KR102431395B1 - A composition which exhibits a composite or selective effect of electromagnetic wave absorption, electromagnetic interference, antistatic, more than flame resistance, antimicrobial, antifungal, freeze protection, Corrosion prevention performance depending on the mixing ratio of additive materials, type of additive material and an application - Google Patents

Abstract

The present invention provides a composition that exhibits electromagnetic wave absorption, electromagnetic wave blocking, antistatic, antibacterial/mildew, flame retardant abnormality, freezing prevention, and corrosion prevention performance in a complex, selective, and selective manner according to the type of additive and the mixing ratio of the additive, and an application product using the same As for plastics, most of them are composed of organic matter and therefore have a property of being easily combustible. It is more susceptible to fire than concrete or metal panels, and there is a concern about the occurrence of mold due to moisture in general coating products. In contrast to concerns about product damage, the product manufactured with the composition and manufacturing method of the present invention suppresses ignition in case of fire, antibacterial and anti-mildew that inhibits various germs, electromagnetic wave (electric field) blocking and extinction by electrical properties, and charging Removal of fine dust adhering to the surface of the product by electromagnetic wave (magnetic field) shielding due to its anti-prevention properties, electromagnetic wave absorption properties, etc., air quality purification, electromagnetic wave reduction, lowering the freezing point and increasing the boiling point among the components of the composition, especially water-soluble in sub-zero weather Adhesives cause product damage due to abrasion, but the present invention is excellent in preventing loss of adhesion due to abrasion-preventing properties.
The present invention provides a comfortable life and life when applied to housing and packaging of houses (spaces where people live, such as houses, apartments, and offices) and electrical/electronic products due to the above functions, in particular, shielding properties in an unfavorable environment; It is a product for painting, packing, and housing that improves the quality of electronic parts and products by removing electrical noise in the workplace and product, and has good electrical properties as an adhesive used for floor construction to reduce static electricity. Thus, when bonding PVC conductive tiles, static electricity generated from the human body, equipment, and the human body during work escapes through the PVC conductive tile, the conductive adhesive of this disease, and the grounding terminal to become an anti-static floor that exhibits anti-static properties. Another feature is that it is a complementary product, and when plastering walls, floors, and ceilings with the composition product of the present invention, humidity control, prevention of various bacteria and mold, electromagnetic wave shielding, prevention of heat during construction, and prevention of ignition by semi-incombustibility It is characterized as a contributing product.

Description

A composition that exhibits electromagnetic wave absorption, electromagnetic wave blocking, antistatic, antibacterial/mildew, flame retardant abnormality, freezing prevention, and corrosion prevention performance in a complex, selective and selective manner according to the type of additive material and the mixing ratio of the additive material, and application products using the same {A composition which exhibits a composite or selective effect of electromagnetic wave absorption, electromagnetic interference, antistatic, more than flame resistance, antimicrobial, antifungal, freeze protection, Corrosion prevention performance depending on the mixing ratio of additive materials, type of additive material and an application}

The present invention provides a composition that exhibits electromagnetic wave absorption, electromagnetic wave blocking, antistatic, antibacterial/mildew, flame retardant abnormality, freezing prevention, and corrosion prevention performance in a complex, selective and selective manner according to the type of additive material and the mixing ratio of the additive material, and an application using the same Through the product, by selectively and selectively having the following electromagnetic wave absorption, electromagnetic wave blocking, antistatic, antibacterial/mildew, flame retardant abnormality, freezing prevention, and corrosion prevention performance, In order to reduce adverse effects such as electromagnetic waves, germs and fires generated in general residential environments, offices, factories, electric/electronic products, transportation means, etc. using accessories and means for communication, and motors (rotors) This is a complex selection and selection function by including attachment of various finishing materials (wallpaper, flooring, etc.) or plastering used on walls, ceilings, and floors, and various automobile interior materials, electronic component packaging, and electronic product cases (eg, mobile phone cases). As a result, it is intended to provide functionality to adhesives, finishing materials, shielding materials, and resin compounds used for EMI (Electromagnetic Interference) or EMC (Electromagnetic Compatibility) shielding, antistatic, antibacterial/mildew, flame retardant abnormality, freeze prevention, and corrosion prevention.

Accordingly, the fields to which the present invention having each selection/selective function can be applied are as follows. ① Due to the fear that the human body will be adversely affected if the human body is exposed to electromagnetic waves generated from electric/electronic products, communication means, wires, electric lights, electric heaters, transformers, ballasts, distribution boards, repeaters, etc. It is necessary to absorb and block the electromagnetic waves (each or both of the electric and magnetic fields) existing in the space in the field requiring reduction of adverse effects, especially electromagnetic waves, so that it is necessary to protect the human body and control devices from unnecessary and unnecessary electromagnetic environment. Fields and fields where electromagnetic waves scattered in the space must be integrated and removed as slight heat from the resistive layer to reduce industrial disturbances caused by electromagnetic waves (electric fields) and static electricity, and electromagnetic waves pollution. Areas where it is difficult to remove fine dust (dust) and areas where dust does not stick to the surface of the product and cause defects, ③ Fields that require air quality purification effect because charged dust in the air can cause fatal injuries if it enters through the respiratory tract (Environment), ④ When there is no ventilation, high humidity areas such as beaches and rivers, poor insulation, and the temperature difference between the outside air and the inside temperature occurs, the humid air adheres to the wall, causing dewdrops or condensation. Exterior walls facing the outside in many places, around windows, walls, floors, bathrooms, etc. Areas (places) or fields that need to suppress the occurrence and growth of bacteria and mold generated by pollution or in a humid environment, ⑤ Construction, Flame retardant (hereinafter referred to as flame retardant) with reinforced flame retardant properties in consideration of safety in case of fire due to the use of (plastic) foam, which is used as a new lightweight material for various industries such as electricity, electronics and automobiles. is generally known to correspond to flame retardant class 3) and fields that require almost non-combustibility, and various plastics and papers are mostly composed of organic and pulp materials, so they are used for products with easy-to-combust properties. ⑥ In cold weather, construction, construction, construction, chemical, material, etc. industrial sites, product manufacturing, interior, etc. Areas where it is necessary to prevent the material (product or construction material) from freezing before drying, or from freezing during distribution and storage to prevent deterioration in adhesion ability. Areas that need it, ⑧ In addition, the phenomenon of deterioration of properties and performance as a metal by forming a non-metal oxide by combining a metal with the components of a given environment is called metal corrosion. Wet corrosion is corrosion caused by the action of a solution due to the presence of an aqueous solution on the surface of the metal. In general, the wet corrosion process is usually caused by an electrochemical or chemical action. Electromagnetic wave absorption, electromagnetic wave blocking, anti-static prevention, air quality purification and electric dust removal by removing static electricity due to neutralization of charged environment or dust, inhibition of bacteria and mold, flame retardant (flame retardant) and higher performance, prevention of freezing in winter, It relates to compositions and products (techniques) applicable to various fields such as anti-corrosion areas.

The present invention is a new invention based on clear evidence by establishing a scientific independent theory and securing engineering data through repeated tests and measurements based on prior investigation of background technologies that can be linked after thoroughly examining the phenomenon, and the inventor's experience and thought. The invention has been implemented.

The present invention is based on electromagnetic wave absorption and blocking and antistatic functions according to the type of additive material and the mixing ratio of the additive material, and has antibacterial/mildew, flame retardant or higher, anti-freeze, and corrosion-preventing performance in a complex, selective and selective manner. It reduces or removes electromagnetic waves and static electricity emitted from various electric and electronic products, reduces the adverse effects of various bacteria and mold in a humid environment, It is possible to manufacture water-soluble products by anti-freezing properties even in cold weather (most water-soluble products are frozen in cold weather, that is, products are frozen at 0℃ or lower), with flame retardant (flame retardant) or higher semi-incombustible properties for combustion gases and flames that are a direct factor. , It is possible to construct (work) by preventing freezing, but there is no risk of damage to the construction product after construction (for example, if the wallpaper paste is applied to the wall paper, in cold weather, the applied wallpaper paste is frozen more easily than when it is in a packaging unit, and the adhesive strength is lowered. There may be a problem that the wallpaper applied to the wall falls off.) "According to the type of additive and the mixing ratio of the additive, electromagnetic wave absorption, It relates to a composition that exhibits electromagnetic wave blocking, antistatic, antibacterial/mildew, flame retardant abnormality, freezing prevention, and corrosion prevention performance in a complex, selective and selective manner, and application products using the same. (For reference, Arabic numerals and units must be spaced for correct notation, but in the present invention, some are spaced and some are attached. For example, numbers and ℃ (Celsius), hr (hour), min (minute), sec (second), %(per cent), weight %, g(gram), L(liter), ㏀(kiloohm), MeV(megaelectron volt), eV(electron volt), meV(millielectron volt), Ω/□ (ohm per square), Ω-cm (ohm-centimeter), μm, mm, cm, km (length units), g/cm 3 (alfeh unit), V/m (Volt per meter), %RH (% relative humidity), N/25㎜(newton per 25 millimeter), cps(centi poise), GHz(frequency unit), rpm(revolution per minute), M/T(metric ton), etc. ), and dB (decibel) and atm (atmosphere) are indicated with a space.)

A look at the sources, current status, actual conditions, etc. of the previously invented materials, techniques, and their problems, and the functions pursued in the present invention are as follows.

(1) Electromagnetic wave absorption and blocking: Electromagnetic waves are an inevitable problem that cannot be separated from civilized society. As the information society rapidly advances, the use of electrical and electronic products increases significantly, and the problems caused by unnecessary and unnecessary electromagnetic waves generated from these devices are on the rise. It is known that there is a possibility that In addition, the fact that electromagnetic waves, which is called the fourth pollution following environmental pollution such as air pollution, water pollution, and noise pollution, cannot be felt even by the human senses (senses) adds to the severity, and also adds to the seriousness of the malfunction of peripheral devices and various diseases. There are warnings that it may cause Therefore, related technology development and products are being developed to cope with this, and high-priced products (S company E product 39,200 won/20g at the time of filing the present invention on January 17, 2018 at the time of filing of the present invention; S company E product / 20g; S company H product 459,730 won / 5L) is a product mainly applied to the manufacture of electrical and electronic parts (products) and electromagnetic shielding. has been understood

(2) Antistatic property: Electric shock, that is, static electricity, electric shock caused by static electricity is remarkably weak, and it does not die from electric shock, but the work efficiency is reduced by the static shock, contact with the machine, or stress caused by the fear. It causes secondary obstacles such as machine malfunctions, and damage to electronic parts (products). When the static electricity of the human body is a problem among the electrification phenomenon, which is one of the fields (products) to which the present invention is applied, the resistance of the human body is several kΩ to several thousand kΩ, so it can be regarded as a conductor electrically, but the human body is separated from the earth due to the shoes. In the insulated state, a type of capacitor is formed between the ground and the static electricity on the conductor, which not only increases the capacitance, but also discharges the entire charge at one place, so it becomes a large discharge energy provider. In addition, there are two types of electric shocks to the human body: the case in which a human body charged with static electricity is discharged in proximity to the ground or another charged object, and the case in which a charged object approaches the human body and discharge occurs. In other words, it is known that it is difficult to prevent the generation of static electricity accumulated in a charged object because it is not only a shock to the human body, but also static electricity caused by instantaneous discharge is generated by friction and contact between substances. In order to prevent such an electrostatic disturbance, it is necessary to remove, neutralize, and leak the generated electric charge. As the information society rapidly advances, the use of electrical and electronic parts (products) increases significantly, and it is difficult to solve the malfunctions of various products or the noise phenomenon of electrical and electronic devices and communication devices due to the electromagnetic fields generated from these devices. . In the meantime, countermeasures against this include grounding and shielding (shielding), in addition to using an inductor capacitor or an electronic component manufactured using ferrite. The shield, which is known to be the most effective among countermeasures, uses metal as an exterior material for general electrical and electronic products in order to exhibit high attenuation characteristics over a wide frequency band. There was an inevitable problem that had to be solved. Materials such as plastics are mostly used as insulating materials and are widely used in various electrical and electronic parts (products), but these insulating properties cause static electricity to accumulate on the surface of the plastic and cause electrification. This charging phenomenon adsorbs dust or dirt and leads to production disturbances and disasters in the industrial field, or it can cause product defects in semiconductors, electronic parts (products), textiles, films, etc. It may also cause malfunction. And when looking at the disturbance caused by static electricity (electric field among electromagnetic waves) and indirectly affecting the human body, there are currently few cathode ray tube type TVs, but the same phenomenon occurs with fluorescent lamps. Positive static electricity of ~10,000V flows. While this static electricity is discharged toward the earth, it attracts negative ions in the air, and as a result, the negative ions are neutralized and removed. At this time, since negative ions in the air are consumed, it becomes a cationic environment in which positive ions are relatively large in the indoor air. Therefore, in the living body, the intake of cations during respiration takes precedence. The composition of this cation is hydrogen ions (H+), and when the concentration of hydrogen ions increases, body fluids including blood become acidic. Table 1 shows the actions of anions and cations. In particular, the hydroxyl ion (OH-) formed by dissociation of a water (H2O) molecule is a strong base and is easily oxidized. Since the hydroxide ions are reduced in this way, the hydrogen ion concentration is relatively high, and in particular, positive static electricity leads to acidity of the body fluid. It is known that positive static electricity also increases free radicals in the body and acidifies the living body, so metabolism is disturbed and cell function is weakened. Therefore, static electricity and electromagnetic waves may disturb the mechanism of the living body. In other words, those lacking electrons are positively charged, so they are cations, and those with too many electrons are negatively charged, so they are called negative ions. Anions, called vitamins of air, exist together with cations in the atmosphere, such as carbon dioxide, oxygen, nitrogen, and hydrogen. People with weak constitutions in an atmosphere with a lot of positive ions will develop chronic diseases, and it is said that all chronic diseases are more likely to get worse. Conversely, if there are many negative ions, the cells become active, and the resistance to disease becomes stronger and the body can become a healthy weak alkaline constitution. Phenomenon that the human body can feel is the refreshing feeling of walking outside after the storm has passed, the feeling of standing in a waterfall, and the feeling of being in a pine forest. This may be because a large amount of negatively charged oxygen ions (negative ions) were generated by the ionization phenomenon (Leonard phenomenon) in which the surrounding air was charged with the cathode. Therefore, the reason why you feel refreshed with negative ions is probably because of the abundance of negative ions that purify minute pollutants in the air. When the water of the waterfall falls and violently collides with the surrounding rocks, the water droplets are split into very small clusters (particles). If you measure the amount of ions in the air, you can see that negative ions are very abundant in forests or near waterfalls. When you come into contact with this nature, you feel refreshed and relaxed. Positive ions are abundantly present in cities polluted with exhaust gas from buildings, concrete, automobiles and factories, and around electrical and electronic products such as cigarette smoke, OA (Office automation) office equipment and computers. The generation of negative ions in nature is called the Leonard phenomenon, after the Nobel Prize-winning physicist Dr. Willib Leonard. Table 2 below shows the amount of negative ions generated by region based on waterfalls in the Americas, a Leonard phenomenon.

division Action negative ions Promotes the supply of oxygen to cells and tissues cation Delays the delivery of oxygen, resulting in oxygen starvation

by region Anion generation [ions/cc] waterfall 50,000 Mountains 5,000 Country 1,500 Office 50

In addition, dust is charged as a kind of colloidal material, and if an ionic environment is created, it sticks to the colloid and removes the charge that the colloid has. It is said that charged dust, rather than uncharged dust, attaches to the respiratory system of the human body and does not fall off easily, causing respiratory disorders. Therefore, this anionic environment acts to neutralize the cationic dust. Denis L. Henshaw, Ph.D. reported an experiment showing that charged fine dust and charged air pollutants, such as radon, bacteria, and viruses, gather by electric charges existing in space. In the experiment, there was an excess of carcinogens around the electric field. Based on this, it was explained that people who live near power lines have an increased risk of getting cancer. The use of radon decay, aerosol, has been shown to selectively accumulate aerosols on the electric field surface of power lines.

Also, from the point of view of Uracil, can very low-energy electrons destroy uracil (a basic substance that is one of the components of ribonucleic acid), and how much radiation (alpha, beta and gamma rays or heavy ions) can damage living cells. There has been a lot of interest in secondary particles generated accompanying the primary invasion of radiation, especially electrons with energies of several tens of electron volts (eV). In fact, it is said that about 40,000 electrons are generated when an energy of 1 MeV is applied. A large number of secondary particles quickly lose energy and attach to the water molecules in the cell as they solvate. Then, studies showing that lower electron energies of less than 20 eV, electrons in the range of 3-20 eV, cause significant detrimental damage to genes, including destruction of single-stranded and double-stranded DNA (Boudaiffa et al., Science). , Vol. 287, p. 1658, 2000). In the study of lower-energy secondary electrons, Tilmann Maerk and colleagues at University Innsbruck and University Claude Bernard Lyon scatter electrons less than 1 eV from a gaseous uracil molecular beam. Uracil is one of the base units of RNA molecules, and uracil is a crucial component in the cell. Research has shown that uracil is broken into pieces by electrons with an energy of only a few meV. It is said that it is not the kinetic energy of electrons that causes this decomposition, but the effect of the charge of electrons that changes the internal potential energy environment of uracil. Although the present invention requires an invention that minimizes the influence of electric charge, which is the source, by identifying the root cause through such scientific research and literature research, there are still many unsatisfactory parts or a solution cannot be secured due to the lack of a clear theory. is the state In order to minimize the effect of charging, an antistatic composition in which at least one conductive material selected from the group consisting of conductive polymer, conductive carbon and graphite, a polymer, a solvent, etc. are mixed is used, but in the case of a solvent, it is volatile. Therefore, caution is required for indoor use.

(3) Antibacterial, anti-mildew (anti-fungal):

Development of products with antibacterial and anti-mildew functions that can remove bacteria and mold bacteria generated by moisture and actively deal with harmful chemicals in use to give antiseptic effect against bacteria and fungi to high molecular substances that are food for bacteria There are laws and regulations to minimize damage to the human body, but in the case of houses such as apartments (APTs), according to the published “Occupant Satisfaction with Construction Supervision,” about 30% of all defects are in the finishing process. , It is said that 60% of repairs are due to the occurrence of mold (Table 3) When looking at the photos taken of mold fungus on the apartment wall (Fig. 1) and mold fungus on the country house (Fig. 2), a significant amount of mold In particular, it was observed that more and more mold bacteria were generated in places such as country houses in a humid environment.

fault type number of cases defect rate mold fungus 127 61.3 exhilaration 37 17.8 dent, contamination 31 14.9 Etc 12 6.0 total 207 100%

(Source: Citing S E&C data)

As a solution to this, inorganic antibacterial agents and organic antibacterial agents are used to manufacture products with antibacterial effects. Antibacterial products are manufactured by adding organic or inorganic antibacterial agents to polymers (polyethylene, polypropylene, polyvinyl, epoxy, etc.) and tiles. Since an expensive antibacterial agent (company C) must be added, there is a problem of cost burden (disability to generalization) to apply in the case of large-area construction. Therefore, the present invention is based on the scientific principle and experimental data first mentioned by the present inventor that the substance added to impart functionality simultaneously inhibits bacteria and fungi, thereby exhibiting antibacterial and anti-mildew performance to inhibit Escherichia coli, Pseudomonas aeruginosa, mold, etc. Based on the description, the content of the technology and the claims will be explained.

