, a metal cation and a non-metal anion are combined by electrostatic attraction, and the sum of the charges is electrically neutral. One or more may be mentioned from the group consisting of Al, Be, Mg, Ca, Ba, and the like, and the anion element is a fluoride anion, a bromide anion, an iodide anion, a sulfide anion, a chloride anion, an ammonium anion, a hydroxide anion, a sulfate anion, carbonic acid. Anion, nitrate anion, phosphate anion, permanganate anion, acetate ion, hydrogen carbonate anion, boric acid anion, chromate anion, dichromate anion, halogen anion, hydrochloric acid anion, and at least one selected from the group consisting of organic acid anions and the like. In consideration of corrosion of equipment and solution stability, ammonium salt may be additionally included, and 2 to 50% by weight of two or more of these substances are used alone or in the form of an anhydride, hydrate, or aqueous solution, or solid content of 5 to 100% by weight of ions A +1-valent cationic metal and a -1 or -2 valent anion are used as the cation compound, and the cationic metal element belonging to this may include at least one selected from the group consisting of Li, Na, K, and the like, and the anion element is fluorine Sulfide anion, bromide anion, iodide anion, sulfide anion, chloride anion, ammonium anion, hydroxide anion, sulfate anion, carbonate anion, nitrate anion, phosphate anion, permanganate anion, acetate ion, hydrogen carbonate anion, borate anion, chromate anion, dichromate anion One or more selected from the group consisting of anions, halogen anions, hydrochloric acid anions, organic acid anions, etc. were included, and 0-50 wt% of these substances alone or two or more were used in anhydrous form, hydrate form, and aqueous solution form, or solid content 0.1 ∼50 wt% Conductive Polymer (Polythiophene, PEDOT-PSS, Polyaniline, Polypyrrole) 0∼50 wt%, or 0.0001∼7,000㎛ Iron powder, Copper powder, Cobalt having various shapes such as spherical, plate, and needle-shaped powder, Tin powder, Aluminum powder, Magnesium powder, Titanium powder, Silicon powder, Nickel powder, Zinc powder, Manganese powder. Soft ferrite such as Silver powder, Ag coated Cu, Ni coated Cu, Indium tin oxide, solder ball (Free lead Tin-Bismuth), silver chloride, Antimony tin oxide, Stainless Steel, Mn (or Mg, Ni, etc.)-Zn ferrite And Ba (or Sr, etc.) hard ferrite such as ferrite, Examples 1, 4, 5, 7, 8, 9, 11, 17, 19, 21, 22, 23 0 to 50% by weight of a mixture prepared in the composition of So; In a wallpaper composition for simple application, application products using a composition that exhibits performance such as strengthening adhesion, anti-freezing, anti-bacterial and anti-mildew, electromagnetic wave blocking, anti-static, flame-retardant, and humidity control pursued in the present invention were developed.

Among the currently commercialized insect repellents, the main ingredients of spray insecticides are phthalthrin and pyrethroid compounds used in pesticides, etc. These ingredients are less toxic than organochlorine or organophosphorus insecticides, so they are widely used. imidacloprid, a colorless and odorless transparent gel, is said to disappear when sprayed on the corners and crevices of a house, but it is also applied to various insects. It is a kind of pesticide that is known to cause a fatal injury to the ecosystem and is a concern that it may disturb the ecosystem.

However, the composition of the present invention, that is, the salts of the additives of Examples 1, 4, 5, 7, 8, 9, 11, 17, 19, 21, 22, 23, 27, 29, 30, and 31 of the present invention are electrolyte ions. The better the dissociation, the better the electrical conductivity, and it is one of the essential components that we need to live. This is because if we do not consume the salt contained in salt, our body cannot function properly. In addition, even if harmful substances or bacteria invade the body, it also plays a role in increasing the body's resistance to prevent intrusion into cells and blood vessels. So, if the human body lacks salt, toxins accumulate in our body, making it easy to get bad diseases, but only the heart in the body never gets cancer, because the heart contains the most salt. Not only humans, but also all living things on Earth cannot survive without salt intake. Animals ingest salt by finding salt rocks or salt caves, and plants absorb salt from the ground. If cows or horses do not consume salt, they cannot use their strength, and trees that lack salt easily rot. Therefore, salt does not give any room for various germs, bacteria or microorganisms to reproduce, and it has properties that do not change even after a long period of time. Salt dissolves well in water, so it penetrates and mixes well with other substances. And since salt has the property of absorbing dust, it can be wiped clean in every nook and cranny. It is a purifying property, so it has been said since ancient times that if you put salt in a place where mold is easily generated in every corner of the house, or if there are a lot of ants in the house, if you sprinkle salt on it, it will go somewhere else. As a good example, the Tripitaka Koreana was completed in 1251, and when the remaining wooden blocks are stacked one by one, the height is about 3.2 km, and the total weight is about 280 M/T. Even if it was well made, it would not have been possible to admire the beauty of the Tripitaka Koreana today if it had not been properly preserved. For the reason that it was able to be preserved in its original form for a long time, first, looking at the wood selection process, the wood, which will be used as a plank, was not used immediately, but was soaked in seawater for 1 to 2 years. After that, it was cut to the size of a plate, boiled in salt water, and dried. Salt has the property of preventing cracking of wood due to temperature and humidity, so it can reduce the phenomenon of cracking or twisting of the plate. The place to store the completed Tripitaka Koreana is also important, so the environment suitable for the preservation of woodblocks is around 20 degrees Celsius and less than 80% humidity. However, the climate of the Tripitaka Koreana does not satisfy this criterion. The average humidity inside Panjeon is 89.09% in summer and 75.91% in winter, which is higher than general wood preservation standards. The average temperature in summer was 19.81℃ and winter average was 2.74℃, which was much lower than the winter indoor temperature standard. What is the reason for the natural ventilation and the floor of the storage building, which was dug deep and sprinkled with charcoal, clay, sand, salt, and fish powder, etc. When it rains a lot and it gets wet, the floor absorbs moisture, and when there is a drought, the moisture hidden in the floor rises and automatically adjusts the humidity. Also, salt can get rid of ants. Ants instinctively like sweet smells. I like sugar or sweet candy, but I hate salt or vinegar, etc. So, as a result of a reaction experiment on salt with 100 ants, it was found that ants did not come to the part where salt was applied. As shown in Figure 59, as seen in this actual experiment, it was confirmed that salt has an ant repelling effect.

Therefore, as the salt used in the present invention, on the one hand, edible salt containing sodium chloride as a main component, chemicals, and materials collected and manufactured from rock salt were used, and on the other hand, seawater was directly collected and used. Salt is naturally present in seawater by 2.8 to 5.0%, and in land where it exists as rock salt, by 3.5 to 5.0%. Rock salt is mainly produced in Europe, North America, and China. For industrial purposes, it is used as it is, but edible salt is refined salt, which is manufactured by the salt field method or by using an ion exchange resin when it is collected from seawater. When hydrochloric acid and sodium hydroxide are neutralized, sodium chloride (salt) and water are produced by the neutralization reaction. That is, sodium chloride exists as ions (Na ⁺ , Cl ^- ) in solution, and when water is evaporated, solid sodium chloride is formed. When it is mixed with water again, it becomes an aqueous electrolyte solution containing Na ⁺ , Cl ^- and exhibits electrical properties. As shown in Table 15, seawater, that is, ordinary seawater contains water as a main component, has a salinity of 5.0% or less, and is composed of trace metals (minerals). The salinity ratio of seawater is higher than the salinity concentration of the living body (about 0.9%), but it can be seen that it has the most similar ratio to humans compared to other organisms (animals) based on Na ⁺ 100. Therefore, salt is a substance beneficial to the human body enough to not be harmful to the human body unless eaten in large quantities. It is a material with excellent flame retardancy as well as the aforementioned conductive properties, as well as the ability to inhibit various bacteria and fungi. , Indian Ocean, Arctic Ocean, Antarctic Ocean, Dead Sea, Black Sea, etc. (European, African, Asian, North American, South American, Oceania) produced in Asia, Europe, USA, Australia (Australia), China, Philippines, Vietnam It is a product manufactured from salt produced in the West Sea or from salt mines on six continents such as Africa, America, and Tibet. It will also be a product that can be given. Therefore, the material of the present invention is friendly, friendly, and beneficial to the human body, and some products manufactured according to the present invention are edible, but there is no harm to the human body.

division Na+ K+ Ca2+ Mg2+ Cl- sea water 100 3,61 3,91 12.1 181 jellyfish 100 5.18 4.13 11.4 186 Humpback Shark 100 4.61 2.71 2.46 166 Dae-gu 100 9.50 3,93 1.41 150 frog 100 - 3.17 0.75 136 dog 100 6.62 2,80 0.75 139 Person 100 6,75 3.10 0.70 129

(Source: Water and Hananika, 講談社)

The cause of static electricity due to charging is the electric charge charged on the surface of the insulator due to electromagnetic waves in electric and electronic products or friction due to low humidity, which is the cause of defective products. However, it can lead to fire and explosion hazards in flammable substances handling workplaces such as gas stations. 60 shows the capture principle and scene of ignition by static electricity at the mother gas station. As such, ignition by static electricity frequently occurs in the vicinity. The cause of ignition at a gas station is that friction electricity generated by friction during movement is charged to an insulator, which is clothing, and then instantly escapes to another nearby object, leading to ignition and explosion. Almost all gas stations have a gas lubricator installed on the floor, which is the surrounding insulator, so the only place to escape in case of static electricity is the lubricator. As a solution to this, when the floor is constructed with the product of the present invention, even if the driver's shoes are an insulator and serve as a charging body, even if the static electricity is not completely eliminated, some drivers and surrounding static electricity is released to the ground to increase the static electricity In addition, if a metal wire, such as a metal wire, is temporarily connected to the vehicle body before refueling, if the vehicle body and the ground are connected with a conductor that can disperse and extract static electricity generated during driving through this, the ignition as shown in FIG. is another feature according to the present invention that it can be largely or completely eliminated. In other words, if a long wire is provided with a lubricator to put the wire on the vehicle body first and then refuel, the static electricity is first discharged from the driver's clothing, which may have static electricity the moment the driver grabs the wire, and the static electricity of the vehicle body is the bottom of the present invention. A system capable of resolving static electricity is also one of the characteristics of the present invention.

It is known that dust causes fire and explosion, respiratory disorders, nervous system-related disorders, and even nausea.

Accordingly, it is characterized in that it provides a production method in consideration of the improvement of the working environment and productivity of the worker, which is another important invention of the present invention. When explaining the manufacturing process of dobae grass (wheat grass), which is one of the manufacturing compositions of the present invention, as an example, the previous or current dobae grass (wheat grass) production line seriously threatens the health of workers by the dust generated during the raw material input process. is known As a method to fundamentally solve this problem, the present invention makes the input of raw materials through the absorption pipeline or covers the currently open (exposed outside without a lid) manufacturing container and puts a part of the lid with a raw material input port that allows flour to be input. It is an important feature to manufacture the papering pool of the present invention by manufacturing the manufacturing equipment to fundamentally block the worker working environment and the threat of explosion caused by the dust by separating the worker from the dust.

Although the above content described in the present invention is epidemiological statistical data, but the medical basis is not yet clear, it is very likely that the worker is suffering from a respiratory disease caused by flour dust, etc. Based on the evidence, a manufacturing line was manufactured and invented as a countermeasure to this.

Through this, the 1 to 99% wheat grass prepared with the composition of Example 1 has little or no possibility of introducing contaminants due to external contact blocking, so aseptic wheat water can be manufactured. 14-21% solid content The distribution and preservation period was improved by 1.5-500 times compared to wheat grass (grade 1 starch used). However, even when the composition of the present invention is produced in an existing production line, the distribution and preservation period is improved by 1.5 to 350 times or more compared to the previous general wheatgrass. This distribution and preservation property was evaluated as a product that does not contain any preservatives (preservatives). When all of the above compositions contain preservatives (preservatives) that are within the legal standards of Korea, the composition of the present invention, 26% solids, has improved 5 to 1,000 times more than the 14-21% solids general wheatgrass distribution and preservation period. 61 is a photograph taken after opening in order to continuously determine whether the composition of the present invention is deteriorated after one month or more has elapsed after manufacture. After opening, there was no odor in the paper grass, the adhesive strength was the same as the first time, and there was mold growth only in the bottle cap area at the time of opening, but there was no mold generation in the wheat grass inside. The composition adhesive material of FIG. 61 is tested, produced, and verified by the general Milful M company and in particular, the self-installed manufacturing line.

In the present invention, as the most important problem, the invention was made for the purpose of improving adhesion better than the conventional concept of strengthening adhesion according to the type of polymer, but with the same adhesive material.

If wheat grass is described as an example among those manufactured according to the above examples, 15 to 20% of solid content using Korean wheat grade 1 starch among general wheat grass, 18 to 23% of solid content used in grade 2 wheat grass, and 15 solid content of the present invention ~30% As a result of comparing the mutual adhesion for the same conditions among wheat grass, it was found that the wheat grass of the present invention was the best. This evaluation was verified through E Painting Institute, and in the evaluation method, a painter purchases wheat grass and dilutes it with water before applying it to the wallpaper. As they all differ depending on the planting company, this evaluation was evaluated after dilution by adding water in a ratio of 1 to wheat grass 1 in common. As a result of the evaluation, surprising results were obtained. It was the best in adhesive strength, which is the original purpose of wheat grass. Assuming that the adhesive strength of the 2nd grade wheat grass is 1, the 1st grade wheat grass was 1.2 to 1.5 times higher, and the wheat grass of the present invention was 1.5 to 3 times superior. This is because, through the intrinsic properties of the composition of the present invention and the hidden mention, the difference in impurities due to the grade of starch, not the solid content, occurred in general wheatgrass, and in the case of the same grade, the present invention is superior to general wheatgrass in terms of product function composition and starch , it is judged that it is highly probable that excellent adhesion was exhibited due to the interaction between the adhesion of the composition between wallpapers and the cellulose-like structure, but the scientific explanation for this is hidden in the specification of the present invention.

In order to improve this, the present inventors improved production output, improved manufacturing process by developing manufacturing equipment, and, in particular, manufactured based on the characteristics of Table 16, replacing the same as the products of FIG. We are building a domestic and overseas sales network through generalization by selling and selling, and have developed to provide better, better, healthier, and healthier wallpaper for users.

general tile characteristic the present invention Adhesive adhesion 1.5~2 times better adhesion doesn't exist antistatic Surface resistance 10 ⁵ to 10 ⁸ Ω/□ Most of the antibacterial agents are not used due to the high price/decreased adhesion performance. antibacterial Antibacterial effect by chemical properties Effects of preservatives anti-fungal Anti-mildew effect by chemical properties Freezes below -5℃ and loses adhesion Freeze protection Does not freeze below -10~19.3℃. smoke from flames flame retardant It has fire suppression ability due to its flame retardancy. Rust caused by moisture Anti-rust properties Rust prevention by chemical properties. Except for powdery mildew, long-term storage is difficult long-term storage possible

The main component of rice or wheat flour is starch. When heated, water quickly penetrates the starch and acts as a plasticizer, resulting in a gel-like paste. The reason why paste made by heating rice or flour with water shows high adhesion to paper is that the cellulose structure of the paper and the starch structure of the paste are similar, so the mutual affinity is high. It is because it can easily diffuse into the fine irregularities of The starch made from starch is easy to make, and because it is a natural product, it is environmentally and human-friendly. However, environmental and human friendliness may rather act as a disadvantage. In hot and humid places, mold easily develops. To prevent this, formaldehyde and phenol were added as preservatives to prevent mold from occurring in the past and now. (Chemistry and Polymers in Life, 2010. 12. 31. Free Academy) Formaldehyde is very toxic to the human body, so Exposure to formaldehyde can cause disease symptoms (irritation, respiratory disorders, asthma, headache, etc.) It has a stinging taste and weak acidity, a peculiar smell, and is classified as a carcinogen. A multifunctional adhesive composition and material are prepared by performing anti-freezing, flame-retardant, humidity control, etc. on the composition, and producing a basic material (salt) by mixing the materials. In addition, although the previous examples have been described with respect to a batch method, Examples 1, 4, 5, 7, 8, 9, 11, 17, 19, 20, 21, 22, 23 , 27, 29, and 34 are first mixed in a compounding machine (mixer or container, tank) for one or more days under the conditions of 0 to 70 ° C, 0.5 to 30 min, 0.01 to 100,000 rpm, 0.5 to 5 atm. Prepare a liquid (mixed liquid liquid), transfer this mixing liquid to the previous container (blending machine or mixing container), preferably a container that is more than twice as large, and mix the transferred mixing liquid at room temperature to prepare or boil it As a means for this, it is prepared with a viscous adhesive material, as an example, wheat paste, while slowly stirring and heating for 5 to 60 min in a traditional method under 50 to 350 ° C, 0.1 to 5 atm, or, on the other hand, although not shown in the drawing, the mixing solution is 0.01 It was manufactured by passing a heat-conducting tube, heat-conducting sheet, drum, etc. installed in oil, steam, water, gas, and electric heat source heated to 70-500°C by -10min instantaneous heating method. The instantaneous heating method may be configured by winding the tube in a straight shape or in a circular shape to save space. The container used here is preferably a corrosion-resistant stainless steel or alloy (stainless steel amd alloy), but general metals and inexpensive plastic materials can be used. As such equipment is additionally installed in the mixing liquid container, the cost competitiveness becomes excellent by reducing the labor cost burden according to the increase in production volume. The manufactured high-temperature adhesive composition and material are immediately packaged at the same time as the prepared composition and material are discharged through the tube of the above-mentioned example, or a device for cooling to 40° C. or less for easy packaging (sheets, drums, containers preferably was passed through the drum) and weighed to the desired weight in a packaging bag or barrel, and then packaged. In particular, when a drum is used as a cooling device, a knife or bar type is mounted on one side of the drum so that agglomeration can be resolved when agglomerated adhesive composition and materials occur, and transport and In the case of packaging, it is passed through a mesh such as a mesh to prevent the agglomerated adhesive composition and material or mixing liquid from passing to the next step process, and in the case of putting it in another container, one or more pipes for packaging are provided at the bottom of the container. . As another example, in the present invention, if it is manufactured by covering an onion net in front of the mixing liquid transfer pipe in a method that costs little, it is also another example that it can be possible to eliminate the agglomeration going to the next step process. characteristics belonging to The adhesive composition and adhesive material prepared as described above are characterized in that they have the same functions described in Examples 1 to 39.

In Figure 62, in accordance with the quality labeling regulations by industrial product quality control according to the addition of harmful mold inhibitors to suppress the occurrence of mold, this should be indicated on the products sold. The data and GHS (Globally Harmonized System of Classification and Labeling of Chemicals abbreviation, classification, labeling, and material safety data sheet for chemical substances) are shown in FIG. 62 . However, in the present invention, one example to be used on the outer surface of the product packaging paper by not using preservatives, etc. is shown in FIG. 63. The technical product of the present invention, in particular, as previously described, is edible, but manufactured as an industrial product. Since it is a product, it is preferable not to eat it, but it is characterized as edible in an emergency as all materials are manufactured to be usable as food in an emergency such as an earthquake. In addition, important features are also shown in FIG. 63 .

It is known that moderate humidity can help prevent or treat respiratory diseases, and drying with other factors such as dry winter or heating causes dead skin cells on the surface of the skin and increases itching, especially in people with atopic dermatitis. said to be getting worse For this reason, humidifiers and dehumidifiers are mainly used as methods to artificially maintain desired humidity when appropriate humidity is needed, and many households are making efforts to maintain proper humidity by using charcoal or plants indoors. In order to create a comfortable indoor environment, humidifiers and dehumidifiers require periodic management for sanitary use. Plants and charcoal are known to be capable of dehumidifying and controlling humidity. It is not currently.

Accordingly, among the composition qualities of the present invention, additive substances and antistatic, antibacterial and anti-mildew, flame retardant and additive substances that exhibit the performance of strengthening adhesion, anti-freezing, anti-bacterial/mildew, anti-static, flame-retardant, anti-corrosion, humidity control, and insect repelling properties mentioned in the above examples Substances added for , increase in weight, impact reinforcement and dispersion, cold resistance, viscosity increase, drying (curing) time shortening, decay prevention, and plastering are non-toxic and sustainable recyclable materials that are essential as building materials. Due to the nature of the material, in a high-humidity environment, the material itself absorbs moisture in the air to lower the indoor humidity, and in a low-humidity dry environment, it contributes to a comfortable indoor environment by spewing the moisture contained in the material into the air. can In particular, wallpaper paste for wallpaper exhibits characteristics throughout the room due to the above-mentioned substances evenly distributed and distributed over a large area, and application products manufactured with this composition, such as paints, boards, tiles, and wallpaper, are expected to be used as eco-friendly building materials. can become According to a research report, it is possible to reduce odors in the air through humidity control and to decompose pollutants (Source: S. S. Lee, J. S. Kim, C. Y. Yun, and J. H. Yi, Adsorption Characteristics of the Sericite) and Diatomite for Ammonia Gas, Clean Technology, 12(3), 175(2006); H. J. Kim, Evaluating IAQ Improvement Performances of Eco-friendly Building Materials, Ph.D. Thesis, Hanyang University (2011)), Functionality in the form of application It is said that application and expansion as an eco-friendly building material is expected through the development of this wallpaper, which is different from paints, thick boards, and tiles (Source: K. Y. Nam and J. S. Lee, Dyeing Properties and Functionality of Methanol Extract from Juniperus chinensis Heartwood, Textile Coloration and Finishing) , 25(3), 194 (2013); (4), 271 (2013)). Therefore, the composition and application products of the present invention are expected to be utilized as a product group that can help the human body.

Charcoal (10 cm in diameter, 15 cm in length) was placed in a room of the same size as a 5 pyeong room coated with the adhesive material of the present invention, and changes in temperature and humidity were measured. For measurement, changes in temperature and humidity were measured from 2 hr after the start of the TEST. As shown in the measurement results, the room serving as the test standard and the room equipped with charcoal showed the same results, so charcoal had almost no efficacy. One room started the experiment at a temperature and humidity similar to that of the reference room, but the measurement results after 2 hrs. In a humid environment, it can be an important basis for showing that the humidity control function, which is a characteristic of the present invention, is excellent, as it shows the result of discharging and increasing the absorbed moisture.

division Humidity standard room Charcoal Beach Room Room upholstered with the material of the present invention Environment before measurement Temperature (℃) 20 20 21 Humidity(%) 90 90 89 environment after measurement Temperature (℃) 20 20 21 Humidity(%) 90 90 82 Environment before measurement Temperature (℃) 30 30 30 Humidity(%) 35 35 37 environment after measurement Temperature (℃) 30 30 30 Humidity(%) 35 35 41

In the composition according to Examples 1, 2, 3, 4, 5, 7, 8, 9, 11, 74 to 100% by weight of solids in 50 to 95% by weight of seawater 1 to 20% by weight of chloride or 30 to 100% by weight of solids 1 to 19% by weight of salt alone or 2, including 3 to 60% by weight of starch As a method of manufacturing it, it was confirmed that it had 10 ^5-9 Ω/□ as a result of manufacturing and evaluating a paper paste that exhibits the main functions of electromagnetic wave blocking, antistatic, antibacterial/mildew, flame retardant, and anti-freezing performance.

The seawater procured from the sea was used after being placed in a container for 0.1 to 240 hours or more. For example, water procured from the East Sea has few impurities and can be used within 0.1 hours, but seawater with many impurities like the West Sea requires time to settle impurities. In addition, for sterilization of the seawater, one including heating at 70-101° C. was used.

In the composition according to Examples 1, 2, 3, 4, 5, 7, 8, 9, 11, 74 to 100% by weight of solid content in 50 to 95% by weight of water 1 to 20% by weight of chloride or 30 to 100% by weight of solid content The above mixing ratio of the liquid paste composition prepared by stirring or extrusion heating at 60 to 350° C., 1 to 60 minutes, 1 to 20,000 rpm, including 1 to 22 wt % of salt alone or 2, including 3 to 60 wt % of starch And as a manufacturing method thereof, it was confirmed that it had 10 ^5-9 Ω/□ as a result of manufacturing and evaluation of the coating paste exhibiting the main functions of electromagnetic wave blocking, antistatic, antibacterial/mildew, flame retardant, and freezing prevention performance.

In the composition according to Examples 1, 2, 3, 4, 5, 7, 8, 9, 11, 74 to 100% by weight of solid content in 50 to 95% by weight of water 1 to 20% by weight of chloride or 30 to 100% by weight of solid content The above blending ratio of the liquid paste composition prepared by 1 to 22 wt% of sea salt alone or 2, including 3 to 60 wt% of starch, 60 to 350 ° C, 1 to 60 minutes, 1 to 20,000 rpm stirring or extrusion heating And as a manufacturing method thereof, it was confirmed that it had 10 ^5-9 Ω/□ as a result of manufacturing and evaluation of the coating paste exhibiting the main functions of electromagnetic wave blocking, antistatic, antibacterial/mildew, flame retardant, and freezing prevention performance.

In the composition according to Examples 1, 2, 3, 4, 5, 7, 8, 9, 11, 74 to 100% by weight of solid content in 50 to 95% by weight of water 1 to 20% by weight of chloride or 30 to 100% by weight of solid content The above blending ratio of the liquid paste composition prepared by 1 to 22 wt% of sea salt alone or 2, including 3 to 60 wt% of starch, 60 to 350 ° C, 1 to 60 minutes, 1 to 20,000 rpm stirring or extrusion heating And as a manufacturing method thereof, it was confirmed that it had 10 ^5-9 Ω/□ as a result of manufacturing and evaluation of the coating paste exhibiting the main functions of electromagnetic wave blocking, antistatic, antibacterial/mildew, flame retardant, and freezing prevention performance.

In the composition according to Examples 1, 2, 3, 4, 5, 7, 8, 9, 11, 74 to 100% by weight of solid content in 50 to 95% by weight of water 1 to 20% by weight of chloride or 30 to 100% by weight of solid content Rock salt (also called stone salt or stone salt) 1 to 22 wt% alone or 2, including 3 to 60 wt% starch, 60 to 350 ° C, 1 to 60 minutes, 1 to 20,000 rpm Stirring or extrusion heating With the above mixing ratio of the prepared liquid paste composition and its manufacturing method, a coating paste exhibiting the main functions of electromagnetic wave blocking, antistatic, antibacterial/mildew, flame retardant, ^and antifreezing performance was manufactured and evaluated. It was confirmed that they have □.