(4) Flame-retardant, semi-non-flammable: Flame-retardant materials are almost the same as or very similar to flame-retardant materials, so they are called flame-retardant. As a flame retardant material, when manufacturing a flame retardant composition with various polymers, generally flame retardant materials containing halogen, antimony, inorganic, phosphorus, and nitrogen-phosphorus as main components are added. The use of specialty products is gradually expanding. Polymers are mostly composed of organic matter and have the property of being easily combusted. A flame retardant material is a substance added to suppress or alleviate combustion by physically and chemically modifying these properties. In general, flame retardant materials are classified according to usage methods and components, and are divided into additive type and reactive type according to usage methods. The additive type is organic and inorganic, and the reactive type is a flame retardant material containing active radicals such as -OH, -H, and -COOH. ), bromine-based, chlorine-based, etc., inorganic types are typically divided into antimony-based and metal hydroxide-based (aluminum hydroxide, magnesium hydroxide). In particular, among organic flame-retardant materials, brominated flame-retardant materials are widely used in various plastic products due to their excellent flame-retardant properties. First, the previous flame-retardant materials will be explained, and the superiority will be explained through comparative evaluation later, and then the semi-non-flammable materials will be explained. The characteristics of flame retardant materials that are mainly used are as follows. ① First, among halogen-based flame retardant materials and halogen compounds, flame retardancy is excellent in the order of I>Br>Cl>F, but iodine compounds are expensive and C-I bonding strength is weak, so they are easily decomposed at processing temperature, and fluorine compounds have high C-F bonding energy It is not used because it is inefficient, and although bromine-based is more expensive than chlorine-based, it has an excellent flame-retardant effect, so it is widely used in general-purpose and en-pla resins. Representative examples of bromine-based flame retardant materials include tribromophenoxyethane, tetrabromobisphenol A (TBBA), and otabromodiphenyl ether (OBDPE), among which TBBA is the most used. Brominated flame retardant materials generally use antimony compounds (antimony trioxide, antimony pentoxide, etc.) as a flame retardant auxiliary material (synergist), and the reaction mechanism is as follows.

<General reaction mechanism of halogen-based flame retardant materials>

HO + HX → HOH + X → inhibitory reaction

X + RH → HX + R → regeneration reaction

↓ Stop the chain reaction

XO + OH → HX + O2 → Reduce the concentration of active O, OH and stop the chain reaction

→ Flame retardant effect

X + O → XO + X → Non-combustible gas generated during decomposition → Block O2

O + OX → O2 + X

<Reaction mechanism of halogen + antimony flame retardant material>

Sb2O3 + 2HBr → 2SbOBr + H2O

5SBOBr → Sb4O5O4Br + SbBr↑

4Sb4O5Br2 → 5Sb8O4Cl + SbBr↑

3Sb8O4Br → 4Sb2Cl3 + SbBr3↑

Chlorine-based flame retardant materials include chlorinated paraffin, chlorinated polyethylene, and substituted chlorine-based flame retardant materials. In the case of chlorine-based paraffin and polyethylene, while the price is low, thermal stability is weak, and in the case of a substituted flame-retardant material, the price is high.

Examples of inorganic flame retardant materials include aluminum hydroxide, magnesium hydroxide, antimony oxide, and boron-containing compounds. Unlike organic flame-retardant materials, inorganic flame-retardant materials are not volatilized by heat, but decompose to release non-flammable gases such as H2O, CO2, SO2, etc., and most have endothermic properties. In the gaseous state, it dilutes the combustible gas, prevents the access of oxygen by coating the plastic surface, and at the same time has the effect of reducing the plastic cooling and the generation of thermal decomposition products through the endothermic reaction on the solid surface. In addition, in the case of a boron compound, there is an effect of blocking oxygen and heat by forming a glassy protective layer on the solid surface. Aluminum hydroxide is the cheapest among inorganic flame-retardant materials, but it can only be used in plastics with a low decomposition temperature of 200°C or less. The reaction mechanism of inorganic flame retardant materials is as follows.

<Flame-retardant mechanism of inorganic flame-retardant material>

2Al(OH) ₃ → Al ₂ O ₃ + 3H ₂ O - 298KJ/mol

Mg(OH) ₂ → MgO + H ₂ O - 328cal/mol

The phosphorus-based compound serves to block oxygen and heat by generating char by esterification and dehydrogenation of polyphosphoric acid produced by thermal decomposition during combustion. Phosphorus-based flame-retardant materials include red, phosphoric acid esters, and phosphine oxide. In the case of red, the compound material is red because its own color is red, and its use is limited due to color problems. Phosphate ester-based flame retardant materials include triaryl phosphate, alkyldiaryl phosphate, and trialkyl phosphate in the form of monomers, and resorcinaol bisdiphnyl phosphate in the form of oligomers. Nitrogen-phosphorus flame retardant materials include melamine-phosphate and melamine-polyphosphate. Nitrogen-phosphorus flame retardant materials are intumescent thick char layer due to the thermal polycondensation catalysis of polyphosphoric acid generated during combustion and nitrogen sources (N2, NH3, etc.). It prevents the diffusion of heat and oxygen. However, there is a disadvantage in that physical properties and price competitiveness are lacking due to the large amount of use. Antimony, tin, zinc, and selenium are heavy metals used to add flame retardancy to wallpaper and are used to improve the functionality of wallpaper. In particular, antimony has a toxicity similar to arsenic, and when exposed it has been reported to cause pneumonia, osteoporosis, and cancer. (Source: KANALYTICAL SCIENCE & TECHNOLOGY, Vol. 21, No. 2, 135-142, 2008 )

In addition, semi-incombustible materials have less fire risk than combustible materials and have the ability to suppress the occurrence of fire. It refers to materials that do not work, and in the Building Act, they are classified into three categories according to their performance: non-combustible materials, semi-non-combustible materials, and flame-retardant materials. (Source: Interior Glossary, Architectural Glossary) Semi-incombustible material is a material equivalent to flame retardant class 2 The average duration of stopping time of a laboratory rat left in the combustion gas of the material is 9min, without any lamps) should be more than Table 4 compares the standards for non-combustible materials, semi-non-combustible materials, and flame-retardant materials disclosed and generally known.

division non-combustible material Semi-incombustible material flame retardant material Justice Materials with non-combustible properties (Article 2 of the Enforcement Decree of the Building Act) Materials with properties comparable to non-combustible materials (Building Act Enforcement Decree Article 2) Materials that are resistant to fire (Article 2 of the Enforcement Decree of the Building Act) standard When heating at 750°C for 20 minutes, the temperature does not rise above 50°C, and there must be no residual flame for more than 30 sec after heating at 305°C for 10 minutes. When heating at 305°C for 10 minutes, there should be no remarkably harmful deformation such as melting or cracking, and there should be no residual flame for more than 30 sec after heating is finished. When heating at 235℃ for 6min, there should be no harmful deformation, and there should be no residual flame for more than 30 sec after heating is finished. test standard Article 6 of the Korean Industrial Standard KSF2271 (Flame Retardant Class 1), Rules for Standards for Evacuation of Buildings, Fire Protection Structures, etc. Korean Industrial Standard KSF2271 (flame retardant class 2), Article 7 of the Rules for Standards for Evacuation of Buildings and Fire Protection Structures Article 5 of the Korean Industrial Standard KSF2271 (Flame Retardant Level 3), Rules for Standards for Evacuation of Buildings, Fire Protection Structures, etc. oilseed Concrete, stone, brick, glass, glass wool, cement board, gypsum cement board, etc. Gypsum board, pulp cement board, etc. Flame-retardant plate, flame-retardant plastic plate, etc.

(Source: http://cafe.naver.com/linecontra/89348)

In order to have an excellent flame retardant effect, flame retardant (or flame retardant) products by increasing the use of flame retardants or using medium to expensive flame retardants are 2 to 6 times more expensive than products without flame retardancy. In the distribution market, based on flame-retardant wallpaper products, assuming that general wallpaper is about 2,000 to 2500 won (as a standard), silk wallpaper is about 6,000 won, and flame-retardant wallpaper is sold at a high price of 12,000 won. The reality is that it is more difficult to apply the flame retardant material to the cheap plastering pool.

(5) Anti-freezing: Adhesives manufactured with water have serious problems due to freezing during construction, distribution and storage in cold weather. As a product containing water, there is, for example, a powder paste that is used by dissolving it in water as a method to prevent freezing among paints, adhesives, and paper glue. This powdery paste (starch powder, corn powder, etc.) has strengths in that it does not freeze during distribution and by reducing its weight, but it may not be completely unwrapped or parts where the grass may be partially aggregated may occur during operation. Preparation may take time, and liquid glue was used at the large-scale construction (construction) site. This also requires the use of water, so if the coating material is coated with grass and applied to the wall in cold weather, there is a risk that the wallpaper will freeze before drying and the wallpaper may fall off. By reducing the amount of water used, it is the same as the grass that is distributed (sold) with water. have. No matter how cheap the grass is, it can be an economic burden and a disadvantage in work when painting a large area.

(6) Corrosion prevention: Concrete has superior durability compared to other materials, so it is impossible to preserve the structure permanently because the durability gradually decreases in a natural environment, but in general, reinforcing bars are made of a protective film in concrete and rust occurs. I never do that. However, due to the neutralization of the concrete surrounding the rebar, corrosion such as cracks occurs. The neutralization of concrete is a phenomenon that occurs by reacting with carbon dioxide in the air and the alkali of concrete. This action proceeds from the surface of the concrete to the inside, and the rate of progress depends on the humidity in the air, the permeability of the concrete, and the strength of the concrete. In general, it is reported that concrete progresses about 12mm in 10 years and 25mm in 50 years. A similar process occurs with sulfur dioxide in air. Therefore, in areas with severe pollution, the combined action of carbon dioxide and sulfur dioxide occurs, so the neutralization action is faster. When the concrete surrounding the reinforcement is neutralized, the reinforcement begins to corrode. It was said that the corrosive action of rebar is accelerated in neutralized concrete. (Source: The main culprit of concrete corrosion, Korea Research Institute of Technology)

Hardened concrete, as a hydration product of cement, contains calcium hydroxide (Ca(OH) ₂ ) and exhibits strong alkalinity (pH 12-13). It is said that carbon dioxide or acid rain in the air chemically reacts with calcium hydroxide in the concrete to gradually turn into calcium carbonate (CaCO ₃ ) and lose the alkalinity of the concrete. This phenomenon is also called "concrete neutralization" or "concrete carbonation".

Ca(OH) ₂ +CO ₂ →CaCO ₃ +H ₂ O[CaCO ₃ ↑ → neutralization ↑]

At a pH of 11 or higher inside the concrete, a passivation film is formed on the surface of the reinforcing bar, so it does not rust even in the presence of oxygen. it expands In other words, when the concrete is neutralized (pH 8.5~10), the reinforcing bars corrode and expansion pressure is generated. When this expansion pressure exceeds the concrete stress, cracks occur and water and carbon dioxide penetrate into the cracks, resulting in rapid deterioration. proceeds Neutralization is judged to be neutralized when an alcohol solution of 1% phenolphthalein is sprayed on concrete, because the alkaline part appears reddish-purple. (Source: [Naver Knowledge Encyclopedia] Concrete Neutralization seonghwa), Geospatial Information System Terminology, 2016. 1. 3., Gumi Seogwan) In addition, the phenomenon of deterioration of properties and performance as a metal by forming a non-metal oxide by combining a metal with the components of a given environment is called metal corrosion. Corrosion caused by the action of a solution due to the presence of an aqueous solution on the surface is called wet corrosion. In general, the wet process is usually caused by electrochemical or chemical action. this is required

(7) Insect control: The main components of spray insecticides are phthalthrin and pyrethroid compounds used in pesticides, etc. This component has lower toxicity than organochlorine and organophosphorus insecticides. It is known that respiratory disorders such as inflammation and pulmonary fibrosis may occur. Imidacloprid, an ant extermination ingredient, is a colorless, odorless, transparent gel that is said to disappear when sprayed on corners and crevices of a house. It is a kind of pesticide that has raised concerns that it may disturb the ecosystem.

(8) In order to solve these problems, the prior art and its problems are as follows. ① Korean Patent Application No. 10-2000-0068297, it was difficult to produce a commercial product due to layer separation caused by the use of a high-density radio wave absorber and a high-density material. ② Korean Patent No. 10-0591003, There was a disadvantage in that long-term adhesion properties were deteriorated due to the absence of a sexual material, and ③ Korean Patent Nos. 10-0526673 and 10-0522267 did not have specific techniques for conductive carbon black and adhesives used as main materials. Therefore, the technology has a fundamental problem because it does not consider the ease of operation, the types and efficacy of materials used, and long-term reliability as a product, which are inevitably required in a method for manufacturing a functional polymer material.

The present invention has been devised to overcome the problems of the above technology, and the mixing ratio of the additive material and the type of additive to provide electromagnetic wave absorption, electromagnetic wave blocking, antistatic and electromagnetic wave shielding performance to adhesive materials, paints, resins, etc. Its main purpose is to provide a composition having suitable electrical properties or magnetic properties and application products using the same.

Another object of the present invention is to provide a composition having an antibacterial and anti-mold function against a polymer that is frequently encountered in real life, which is a prey of bacteria or mold, and an application product using the composition.

Another object of the present invention is to provide a composition that enables flame-retardant (flame retardant) or more semi-incombustible properties for combustion gases and flames, which are a direct factor in casualties due to toxic gases and smoke in case of fire, and application products using the same to do that for that purpose.

Another object of the present invention is the anti-freeze properties to suppress the problem of freezing in cold weather,

To provide a composition and application products using the composition that enables anti-freezing, corrosion prevention, and insect repelling properties by including eco-friendly compositions instead of insecticides for the purpose of neutralizing concrete and inhibiting corrosion of metals and other insect repellents. for that purpose

It is an object of the present invention to provide a manufacturing method for achieving the above object.

Another object of the present invention is to provide an applied product that is also manufactured by the manufacturing method.

In order to achieve the above object, electromagnetic wave absorption, electromagnetic wave blocking, antistatic, antibacterial/ To implement a composition that exhibits anti-mildew, flame-retardant abnormality, anti-freeze, and anti-corrosion performance in a complex, selective and selective manner, and application products using the same;

First, as a material that provides adhesion and appearance, acrylic, epoxy, polyvinyl alcohol, polyvinyl acetate, silicone, poly with a solid content of 1 to 100% by weight. Polyurethane, Ethylenevinyl Acetate, Polyvinyl Chloride, Vinyl Acetate Acrylic Copolymer, Acrylic Copolymer. Gum Rosin, 2-Ethylhexyl 2-Propenoate, 2-Ethyl Hexyl Acryl Acid, N-Butyl Ester, Resin, Solution or Acid, Primer, Emulsion, Copolymer, Resorcinol, α-olefin (Butyl 2-Propenoic Chloroprene Rubber), n-Butylacrylate α-Olefin), Isocyanate, Phenolic, Thermosoftening Plastic [PVC (Polyviny chloride), Polyester, PVC sol, PP (Polypropylene), ABS (Acrylonitrile Butadiene Styrene), PMMA (Polymethlmethacrylate), PE (Polyethylene) ), PET (Polyethylene Terephthalate), PBT (Polybuthylene Terephthalate), PPS (Polyphenylene Sulfide), PC (PolyCabonate), Nylon, LDPE (Low Density Polyethylene), HDPE (High Density Polyethylene), Polystyrene any one or a mixture of two or more], Thermosetting Plastic (Phenol, Urea, Melamine, Polyurethane, Unsaturated Polyester, Silicon Resin alone or a mixture of two or more), Starch, Rice, Wheat, Bran, Corn, Potato, Dextrin, Modified starch, Glutinous Rice, Nori, Gelidium amansii Substances made from seaweed such as LAMOUROUX, grains such as dextrin, modified starch, etc., powder Among the grasses (manufacturers Germany's H company, Korea's E company, K company, Y company, etc. powdered grass is used); Characterized by including the use of 1 to 99% by weight alone or in a mixture of two or more,

One of the main purposes of the present invention is electromagnetic wave blocking, antistatic, antibacterial/mildew, flame retardant abnormality, freezing prevention, and the mixing ratio of additive materials that selectively and selectively exhibit anti-corrosion performance. Sodium Chloride, Magnesium Chloride, Calcium Chloride belonging to metal chlorides of % hydrous nH ₂ O (n=0~99) (European, African, Asian, North American, South American, Oceania, especially domestic products that are easy to secure , Asian acid, etc.) were prepared in the form of a powder or an aqueous solution thereof and used in an amount of 0 to 50% by weight, or used alone or in a mixed composition of two or more thereof; 1 to 100% by weight of solids Salt is edible salt with sodium chloride as the main ingredient, sea salt and industrial salt materials used as chemicals, East Sea, West Sea, South Sea, Mediterranean Coast, Pacific Ocean, Atlantic Ocean, Indian Ocean, Arctic Ocean, Antarctic Ocean, Dead Sea, Black Sea, etc. (Europe, Africa, Asian, North American, South American, Oceania) Salt salt produced in Asia, Europe and West Sea such as USA, Australia (Australia), China, Philippines, Vietnam or Africa, America , produced in salt mines (rock salt) on six continents such as Tibet - The salt of the present invention is largely classified into sea salt and refined salt. Sea salt is a thick, translucent hexagonal crystal made by drawing seawater to a salt farm and evaporating harmful components along with moisture with wind and sunlight. On the other hand, refined salt is a crystal of sodium chloride obtained by electrolyzing seawater to remove impurities and heavy metals with an ion resin film. In Korea, it is produced a lot in the west coast or south coast where the water depth is not deep and the tidal difference is large, and it is also produced in Asia and Europe such as the Indian Ocean, the Mediterranean coast, the United States, Australia, China, and the Philippines. Sinan-gun, Jeollanam-do accounts for 65% of the domestic solar salt production and more than half of the salt farm area, and its quality is excellent worldwide. In addition, salt containing sulfur produced in the vicinity of Baengnyeongdo is considered a commodity. Cheonil Salt Farms in Korea usually consist of a reservoir, an evaporation pond, and a crystallization pond. At high tide, the sluice gate is opened to make concentrated brine in the evaporation pond and send it to the crystallization area to obtain salt crystals. When the wind is strong, the crystals are small, and when the temperature is low, the salt tastes bitter and the quality of salt decreases. The sea salt produced in Korea is alkaline and its salinity is about 88%. Since sea salt has a lot of minerals and moisture such as Ca, Mg, Zn, K, and Fe, it is good for pickling vegetables or fish and is mainly used for making kimchi, soy sauce, and soybean paste. While it contains many minerals that are good for the body, but also contains some toxic substances, it must be removed and consumed. In addition, sea salt has high hygroscopicity due to various minerals, and has anti-corrosive effect by sterilizing power beyond antibacterial. Source: Doosan Encyclopedia, S Salt Farm, Sinan, Company G, refer to the data search data and the inventor's knowledge), - Use 0-50% by weight alone or in combination of two or more; Magnesium Chloride 15~19%, Magnesium Sulfate 6~9%, Potassium Chloride 2~4%, Sodium Chloride 2~6%, Magnesium Bromide 0.2~0.4%, etc. Solid content 1~69% by weight bittern, or 100g of these 0 to 50% by weight of 5 to 90% concentration by heating; Where antibacterial power is more needed, 0-50% by weight of purified salt that does not contain any bacteria is used instead of sea salt to further secure antibacterial and anti-mildew effects. used to eradicate all bacteria; When manufacturing a product, 0.01 to 5% by weight of acid (pH<4) is mixed with some products to remove not only the miscibility of the adhesive material but also the adhesive and self-retaining bacteria of the composition; Among the above-mentioned calcium chloride and sodium chloride of hydrous nH ₂ O (n=0 to 99) having a solid content of 1 to 100% by weight, these substances are treated with an acid, etc. Use alone or two or more 0 to 50% by weight; As an ionic compound with a solid content of 5 to 100% by weight - In the ionic compound used in the present invention, a metal cation and a non-metal anion are combined by electrostatic attraction, and the sum of the charges is electrically neutral. The element may be one or more from the group consisting of Co, Cu, Ni, Mn, Zn, Fe, Al, Be, Mg, Ca, Ba, etc., and the anionic element is a fluoride anion, a bromide anion, an iodide anion, a sulfide anion. , chloride anion, ammonium anion, hydroxide anion, sulfate anion, carbonate anion, nitrate anion, phosphate anion, permanganate anion, acetate ion, hydrogen carbonate anion, borate anion, chromate anion, dichromate anion, halogen anion, hydrochloric acid anion, organic acid anion, etc. may include one or more selected from the group consisting of, and may additionally include an ammonium salt in consideration of equipment corrosion and solution stability, and in the form of an anhydride, hydrate, or aqueous solution, these substances alone or two or more 50% by weight or 5 to 100% by weight of solid content The ionic compound uses a +1 cation metal and a -1 valent or -2 valent anion, and the cationic metal element belonging to this is from the group consisting of Li, Na, K, etc. and at least one selected from among them, the anion element is a fluoride anion, a bromide anion, an iodide anion, a sulfide anion, a chloride anion, an ammonium anion, a hydroxide anion, a sulfate anion, a carbonate anion, a nitrate anion, a phosphate anion, a permanganate anion, an acetic acid ions, hydrogen carbonate anions, boric acid anions, chromate anions, dichromate anions, halogen anions, hydrochloric acid anions, organic acid anions, etc. were included, and these substances alone in the form of anhydrides, hydrates, and aqueous solutions or 0 to 50% by weight of two or more; Solid content 0.1 to 50% by weight Conductive polymer (Polythiophene, PEDOT-PSS, Polyaniline, Polypyrrole) 0 to 50% by weight used or used; Characterized by including the use of 0 to 99% by weight alone or in a mixture of two or more,