In the composition according to Examples 1, 2, 3, 4, 5, 7, 8, 9, 11, 74 to 100% by weight of solid content in 50 to 95% by weight of water 1 to 20% by weight of chloride or 30 to 100% by weight of solid content The above mixing ratio of the liquid paste composition prepared by 1 to 22 wt% of refined salt alone or 2, including 3 to 60 wt% of starch, 60 to 350 ° C, 1 to 60 minutes, 1 to 20,000 rpm stirring or extrusion heating And as a manufacturing method thereof, it was confirmed that it had 10 ^5-9 Ω/□ as a result of manufacturing and evaluation of the coating paste exhibiting the main functions of electromagnetic wave blocking, antistatic, antibacterial/mildew, flame retardant, and freezing prevention performance.

In the composition according to Examples 1, 2, 3, 4, 5, 7, 8, 9, and 11, 40 to 95 wt% of seawater contains 5 to 60 wt% of starch, 60 to 350°C, 1 to 60 minutes, 1 The above mixing ratio of the liquid paste composition prepared by stirring at ~20,000 rpm or heating by extrusion and its manufacturing method, the main function of electromagnetic shielding, antistatic, antibacterial and anti-mildew, flame retardant, antifreezing performance, As a result, it was confirmed that 10 ^{5 ~ 9} Ω/□.

Among the compositions according to Examples 1, 2, 3, 4, 5, 7, 8, 9, and 11, an adhesive material providing adhesion, chloride, or salt is included, and the adhesive material is an acrylic resin, an epoxy resin, or polyvinyl alcohol. Resin, polyvinyl acetate resin, silicone resin, polyurethane resin, ethylene vinyl acetate resin, polyvinyl chloride resin, olefin (olefin), isocyanate resin, including one or two or more of adhesives made of vinyl acetate monomer resin, solid content This is 1 to 99% by weight, and 1 to 25% by weight of chloride or salt alone or as an adhesive composition comprising two or more, 5 to 350 ° C., 1 to 600 minutes, 1 to 20,000 rpm An adhesive prepared by stirring As a result of the evaluation by preparing a coating paste that exhibits the main functions of electromagnetic wave blocking, antistatic, antibacterial/mildew, flame retardant, and anti-freezing performance with the above compounding ratio of the composition and its manufacturing method, it has 10 ^5-9 Ω/□ was confirmed.

Powdered grass (K company) was prepared by including 1 to 20% by weight of 100% by weight chloride or 1 to 22% by weight of salt alone or by mixing. As a result of dissolving the composition and evaluating it, it was confirmed that it had 10 ^5-9 Ω/□ as a result of manufacturing and evaluating the coating paste exhibiting the main functions of electromagnetic wave blocking, antistatic, antibacterial/mildew, flame retardant, and anti-freezing performance. .

Starch, cellulose, natrium ansinhyang, borax containing 100% by weight of solids 100% by weight chloride in powdered grass or 1 to 20% by weight of solids 100% by weight of salt 1 to 22% by weight alone or two, the composition is melted and evaluated As a result, it was confirmed that it had 10 ^5~9 Ω/□ as a result of manufacturing and evaluating a wallpaper that exhibits the main functions of electromagnetic wave blocking, antistatic, antibacterial/mildew, flame retardant, and freezing prevention performance.

In the above embodiment, the purpose of increasing the solid content of the water-soluble compositions is to reduce the distribution cost by weight reduction, to improve the working environment by reducing the weight during movement, and to improve the freezing and antibacterial performance. There are many advantages by weight reduction such as improvement. However, as a disadvantage, the higher the solid content, the longer the annealing time of the added water, but there are many advantages compared to the disadvantages. Therefore, as a method of increasing the solid content, in the present invention, a method of lowering the mixing ratio of water or evaporating by heating was selected.

Among the compositions according to Examples 43, 44, 45, 46,47, 48, 49, 50, and 51, as a method of further improving the adhesive strength of the coating paste, one of the compositions of Example 1 in the present invention is the starch paste ( ) of Examples 1, 6, and 7 containing 5 wt% or less of the adhesive component, 50 to 350 ° C, 1 to 60 minutes, 1 to 20,000 rpm stirring or extrusion heating, or prepared through Examples 1 to 41 It was prepared by mixing the adhesive components of Examples 1, 6, and 7 to the coating pool and stirring or extruding at 5-350° C. for 1 to 60 minutes, 1 to 20,000 rpm.

Of the composition according to Example 52, as a method of further improving the adhesion of the dobae paste, the adhesive component of Examples 1, 6, 7 was added to the starch paste (paper paste), which is one of the compositions of Example 1 in the present invention, by 5 wt% or less included. The composition prepared in this way was prepared and used in a liquid state by stirring while raising the temperature to 70°C or higher under a water bath after 3 to 50 minutes after adding water at 70°C or lower during use.

The composition plaster of the present invention is mainly used for wallpaper interior, and the composition adhesive as in Examples 1, 6, 7 is used when constructing articles except for tiles, non-woven fabrics, and papers such as tex, therefore, the composition of the present invention, practice Examples 1, 2, 3, 4, 5, 6, 7, 8, 9, 11, 17, 19, 23, 29, 31, 38, 43, 44, 45, 46, 47, 48, 49, 50, 51 , 52, 53, 54, 55 as a result of indoor interior construction with composition 10 ^5-9 Ω / came to be formed.

Interior means interior decoration, and it can be said that convenience and coziness are mainly pursued through construction or arrangement such as lighting/flooring, tile/wallpaper/curtain, etc.

Accordingly, in allowing customers to lead a healthy life indoors through the interior business pursued by the present inventor, the electric field generated from lighting is attenuated through the wallpaper applying the wallpaper / The floor and tiles are applied inside and outside through the adhesive Blocking electric field and suppressing mold in adhesive part / The curtain made with the adhesive of the present invention has fine dust reduction by antistatic, electric field reduction, antibacterial, anti-mildew effect, and flame retardant performance.

Thus the composition of the present invention, Examples 1, 2, 3, 4, 5, 6, 7, 8, 9, 11, 17, 19, 23, 29, 31, 38, 43, 44, 45 Composition 10 ⁵ As a result of constructing the interior with ^~9 Ω/□, as shown in FIG. 64, it was confirmed that it had fine dust reduction, electric field reduction, antibacterial, anti-mildew effect, and flame retardant performance. Accordingly, the present inventors intend to pursue interior commercialization based on the interior effect confirmed through the present invention.

Although it is preferable that the examples and modifications described in this specification are described as examples, modifications, etc. according to the acronym rule, in the present specification, the inscription rule is not applied as indicated in the identification items of the specification, but in context Some mixed descriptions were also made. Although the scientific principles, considerations, experiments (tests), and descriptions and illustrations of the present invention have been described above, it is apparent that the present invention may be practiced with various modifications by those skilled in the art. Such modified examples should not be individually understood from the technical spirit or perspective of the present invention, and such modified examples should fall within the scope of the appended claims of the present invention.

10: printed layer (base material layer, embossing layer).
20: A flame retardant (antistatic) coating layer.
30: Foam or sheet (paper, plastics, etc.).
40: aluminum foil layer.
50: adhesive layer.
60: Lee Hyung-ji.
70: polymer material.
70' paper.

Claims (2)

The present invention relates to a composition and manufacturing method that complexly or selectively/selectively exhibits adhesion strength, anti-freezing, anti-bacterial/mildew, anti-static, flame-retardant, and anti-corrosion performance according to the type of additive material and the mixing ratio of the additive material, and the structure of the present invention It relates to structural products, product construction methods, and application products based on in order to;
First, as materials that provide adhesion and appearance, Acrylic, Epoxy, Polyvinyl Alcohol, Polyvinyl Acetate, Silicone, Polyurethane, Ethylenevinyl Acetate, Polyvinyl Chloride, Vinyl Acetate Acrylic Copolymer, Acrylic Copolymer with a solid content of 1 to 100% by weight. Gum Rosin, 2-Ethyl Hexyl Acrylate Monomer, 2-Ethylhexyl 2-Propenoate, 2-Hexyl. 2-EHAM, 2-Ethyl Hexyl Acryl Acid, Butyl Acrylate *?*Monomer, N-Butyl Ester, Butyl 2-Propenoic Chloroprene Rubber, Acid, n-Butylacrylate, Vinyl Acetate Monomer Resin, Solution or Acid, Primer, Emulsion, Monomer, Copolymer, Resorcinol, α-Olefin, Isocyanate, Phenolic, Thermosoftening Plastic [PVC (Polyviny chloride), polyester, PVC sol, PP (Polypropylene), ABS (Acrylonitrile Butadiene Styrene), PMMA (Polymethlmethacrylate), PE (Polyethylene) , PET (Polyethylene Terephthalate), PBT (Polybuthylene Terephthalate), PPS (Polyphenylene Sulfide), PC (PolyCabonate), Nylon, LDPE (Low Density Polyethylene), HDPE (High Density Polyethylene), Polystyrene any one or a mixture of two or more], Thermosetting Plastic (Phenol, Urea, Melamine, Polyurethane, Unsaturated Polyester, Silicon Resin alone or a mixture of two or more), Starch, Rice, Wheat, Bran, Corn, Potato, Dextrin, Modified starch, Glutinous Rice, Nori, Gelidium amansii LAMOUROUX of seaweed, such as dextrin, grains such as dextrin, substances manufactured from modified starch, etc., powdered grass (Germany H company, Korea E company, K company, Y company, etc. powder grass is used); Characterized by including the use of 1 to 99% by weight alone or in a mixture of two or more,
As one of the main purposes of the present invention, the mixing ratio of the additive material that exhibits the performance of strengthening adhesion, anti-freezing, antibacterial/mildew, electromagnetic wave blocking, antistatic, flame retardant, corrosion prevention, and insect repelling performance in a complex or selective manner, as an additive material, Sodium Chloride, Magnesium Chloride, Calcium Chloride (European, African, Asian, North American, South American, _Oceanian , especially Domestic and Asian acids, which are easy to secure, are mainly used), etc.), etc. powder or its aqueous solution form is prepared and used in an amount of 0 to 50% by weight, or these substances are used alone or in a mixture composition of two or more; 1 to 100% by weight of solids Salt is edible salt with sodium chloride as the main ingredient, sea salt and industrial salt materials used as chemicals, East Sea, West Sea, South Sea, Mediterranean Coast, Pacific Ocean, Atlantic Ocean, Indian Ocean, Arctic Ocean, Antarctic Ocean, Dead Sea, Black Sea, etc. (Europe, Africa, Asian, North American, South American, Oceania) Salt salt produced in Asia, Europe and West Sea such as USA, Australia (Australia), China, Philippines, Vietnam or Africa, America , produced in salt mines (rock salt) on six continents such as Tibet - The salt of the present invention is largely classified into sea salt and refined salt. Sea salt is a thick, translucent hexagonal crystal made by drawing seawater to a salt farm and evaporating harmful components along with moisture with wind and sunlight. In contrast, purified salt is a crystal of sodium chloride obtained by electrolyzing seawater to remove impurities and heavy metals with an ion resin film. In Korea, it is produced a lot in the west coast or south coast where the water depth is not deep and the tidal difference is large. Sinan-gun, Jeollanam-do accounts for 65% of the domestic solar salt production and more than half of the salt farm area, and its quality is excellent worldwide. Also, salt containing sulfur that is produced near Baengnyeongdo is considered a commodity. Cheonil Salt Farms in Korea usually consist of a reservoir, an evaporation pond, and a crystallization pond. At high tide, the sluice gate is opened to make concentrated brine in the evaporation pond and send it to the crystallization area to obtain salt crystals. When the wind is strong, the crystals are small, and when the temperature is low, the salt tastes bitter and the quality of salt is poor. The sea salt produced in Korea is alkaline and its salinity is about 88%. Sea salt has a lot of minerals and moisture such as Ca, Mg, Zn, K, and Fe, so it is good for pickling vegetables or fish and is mainly used for making kimchi, soy sauce, and soybean paste. While it contains a lot of minerals that are good for the body, but also contains some toxic substances, it must be removed and consumed. In addition, sea salt has high hygroscopicity due to various minerals, and has anti-corrosive effect by sterilizing power beyond antibacterial. Source: Doosan Encyclopedia, S Salt Farm, Sinan, Company G, refer to data search data and inventor's knowledge), - Use 0-50 wt% alone or in a mixture of two or more; Magnesium Chloride 15~19%, Magnesium Sulfate 6~9%, Potassium Chloride 2~4%, Sodium Chloride 2~6%, Magnesium Bromide 0.2~0.4%, etc. Solid content 1~69% by weight bittern, or 100g of these 0 to 50% by weight of 5 to 90% concentration by heating; Where antibacterial activity is needed even more, 0-50% by weight of refined salt is used instead of sea salt to secure antibacterial and anti-mildew effects, and in particular, it is treated at a high temperature of 100° C. or higher to eradicate all bacteria of the additive material itself; When manufacturing a product, 0.01-5% by weight of acid (pH<4) is mixed with some products to remove not only the miscibility of the adhesive material but also the adhesive and self-retaining bacteria of the composition; Among the above-mentioned calcium chloride and sodium chloride of hydrous nH ₂ O (n=0 to 99) having a solid content of 1 to 100% by weight, they are treated with an acid and a chemical reaction between a heterogeneous aqueous solution, etc. Among the lowered ones, 0-50 wt% of these materials alone or two or more are used; As an ionic compound with a solid content of 5 to 100% by weight - In the ionic compound used in the present invention, a metal cation and a non-metal anion are coupled by electrostatic attraction, and the sum of the charges is electrically neutral. The element may be one or more from the group consisting of Co, Cu, Ni, Mn, Zn, Fe, Al, Be, Mg, Ca, Ba, and the like, and the anionic element is a fluoride anion, a bromide anion, an iodide anion, a sulfide anion , chloride anion, ammonium anion, hydroxide anion, sulfate anion, carbonate anion, nitrate anion, phosphate anion, permanganate anion, acetate ion, hydrogen carbonate anion, borate anion, chromate anion, dichromate anion, halogen anion, hydrochloric acid anion, organic acid anion, etc. may include one or more selected from the group consisting of, and may further include an ammonium salt in consideration of equipment corrosion and solution stability, and in the form of an anhydride, hydrate, or aqueous solution, these substances alone or two or more 2~ 50% by weight or 5 to 100% by weight of solid content The ionic compound uses a +1 cation metal and a -1 valent or a -2 valent anion, and the cationic metal element belonging to this is from the group consisting of Li, Na, K, etc. and at least one selected from among them, the anion element is a fluoride anion, a bromide anion, an iodide anion, a sulfide anion, a chloride anion, an ammonium anion, a hydroxide anion, a sulfate anion, a carbonate anion, a nitrate anion, a phosphate anion, a permanganate anion, and an acetic acid ions, hydrogen carbonate anions, boric acid anions, chromate anions, dichromate anions, halogen anions, hydrochloric acid anions, organic acid anions, etc. were included, and these substances alone in anhydrous form, hydrate form, and aqueous solution form or 0 to 50% by weight of two or more; Solid content 0.1-50 wt % Conductive Polymer (Polythiophene, PEDOT-PSS, Polyaniline, Polypyrrole) 0-50 wt % used or used; Characterized by including the use of 0 to 99% by weight alone or in a mixture of two or more,
Adhesive strength, antistatic, antibacterial/mildew, flame retardant abnormality, increase in weight, impact reinforcement and dispersion, cold resistance, viscosity increase, shortening of drying (curing) time, corrosion prevention, for plastering, 0.0001~7,000㎛ A hydrous aluminum silicate mineral containing alkali or alkaline earth metals with various shapes, a porous structure in which (Si,Al)O4 tetrahedra are combined in a three-dimensional network, and WmZξO2ξ2O compositional formula, W is Na, Ca, Ba, Sr, Z=Si+Al, quartz SiO2, zeolite in which a part of Si in the three-dimensional network structure of infinitely connected diamond tetrahedral structure is replaced by Al, siliceous porous material, lightweight foamed ceramic, Silica, Perlite, Titanium Dioxide, Clay, talc , Aluminum Hydroxide, Kaolin, Magnesium Hydroxide, Calcium Carbonate, Diatomite, Loess, Bentonite, Quartz sand, Gypsum, Lime, cement, Terra alba, Pozzolan, Diatom, Pupl or 1~100 wt% of water (H2O) dispersed solid content Pupl, etc. is used alone or in an amount of 0 to 99% by weight of two or more; Among anionic, cationic and amphoteric surfactants, Ammonium Dodecylbenzenesulfona, Polyoxyethylenenonylphenyl Ether, Polyoxyethyleneoctylphenyl Ether, Sodium Dodecylsulfonate, Sodium Dioctylsulfosuccinate, Sodium Dodecylbenzenesulfonate, Ammonium Dodecylbenzenesulfonate, Ammonium Dodecylbenzenesulfonate, Sodium Alkylaryl Esterlic Dispersant, Soda-based dispersant, Soda-based dispersant, Sodium Alkylaryl Esterlic, Phosphate dispersant Sodium Polycarboxyl Acid; Octylalcohol, Cyclohexane, Polydimethylsiloxan, other higher alcohols or Ethylene Glycol, Span and other nonionic active agents, Silicon defoaming agents; It is characterized in that it contains 0 to 55% by weight of each of at least one type,
For thickening and initial adhesion, cellulose type, alkali swellable type, ester type, urethane compound type, bento type, airgel type, acrylic type, etc., for example, gum arabic, jintan gum, tara gum, guar gum, agar, kera Jinan (carrageenan), sodium alginate, powdered cellulose, cellulose, methylcellulose, HEC, CMC, MC, SD, BT, EHEC, MEHEC, LBG, tararind, arabic, soybean polysaccharide, curdran, gellan, glucomannan, Soda alginate, pectin, carbomer, Hisel, gelatin, polycarboxylic acid, carboxyvinyl polymer, metal ethyl cellulose, potassium alginate, ritextose, sodium carboxymethyl starch, casein, starch; It is characterized in that it contains 0 to 55% by weight of each of at least one type,
For cold-resistant adhesive properties, Dioctyl Phthalate, Dibutyl Phthalate, Ester, etc. are used, preferably Alkyl Ester; It is characterized by including the use of 0 to 20% by weight alone or two or more,
For better antibacterial and anti-rust and anti-corrosive effects after manufacturing or installation, sodium carboxymethylcellulose (CMC), chlorinated 5 Chloro 2 methyl 4 isothiazolin 3 one and unchlorinated 2 Methyl 4 isotiazolin 3 one are mixed together. Organic nitrogen sulfide and strong acids (pH <4) can be used in 0 to 3% by weight, preferably 0 to 2% by weight, respectively, and 3-lodo-2 propynl butyl carbamate (product name: MX-3 Advanced Plus, manufacturer: CONNELL FAMILY INC.), C ₁₁ H ₁₉ NOS (TK-800), UNICOOL-K14 (manufacturer: UCC), NP-40; Characterized by including the use of 0-5% by weight alone or in a mixture of two or more,
Electromagnetic wave absorption and electromagnetic wave blocking, electromagnetic wave shielding (those that exhibit both electromagnetic wave absorption and electromagnetic wave blocking at the same time are called shielding), antistatic. Iron powder, Copper powder, Cobalt powder, Tin powder, Aluminum powder with various shapes such as spherical shape, plate shape, needle shape, etc. of 0.0001~7,000㎛ for antibacterial and anti-mildew, flame retardant, corrosion prevention, electrical conduction, heat conduction (adhesion) electrode usage characteristics , Magnesium powder, Titanium powder, Silicon powder, Nickel powder, Zinc powder, Manganese powder. Soft ferrite such as Silver powder, Ag coated Cu, Ni coated Cu, Indium tin oxide, solder ball (Free lead Tin-Bismuth), silver chloride, Antimony tin oxide, Stainless Steel, Mn (or Mg, Ni, etc.)-Zn ferrite and hard ferrite such as Ba (or Sr, etc.) ferrite, conductive carbon powder and fiber, solid content 1.0-80.0 wt% Conductive carbon sol alone or a mixture of two or more types 0-97.5 wt%, or these metal materials with carboxylic acid It is also characterized in that it can have a feature that can be manufactured into a product having a color by a composition prepared by surface-modifying using a fatty acid or a silane-based material, and composition of 0-90.0% by weight of a surface-modified metal material and an additive material thereof with
The solvent for dispersion is; Content 1~99.9% by weight Methanol, Ethanol, Butanol, Dichloromethane, Ethylacetate, Hexane, Diethylehter, Acetonitrile, Benznene, Dibasic Ester, 1-METHOXY-2-PROPANOL, BC, Diethylene Glycol Monoethyl Ether Acetate, Toluene, Alcohol, H2O, etc cast; It is characterized by mixing 0 to 97% by weight alone or two or more types,
The materials for the above purpose do not matter much in the order of mixing, but it is preferable to mix compositions in approximately the order of resins, solvents, performance-imparting additives, etc., characterized by including at least one material, According to the type of additive material and the mixing ratio of the additive material, the performance of complex or selective performance is first, according to the type of additive, ① electromagnetic wave absorption and electromagnetic wave blocking, ② flame retardant (flame retardant) and semi-noncombustible, ③ corrosion prevention performance, blending ratio It is characterized in that ① electromagnetic wave blocking (electromagnetic wave reduction) and antistatic, ② antibacterial and anti-mildew, ③ freezing temperature change, etc. are selectively or selectively exhibited by the content difference. High-pressure disperser, high-shear mixer (inline mixer, homomixer), premixer (stirrer), homodisperse, homogenizer, (impeller) high-speed stirrer, paste mixer, corotatory mixer, commonly used mixers and stirring devices ( mixing container), feed/aggregate/cement/mortar/concrete mixing machine (for example, a type of powder mixer manufactured by Daekwang Construction Machinery, etc.), crucible heating type, extrusion steam type, extrusion heating type, using single or multiple or more A method for producing a composition, characterized in that it is formulated under the conditions of -15 to 350° C., 1 to 600 minutes, and 1 to 20,000 rpm, and after the operator improves the composition that comes out through the mixing vessel discharge valve after the composition is prepared by the method In addition to the traditional and current manufacturing methods of packaging, automated equipment is used to input raw materials and transfer packaging, and a fully automatic production line such as an in-line/outline PLC-controlled unmanned system, etc., enables packaging to a desired weight by automatic weighing. It is characterized in that it can also be manufactured as (applicable to dry mixing manufacturing), and further, dry mixing is a mixture between two or more types of powder and powder, mainly feed/aggregate/cement/mortar/concrete mixing machine at room temperature below humidity 65%RH However, when mixing in a mixing container (內), it is preferably mixed at a humidity of 0 to 65% RH and a temperature of -10 to 190 ° C. The moisture is removed from the packaging and sealed, and the resin compound is prepared by mixing the above-mentioned additives of the present invention with the resin alone or by mixing two or more types, or the mixed composition is prepared at a processing temperature of 150-350°C using an extruder. 60 to 450 in an injection machine or press equipped with a mold of the shape to be made (to be produced), characterized in that it is formed with resin (hereinafter referred to as resin chempound pellets) to be pelletized in It is characterized in that the product is manufactured at a processing temperature of ℃. In the same manner as above, depending on the type of additive, the mixing ratio of the additive, and the manufacturing method, freeze prevention, antibacterial/mildew, electromagnetic wave absorption, electromagnetic wave blocking, antistatic, flame retardant, A composition that exhibits corrosion prevention and insect repelling performance in a complex, selective and selective manner, an applied product using the composition, and a manufacturing method thereof. The method according to claim 1,
The present invention exhibits all, selective, and selective performance of adhesive strength, anti-freezing, anti-bacterial/mildew, anti-static, flame-retardant, and anti-corrosion performance according to the type of additive material, the type of additive according to the mixing ratio of the additive material, and the adhesive strength according to the mixing ratio of the additive material In order to realize the above purpose, the composition and application products using the composition and application products using the composition and application products using the same to implement;
First, as materials that provide adhesion and appearance, Acrylic, Epoxy, Polyvinyl Alcohol, Polyvinyl Acetate, Silicone, Polyurethane, Ethylenevinyl Acetate, Polyvinyl Chloride, Vinyl Acetate Acrylic Copolymer, Acrylic Copolymer with a solid content of 1 to 100% by weight. Gum Rosin, 2-Ethyl Hexyl Acrylate Monomer, 2-Ethylhexyl 2-Propenoate, 2-Hexyl. Resin, Solution or Acid, Primer, Emulsion, Monomer, Copolymer of 2-EHAM, 2-Ethyl Hexyl Acryl Acid, Butyl Acrylate Monomer, N-Butyl Ester, Butyl 2-Propenoic Chloroprene Rubber, Acid, n-Butylacrylate, Vinyl Acetate Monomer , Resorcinol, α-Olefin, Isocyanate, Phenolic, Thermosoftening Plastic [PVC (Polyvinyl chloride), polyester, PVC sol, PP (Polypropylene), ABS (Acrylonitrile Butadiene Styrene), PMMA (Polymethlmethacrylate), PE (Polyethylene), PET ( Polyethylene Terephthalate), PBT (Polybuthylene Terephthalate), PPS (Polyphenylene Sulfide), PC (PolyCabonate), Nylon, LDPE (Low Density Polyethylene), HDPE (High Density Polyethylene), Polystyrene any one or a mixture of two or more], Thermosetting Plastic (Phenol) , Urea, Melamine, Polyurethane, Unsaturated Polyester, Silicon Resin alone or a mixture of two or more), Starch, Rice, Wheat, Bran, Corn, Potato, Dextrin, Modified starch, Grains such as Glutinous Rice, Nori, Gelidium amansii Seaweed such as LAMOUROUX , grains such as dextrin, modified starches, etc. alone or mixed with two or more substances, powdered grass (using powdered paste such as German H company, Korea E company, K company, Y company), and solid content 1~ 100% free Subtitle of wheatgrass; Characterized by including the use of 1 to 99% by weight alone or in a mixture of two or more,
Adhesive strength strengthening, anti-freezing, anti-bacterial/mildew, anti-static, flame-retardant, corrosion prevention, humidity control, insect repellent, anti-rust performance, etc., which are one of the main purposes of the present invention As a quality, hydrous nH with a solid content of 1 to 100% by weight₂Sodium Chloride, Magnesium Chloride, Calcium Chloride belonging to the metal chlorides of O(n=0~99) (European, African, Asian, North American, South American, Oceanian, especially domestic and Asian acid, etc.) were prepared in the form of a powder or an aqueous solution thereof and contained in an amount of 0 to 50% by weight, or a mixture of two or more of these substances was included; 1 to 100% by weight of solids Salt is edible salt with sodium chloride as the main ingredient, sea salt and industrial salt materials used as chemicals, East Sea, West Sea, South Sea, Mediterranean Coast, Pacific Ocean, Atlantic Ocean, Indian Ocean, Arctic Ocean, Antarctic Ocean, Dead Sea, Black Sea, etc. (Europe, Africa, Asian, North American, South American, Oceania) Salt salt produced in Asia, Europe and West Sea such as USA, Australia (Australia), China, Philippines, Vietnam or Africa, America , produced in salt mines (rock salt) on six continents such as Tibet - The salt of the present invention is largely classified into sea salt and refined salt. Sea salt is a thick, translucent hexagonal crystal made by drawing seawater to a salt farm and evaporating harmful components along with moisture with wind and sunlight. On the other hand, refined salt is a crystal of sodium chloride obtained by electrolyzing seawater to remove impurities and heavy metals with an ion resin film. In Korea, it is produced a lot in the west coast or south coast where the water depth is not deep and the tidal difference is large. Sinan-gun, Jeollanam-do accounts for 65% of the domestic solar salt production and more than half of the salt farm area, and its quality is excellent worldwide. Also, salt containing sulfur that is produced near Baengnyeongdo is considered a commodity. Cheonil Salt Farms in Korea usually consist of a reservoir, an evaporation pond, and a crystallization pond. At high tide, the sluice gate is opened to make concentrated brine in the evaporation pond and send it to the crystallization area to obtain salt crystals. When the wind is strong, the crystals are small, and when the temperature is low, the salt tastes bitter and the quality of salt is poor. The sea salt produced in Korea is alkaline and its salinity is about 88%. Sea salt has a lot of minerals and moisture such as Ca, Mg, Zn, K, and Fe, so it is good for pickling vegetables or fish and is mainly used for making kimchi, soy sauce, and soybean paste. While it contains a lot of minerals that are good for the body, but also contains some toxic substances, it must be removed and consumed. In addition, sea salt has high hygroscopicity due to various minerals and has anti-corruption effect by sterilizing power beyond antibacterial. or 0 to 50% by weight of a mixture of two or more; Magnesium Chloride 15~19%, Magnesium Sulfate 6~9%, Potassium Chloride 2~4%, Sodium Chloride 2~6%, Magnesium Bromide 0.2~0.4%, etc. Solid content 1~69% by weight bittern, or 100g of these or 0 to 50% by weight of 5 to 90% concentration by heating; Where bacteria-inhibiting power is further required, 0-50% by weight of purified salt is included instead of sea salt to secure antibacterial and anti-mildew effects, and in particular, by treating at a high temperature of 100° C. or higher to eradicate all bacteria of the additive material itself; When manufacturing a product, 0 to 5% by weight of an acid (pH<4) of 1 to 100% by weight of solid content (purity) is mixed with some products to remove not only the compatibility of the adhesive material but also the adhesive and self-retained bacteria in the composition. ; Hydrous nH having 1 to 100% by weight of the above-mentioned solids₂Among O(n=0~99) Calcium Chloride and Sodium Chloride by treating them with acid, etc. to generate low corrosive salts or lower corrosiveness by a low chlorination system, 0 to 50% by weight of these substances alone or two or more are included or ; As an ionic compound with a solid content of 5 to 100% by weight - In the ionic compound used in the present invention, a metal cation and a non-metal anion are coupled by electrostatic attraction, and the sum of charges is electrically neutral. - The cationic metal element having a valence of +2 or higher may be one or more from the group consisting of Co, Cu, Ni, Mn, Zn, Fe, Al, Be, Mg, Ca, Ba, and the like, and the anion element is a fluoride anion, bromide Anion, iodide anion, sulfide anion, chloride anion, ammonium anion, hydroxide anion, sulfate anion, carbonate anion, nitrate anion, phosphate anion, permanganate anion, acetate ion, hydrogen carbonate anion, borate anion, chromate anion, dichromate anion, halogen anion , hydrochloric acid anion, organic acid anion, etc. may be mentioned, and may further include an ammonium salt in consideration of equipment corrosion and solution stability, and in the form of an anhydride, hydrate, and aqueous solution The ionic compound contains 0 to 50% by weight of the substance alone or two or more, or 5 to 100% by weight of the solid content The ionic compound uses a +1 cation metal and a -1 valent or a -2 valent anion, and the cationic metal element belonging to this is Li, and at least one selected from the group consisting of Na, K, and the like, and the anion element is a fluoride anion, a bromide anion, an iodide anion, a sulfide anion, a chloride anion, an ammonium anion, a hydroxide anion, a sulfate anion, a carbonate anion, a nitrate anion , phosphate anion, permanganate anion, acetate ion, hydrogen carbonate anion, boric acid anion, chromate anion, dichromate anion, halogen anion, hydrochloric acid anion, organic acid anion, etc. It contained at least one selected from the group consisting of, anhydride form, hydrate form , containing 0 to 50% by weight of alone or two or more of these substances in the form of an aqueous solution; 5 to 100% by weight of the solid content of the ionic compounds in the form of an anhydride, hydrate, or aqueous solution, alone or 1 to 50% by weight of two or more; 1 to 100% by weight of solids produced by mixing two or more of the ionic compounds 0 to 50% by weight of alkaline white basic material, 0.1 to 50% by weight of solids Conductive Polymer (Polythiophene, PEDOT-PSS, Polyaniline, Polypyrrole) 0 to 50% by weight used or one of those; Characterized by including the use of 0 to 99% by weight alone or in a mixture of two or more,
Adhesive strength, antistatic, antibacterial and anti-mildew, flame retardant abnormality, increase in weight, impact reinforcement and dispersion, cold resistance, viscosity increase, shortening of drying (curing) time, anti-corruption, anti-rust, for plastering, 0.0001~7,000㎛ spherical and plate-shaped, needle-like A hydrous aluminum silicate mineral containing alkali metals or alkaline earth metals with various shapes such as_2n2O composition formula, W is Na, Ca, Ba, Sr, Z = Si + Al, quartz SiO₂, Zeolite in which a part of Si in the three-dimensional network structure in which the diamond-shaped tetrahedral structure is infinitely connected is substituted by Al, siliceous porous material, lightweight foamed ceramic, Silica, Perlite, Titanium Dioxide, Clay, talc, Aluminum Hydroxide, Kaolin, Magnesium Hydroxide, Calcium Carbonate, Diatomite, Loess, Bentonite, Quartz sand, Gypsum, Lime, cement, Terra alba, Pozzolan, Diatom, Pulp or water (H₂O) Dispersed solid content of 1 to 100% by weight Pulp, etc. alone or including 0 to 99% by weight of two or more; Among anionic, cationic and amphoteric surfactants, Ammonium Dodecylbenzenesulfona, Polyoxyethylenenonylphenyl Ether, Polyoxyethyleneoctylphenyl Ether, Sodium Dodecylsulfonate, Sodium Dioctylsulfosuccinate, Sodium Dodecylbenzenesulfonate, Ammonium Dodecylbenzenesulfonate, Ammonium Dodecylbenzenesulfonate, Sodium Alkylaryl Esterlic Dispersant, Soda-based dispersant, Soda-based dispersant, Sodium Alkylaryl Esterlic, Phosphate dispersant Sodium Polycarboxyl Acid; Octylalcohol, Cyclohexane, Polydimethylsiloxan, other higher alcohols or Ethylene Glycol, Span and other nonionic active agents, Silicon defoaming agents; It is characterized in that it contains 0 to 55% by weight of each of at least one type,
For thickening and initial adhesion, cellulose type, alkali swellable type, ester type, urethane compound type, bento type, airgel type, acrylic type, etc. i.e., for example, gum arabic, jintan gum, tara gum, guar Gum, agar, kerazinan (carrageenan), sodium alginate, powdered cellulose, cellulose, methylcellulose, HEC, CMC, MC, SD, BT, EHEC, MEHEC, LBG, tararind, arabic, soybean polysaccharide, curdran , gellan, glucomannan, soda alginate, pectin, carbomer, Hisel, gelatin, polycarboxylic acid, carboxyvinyl polymer, metal ethyl cellulose, potassium alginate, ritextose, sodium carboxymethyl starch, casein, starch; It is characterized in that it contains 0 to 55% by weight of each of at least one type,
For cold-resistant adhesive properties, Dioctyl Phthalate, Dibutyl Phthalate, Ester, etc. are used, preferably Alkyl Ester; It is characterized in that it contains 0 to 20% by weight alone or two or more,
For better antibacterial, anti-mildew and anti-corruption effects after manufacturing or installation, solids 1-100 wt% sodium carboxymethyl cellulose (CMC), chlorine-treated 5 Chloro 2 methyl 4 isothiazolin 3 one and non-chlorinated 2 Methyl 4 Organic nitrogen sulfide mixed with isotiazolin 3 one, solid content (purity) 1-100% by weight Hydrochloric acid, sulfuric acid, citric acid, glacial acetic acid, malic acid oxalic acid, etc., each or two or more of strong acids (pH <4), sodium benzoate, borax The mixture may contain 0 to 3% by weight, preferably 0 to 2% by weight, and 3-lodo-2 propynl butyl carbamate (product name: MX-3 Advanced Plus, manufacturer: CONNELL FAMILY INC.), C₁₁H₁₉NOS (TK-800), UNICOOL-K14 (manufacturer: UCC), NP-40; Characterized by including the use of 0-5% by weight alone or in a mixture of two or more, preferably, when using an acidity of 1 to 99 (solids = acidity)% acid (pH <4), the antibacterial, anti-mildew, anti-corruption effect Substance (hereinafter referred to as anti-corruption material) 1: It is characterized in that it contains 0 to 5% by weight in a ratio of 0.1 to 50,
Electromagnetic wave absorption and electromagnetic wave blocking, electromagnetic wave shielding (those that exhibit both electromagnetic wave absorption and electromagnetic wave blocking at the same time are called shielding), antistatic. Iron powder, Copper powder, Cobalt powder, Tin powder, Aluminum powder with various shapes such as spherical shape, plate shape, needle shape, etc. of 0.0001~7,000㎛ for antibacterial and anti-mildew, flame retardant, corrosion prevention, electrical conduction, heat conduction (adhesion) electrode usage characteristics , Magnesium powder, Titanium powder, Silicon powder, Nickel powder, Zinc powder, Manganese powder. Soft ferrite such as Silver powder, Ag coated Cu, Ni coated Cu, Indium tin oxide, solder ball (Free lead Tin-Bismuth), silver chloride, Antimony tin oxide, Stainless Steel, Mn (or Mg, Ni, etc.)-Zn ferrite And hard ferrite such as Ba (or Sr, etc.) ferrite, conductive carbon powder and fiber, solid content 1.0-80.0 wt% Conductive carbon sol alone or a mixture of 2 or more types 0-97.5 wt%, or these metal materials with carboxylic acid It is also characterized in that it can have a feature that can be manufactured into a product having a color by a composition prepared by surface-modifying using a fatty acid or a silane-based material, and composition of 0 to 90.0% by weight of a surface-modified metal material and an additive material thereof. with
The solvent for dispersion is; Content 1∼99.9 wt% Methanol, Ethanol, Butanol, Dichloromethane, Ethylacetate, Hexane, Diethylehter, Acetonitrile, Benznene, Dibasic Ester, 1-METHOXY-2-PROPANOL, BC, Diethylene Glycol Monoethyl Ether Acetate, Toluene, Alcohol, H2O, etc cast; It is characterized in that it contains 0 to 97% by weight alone or two or more types,
The materials for the above purpose do not matter much in the order of mixing, but it is preferable to mix compositions in approximately the order of the resin and the adhesive material, the solvent, the performance-imparting additive material, and the like, and it is characterized by including at least one material.
Therefore, the main purpose of the present invention is the performance of complex or selective/selective performance depending on the type of additive and the blending ratio of the additive, first by the difference in the content of the blending ratio, ① strengthening of adhesion and changing the freezing temperature, ② antibacterial and anti-mildew, ③ surface resistance 10³~10⁶⁽⁵⁾Blocking electromagnetic waves in Ω/□, 10⁶⁽⁵⁾~10⁹In Ω/□, antistatic performance, according to the type of additive, ① electromagnetic wave absorption and electromagnetic wave blocking, ② flame retardant (flame retardant) and semi-non-flammable, ③ corrosion prevention performance ④ adhesion strength ⑤ humidity control, rust prevention, etc. It is characterized by performance.