Antistatic, antibacterial and anti-mildew, flame retardant abnormality, increase in weight, impact reinforcement, dispersion, cold resistance, viscosity increase, shortening of drying (curing) time, anti-corruption, for plastering, A hydrous aluminum silicate mineral containing alkali metal or alkaline earth metal, with a porous structure in which tetrahedra of (Si,Al)O ₄ are combined in a three-dimensional network and WmZnO _2n2 O composition formula, W is Na, Ca, Ba, Sr, and Z ＝Si+Al, quartz SiO ₂ , Zeolite in which part of Si in the three-dimensional network structure of infinitely connected diamond tetrahedral structure is replaced by Al, siliceous porous material, lightweight foamed ceramic, Silica, Perlite, Titanium Dioxide, Clay, talc , Aluminum Hydroxide, Kaolin, Magnesium Hydroxide, Calcium Carbonate, Diatomite, Loess, Bentonite, Quartz sand, Gypsum, Lime, cement, Terra alba, Pozzolan, Diatom, Pupl or water (H ₂ O) dispersed solid content 1-100 wt% Pupl or the like is used alone or in an amount of 0 to 99% by weight of two or more; Among anionic, cationic, and amphoteric surfactants, Ammonium Dodecylbenzenesulfona, Polyoxyethylenenonylphenyl Ether, Polyoxyethyleneoctylphenyl Ether, Sodium Dodecylsulfonate, Sodium Dioctylsulfosuccinate, Sodium Dodecylbenzenesulfonate, Ammonium Dodecylbenzenesulfonate, Sodium Alkylaryl dispersant, Soda organic/inorganic dispersant, Acmonium dispersant, Soda-based organic/inorganic dispersant Sodium Polycarboxyl Acid, etc.; Octylalcohol, Cyclohexane, Polydimethylsiloxan Other higher alcohols or Ethylene Glycol, Span other nonionic active agents, Silicon antifoaming agents; It is characterized in that it contains 0 to 55% by weight of each of at least one type,

For thickening and initial adhesion, cellulose type, alkali swellable type, ester type, urethane compound type, bento type, airgel type, acrylic type, etc. i.e., for example, gum arabic, jintan gum, tara gum, guar gum, agar, kera Jinan (carrageenan), sodium alginate, powdered cellulose, cellulose, methylcellulose, HEC, CMC, MC, SD, BT, EHEC, MEHEC, LBG, tararind, arabic, soybean polysaccharide, curdran, gellan, glucomannan, Soda alginate, pectin, carbomer, Hisel, gelatin, polycarboxylic acid, carboxyvinyl polymer, metal ethyl cellulose, potassium alginate, ritextose, sodium carboxymethyl starch, casein, starch; It is characterized in that it contains 0 to 55% by weight of each of at least one type,

For cold-resistant adhesive properties, Dioctyl Phthalate, Dibutyl Phthalate, Ester, etc. are used, preferably Alkyl Ester; It is characterized in that it contains 0-20% by weight alone or two or more,

For better antibacterial, anti-mildew and anti-corrosive effects after manufacturing or installation, sodium carboxymethylcellulose (CMC), chlorinated 5 Chloro 2 methyl 4 isothiazolin 3 one and unchlorinated 2 Methyl 4 isothiazolin 3 one are mixed together. 0 to 3% by weight, preferably 0 to 2% by weight of organic nitrogen sulfide and strong acids (pH <4), respectively, can be used, among 3-lodo-2 propynyl butyl carbamate and Octylisothiazolinone; It is characterized in that it comprises the use of 0-5% by weight alone or in a mixture of two or more,

Electromagnetic wave absorption and electromagnetic wave blocking, antistatic. Antibacterial/mildew, flame retardant, anti-corrosion, electrical conduction, heat conduction (adhesive) For electrode application characteristics, 0.0001~7,000㎛ Iron powder, Copper powder, Cobalt powder, Tin powder, Aluminum with various shapes such as spherical, plate, and needle shape powder, Magnesium powder, Titanium powder, Silicon powder, Nickel powder, Zinc powder, Manganese powder. Soft ferrite such as Silver powder, Ag coated Cu, Ni coated Cu, Indium tin oxide, solder ball (Free lead Tin-Bismuth), silver chloride, Antimony tin oxide, Stainless Steel, Mn (or Mg, Ni, etc.)-Zn ferrite And hard ferrite such as Ba (or Sr, etc.) ferrite, conductive carbon powder and fiber, solid content 1.0-80.0 wt% Conductive carbon sol alone or a mixture of 2 or more types 0-97.5 wt%, or these metal materials are mixed with carboxylic acid It is also characterized in that it can have a feature that can be manufactured into a product having a color by a composition prepared by surface-modifying using a fatty acid, a silane-based material, and composition of 0-90.0% by weight of a surface-modified metal material and an additive material thereof with

The solvent for dispersion is; Content 1∼99.9 wt% Methanol, Ethanol, Butanol, Dichloromethane, Ethylacetate, Hexane, Diethylether, Acetonitrile, Benzene, Dibasic Ester, 1-METHOXY-2-PROPANOL, BC, Diethylene Glycol Monoethyl Ether Acetate, Toluene, Alcohol, H ₂ O , etc; It is characterized by mixing 0 to 97% by weight alone or two or more types,

The materials for the above purpose do not matter much in the order of mixing, but it is preferable to mix compositions in approximately the order of resins, solvents, performance-imparting additives, etc., and it is characterized by including at least one material.

Therefore, the main purpose of the present invention is the compounding ratio of the additive material, the performance to exhibit complex or selective/selective performance according to the type of additive, first, by the difference in the content of the blending ratio, ① shielding electromagnetic waves at the surface resistance of 10 ³ ~ 10 ⁶ Ω/□, 10 ⁶ ~ 10 ⁹ Antistatic performance at Ω/□, ② antibacterial and anti-mildew, ③ freezing temperature change, depending on the type of additive, ① electromagnetic wave absorption and electromagnetic wave blocking, ② flame retardant (flame retardant) and semi-non-flammable, ③ anti-corrosion performance, etc. It is characterized by exhibiting this plurality or selection and selection.

In addition, wet mixing is a high-pressure disperser, high-shear mixer (in-line mixer, homomixer), premixer (stirrer), homodisperse, homogenizer, (impeller) high-speed stirrer, paste mixer, co-rotation mixer, etc. in a reactor or mixing vessel. , commonly used mixers and stirring devices (mixing containers), feed/aggregate/cement/mortar/concrete mixing machines (eg, types of powder mixers manufactured by Daekwang Construction Machinery, etc.), using single or multiple or more A method for producing a composition, characterized in that it is formulated in a production method under the conditions of -15 to 100° C., 1 to 600 minutes, and 1 to 20,000 rpm, and after preparing the composition by the method, an operator improves the composition that comes out through the mixing vessel discharge valve In addition to the traditional and current manufacturing methods of post-packaging, automated equipment is used to input raw materials and transport packaging, and fully automatic production lines such as in-line/outline PLC-controlled unmanned systems are built to enable packaging to a desired weight by automatic weighing. It is characterized in that it can also be manufactured by a manufacturing method (applicable to dry mixing manufacturing). Dry mixing is a mixture between two or more types of powder and powder, and a feed/aggregate/cement/mortar/concrete blender was mainly used at room temperature below humidity 65%RH. Mix at 65%RH, temperature -10 to 190°C, remove moisture from the powder composition to seal and package, and resin compound is composed of the above-mentioned additive material of the present invention alone or by mixing two or more types in the resin, or , characterized in that the mixed composition was formed into a pelletized resin (hereinafter referred to as a resin chempound pellet) at a processing temperature of 150 to 350 ° C using an extruder, and to make it ( It is characterized in that the product is manufactured at a processing temperature of 60 to 450° C. in an injection machine or press equipped with a mold for production.

In the same way as described above, we developed compositions and application products using the same, which have electromagnetic wave absorption, electromagnetic wave blocking, antistatic, antibacterial/mildew, flame retardant abnormality, anti-freezing, anti-corrosion performance, etc. The complex or selection/selection performance according to the type of additive material, which is the subject (main object) of the present invention, and the mixing ratio of the additive material, will be described in more detail in the specific content and claims.

As described above, a composition that exhibits electromagnetic wave absorption, electromagnetic wave blocking, antistatic, antibacterial/mildew, flame retardant abnormality, freeze prevention, and corrosion prevention performance according to the type of additive and the mixing ratio of the additive, and its application The products suppress electromagnetic waves generated from various electric and electronic products caused by electromagnetic waves and static electricity, easily remove fine dust and static electricity attached to the product surface by antistatic properties, remove static electricity, suppress various bacteria, suppress ignition in case of fire, and freeze point Prevents adhesion damage by preventing freezing in cold weather by lowering has the effect of Therefore, the present invention provides the above-mentioned functions in an unfavorable environment, - electromagnetic wave absorption, electromagnetic wave blocking, antistatic, antibacterial/mildew, flame retardant abnormality, freezing prevention, corrosion prevention function - especially by shielding (electromagnetic wave absorption and blocking) properties When applied to houses (houses, apartments, offices, places where people live, such as workplaces, places of education) and housing and packaging of electrical and electronic products, electronic components and products can be used for a comfortable life and life, and to remove electrical noise in the workplace and in the product. It is a product for painting, packing, and housing that is protected from foreign substances and has good electrical properties, especially when using an adhesive used for floor construction to reduce static electricity. Another feature is that it becomes an intermediate (complementary) product so that static electricity generated from the human body, etc. passes through the PVC conductive tile, and through the conductive adhesive of the present invention and the ground terminal to become an anti-static floor that exhibits anti-static properties. In the case of pasting or plastering walls, floors and ceilings with the composition product of the present invention, electromagnetic wave shielding, prevention of various bacteria and fungi, freezing prevention during construction, prevention of ignition/flame with flame retardant or semi-incombustible, alkali resistance It helps to prevent corrosion of reinforcing bars in concrete and to prevent neutralization of concrete.

In other words, the electrical properties capable of exhibiting the antistatic performance of the present invention include annihilation of the electric field into self-resistance heat in electromagnetic waves and reduction of the electric field through grounding, further blocking and absorbing electromagnetic waves, and the material to be composed is anionic bacteria by anion and cation, It has antibacterial power against cationic bacteria, etc., and its freezing point is lowered so that it does not freeze like antifreeze in cold weather, and it suppresses fire and smoke generation by flame retardant and flame retardant properties, and also has insect repellent ability. As described above, such a performance exhibits a function of compounding or selecting/selecting functions according to the type of additive material and the mixing ratio of the additive material of the present invention as described above.

1 is a photograph of the surface and ground resistance measurement taken after construction of conductive tile in a clean room of company A with the composition of the present invention, results thereof, and mechanism.
2 is a photograph and measurement result of a surface resistance report obtained by requesting a test researcher for a specimen manufactured using conductive carbon and an adhesive as the composition of the present invention.
Figure 3 is a real photograph of a nonwoven fabric made of an adhesive product, which is one of the compositions of the present invention.
Figure 4 is a picture taken on-site to construct an apartment with the composition product of the present invention.
5 is a conductive carbon (graphite) structure used in the present invention.
Figure 6 is a photograph and measurement result of the surface resistance and half-life report captured by requesting the specimen prepared from the composition of the present invention to Test Researcher B.
7 is an electric field measurement result with E-tester equipment before and after box inner treatment (construction) with the composition of the present invention.
8 is an electric field measurement result with an E-tester equipment before and after box inner treatment (construction) with the composition of the present invention.
9 is an electric field measurement result with a TriField meter before and after construction with the composition of the present invention
10 is a schematic diagram for explaining the theory of a metal sphere.
11 is a photograph of the electric field measurement result with HI-3604 before construction with the composition of the present invention (video captured as a photograph).
12 is a composition of the present invention in the frequency counter before construction, the light on state vs. A photo of the difference in electric field generation when the light is off (capture a video as a photo).
13 is a photograph of the electric field measurement result with HI-3604 after construction with the composition of the present invention (video captured as a photograph).
14 is a frequency counter after construction with the composition of the present invention, the light on state vs. A photo of the difference in electric field generation when the light is off (capture a video as a photo).
Figure 15 is the result of measuring the electric field with a GIGA SOLUTIONS meter before and after construction of an apartment in which the interior walls of the apartment are coated using laminated wallpaper as one of the compositions of the present invention.
16 is a schematic diagram of shielding according to the difference in received power by a shielding agent with respect to the incident power used in the present invention.
17 is an electromagnetic wave shielding system used in the present invention.
18 is a Soft-1 scanning electron microscope (SEM) photographing result of the present invention.
19 is a measurement result of the shielding rate of the sheet manufactured by the present invention.
20 is a three-roll mill according to the present invention, the composition aggregation state during two passes or less photographing results.
Figure 21 is a three roll mill according to the present invention, the composition in good condition when three or more passes are taken.
22 is a captured photograph of a surface resistance report obtained by requesting a test researcher for the composition product of the present invention.
23 is a measurement equipment Network Analyzer Mod. MS46322A, Specifications 10MHz~20GHz, Tell Cell DC~5GHz, showing the state of the equipment before measuring the electromagnetic wave absorption rate.
24 is a measurement equipment Network Analyzer Mod. MS46322A, specification 10MHz~20GHz, Tell Cell DC~5GHz, showing the state of mounting the sample for measuring the electromagnetic wave absorption rate.
25 is a capture photograph of an antibacterial test report evaluated by requesting a test researcher for a sample prepared according to the present invention.
26 is a photograph of a fungal strain experiment (video) capture for a general acrylic primer and an acrylic primer according to the present invention.
27 is a photograph of a fungal strain experiment (video) capture for an adhesive according to the present invention and a general adhesive.
28 is a mold inhibition test result in the composition according to the present invention for bread.
29 is a photograph of mold fungus growing on the outer wall of the apartment.
30 is a photograph of mold fungus generated on the living room wall of a country house.
31 is a capture photograph of an antibacterial test report evaluated by requesting a test researcher for a sample prepared according to the present invention.
Figure 32 is a sample taken after the flame test for PS foam (polystyrene foam).
33 is a representative schematic view of a foam prepared by the present invention.
34 is a schematic view of a foam with multiple flame retardant layers produced by the present invention.
35 is a schematic view of a foam having an antistatic flame retardant layer prepared by the present invention.
36 is a schematic view of wallpaper with double-sided flame retardant layers without foam according to the present invention.
37 is a schematic view of wallpaper with a flame retardant layer on one side, not a foam, according to the present invention.
38 is a photograph taken after the flame test of the laminated wallpaper and the general wallpaper manufactured by the invention.
39 is a photograph of occurrence of dew condensation.
40 is a photograph taken to prevent dew condensation according to the present invention.
41 is a change in freezing point according to the weight ratio of ethylene glycol.
42 is a diagram for explaining the phenomenon of lowering the freezing point.
43 is a refrigeration test result of two kinds of general grass and the present invention.
44 is a photograph of an external state in which a general water-based paint and a water-based paint according to the present invention are frozen and then thawed.
45 is a photograph taken after bonding the wood flooring with the composition of the present invention.
46 is a photograph taken after injecting and culturing mold fungi into the dobae grass of the present invention and the commercially available dobae grass (S company).
Figure 47 is a picture 1/2 taken after the flame test on both sides or one side coated and not coated with the composition of the present invention for general wallpaper and silk wallpaper.
Figure 48 is a photo 2/2 taken after the flame test for both sides or one side coated and uncoated of normal wallpaper and silk wallpaper with the composition of the present invention.
49 is an adhesion test after completely freezing and thawing in two types of dobae grass and general dobae grass among the compositions of the present invention.
Figure 50 is a photograph of the appearance of the thawed state after complete freezing of the dobae grass and the general dobae grass of the present invention.
51 is a result of testing the corrosion state of the screw surface after immersing the screw in the plastering pool of the present invention and the general plastering pool and leaving it for a long time.
52 is a photograph of a captured surface resistance measurement result after application with the plastering finishing material composition of the present invention.
Fig. 53 is a photograph taken in which the degree of corrosion is evaluated over a long period of time in the present invention.
54 is a photograph of a captured surface resistance measurement result after application with another plastering finishing material composition of the present invention.
55 is an electric field measurement result with an E-tester equipment after box inner treatment (construction) with the plastering finishing material composition of the present invention.
56 is a captured photo of the far-infrared emissivity measurement result evaluated by requesting the testing researcher for the plaster finishing material of the present invention.
57 is a photograph taken of the ocher plaster finishing material composition prepared according to the present invention.
58 is an electric field measurement result with E-tester equipment after box inner treatment (construction) with the loess plaster finishing material of the present invention.
59 is an ant extermination experiment of the composition according to the present invention.
60 is a photograph of a fire generation mechanism and actual ignition scene due to static electricity at a gas station.

Hereinafter, the present invention will be described in more detail. There may be a plurality of preferred embodiments of the present invention, and the following will be described in detail below based on the consideration of the phenomena of the above-mentioned problems, the solving principles and methods, etc., and through these preferred examples and drawings, the object, features, It will be possible to understand better through detailed descriptions of the current status, selection and screening performance, and effects. In addition, it will be possible to understand the content of the present invention more specifically through testing and measurement. And like reference numbers in each drawing refer to like components.