In addition, wet mixing is a high-pressure disperser, high-shear mixer (in-line mixer, homomixer), premixer (stirrer), homodisperse, homogenizer, (impeller) high-speed stirrer, paste mixer, corotatory mixer, etc. in a reaction tank or mixing vessel. , commonly used mixers and stirring devices (mixing containers), feed/aggregate/cement/mortar/concrete blenders (eg, types of powder mixers manufactured by Daekwang Construction Machinery, etc.), existing (current) crucible heating type or extrusion steam A method for producing a composition, characterized in that it is formulated in a production method under the conditions of -15 to 350° C., 1 to 600 min, and 1 to 20,000 rpm, using single or multiple methods such as a formula, an extrusion heating device, and a production device developed in the present invention, and In addition to the traditional and current manufacturing methods in which an operator improves and packs the composition that comes out through the mixing vessel discharge valve after the composition is manufactured by the above manufacturing method, raw material input and packaging transfer using automation equipment, inline/outline PLC control It is characterized in that it can be manufactured by a manufacturing method (applicable to dry mixing manufacturing) that can be packaged at a desired weight by automatic weighing by establishing a fully automatic production line such as an unmanned system. Furthermore, in dry mixing, a feed/aggregate/cement/mortar/concrete blender was mainly used at room temperature below 65%RH for mixing between two or more types of powder and powder, but preferably humidity when mixing in a mixing container Mixing at 0 to 65% RH, temperature -10 to 190° C., removing moisture from the powder composition, and sealingly packaging. Or, it is characterized in that the mixed composition is formed into a resin (hereinafter referred to as a resin compound pellet) that is pelletized at a processing temperature of 150 to 350° C. using an extruder, and to make it also It is characterized in that the product is manufactured at a processing temperature of 60 to 450°C in an injection machine or press equipped with a mold of the shape of (to be produced).
And another most important feature of the present invention is that it provides a production method in consideration of the improvement of the worker's working environment and productivity in addition. Looking at the dobae grass (wheat grass), which is one of the manufacturing compositions of the present invention, it is known that the previous or current dobae grass production lines can threaten the health of workers by the dust generated from the raw material input household. As a way to solve this, work clothes and a mask are provided as a way to minimize the exposure of workers, and as a method to fundamentally solve the present invention, the raw material input is made through the absorption pipeline or is currently open (open, outside without a lid) It is also an important feature to cover the exposed manufacturing container with a lid and to provide a raw material input port for adding flour to a part of the lid to fundamentally block the health of workers and the threat of explosion caused by dust caused by dust generated during input.
In the case of mixing a material that imparts the functionality of the present invention to the previously prepared adhesive such as PVA, the composition and mixing are carried out under the conditions of -10 to 70° C., 0.5 to 30 min, 0.01 to 100,000 rpm, and 0.5 to 5 atm, and then packaging do,
On the other hand, it is a manufacturing method that puts water and flour in a container and stirs it while heating it with a heat source to produce an adhesive composition and material, or to increase the production amount. ), a mixing solution (mixed liquid solution) is first prepared under the conditions of 0~70℃, 0.5~30min, 0.01~100,000rpm, 0.5~5 atm, and this mixing solution is placed in a larger container than the previous container (mixer). , Preferably, it is transferred to a container twice or more, and as a means for breaking the transferred mixing solution, it is 50 to 120 ° C, 0.1 to 5 atm. A heat conduction tube, heat conduction sheet, or drum equipped with a heat source such as oil, steam, water, gas, electricity, etc., made with a viscous composition, adhesive material, or wheat paste while slowly stirring and heating, or heated to 70∼500°C by 0.01∼10min instantaneous heating method It was prepared by passing through the back. The container used here is preferably corrosion-resistant stainless steel, cast iron, carbon steel, etc., but inexpensive plastic materials were used for general metals and packaging. The manufactured high-temperature adhesive composition and material are immediately packaged at the same time as the prepared composition and material are discharged through the tube of the above-mentioned example, or a device for cooling to 40° C. or less for easy packaging (sheets, drums, containers preferably drum) was passed through or packed, and then packaged. In particular, when a drum is used as a cooling device, a knife or bar type is installed on one side of the drum so that if agglomerated adhesive material occurs, the agglomeration is resolved, and it is transported and packaged through the tube. In this case, it is passed through a mesh such as a mesh to prevent the agglomerated adhesive composition and material or mixing solution from passing to the next step process, and when it is closed in another container, one or more packaging pipes are installed at the bottom of the container. As another example, in the present invention, in a method that costs little, if it is manufactured by using an onion net in front of the mixing liquid transfer pipe, it is possible to simply eliminate the agglomeration going to the next step process. It is also a feature belonging to another example.
In the same way as above, depending on the type of additive, the mixing ratio of the additive, and the manufacturing method, the adhesive strength is strengthened, freeze prevention, antibacterial/mildew, electromagnetic wave absorption, electromagnetic wave blocking, antistatic, flame retardant, corrosion prevention, humidity control, insect repellent, rust prevention performance We have developed a composition that exhibits complex, selective, and selective effects, and application products using the same.
15 to 55% by weight of each mixture of 1 to 2 or more of Acrylic Emulsion, Polyvinyl Acetate, and Polyvinyl Chloride having a solid content of 1 to 65% by weight, H₂O 65-84 wt%, 0thers 1-10 wt% composition to 2-EHAM: BAM = 2-3:1 ratio 30-99 wt%, CaCO₃ 10-50% by weight, H₂O 10-60% by weight, others 0.01-5% by weight Mixed composition or acrylic copolymer 45-55% by weight, CaCO₃ 30-40%, H₂O 10-20 wt%, Gum Rosin 5-10 wt%, 0thers 1-70 wt% Acrylic sealant or silicon sealant alone or 2 or more types 0-90 wt% in 1 to 90 wt% of 1 to 2 or more in the composition create; - Others are substances that correspond to the above-mentioned electromagnetic wave shielding, weight increase, impact reinforcement and aesthetics, dispersion, cold resistance, viscosity increase, dispersing agent, etc. - 0∼20 wt% of calcium chloride powder, 0∼ 20% by weight, conductive carbon powder and fiber 0 to 30% by weight, solid content 1 to 80% by weight 0 to 80% by weight of conductive carbon sol Adhesive that exhibits the main function of electromagnetic wave blocking and antistatic performance, either alone or in combination As a result of the evaluation as follows, the adhesive properties and workability were good as well as excellent electrical properties. Test standard ANSI/ESD STM 11.11-2015, test environment 23℃, 50%RH, Resistance Meter (Manufacturer Trek) Model As a result of measuring with 152, 10 satisfying cleanroom SPEC.⁴~10⁶Ω/□. After the antistatic tile construction with the composition of the present invention, the result of measuring the surface resistance was photographed and shown in FIG. 1 . As a result of measuring the surface resistance after on-site construction, 10 at 45%RH⁵As it turned out to be Ω/□, it was confirmed that the antistatic tile constructed with the composition of the present invention satisfies the cleanroom construction SPEC. 1 is a scene in which A company clean room is constructed with the composition of the present invention, first dried in order to check the conductivity of the adhesive of the present invention, and the resistance is measured in the center of FIG. 1 , and is shown at the bottom of FIG. Given that, when the antistatic tile is adhered with an adhesive having electrical characteristics for the (clean room) floor construction to reduce static electricity, static electricity generated from the human body or equipment during work passes through the antistatic tile, the adhesive of the present invention, and the ground terminal It is exhibited as another feature to become an antistatic floor (clean room) that escapes through and exhibits antistatic (static prevention) properties. And the surface resistance meter used after construction is Wolfgang Warmbier's Surface Resistance Meter SRMⓡ110/Made in EURO.
And Figure 2 is evaluated by requesting a test research institute A, after manufacturing 2-30% by weight of carbon sol in the PVA, ANSI/ESD STM 11.11-2015, test environment 23℃, 50%RH, Resistance Meter (Manufacturer Trek) As a result of measurement with Model 152, the surface resistance is 1.05×10⁴∼1.23×10⁴As Ω/□, it can be seen that the adhesive has electromagnetic wave blocking properties.
And, for evaluation of the adhesive strength of the composition adhesive of the present invention, which is one of the most important characteristics, adhesive strength evaluation was performed at room temperature 23°C and low temperature 10°C, respectively, for 2hr, 4hr, 24hr, and 168hr after bonding. It was carried out at ℃, 45%RH, and the open time before bonding was 20 min. After unification, the results are shown in Table 5.
After preparing 2 to 30% by weight of carbon sol with a solid content of 1 to 80% by weight in an acrylic emulsion with a solid content of 1 to 65% by weight, gravure printing this with 80 rolls on a paper medium is applied. 3 is shown. And the actual construction scene of the apartment with a product made of carbon sol in acrylic emulsion as the main adhesive is shown in FIG. 4 . As described above, the composition of the present invention is an example showing the variety of application fields by being characterized in that it can be used in various application products and actual construction. And as a result of measuring the surface resistance by requesting the construction product to K Test Research Institute, 2.5 × 10⁶Ω/□, which is shown in FIG. 4 .
In addition, the Republic of Korea Patent Application Nos. 10-0526673 and 10-0522267 mentioned above in the technology that is the background of the invention, mainly, "There is no specific technology for the conductive carbon black (conducting carbon) used and the adhesive." First, carbon It can be said that it is a living material that has been used for a long time. Carbon black is one of the materials that have been used in various ways ranging from ink, ink, rubber reinforcing agent, etc., and activated carbon is used as a deodorant, solvent recovery, and catalyst. Here, carbon is produced by thermal decomposition or incomplete combustion of hydrocarbons. The manufacturing method is divided into pyrolysis method and incomplete combustion method. Depending on the manufacturing method, it has various uses due to its high surface area and unique surface. About 85% of carbon consumption is for rubber, and about 11% is used for printing ink and conductive carbon. Carbon is a structure in which layers of a carbon hexagonal net of graphite-like structure are overlapped and connected in a chain shape. In the case of graphite, there are three lines per atom. The layer lattice of graphite structure with weak van der waals force between layers and strong covalent bonds within the layers is anisotropic in physical properties, and the dotted line shown in FIG. (pi bonds, π bonds) are responsible for the conduction of electricity through graphite. A pi bond is a chemical bond caused by the overlapping of electron orbitals of each atom adjacent to each other in a molecule. Unlike a sigma bond, a pi bond is centered on the x-axis or y-axis, so the electron density on the z-axis connecting both atomic nuclei is zero. The pi bond is named from the Greek letter (π) meaning p orbital. And the valence electron is the outermost electron of an atom, and plays the biggest role in determining molecular bonds and chemical properties. A carbon atom in the neutral state has 4 valence electrons. 3 out of 4 valence electrons of carbon are used, and there is one free electron that does not participate in bonding in carbon having a graphite (carbon) structure. By these free electrons, graphite becomes a conductor and such conductive graphite (carbon) - One of CNT, graphene, modified graphite or xGnP - is one of the main functional materials used in the present invention. The microstructure is needle-like, plate-like, or cubic, and a particle size of 0.0001 to 25 μm was used.
Another one of the mixing ratios of the present invention is 10 to 35% by weight of starch, 70 to 100% by weight of solids, 0 to 40% of chloride, 1 to 100% by weight of solids, 5 to 40% by weight of salt, and 30 to 95% by weight of water. The composition is heated/mixed at 70-350° C., 1-60 min. A pool with a viscosity of 1,000 to 500,000 cps (using Brookfield RV DV-II + PRO) was prepared under the conditions of 1 to 20,000 rpm. In the case of construction using the prepared glue, it was additionally mixed with water 10 to 0.3 times (eg, wallpaper). At this time, the prepared and used glue was dried and the surface resistance was measured at 45%RH at 10⁵~10⁹As Ω/□, it was confirmed that it had antistatic properties and electromagnetic wave blocking properties. The measuring instrument used at this time was Wolfgang Warmbier's Surface Resistance Meter SRMⓡ110/Made in EURO to evaluate the resistance. As shown in Figure 6, test conditions, applied voltage 500V, 60 sec, 20℃, 65%RH, test equipment is TOA SME-8511, D_One=1.96 cm, D₂= 5.1×10 as a result of measurement based on 2.41 cm⁷Ω/□ (half-life 1.5 sec), 4.3×10⁸A resistance value of Ω/□ (half-life of 2.1 sec) was obtained.
In particular, one of the mixing ratios of the present invention is 60 to 83% by weight of solids 20% by weight, adhesive substances, 48% by weight of solids, 11% by weight of chlorides, 25% by weight of solids, 6% by weight of salt solution, and other H₂By manufacturing an adhesive and coating material containing O, each box was coated with wallpaper using the general paper glue (referring to the existing or currently marketed paper glue) and the paper glue of the present invention in each box, and then the degree of electric field reduction was measured. One result is shown in FIG. 7 . As shown in Fig. 7, it was confirmed that the measured value of PULSE's E-tester before construction was 575V/m, but after construction, it was confirmed that the place where the internal construction was performed at 0V/m is going to 0 due to the attenuation of the electric field. If the manufacturing adhesive material has three or less sides, such as a box, when the coating layer of the present invention is grounded to the ground terminal using a material that conducts electricity, the electric field (static electricity) accumulated in the coating layer (surface) escapes through the ground terminal. In case of coating (painting) on more than 4 sides, the electric field is reduced by the phenomenon that the electric field is reduced to zero (0) like the inside of a metal.
Under the same conditions as in Fig. 8, the measured value of PULSE's E-tester before painting was 346V/m, but after painting, it was 11V/m. In the sample (Fig. 9), the measuring instrument ALPHA LAB. As a result of measuring using a TriField meter (ELF-1kHz), it was over 1,000V/m, which is an area that could not be measured due to excessive generation of electromagnetic waves before coating, but it was measured at 20V/m after coating.
“The electric charge inside the conductor does not move, and the electric field inside the conductor is zero. The absence of an electric field in a conductor is not because the electric field cannot penetrate the metal, but because the free electrons in the conductor stop moving and can 'stop' only when the internal electric field is zero. As the charged metal spheres exert a pushing force, the electrons move as far apart as possible from each other, and the electrons are uniformly distributed on the surface of the sphere. If you place a positive charge exactly in the center of the sphere, you will not receive any force. The electrons on the left side of the sphere pull the charge to the left, while the electrons on the right side of the sphere pull the charge to the right with an equal force. The force acting on the charge is zero. Therefore, the electric field is also zero. If the conductor is not spherical, the charge distribution is not uniform, but - if it is a cube - most of the charge is concentrated at the edges. It is the same principle as the concentration of electric charge and force at a sharp point, but the distribution of electrons on the faces and edges is made so that the electric field becomes zero anywhere in the cube. If there is an electric field inside the conductor, the free electrons inside the conductor will start to move. Until equilibrium is reached, the positions of all electrons move until the electric field inside the conductor is zero. Therefore, regardless of its shape, the interior of a metal has zero electric field. In the initial state, assuming that there is an electric charge and an electric field in the conductor, the presence of an electric field means that there is a movement of the electric charge. The electric charges in the conductor start to move under the influence of the electric field, and the movement of the electric charges moves in the direction that makes the electric field within it zero and continues until it becomes zero, i.e., there are no more electric charges moving. . If the electric field in the conductor does not become zero, the charges move under a force until the electric field becomes zero. This movement causes all the charges to gather on the surface of the conductor and is forced outward, where it can no longer move. This is the metal sphere theory (the theory first mentioned by the inventor) (see Figure 10), and is why the electric field on the surface of a conductor is always perpendicular to the surface. The inside moves continuously to become a (-) ion environment. Based on this theory, the present inventor thinks that electronic components are put in a shielding bag such as an aluminum bag, etc. , it is judged that this also used the principle of the metal sphere.”
11, 12, 13, and 14, a commonly used Donggeun fluorescent lamp is installed at a height of 2.3 m equal to or similar to the height of an apartment from the floor to the ceiling, and is located at a position 1.0 m away from the floor, which is usually the height of a child. The electromagnetic wave measuring instrument HI-3604 was connected to the frequency counter (FC-1022), and the HI-3604 was displayed as an analog waveform, and pictures were sequentially captured after shooting a video. The electric field observed by the measuring instrument before construction (painting) was 90-100V/m, and it was found that a significant amount of the electric field was generated even when the light was off. An actual measurement result showing that it is not is obtained, and it is shown by shooting and capturing a video.
And the apartment in which they actually reside was mass-produced and manufactured in a pool manufacturing plant in the same proportion (content) as the composition of the present invention, and the interior of the apartment was painted. In the apartment rooms 1, 2, 3, living room, kitchen, etc., the degree of electric field generation before and after painting was measured and shown in FIG. to /m, Zone 2 from 160V/m pre-padding to 99V/m after coating, Zone 3 from 258V/m before coating to 73V/m after coating, Zone 4 to 69V/m before coating The electromagnetic wave environment was improved with an electric field of 48V/m after painting. As such, the attenuation rate fell in the area where the difference in the attenuation rate was mainly absorbed by the ceiling. It could be seen that the electromagnetic wave attenuation environment was improved as the
In Example 3, a composition (composition 1) in which 3.5 to 12% by weight of salt in an antistatic material is mixed with an adhesive material with a solid content of 3 to 65% by weight, and 5 to 10% by weight of seawater (collected in July in the East Sea) are mixed As shown in Table 7, the surface resistance and half-life of the composition (composition 2) and the composition (composition 3) prepared by mixing 6-30 wt% of Mn-Zn ferrite (soft-1) in the metal powder are shown. together. The composition containing salt and the composition containing seawater are 10⁶~10⁷It was as low as Ω/□, and the composition containing ferrite, an insulator, has a high resistance value, but ferrite is a composition that absorbs a magnetic field rather than an electric field to dissipate heat by resonance and shield it.
An antibacterial test, which is another object of the present invention, was performed on the compositions, and the results are shown in Table 8. According to the results of the antibacterial test, - In Japan, children's products should be 70% or less. This is because the high antibacterial activity can eradicate all bacteria and may have a rather bad effect, but in Korea, antibacterial activity of 90% or more is preferred. - As a result of measuring the antibacterial rate against E. coli strain by KS K 0693-95, composition 1 and composition 2 obtained more than 90% antibacterial value, and composition 3 obtained more than about 30% antibacterial value. Salt, which is the main material in the present invention, does not give a chance for various germs, bacteria or microorganisms to reproduce, and has properties that do not change even after a long time. Salt dissolves well in water, so it penetrates and mixes well with other substances. Salt leads the metabolism in the human body by decomposing food and excreting wastes. The biggest cause of harm to human health may be poor metabolism. It is said that when the metabolism of pushing out old things and accepting new things in cells does not work smoothly, the blood becomes acidic and immunity is weakened, which increases the risk of disease. Intake of salt before and after surgery is said to speed up wound healing, which would prove that salt plays an important role. Ringer's solution is also Na⁺ 130, K⁺ 4, Ca²⁺ 3, Cl^- 109, which is similar to the human body ≒ seawater ratio. Salt quickly restores dead or destroyed cells. As described above, due to the beneficial action of salt (salt), it has lower antibacterial activity than herbicides, but the salt (according to the present invention) material is beneficial to the human body. In the antibacterial experiment of the present invention, the bacterial solution was shaken and incubated at 25° C. for 24 hours, and the number of bacteria was measured (running frequency: 150 times/min). ATCC25922 was used.
Materials that provide adhesion and appearance include Acrylic, Epoxy, Polyvinyl Alcohol, Polyvinyl Acetate, Silicone, Polyurethane, Ethylenevinyl Acetate, Polyvinyl Chloride, Vinyl Acetate Acrylic Copolymer, Acrylic Copolymer with a solid content of 1 to 100% by weight. Gum Rosin, 2-Ethyl Hexyl Acrylate Monomer, 2-Ethylhexyl 2-Propenoate, 2-Hexyl. Resin, Solution or Acid, Primer, Emulsion, Monomer, Copolymer of 2-EHAM, 2-Ethyl Hexyl Acryl Acid, Butyl Acrylate Monomer, N-Butyl Ester, Butyl 2-Propenoic Chloroprene Rubber, Acid, n-Butylacrylate, Vinyl Acetate Monomer , Resorcinol, α-Olefin, Isocyanate, Phenolic, Thermosoftening Plastic [PVC (Polyviny chloride), polyester, PVC sol, PP (Polypropylene), ABS (Acrylonitrile Butadiene Styrene), PMMA (Polymethlmethacrylate), PE (Polyethylene), PET ( Polyethylene Terephthalate), PBT (Polybuthylene Terephthalate), PPS (Polyphenylene Sulfide), PC (PolyCabonate), Nylon, LDPE (Low Density Polyethylene), HDPE (High Density Polyethylene), Polystyrene any one or a mixture of two or more], Thermosetting Plastic (Phenol) , Urea, Melamine, Polyurethane, Unsaturated Polyester, Silicon Resin alone or a mixture of two or more), Starch, Rice, Wheat, Bran, Corn, Potato, Dextrin, Modified starch, Grains such as Glutinous Rice, Nori, Gelidium amansii Seaweed such as LAMOUROUX , materials manufactured from grains such as dextrin, modified starch, etc., powdered grass (using powdered glue such as German H company, Korea E company, K company, Y company); Use 1 to 99% by weight alone or in a mixture of two or more,
The metallic substances used are 0.0001∼7,000㎛ spherical, with various shapes such as plate, needle, etc. Iron powder, Copper powder, Cobalt powder, Tin powder, Aluminum powder, Magnesium powder, Titanium powder, Silicon powder, Nickel powder, Zinc powder, Manganese powder. Soft ferrite such as Silver powder, Ag coated Cu, Ni coated Cu, Indium tin oxide, solder ball (Free lead Tin-Bismuth), silver chloride, Antimony tin oxide, Stainless Steel, Mn (or Mg, Ni, etc.)-Zn ferrite and hard ferrite, such as Ba (or Sr, etc.) ferrite. The added polymer of the activator has a surface resistance of 10⁹When used alone with more than Ω/□, the antistatic performance is poor. - For this reason, spherical and flake-shaped (or plate-shaped) metal materials with a particle diameter of 0.001-25㎛ are surface-modified using carboxylic acid, fatty acid, and silane, and 3.5-90.0% by weight of the surface-modified metal material is added to the polymer. As a result of evaluating the electric and magnetic field characteristics in the state of dispersing and dispersing the crystalline metal material on the surface (manufactured in the form of a sheet for measurement), it exhibits amorphous properties and acts as a broadband electric and magnetic field shielding agent. 10 surface resistance^-3~10¹³It is measured in Ω/□, and it can be used in a wide range from conductors to insulators depending on the metal material and content used. The shielding effect is defined as the ratio of the received power received through the specimen to the incident power. For a constant incident power, the difference in the received power when the material to be tested is installed on the measuring jig and when it is not, that is, insertion loss. By measuring the shielding effect can be measured. The theoretical shielding effect was calculated by Schelkunoff et al. by dividing the signal transmitting and receiving parts by an infinitely large shielding surface, and considering the reflection, absorption, and transmission processes of electromagnetic waves perpendicular to the shielding surface. Calculation of the shielding rate (%) is shown by the effective shielding value (dB) obtained in the following FIGS. 16, 17, and Table 9.
Through the above experiment, - Mn-Zn ferrite (Soft-1, Table 10, Fig. 18) of the metal material is used to absorb the magnetic field and then convert it into heat to remove it - Depending on the additive material and the mixing ratio The absorption area and absorption power of the magnetic field are different, and the greater the content of the metal material with respect to the magnetic field, the better the shielding effect. A magnetic field absorbing composition was prepared by mixing 5 to 30% by weight of soft ferrite with a polymer material based on the total weight. It was found that the prepared composition sheet acts as an amorphous material by adding it in a powder state, and thus the area capable of shielding electromagnetic waves is broadened. It can be seen that FIG. 19 shows a shielding rate of 20 to 45% in the entire area of the 10 to 1000 MHz band (measurement standard: D4935-99 Standard Test method for Measuring the Electromagnetic Shielding Effectiveness of Planar Materials), which is the measurement area.
And the Republic of Korea Patent Application No. 10-2000-0068297, which was mentioned in the technology that is the background of the invention, solves "the problem of difficulty in manufacturing a commercial product due to the occurrence of layer separation due to the use of a high-density radio wave absorber and high viscosity" Here's how to do it: Layer separation occurs when high-density powder and polymer have poor miscibility. As a solution to this, hydrophilic powder was modified using a surface treatment agent for hydrophobic treatment, for example, a carboxylic acid-based, fatty acid, and silane-based surface treatment agent. In addition, the composition, which is difficult to disperse due to high viscosity, was dispersed using a thress roll mill (three-roll mill or three-roll mill). When the number of passes of powder was 2 or less, agglomerated parts were present (FIG. 20), but a composition suitable for application could be prepared by passing 3 to 10 times or adding a solvent during the pass (FIG. 21). The experimental photos were taken and shown in FIGS. 20 and 21 .
Acrylic, Epoxy, Polyvinyl Alcohol, Polyvinyl Acetate, Silicone, Polyurethane, Ethylenevinyl Acetate, Polyvinyl Chloride, Vinyl Acetate Acrylic Copolymer, Acrylic Copolymer with a solid content of 1 to 100% by weight. Gum Rosin, 2-Ethyl Hexyl Acrylate Monomer, 2-Ethylhexyl 2-Propenoate, 2-Hexyl. Resin, Solution or Acid, Primer, Emulsion, Monomer, Copolymer of 2-EHAM, 2-Ethyl Hexyl Acryl Acid, Butyl Acrylate Monomer, N-Butyl Ester, Butyl 2-Propenoic Chloroprene Rubber, Acid, n-Butylacrylate, Vinyl Acetate Monomer , Resorcinol, α-Olefin, Isocyanate, Phenolic, Thermosoftening Plastic, Thermosetting Plastic, Starch, Rice, Wheat, Bran, Corn, Potato, Dextrin, Modified starch, Grains such as Glutinous Rice, Nori, Gelidium amansii Seaweed such as LAMOUROUX, Dextrin substances manufactured from grains, modified starch, etc., powdered grass (Germany H company, Korean company E, K company, Y company, etc.) of 1 to 99% by weight alone or a mixture of two or more,
Hydrous nH with a solid content of 1 to 100% by weight₂O (n = 0 to 99) metal chloride powder or its aqueous solution in the form of 0 to 50% by weight or used alone or in a mixture of two or more of these substances 0 to 50% by weight; Solid content 1-100% by weight Salt is edible salt containing sodium chloride as the main component, sea salt and industrial substances used as chemicals, and rock salt alone or in a mixture of 0-50% by weight; 0-50 wt% of bittern or 100 g of these heated and concentrated 5 to 90% is used; Use 0-50% by weight of purified salt instead of sea salt to secure antibacterial and anti-mildew effects, especially by treating at a high temperature of 100°C or higher to eradicate all bacteria of the additive material itself; When manufacturing a product, 0 to 5% by weight of an acid (pH<4) of 1 to 100% by weight of solid content (purity) is mixed with some products to remove not only the compatibility of the adhesive material but also the adhesive and self-retained bacteria in the composition. ; Hydrous nH having 1 to 100% by weight of the above-mentioned solids₂Among O(n=0~99) Calcium Chloride and Sodium Chloride, they are treated with a chemical reaction between acid and heterogeneous aqueous solution to generate low corrosive salts or among those whose corrosiveness is lowered by a low chlorination system, these substances alone or two or more 0 to 50% by weight is used; In addition, 5 to 100% by weight of solid content ionic compounds are used alone or 0 to 50% by weight of two or more of the ionic compounds in anhydrous form, hydrate form, or aqueous solution form; Solids 0.1 to 50% by weight Conductive Polymer 0 to 50% by weight of either used; Use 0 to 99% by weight alone or in a mixture of two or more,
solvent; Content 1∼99.9 wt% Methanol, Ethanol, Butanol, Dichloromethane, Ethylacetate, Hexane, Diethylehter, Acetonitrile, Benznene, Dibasic Ester, 1-METHOXY-2-PROPANOL, BC, Diethylene Glycol Monoethyl Ether Acetate, Toluene, Alcohol, H₂O, etc; Used alone or in a mixture of 0 to 97% by weight of two or more,
Iron powder, Copper powder, Cobalt powder, Tin powder, Aluminum powder, Magnesium powder, Titanium powder, Silicon powder, Nickel powder, Zinc having various shapes such as 0.0001~7,000㎛ spherical shape, plate shape, needle shape, etc. in the above single or mixed adhesive composition powder, Manganese powder. Soft ferrite such as Silver powder, Ag coated Cu, Ni coated Cu, Indium tin oxide, solder ball (Free lead Tin-Bismuth), silver chloride, Antimony tin oxide, Stainless Steel, Mn (or Mg, Ni, etc.)-Zn ferrite and 0 to 99% by weight of one or more hard ferrites such as Ba (or Sr, etc.) ferrite alone or mixed to absorb electromagnetic waves, block electromagnetic waves, antistatic, antibacterial/mildew, flame retardant, freeze prevention, corrosion prevention, humidity As a result of manufacturing and evaluation of adhesives that exhibit control and rust prevention performance, 10^4-6It is shown in FIG. 22 that it has Ω/□.
The samples prepared according to Examples 1, 2, and 3 are mainly for the purpose of reducing the electric field among electromagnetic waves, and the purpose of this Example and Examples 4 and 5 is to absorb and remove electromagnetic waves from the viewpoint of the magnetic field.
Measurements are performed using the instrument Network Analyzer Mod. Using MS46322A, specification 10MHz~20GHz, Tell Cell DC~5GHz, the following test sequence was carried out. ① Install the equipment as shown in FIG. 23 before measuring the absorption rate of the measurement sample. ② Adjust the height of the sample stand and the antenna to the same height. ③ Turn on the power of the measuring equipment and preheat for 30 minutes and set up the equipment necessary for measurement. ④ When calibration is performed, the value of the measuring device is fixed at 0 dB. ⑤ If it is not fixed to 0 dB, check the height of the sample mount and antenna and set it to 0 dB. ⑥ When the calibration of the measuring equipment is finished, the sample is mounted on the sample mounting table and fixed as shown in FIG. 24 . ⑦ At this time, be careful not to move the sample holder. ⑧ After checking whether the value at 0 dB has changed in the measuring device, write it in the data sheet and save it.
Through the above procedure, the test method IEEE-SDT-1128-1998, the test environment temperature 23 ℃, humidity 44% RH, the absorption rate measurement results for six main several frequencies are shown in Table 11. As shown in Table 11, it can be seen that the product (measurement sample) manufactured using the metal powder exhibits an effect on the magnetic field.
Acrylic, Epoxy, Polyvinyl Alcohol, Polyvinyl Acetate, Silicone, Polyurethane, Ethylenevinyl Acetate, Polyvinyl Chloride, Vinyl Acetate Acrylic Copolymer, Acrylic Copolymer with a solid content of 1 to 100% by weight. Gum Rosin, 2-Ethyl Hexyl Acrylate Monomer, 2-Ethylhexyl 2-Propenoate, 2-Hexyl. Resin, Solution or Acid, Primer, Emulsion, Monomer, Copolymer of 2-EHAM, 2-Ethyl Hexyl Acryl Acid, Butyl Acrylate Monomer, N-Butyl Ester, Butyl 2-Propenoic Chloroprene Rubber, Acid, n-Butylacrylate, Vinyl Acetate Monomer , Resorcinol, α-Olefin, Isocyanate, Phenolic, Thermosoftening Plastic, Thermosetting Plastic, Starch, Rice, Wheat, Bran, Corn, Potato, Dextrin, Modified starch, Grains such as Glutinous Rice, Nori, Gelidium amansii Seaweed such as LAMOUROUX, Dextrin 1~99% by weight of materials manufactured from grains, modified starch, etc., powdered grass (using powdered paste such as German company H, Korea company E, company K, company Y, etc.) do,
Hydrous nH with a solid content of 1 to 100% by weight₂Sodium Chloride, Magnesium Chloride, Calcium Chloride, etc. belonging to the metal chloride of O (n = 0 to 99), powder or aqueous solution thereof is prepared and used in an amount of 0 to 50 wt % use % or; Solid content 1-100% by weight Salt uses 0-50% by weight of edible salt containing sodium chloride as the main component, sea salt and industrial salt materials used as chemicals, rock salt, or refined salt alone or in a mixture of two or more; Magnesium Chloride 15~19%, Magnesium Sulfate 6~9%, Potassium Chloride 2~4%, Sodium Chloride 2~6%, Magnesium Bromide 0.2~0.4%, etc. Solid content 1~69% by weight bittern, or 100g of these 0 to 50% by weight of 5 to 90% concentration by heating; Mixing 0-5% by weight of an acid (pH<4) of 1-100% by weight of solid content (purity) to remove not only the miscibility of the adhesive material but also the adhesive and self-retained bacteria of the composition; Hydrous nH having 1 to 100% by weight of the above-mentioned solids₂Among O(n=0~99) Calcium Chloride and Sodium Chloride, they are treated with a chemical reaction between acid and heterogeneous aqueous solution to generate low corrosive salts or among those whose corrosiveness is lowered by a low chlorination system, these substances alone or two or more 0 to 50% by weight is used;
In addition, 5 to 100% by weight of the solid content of the ionic compound is used alone or 0 to 50% by weight of two or more of the ionic compound in the form of an anhydride, hydrate, or aqueous solution; Solids 0.1 to 50% by weight Conductive Polymer 0 to 50% by weight of either used; Use 0 to 99% by weight alone or in a mixture of two or more,
0.0001~7,000㎛ Water-containing aluminum silicate mineral containing alkali metal or alkaline earth metal with various shapes such as spherical and plate-like, needle-like, zeolite substituted with Al, siliceous porous material, lightweight foamed ceramic, Silica, Perlite, Titanium Dioxide, Clay, talc, Aluminum Hydroxide, Kaolin, Magnesium Hydroxide, Calcium Carbonate, Diatomite, Loess, Bentonite, Quartz sand, Gypsum, Lime, cement, Terra alba, Pozzolan, Diatom, Pupl or water (H₂O) 1 to 100% by weight of the dispersed solid content Pupl or the like is used alone or 0 to 99% by weight of two or more; Among anionic, cationic and amphoteric surfactants, Ammonium Dodecylbenzenesulfona, Polyoxyethylenenonylphenyl Ether, Polyoxyethyleneoctylphenyl Ether, Sodium Dodecylsulfonate, Sodium Dioctylsulfosuccinate, Sodium Dodecylbenzenesulfonate, Ammonium Dodecylbenzenesulfonate, Ammonium Dodecylbenzenesulfonate, Sodium Alkylaryl Esterlic Dispersant, Soda-based dispersant, Soda-based dispersant, Sodium Alkylaryl Esterlic, Phosphate dispersant Sodium Polycarboxyl Acid; Octylalcohol, Cyclohexane, Polydimethylsiloxan, other higher alcohols or Ethylene Glycol, Span and other nonionic active agents, Silicon defoaming agents; It is characterized in that it contains 0 to 55% by weight of each of at least one type, and cellulose type, alkali swellable type, ester type, urethane compound type, bento type, airgel type, acrylic type, etc. That is, for example, gum arabic, jintan Gum, tara gum, guar gum, agar, kerazinan (carrageenan), sodium alginate, powdered cellulose, cellulose, methylcellulose, HEC, CMC, MC, SD, BT, EHEC, MEHEC, LBG, tararind, arabic , soybean polysaccharide, curdlan, gellan, glucomannan, soda alginate, pectin, carbomer, hicell, gelatin, polycarboxylic acid, carboxyvinyl polymer, metal ethyl cellulose, potassium alginate, ritexrose, sodium carboxymethyl starch, casein, starch among them; It is characterized in that it contains 0 to 55% by weight of each of at least one type, and Dioctyl Phthalate, Dibutyl Phthalate, Ester, etc. are used, preferably Alkyl Ester; It is characterized by including the use of 0 to 20% by weight alone or two or more,
Solid content 1-100 wt% Sodium carboxymethylcellulose (CMC), chlorinated 5 Chloro 2 methyl 4 isothiazolin 3 one and unchlorinated 2 Methyl 4 isotiazolin 3 one organic nitrogen sulfide, strong acids (pH <4) ), hydrochloric acid, sulfuric acid, citric acid, glacial acetic acid, malic acid oxalic acid, sodium benzoate, and borax individually or in a mixture of 2 or more types 0 to 3% by weight, preferably 0 to 2% by weight, 3-lodo-2 propynl butyl carbamate (product name: MX-3 advanced plus, manufacturer: CONNELL FAMILY INC.), C₁₁H₁₉NOS (TK-800), UNICOOL-K14 (manufacturer: UCC), NP-40; It is characterized in that it comprises the use of 0-5% by weight alone or in a mixture of two or more,
0.0001~7,000㎛ Iron powder, Copper powder, Cobalt powder, Tin powder, Aluminum powder, Magnesium powder, Titanium powder, Silicon powder, Nickel powder, Zinc powder, Manganese powder with various shapes such as spherical, plate, and needle shape. Soft ferrite such as Silver powder, Ag coated Cu, Ni coated Cu, Indium tin oxide, solder ball (Free lead Tin-Bismuth), silver chloride, Antimony tin oxide, Stainless Steel, Mn (or Mg, Ni, etc.)-Zn ferrite And hard ferrite such as Ba (or Sr, etc.) ferrite, conductive carbon powder and fiber, solid content 1.0-80.0% by weight Conductive carbon sol alone or a mixture of two or more types 0-97.5% by weight, or these metal materials with carboxylic acid It is also characterized in that it can have a characteristic that can be manufactured into a product having a color by a composition prepared by surface-modifying using a fatty acid or a silane-based material and composition of 0-90.0% by weight of a surface-modified metal material and an additive material thereof with
Content 1∼99.9 wt% Methanol, Ethanol, Butanol, Dichloromethane, Ethylacetate, Hexane, Diethylehter, Acetonitrile, Benznene, Dibasic Ester, 1-METHOXY-2-PROPANOL, BC, Diethylene Glycol Monoethyl Ether Acetate, Toluene, Alcohol, H₂O, etc; In order to identify the antibacterial and anti-mold characteristics, which is another object of the present invention, the specimen prepared by the composition, characterized in that it is mixed alone or 2 or more types 0-97.0 wt% It is possible to simultaneously exhibit antibacterial and anti-mildew performance by simultaneously inhibiting E. coli, Pseudomonas aeruginosa, Staphylococcus aureus, etc. or mold bacteria added to impart functionality; 「E. coli, Pseudomonas aeruginosa, and Staphylococcus aureus belonging to the (-)charge strain, etc., and fungi belonging to the (+)charge strain. Fungi and (+)charge are the scientific principles first mentioned by the present inventor that they adsorb (collect) E. coli, which is a (-)charge strain, respectively, and penetrate the cell wall and kill them.” +) Charge Ag carrier zeolite is a product made by mixing and sold as an antibacterial product that inhibits E. coli. Therefore, the result of each evaluation according to the principle by the inventor - that is, the antibacterial test result (shown in FIG. 25) is the test standard KS K 0693:2001, nonionic surfactant Tweea 80, and Staphylococcus aureus ( Staphyococcus aureus ATCC 6538P) bacteriostatic reduction rate of 99.9% and pneumococcus (Klebsiella pneum oniae 4352) was also 99.9%, confirming excellent antibacterial performance.
26 is a comparison of the results of an acrylic (acrylic primer, acrylic emulsion)-based adhesive with an adhesive in which the composition material of the present invention is not added and an adhesive in which 3.5% of the refined salt composition additive of the present invention is added as an anti-military test. As shown in Figure 26, it can be seen that there is a mold inhibitory effect. The experiment is the result of measuring the fungal strain after culturing it in a constant temperature and humidity chamber (experimental device) for one week. The results of comparative evaluation of the acrylic primer (acrylic emulsion) adhesive used for construction and the acrylic adhesive prepared by the present invention were captured after simultaneous shooting. Although it was confirmed that a large amount of mold is generated in the acrylic adhesive system, which is used for waterproofing or adhesion purposes, even now when the present invention is applied for a patent, it can be seen that the product of the present invention has anti-fungal properties. 27 is a result of comparative evaluation in the same manner by applying the same composition ratio of the present invention to the PVA-based adhesive, and the same result as that of the acrylic adhesive was obtained. 28 is a method for additionally evaluating the superiority of the present invention, showing the results of an experiment with bread, which is highly resistant to mold. For the evaluation of the experiment, the experiment was carried out in the state that moisture was always kept on the bread for 4 days. The portion of the bread that was not in contact with the noodles prepared by the above composition had more mold than the portion of the bread that was in contact with the present invention. It was found that the anti-mildew effect was very good, as the composition of the present invention contained no or almost no mold. And, in fact, Fig. 29 is a photograph of mold occurring on the apartment wall, and Fig. 30 is a photograph of mold bacteria occurring on the wall of a country house exposed to a humid environment.
40 to 85% by weight of water, 50 to 100% by weight of solids, 3 to 30% by weight of chlorides, and 2 to 30% by weight of salt, 78% by weight of solids, into 12-30% by weight of starch, which is one of the mixing ratios of the present invention, and heated (50-350° C., 1-150 min. After boiling while stirring or extruding at 1-100,00 rpm), it was prepared in a gel state. In general, the solid content was 3 to 35 wt% higher than that of commercially available grass, but the viscosity was 80,000 to 200,000 cps (viscometer, when using Brookfield RVDV-II + PRO), which was somewhat lower or the same. General grass (commercial grass) solids ca. In order to meet 15-20 wt%, 120,000-240,000 cps, the content of water was reduced during manufacturing to prepare a grass that does not freeze.
The composition of the present invention has the effect of lowering the freezing point depending on the content of the added chlorinated material - in particular, paper grass (wheat grass), water-soluble EVA, water-soluble acrylic, etc. - It was invented for the first time in the present invention, and thus the freezing point lowering phenomenon like antifreeze for automobiles It was not easy to freeze. That is, it is characterized by lowering the freezing point and preventing the phenomenon of freezing, and the viscosity in commercially available starch paste (wheat paste) with a solid content of 15 to 21% by weight is about 140,000cps (measured by Brookfield RV DV-II + PRO). In order to lower the viscosity (to facilitate construction (painting)), water is additionally added and used. In winter, a small amount of water should be used compared to summer due to the freezing (hyp) phenomenon of water, but adhesion according to the present invention The composition can be used in all weather without the above concerns, so it can be used as it is at the additional water mixing ratio of the previous plastering company. Another strength is that it is possible to secure an economic advantage by securing the quantity according to the forecasting of the use of wallpapering grass (wheat grass) and reducing the cost of construction materials.
The motive of the present invention starts from that seawater does not freeze well in winter. In order to confirm the above principle, the following test was first performed. Water starts to freeze past 0℃ and freezes completely when it reaches -1.0℃, but a mixture of 0.24g of salt and 19.76g of water starts to freeze at -0.45℃ and partially freezes at -1.0℃ (salt 1.12% by weight). A mixture of 0.62 g of salt and 19.38 g of water was not frozen at -1.0°C at all, but slightly frozen at -2.0°C, and more unfrozen water remained than the previous brine (1.12% by weight of salt) (3.1% by weight of salt). As described above, as the concentration of salt increases, it is confirmed that the freezing point is lowered and thus does not freeze well, and applied to the present invention to invent a new product. When this invention is applied to a product with a high freezing point such as a water-soluble product, it lowers the freezing point like an antifreeze (liquid used to prevent the freezing of cooling water for automobile engines), thereby reducing the original product's inherent adhesion and coating power due to freezing prevention. It prevents the loss of adhesion and coating power by maintaining its original performance.
Therefore, the present invention prevents the phenomenon of the adhesive material from freezing before drying when constructing structures, interiors, etc., such as building materials and construction in a cold environment. Innovative technology that can be applied to fields that can prevent
Another object relates to antibacterial properties, and the antibacterial test evaluated by requesting the composition prepared by Examples 1, 4, 5, 7, 8, and 9 to Test Researcher C is the test standard JIS Z 2801-2010, standard film sterilized The antibacterial activity of Staphyococcus aureus ATCC 6538P was 2.5 in PP film, 0.1 mL of the inoculum solution, and the antibacterial activity was 3.1 in Escherichia coli ATCC 8739, confirming that the antibacterial performance was excellent. The antibacterial activity value of Staphyococcus aureus ATCC 6538P was 2.5, and in Blank, the initial strain was 5.6*?*⁴, the number of bacteria after 24 hours of incubation 2.1×10⁴, in the present invention, the number of bacteria after 24 hours of incubation was 62. when Escherichia coli ATCC 8739; In the blank, the initial strain 4.6×10⁴, the number of bacteria 5.0×10 after 24 hours of incubation⁴, The product of the present invention showed an antibacterial activity value of 3.1 with the number of bacteria <0.63 after 24 hours of incubation. The experimental results are shown in FIG. 31, and it can be confirmed that the antibacterial performance is excellent.
As one of the compositions of the invention important in the present invention, a composition of dobae grass (wheat grass); According to Examples 1, 4, 5, 7, 8, and 9, starch as one of the above compositions (grade 1, grade 2, grade 3, each alone or mixed composition of two or more) 10-40 wt%, water 30-95 45 to 350 including 30 to 100% by weight of solids, 3 to 40% by weight of calcium chloride, 20 to 99% by weight of solids, and 3 to 40% by weight of salt components (sun salt, rock salt, refined salt, etc. alone or mixed) ℃, 3-60 min. 1 to 20,000 rpm, 0.5 to 5 atm while stirring, and then packaged, including preservative-free (formaldehyde is not included in the preservative), etc. containing liquid composition ratio and manufacturing method thereof; Among the above compositions, as one of the compositions of the invention, which is important in the present invention, the composition of the planting grass: 10 to 40 wt% of starch (1st grade, 2nd grade, 3rd grade, each alone or mixed composition of two or more), 30 water 45 to 350° C., including at least one 30 to 100% by weight of solids, 30 to 100% by weight of calcium chloride, 3 to 40% by weight of calcium chloride, 20 to 99% by weight of solids, and 3 to 40% by weight of salt components (sun salt, rock salt, refined salt, etc.) to 95% by weight, 3 to 60 min. 1 to 20,000 rpm, 0.5 to 5 atm, the mixing ratio of the liquid coating composition containing preservatives (no formaldehyde in the preservative), etc., packaged after manufacturing, and its manufacturing method; Another composition, starch (1st grade, 2nd grade, 3rd grade, each alone or mixed composition of two or more) 15-30 wt% calcium chloride solution in 15-90 wt% water 15-30 wt% %, solid content 20-35 wt% Salt component (solar salt, rock salt, refined salt, etc. alone or mixed use) 5-40 wt% of at least one solution, and anti-corruption substance (solid content (acidity) 1-99 wt% acid substance ( pH <4)) at 45 to 350° C., 3 to 60 min. 1 to 20,000 rpm while stirring, the mixing ratio of the packaged liquid paste composition and its manufacturing method; Another composition, starch (1st grade, 2nd grade, 3rd grade, each alone or mixed composition of two or more), 15 to 90% by weight of water, 15 to 30% by weight of calcium chloride solution %, 20 to 5% by weight of solid content Salt component (solar salt, rock salt, refined salt, etc. alone or mixed use) 5 to 40% by weight of two or more solutions, and anti-corruption substances (solids (acidity) 1 to 99% by weight acid substances ( pH <4) and the anti-corruption material mentioned in Example 1 in a ratio of 1: 1 to 50) 45 to 350° C., 3 to 60 min. 1 to 20,000 rpm while stirring, the mixing ratio of the packaged liquid paste composition and its manufacturing method; Another composition, starch (1st grade, 2nd grade, 3rd grade, each alone or mixed composition of two or more) 15 to 90% by weight of water, 15 to 30% by weight of calcium chloride solution %, solid content 20-100 wt% Salt component (solar salt, rock salt, refined salt, etc. alone or mixed use) 5-40 wt% of two or more solutions, solid content 1-100 wt% sodium carboxymethylcellulose (CMC), chlorine treatment Organic nitrogen sulfide, acids (pH <4), citric acid, glacial acetic acid, malic acid oxalic acid, sodium benzoate, and borax in which 5 Chloro 2 methyl 4 isothiazolin 3 one and unchlorinated 2 Methyl 4 isotiazolin 3 one are mixed together or Solid content (acidity) of 2 or more 1~99 wt% Hydrochloric acid 1: 1~20 ratio 0~3 wt%, 3-lodo-2 propynl butyl carbamate (MX-3), C₁₁H₁₉NOS (TK-800), UNICOOL-K14 (manufacturer: UCC), NP-40; 45 to 350° C., 3 to 60 min under compositional mixing conditions including the use of 0 to 5% by weight alone or in a mixture of two or more. 1 to 20,000 rpm while stirring, the mixing ratio of the packaged liquid paste composition and its manufacturing method; The biggest feature of the present invention is that different compositions (prescriptions), blending, and classification of substances to be blended in the composition, etc. are different in order to improve long-term storage (aka, long-term storage) of the composition/manufactured product depending on the season. one of them
Filming of those not surface-coated on PS foam (left) and coated with the composition of the present invention (right) with the composition products of the present invention according to Examples 1, 4, 5, 7, 8, 9, and 11 After capture results are shown in FIG. 32 . When the sample before and after coating the PS foam was lit, as a result, the right side completely melted and the PS foam in the area where there was a flame melted and disappeared, but the sample coated on the surface did not melt due to the flame retardant properties of the composition of the present invention Cotton is the result of confirming the flame retardant (flame retardant) characteristics of the present invention as a photograph showing that it remains.
One of the compositions according to Examples 1, 4, 5, 7, 8, 9, and 11 is first coated with 0.01 to 10,000 μm on one side or both sides, and the adhesive material of the composition and the adhesive material used for the composition are aqueous Or a method for protecting a functional part coated with the composition of the present invention by coating one or both sides with an adhesive material such as oil or varnish and a paint with an additional 0.01 to 10,000 μm, and their application products, including wood and Application products that can be manufactured by coating adhesives and paints prepared according to the present invention to those easily prone to fire can be variously applied to various fields. Applicable application products include products featuring furniture, curtains, verticals, wallpaper, flooring, blinds, and clothing, and the product structure is a base material layer (or printing layer, embossing layer) 10 and plastic foam 30 ( Depending on the product, it may be a sheet other than plastic foam. Papers, plastics, etc. belong to this, and these are named sheets.) Between, for example, the compositions of Examples 1, 4, 5, 7, 8, 9, and 11 A flame retardant layer 20 made of is formed, an aluminum foil layer 40 is formed at the bottom of the plastic foam 30 , and an adhesive layer 50 and a release paper 60 are formed on the lower surface thereof. The flame retardant layer 20 suppresses or delays ignition in case of fire. The structure for this is shown in FIG. 33 and not shown in the figure, but in the case of a product constructed in a different environment, the base material layer 10 / flame retardant layer 20 / plastic foam 30 / nonwoven fabric such as polyester long fiber nonwoven fabric It is composed of plastic/plastic foam (30)/aluminum layer (40)/adhesive layer (50)/release paper (60) to form a structure that prevents distortion of the product, or if the installer directly uses an adhesive, aluminum foil Without the layer 40 and the adhesive layer 50, the release paper 60 to the composition of the present invention or the above-listed adhesive (coating) materials that are not included can be coated and then dried.
In Example 13, only one side of the plastic foam 30 is flame-retardant, but FIG. 34 is a case in which the plastic foam 30 is manufactured by forming the flame-retardant layer 20 on both sides of the plastic foam 30, and the plastic foam 30 is In the case of the constituted product, when both surfaces of the plastic foam 30 are flame-retardant, the flame-retardant effect is further improved. Although schematically illustrated in the present invention, a person skilled in the art may further comprise a plurality or a plurality of layers or may be manufactured without a constituent layer. For example, when wallpaper is installed on the plastic foam 30 , it may be manufactured as shown in FIG. 35 without the base material layer 10 . Here, the coating layer was made to exist with the adhesive (coating) material described in Example 13, except for the case where the upper release paper part was attached. 36 and 37, when manufactured with the above configuration even for non-foam real wallpaper or paper wallpaper, it has electromagnetic wave absorption or electromagnetic wave blocking, antistatic, antibacterial/mildew, flame retardant abnormality, antifreeze, anticorrosion performance, and the like.
In the case of the flame retardant layer, it is also possible to remove the attached dust or to shield the electromagnetic wave by the antistatic function. It can be said that the electrical properties are improved according to the additive material and the blending amount of the composition. Taking carbon black as an additive material, when the mixing ratio is 3% by weight of carbon black to 20% by weight of solid content, the surface resistance is 10⁶~10⁸When Ω/□, 6% by weight, the surface resistance is 10⁵~10⁶When Ω/□, 10% by weight, the surface resistance is 10⁴~10⁵Conductivity is improved by Ω/□, and the ability to exhibit electromagnetic wave blocking properties from antistatic properties is also improved. And as for the difference in additive materials, when PEDOT, a conductive polymer, is added instead of carbon black, the surface resistance is 10.⁷~10⁸Antistatic performance in Ω/□, 10 when adding Ag powder to mutual energization^-5~10^-OneWith Ω-cm, electromagnetic wave shielding performance can also be exhibited, and it can also be applied as an electrode material.
With the composition product of the present invention according to Examples 1, 4, 5, 7, 8, 9, 10, 11, to form one layer on the back side of the silk wallpaper or to permeate into the stratum of the back side (rear side or back side) of the silk wallpaper It is a product manufactured with a structure that has been turned off, and has a product structure characterized by complex selection and selection of two or more functions among electromagnetic wave absorption, electromagnetic wave blocking, antistatic, antibacterial/mildew, flame retardant abnormality, and corrosion prevention performance. In particular, it imparts flame retardancy to the silk wallpaper of As a painting method that maximizes the flame-retardant properties by applying the composition product to the back side, allowing it to permeate the wallpaper for 15 to 100,000 sec, and installing it on the wall, it features a product manufacturing method, structure, and construction method that can be applied to product groups such as laminated wallpaper. do.
One of the additives of the present invention - mentioned in Example 1 - was prepared by adding chloride and salt, and then flame retardant performance according to surface resistance and thickness (after applying the composition to paper wallpaper, respectively, ignition was tested. ) was tested. At this time, water-based EVA was used as the adhesive material, and the surface resistance of the water-based EVA adhesive prepared by mixing 7.90% by weight and 12.18% by weight among various mixing ratios (measurement conditions: 19.5℃, humidity 45%) was KS M 3015- According to 1997 or ASTM D257 evaluation method 10⁵~10⁸Ω/□, and the half-life according to KS K 0555-2000, method A was 0.5 to 0.7 sec. Coat paper wallpaper with a paint brush with a width of 50 mm, and surface resistance and flame retardancy by ratio (content) Table 12 shows the results of measurement and evaluation of coating thickness.
From the above results, when the chloride content is 8% by weight or more, it is possible to secure within the surface resistance pursued in the present invention, and the higher the chloride ratio, the more flame retardant properties can be realized even when the coating thickness is thin. It can be seen that the required surface resistance and flame retardant effect can be realized by increasing the coating thickness. In this case, instead of the adhesive EVA material, Acrylic, Epoxy, Polyvinyl Alcohol, Polyvinyl Acetate, Silicone, Polyurethane, Ethylenevinyl Acetate, Polyvinyl Chloride, Vinyl Acetate Acrylic Copolymer, Acrylic Copolymer. Gum Rosin, 2-Ethyl Hexyl Acrylate Monomer, 2-Ethylhexyl 2-Propenoate, 2-Hexyl. Resin, Solution or Acid, Primer, Emulsion, Monomer, Copolymer of 2-EHAM, 2-Ethyl Hexyl Acryl Acid, Butyl Acrylate Monomer, N-Butyl Ester, Butyl 2-Propenoic Chloroprene Rubber, Acid, n-Butylacrylate, Vinyl Acetate Monomer , Resorcinol, α-Olefin, Isocyanate, and Phenolic substances were used alone or in a mixture of two or more substances to obtain the same results.
Another object of the present invention is to prepare a heat-resistant polymer material through molecular structure change, a reactive flame-retardant material in which a flame-retardant component is chemically combined in a polymer structure, and an additive type in which a flame-retardant material is physically added to a polymer material, which is another object of the present invention. There are methods to improve heat resistance by coating or painting flame retardant materials or other flame retardant materials, or by changing product design. Therefore, flame-retardant materials can be generally divided into reactive and additive types, and in reactive flame-retardant materials, the flame retardant component is chemically bonded to the polymer material to maintain the flame-retardant effect, and the additive-type flame-retardant material is physically dispersed in the polymer material. And if there is some compatibility with the material to be used, it acts as a plasticizer or as a filler. Unlike reactive flame-retardant materials, additive-type flame-retardant materials may bloom on the surface of polymer materials depending on their structure and external conditions, so caution in use is required. In the case of a combination type flame retardant material, it exhibits a flame retardant synergistic or inhibitory effect depending on the combination type. Additive-type flame-retardant materials can be classified into the following 4 types according to their flame-retardant behavior. First, it is a substance that can block the emission of incombustible gas or combustible gas and oxygen, and is related to the decomposition and ignition behavior of macro scale. For example, there are a halogenated compound that suppresses the generation of highly reactive radicals in a gas phase reaction and a phosphorus compound that inhibits a decomposition reaction through char formation in a solid phase reaction. Second, as a method of reducing the heat of combustion, there is a phosphorus-based compound that is related to the macro-scale combustion stage and inhibits the decomposition reaction through the formation of charcoal. Third, it is a method of maintaining the physical shape of a material through oxygen and heat blocking, which is related to macro-scale decomposition, and there are fillers, glass fiber reinforcement, and phosphorus-based compounds. Fourth, as a method of increasing the specific heat or thermal conductivity of a substance, there is a hydrate as a method related to the macro-scale heating process. Therefore, the flame retardant principle; ① Increase the degree of crosslinking of the polymer and add a filler to increase the ignition point, ② Al(OH)₃or Mg(OH)₂Silver blocks combustion by generating water during combustion, ③ phosphorus or boron compounds block oxygen by coating a char film on the polymer surface during combustion, and ④ halogen compounds cool the combustion process by taking heat of vaporization during combustion. In case of ①, the physical strength is lowered, in case of ②, aluminum hydroxide is used in large amounts and has the disadvantage of being decomposed at a temperature below 200℃, and in case of ③ and ④, harmful substances such as dioxins are generated. As flame retardant materials that can overcome the regulated boron and halogen-based materials, chloride-based materials, salt and seawater, and white carbon as additional flame-retardant materials were also possible. In the case of products that require black color, if conductive carbon is additionally mixed, better results can be obtained in terms of antistatic and electromagnetic wave blocking. ⓐ Carbon: Using the theory that phosphorus-based flame-retardant material acts as a flame-retardant material by blocking oxygen and generating charcoal during combustion, it can be flame-retardant if a polymer material is coated with charcoal (carbon, charcoal), and carbon can also act as a deodorant. can The problem is that black carbon can be used in fields limited by color problems, but there is also white carbon, so it can be used in various areas. ⓑ If the heat transfer rate is good, if the localized heat is dispersed within a short time, the flame retardancy will be good. First, since the flame retardant synergistic effect linked with ⓐ, thermal conductivity and electrical conductivity are in a proportional relationship. ⓒ Na-based or Ca-based materials, which are analyzed by photoelectron spectroscopy at the Kyushu Institute of Technology, and the calcium oxide film, which cannot be observed with an electron microscope, is ignited as such a film has a protective action to block oxygen. The mechanism by which the temperature rises was revealed. And ⓓ NaCl is not deliquescent, but salts containing Mg ions or Ca ions are deliquescent. This is the reason why the antistatic performance of polymers made from seawater is better. CaCl₂or MgCl₂It is a kind of chloride-based material and chloride-based material, but it is a deliquescent electrolyte by abundant minerals such as sea salt, so that it can have electrical resistance as well as flame-retardant and flame-retardant properties, so that it can have an antistatic function.