The present invention provides a composition and method for selectively or selectively exhibiting electromagnetic wave absorption, electromagnetic wave blocking, antistatic, antibacterial/mildew, flame retardant abnormality, freezing prevention, and corrosion prevention performance according to the type of additive material and the mixing ratio of the additive material, The present invention relates to a structural product, a product construction method, an applied product, and the like characterized by the structure of the present invention. In order to realize the above object, in order to realize the composition and application products using the materials exhibiting electromagnetic wave absorption, electromagnetic wave blocking, antistatic, antibacterial/mildew, flame retardant abnormality, freezing prevention, and corrosion prevention performance;

First, as a material that provides adhesion and appearance, acrylic, epoxy, polyvinyl alcohol, polyvinyl acetate, silicone, poly with a solid content of 1 to 100% by weight. Polyurethane, Ethylenevinyl Acetate, Polyvinyl Chloride, Vinyl Acetate Acrylic Copolymer, Acrylic Copolymer. Gum Rosin, 2-Ethylhexyl 2-Propenoate, 2-Ethyl Hexyl Acryl Acid, N-Butyl Ester, Resin, Solution or Acid, Primer, Emulsion, Copolymer, Resorcinol, α-olefin (Butyl 2-Propenoic Chloroprene Rubber), n-Butylacrylate α-Olefin), Isocyanate, Phenolic, Thermosoftening Plastic [PVC (Polyviny chloride), Polyester, PVC sol, PP (Polypropylene), ABS (Acrylonitrile Butadiene Styrene), PMMA (Polymethlmethacrylate), PE (Polyethylene) ), PET (Polyethylene Terephthalate), PBT (Polybuthylene Terephthalate), PPS (Polyphenylene Sulfide), PC (PolyCabonate), Nylon, LDPE (Low Density Polyethylene), HDPE (High Density Polyethylene), Polystyrene any one or a mixture of two or more], Thermosetting Plastic (Phenol, Urea, Melamine, Polyurethane, Unsaturated Polyester, Silicon Resin alone or a mixture of two or more), Starch, Rice, Wheat, Bran, Corn, Potato, Dextrin, Modified starch, Glutinous Rice, Nori, Gelidium amansii Substances made from seaweed such as LAMOUROUX, grains such as dextrin, modified starch, etc., powder Among the grasses (manufacturers Germany's H company, Korea's E company, K company, Y company, etc. powdered grass is used); Characterized by including the use of 1 to 99% by weight alone or in a mixture of two or more,

One of the main objects of the present invention is electromagnetic wave blocking, antistatic, antibacterial/mildew, flame retardant abnormality, freezing prevention, corrosion prevention, and the mixing ratio of additive materials that selectively and selectively exhibit insect repellent performance, as an additive material, solid content 1 Sodium Chloride, Magnesium Chloride, Calcium Chloride (European, African, Asian, North American, South American, _Oceanian , especially easily produced in the form of a powder or an aqueous solution thereof, such as domestic and Asian acids), etc., and used in an amount of 0 to 50% by weight, or used alone or in a mixture composition of two or more thereof; 1 to 100% by weight of solids Salt is edible salt with sodium chloride as the main ingredient, sea salt and industrial salt materials used as chemicals, East Sea, West Sea, South Sea, Mediterranean Coast, Pacific Ocean, Atlantic Ocean, Indian Ocean, Arctic Ocean, Antarctic Ocean, Dead Sea, Black Sea, etc. (Europe, Africa, Asian, North American, South American, Oceania) Salt salt produced in Asia, Europe and West Sea such as USA, Australia (Australia), China, Philippines, Vietnam or Africa, America , produced in salt mines (rock salt) on six continents such as Tibet - The salt of the present invention is largely classified into sea salt and refined salt. Sea salt is a thick, translucent hexagonal crystal made by drawing seawater to a salt farm and evaporating harmful components along with moisture with wind and sunlight. On the other hand, refined salt is a crystal of sodium chloride obtained by electrolyzing seawater to remove impurities and heavy metals with an ion resin film. In Korea, it is produced a lot in the west coast or south coast where the water depth is not deep and the tidal difference is large, and it is also produced in Asia and Europe such as the Indian Ocean, the Mediterranean coast, the United States, Australia, China, and the Philippines. Sinan-gun, Jeollanam-do accounts for 65% of the domestic solar salt production and more than half of the salt farm area, and its quality is excellent worldwide. In addition, salt containing sulfur produced in the vicinity of Baengnyeongdo is considered a commodity. Cheonil Salt Farms in Korea usually consist of a reservoir, an evaporation pond, and a crystallization pond. At high tide, the sluice gate is opened to make concentrated brine in the evaporation pond and send it to the crystallization area to obtain salt crystals. When the wind is strong, the crystals are small, and when the temperature is low, the salt tastes bitter and the quality of salt decreases. The sea salt produced in Korea is alkaline and its salinity is about 88%. Since sea salt has a lot of minerals and moisture such as Ca, Mg, Zn, K, and Fe, it is good for pickling vegetables or fish and is mainly used for making kimchi, soy sauce, and soybean paste. While it contains many minerals that are good for the body, but also contains some toxic substances, it must be removed and consumed. In addition, sea salt has high hygroscopicity due to various minerals, and has anti-corrosive effect by sterilizing power beyond antibacterial. Source: Doosan Encyclopedia, S Salt Farm, Sinan, Company G, refer to the data search data and the inventor's knowledge), - Use 0-50% by weight alone or in combination of two or more; Magnesium Chloride 15~19%, Magnesium Sulfate 6~9%, Potassium Chloride 2~4%, Sodium Chloride 2~6%, Magnesium Bromide 0.2~0.4%, etc. Solid content 1~69% by weight bittern, or 100g of these 0 to 50% by weight of 5 to 90% concentration by heating; Where antibacterial power is more needed, 0-50% by weight of purified salt that does not contain any bacteria is used instead of sea salt to further secure antibacterial and anti-mildew effects. used to eradicate all bacteria; When manufacturing a product, 0.01 to 5% by weight of acid (pH<4) is mixed with some products to remove not only the miscibility of the adhesive material but also the adhesive and self-retaining bacteria of the composition; Among the above-mentioned Calcium Chloride and Sodium Chloride of hydrous nH2O (n=0 to 99) having a solid content of 1 to 100% by weight, these substances are treated with an acid, etc. or two or more are used in an amount of 0 to 50% by weight; As an ionic compound with a solid content of 5 to 100% by weight - In the ionic compound used in the present invention, a metal cation and a non-metal anion are combined by electrostatic attraction, and the sum of the charges is electrically neutral. The element may be one or more from the group consisting of Co, Cu, Ni, Mn, Zn, Fe, Al, Be, Mg, Ca, Ba, etc., and the anionic element is a fluoride anion, a bromide anion, an iodide anion, a sulfide anion. , chloride anion, ammonium anion, hydroxide anion, sulfate anion, carbonate anion, nitrate anion, phosphate anion, permanganate anion, acetate ion, hydrogen carbonate anion, borate anion, chromate anion, dichromate anion, halogen anion, hydrochloric acid anion, organic acid anion, etc. may include one or more selected from the group consisting of, and may additionally include an ammonium salt in consideration of equipment corrosion and solution stability, and in the form of an anhydride, hydrate, or aqueous solution, these substances alone or two or more 50% by weight or 5 to 100% by weight of solid content The ionic compound uses a +1 cation metal and a -1 valent or -2 valent anion, and the cationic metal element belonging to this is from the group consisting of Li, Na, K, etc. and at least one selected from among them, the anion element is a fluoride anion, a bromide anion, an iodide anion, a sulfide anion, a chloride anion, an ammonium anion, a hydroxide anion, a sulfate anion, a carbonate anion, a nitrate anion, a phosphate anion, a permanganate anion, an acetic acid ions, hydrogen carbonate anions, boric acid anions, chromate anions, dichromate anions, halogen anions, hydrochloric acid anions, organic acid anions, etc. were included, and these substances alone in the form of anhydrides, hydrates, and aqueous solutions or 0 to 50% by weight of two or more; Solid content 0.1 to 50% by weight Conductive polymer (Polythiophene, PEDOT-PSS, Polyaniline, Polypyrrole) 0 to 50% by weight used or used; Characterized by including the use of 0 to 99% by weight alone or in a mixture of two or more,

Antistatic, antibacterial/mildew, flame retardant abnormality, increase in weight, impact reinforcement, dispersion, cold resistance, viscosity increase, shortening of drying (curing) time, corrosion prevention, and plastering, various shapes such as 0.0001~7,000㎛ spherical shape, plate shape, needle shape, etc. A hydrous aluminum silicate mineral containing alkali or alkaline earth metals with a porous structure in which (Si,Al)O4 tetrahedra are combined in a three-dimensional network and WmZξO2ξ2O composition formula, W is Na, Ca, Ba, Sr, and Z=Si+Al , Quartz SiO2, Zeolite in which a part of Si in the three-dimensional network structure of infinitely connected diamond tetrahedral structure is substituted by Al, siliceous porous material, lightweight foamed ceramic, Silica, Perlite, Titanium Dioxide, Clay, talc, Aluminum Hydroxide , Kaolin, Magnesium Hydroxide, Calcium Carbonate, Diatomite, Loess, Bentonite, Quartz sand, Gypsum, Lime, cement, Terra alba, Pozzolan, Diatom, Pupl or water (H2O) dispersed solid content 1~100% by weight Pupl, etc. alone or or 0 to 99% by weight of two or more; Among anionic, cationic, and amphoteric surfactants, Ammonium Dodecylbenzenesulfona, Polyoxyethylenenonylphenyl Ether, Polyoxyethyleneoctylphenyl Ether, Sodium Dodecylsulfonate, Sodium Dioctylsulfosuccinate, Sodium Dodecylbenzenesulfonate, Ammonium Dodecylbenzenesulfonate, Sodium Alkylaryl Esterlic Dispersant, Soda-based dispersant, Soda-based dispersant, Sodium Alkylaryl Esterlic, Phosphate Sodium Polycarboxyl Acid; Octylalcohol, Cyclohexane, Polydimethylsiloxan Other higher alcohols or Ethylene Glycol, Span other nonionic active agents, Silicon antifoaming agents; It is characterized in that it contains 0 to 55% by weight of each of at least one type,

For thickening and initial adhesion, cellulose type, alkali swellable type, ester type, urethane compound type, bento type, airgel type, acrylic type, etc. i.e., for example, gum arabic, jintan gum, tara gum, guar gum, agar, kera Jinan (carrageenan), sodium alginate, powdered cellulose, cellulose, methylcellulose, HEC, CMC, MC, SD, BT, EHEC, MEHEC, LBG, tararind, arabic, soybean polysaccharide, curdran, gellan, glucomannan, Soda alginate, pectin, carbomer, Hisel, gelatin, polycarboxylic acid, carboxyvinyl polymer, metal ethyl cellulose, potassium alginate, ritextose, sodium carboxymethyl starch, casein, starch; It is characterized in that it contains 0 to 55% by weight of each of at least one type,

For cold-resistant adhesive properties, Dioctyl Phthalate, Dibutyl Phthalate, Ester, etc. are used, preferably Alkyl Ester; It is characterized in that it contains the use of 0-20% by weight alone or two or more,

For better antibacterial and anti-rust and anti-corrosive effects after manufacturing or construction, sodium carboxymethylcellulose (CMC), chlorine-treated 5 Chloro 2 methyl 4 isothiazolin 3 one and unchlorinated 2 Methyl 4 isothiazolin 3 one, strong acids ( pH <4) 0 to 3% by weight, preferably 0 to 2% by weight, respectively, among 3-lodo-2 propynyl butyl carbamate and Octylisothiazolinone; It is characterized in that it comprises the use of 0-5% by weight alone or in a mixture of two or more,

Electromagnetic wave absorption and electromagnetic wave blocking, electromagnetic wave shielding (those that exhibit both electromagnetic wave absorption and electromagnetic wave blocking at the same time are called shielding), antistatic. Iron powder, Copper powder, Cobalt powder, Tin powder, Aluminum powder with various shapes such as spherical shape, plate shape, needle shape, etc. of 0.0001~7,000㎛ for antibacterial and anti-mildew, flame retardant, corrosion prevention, electrical conduction, heat conduction (adhesion) electrode application characteristics , Magnesium powder, Titanium powder, Silicon powder, Nickel powder, Zinc powder, Manganese powder. Soft ferrite such as Silver powder, Ag coated Cu, Ni coated Cu, Indium tin oxide, solder ball (Free lead Tin-Bismuth), silver chloride, Antimony tin oxide, Stainless Steel, Mn (or Mg, Ni, etc.)-Zn ferrite and hard ferrite such as Ba (or Sr) ferrite, conductive carbon powder and fiber, solid content 1.0-80.0 wt% Conductive carbon sol alone or a mixture of two or more types 0-97.5 wt%, or these metal materials with carboxylic acid It is also characterized in that it can have a feature that can be manufactured into a product having a color by a composition prepared by surface-modifying using a fatty acid, a silane-based material, and a composition of 0-90.0% by weight of a surface-modified metal material and an additive material thereof with

The solvent for dispersion is; Content 1~99.9% by weight Methanol, Ethanol, Butanol, Dichloromethane, Ethylacetate, Hexane, Diethylether, Acetonitrile, Benzene, Dibasic Ester, 1-METHOXY-2-PROPANOL, BC, Diethylene Glycol Monoethyl Ether Acetate, Toluene, Alcohol, H ₂ O , My back; It is characterized by mixing 0 to 97% by weight alone or two or more types,

The materials for the above purpose do not matter much in the order of mixing, but it is preferable to mix compositions in approximately the order of resins, solvents, performance-imparting additives, etc., and it is characterized by including at least one material.

Therefore, the main purpose of the present invention is the performance to exhibit complex or selective selection according to the type of additive material and the mixing ratio of the additive material, ① electromagnetic wave absorption and electromagnetic wave blocking, ② flame retardant (flame retardant) and semi-non-flammable, ③ It is characterized in that ① electromagnetic wave blocking (electromagnetic wave reduction) and antistatic, ② antibacterial and anti-mildew, ③ freezing temperature change, etc. are selectively or selectively exhibited by the difference in corrosion prevention performance and mixing ratio content.

In addition, wet mixing is a high-pressure disperser, high-shear mixer (in-line mixer, homomixer), premixer (stirrer), homodisperse, homogenizer, (impeller) high-speed stirrer, paste mixer, co-rotation mixer, etc. in a reactor or mixing vessel. , commonly used mixers and stirring devices (mixing containers), feed/aggregate/cement/mortar/concrete mixing machines (eg, types of powder mixers manufactured by Daekwang Construction Machinery, etc.), using single or multiple or more A method for producing a composition, characterized in that it is formulated in a production method under the conditions of -15 to 100° C., 1 to 600 minutes, and 1 to 20,000 rpm, and after preparing the composition by the method, an operator improves the composition that comes out through the mixing vessel discharge valve In addition to the traditional and current manufacturing methods of post-packaging, automated equipment is used to input raw materials and transport packaging, and fully automatic production lines such as PLC-controlled unmanned systems in the in-line outline are built to allow packaging to a desired weight by automatic weighing. It is characterized in that it can also be manufactured by a method (applicable to dry mixing manufacturing).

Furthermore, dry mixing is a mixture between two or more types of powder and powder, and a feed/aggregate/cement/mortar/concrete blender is mainly used at room temperature below humidity 65% RH, but preferably humidity 0 when mixing in the mixing container. Mix at ~65%RH, temperature -10~190℃, and remove moisture from the powder composition to seal and pack, and the resin compound is composed of the above-mentioned additive material of the present invention alone or by mixing two or more types in the resin, or , characterized in that the mixed composition is formed into a resin (hereinafter referred to as a resin chempound pellet) that is pelletized at a processing temperature of 150 to 350 ° C using an extruder, and to make it also It is characterized in that the product is manufactured at a processing temperature of 60 to 450 ° C in an injection machine or press equipped with a mold in the shape of (to be produced).

In the same way as described above, according to the type of additive, the mixing ratio of the additive, and the manufacturing method, electromagnetic wave absorption, electromagnetic wave blocking, antistatic, antibacterial and anti-mildew, flame retardant abnormality, freezing prevention, corrosion prevention, insect repellent performance, etc. are combined or selected and selected. We developed a composition that exerts a positive effect and application products using it.

1 to 65% by weight of solid content of Acrylic Emulsion, Polyvinyl Acetate, and Polyvinyl Chloride 15 to 55% by weight of each mixture, 65 to 84% by weight of H2O, 1 to 10% by weight of 0thers Composition to 2-EHAM: BAM = 2~3:1 ratio of 30~99% by weight, CaCO3 10~50% by weight, H2O 10~60% by weight, others 0.01~5% by weight mixed composition or acrylic copolymer 45~55% by weight, CaCO3 30~40%, H2O 10-20 wt%, Gum Rosin 5-10 wt%, 0thers 1-70 wt% Acrylic sealant or silicon sealant alone or 2 or more types 0-90 wt% in 1 to 90 wt% of 1 to 2 or more in the composition make up; - Others are substances that correspond to the above-mentioned electromagnetic wave shielding, increase in weight, impact reinforcement, beauty, dispersion, cold resistance, viscosity increase, dispersant, etc. - 0~20 wt% of calcium chloride powder, 0~ 20% by weight, conductive carbon powder and fiber 0 to 30% by weight, solids 1 to 80% by weight 0 to 80% by weight of conductive carbon sol An adhesive that exhibits the main function of electromagnetic wave blocking and antistatic performance, either alone or in combination As a result of the evaluation as follows, the adhesive properties and workability were good as well as excellent electrical properties. Test standard ANSI/ESD STM 11.11-2015, test environment 23℃, 50%RH, Resistance Meter (Manufacturer Trek) Model As a result of measuring with 152, it was 10 ⁴ to 10 ⁶ Ω/□ that satisfies the cleanroom SPEC. The result of measuring the surface resistance after the antistatic tile construction with the composition of the present invention was photographed and shown in FIG. 1 . As a result of measuring the surface resistance after on-site construction, it was found to be 10 ⁵ Ω/□ at a humidity of 45%RH, so it was confirmed that the antistatic tile constructed with the composition of the present invention satisfies the cleanroom construction SPEC. 1 shows a scene in the center of FIG. 1 of measuring the resistance after drying in order to check the conductivity of the adhesive of the present invention in the construction of company A's clean room with the composition of the present invention, and shown at the bottom of FIG. 1 , static electricity When the antistatic tile is adhered with an adhesive having electrical characteristics for floor construction for reduction (clean room), static electricity generated from the human body or equipment during work passes through the antistatic tile and escapes through the adhesive of the present invention and the grounding terminal. It is exhibited as another feature to become an antistatic floor (clean room) that exhibits antistatic (static prevention) properties. And the surface resistance meter used after construction is Wolfgang Warmbier's Surface Resistance Meter SRMⓡ110/Made in EURO.

And FIG. 2 is an evaluation by request of Test Researcher A, and after manufacturing 2 to 30% by weight of carbon sol in the PVA, test standard ANSI/ESD STM 11.11-2015, test environment 23℃, 50%RH, Resistance Meter (Manufacturer Trek) As a result of measurement with Model 152, the surface resistance was 1.05×10 ⁴ ~1.23×10 ⁴ Ω/□, indicating that it was an adhesive with electromagnetic wave blocking properties.

And, for evaluation of the adhesive strength of the composition adhesive of the present invention, which is one of the most important characteristics, the adhesive strength evaluation was conducted at room temperature 23°C and low temperature 10°C, respectively, for 2hr, 4hr, 24hr, and 168hr after bonding. It was carried out at ℃, 45% RH, and the open time before bonding was 20 min. After unification, the results are shown in Table 5.

Item composition 1 composition 2 composition 3 25℃ 10℃ 25℃ 10℃ 25℃ 10℃ 90° peel
Adhesive strength (Kg _f /25mm) after 2hr 1.2 0.9 2.1 1.6 2.9 2.5 after 4hr 2.6 2.0 3.4 3.0 4.4 4.1 after 24hr 7.6 5.8 7.9 7.1 77 7.4 after 168hr 9.7 7.8 10.7 9.9 11.9 12.8

As can be seen from Table 5, it can be seen that the adhesive according to the present invention has good adhesion.

[Adhesive strength test method]

(1) Adhesive strength at room temperature (23℃)

① Apply adhesive to flat cement, plywood, and plastic plates with a spatula.

② After leaving the open time for 10 to 60 min, the tile specimen was pressed and attached to a flat plate, especially a plastic plate.

③ After 2 hr, 4 hr, 24 hr, and 168 hr of drying time at room temperature, respectively, the specimen was peeled at 90° and measured.