Comparative evaluation results for the compositions, flame retardant and flame retardant properties according to Examples 1, 2, 3, 4, 5, 7, 8, 9, and 11 are shown in Table 13, and the test conditions are sample size 5 mm, heat source methyl alcohol (using alcohol lamp), flame length 5cm and flame contact length 1cm Through the above results, for comparative evaluation in the present invention, the result of conducting a flame retardancy test on a specimen prepared using other flame-retardant materials and the additive material of the present invention; Nitrogen-phosphorus flame retardant materials can achieve UL standard V-0 flame retardancy when the flame retardant content is 40% or more compared to the total content. Compared to the material, the amount of flame-retardant material used was large. Halogen-based flame retardant material exhibited V-0 grade flame retardancy with only 20% content, and showed the best flame retardancy. In addition, there was no dripping phenomenon in flame-retardant specimens prepared using nitrogen-phosphorus and inorganic flame-retardant materials when heated continuously for 2 minutes without checking the turn-off time, but dripping occurred when halogen-based flame-retardant materials were used. As a result of comparative evaluation of the adhesive material prepared by adding the composition additive of the present invention and other flame-retardant materials, it can be seen that the product of the present invention is equal to or superior to other flame-retardant specimens. Among the additives used to exhibit flame retardancy, which is another function of the present invention, the possibility of exhibiting a function similar to that of the previous flame retardant material was revealed through physical and chemical consideration, and an additional environmental risk test was conducted. 2271 (flame retardant class 2~3 standard) and export UL-94 (V-0, V-1 standard) standard specimens (220mm × construction thickness (max. 15mm)) were manufactured to evaluate environmental hazards. did The gas hazard test, which is an objective evaluation index for environmental risk, was performed with the adhesive and coating material of the present invention.
As shown in Table 14, the weight loss of the specimen after the test was 2.5 g and 2.3 g, respectively, and the mouse action stop time was also measured as a value higher than 9 sec, which is the judgment standard, so the adhesive and coating material of the present invention has excellent flame retardancy was able to confirm
Examples 1, 2, 3, 4, 5, 7, 8, 9, 11 solid content 33% by weight, adhesive material 60% by weight, anti-condensation and humidity control material 3% by weight, solid content 47-100 As a result of measuring the surface resistance using a composition containing 5 to 20% by weight of chloride, 25 to 100% by weight of solid content, 3 to 20% by weight of salt, and 5 to 30% by weight of additional water, 10 at 40%RH⁶~10⁸As Ω/□, it could be confirmed that there was an antistatic property. Next, the results of flame retardancy measurement through D Test Research Institute are as follows.
KS M 2150 (liquefied petroleum gas) is used for the fuel used in the flame retardant test of the present invention, and the length of the burner flame is 45 mm for the micro burner and 65 mm for the McKell burner, and the tip of the flame is the lower end of the center of the specimen. The burner was installed so as to be in contact with Specimens are cut into pieces of 35 cm in width and 25 cm in length, which are arbitrarily cut from the object to be measured over 2 m 2 , and cut three at a time. The specimen is dried for 24 hours in a constant temperature dryer at 50 ° C. After drying for 2 hours in a desiccator containing silica gel, It was carried out at a temperature of 16°C and a humidity of 34%RH. After coating 120 μm of the composition adhesive and coating material (EVA base) prepared according to the present invention on the coating base plywood, the flame retardant performance test as described above was performed on three specimens, respectively. As a result, the carbonization area of the specimen ① 28.4 cm², specimen② 27.6cm², Subject ③ 31.3cm², the carbonization length is for specimen ① 7.1 cm, specimen ② 6.7 cm, specimen ③ 8.1 cm, afterflame time is specimen ① 0 sec, specimen ② 0 sec, specimen ③ 0 sec, remaining time is specimen ① 0 sec, specimen ② 0 sec, The specimen ③ showed 0 sec. In addition, after coating 120 μm of the composition adhesive and coating material (PVA base) prepared according to the present invention on the plywood as a coating base, the flame-retardant performance test as described above was performed on three specimens, respectively. As a result, the carbonization area of the specimen ① 38.7 cm², Subject② 40.3cm²2, Test object ③ 30.8cm², the carbonization length is for specimen ① 8.9cm, specimen ② 9.5cm, specimen ③ 7.5cm, afterflame time is specimen ① 0 sec, specimen ② 0 sec, specimen ③ 0 sec, remaining time is specimen ① 0 sec, specimen ② 0 sec, The specimen ③ showed 0 sec. At this time, the carbonization length was set to the maximum length in the carbonized part of the specimen, and heating was performed for 2 min for each specimen. It was found that the adhesive and coating composition had good flame retardant properties.
38 is a photograph taken of a specimen after a flame test for non-coated and coated paper wallpaper with the composition of the present invention. In the case of non-coated laminated wallpaper, the specimen was completely burned as soon as a flame was applied (left side of the photo). turned off within ∼2 sec. Therefore, it was found that the composition of the present invention has very excellent flame retardancy or flame retardancy.
Therefore, as the adhesive and coating composition using the chloride of the present invention and application products using the same, such as an adhesive for painting, a paint for painting (coating agent), etc. , film sheet, laminated wallpaper and silk wallpaper that require flame retardancy and anti-mildness properties, flooring materials such as PVC flooring or flooring, and clothing are manufactured by coating the front or both sides. A coating layer made of chloride and salts (sun salt, rock salt, refined salt, etc.), bittern, conductive carbon black, metal material, ceramic (the material mentioned in Example 1), etc. used in the present invention is a method of preventing direct exposure to the outside. , As previously described, on one and both sides of the coating substrate (product), first, the adhesion and coating materials using the chloride and salts, bittern water, conductive carbon black, metal materials, ceramics, etc. mentioned in the present invention are applied 1 to 10 times to 0.01 ~10,000 μm coating, one or both sides of the coating layer are coated with 0.01 to 10,000 μm of water-based as well as oil-based, varnish, and adhesive paints in one of the adhesive materials listed in the present invention or one of the adhesives used in the composition Treatment to prevent direct exposure of the primary coating layer pursued in the present invention to the outside, or, in particular, furniture, curtains, It was confirmed in the present invention that it can be used without restrictions in various fields by additionally coating water-based or oil-based adhesives, varnishes, and adhesive paints when applied to vertical areas. Above all, it is another feature of the present invention that it is applied to products such as upholstered furniture that are subject to the Fire Protection Act and becomes a product that exhibits flame retardancy (flame retardancy) among various functions.
Condensation phenomenon; Although the general paint shows dew formation as shown in FIG. 39, FIG. 40 shows that the present invention does not show dew formation on the surface due to hygroscopicity due to the added ceramic and chloride. And through this function, one of the objects of another invention of the present invention is a flame retardant (flame retardant) synergistic action and method as follows. It appears that the composition of the present invention has excellent flame retardancy properties than the composition without additives of the present invention.
According to Korean Patent Application No. 10-2006-0019024, when exposed to a high humidity environment due to its high water absorption, it may have adverse effects such as contamination of the coated surface due to the generation of humidity on the coated surface. As a way to overcome this, the present invention has provided the following solution. When the additive material of the present invention is used alone or in combination among the composition additives, the additive material specified in Example 1 is used as the additive material of the present invention in the adhesive material and paint (or paint) with a solid content of 35% by weight in the weight ratio of the total composition. The ratio (content) is preferably at least one type and within 30%, and the above problems no longer occur, thereby exhibiting the function of preventing dew condensation while exhibiting the function of more than flame retardant. In order to realize the purpose of preventing dew condensation, even when calcium chloride in chloride is used alone instead of ceramics such as siliceous porous material, lightweight foamed ceramic, and clay as a composition participating material, in terms of using an aqueous solution of calcium chloride that is theoretically soluble as much as possible. When the composition is made so as not to exceed 30% in the weight ratio of the composition, the above-described problems do not occur any more, so that the antistatic function can be additionally exhibited.
However, considering the humid environment in case of rain due to climatic change, calcium chloride (anhydrous CaCl commercially available₂in CaCl_2·6H₂O) content is more preferably within 25% by weight. In the case of using it with salt, in the above composition, the ratio of calcium chloride to salt (sea salt or refined salt, sawmill salt, processed salt, rock salt, industrial slat material, etc.) is 1: 0.5 to 10. It becomes possible to further promote antibacterial/mildew function, partial antistatic function, antistatic and flame retardant function by calcium chloride, freeze prevention, and anti-condensation prevention.
Conductive carbon black compensated for the shortcomings of color through the use of conductive polymers such as PEDOT, white carbon, chloride, salt, and bittern. By using conductive carbon black at the same addition ratio, it was possible to double the electromagnetic wave shielding (electromagnetic wave reduction) beyond the flame retardant properties through char formation and the antistatic performance by conductivity. In particular, the bittern used in the present invention is also called high salt old water. It can be obtained as a by-product when producing salt, and can be obtained by using the deliquescent action when storing salt. The composition consists of 15-19% magnesium chloride, 6-9% magnesium sulfate, 2-4% potassium chloride, 2-6% sodium chloride, 0.2-0.4% magnesium bromide, and the like. It has been used as a coagulant when making tofu since ancient times, but research on bittern has been conducted since World War I, and now it is used as an important resource for inorganic pharmaceuticals. The bittern water treatment industry is a sector such as potassium industry and potassium fertilizer manufacturing industry, and there is also research to manufacture magnesium hydroxide or metallic magnesium using bittern water. The bittern is used directly for tofu production and magnesia cement, and in addition, it has been used in small amounts for rice cleaning, etc., but has been used since ancient times. A material containing 3 to 35% magnesium, 0.1 to 7% calcium chloride, 2 to 27% sodium chloride, 0.01 to 1% magnesium bromide, etc. was used, and 20% by weight of a polymer, which is one of the mixing ratios of Example 1, 50 wt% adhesive material The degree of attenuation of the electric field before and after internal treatment (construction) of the box is measured using an adhesive and coating material containing 50% by weight of weight, 50% by weight of chloride, 25% by weight of solids, 7% by weight of bittern, and 38% by weight of water. measured. It was also confirmed that the measured value of PULSE's E-tester before construction was 136V/m, but after construction, it was 0V/m, and it was also confirmed that the place where the internal construction was performed was going to 0 due to the attenuation of the electric field.
As mentioned in Examples 1, 4, 5, 7, 8, 9, 11, 17, 19, the present invention also relates to an anti-freezing adhesive and coating composition (product), wherein in cold weather, a water-soluble paste, adhesive or paint, etc. The product relates to a composition product and its application products that can be used in all weathers by lowering the freezing point to reduce the adverse effects of freezing during transportation and construction, etc.
In order to realize this, the present invention first secured specific data through the following considerations, solution principles, and tests in order to confirm the principle of lowering a certain point.
As a solid substance that dissolves well in water and can lower the freezing point, there are chloride, nitrate, and ammonium salt. For example, magnesium chloride has less ionized water than calcium chloride, but has the same effect of lowering the freezing point at the same number of moles, so magnesium chloride is more effective than calcium chloride and better than sodium chloride for the same weight. On the other hand, liquid substances, alcohols, glycols, etc. have the same effect. In the case of methyl alcohol, the mass of 1 mole is 32 g, and the freezing point reduction is slightly less than the freezing point reduction mole number of salt 24.25, so the freezing point lowering effect is large. Ethylene glycol is used as an automobile antifreeze, which has a molar mass of 62 and is half that of salt. And freezing point depression is the freezing point depression constant In the case of water, the freezing point depression constant per mole is 1.86 °C/m. Using the principle of lowering the freezing point as described above, it became the motivation (motiv) of the present invention. As shown in FIG. 41, the freezing temperature of pure ethylene glycol is -12 °C, but the freezing temperature (freezing point) of a liquid in which ethylene glycol and water are mixed depends on the mixing ratio. When water is mixed, the hydrogen bonding of ethylene glycol is disrupted and the freezing point is lowered. The freezing point of a liquid in which the amount of ethylene glycol is 70% and water 30% is reduced to about -50℃. Antifreeze with a 1:1 ratio of water and ethylene glycol is about -35 to -40℃, so it is a good example of an antifreeze that can be used in the winter environment of Korea. (Source: Naver Cast, Today's Science, Chemistry Walk , Antifreeze, Prof. Yeo-Hyung Yeo) Also, the principle of lowering the freezing point is that ordinary water starts to freeze from 0℃, but the composition of the present invention, contrary to caustic soda, the higher the content, the lower the freezing point occurs, so it freezes even at a temperature lower than 0℃. The theoretical principle for this is shown in FIG. 42 with reference to the Naver Knowledge Window, rsy7979. If the plane is divided into three places with a red line, the leftmost part is solid state, the upper middle part is liquid state, and the lower right part is gaseous state. And the red line between the solid and liquid states is the solidification point = melting point line, and the solidification point = melting point line of the solution rather than water moves in parallel to the left, that is, since the x-axis is the axis representing temperature, moving in parallel to the left means that the freezing point = melting point. This means that the temperature is lowered. Therefore, the freezing point of the composition of the present invention is lower than that of ordinary water, and there is an advantage in product storage, distribution, and construction in cold weather due to the prevention of freezing.
Products containing water such as water-soluble adhesives, paints, and glue have a problem of freezing (freezing phenomenon) in sub-zero weather. In addition, the increase in material cost compared to summer due to the use of less water than summer during winter construction (painting), and the occurrence of freezing (freezing) in winter when the wall of the apartment veranda with a lower temperature than the apartment room or living room is painted with water-soluble paint In most cases, the builder is unable to construct. In addition, special attention (management) is required as there are cases in which adhesiveness is lowered or the product must be discarded due to agglomeration/separation due to freezing (freezing) during winter movement (product movement stage for distribution or construction) and warehouse storage. In the case of products manufactured with water in circulation, when thawed after freezing, water and adhesive components are separated, resulting in agglomeration or significantly lower viscosity. In order to solve these problems and to prevent the freezing phenomenon by lowering the freezing point, the results of the freezing test are as follows.
As a major part of the present invention, current water-soluble adhesive and coating products always had a problem due to freezing in sub-zero weather in winter. The freezing phenomenon was confirmed as shown, and a comparative freezing (freezing) evaluation experiment was conducted with the present invention. As a result of evaluating whether the products currently distributed on the market and the dobae grass manufactured according to the present invention (the grass manufactured by the S company dobae grass production line) were frozen together in the freezer (Fig. 39 upper part), the distribution products containing water were After about -11°C for 2 hours, freezing began at the time of the first evaluation, and after leaving the freezer for 24 hours, it became a hard lump of ice, but the product of the present invention (see FIG. 43) did not freeze at -11.8 to -15.6°C for 24 hours, and subsequent evaluation At -16.5℃, 12hr evaluation, only the surface showed a slight degree of freezing, but when it was thawed at 16℃ for 4hr (I left it in the indoor atmosphere), the product of the present invention was restored to its original state, --19.3℃ 50hr In the additional freezing test, the product of the present invention completely turned into a lump of ice, but upon thawing, it maintained its original state and adhesive strength. -, When products distributed in the market (current products sold) are completely frozen and thawed, agglomeration occurs due to the separation of the water and flour components, which are the solutions used in manufacturing, and the inherent adhesive function of adhesives such as starch is significantly reduced. phenomenon occurred. Then, for the adhesion test, glue was applied to the paper wallpaper and dried, followed by peeling by hand. The products distributed easily fell off, and even some wallpapers that were glued on by themselves fell off, but the adhesive strength of the present invention did not change, and there was no problem with the adhesive strength (adhesion) enough that the paper wallpaper itself was torn when peeled (when), so adhesives and paints The intrinsic properties were maintained. The experimental results for this will be described in more detail in the following examples.
In addition to the starch coating paste, EVA composed of water-based EVA paint (experiment conducted with N company water-based paint) and the same proportions and materials as those of Examples 1, 2, 3, 4, 5, 7, 8, 9, 11 A freeze test was carried out with a product made with a paint invention composition, and it was completely frozen in the freezer and then thawed, and if you look at the condition, the appearance color of the EVA paint in circulation has changed. The composition EVA paint of the present invention did not change the appearance color before and after freezing. In the painting experiment, the distribution paint that was frozen and then thawed was not applied, but there was no problem in the present invention. 44 shows the state before and after thawing, looking at the principle and test results; The paint has an effect of lowering the freezing point of paints or adhesives containing additives according to the present invention compared to paints that do not contain any additives such as the present invention among water-soluble paints (including adhesives currently on sale). Previous water-soluble paints and adhesives start to freeze after 0°C, but according to the present invention, when one type of additive is mixed, that is, 3% by weight, about -2 to -3°C, 6% by weight -3 to 4°C, 10 wt% -7~-8℃, 15wt% -10~-12℃, 20wt% -13~-15℃, 29wt% -20~-22℃, solid content in the same content ratio when two types are mixed It was confirmed that the adhesive prepared by mixing two types of additive materials with a difference of 2:1 was lower than the freezing point temperature of the above ratio by -2 to -7°C. According to the present invention, even if the paint or adhesive containing the additive material is frozen, the adhesive strength is restored to its original state after thawing, so there is no problem in adhesive strength. was separated like an island, resulting in almost loss of coating power and adhesion. Therefore, when the materials of the present invention are mixed, the freezing point is lowered and the adhesive strength is restored when thawed after freezing. However, it is one of the very important features that it is a product that is easy to install regardless of the season, which was first invented by solving the fundamental problem of the previous adhesive with the antifreeze effect as described above by the present invention.
As in Examples 1, 4, 5, 7, 8, 9, 11, 17, 19, chloride and salt were each H₂Composition by dissolving in O - Chloride as a solution with a solid content of 20 to 50 wt% and salt as a solution with a solid content of 20 to 33 wt% and CaCl₂ Powder and salt powder were added and stirred to dissolve, and starch was added thereto. Accordingly, preferably CaCl₂It is preferable to dissolve it by adding salt first and then adding salt. It is CaCl₂When salt is dissolved in a chloride solution in a heated state using the heat generated when melting thought and implemented. The manufacturing method was prepared in the same manner as in Example 1.
Salt, CaCl in the same formulation as the method for making the above paper grass₂ The same physical properties and the same performance were realized even when the powder was added and the paper grass of the present invention was prepared. That is, in the mixing container, first H₂O (refined pure water is best, but usually groundwater, tap water), salt, CaCl₂, starch is added in this order, and a paper paste is prepared under the production conditions of 30-350° C. 1-100 min, 1-10,000 rpm among the production conditions of Example 1; First, salt, CaCl₂ powder, H₂One of the best features of the present invention is that it can be manufactured by mass production and various methods because it has excellent solubility, dispersibility, and miscibility of the additives of the present invention, such as adding and dissolving O and adding starch to manufacture it. Another one.
In addition, it is preferable to boil water in advance for sterilization of bacteria that may be included in the water and then use it, and it is possible to shorten the manufacturing time even more by increasing the stirring and temperature during pre-solution. In this case, the mixing condition is H₂O 200-600 kg CaCl₂ Powder (CaCl used in the present invention)₂ Among the products marked 100%, 77%, and 74%, from Australia, Vietnam, South America, North America, Europe, Africa, Asia, Japan, Vietnam, India, and the Philippines. In particular, 15 to 100 kg of one or two or more of domestic and Chinese-made deicing agents, edible, low corrosive, reagent grade, and dehumidifying), salt (salt used in the present invention is sea salt or rock salt, etc. For playground/tennis courts, one or more of low corrosive properties are mixed, and they are made in Australia, Vietnam, South America, North America, Europe, Africa, Asia among Japan, Vietnam, India, Philippines. Either one or a mixture of two or more of deicing agents, food, low corrosiveness, dehumidification, etc. One to two or more of grades and grades were mixed and used.) Add 20-160 kg and stir at 30-350 ° C for 1-100 min, 1-10,000 rpm, 0.5-5 atm, but mainly under atmospheric pressure It is one of the characteristics of the present invention to manufacture a porcelain grass while making it.
Examples 4, 5, 7, 9, 11, 17, 19, and 21 for further starch miscibility in the prepared paper grass, an acid with a pH < 4 or less at a solid content of 1 to 100% by weight, as mentioned in Example 1 One anti-rotting agent was prepared by adding 0 to 5% by weight, respectively, based on 100% by weight of the total composition. Preferably, 0 to 5% by weight of strong acid in 90 to 99.999% by weight of the prepared paper paste, 3-lodo-2 propynl butyl carbamate as the main ingredient (product name: MX-3 Advanced Plus, manufacturer: CONNELL) FAMILY INC.), C.₁₁H₁₉NOS (TK-800), UNICOOL-K14 (manufacturer: UCC), NP-40; By adding 0 to 5% by weight alone or in a mixture of two or more, the anti-mildew effect was maximized. With this composition, the shelf life can be maintained for more than one year. In this case, the preservation and storage properties can be maintained for more than 1 year mainly in summer and long-term storage composition. In this case, it was prepared by mixing in case of pre-production mainly for summer and long-term storage. It is one of the most excellent characteristics of the present invention that long-term storage properties are maintained.
And when the prepared composition is stored/distributed/marketed in an insulating box such as Styrofoam or the composition in a frozen state, at least twice or more than the above period, in particular, the frozen composition maintains a semi-permanent storage period. This is compared to the composition of the present invention that loses adhesiveness due to the separation of the solute and the solvent due to the separation of the solute and solvent when the composition of the present invention is mostly water-soluble adhesive or when the paper is frozen, in the present invention, the composition is restored to its original state when thawed and the adhesive force is maintained as it is. By - see Example 20 above - As an adhesive composition, it is one of the greatest inventions of the present invention that has not been implemented in any composition so far.
One of the compositions of the present invention according to Examples 1, 4, 5, 7, 8, 9, 11, 17, 19, 21, 22, starch strong flour and wheat flour or corn or potato 15 to 35 wt%, water 15 to 85 20-49 wt% CaCl solids in wt%₂ 3 to 35% by weight, 10 to 35% by weight of solid content, 1 to 30% by weight of salt, and 0 to 5% by weight of other strong acids or dispersants in one or more mixing conditions at 1-350° C., 1-600min. 1 to 20,000 rpm 0.5 to 5 atm A liquid coating composition prepared while stirring, and its manufacturing method, and the liquid composition is diluted 1-1,000 times and then spray-dried and then subdivided or completely dried and then pulverized to form a powder paste, this powder If water is added to the paste again and stirred, it becomes a liquid coating paste and can be used for painting. The powdered paste produced in this way increases the manufacturing cost due to the additional process for producing the powdered paste, but it can be stored for a long time due to the powder state and has the effect of reducing distribution costs due to weight loss.
Unlike the sol-gel (or sol-powder) manufacturing method of the above embodiment, the sol-powder manufacturing method strengthens adhesion according to the type of additive material and the mixing ratio of the additive material, freeze prevention, antibacterial/mildew, electromagnetic wave absorption, electromagnetic wave blocking, charging Powdered paste that exhibits the properties of prevention, flame retardancy, corrosion prevention, and decay prevention in a complex, selective and selective manner is manufactured, so that it has excellent long-term storage properties.
45 is a photograph taken after bonding a wooden floor tile (flooring material) using the composition adhesive prepared in Examples 1, 2, and 3, and is constructed and dried to a level as good as the adhesive for conductive antistatic tile of Example 2; No peeling occurred after
In this example, the composition of the products prepared according to Examples 1, 4, 5, 7, 8, 9, 11, 17, 19, 21, 22, and 23, and the commercially purchased preservative S company containing the Figure 46 shows the results of artificially putting a fungal strain into the product (injection) and performing a culture experiment for one week. As shown in the figure, the spread of mold did not occur in the paper grass prepared according to the composition of the present invention, and the spread of fungus was severe in the commercial paper grass containing preservatives, etc. Therefore, it was found that the coating grass containing the functional composition material in the present invention had better (good) anti-mildew effect than the coating grass containing preservatives as it prevented the spread of mold.
As mentioned in Examples 12, 16, and 17, the properties regarding flame retardancy, flame retardancy, and non-flammability are as follows. Flame retardancy is a property that prevents flame combustion from occurring when ignited through chemical or physical treatment of combustible materials, flame retardancy is a property that makes the combustion rate relatively slower than inflammable materials, and non-flammability is a property that does not burn even at high temperatures like metal or inorganic materials say that with In other words, flame-retardant burns when exposed to a flame, but does not burn by igniting itself when the flame is removed, and does not spread or expand fire beyond the standard carbonized area by receiving the flame directly. It was made to have (self-turning off). Although flame retardant has a flame retardant effect under weak combustion conditions, it can be said that there is no significant difference from general combustible materials under high temperature or strong combustion conditions. (Source: Doosan Encyclopedia) When classified into flame retardant grades, flame retardant grade 1 is a non-combustible material that does not burn, flame retardant grade 2 is a semi-incombustible material that does not burn easily, and flame retardant grade 3 is called a flame retardant material. Materials that are difficult to burn with Therefore, flame-retardant material refers to a material that does not burn well even when ignited, and it is a material that burns in a flame but does not burn well. There should be no damage. When a flame is ignited, some toxic gas is generated, and there is no burning phenomenon. Flame-retardant board, flame-retardant fiber board, and flame-retardant plastic board are among the flame-retardant materials. According to the Enforcement Decree of the Building Act, it is specified as a 'material with non-combustible performance', and as a result of testing as stipulated by the Korean Industrial Standards Act under the Industrial Standardization Act stipulated by the Ordinance of the Ministry of Construction, In order to evaluate whether it has a flame retardant property corresponding to such a flame retardant class 3, the wallpapering glue and the general wallpapering glue prepared by Examples 1, 4, 7, 8, 9, 11, 17, 19, 21, 22, 23 It was applied on paper and silk wallpaper with a flame test. Figures 47 and 48 show that general wallpaper and silk wallpaper are coated on both sides or one side with the composition of the present invention, and a commercially available wallpapering paste made of water and starch for painting, or a general wallpapering paste containing a fungicide therein ( Because it is not coated with the composition of the present invention, it is described as “not coated”) by capturing a video taken during the flame test and showing it as a photograph. 「The first on the right of the captured photo (paper wallpaper); It was not coated with the paper glue of the present invention, and the second from the right (paper wallpaper); Both sides were coated with the paper paste of the present invention, and the last additional experimental video capture photo (paper wallpaper); Only the back (one side) is applied. And if you look at the captured picture of the same screen, the first on the left (silk wallpaper); Not coated with silk wallpaper, the second from the left (silk wallpaper): only the back side (one side) is applied, and the third from the left (in the captured photo, the center is silk wallpaper) ; It was applied on both sides.” As it was shown in the test, the laminated wallpaper coated with general paper paste had less flame than silk wallpaper, but it burned completely. It burned while in this psalm, and burned and extinguished when the flame was removed from the psalm. As shown in FIGS. 47 and 48, the silk wallpaper applied had the same results as the laminated wallpaper, but the uncoated silk wallpaper burned better than the laminated wallpaper while generating dark smoke. It can be seen that this product needs flame-retardant properties because it is coated on one side (or both sides) of the paper with PVC, a chemical substance, and the silk wallpaper with a printed layer is good for harmful smoke and combustion due to the combustion of PVC. Therefore, the composition product of the present invention is characterized in that it has very excellent flame retardant properties.