(2) Cold-resistant adhesive strength

① In a thermostat at 10℃, the adhesive was applied on a flat plate with a spatula.

② After leaving the open time for 10 to 60 min, the tile specimen was pressed and attached to a flat plate, especially a plastic plate.

③ After 2 hr, 4 hr, 24 hr, 168 hr, and 168 hr, respectively, in a thermostat at 10° C., peeled at 90° and measured.

Fig. 3 shows the real paper medium prepared by gravure printing with 80 rolls on paper after preparing by preparing 2-30 weight% of carbon sol with a solid content of 1 to 80% by weight in an acrylic emulsion with a solid content of 1 to 65% by weight. And the actual construction scene of the apartment with a product composed of carbon sol in acrylic emulsion as the main adhesive is shown in FIG. 4 . As described above, the composition of the present invention is an example showing the diversity of application fields by being characterized in that it can be used with various application products and actual construction. And as a result of measuring the surface resistance by requesting the construction product to the testing institute, it was 2.5×10 ⁶ Ω/□, which is shown in FIG. 4 .

And the Republic of Korea Patent Application Nos. 10-0526673 and 10-0522267, which were mentioned in the technology that is the background of the invention, are mainly in "There is no specific technology for the conductive carbon black (conducting carbon) used and the adhesive."

First, carbon is a living material that has been used for a long time. Carbon black is one of the materials that have been used in various ways ranging from ink, ink, and rubber reinforcing agents, and activated carbon is used as a deodorant, solvent recovery, and catalyst. Here, carbon is produced by pyrolysis or incomplete combustion of hydrocarbons. The manufacturing method is divided into pyrolysis method and incomplete combustion method. Depending on the manufacturing method, it has various uses due to its high surface area and unique surface. About 85% of carbon consumption is for rubber, and about 11% is used for printing ink and conductive carbon. Carbon is a structure in which layers of a carbon hexagonal net of graphite-like structure are overlapped and connected in a chain shape. In the case of graphite, there are three lines per atom. The layer lattice of the graphite structure with weak van der waals forces between layers and strong covalent bonds within the layers is anisotropic in physical properties, and the dotted line shown in FIG. 5 is a weak pi bond between layers, and the pi bond (pi bonds, π bonds) are responsible for the conduction of electricity through graphite. A pi bond is a chemical bond caused by the superposition of electron orbitals of neighboring atoms in a molecule. Unlike a sigma bond, a pi bond is centered on the x-axis or y-axis, so the electron density on the z-axis connecting both atomic nuclei is zero. The pi bond is named from the Greek letter (π) meaning p orbital. And the valence electron is the outermost electron of an atom and plays the biggest role in determining molecular bonds and chemical properties. A carbon atom in the neutral state has 4 valence electrons. 3 out of 4 valence electrons of carbon are used, and there is one free electron that does not participate in bonding in carbon having a graphite (carbon) structure. These free electrons make graphite a conductor and conduct graphite (carbon) - One of CNT, graphene, modified graphite, or xGnP - is one of the main functional materials used in the present invention. The microstructure is needle-like, plate-like, or cubic, and a particle size of 0.0001 to 25 μm was used.

division CNT Graphene (modified) graphite or xGnP rescue 6 carbons are hexagonal and tubular A thin film composed of 6 carbons in a hexagon and 1 atom thick Single-layer graphene forms multiple layers difference Numerous studies have been made as it is known as the best thermal conductive material, but when the shape is changed, the properties change. Thus, graphene appeared as an alternative material. No change in electrical properties even when stretched or bent.
The characteristic of graphene is that the effective mass of internal electrons is 0, so there is an effect that electrons move at the speed of light in graphene. Therefore, the conductivity is high As single-layer graphene is piled up, the more the stacks are, the higher the conductivity is due to the decrease in resistance due to the collapse of the symmetry due to the overlapping of the band gap. band gap 0~1.9eV 0eV 0eV electrical conductivity 0.17~2.0-5Ω-cm ~10-6Ω-cm 104~10-7Ω-cm same
weight
compare Appearance: Fiber(1D)
Density: 1.33g/cm3 Density: 2.2g/cm3 Appearance: small and bulky
Plate-shaped thin film (3D)
Density: 1.9~2.0g/cm3 dispersion time
Properties Multi-layered structure (modified graphite) when mechanically dispersed → The laminate is broken and the number of layers is reduced to become graphene, improving mechanical properties

Another one of the mixing ratios of the present invention is 10 to 25% by weight of starch, 40 to 60% by weight of solids 0 to 15% of chloride, 1 to 35% by weight of solids, 0 to 20% by weight of sea salt, and 30 to 95% by weight of water. The composition is heated and stirred at 50 to 103°C for 1 to 600 min. A viscosity of 1,000 to 250,000 cps (using Brookfield RV DV-II + PRO) pool was prepared under the conditions of 1 to 20,000 rpm. In the case of construction using the prepared glue, it was additionally mixed with water 1 to 0.3 times and applied (eg, wallpaper). At this time, as a result of measuring the surface resistance of the prepared and used glue after drying, it was confirmed that it had antistatic properties and electromagnetic wave shielding properties as 10 ⁵ ~ 10 ⁹ Ω/□ at 45%RH. The measuring instrument used at this time was Wolfgang Warmbier's Surface Resistance Meter SRMⓡ110/Made in EURO to evaluate the resistance. As shown in FIG. 6, the test conditions, applied voltage 500V, 60 sec, 20°C, 65%RH, and the test equipment is 5.1×10 as a result of measurement according to TOA SME-8511, D1=1.96cm, D2=2.41cm Resistance values of ⁷ Ω/□ (half-life 1.5 sec) and 4.3×10 ⁸ Ω/□ (half-life 2.1 sec) were obtained.

In particular, adhesion and coating containing 20% by weight of solid content, 60 to 83% by weight of adhesive material, 48% by weight of solid content, 11% by weight of chloride, 25% by weight of solid content, 6% by weight of salt solution, which is another one of the mixing ratios of the present invention, and other H2O 7 shows the results of measuring the degree of reduction in the electric field after the material was prepared and each of the four boxes was covered with wallpaper using the general and the present invention. As shown in FIG. 7 , it was confirmed that the measured value of PULSE's E-tester before construction was 575V/m, but after construction, it was confirmed that the place where the internal construction was performed at 0V/m is going to 0 due to the attenuation of the electric field. If the manufacturing adhesive material has three or less sides, such as a box, when the coating layer of the present invention is grounded to the ground terminal using a material that conducts electricity, the electric field (static electricity) accumulated in the coating layer (surface) escapes through the ground terminal. In case of coating (painting) more than 4 sides, the electric field is reduced by the phenomenon that the electric field is reduced to zero (0) like the inside of a metal.

Under the same conditions as in Fig. 8, it can be confirmed that the measured value of PULSE's E-tester before coating was 346V/m, but after coating, it was 11V/m, and the place where the internal coating was done goes to 0 due to the attenuation of the electric field, and another coating In the sample (Fig. 9), the measuring equipment ALPHA LAB. As a result of measuring using a TriField meter (ELF-1kHz), it was more than 1,000V/m, which is an area that cannot be measured due to excessive generation of electromagnetic waves before coating, but it was measured at 20V/m after coating.

“The electric charge inside the conductor does not move, and the electric field inside the conductor is zero. The absence of an electric field in a conductor is not because the electric field cannot penetrate the metal, but because the free electrons in the conductor stop moving and can 'stop' only when the internal electric field is zero. As the charged metal spheres exert a pushing force, the electrons move as far apart as possible from each other, and the electrons are uniformly distributed on the surface of the sphere. If you place a positive charge exactly in the center of the sphere, you will not receive any force. The electrons on the left side of the sphere pull the charge to the left, while the electrons on the right side of the sphere pull the charge to the right with an equal force. The force acting on the charge is zero. Therefore, the electric field is also zero. If the conductor is not spherical, the charge distribution is not uniform, but - if it is a cube - most of the charge is concentrated at the edges. It is the same as the principle that charges and forces are concentrated at the sharp point, but the electron distribution of the faces and edges is made so that the electric field becomes zero anywhere in the cube. If there is an electric field inside the conductor, the free electrons inside the conductor will start to move. Until equilibrium is reached, the positions of all electrons move until the electric field inside the conductor is zero. Therefore, regardless of its shape, the interior of a metal has zero electric field. In the initial state, assuming that there is an electric charge and an electric field in the conductor, the presence of an electric field means that there is a movement of the electric charge. Charges in the conductor begin to move under the influence of an electric field, and the movement of the electric charges moves in a direction that makes the electric field within it zero and continues until it becomes zero, i.e., there are no more charges. . If the electric field in the conductor does not become zero, the charges move under a force until the electric field becomes zero. This movement causes all the charges to gather on the surface of the conductor and is forced outward, where it can no longer move. This is the metal sphere theory (the theory first mentioned by the inventor) (see Fig. 10), which is why the electric field on the surface of a conductor is always perpendicular to the surface. The inside moves continuously to become a (-) ion environment. Based on this theory, the present inventor thinks that electronic components are put in a shielding bag such as an aluminum bag, etc. , it is judged that this also used the principle of the metal sphere.”

11, 12, 13, and 14, a commonly used Donggeun fluorescent lamp is installed at a height of 2.3 m equal to or similar to the height of an apartment from the floor to the ceiling, and is located at a position 1.0 m away from the floor, which is usually the height of a child. The electromagnetic wave measuring instrument HI-3604 was connected to the frequency counter (FC-1022), and the HI-3604 was displayed as an analog waveform, and the pictures were captured sequentially after shooting a video. The electric field observed by the measuring instrument before construction (painting) was 90-100V/m, and it was found that a considerable amount of the electric field was generated even when the light was off, but after construction (painting), the electric field observed by the measuring instrument was 5-6V/m, and almost an electric field was generated when the light was off An actual measurement result showing that this is not the case was obtained, and it was shown by shooting and turning on a video.

And the apartment in which they actually reside was mass-produced and manufactured in a pool manufacturing plant in the same proportion (content) as the composition of the present invention, and the interior of the apartment was painted. As shown in FIG. 15 by measuring the degree of electric field generation before and after painting in rooms 1, 2, 3, living room, kitchen, etc. of the apartment, Area 1 had an electric field of 125V/m before painting and an electric field of 61V after painting. /m, Zone 2 from 160V/m pre-padding to 99V/m post-painting, Zone 3 from 258V/m pre-padding to 73V/m post-painting, Zone 4 at 69V/m pre-padding The electromagnetic wave environment was improved with an electric field of 48V/m after coating, and the attenuation ratio fell in the area where the difference in the attenuation rate was mainly absorbed by the ceiling. It could be seen that the electromagnetic wave attenuation environment was improved as a result of this

In Example 3, a composition (composition 1) in which 3.5 to 12% by weight of salt in an antistatic material is mixed with an adhesive material of 18 to 65% by weight of solid content, and 5 to 10% by weight of seawater (collected in July in the East Sea) is mixed As shown in Table 7, the surface resistance and half-life of the composition (composition 2) and the composition (composition 3) prepared by mixing 6-30 wt% of Mn-Zn ferrite (soft-1) in the metal powder are shown. together. The composition containing salt and the composition containing seawater were as low as 10 ⁶ ~ 10 ⁷ Ω/□, and the composition containing ferrite, an insulator, had a high resistance value, but the ferrite absorbs the magnetic field instead of the electric field, and It is a composition that dissipates heat and shields.

An antibacterial test, which is another object of the present invention, was performed on the compositions, and the results are shown in Table 8. According to the results of the antibacterial test, - In Japan, children's products should be 70% or less. This is because the high antibacterial activity can eradicate all bacteria and may have a rather bad effect. - As a result of measuring the antibacterial rate against E. coli strain by KS K 0693-95, composition 1 and composition 2 obtained more than 90% antibacterial value, and composition 3 obtained more than about 30% antibacterial value. Salt, which is the main material in the present invention, does not give a chance for various germs, bacteria or microorganisms to reproduce and has properties that do not change even after a long time. Salt dissolves well in water, so it penetrates and mixes well with other substances. Salt leads the metabolism in the human body by decomposing food and excreting wastes. The biggest cause of harm to human health may be poor metabolism. It is said that when the metabolism of pushing out old things in cells and accepting new things is not done smoothly, the blood becomes acidic and immunity is weakened, increasing the risk of developing diseases. Intake of salt before and after surgery is said to speed up wound healing, which would prove that salt plays an important role. Ringer's solution also has a Na+ 130, K+ 4, Ca2+ 3, Cl- 109 ratio, similar to the human body ≒ seawater ratio. Salt quickly restores dead or destroyed cells. As described above, due to the beneficial action of salt (salt), it has a lower antibacterial activity than herbicides, but the salt (according to the present invention) material is beneficial to the human body. In addition, in the antibacterial experiment of the present invention, the bacterial solution was cultured with shaking at 25° C. for 24 hours, and the number of bacteria was measured (running frequency: 150 times/min). The measurement method was the Shake Flask method, and Escherichia Coli ATCC25922 was used.

Item unit of measure composition 1 composition 2 composition 3 Assessment Methods surface resistivity Ω/□ 2.1x10 ⁵ 1.3 x 10 ⁷ 6.4 x 10 ¹¹ KS M 3015-1997
(or ASTM D257) half-life sec 0.5 0.8 20 KS K 0555-2000, method A

composition Test analysis result (number of bacteria/ml) antibacterial immediately after contact after 24 hours (increase rate) Blank 120,000 3,180,000 -2,550.0 % (26.5 times) composition 1 120,000 897 99.6% composition 2 120,000 2,378 98,9% composition 3 120,000 57,875 51.8%

Materials that provide adhesion and appearance include acrylic, epoxy, polyvinyl alcohol, polyvinyl acetate, silicone, and polyurethane having a solid content of 1 to 100% by weight. (Polyurethane), Ethylenevinyl Acetate), Polyvinyl Chloride, Vinyl Acetate Acrylic Copolymer, Acrylic Copolymer. Gum Rosin, 2-Ethylhexyl 2-Propenoate, 2-Ethyl Hexyl Acryl Acid, N-Butyl Ester, Resin, Solution or Acid, Primer, Emulsion, Copolymer, Resorcinol, α-olefin (Butyl 2-Propenoic Chloroprene Rubber), n-Butylacrylate α-Olefin), Isocyanate, Phenolic, Thermosoftening Plastic [PVC (Polyviny chloride), Polyester, PVC sol, PP (Polypropylene), ABS (Acrylonitrile Butadiene Styrene), PMMA (Polymethlmethacrylate), PE (Polyethylene) ), PET (Polyethylene Terephthalate), PBT (Polybuthylene Terephthalate), PPS (Polyphenylene Sulfide), PC (PolyCabonate), Nylon, LDPE (Low Density Polyethylene), HDPE (High Density Polyethylene), Polystyrene any one or a mixture of two or more], Thermosetting Plastic (Phenol, Urea, Melamine, Polyurethane, Unsaturated Polyester, Silicon Resin alone or a mixture of two or more), Starch, Rice, Wheat, Bran, Corn, Potato, Dextrin, Modified starch, Glutinous Rice, Nori, Gelidium amansii Substances made from seaweed such as LAMOUROUX, grains such as dextrin, modified starch, etc., powder Among the grasses (manufacturers Germany's H company, Korea's E company, K company, Y company, etc. powdered grass is used); Use 1 to 99% by weight alone or in a mixture of two or more,

The metallic materials used are 0.0001~7,000㎛ Iron powder, Copper powder, Cobalt powder, Tin powder, Aluminum powder, Magnesium powder, Titanium powder, Silicon powder, Nickel powder, Zinc powder, Manganese powder. Soft ferrite such as Silver powder, Ag coated Cu, Ni coated Cu, Indium tin oxide, solder ball (Free lead Tin-Bismuth), silver chloride, Antimony tin oxide, Stainless Steel, Mn (or Mg, Ni, etc.)-Zn ferrite And hard ferrite such as Ba (or Sr, etc.) ferrite was used. - In the previous invention to prevent electrification, conductive fillers or surfactants were added, but these materials cause loss of mechanical properties of polymeric resins or interfacial properties. The polymer added with the activator has a surface resistance of 10 ⁹ Ω/□ or more and has a disadvantage in that the antistatic performance is poor when used alone. - Therefore, spherical and flake-shaped (or plate-shaped) metal materials with a particle diameter of 0.001-25㎛ are surface-modified using carboxylic acid, fatty acid, and silane, and 3.5-90.0% by weight of the surface-modified metal material is added to the polymer. As a result of evaluating the electric and magnetic field characteristics in the state of dispersing and dispersing the crystalline metal material on the surface (manufactured in the form of a sheet for measurement), it exhibits amorphous properties and acts as a shielding agent for a broadband electric and magnetic field and is a measure of antistatic effect. The surface resistance is measured as 10 ^-3 ~ 10 ¹³ Ω/□, and it can be used in a wide range from conductors to insulators depending on the metal material and content used. The shielding effect is defined as the ratio of the received power received through the specimen to the incident power. For a constant incident power, the difference between the received power when the material to be tested is installed on the measuring tool and when the material to be tested is not installed, that is, the insertion loss. By measuring the shielding effect can be measured. The theoretical shielding effect was calculated by Schelkunoff et al. by dividing the signal transmitting and receiving parts by an infinitely large shielding surface, and considering the reflection, absorption, and transmission processes of electromagnetic waves perpendicular to the shielding surface. The shielding ratio (%) calculation is shown by the shielding effective value (dB) obtained in the following Figures 16, 17, and Table 9.

dB Shielding rate (%) 20 90 40 99 60 99.9 90 99.99 100 99.999

Shielding Effectiveness (dB) = 20 log V1/V2

Shielding effectiveness (SE) is as follows.

SE(dB) = A + R + B

A: absorption loss

R: reflection loss

B: multiple internal reflection loss

*where A(dB) is

t: thickness of barrier f(MHz): frequency(MHz)

σ: conductivity (relative to Cu=1)

μ: magnetic permeability (relative to vacuum or Cu=1)

A is proportional to the shield thickness (t) and the conductivity (σ) and permeability (μ). The measurement error of the shielding test varies depending on the signal generator, spectrum analyzer, RF (Radio Frequency) switch, step attenuator, and measurement repeatability, but the total error range of this system is less than 5%.

Through the above experiment, - Mn-Zn ferrite (Soft-1, Table 10, Fig. 18) of the metal material is used to absorb the magnetic field and then convert it into heat to remove it - Depending on the additive material and the mixing ratio The absorption region and absorption power of the magnetic field are different, and the greater the content of the metal material with respect to the magnetic field, the better the shielding effect. A magnetic field absorbing composition was prepared by mixing 5 to 30% by weight of soft ferrite with a polymer material based on the total weight. It was found that the prepared composition sheet acts as an amorphous material by adding it in a powder state, and thus the area capable of shielding electromagnetic waves is broadened. It can be seen that FIG. 19 shows a shielding rate of 20 to 45% in the entire area of the measurement range of 10 to 1000 MHz band (measurement standard: D4935-99 Standard Test method for Measuring the Electromagnetic Shielding Effectiveness of Planar Materials).

Measurement Method Symbol Unit Soft-1 Soft-2 Soft-3 Soft-4 Surface Area (BET) m2/g 1.4 0.9 0.8 1.6 Moment Saturation EMU/g 73 60 59 83 Average Particle
Diameter (Fisher) μm 3.2 4.4 3.6 3.7 Moisture % 0.02 0.02 0.00 0.01 Initial Permeability μ _i 120 800 350 2500 Saturation Flux Density
at Filed Density B _s
H Gauss
Oersteds 3400
10 3000
10 2700
10 5000
10 Residual Flux Density Br Gauss 2500 1800 1500 1000 Coercive Force H _c Oersteds 1.5 0.2 32 0.3 Curie Temperature T _c ℃ >200 >160 >120 >190 Resistivity ρ Ω-cm <106 <105 <104 <102 Sintering Density g/cm3 5.1 5.0 4.8 4.7

And the Republic of Korea Patent Application No. 10-2000-0068297, which was mentioned in the technology that is the background of the invention, solves "the problem of difficulty in manufacturing a commercial product due to the occurrence of layer separation due to the use of a high-density radio wave absorber and high viscosity" Here's how to do it: Layer separation occurs when high-density powder and polymer have poor miscibility. As a solution to this problem, hydrophilic powder was modified using a surface treatment agent for hydrophobic treatment, for example, a carboxylic acid-based, fatty acid, and silane-based surface treatment agent. In addition, the composition having high viscosity and difficult to disperse was dispersed using a thress roll mill (three-roll mill or three-roll mill). When the number of passes of powder was less than 2 times, agglomerated parts were present (FIG. 20), but a composition suitable for application could be prepared by passing 3 to 10 times or adding a solvent during the pass (FIG. 21). The experimental photos were taken and shown in FIGS. 20 and 21 .

Acrylic, Epoxy, Polyvinyl Alcohol, Polyvinyl Acetate, Silicone, Polyurethane, Ethylenevinyl Acetate with a solid content of 1 to 100% by weight , Polyvinyl Chloride, Vinyl Acetate Acrylic Copolymer, Acrylic Copolymer. Gum Rosin, 2-Ethylhexyl 2-Propenoate, 2-Ethyl Hexyl Acryl Acid, N-Butyl Ester, Resin, Solution or Acid, Primer, Emulsion, Copolymer, Resorcinol, α-olefin (Butyl 2-Propenoic Chloroprene Rubber), n-Butylacrylate Grains such as α-Olefin), Isocyanate, Phenolic, Thermosoftening Plastic, Thermosetting Plastic, Starch, Rice, Wheat, Bran, Corn, Potato, Dextrin, Modified starch, Glutinous Rice, Nori, Gelidium amansii LAMOUROUX One or a mixture of two or more of substances manufactured from the same seaweed, grains such as dextrin, modified starch, etc. % by weight is used,

0-50 wt% of metal chloride powder or aqueous solution thereof of nH ₂ O (n=0-99) having a solid content of 1 to 100 wt% is used alone or a mixture composition of two or more thereof is used; Solid content 1-100% by weight Salt is an edible salt containing sodium chloride as the main component, sea salt and industrial materials used as chemicals, and rock salt alone or in a mixture of 2 or more types 0-50% by weight; 0-50 wt% of bittern or 100 g of these heated and concentrated 5 to 90% is used; Use 0-50% by weight of purified salt that does not contain any bacteria instead of sea salt to further secure antibacterial and anti-mildew effects, especially by treating at a high temperature of 100° C. or higher to eradicate all bacteria of the additive material itself; When manufacturing a product, 0.01 to 5% by weight of acid (pH<4) is mixed with some products to remove not only the miscibility of the adhesive material but also the adhesive and self-retaining bacteria of the composition; Among the above-mentioned calcium chloride and sodium chloride of hydrous nH ₂ O (n=0 to 99) having a solid content of 1 to 100% by weight, these substances are treated with an acid, etc. Use alone or two or more 0 to 50% by weight; In addition, 5 to 100% by weight of the solid content of the ionic compound is used alone or 2 to 50% by weight of two or more of the ionic compound in the form of an anhydride, hydrate, or aqueous solution; Solids 0.1 to 50% by weight Conductive Polymer 0 to 50% by weight, either used; Use 0 to 99% by weight alone or in a mixture of two or more,

Iron powder, Copper powder, Cobalt powder, Tin powder, Aluminum powder, Magnesium powder, Titanium powder, Silicon powder, Nickel powder, Zinc having various shapes such as 0.0001∼7,000㎛ spherical shape, plate shape, needle shape, etc. in the above single or mixed adhesive composition powder, Manganese powder. Soft ferrite such as Silver powder, Ag coated Cu, Ni coated Cu, Indium tin oxide, solder ball (Free lead Tin-Bismuth), silver chloride, Antimony tin oxide, Stainless Steel, Mn (or Mg, Ni, etc.)-Zn ferrite and 0~99% by weight of one or more of hard ferrites such as Ba (or Sr) ferrite alone or in a mixture composition to provide the main functions of electromagnetic wave absorption, electromagnetic wave blocking, antistatic, antibacterial/mildew, flame retardant, freeze prevention, and corrosion prevention performance. As a result of manufacturing and evaluating an adhesive that exhibits, it is shown in FIG. 22 that it has 10 ⁴ to ⁶ Ω/□.

The samples prepared according to Examples 1, 2, and 3 are mainly for the purpose of reducing the electric field among electromagnetic waves, and the purpose of this Example and Examples 4 and 5 is to absorb and remove electromagnetic waves from the viewpoint of the magnetic field.

Measurements are performed using the instrument Network Analyzer Mod. Using MS46322A, specification 10MHz~20GHz, Tell Cell DC~5GHz, the following test sequence was carried out. ① Install the equipment as shown in FIG. 23 before measuring the absorption rate of the measurement sample. ② Adjust the height of the sample mount and the antenna to the same height. ③ Turn on the power of the measuring equipment and preheat for 30 minutes and set up the equipment necessary for measurement. ④ When calibration is performed, the value of the measuring device is fixed at 0 dB. ⑤ If it is not fixed at 0 dB, check the height of the sample mount and antenna and set it to 0 dB. ⑥ When the calibration of the measuring equipment is finished, the sample is mounted on the sample mounting table and fixed as shown in FIG. 24 . ⑦ At this time, be careful not to move the sample holder. ⑧ After checking whether the value at 0 dB has changed in the measuring device, write it in the data sheet and save it.

Through the above procedure, the test method IEEE-SDT-1128-1998, the test environment temperature 23 ℃, humidity 44%RH, the absorption rate measurement results for six main several frequencies are shown in Table 11. As shown in Table 11, it can be seen that the product (measurement sample) manufactured using the metal powder exhibits an effect on the magnetic field.

(Unit: dB) Frequency [GHz] antistatic
paper grass Conductive carbon 3~10% in antistatic coating pool Frequency [MHz] General coating paste + Ni powder 5~30% Antistatic coating paste + Ni powder 20~30%% Antistatic coating paste + Ni powder 25~35% General paper paste + Ni powder 30~50% One - 0.47 - 0.06 200 - 0.12 - 0.12 - 0.12 - 0.15 2 - 0.40 - 0.40 400 - 0.75 - 0.80 - 0.80 - 0.86 3 - 0.40 - 1.02 600 - 4.31 - 4.33 - 4.31 - 6.05 786 - 4.43 - 5.20 - 6.32 - 9.63 4 - 0.41 - 1.66 800 - 1.54 - 1.56 - 1.54 - 1.87 5 - 0.42 - 1.14 966 - 7.50 - 9.82 - 11.40 - 19.89 1000 - 1.19 - 1.19 - 1.20 - 2.24

Acrylic, E-acrylic, Epoxy, Polyvinyl Alcohol, Polyvinyl Acetate, Silicone, Polyurethane, Ethylene Vinyl Acetate with a solid content of 1 to 100% by weight Ethylenevinyl Acetate), Polyvinyl Chloride, Vinyl Acetate Acrylic Copolymer, Acrylic Copolymer. Gum Rosin, 2-Ethylhexyl 2-Propenoate, 2-Ethyl Hexyl Acryl Acid, N-Butyl Ester, Resin, Solution or Acid, Primer, Emulsion, Copolymer, Resorcinol, α-olefin (Butyl 2-Propenoic Chloroprene Rubber), n-Butylacrylate Grains such as α-Olefin), Isocyanate, Phenolic, Thermosoftening Plastic, Thermosetting Plastic, Starch, Rice, Wheat, Bran, Corn, Potato, Dextrin, Modified Starch, Glutinous Rice, Nori, Gelidium amansii LAMOUROUX One or a mixture of two or more of substances manufactured from the same seaweed, grains such as dextrin, modified starch, etc. % by weight is used,

Sodium Chloride, Magnesium Chloride, Calcium Chloride, etc. belonging to metal chlorides of hydrated nH ₂ O (n = 0 to 99) having a solid content of 1 to 100% by weight or in the form of an aqueous solution thereof are prepared and used in an amount of 0 to 50% by weight, or a substance thereof use alone or a mixture of two or more; Solid content of 1 to 100% by weight Salt is used alone or 0 to 50% by weight of edible salt containing sodium chloride, sea salt and industrial salt used as a chemical, rock salt, or refined salt alone or in a mixture of two or more; Magnesium Chloride 15~19%, Magnesium Sulfate 6~9%, Potassium Chloride 2~4%, Sodium Chloride 2~6%, Magnesium Bromide 0.2~0.4%, etc. Solid content 1~69% by weight bittern, or 100g of these 0 to 50% by weight of 5 to 90% concentration by heating; Acid (pH <4) is mixed with 0.01 to 5% by weight to remove not only the miscibility of the adhesive material but also the adhesive and self-retained bacteria of the composition; Among the above-mentioned calcium chloride and sodium chloride of hydrous nH ₂ O (n=0 to 99) having a solid content of 1 to 100% by weight, these substances are treated with an acid, etc. Use alone or two or more 0 to 50% by weight;

In addition, 5 to 100% by weight of the solid content of the ionic compound is used alone or 2 to 50% by weight of two or more of the ionic compound in the form of an anhydride, hydrate, or aqueous solution; Solids 0.1 to 50% by weight Conductive Polymer 0 to 50% by weight, either used; Use 0 to 99% by weight alone or in a mixture of two or more,

0.0001~7,000㎛ Hydrous aluminum silicate mineral containing alkali metal or alkaline earth metal with various shapes such as spherical, plate, and needle-shaped, zeolite substituted with Al, siliceous porous material, lightweight foamed ceramic, Silica, Perlite, Titanium Dioxide, Clay, talc, Aluminum Hydroxide, Kaolin, Magnesium Hydroxide, Calcium Carbonate, Diatomite, Loess, Bentonite, Quartz sand, Gypsum, Lime, cement, Terra alba, Pozzolan, Diatom, Pupl or water (H ₂ O) dispersed solids 1 to 100% by weight Pupl or the like is used alone or 0 to 99% by weight of two or more; Among anionic, cationic and amphoteric surfactants, Ammonium Dodecylbenzenesulfona, Polyoxyethylenenonylphenyl Ether, Polyoxyethyleneoctylphenyl Ether, Sodium Dodecylsulfonate, Sodium Dioctylsulfosuccinate, Sodium Dodecylbenzenesulfonate, Ammonium Dodecylbenzenesulfonate, Ammonium Dodecylbenzenesulfonate, Sodium Alkylaryl Esterlic Dispersant, Soda-based dispersant, Soda-based dispersant, Sodium Alkylaryl Esterlic, Phosphate dispersant Sodium Polycarboxyl Acid; Octylalcohol, Cyclohexane, Polydimethylsiloxan, other higher alcohols or Ethylene Glycol, Span and other nonionic active agents, Silicon defoaming agents; It is characterized in that it contains 0 to 55% by weight of each of at least one type, and cellulose type, alkali swellable type, ester type, urethane compound type, bento type, airgel type, acrylic type, etc. That is, for example, gum arabic, jintan Gum, tara gum, guar gum, agar, kerazinan (carrageenan), sodium alginate, powdered cellulose, cellulose, methylcellulose, HEC, CMC, MC, SD, BT, EHEC, MEHEC, LBG, tararind, arabic , soybean polysaccharide, curdlan, gellan, glucomannan, soda alginate, pectin, carbomer, highcell, gelatin, polycarboxylic acid, carboxyvinyl polymer, metal ethyl cellulose, potassium alginate, ritexrose, sodium carboxymethyl starch, casein, starch among them; It is characterized in that it contains 0 to 55% by weight of each of at least one type, and uses Dioctyl Phthalate, Dibutyl Phthalate, Ester, etc., preferably Alkyl Ester; It is characterized by including the use of 0~20% by weight alone or two or more, sodium carboxymethylcellulose (CMC), chlorinated 5 Chloro 2 methyl 4 isothiazolin 3 one and unchlorinated 2 Methyl 4 isothiazolin 3 one together Mixed organic nitrogen sulfide and strong acids (pH <4) may be used in 0 to 3% by weight, preferably 0 to 2% by weight, of 3-lodo-2 propynyl butyl carbamate and Octylisothiazolinone; It is characterized in that it comprises the use of 0-5% by weight alone or in a mixture of two or more,

0.0001~7,000㎛ Iron powder, Copper powder, Cobalt powder, Tin powder, Aluminum powder, Magnesium powder, Titanium powder, Silicon powder, Nickel powder, Zinc powder, Manganese powder with various shapes such as spherical shape, plate shape, and needle shape. Soft ferrite such as Silver powder, Ag coated Cu, Ni coated Cu, Indium tin oxide, solder ball (Free lead Tin-Bismuth), silver chloride, Antimony tin oxide, Stainless Steel, Mn (or Mg, Ni, etc.)-Zn ferrite and hard ferrite such as Ba (or Sr, etc.) ferrite, conductive carbon powder and fiber, solid content 1.0-80.0 wt% Conductive carbon sol alone or a mixture of two or more types 0-97.5 wt%, or these metal materials are mixed with carboxylic acid It is also characterized in that it can have a feature that can be manufactured into a product having a color by a composition prepared by surface-modifying using a fatty acid, a silane-based material, and a composition of 0-90.0% by weight of a surface-modified metal material and an additive material thereof with

Content 1∼99.9 wt% Methanol, Ethanol, Butanol, Dichloromethane, Ethylacetate, Hexane, Diethylether, Acetonitrile, Benzene, Dibasic Ester, 1-METHOXY-2-PROPANOL, BC, Diethylene Glycol Monoethyl Ether Acetate, Toluene, Alcohol, H ₂ O My back; In order to identify the antibacterial and anti-mold characteristics, which is another object of the present invention, the specimen prepared by the composition, characterized by mixing 0-97.0% by weight of two or more types, commissioned by Test Researcher B and evaluated,

- Substances added to impart the functionality of the present invention simultaneously inhibit E. coli, Pseudomonas aeruginosa, Staphylococcus aureus, etc. or fungi, thereby simultaneously exhibiting antibacterial and anti-mildew performance; 「E. coli, Pseudomonas aeruginosa, and Staphylococcus aureus belonging to the (-) charge strain, etc., and fungi belonging to the (+) charge strain. Fungi and (+)charge are the scientific principles first mentioned by the present inventor that it adsorbs (collects) E. coli, the (-)charge strain, etc., penetrates the cell wall and kills them.” It is a product made by mixing +) charge Ag carrier zeolite and is sold as an antibacterial product that inhibits E. coli. Therefore, the result of each evaluation according to the principle by the inventor - that is, the result of the antibacterial test (shown in Fig. 25) is the test standard KS K 0693:2001, the nonionic surfactant Tweea 80, and Staphylococcus aureus ( Staphyococcus aureus ATCC 6538P) bacteriostatic reduction rate of 99.9% and pneumococcus pneumoniae (Klebsiella pneum oniae 4352) 99.9%, confirming the excellent antibacterial performance.

26 is a result of comparing the adhesive without adding the composition material of the present invention to the acrylic primer, acrylic emulsion-based adhesive and the adhesive containing 3.5% of the refined salt composition additive of the present invention as an anti-military test. As shown in Figure 26, it can be seen that there is a mold inhibitory effect. The experiment is the result of measuring the fungal strain after culturing for one week in a constant temperature and humidity chamber (experimental device). The results of comparative evaluation of the acrylic primer (acrylic emulsion) adhesive used for construction and the acrylic adhesive prepared by the present invention were captured after simultaneous shooting. Although it was confirmed that a large amount of mold is generated in the acrylic adhesive system, which is used for waterproofing or adhesion purposes, even now when the present invention is applied for a patent, it can be seen that the product of the present invention has anti-fungal properties. 27 is a result of comparative evaluation in the same method by applying the same composition ratio of the present invention to the PVA-based adhesive, and the same result as that of the acrylic adhesive was obtained. 28 is a method for additionally evaluating the superiority of the present invention, and is a result of an experiment with bread, which is highly resistant to mold. For the evaluation of the experiment, the experiment was carried out in the state that moisture was always kept on the bread for 4 days. The portion of the bread that was not in contact with the noodles prepared by the above composition had more mold than the portion of the bread that was in contact with the present invention. It can be seen that the composition containing the composition of the present invention has very good anti-mold effect as there is little or no mold occurrence. And actually, Fig. 29 is a photograph of mold on the wall of the apartment, and Fig. 30 is a photograph of mold on the wall of a country house exposed to a humid environment.

Add 40 to 85% by weight of water, 50% by weight of solid content, 3 to 30% by weight of chloride, 27% by weight of solid content, 2-30% by weight of salt solution to 12-30% by weight of strong flour, which is one of the mixing ratios of the present invention, and boil (30 ~100° C., 15-150 min. After boiling while stirring), it was prepared in a gel state. In general, the solid content is 3 to 15% by weight compared to commercially available grass, but the viscosity was low at 95,000 to 140,000 cps (in case of using a viscometer, Brookfield RVDV-II + PRO). Common grass (commercial grass) has a solid content ca. By reducing the content of water to meet 20% by weight, 135,000 ~ 140,000cps, a grass that does not freeze was prepared.

The composition of the present invention has the effect of lowering the freezing point depending on the content of the added chlorinated material - in particular, paper glue, water-soluble EVA, water-soluble acrylic, etc. - It was invented for the first time in the present invention. It wasn't easy. In other words, it is characterized by lowering the freezing point and preventing the phenomenon of freezing, and the viscosity of commercially available starch paste with a solid content of about 19 to 21% by weight is about 140,000 cps (measured by Brookfield RV DV-II + PRO). In order to lower it (to facilitate construction (painting)), water is additionally added and used. In winter, a small amount of water should be used compared to summer due to the freezing (hyp) phenomenon of water, but the adhesive composition according to the present invention Without the above concerns, it can be used in all weather, so it can be used as it is with the additional water mixing ratio of the previous plastering company. Another strength is that it is possible to secure an economic advantage by securing the quantity according to the prediction of the use of paving grass and reducing the cost of construction materials.

The motive of the present invention starts from the fact that seawater does not freeze well in winter. In order to confirm the above principle, the following test was first performed. Water starts to freeze past 0°C and freezes completely when it reaches -1.0°C, but a mixture of 0.24 g of salt and 19.76 g of water starts to freeze at -0.45°C and partially freezes at -1.0°C (salt 1.12% by weight). A mixture of 0.62 g of salt and 19.38 g of water was not frozen at -1.0°C at all, but slightly frozen at -2.0°C, and more unfrozen water remained than the previous brine (1.12% by weight of salt) (3.1% by weight of salt). As described above, as the concentration of salt increases, it is confirmed that the freezing point is lowered and thus does not freeze well, and applied to the present invention to invent a new product. When this invention is applied to a product with a high freezing point such as a water-soluble product, it lowers the freezing point like an antifreeze (a liquid used to prevent the freezing of cooling water for automobile engines), so that the original product's original adhesive strength and coating strength are lowered by freezing prevention. It prevents the loss of adhesion and coating power by maintaining its original performance.