Following Example 20, in order to secure the superiority of the present invention by freezing, a more detailed TEST was additionally performed. The results of the freezing test on the dobae grass and the general dobae grass among the compositions of the present invention are shown in the upper part of FIG. 49 . The paper grass of the present invention did not freeze after 24 hours at -11.8 to -15.6°C, but the general paper grass was completely frozen like ice. So, the present invention was further frozen (freeze) by lowering the temperature further at -16.5 ° C for 12 hours, but only the surface was frozen. As such, it was found that the composition according to the composition of the present invention becomes antifreeze like antifreeze that does not freeze well at low temperatures, and therefore, for specific evaluation, the temperature -16 ℃ (fixed), depending on the content of the additive of the present invention, To evaluate the degree of change in the product state according to the change in freezing time and the time to thaw after freezing, surface resistance and adhesion, which are the main items of the present invention, were additionally measured. Does not freeze after freezing at -16℃ 8hrs at 11% chloride and 6% salt based on total weight, surface resistance 14.8℃ 36%RH 10⁶Ω/□, 17.2℃ 27%RH 10⁶~10⁷Ω/□, 14.7℃ 33%RH 10⁷Based on Ω/□, it was completely frozen after freezing at -16℃ for 8hrs at 3% of salt, only the surface melted at 2hrs of thawing, and half melted at 3hrs of thawing, and the surface resistance of this sample was 14.8℃ 36%RH 10⁸Ω/□, 17.2℃ 27%RH 10⁸~10⁹Ω/□, 14.7℃ 33%RH 10⁹Ω/□; It was completely frozen after 8hrs freezing at -16℃ in salt 6%, half-melted at 2hrs of thawing, and slushed at 3hrs of thawing, and the surface resistance of this sample was 14.8℃ 36%RH 10⁸Ω/□, 17.2℃ 27%RH 10⁸Ω/□, 14.7℃ 33%RH 10⁸~10⁹Ω/□; After freezing at -16℃ for 8hrs in 3% chloride and 3% salt, it was completely frozen, half-melted at 2hrs of thawing, and slushed at 3hrs of thawing. The surface resistance of this sample was 14.8℃ 36%RH 10⁷Ω/□, 17.2℃ 27%RH 10⁷~10⁸Ω/□, 14.7℃ 33%RH 10⁸Ω/□; After freezing at -16℃ for 8hrs at -16℃ with 6% chloride and 6% salt, it was frozen about 3/4 of the way, slushed at 2hrs of thawing and completely thawed at 3hrs, and the surface resistance of this sample was 14.8℃ 36%RH 10⁷Ω/□, 17.2℃ 27%RH 10⁷~10⁸Ω/□, 14.7℃ 33%RH 10⁸Ω/□; In 6% chloride and 6% salt, it was frozen 4/5 after 8.5 hrs of freezing, slush was slightly more molten at 1 hr of thawing, and completely thawed at 2 hrs of thawing. The surface resistance of this sample was 14.7℃ 33%RH 10⁸Ω/□; In 8% chloride and 3% salt, after freezing at -16℃ 8.5hrs, it was frozen 9/10, more than half melted in 1hr of thawing, and completely thawed in 2hrs of thawing, and the surface resistance of this sample was 14.7℃ 33%RH 10⁷~10⁸Ω/□; In 9% chloride and 3% salt, it was frozen 4/5 after 8.5 hrs freezing at -16℃, slightly more frozen than slush at 1hr of thawing, completely thawed at 2hrs of thawing, and the surface resistance of this sample was 14.7℃ 33% RH 10⁷~10⁸Ω/□; After freezing at -16℃ 8.5hrs in 7% chloride and 4% salt, it was frozen 9/10, half-melted at 1hr of thawing, and thawed 9/10 at 2hrs of thawing, and the surface resistance of this sample was 14.7℃ 33% RH 10⁸~10⁹Ω/□; In 7% chloride and 5% salt, it was frozen 4/5 after freezing at -16℃ 8.5hrs, slightly more molten than slush at 1hr of thawing, completely thawed at 2hrs of thawing, and the surface resistance of this sample was 14.7℃ 33% RH 10⁸~10⁸Ω/□; In 7% chloride and 4% salt, it was frozen 4/5 after 8.5 hours at -16℃, slightly more molten than slush at 1hr of thawing, completely thawed at 2hr of thawing, and the surface resistance of this sample was 14.7℃ 33% RH 10⁸Ω/□; In 6% chloride and 6% salt, it was completely frozen at -16℃ for 11hrs, slushed at 1hr of thawing, completely thawed at 2hrs of thawing, and the surface resistance of this sample was 17.2℃ 27%RH 10⁸Ω/□, 14.7℃ 33%RH 10⁸Ω/□; In 5% chloride and 3% salt, it was completely frozen at -16℃ 11hrs after freezing, only the surface was thawed at 1hr of thawing, half melted at 2hrs of thawing, and slushed at 3hrs of thawing, and the surface resistance of this sample was 17.2℃ 27%RH 10⁹Ω/□, 14.7℃ 33%RH 10⁸~10⁹Ω/□; 6% chloride and 3% salt at -16℃ After freezing for 11 hours, only the surface was thawed at 1 hour of thawing, slushed at 2 hours of thawing, and completely thawed at 3 hours of thawing, and the surface resistance of this sample was 17.2℃ 27%RH 10⁸~10⁹Ω/□, 14.7℃ 33%RH 10⁸Ω/□; In 7% chloride and 3% salt, it was completely frozen at -16℃ 11hrs after freezing, slushed at 1hr thawed, slushed at 2hrs thawed, completely thawed at 3hrs thaw, and the surface resistance of this sample was 17.2℃ 27% RH 10⁸Ω/□, 14.7℃ 33%RH 10⁸Ω/□; Surface resistance 10 pursued in the present invention after complete thawing in the above composition⁹Adhesiveness of those observed with Ω/□ was not a problem. However, if the waiting time is taken into account during construction after freezing, more preferably, the surface resistance of 10⁸In the composition of Ω/□, a blending ratio in which complete thawing occurs at 2 hours of thawing is the most preferable. However, it is a feature of the present invention that all TEST preparations can be manufactured as anti-freezing composition products because there is no defect in adhesive strength after thawing.
In another evaluation experiment, the results of evaluation of adhesion strength by thawing completely frozen paper plants, applying glue to paper wallpaper, and then attaching them to the wall are shown in the lower part of FIG. 49 . First, after thawing, water and starch were separated from common (existing) paper plants, but the present invention was externally restored to its original state (refer to FIG. 50). After freezing, thawing, coating, and drying 2 hours later, peeling test was performed. The upper layer was coated by diluting the grass by adding water (manufactured paper paste 1: water 1 ratio (weight) added) to the grass, and the lower one was coated with the paper grass manufactured in the manufacturing plant after freezing and thawing. It was painted without adding water. The left side of the continuous photo of Fig. 49 is that the general paper grass #1 is coated after freezing and thawing at -11.8 ° C for 24 hours, and the center is the general paper grass #2 at -11.8 ° C 24 hours after freezing and thawing, and the right side is this According to the invention, it was completely frozen at -19.3℃ for 50hrs and thawed twice, and then coated. As shown in the results, it can be seen that the wallpaper coated on the wall simply fell off due to loss of adhesion in the general paper glue or fell even with a slight peeling force, but the paper glue of the present invention has no problem in adhesion even when frozen like ice. As shown in the peel test, the paper part between the wall and the wallpaper does not fall, but the paper part is torn, indicating that the adhesive strength is good.
These are the test progress results to determine the degree of corrosion to metals such as screws in the wallpapering pools according to the present invention and the two types of mating pools #1 and #2 sold in the general market (see FIG. 51). According to the present invention, purchase the papering grass manufactured in the papering pool manufacturing plant and two different general papering pools, soak the screws, leave them for a long time (at room temperature for 30 days) until the grass is completely dry (30 days at room temperature), and then observe the appearance of the screws is a result The screws placed in the general paper pool are corroded and oxidized, but the level of corrosion of the screws cannot be known in the paper glue factory (C, S, M company mass production line, own production line) line according to the present invention. There was no change in the color of the screw surface.
0-100 parts by weight of dried solid chloride, dried salt (sodium as in Example 1) Edible salt whose main ingredient is Chloride, sea salt and industrial substances used as chemicals, East Sea, West Sea, South Sea, Mediterranean Sea Pacific, Atlantic Ocean, Indian Ocean, Northern Sea, Antarctic Sea, Dead Sea, Black Sea European, African, Asian , North America, South America, and Oceania, especially in the United States, Australia (Australia), China, and the Philippines, such as Asia, Europe, and the West Sea, or salt mines on 6 continents such as Africa, America, and Tibet. Alone or mixed of two or more) 1-100 parts by weight of the powder alone or in a mixture of two kinds, the mixing ratio of chloride 1: salt is prepared in a ratio of 0.1-5, by the manufacturing method mentioned in Example 1, - The present invention by the present inventor As the first powdered powder manufacturing method invented - a composition that exhibits antistatic, antibacterial/mildew, flame retardant abnormality, freezing prevention, and humidity control performance in a complex manner, and powdered paste was manufactured through this. The pool is a solid powder with H₂Because there is no O, it is advantageous for long-term storage and distribution. Examples 1, 4, 5, 7, 8, 9, 11, 17, 19, 21, 22, 23, and 27 have the same characteristics as the liquid porcelain paste of the present invention, but long-term storage by solid standing and distribution by light weight advantageous to
In addition, powdered grass manufactured with grains such as Starch, Rice, Wheat, bran, Corn, Potato, Dextrin, Modified starch, Glutinous Rice, seaweed such as nori, Gelidium amansii LAMOUROUX, grains such as dextrin, modified starch, etc. , Korea E company, K company, Y company, etc. 1 to 100 parts by weight of powdered grass, 0 to 100 parts by weight of the solid chloride mentioned in Example 1, dried sea salt or rock salt, refined salt powder alone or two or more 01 to 100 Mix by weight, and here 0.0001~7,000㎛ spherical and plate-like, needle-like Zeolite, siliceous porous material, Silica, Perlite, Clay, talc, Aluminum Hydroxide, Kaolin, Magnesium Hydroxide, Calcium Carbonate, Diatomite, Loess, Bentonite, Quartz sand , Gypsum, Lime, cement, Terra alba, Pozzolan, Diatom, Pulp, etc. alone or in an amount of 0-100 parts by weight of two or more were used to prepare a powdery or solid-type plastering finishing material. In contrast, a photograph of surface resistance measurement is shown in FIG. 52, and as shown, the measured value is 10⁶As Ω/□, it was at a level capable of exhibiting electromagnetic wave blocking or antistatic properties.
It was confirmed in Example 28 that the functional additive material of the present invention was not more corrosive than general coating pastes or adhesives due to its compatibility with the adhesive and chemical action. In order to infer and clarify more clear reasons and principles, a long-term test was conducted. Therefore, in the present invention, Figure 53 is a test for evaluating the degree of corrosion over a long period of time - currently in progress for about 300 days - (a) The evaluation was carried out by putting a clip and a nail in the container on the start date of the experiment. The middle two are by the present invention, and the two containers on the left contain water in order to determine the effect of water because the water-soluble adhesive material contains water. In addition, after one day, the experiment was carried out by inserting clips and nails. As shown in Fig. 53 (b), in the clip placed in water, corrosion was occurring before 24 hr elapsed, and the degree of corrosion was gradually diffused, but the composition of the present invention also caused very little corrosion due to water. it can be seen that there is This resulted in the same result as in Example 28 due to the generation of a material (calcium hydroxide) that prevents corrosion of iron while the composition of the present invention goes through the mixing process during the manufacturing process, and this material is also neutralized and coated in the atmosphere when the concrete is painted. The durability of the building can be increased by forming blocks by first reacting with the polluting gas in the building. The present invention mentioned in the above and examples is more than the contents invented in Patent Application No. 10-0118954 ~ Application No. 10-0162120, etc. applied by the present inventor "Supplementation, further improvement, further improvement, new development (invention)" Addition, improvement of the manufacturing method, and characteristics of the invention were identified and shown in detail by securing specific data for "new invention, the source of efficacy of the invention, etc." In the present invention, the previous patent invented by the present inventor did not solve the mechanism for corrosion, but in the present invention, an excellent mechanism for corrosion resolution was secured compared to the conventional water-soluble adhesive. This is because it can be explained academically and theoretically that the added functional materials can not only reduce corrosion as well as increase the durability of buildings as they lead to new salts in a water-soluble state. From the left of (a), the composition of the present invention in the center, in which the yellow container solution and the purple container solution are mixed, shows the formation of new salts, and these salts play a role in preventing corrosion, in particular, corrosion of iron. It is left hidden in the specification of the present invention that the substances for this are only referred to as salts.
In Example 29, if the plaster thickness was more than 10 mmm, cracks were likely to occur in the plastered part, and the construction was preferably less than 2mmm smoothly, but as a method of overcoming the crack limit in raising the plaster thickness more; Acrylic, Epoxy, Polyvinyl Alcohol, Polyvinyl Acetate, Silicone, Polyurethane, Ethylenevinyl Acetate, Polyvinyl Chloride, Vinyl Acetate Acrylic Copolymer, Acrylic Copolymer with a solid content of 1 to 100% by weight. Gum Rosin, 2-Ethyl Hexyl Acrylate Monomer, 2-Ethylhexyl 2-Propenoate, 2-Hexyl. Resin, Solution or Acid, Primer, Emulsion, Monomer, Copolymer of 2-EHAM, 2-Ethyl Hexyl Acryl Acid, Butyl Acrylate Monomer, N-Butyl Ester, Butyl 2-Propenoic Chloroprene Rubber, Acid, n-Butylacrylate, Vinyl Acetate Monomer , Resorcinol, α-Olefin, Isocyanate, Phenolic, Thermosoftening Plastic, Thermosetting Plastic, Starch, Rice, Wheat, Bran, Corn, Potato, Dextrin, Modified starch, Grains such as Glutinous Rice, Nori, Gelidium amansii Seaweed such as LAMOUROUX, Dextrin A single or a mixture of two or more substances manufactured with 15 to 50% by weight of solid content, such as grains, modified starch, etc. -99% by weight is used, and the water content nH with a solid content of 1 to 100% by weight₂Sodium Chloride, Magnesium Chloride, Calcium Chloride belonging to O(n=0~99) metal chlorides (European, African, Asian, North American, South American, Oceanian, especially domestic and Chinese products that are easy to secure are mainly used used in 0-50 wt% in the form of powder or aqueous solution thereof, etc.), a composition of these substances alone or a mixture of two or more; Solid content 1-100% by weight Salt is edible salt whose main ingredient is sodium chloride, sea salt and industrial substances used as chemicals, East Sea, West Sea, South Sea, Mediterranean Sea, Pacific Ocean, Atlantic Ocean, Indian Ocean, Northern Sea, Antarctic Sea, Dead Sea, Black Sea, etc. Produced in Europe, Africa, Asia, North America, South America, Oceania, especially in the United States, Australia (Australia), China, and Asia such as the Philippines, Europe, and the West Sea, etc. 6 such as Africa, America and Tibet Use 0-50% by weight alone or a mixture of 2 or more types produced in salt mines on the continent, 15-19% Magnesium Chloride, 6-9% Magnesium Sulfate, 2-4% Potassium Chloride, 2-6% Sodium Chloride, Use 0-50% by weight of 1 to 69% by weight of solid content consisting of 0.2 to 0.4% of Magnesium Bromide, or 5 to 90% of boiling water by heating 100 g of these, or using these chlorides among Calcium Chloride and Sodium Chloride. And among those whose corrosiveness is lowered by generating a low corrosive salt or by a low chlorination system by treatment with a chemical reaction between heterogeneous aqueous solutions, 0 to 50% by weight of these materials alone or two or more thereof are used, or 5 to 100% by weight of a solid content of an ionic compound In the ionic compound used in the present invention, a metal cation and a non-metal anion are coupled by electrostatic attraction, and the sum of the charges is electrically neutral. , Zn, Fe, Al, Be, Mg, Ca, Ba, etc. may be mentioned at least one anion, and the anion element is a fluoride anion, a bromide anion, an iodide anion, a sulfide anion, a chloride anion, an ammonium anion, a hydroxide anion , sulfate anion, carbonate anion, nitrate anion, phosphate anion, permanganate anion, acetate ion, hydrogen carbonate anion, borate anion, chromate anion, dichromate anion, do and one or more selected from the group consisting of rogen anion, hydrochloric acid anion, organic acid anion, and the like, and may additionally include an ammonium salt in consideration of equipment corrosion and solution stability, in anhydrous form, hydrate form, aqueous solution form These materials alone or two or more are used in 0-50% by weight, or solid content is 5-100% by weight The ionic compound uses a +1-valent cation metal and a -1 or -2 valent anion, and the cationic metal element belonging to this is Li , Na, K, and the like, and the anion element is a fluoride anion, a bromide anion, an iodide anion, a sulfide anion, a chloride anion, an ammonium anion, a hydroxide anion, a sulfate anion, a carbonate anion, nitric acid Anion, phosphate anion, permanganate anion, acetate ion, hydrogen carbonate anion, boric acid anion, chromate anion, dichromate anion, halogen anion, hydrochloric acid anion, organic acid anion, etc. It contained at least one selected from the group consisting of, anhydride form, hydrate As a hydrous aluminum silicate mineral containing an alkali metal or alkaline earth metal having various shapes such as 0.0001 to 7,000 μm spherical and plate-like, needle-like, or 0-50 wt% of two or more of these substances alone or in the form of an aqueous solution ( Si,Al)O₄The porous structure and WmZnO in which the tetrahedra of_2n2O composition formula, W is Na, Ca, Ba, Sr, Z = Si + Al, quartz SiO₂, Zeolite in which a part of Si in the three-dimensional network structure in which the diamond-shaped tetrahedral structure is infinitely connected is substituted by Al, siliceous porous material, lightweight foamed ceramic, Silica, Perlite, Titanium Dioxide, Clay, talc, Aluminum Hydroxide, Kaolin, Magnesium Hydroxide, Calcium Carbonate, Diatomite, Loess, Bentonite, Quartz sand, Gypsum, Lime, cement, Terra alba, Pozzolan, Diatom, Pulp or water (H₂O) Dispersed solid content of 1 to 100% by weight Pulp, etc. alone or using 1 to 99% by weight of two or more, to protect interior and exterior walls, ceilings, floors, etc. did The plastering material of the present invention is a material that is strongly formed without cracks after drying or curing by application, and is preferably used mainly as a finishing material for interior decoration. It is also a strength that it can obtain fire prevention and insulation of more than semi-incombustible by mixing it with other materials without background treatment, and that it can form patterns in various shapes due to various finishing methods.
To give one example of the various composition ratios of Example 31, one side and a square box are plastered with a plastering finishing material prepared by mixing 30g of the present invention, 50% by weight of solid content, 20g of pulp, and 500g of white clay containing sand. Afterwards, resistance and electromagnetic wave attenuation were measured. 54 is a Surface Resistance Meter SRMⓡ110/Made in EURO of Wolfgang Warmbier, a surface resistance measuring instrument conducted in a test environment of 21° C., 38% RH, and resistance 10⁶Ω/□ was obtained, and in Fig. 55, the inside of the square box was plastered to determine the degree of electromagnetic wave attenuation. The same electromagnetic wave generation environment was created for the one coated with the general plastering paste (non-functional plastering paste) and the one plastered with the composition of the present invention, and the results were measured using the measuring device E-tester (manufacturer: Pulse) at the same time, and the results are as follows. . The electromagnetic environment was improved from 1,848V/m in electric field to 0V/m in case of general coating. In addition, plaster, lime, water, sand, etc. were the main ingredients for plaster, and gypsum was the main ingredient and dolomite. It is a gypsum plaster mixed with clay, the adhesive (glue, etc.) of the present invention, and a glue material, and has been developed as a plastering material for walls and ceilings. Therefore, a cosmetic product that exhibits electromagnetic wave blocking, antistatic, antibacterial/mildew, semi-incombustible abnormality, freezing prevention, and humidity control performance pursued in the present invention by mixing the functional additive material described in Example 30 alone or by mixing two or more types In addition to one-time plastering, the performance improves as the plaster is applied 1 to 10 times thinly, such as prime plastering, chaebol plastering, and finishing plastering. For example, the use of the coating paste of the present invention improves adhesion and suppresses the occurrence of plaster cracks due to rapid drying, and the pulp used also reduces cracks by dispersing and reducing cracks. The advantage is that it increases the thickness of the plaster, increases the strength of sand, and implements the unique color of the added ceramic. Here, one or two examples of hydraulic hardening by evaporating water and hardening by reacting with gas in the atmosphere, respectively, and all of the following materials mixed with the above-mentioned 0.0001~7,000㎛ spherical shape and various shapes such as plate shape, needle shape, etc. If you change this to a mesh unit, materials with 3 mesh or more are used. The loess plaster is 30 to 99% by weight of loess, 2 to 50% by weight of pulp, 1 to 80% by weight, preferably 80% by weight, 16% by weight, 4% by weight, of the present invention produced porphyry (solid content 25 to 32% by weight) With a composition ratio of 1-50 wt% gypsum, 10-90 wt% loess, 5-30 wt% sand, and 1-50 wt% pulp, it is a hydraulic product that is hardened by evaporation of water, and limestone 1~ 45% by weight, 5-30% by weight of silica sand, 5 to 90% by weight of loess soil, pulp (I decided to use rice bran or rice husk, etc. in all of the above-mentioned compositions instead of pulp), 0-15% by weight of calcium chloride, 1-20% by weight of salt Weight %, nickel powder 1-90% by weight The composition is a hard product and has electromagnetic wave absorption, electromagnetic wave blocking, antistatic, antibacterial/mildew-proof, semi-incombustible abnormality, and anti-freezing performance. Humidity control performance, etc.
And additionally, the effect of far-infrared rays on the loess composition in the composition was measured. As a result of measuring at 40℃ compared to the black body by the FT-IR Spectrometer Method, the far-infrared emissivity (5-20㎛) was about 0.902 and the radiant energy was 3.64×10²㎛. This means that the main component of loess of the present invention is kaolinite Al₂O_3·2SiO_2·2H₂O and Halloysite Al₂O_3·SiO_2·4H₂As O, it is a substance composed of an excess of Al and Si. Therefore, it is known that materials containing a lot of Al and Si materials have high far-infrared emissivity at high temperatures. 56 shows the measurement results commissioned and evaluated by Test Researcher D. In addition, as mentioned, the loess used in the composition exhibits its unique characteristic ocher color, thereby exhibiting the effect as a beautiful exterior product (see FIG. 57), and emitting far-infrared rays, which are a kind of human-friendly wavelength in the loess products of the present invention. At the same time as having a radiation function, it has (+) and (-) ionic properties, so it has an inhibitory effect on (-) and (+) strains. In addition, loess exhibits the effect of having semi-incombustibility more than flame retardant by acting as an inorganic flame retardant. As a result of testing the loess-added sample in the present invention in accordance with KS K 0693-2001, a test result was obtained showing an antibacterial effect of 99.9% against Staphylococcus aureus and pneumoniae, respectively. As shown in FIG. 58, the square box was plastered with the loess plaster composition, and electromagnetic waves were measured using a measuring instrument GIGA SOLUTIONS/Made in Germany. As a result, it was found that the attenuation of the electric field was evident at 8V/m.
Among the above examples and the mixed composition, 0.001 to 100mm carbon fiber or hair, animal hair, or rice bran is used as a substitute for pulp to improve strength and suppress cracking, and improve coating thickness with one plastering (fiber such as pulp has a synergistic effect ) to shorten the construction period. In particular, the carbon fiber exhibits electrical properties as well as (+) charges. -Like silver carrier antibacterial agent- Not only antibacterial effect, but also one stone eight trillions due to electromagnetic wave shielding effect (It can be dispersed into fibers in the above-mentioned and listed water-soluble substances, so it has fiber-like mechanical strength, anti-cracking, antibacterial, anti-mildew, Effect of electromagnetic wave and antistatic, antifreeze, flame retardant (flame retardant) effect, and humidity control.
In Patent No. 1187976, the liquid loess wallpaper composition contains 70 to 90 wt% of loess sediment having a moisture content of 85 to 95% and 60 to 79 wt% of a loess mixture composed of 10 to 30 wt% of diatomaceous earth; 1 to 10% by weight of mulberry powder; Carboxymethyl cellulose sodium (CMC) 0.5 to 3% by weight, propylene glycol (PG) 5 to 10% by weight, terrapin oil 1 to 5% by weight, water 72 to 88.5% by weight of a liquid aqueous solution containing 20 to 30% by weight; comprising; The liquid aqueous solution was a liquid loess wallpaper composition characterized in that 5 to 10 wt% of modified starch was further added for quick drying, and in Patent No. 1138128, propylene glycol and terrapin oil were added to the water in the water tank and stirred, , preparing a liquid aqueous solution by adding and stirring sodium carboxymethylcellulose, mixing mulberry powder in the previously prepared aqueous solution, mixing the ocher mixture consisting of loess sediment and diatomaceous earth with the mulberry powder mixture; It relates to a method for preparing a liquid loess wallpaper composition for applying, characterized in that it comprises a liquid grinding step of grinding a mixture of the loess mixture consisting of the liquid aqueous solution, mulberry powder, loess sediment and diatomaceous earth, wherein the liquid aqueous solution is 82 to 88.5 wt% of water, Propylene glycol (PG) 5-10% by weight, terrapin oil 1-5% by weight, carboxymethylcellulose sodium (CMC) 0.5-3% by weight of sodium carboxymethyl cellulose (CMC) in the aqueous solution in which the alpha (α) starch is additionally included Hydrous nH having a solid content of 1 to 100% by weight in 100 parts by weight of the composition₂Sodium Chloride, Magnesium Chloride, Calcium Chloride belonging to O(n=0~99) metal chlorides (European, African, Asian, North American, South American, Oceanian, especially domestic and Chinese products that are easy to secure were mainly used. ), etc., in the form of a powder or an aqueous solution thereof, in an amount of 0 to 50% by weight, a composition of these substances alone or a mixture of two or more; 1~100% by weight Salt is edible salt with sodium chloride as its main ingredient, sea salt and industrial substances used as chemicals, East Sea, West Sea, South Sea, Mediterranean Sea Pacific, Atlantic Ocean, Indian Ocean, Northern Sea, Antarctic Sea, Dead Sea, Black Sea, etc. Salts produced in Europe, Africa, Asia, North America, South America, Oceania, especially in Asia such as the United States, Australia (Australia), China and the Philippines, Europe, and the West Sea, or 6 continents such as Africa, America, and Tibet 0-50% by weight alone or in a mixture of two or more products produced in the salt mines of Use 0-50 wt% of 1 to 69% by weight of solid content consisting of bromide 0.2 to 0.4%, or 5 to 90% concentration of 5 to 90% by heating 100 g of these, or Calcium Chloride, Sodium Chloride, Among those whose corrosiveness is lowered by the generation of low-corrosive salts or low-chlorination systems by treatment with a chemical reaction between heterogeneous aqueous solutions, 0 to 50% by weight of these materials alone or two or more thereof are used, or as an ionic compound with a solid content of 5 to 100% by weight. - In an ionic compound, a metal cation and a non-metal anion are combined by electrostatic attraction, and the sum of the charges is electrically neutral. One or more may be mentioned from the group consisting of Al, Be, Mg, Ca, Ba, and the like, and the anion element is a fluoride anion, a bromide anion, an iodide anion, a sulfide anion, a chloride anion, an ammonium anion, a hydroxide anion, a sulfate anion, carbonic acid. Anion, nitrate anion, phosphate anion, permanganate anion, acetate ion, hydrogen carbonate anion, boric acid anion, chromate anion, dichromate anion, halogen anion, hydrochloric acid anion, and at least one selected from the group consisting of organic acid anions and the like. In consideration of corrosion of equipment and solution stability, ammonium salt may be additionally included, and 2 to 50% by weight of two or more of these substances are used alone or in the form of an anhydride, hydrate, or aqueous solution, or solid content of 5 to 100% by weight of ions A +1-valent cationic metal and a -1 or -2 valent anion are used as the cation compound, and the cationic metal element belonging to this may include at least one selected from the group consisting of Li, Na, K, and the like, and the anion element is fluorine Sulfide anion, bromide anion, iodide anion, sulfide anion, chloride anion, ammonium anion, hydroxide anion, sulfate anion, carbonate anion, nitrate anion, phosphate anion, permanganate anion, acetate ion, hydrogen carbonate anion, borate anion, chromate anion, dichromate anion One or more selected from the group consisting of anions, halogen anions, hydrochloric acid anions, organic acid anions, etc. were included, and 0-50 wt% of these substances alone or two or more were used in anhydrous form, hydrate form, and aqueous solution form, or solid content 0.1 ∼50 wt% Conductive Polymer (Polythiophene, PEDOT-PSS, Polyaniline, Polypyrrole) 0∼50 wt%, or 0.0001∼7,000㎛ Iron powder, Copper powder, Cobalt having various shapes such as spherical, plate, and needle-shaped powder, Tin powder, Aluminum powder, Magnesium powder, Titanium powder, Silicon powder, Nickel powder, Zinc powder, Manganese powder. Soft ferrite such as Silver powder, Ag coated Cu, Ni coated Cu, Indium tin oxide, solder ball (Free lead Tin-Bismuth), silver chloride, Antimony tin oxide, Stainless Steel, Mn (or Mg, Ni, etc.)-Zn ferrite and 0-50 wt% of a hard ferrite such as Ba (or Sr, etc.) ferrite, prepared in the composition of Examples 1, 4, 5, 7, 8, 9, 11, 17, 19, 21, 22, 23 So; In a wallpaper composition for simple application, application products using a composition that exhibits performance such as strengthening adhesion, anti-freezing, anti-bacterial and anti-mildew, electromagnetic wave blocking, anti-static, flame-retardant, and humidity control pursued in the present invention were developed.
Among the currently commercialized insect repellents, the main ingredients of spray insecticides are phthalthrin and pyrethroid compounds used in pesticides, etc. These ingredients are less toxic than organochlorine or organophosphorus insecticides, so they are widely used. imidacloprid, a colorless and odorless transparent gel, is said to disappear when sprayed on the corners and crevices of a house, but it is also applied to various insects. It is a kind of pesticide that is known to cause a fatal injury to the ecosystem and is a concern that it may disturb the ecosystem.