Therefore, the present invention prevents the phenomenon of the adhesive material from freezing before drying when constructing structures, interiors, etc., such as building materials and construction in a cold environment, and, in particular, the phenomenon that the adhesive material is frozen during distribution and storage, and the adhesion ability, which is inherent in nature, is reduced. We have developed innovative technology that can be applied to fields that can prevent

Another object relates to the antibacterial properties, and the antibacterial test in which the compositions prepared according to Examples 1, 4, 5, 7, 8, 9 were evaluated by requesting the C Test Research Institute were tested according to the test standard JIS Z 2801-2010, standard film sterilized The antibacterial activity of Staphyococcus aureus ATCC 6538P was 2.5 in PP film, 0.1 mL of the inoculum solution, and the antibacterial activity was 3.1 in Escherichia coli ATCC 8739, confirming that the antibacterial performance was excellent. The antibacterial activity value of Staphyococcus aureus ATCC 6538P was 2.5, in the blank, the initial strain 5.6×10 ⁴ , the number of cells after 24 hours of incubation 2.1×10 ⁴ , and in the present invention, the number of bacteria after 24 hours of incubation was 62. when Escherichia coli ATCC 8739; In the blank, the initial strain was 4.6×10 ⁴ , the number of bacteria after culturing for 24 hours was 5.0×10 ⁴ , and in the present invention, the number of bacteria was <0.63 after culturing for 24 hours, indicating an antibacterial activity value of 3.1. The experimental results are shown in FIG. 31, and it can be confirmed that the antibacterial performance is excellent.

As one of the compositions of the invention important in the present invention, the composition of the padding; According to Examples 1, 4, 5, 7, 8, and 9, starch as one of the above compositions (grade 1, grade 2, grade 3, each alone or mixed composition of two or more) 10-40 wt%, water 30-95 Weight %, solid content 30-100 wt% Calcium chloride 3-40 wt%, solid content 20-99 wt% Salt component (sun salt, rock salt, refined salt, etc. alone or mixed use) 3-40% wt% 45-103°C, 3- 60 min. 1 to 20,000 rpm, 0.5 to 5 atm, the mixing ratio of the liquid coating composition containing preservative-free (no formaldehyde in preservatives), etc., packaged after manufacturing while stirring, and its manufacturing method; Among the above compositions, as one of the compositions of the invention, which is important in the present invention, the composition of the planting grass: 10 to 40 wt% of starch (1st grade, 2nd grade, 3rd grade, each alone or mixed composition of two or more), 30 water ~95 wt%, solid content 30-100 wt% Calcium chloride 3-40 wt%, solid content 20-99 wt% Salt component (sun salt, rock salt, refined salt, etc.) 3-40% wt% 45-103 ° C, 3-60 min. 1 to 20,000 rpm, 0.5 to 5 atm, the mixing ratio of the liquid coating composition containing preservative-free (no formaldehyde in preservatives), etc., packaged after manufacturing while stirring, and its manufacturing method; Another composition, starch (1st grade, 2nd grade, 3rd grade, each alone or mixed composition of two or more) 15 to 90% by weight of water, 15 to 30% by weight of calcium chloride solution with 45 to 50% by weight of solids %, solid content 20-35 wt% Salt component (solar salt, rock salt, refined salt, etc. alone or mixed use) 5-40 wt% solution, 0.0001-3 wt. % at 45~103℃, 3~60min. 1 to 20,000 rpm while stirring, the mixing ratio of the packaged liquid paste composition and its manufacturing method; Another composition, starch (1st grade, 2nd grade, 3rd grade, each alone or mixed composition of two or more) 15 to 90% by weight of water, 15 to 30% by weight of calcium chloride solution with 45 to 50% by weight of solids %, solid content 20-35 wt% Salt component (solar salt, rock salt, refined salt, etc. alone or mixed use) solution 5-40 wt%, anti-corruption substance (strong acid pH<4 and anti-corruption substance used in Samsung industry) 0.0001 each 45~103℃, 3~60min under composition mixing conditions including ~3% by weight. 1 to 20,000 rpm while stirring, the mixing ratio of the packaged liquid paste composition and its manufacturing method; Another composition, starch (1st grade, 2nd grade, 3rd grade, each alone or mixed composition of two or more) 15 to 90% by weight of water, 15 to 30% by weight of calcium chloride solution %, solid content 20-35 wt% Salt component (solar salt, rock salt, refined salt, etc. alone or mixed use) 5-40 wt% solution, sodium carboxymethylcellulose (CMC), chlorine-treated 5 Chloro 2 methyl 4 isothiazolin 3 one and chlorine Untreated 2 Methyl 4 isothiazolin 3 one, strong acids (pH <4) 0~3% by weight each, among 3-lodo-2 propynyl butyl carbamate and Octylisothiazolinone; 45~103℃, 3~60min under composition mixing conditions including the use of 0~5% by weight alone or in mixture of two or more. 1 to 20,000 rpm while stirring, the mixing ratio of the packaged liquid paste composition and its manufacturing method; Among the most characteristic features of the present invention, the composition (prescription) and compounding and classification of the substances to be blended in the composition are different in order to improve the long-term storage (aka, long-term storage) of the composition and manufactured product according to the season. one of

Examples 1, 4, 5, 7, 8, 9, and 11 of the composition product of the present invention, without surface coating on the PS foam (left) and the film coated with the composition of the present invention (right) After capture results are shown in FIG. 32 . When the sample before and after coating on the PS foam was lit, as a result, the right side completely melted and the PS foam of the part where there was a flame melted and disappeared, but the sample coated on the surface did not melt due to the flame retardant properties of the composition of the present invention Cotton is the result of confirming the flame retardant (flame retardant) characteristics of the present invention as a photograph showing that it remains.

One of the compositions according to Examples 1, 4, 5, 7, 8, 9, and 11 was first coated with 0.01 to 10,000 μm on one side or both sides, and the adhesive material of the composition and the aqueous adhesive used in the composition Alternatively, a method for protecting a functional part coated with the composition of the present invention by coating one or both surfaces with an adhesive material such as oil or varnish and a paint by 0.01 to 10,000 μm, and their application products, including wood and The application products that can be manufactured by coating the adhesive and paint composition according to the present invention to the same easy fire occurrence can be variously applied to various fields. Applicable application products include products featuring furniture, curtains, verticals, wallpaper, flooring, blinds, clothing, etc., and the product structure is a base material layer (or printing layer, embossing layer) 10 and plastic foam 30 ( Depending on the product, it may be a sheet other than plastic foam. Papers, plastics, etc. belong to this, and these are named sheets.) Between, for example, the compositions of Examples 1, 4, 5, 7, 8, 9, and 11 A flame retardant layer 20 made of is formed, an aluminum foil layer 40 is formed at the bottom of the plastic foam 30 , and an adhesive layer 50 and a release paper 60 are formed on the lower surface thereof. The flame retardant layer 20 suppresses or delays ignition in case of fire. The structure for this is shown in FIG. 33 and not shown in the figure, but in the case of a product constructed in a different environment, the base material layer 10 / flame retardant layer 20 / plastic foam 30 / nonwoven fabric such as polyester long fiber nonwoven fabric In case of forming and manufacturing in a structure that prevents distortion of the product as it is composed of paper/plastic foam (30)/aluminum layer (40)/adhesive layer (50)/release paper (60) Without the layer 40 and the adhesive layer 50, the release paper 60 to the composition of the present invention or the above-listed adhesive (coating) materials that are not included can be coated and then dried.

In Example 13, only one side of the plastic foam 30 is flame-retardant, but FIG. 34 is a case in which the plastic foam 30 is prepared by forming the flame-retardant layer 20 on both sides of the plastic foam 30, and the plastic foam 30 is In the case of the constituted product, when both sides of the plastic foam 30 are flame-retardant, the flame-retardant effect is further improved. Although schematically illustrated in the present invention, a person skilled in the art may further comprise a plurality or a plurality of layers, or may be manufactured without a constituent layer. For example, when wallpaper is installed on the plastic foam 30 , it may be manufactured as shown in FIG. 35 without the base material layer 10 . Here, the coating layer was made to exist with the adhesive (coating) material described in Example 13, except for the case where the upper release paper part was attached. 36 and 37, when manufactured in the same configuration as the actual wallpaper or paper wallpaper, not foam, it has electromagnetic wave absorption or electromagnetic wave blocking, antistatic, antibacterial/mildew, flame retardant abnormality, freeze prevention, corrosion prevention performance, and the like.

In the case of the flame retardant layer, it is also possible to remove the attached dust or to shield the electromagnetic wave by the antistatic function. It can be said that the electrical properties are improved according to the additive material and the blending amount of the composition. Taking carbon black as an example as an additive, when the mixing ratio is 3 wt% of carbon black to 20 wt% of solid content, the surface resistance is 10 ⁶ ~ 10 ⁸ Ω/□, and when it is 6 wt%, the surface resistance is 10 ⁵ ~ 10 ⁶ Ω/ When □, 10% by weight, the surface resistance is 10 ⁴ ~ 10 ⁵ Ω/□, and the conductive properties are improved, and the ability to exhibit electromagnetic wave blocking properties from antistatic properties is also improved. And the difference in additive material is that when PEDOT, a conductive polymer, is added instead of carbon black, the surface resistance is 10 ⁷ ~ 10 ⁸ Ω/□, antistatic performance, and when Ag powder is added, 5-5 ~ 10 ^-1 With Ω-cm, electromagnetic shielding performance can also be exhibited, and it can also be applied as an electrode material.

Examples 1, 4, 5, 7, 8, 9, 10, 11 to the composition product of the present invention

It is a product manufactured with a structure composed of forming a single layer on the back of the silk wallpaper or permeating into the stratum of the back (back or back) of the silk wallpaper. , It is a product structure characterized by having more than two functions among the corrosion-preventing properties, and it gives special flame retardancy to the existing silk wallpaper. When the product features a product structure that maximizes the characteristics and is coated with the conventional silk wallpaper, apply the back side with the composition product of the present invention, let it soak into the wallpaper for 15 to 1,800 sec, and maximize the flame-retardant property by installing it on the wall As a method of wallpapering, it is characterized by a product manufacturing method, structure, and construction method that can be applied to product groups such as laminated wallpaper.

One of the additive materials of the present invention - mentioned in Example 1 - was prepared by adding chloride and sea salt, and then flame retardant performance according to surface resistance and thickness (after applying the composition to paper wallpaper, respectively, ignition was tested. ) was tested. At this time, water-based EVA was used as the adhesive material, and the surface resistance of the water-based EVA adhesive prepared by mixing 7.90% by weight and 12.18% by weight among various mixing ratios (measurement conditions: 19.5℃, humidity 45%) was KS M 3015- It was 10 ⁵ ~ 10 ⁸ Ω/□ according to 1997 or ASTM D257 evaluation method, and the half-life according to KS K 0555-2000, method A was 0.5 to 0.7 sec. Coat paper wallpaper with a paint brush with a width of 50 mm, and surface resistance and flame retardancy by ratio (content) Table 12 shows the results of measurement and evaluation of coating thickness.

division chloride ratio(%) 0% 7.89 7.90 9.81 9.82 12.18 13.89 13.92 16.21 sea salt ratio(%) 0% 2.94 6.22 Sheet resistance (width 50 mm paint brush) 2 coats 10 ¹¹ 10 ⁸ 10 ⁷ 10 ⁷ 10 ⁷ 10 ⁶ 10 ⁶ 10 ⁶ 10 ⁵ 1 coat 10 ¹² 10 ⁹ 10 ⁸ 10 ⁷ 10 ⁸ flame retardant N.G. N.G~△ O.K. O.K. △ O.K. O.K. O.K. O.K. Coating thickness (㎛) 2 coats (including base 229mm) 341 440 829 375 391 349 403 485 one side coating 56 150 300 73 81 60 87 129

From the above results, when the chloride content is 8% by weight or more, it is possible to secure within the surface resistance pursued in the present invention, and the higher the chloride ratio, the more flame retardant properties can be realized even when the coating thickness is thin. It can be seen that the required surface resistance and flame retardant effect can be realized by increasing the coating thickness. In this case, instead of the adhesive EVA material, Acrylic, Epoxy, Polyvinyl Alcohol, Polyvinyl Acetate, Silicone, Polyurethane, Ethylenevinyl Acetate ), Polyvinyl Chloride, Vinyl Acetate Acrylic Copolymer, Acrylic Copolymer. Gum Rosin, 2-Ethylhexyl 2-Propenoate, 2-Ethyl Hexyl Acryl Acid, N-Butyl Ester, Resin, Solution or Acid, Primer, Emulsion, Copolymer, Resorcinol, α-olefin (Butyl 2-Propenoic Chloroprene Rubber), n-Butylacrylate α-Olefin), isocyanate, and phenolic substances were used alone or in a mixture of two or more substances to ensure the same results.

Another object of the present invention is to prepare a heat-resistant polymer material through a molecular structure change, a reactive flame-retardant material in which a flame-retardant component is chemically combined in a polymer structure, and an additive type in which a flame-retardant material is physically added to a polymer material, which is another object of the present invention. There are methods to improve heat resistance by coating or painting with flame retardant materials or other flame retardant materials, or by changing product design. Therefore, flame-retardant materials can be generally divided into reactive and additive types, and in reactive flame-retardant materials, the flame retardant component is chemically bonded to the polymer material to maintain the flame-retardant effect, and the additive-type flame-retardant material is physically dispersed in the polymer material. And if there is some compatibility with the material used, it acts as a plasticizer or as a filler. Unlike reactive flame-retardant materials, additive-type flame-retardant materials may bloom on the surface of polymer materials depending on their structure and external conditions, so caution in use is required. In the case of a combination type flame retardant material, it exhibits a flame retardant synergistic or inhibitory effect depending on the combination type. Additive-type flame-retardant materials can be classified into the following 4 types according to their flame-retardant behavior. First, it is a material that can block the emission of incombustible gas or combustible gas and oxygen, and is related to the decomposition and ignition behavior of macro scale. For example, there are a halogenated compound that suppresses the generation of highly reactive radicals in a gas phase reaction and a phosphorus compound that inhibits a decomposition reaction through char formation in a solid phase reaction. Second, as a method of reducing the heat of combustion, there is a phosphorus-based compound that is related to the macro-scale combustion stage and inhibits the decomposition reaction through the formation of charcoal. Third, it is a method of maintaining the physical shape of a material through oxygen and heat blocking, which is related to macro-scale decomposition, and there are fillers, glass fiber reinforcement, and phosphorus-based compounds. Fourth, as a method for increasing the specific heat or thermal conductivity of a substance, there is a hydrate as a method related to the macro-scale heating process. Therefore, the flame retardant principle is: ① increase the degree of crosslinking of the polymer and add a filler to increase the ignition point, ② Al(OH) ₃ or Mg(OH) ₂ blocks combustion by generating water during combustion, ③ phosphorus or boron compounds During combustion, a polymer surface char film is applied to block oxygen, and ④ halogen compounds take away the heat of vaporization during combustion to cool the combustion process. In case of ①, the physical strength is lowered, or in case of ②, aluminum hydroxide has a disadvantage in that it uses a large amount and is decomposed at a temperature below 200℃, and in case of ③ and ④, harmful substances such as dioxins are generated. As a flame retardant material that can overcome the regulated boron and halogen-based materials, it was possible to use a chloride-based material, salt and seawater, and white carbon as an additional flame-retardant material. In the case of products requiring a black color, if conductive carbon is additionally mixed, better results can be obtained in terms of antistatic and electromagnetic wave blocking. ⓐ Carbon: Using the theory that phosphorus-based flame-retardant material acts as a flame-retardant material by blocking oxygen and generating charcoal during combustion, it can be flame-retardant if the polymer material is coated with charcoal (carbon, charcoal), and carbon can also serve as a deodorant. can The problem is that black carbon can be used in fields limited by color problems, but there is also white carbon, so it can be used in various areas. ⓑ If the heat transfer rate is good, if the localized heat is dispersed quickly, the flame retardancy will be good. First, since the flame retardant synergistic effect linked with ⓐ, thermal conductivity and electrical conductivity are in a proportional relationship, when the carbon presented in ⓐ is used as the conductive carbon, there was a synergistic effect by the action of ⓐ and ⓑ. ⓒ Na-based or Ca-based materials, which are analyzed by photoelectron spectroscopy at the Kyushu Institute of Technology, and the calcium oxide film, which cannot be observed with an electron microscope, is ignited as such a film has a protective action to block oxygen. The mechanism by which the temperature rises was revealed. And ⓓ NaCl is not deliquescent, but salts containing Mg ions or Ca ions are deliquescent. This is the reason why the antistatic performance of polymers made from seawater is better. Although it is a kind of chloride-based material and a chloride-based material such as CaCl ₂ or MgCl ₂ , it is a deliquescent electrolyte by abundant minerals such as sea salt, so that it can have electrical resistance as well as flame retardancy and flame retardancy, and can have an antistatic function.

Comparative evaluation results for the compositions, flame retardant and flame retardant properties according to Examples 1, 2, 3, 4, 5, 7, 8, 9, and 11 are shown in Table 13, and the test conditions are specimen size 5 mm, heat source methyl alcohol (using alcohol lamp), flame length 5cm and flame contact length 1cm Through the above results, for comparative evaluation in the present invention, the result of conducting a flame retardancy test on a specimen prepared using other flame retardant materials and the additive material of the present invention; Nitrogen-phosphorus flame retardant materials can achieve UL standard V-0 flame retardancy when the flame retardant content is 40% or more compared to the total content. Compared to that, the amount of flame retardant material used was higher. Halogen-based flame retardant material exhibited V-0 grade flame retardancy with only 20% content, and showed the best flame retardancy, but black toxic gas was generated and a characteristic odor of Br compound was produced. In addition, there was no dripping phenomenon in flame-retardant specimens prepared using nitrogen-phosphorus and inorganic flame-retardant materials when heated continuously for 2 minutes without checking the turn-off time, but dripping occurred when halogen-based flame-retardant materials were used. As a result of comparative evaluation of the adhesive material prepared by adding the composition additive of the present invention and other flame-retardant materials, it can be seen that the product of the present invention is equal to or superior to other flame-retardant specimens. Among the additives used to exhibit flame retardancy, which is another function of the present invention, the possibility of exhibiting a function similar to that of the previous flame retardant material was revealed through physical and chemical consideration, and an additional environmental risk test was conducted. 2271 (flame retardant grade 2~3 standards) and export UL-94 (V-0, V-1 standards) standard specimens (220mm × construction thickness (max. 15mm)) were manufactured and evaluated for environmental hazard. A gas hazard test, which is an objective evaluation index for environmental risk, was performed with the adhesive and coating material of the present invention.

As shown in Table 14, the weight loss of the specimen after the test was 2.5 g and 2.3 g, respectively, and the mouse action stop time was also measured at a value higher than 9 sec, which is the judgment standard, so the adhesive and coating material of the present invention has excellent flame retardancy. was able to confirm

Item Specimen Specification T1(sec) T2(sec) Judgment Nitrogen-Phosphorus Flame Retardant

50 5mm×5mm















One One V-0















40 One One 30 One 1-2 Inorganic flame retardant

60 One One 50 One 1-2 40 One 5 Halogen-based flame retardant

40 One One 30 One One 20 One One Addition of flame retardant material


30 One One 20 One One 10 One One 8 One 1-2 Addition of 2 kinds of chlorides

30 One One 20 One One 10 One One 8 One 1-2

Test name Gas toxicity test Criteria test specimen number One 2 -
Size (mm) 220 220 Thickness (mm) 4.0 4.0 Weight (g) 371.4 368.2 Weight loss after test (g) 2.0 1.8 mouse
(mouse) pedigree sex ICR, female ICR, female average weight 20.4 20.4 test box temperature
(℃) Early 31.3 31.2 best 32.1 32.0 average mouse stop time 11min 51sec 10min 54sec Standard Deviation 0min 7sec 0min 4sec mouse stop time 9min 44sec 10min 50sec 9min or more Judgment fitness fitness -

[Surface test]

◎ Related standards: KS F 2271.

◎ Test method: After heating a 220mm wide and 220mm long specimen with a sub-heat source, continuously heat it for 6 minutes by a main and sub-heat source, and measure the weight loss, temperature time area and smoke coefficient per unit area, afterflame, melting, cracking, and deformation. measurement.