However, the composition of the present invention, that is, the salts of the additives of Examples 1, 4, 5, 7, 8, 9, 11, 17, 19, 21, 22, 23, 27, 29, 30, and 31 of the present invention are electrolyte ions. The better the dissociation, the better the electrical conductivity, and it is one of the essential components that we need to live. This is because if we do not consume the salt contained in salt, our body cannot function properly. In addition, even if harmful substances or bacteria invade the body, it also plays a role in increasing the body's resistance to prevent intrusion into cells and blood vessels. So, if the human body lacks salt, toxins accumulate in our body, making it easy to get bad diseases, but only the heart in the body never gets cancer, because the heart contains the most salt. Not only humans, but also all living things on Earth cannot survive without salt intake. Animals ingest salt by finding salt rocks or salt caves, and plants absorb salt from the ground. If cows or horses do not consume salt, they cannot use their strength, and trees that lack salt easily rot. Therefore, salt does not give any room for various germs, bacteria or microorganisms to reproduce, and it has properties that do not change even after a long period of time. Salt dissolves well in water, so it penetrates and mixes well with other substances. And since salt has the property of absorbing dust, it can be wiped clean in every nook and cranny. It is a purifying property, so it has been said since ancient times that if you put salt in a place where mold is easily generated in every corner of the house, or if there are a lot of ants in the house, if you sprinkle salt on it, it will go somewhere else. As a good example, the Tripitaka Koreana was completed in 1251, and when the remaining wooden blocks are stacked one by one, the height is about 3.2 km, and the total weight is about 280 M/T. Even if it was well made, it would not have been possible to admire the beauty of the Tripitaka Koreana today if it had not been properly preserved. For the reason that it was able to be preserved in its original form for a long time, first, looking at the wood selection process, the wood, which will be used as a plank, was not used immediately, but was soaked in seawater for 1 to 2 years. After that, it was cut to the size of a plate, boiled in salt water, and dried. Salt has the property of preventing cracking of wood due to temperature and humidity, so it can reduce the phenomenon of cracking or twisting of the plate. The place to store the completed Tripitaka Koreana is also important, so the environment suitable for the preservation of woodblocks is around 20 degrees Celsius and less than 80% humidity. However, the climate of the Tripitaka Koreana does not satisfy this criterion. The average humidity inside Panjeon is 89.09% in summer and 75.91% in winter, which is higher than general wood preservation standards. The average temperature in summer was 19.81℃ and winter average was 2.74℃, which was much lower than the winter indoor temperature standard. What is the reason for the natural ventilation and the floor of the storage building, which was dug deep and sprinkled with charcoal, clay, sand, salt, and fish powder, etc. When it rains a lot and it gets wet, the floor absorbs moisture, and when there is a drought, the moisture hidden in the floor rises and automatically adjusts the humidity. Also, salt can get rid of ants. Ants instinctively like sweet smells. I like sugar or sweet candy, but I hate salt or vinegar, etc. So, as a result of a reaction experiment on salt with 100 ants, it was found that ants did not come to the part where salt was applied. As shown in Figure 59, as seen in this actual experiment, it was confirmed that salt has an ant repelling effect.
Therefore, as the salt used in the present invention, on the one hand, edible salt containing sodium chloride as a main component, chemicals, and materials collected and manufactured from rock salt were used, and on the other hand, seawater was directly collected and used. Salt is naturally present in seawater by 2.8 to 5.0%, and in land where it exists as rock salt, by 3.5 to 5.0%. Rock salt is mainly produced in Europe, North America, and China, and for industrial purposes, it is used as it is, but edible salt is manufactured by the salt field method or by using an ion exchange resin when it is collected from seawater as refined salt. When hydrochloric acid and sodium hydroxide are neutralized, sodium chloride (salt) and water are produced by the neutralization reaction. That is, sodium chloride is an ion (Na⁺, Cl^-) and evaporation of water forms solid sodium chloride. When it is mixed with water again, Na⁺, Cl^-It becomes an aqueous electrolyte solution containing As shown in Table 15, seawater, that is, ordinary seawater contains water as a main component, has a salinity of 5.0% or less, and is composed of trace amounts of metals (minerals). The salinity ratio of seawater is higher than the salinity concentration of living body (about 0.9%), but as⁺ It can be seen that it has the most similar ratio to humans compared to other living things (animals) based on 100 standards. Therefore, salt is a substance beneficial to the human body enough to not be harmful to the human body unless eaten in large quantities. This is a material with excellent flame retardancy as well as the aforementioned conductive properties, as well as the ability to inhibit various bacteria and fungi. , Indian Ocean, Arctic Ocean, Antarctic Ocean, Dead Sea, Black Sea, etc. (European, African, Asian, North American, South American, Oceania) produced in America, Australia (Australia), China, Philippines and Vietnam, such as Asia, Europe, It is a product manufactured from salt produced in the West Sea or from salt mines on six continents such as Africa, America, and Tibet. It will also be a product that can be given. Therefore, the material of the present invention is friendly, friendly, and beneficial to the human body, and some products manufactured according to the present invention are edible, but there is no harm to the human body.
The cause of static electricity due to charging is the electric charge charged on the surface of the insulator due to electromagnetic waves in electric and electronic products or friction due to low humidity, which is the cause of defective products. However, it can lead to fire and explosion hazards in flammable substances handling workplaces such as gas stations. 60 shows the capture principle and scene of ignition by static electricity at the mother gas station. As such, ignition by static electricity frequently occurs in the vicinity. The cause of ignition at a gas station is that friction electricity generated by friction during movement is charged to an insulator, which is clothing, and then instantly escapes to another nearby object, leading to ignition and explosion. Almost all gas stations have a gas lubricator installed on the floor, which is the surrounding insulator, so the only place to escape in case of static electricity is the lubricator. As a solution to this, when the floor is constructed with the product of the present invention, even if the driver's shoes are an insulator and serve as a charging body, even if the static electricity is not completely eliminated, some drivers and surrounding static electricity is released to the ground to increase the static electricity In addition, if a metal wire, such as a metal wire, is temporarily connected to the vehicle body before refueling, if the vehicle body and the ground are connected with a conductor that can disperse and extract static electricity generated during driving through this, the ignition as shown in FIG. is another feature according to the present invention that it can be largely or completely eliminated. In other words, if a long wire is provided with a lubricator so that the wire is placed on the vehicle body first and then refueled, the static electricity is first discharged from the driver's clothing, which may have static electricity the moment the driver grabs the wire, and the static electricity of the vehicle body is the bottom of the present invention. A system capable of resolving static electricity is also one of the characteristics of the present invention.
It is known that dust causes fire and explosion, respiratory disorders, nervous system-related disorders, and even nausea.
Accordingly, it is characterized in that it provides a production method in consideration of the improvement of the working environment and productivity of the worker, which is another important invention of the present invention. When explaining the manufacturing process of dobae grass (wheat grass), which is one of the manufacturing compositions of the present invention, as an example, the previous or current dobae grass (wheat grass) production line seriously threatens the health of workers by the dust generated during the raw material input process. is known As a method to fundamentally solve this problem, the present invention makes the input of raw materials through the absorption pipeline or covers the currently open (exposed outside without a lid) manufacturing container and puts a part of the lid with a raw material input port that allows flour to be input. It is an important feature to manufacture the papering pool of the present invention by manufacturing the manufacturing equipment to fundamentally block the worker working environment and the threat of explosion caused by the dust by separating the worker from the dust.
Although the above content described in the present invention is epidemiological statistical data, but the medical basis is not yet clear, through interviews with workers and operators of paper grass (wheat grass), and common sense, it is said that they are suffering from respiratory diseases caused by flour dust, or have a very high possibility. Based on the evidence, a manufacturing line was manufactured and invented as a countermeasure to this.
Through this, the 1 to 99% wheat grass prepared with the composition of Example 1 has little or no possibility of introducing contaminants due to external contact blocking, so aseptic wheat water can be manufactured. 14-21% solid content The distribution and preservation period was improved by 1.5-500 times compared to wheat grass (grade 1 starch used). However, even when the composition of the present invention is produced in an existing production line, the distribution and preservation period is improved by 1.5 to 350 times or more compared to the previous general wheatgrass. This distribution and preservation property was evaluated as a product that does not contain any preservatives (preservatives). When all of the above compositions contain preservatives (preservatives) that are within the legal standards of Korea, the composition of the present invention, 26% solids, has improved 5 to 1,000 times more than the 14-21% solids general wheatgrass distribution and preservation period. 61 is a photograph taken after opening in order to continuously determine whether the composition of the present invention is deteriorated after one month or more has elapsed after manufacture. After opening, there was no odor in the paper grass, the adhesive strength was the same as the first time, and there was mold growth only in the bottle cap area at the time of opening, but there was no mold generation in the wheat grass inside. The composition adhesive material of FIG. 61 is tested, produced, and verified by the general Milful M company and in particular, the self-installed manufacturing line.
In the present invention, as the most important problem, the invention was made for the purpose of improving adhesion better than the conventional concept of strengthening adhesion according to the type of polymer, but with the same adhesive material.
If wheat grass is described as an example among those manufactured according to the above examples, 15 to 20% of solid content using Korean wheat grade 1 starch among general wheat grass, 18 to 23% of solid content used in grade 2 wheat grass, and 15 solid content of the present invention ~30% As a result of comparing the mutual adhesion for the same conditions among wheat grass, it was found that the wheat grass of the present invention was the best. This evaluation was verified through E Painting Institute, and in the evaluation method, a painter purchases wheat grass and dilutes it with water before applying it to the wallpaper. As they all differ depending on the planting company, this evaluation was evaluated after dilution by adding water in a ratio of 1 to wheat grass 1 in common. As a result of the evaluation, surprising results were obtained. It was the best in adhesive strength, which is the original purpose of wheat grass. Assuming that the adhesive strength of the 2nd grade wheat grass is 1, the 1st grade wheat grass was 1.2 to 1.5 times higher, and the wheat grass of the present invention was 1.5 to 3 times superior. This is because, through the intrinsic properties of the composition of the present invention and the hidden mention, the difference in impurities due to the grade of starch, not the solid content, occurred in general wheatgrass, and in the case of the same grade, the present invention is superior to general wheatgrass in terms of product function exhibiting composition and starch , it is judged that it is highly probable that excellent adhesion was exhibited due to the interaction between the adhesion of the composition between wallpapers and the cellulose-like structure, but the scientific explanation for this is hidden in the specification of the present invention.
In order to improve this, the present inventors improved production output, improved manufacturing process by developing manufacturing equipment, and, in particular, manufactured based on the characteristics of Table 16, replacing the same as the products of FIG. We are building a domestic and overseas sales network through generalization by selling and selling, and have developed to provide better, better, healthier, and healthier wallpaper for users.
The main component of rice or wheat flour is starch. When heated, water quickly penetrates the starch and acts as a plasticizer, resulting in a gel-like paste. The reason why paste made by heating rice or flour with water shows high adhesion to paper is that the cellulose structure of the paper and the starch structure of the paste are similar, so the mutual affinity is high. It is because it can easily diffuse into the fine irregularities of The starch made from starch is easy to make, and because it is a natural product, it is environmentally and human-friendly. However, environmental and human friendliness may rather act as a disadvantage. In hot and humid places, mold easily develops. To prevent this, formaldehyde and phenol were added as preservatives to prevent mold from occurring in the past and now. (Chemistry and Polymers in Life, 2010. 12. 31. Free Academy) Formaldehyde is very toxic to the human body, so Exposure to formaldehyde can cause disease symptoms (irritation, respiratory disorders, asthma, headache, etc.) It has a stinging taste and weak acidity, a peculiar smell, and is classified as a carcinogen. A multifunctional adhesive composition and material are prepared by performing anti-freezing, flame-retardant, humidity control, etc. on the composition, and producing a basic material (salt) by mixing the materials. In addition, although the previous examples have been described with respect to a batch method, Examples 1, 4, 5, 7, 8, 9, 11, 17, 19, 20, 21, 22, 23 , 27, 29, and 34 are first mixed in a compounding machine (mixer or container, tank) for one or more days under the conditions of 0 to 70 ° C, 0.5 to 30 min, 0.01 to 100,000 rpm, 0.5 to 5 atm. Prepare a liquid (mixed liquid liquid), transfer this mixing liquid to the previous container (blending machine or mixing container), preferably a container that is more than twice as large, and mix the transferred mixing liquid at room temperature to prepare or boil it As a means for this, it is prepared with a viscous adhesive material, as an example, wheat paste, while slowly stirring and heating for 5 to 60 min in a traditional method under 50 to 350 ° C, 0.1 to 5 atm, or, on the other hand, although not shown in the drawing, the mixing solution is 0.01 It was manufactured by passing a heat-conducting tube, heat-conducting sheet, drum, etc. installed in oil, steam, water, gas, and electric heat source heated to 70-500°C by -10min instantaneous heating method. The instantaneous heating method may be configured by winding the tube in a straight shape or in a circular shape to save space. The container used here is preferably a corrosion-resistant stainless steel or alloy (stainless steel amd alloy), but general metals and inexpensive plastic materials can be used. As such equipment is additionally installed in the mixing liquid container, the cost competitiveness becomes excellent by reducing the labor cost burden according to the increase in production volume. The manufactured high-temperature adhesive composition and material are immediately packaged at the same time as the prepared composition and material are discharged through the tube of the above-mentioned example, or a device for cooling to 40° C. or less for easy packaging (sheets, drums, containers preferably was passed through the drum) and weighed to the desired weight in a packaging bag or barrel, and then packaged. In particular, when a drum is used as a cooling device, a knife or bar type is mounted on one side of the drum so that agglomeration can be resolved when agglomerated adhesive composition and materials occur, and transport and In the case of packaging, it is passed through a mesh such as a mesh to prevent the agglomerated adhesive composition and material or mixing liquid from passing to the next step process, and in the case of putting it in another container, one or more packaging pipes are provided at the bottom of the container . As another example, in the present invention, if it is manufactured by covering an onion net in front of the mixing liquid transfer pipe in a method that costs little, it is another example that it can be possible to eliminate the agglomeration going to the next step process. characteristics belonging to The adhesive composition and adhesive material prepared as described above are characterized in that they have the same functions described in Examples 1 to 39.
In Figure 62, in accordance with the quality labeling regulations by industrial product quality control according to the addition of harmful mold inhibitors to suppress the occurrence of mold, this should be indicated on the products sold. The data and GHS (Globally Harmonized System of Classification and Labeling of Chemicals abbreviation, classification, labeling, and material safety data sheet for chemical substances) are shown in FIG. 62 . However, in the present invention, one example to be used on the outer surface of the product packaging paper by not using preservatives, etc. is shown in FIG. 63. The technical product of the present invention, in particular, as previously described, is edible, but manufactured as an industrial product. Since it is a product, it is preferable not to eat it, but it is characterized as edible in an emergency as all materials are manufactured to be usable as food in an emergency such as an earthquake. In addition, important features are also shown in FIG. 63 .
It is known that moderate humidity can help prevent or treat respiratory diseases, and drying with other factors such as dry winter or heating causes dead skin cells on the skin surface and increases itching, especially in people with atopic dermatitis. said to be getting worse For this reason, humidifiers and dehumidifiers are mainly used as methods to artificially maintain desired humidity when appropriate humidity is needed, and many households are making efforts to maintain proper humidity by using charcoal or plants indoors. Therefore, to create a comfortable indoor environment, humidifiers and dehumidifiers require periodic management for sanitary use. Plants and charcoal are known to be able to dehumidify and control humidity. It is not currently.
Accordingly, among the composition qualities of the present invention, additive substances and antistatic, antibacterial and anti-mildew, flame retardant and additive substances that exhibit the performance of strengthening adhesion, anti-freezing, anti-bacterial/mildew, anti-static, flame-retardant, anti-corrosion, humidity control, and insect repelling properties mentioned in the above examples Substances added for , increase in weight, impact reinforcement and dispersion, cold resistance, viscosity increase, drying (curing) time shortening, decay prevention, and plastering are non-toxic and sustainable recyclable materials that are essential as building materials. Due to the nature of the material, it can contribute to a comfortable indoor environment by absorbing moisture from the air by the hygroscopicity of the material itself in a high humidity environment, and lowering the indoor humidity in a dry environment with low humidity by blowing out the moisture contained in the material into the air. can In particular, wallpaper paste for wallpaper exhibits characteristics throughout the room due to the above-mentioned substances evenly distributed and distributed over a large area, and application products manufactured with this composition, such as paints, boards, tiles, and wallpaper, are expected to be used as eco-friendly building materials. can become According to a research report, it is possible to reduce odors in the air through humidity control and to decompose pollutants (Source: S. S. Lee, J. S. Kim, C. Y. Yun, and J. H. Yi, Adsorption Characteristics of the Sericite) and Diatomite for Ammonia Gas, Clean Technology, 12(3), 175(2006); H. J. Kim, Evaluating IAQ Improvement Performances of Eco-friendly Building Materials, Ph.D. Thesis, Hanyang University (2011)), Functionality in the form of application It is said that application and expansion as an eco-friendly building material is expected through the development of this wallpaper, which is different from paints, thick boards, and tiles (Source: K. Y. Nam and J. S. Lee, Dyeing Properties and Functionality of Methanol Extract from Juniperus chinensis Heartwood, Textile Coloration and Finishing) , 25(3), 194 (2013); (4), 271 (2013)). Therefore, the composition and application products of the present invention are expected to be utilized as a product group that can help the human body.
Charcoal (10 cm in diameter, 15 cm in length) was placed in a room of the same size as a 5 pyeong room coated with the adhesive material of the present invention, and changes in temperature and humidity were measured. For measurement, changes in temperature and humidity were measured from 2 hr after the start of the TEST. As shown in the measurement results, the room serving as the test standard and the room equipped with charcoal showed the same results, so charcoal had almost no efficacy. One room started the experiment at a temperature and humidity similar to that of the reference room, but the measurement results after 2 hrs. In a humid environment, it can be an important basis for showing that the humidity control function, which is a characteristic of the present invention, is excellent, as it shows the result of discharging and increasing the absorbed moisture.
In the composition according to Examples 1, 2, 3, 4, 5, 7, 8, 9, 11, 74 to 100% by weight of solids in 50 to 95% by weight of seawater 1 to 20% by weight of chloride or 30 to 100% by weight of solids 1 to 19% by weight of salt alone or two, including 3 to 60% by weight of starch, 60 to 350 ℃, 1 to 60 minutes, 1 to 20,000 rpm Stirring or extrusion heating the mixture ratio of the paste composition and As a manufacturing method, the result of evaluation by manufacturing a porcelain paste that exhibits the main functions of electromagnetic wave blocking, antistatic, antibacterial/mildew, flame retardant, and antifreeze performance 10^5~9It was confirmed that it has Ω/□.
The seawater procured from the sea was used after being placed in a container for 0.1 to 240 hours or more. For example, water procured from the East Sea has few impurities and can be used within 0.1 hours, but seawater with many impurities like the West Sea requires time to settle impurities. In addition, for sterilization of the seawater, one including heating at 70-101° C. was used.
In the composition according to Examples 1, 2, 3, 4, 5, 7, 8, 9, 11, 74 to 100% by weight of solid content in 50 to 95% by weight of water 1 to 20% by weight of chloride or 30 to 100% by weight of solid content The above mixing ratio of the liquid paste composition prepared by stirring or extrusion heating at 60 to 350 ° C, 1 to 60 minutes, 1 to 20,000 rpm, including 1 to 22 wt% of salt alone or 2, including 3 to 60 wt% of starch And as a method for manufacturing the same, the result of evaluation by manufacturing a paper paste that exhibits the main functions of electromagnetic wave blocking, antistatic, antibacterial/mildew, flame retardant, and antifreeze performance 10^5~9It was confirmed that it has Ω/□.
In the composition according to Examples 1, 2, 3, 4, 5, 7, 8, 9, 11, 74 to 100% by weight of solid content in 50 to 95% by weight of water 1 to 20% by weight of chloride or 30 to 100% by weight of solid content The above mixing ratio of the liquid paste composition prepared by heating 1 to 22 wt% of sea salt alone or 2, including 3 to 60 wt% of starch, 60 to 350 ° C, 1 to 60 minutes, 1 to 20,000 rpm stirring or extrusion heating And as a method for manufacturing the same, the result of evaluation by manufacturing a paper paste that exhibits the main functions of electromagnetic wave blocking, antistatic, antibacterial/mildew, flame retardant, and antifreeze performance 10^5~9It was confirmed that it has Ω/□.
In the composition according to Examples 1, 2, 3, 4, 5, 7, 8, 9, 11, 74 to 100% by weight of solid content in 50 to 95% by weight of water 1 to 20% by weight of chloride or 30 to 100% by weight of solid content The above mixing ratio of the liquid paste composition prepared by heating 1 to 22 wt% of sea salt alone or 2, including 3 to 60 wt% of starch, 60 to 350 ° C, 1 to 60 minutes, 1 to 20,000 rpm stirring or extrusion heating And as a method for manufacturing the same, the result of evaluation by manufacturing a paper paste that exhibits the main functions of electromagnetic wave blocking, antistatic, antibacterial/mildew, flame retardant, and antifreeze performance 10^5~9It was confirmed that it has Ω/□.
In the composition according to Examples 1, 2, 3, 4, 5, 7, 8, 9, 11, 74 to 100% by weight of solid content in 50 to 95% by weight of water 1 to 20% by weight of chloride or 30 to 100% by weight of solid content Rock salt (also called stone salt or stone salt) 1 to 22 wt% alone or 2, including 3 to 60 wt% starch, 60 to 350 ° C, 1 to 60 minutes, 1 to 20,000 rpm Stirring or extrusion heating According to the above mixing ratio of the prepared liquid paste composition and its manufacturing method, a coating paste exhibiting the main functions of electromagnetic wave blocking, antistatic, antibacterial/mildew, flame retardant, and antifreezing performance was produced and evaluated 10^5~9It was confirmed that it has Ω/□.
In the composition according to Examples 1, 2, 3, 4, 5, 7, 8, 9, 11, 74 to 100% by weight of solid content in 50 to 95% by weight of water 1 to 20% by weight of chloride or 30 to 100% by weight of solid content The above blending ratio of the liquid paste composition prepared by 1 to 22 wt% of refined salt alone or 2, including 3 to 60 wt% of starch, 60 to 350 ° C, 1 to 60 minutes, 1 to 20,000 rpm stirring or extrusion heating And as a method for manufacturing the same, the result of evaluation by manufacturing a paper paste that exhibits the main functions of electromagnetic wave blocking, antistatic, antibacterial/mildew, flame retardant, and antifreeze performance 10^5~9It was confirmed that it has Ω/□.
In the composition according to Examples 1, 2, 3, 4, 5, 7, 8, 9, and 11, 40 to 95 wt% of seawater contains 5 to 60 wt% of starch, 60 to 350°C, 1 to 60 minutes, 1 With the above mixing ratio of the liquid paste composition prepared by stirring at ~20,000 rpm or heating by extrusion and its manufacturing method, the coating paste exhibiting the main functions of electromagnetic wave blocking, antistatic, antibacterial/mildew, flame retardant, and antifreezing performance was evaluated and evaluated. Results 10^5~9It was confirmed that it has Ω/□.
Among the compositions according to Examples 1, 2, 3, 4, 5, 7, 8, 9, and 11, an adhesive material providing adhesion, chloride, or salt is included, and the adhesive material is an acrylic resin, an epoxy resin, or polyvinyl alcohol. Resin, polyvinyl acetate resin, silicone resin, polyurethane resin, ethylene vinyl acetate resin, polyvinyl chloride resin, olefin (olefin), isocyanate resin, including one or two or more of adhesives made of vinyl acetate monomer resin, solid content This is 1 to 99% by weight, and an adhesive composition comprising 1 to 25% by weight of chloride or salt alone or two or more, 5 to 350° C., 1 to 600 minutes, 1 to 20,000 rpm An adhesive prepared by stirring As a result of evaluation by manufacturing a coating paste that exhibits the main functions of electromagnetic wave blocking, antistatic, antibacterial/mildew, flame retardant, and antifreezing performance, the main functions of the composition ratio and its manufacturing method are 10^5~9It was confirmed that it has Ω/□.
Powdered grass (company K) contains 100% by weight of solids 100% by weight of chloride or 1 to 20% by weight of 100% by weight of solids salts alone or two, and a mixture is prepared. As a result of dissolving the composition and evaluating it, the result of evaluation by producing a coating paste that exhibits the main functions of electromagnetic wave blocking, antistatic, antibacterial/mildew, flame retardant, and antifreeze performance 10^5~9It was confirmed that it has Ω/□.
Starch, cellulose, natrium ansinhyang, borax containing 100% by weight of solids 100% by weight chloride in powdered grass or 1 to 20% by weight of solids 100% by weight of salt 1 to 22% by weight alone or two, the composition is melted and evaluated As a result, the result of evaluation by manufacturing a paper paste that exhibits the main functions of electromagnetic wave blocking, antistatic, antibacterial/mildew, flame retardant, and antifreeze performance 10^5~9It was confirmed that it has Ω/□.
In the above embodiment, the purpose of increasing the solid content of the water-soluble compositions is to reduce the distribution cost by weight reduction, to improve the working environment by reducing the weight during movement, and to improve the freezing and antibacterial performance. There are many advantages by weight reduction such as improvement. However, as a disadvantage, the higher the solid content, the longer the annealing time of the added water, but there are many advantages compared to the disadvantages. Therefore, as a method of increasing the solid content, in the present invention, a method of lowering the mixing ratio of water or evaporating by heating was selected.
Among the compositions according to Examples 43, 44, 45, 46,47, 48, 49, 50, and 51, as a method of further improving the adhesive strength of the coating paste, one of the compositions of Example 1 in the present invention is the starch paste ( ) of Examples 1, 6, and 7 containing 5 wt% or less of the adhesive component, 50 to 350 ° C, 1 to 60 minutes, 1 to 20,000 rpm stirring or extrusion heating, or prepared through Examples 1 to 41 It was prepared by mixing the adhesive components of Examples 1, 6, and 7 in the coating pool and stirring or extruding at 5 to 350° C. for 1 to 60 minutes, 1 to 20,000 rpm.
Of the composition according to Example 52, as a method of further improving the adhesive force of the dobae paste, 5 wt% or less of the adhesive component of Examples 1, 6, 7 to the starch paste (paper paste), which is one of the compositions of Example 1 in the present invention included. The composition prepared in this way was prepared and used in a liquid state by stirring while raising the temperature to 70°C or higher under a water bath after 3 to 50 minutes after adding water at 70°C or lower during use.
Accordingly, the compositions of the present invention, Examples 1, 2, 3, 4, 5, 6, 7, 8, 9, 11, 17, 19, 23, 29, 31, 38, 43, 44, 45, 46, Composition 10 according to 47, 48, 49, 50, 51, 52, 53, 54, 55^5~9As a result of constructing the interior with Ω/□, as shown in FIG. 64, it was confirmed that it had fine dust reduction, electric field reduction, antibacterial, anti-mild effect, and flame retardant performance. Accordingly, the present inventors intend to pursue interior commercialization based on the interior effects confirmed through the present invention.
In addition, the room coated with the composition plaster absorbs and lowers moisture in the air in a high humidity environment, and discharges the absorbed moisture to increase it in a low humidity environment. system.

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