◎ Judgment Criteria:

― Weight loss: less

― Temperature time area: Do not exceed the standard temperature curve within 3 minutes after the start of the test.

― Smoke coefficient per unit area: 350 or less.

― Afterflame time: less than 30 sec.

― No melting, cracking (less than 1/10 of the thickness) or deformation.

[Gas toxicity test]

◎ Related standards: KS F 2271.

◎ Test method: Measure the average behavioral stop time of 8 female ICR (Institute of Cancer Research) mice in smoke generated by heating a 220 mm wide and 220 mm long specimen.

◎ Judgment criteria: Average action stop time is 9min or more.

Examples 1, 2, 3, 4, 5, 7, 8, 9, 11, solid content 33% by weight, adhesive material 60% by weight, anti-condensation and humidity control material 3% by weight, solid content 47% by weight As a result of measuring the surface resistance using a composition containing 5 to 20% by weight of chloride, 25% by weight of solid content, 3 to 10% by weight of sea salt, and 5 to 30% by weight of additional water, 10 ⁶ to 10 ⁸ Ω/□ at 40%RH was confirmed to have antistatic properties. Then, the results of flame retardancy measurement through D Test Research Institute are as follows.

KS M 2150 (liquefied petroleum gas) is used for the fuel used in the flame retardant test of the present invention, and the length of the burner flame is 45 mm for the micro burner and 65 mm for the McKell burner, and the tip of the flame is the lower end of the center of the test body. The burner was installed so as to be in contact with Specimens are cut into pieces of 35 cm in width and 25 cm in length, each of which is arbitrarily cut from the object to be measured over 2 m 2 , and the specimen is dried for 24 hours in a constant temperature dryer at 50 ° C. It carried out at the temperature of 16 degreeC, and a humidity of 34%RH. After coating 120 μm of the composition adhesive and coating material (EVA base) prepared according to the present invention on the coating base plywood, the flame retardant performance test as described above was performed on three specimens, respectively. The result of this is that the carbonization area is for specimen ① 28.4cm ² , specimen ② 27.6cm ² , specimen ③ 31.3cm ² , the carbonization length is for specimen ① 7.1cm, specimen ② 6.7cm, specimen ③ 8.1cm, after-flame time is 0 sec for specimen ① , Subject ② 0 sec, Subject ③ 0 sec, and remaining time are as follows: Subject ① 0 sec, Subject ② 0 sec, and Subject ③ 0 sec. In addition, after coating 120 μm of the composition adhesive and coating material (PVA base) prepared according to the present invention on the plywood as a coating base, the flame-retardant performance test as described above was performed on three specimens, respectively. As a result, the carbonization area is for specimen ① 38.7cm ² , specimen ② 40.3cm ² 2 , specimen ③ 30.8cm ² , and the carbonization length is for specimen ① 8.9cm, specimen ② 9.5cm, specimen ③ 7.5cm, after-flame time is specimen ① 0 sec, test object② 0 sec, test object③ 0 sec, and remaining time are indicated for test object① 0 sec, test object② 0 sec, and test object③ 0 sec. At this time, the carbonization length was the maximum length in the carbonized part of the specimen, and heating was performed for 2 min for each specimen. It was found that the adhesive and coating composition had good flame retardant properties.

[Flame proof test]

◎ Carbonization area: The area carbonized by the flame.

◎ Carbonization Length: Length carbonized by flame.

◎ After-flame time: The time from when the flame of the burner is removed until the state of burning with the flame stops.

◎ Remaining time: The time from when the flame of the burner is removed until the state of combustion ceases without raising the flame (excluding the time during which after-flame is generated).

◎ Judgment criteria: The flame-retardant performance for thick fabric corresponding to the specimen (coated on paper wallpaper) of the present invention is based on after-flame time within 5 sec, after-life time within 20 sec, carbonization area within 40 cm2, and carbonization length within 20 cm.

38 is a photograph taken of a specimen after a flame test for non-coated and coated paper wallpaper with the composition of the present invention. In the case of uncoated laminated wallpaper, the specimen was completely burned as soon as a flame was applied (left side of the photo), but the coated laminated wallpaper (right side of the photo) had a flame applied for 10 sec and then the flame was removed. turned off within ∼2 sec. Therefore, it was found that the composition of the present invention has very excellent flame retardancy or flame retardancy.

Therefore, the adhesive and coating composition using the chloride of the present invention and application products using the same, such as an adhesive for painting, a paint (coating agent), etc. , film sheet, paper and silk wallpaper requiring flame retardancy and anti-fog properties, flooring materials such as PVC flooring and flooring, and clothing by coating the front or both sides. A coating layer made of chloride and salts (sun salt, rock salt, refined salt, etc.), bittern, conductive carbon black, metal material, ceramic (material mentioned in Example 1), etc. used in the present invention is a method of preventing direct exposure to the outside. , As previously described, on one and both sides of the coating substrate (product), firstly apply the adhesion and coating materials using the chloride and salts, bittern water, conductive carbon black, metal materials, ceramics, etc. mentioned in the present invention 1 to 10 times to 0.01 Coating ~10,000㎛, and coating one or both sides on the coating layer by adding 0.01~10,000㎛ of water-based as well as oil-based, varnish, and adhesive paint in one of the adhesive materials listed in the present invention to one of the adhesive materials used in the composition and the composition Treatment to prevent direct exposure of the primary coating layer pursued in the present invention to the outside, or to prevent direct exposure of the primary coating layer such as clothes, blankets (blankets, etc.) It was confirmed in the present invention that it can be used without restrictions in various fields by additionally coating a water-based or oil-based adhesive, varnish, or adhesive paint when applied to vertical areas. Above all, it is another feature of the present invention that it is applied to products such as upholstered furniture that are subject to the Fire Protection Act and becomes a product that exhibits flame retardancy (flame retardancy) among various functions.

Condensation phenomenon; Although the general paint shows dew formation as shown in FIG. 39, FIG. 40 shows that the present invention does not show dew formation on the surface due to hygroscopicity due to the added ceramic and chloride. And through this function, one of the objects of another invention of the present invention is a flame retardant (flame retardant) synergistic action and method as follows. It appears that the composition of the present invention is superior to the composition without additives of the present invention, and the flame retardant property is also improved by 50 to 99% depending on the composition content in the flame retardant test after coating on wood.

In the Korean Patent Application No. 10-2006-0019024, due to its high water absorption, when exposed to a high humidity environment, the moisture generated on the coated surface could have adverse effects such as contamination of the coated surface. As a way to overcome this, the present invention has provided the following solution. When the additive material of the present invention is used alone or in combination among the composition additives, the additive material specified in Example 1 is used as the additive material of the present invention in the adhesive material and paint (or paint) with a solid content of 35% by weight in the weight ratio of the total composition. The ratio (content) is preferably at least one type and within 30%, and the above problems do not occur any longer, thereby exhibiting the function of preventing dew condensation while exhibiting the function of more than flame retardant. In order to realize the purpose of preventing condensation above, even when calcium chloride in chloride is used alone instead of ceramics such as siliceous porous material, lightweight foamed ceramic, and clay as a composition participating material, in the standard of using an aqueous solution of calcium chloride that is theoretically soluble as much as possible. When the composition is made so as not to exceed 30% in the weight ratio of the composition, the above problems do not occur any more, so that the antistatic function can be additionally exhibited.

However, considering the wet environment in case of rain due to climatic change, the content of calcium chloride (in anhydrous CaCl ₂ commercially available in general commercial anhydrous CaCl ₂ .6H ₂ O) content is 25% by weight based on the weight ratio of the total composition, especially 20% by weight of the solids adhesive less is more preferable. In the case of using with sea salt, when the ratio of calcium chloride to sea salt (or refined salt, rock salt, industrial slat material, etc. are called salts) in the above composition is 1: 0.5 to 10, antibacterial and anti-mildew function due to sea salt, some It becomes possible to further promote the antistatic function and the antistatic and flame retardant function by calcium chloride, antifreeze and anti-condensation.

Conductive carbon black compensated for the disadvantages of color through the use of conductive polymers such as PEDOT, white carbon, chloride, salt, and bittern. By using conductive carbon black at the same addition ratio, it was possible to double the electromagnetic wave blocking (electromagnetic wave reduction) beyond the flame retardant properties through char formation and the antistatic performance by conductivity. In particular, bittern water used in the present invention is also referred to as high salt old water. It can be obtained as a by-product when manufacturing salt, and can be obtained by using the deliquescent action when storing salt. The composition consists of 15-19% magnesium chloride, 6-9% magnesium sulfate, 2-4% potassium chloride, 2-6% sodium chloride, 0.2-0.4% magnesium bromide, and the like. It has been used as a coagulant when making tofu since ancient times, but research on bittern has been conducted since World War I, and now it is used as an important resource for inorganic pharmaceuticals. The bran water treatment industry is a sector such as the potassium industry and the potassium fertilizer manufacturing industry, and there are also studies to manufacture magnesium hydroxide or metallic magnesium using bittern water. The bittern is used directly for tofu production and magnesia cement, and in addition, it has been used in small amounts for rice cleaning, etc., but has been used since ancient times. A material containing 3 to 35% magnesium, 0.1 to 7% calcium chloride, 2 to 27% sodium chloride, 0.01 to 1% magnesium bromide, etc. was used, and 20% by weight of a polymer, one of the mixing ratios of Example 1, 50% by weight adhesive material Weight, 50 wt% of solid content, 5 wt% of chloride, 25 wt% of solid content, 7 wt% of bittern, and 38 wt% of water Use the adhesive and coating material to measure the degree of attenuation of the electric field before and after internal treatment (construction) of the box. measured. It was also confirmed that the measured value of PULSE's E-tester before construction was 136V/m, but after construction, it was 0V/m, and it was also confirmed that the place where the internal construction was performed was going to 0 due to the attenuation of the electric field.

As mentioned in Example 9, the present invention also relates to an anti-freeze adhesive and coating composition (product), so that in cold weather, a product such as a water-soluble glue, adhesive or paint can reduce the adverse effects of freezing during movement and during construction It relates to a compositional product and its application products that can be used in all weathers by lowering the freezing point to prevent hypothermia.

In order to realize this, the present invention first secured specific data through the following considerations, solution principles, and tests in order to confirm the principle of lowering a certain point.

As a solid substance that dissolves well in water and can lower the freezing point, there are chlorides, nitrates, ammonium salts, and the like. For example, magnesium chloride has less ionized water than calcium chloride, but the effect of lowering the freezing point at the same number of moles is the same, so for the same weight, magnesium chloride is more effective than calcium chloride and better than sodium chloride. On the other hand, liquid substances, alcohols, glycols, etc. have the same effect. In the case of methyl alcohol, the mass of 1 mole is 32 g, and the freezing point reduction is slightly less than the freezing point reduction mole number of salt 24.25, so the freezing point lowering effect is large. Ethylene glycol is used as an automobile antifreeze, which has a molar mass of 62 and is half that of salt. And freezing point depression is the freezing point depression constant In the case of water, the freezing point depression constant per mole is 1.86 °C/m. Using the principle of lowering the freezing point as described above, it became the motivation (motiv) of the present invention. As shown in FIG. 41, the freezing temperature of pure ethylene glycol is -12 °C, but the freezing temperature (freezing point) of a liquid in which ethylene glycol and water are mixed depends on the mixing ratio. When water is mixed, the hydrogen bonding of ethylene glycol is disrupted and the freezing point is lowered. The freezing point of a liquid in which the amount of ethylene glycol is 70% and water 30% is reduced to about -50℃. Antifreeze with a 1:1 ratio of water and ethylene glycol is about -35 to -40℃, so it is a good example of an antifreeze that can be used without any problem in the winter environment of Korea. (Source: Naver Cast, Today's Science, Chemistry Walk , Antifreeze, Prof. Yeo-Hyung Yeo) Also, the principle of lowering the freezing point is that ordinary water starts to freeze at 0°C, but the composition of the present invention, in contrast to caustic soda, does not freeze at a temperature lower than 0°C because the higher the content, the lower the freezing point. The theoretical principle for this is shown in FIG. 42 with reference to the Naver Knowledge Window, rsy7979. If the plane is divided into three areas with a red line, the leftmost part is in the solid state, the upper middle part is in the liquid state, and the lower right part is the gaseous state. And the red line in the middle between the solid and liquid states is the solidification point = melting point line, and the solidification point = melting point line of the solution rather than water moves in parallel to the left, that is, the x-axis is the axis representing temperature. This means that the temperature is lowered. Therefore, the freezing point of the composition of the present invention is lower than that of ordinary water, and there is an advantage in product storage, distribution and construction in cold weather due to the prevention of freezing.

Products containing water such as water-soluble adhesives, paints, and pastes have a problem of freezing (freezing phenomenon) in sub-zero weather. In addition, the increase in material cost compared to summer due to the use of less water than summer during winter construction (painting), and the occurrence of freezing (freezing) in winter when the wall of the apartment veranda with a lower temperature than the apartment room or living room is painted with water-soluble paint. In most cases, the builder is unable to construct. In addition, special attention (management) is required as there are cases in which adhesiveness is lowered or the product must be discarded due to agglomeration/separation due to freezing (freezing) during winter movement (product movement stage for distribution or construction) and warehouse storage. In the case of products manufactured with distributed water, when thawed after freezing, water and adhesive components are separated, resulting in agglomeration or significantly lower viscosity. In order to solve these problems and to prevent freezing by lowering the freezing point, the results of the freezing test are as follows.

As a major part of the present invention, current water-soluble adhesive and coating products always had a problem due to freezing in sub-zero weather in winter. The freezing phenomenon was confirmed as shown, and a comparative freezing (freezing) evaluation experiment was performed with the present invention. As a result of evaluating whether or not the products currently distributed on the market and the dobae grass manufactured according to the present invention (the grass manufactured by S company's dobae grass production line) were frozen together in the freezer (Fig. 39 upper part), the distribution products containing water were After about -11°C for 2 hours, freezing began at the time of the first evaluation, and after leaving the freezer for 24 hours, it became a hard lump of ice, but the product of the present invention (see FIG. 43) did not freeze at -11.8 to -15.6°C for 24 hours, and subsequent evaluation At -16.5℃, 12hr evaluation, only the surface was slightly frozen, but when it was thawed at 16℃ for 4 hours (I left it in the indoor air), the product of the present invention was restored to its original state, --19.3℃ In the 50 hr additional freezing test, the present invention completely turned into a lump of ice, but when thawed, its original state and adhesion were maintained. -, If products distributed in the market (current products sold) are completely frozen and then thawed, agglomeration occurs due to the separation between the water and flour components, which are the solutions used in manufacturing, and the inherent adhesive function of adhesives such as starch is significantly reduced. phenomenon occurred. In order to test the adhesion, glue was applied to the paper wallpaper and then dried and peeled by hand. The products distributed easily fell off, and even some wallpapers that were glued on themselves fell off, but the adhesive strength of the present invention did not change, and there was no problem with the adhesive strength (adhesion strength) enough that the paper wallpaper itself was torn when peeled off (when peeling), so adhesives and paints The intrinsic properties were maintained. The experimental results for this will be described in more detail in the following examples.

In addition to starch coating paste, EVA composed of water-based EVA paint (experiment conducted with N company's water-based paint) and the same proportions and materials as those of Examples 1, 2, 3, 4, 5, 7, 8, 9, 11 A freeze test was carried out with a product made with a paint invention composition, and it was completely frozen in the freezer and then thawed. If you look at the condition, the appearance color of the EVA paint in circulation has changed. The composition EVA paint of the present invention did not change the appearance color before and after freezing. In the painting experiment, the distribution paint that was frozen and then thawed was not applied, but there was no problem in the present invention. 44 shows the state before and after thawing, looking at the principle and test results; The paint has an effect of lowering the freezing point of paints or adhesives containing additives according to the present invention, especially compared to paints without additives such as the present invention among water-soluble paints (including adhesives currently on sale). Previous water-soluble paints and adhesives start to freeze after 0°C, but according to the present invention, when one type of additive is mixed, that is, 3% by weight, about -2 to -3°C, 6% by weight -3 to 4°C, 10 wt% -7~-8℃, 15wt% -10~-12℃, 20wt% -13~-15℃, 29wt% -20~-22℃, solid content in the same content ratio when two types are mixed It was confirmed that the adhesive prepared by mixing two types of additive materials with a difference of 2:1 was lower than the freezing point temperature of the ratio by -2 to -7°C. According to the present invention, even if the paint or adhesive containing the additive material is frozen, the adhesive strength is restored to its original state after thawing, so there is no problem in adhesive strength. was separated like an island, resulting in almost loss of coating power and adhesion. Therefore, when the material of the present invention is mixed, the freezing point is lowered and the adhesive strength is restored when thawed after freezing. However, it is one of the very important features that it is a product that is easy to install regardless of the season, which was first invented by solving the fundamental problem of the previous adhesive with the antifreeze effect as described above by the present invention.

As in Examples 1, 4, 5, 7, 8, 9, 11, 17, 19, each of a chloride and a sea salt is dissolved in H ₂ O - Chloride is a solution with a solid content of 20 to 50 wt%, and a sea salt is a solid content of 20 In a ~33 wt% solution - otherwise, in the case of preparing dobae grass by putting it in a powdered mixing container for preparing dobae grass, first put water, CaCl ₂ powder, and sea salt powder were added and stirred to dissolve, and then starch was added. Preferably, CaCl ₂ is first added and dissolved, and then sea salt is added and dissolved. This is because, using the amount of heat generated when CaCl ₂ is melted, adding sun-dried salt to a chloride solution in a heated state to dissolve it shortens the melting time and dissolves well. It was thought to be advantageous for The manufacturing method was prepared in the same manner as in Example 1.

The same physical properties and the same performance were realized even when the seaweed and CaCl ₂ powder were added in the same formulation as the method for making the dobae grass and the dobae grass of the present invention was prepared. That is, first, H ₂ O (purified pure water is most advantageous, but usually groundwater, tap water), sea salt, CaCl ₂ , and starch are added to the mixing container in this order, and 30 to 103° C. 1 to 100 min, 1 among the manufacturing conditions of Example 1. Produce a paper grass at ~10,000 rpm manufacturing conditions; First, sea salt, CaCl ₂ powder, H ₂ O are put and dissolved, and then starch is added to prepare it. The solubility, dispersibility, and miscibility of the additive material of the present invention are very excellent, making it easy to mass-produce and easy to manufacture in various ways. Being possible is yet another of the best features of the present invention.

In addition, it is preferable to boil water in advance for sterilization of bacteria that may be contained in water in advance, and it is possible to shorten the manufacturing time even more by increasing the agitation and temperature during pre-solution. At this time, the mixing conditions are 200~600kg of H ₂ O and CaCl ₂ powder (Australian, Vietnamese, South American, North American, European, African, Asian among the products labeled 100%, 77%, 74% of CaCl ₂ used in the present invention) Among the mountains, from Japan, Vietnam, India, the Philippines, etc. In particular, one or two or more of deicing agents, edible, low corrosive, reagent grade, and dehumidifying, such as domestic Chinese products) 15-100 kg, sun-dried salt (used in the present invention) Salt is sun-dried or rock salt, and one or more of the low-corrosive properties are mixed with one or more of the deicing agents, food, sports grounds/tennis courts, and the like. , Vietnam, India, Philippines, etc. In particular, one or a mixture of two or more of deicing agents, edible, low corrosive, and dehumidifying agents, such as domestic Chinese, or Asian products such as domestic, Chinese, and Vietnamese products were used. ) 5-100 kg, starch (1 or 2 or more of grades 1, 2, and 3 were mixed and used.) 20-160 kg were added and 1-100 min, 1-10,000 rpm, 0.5-5 atm at 30-103 ° C. It is one of the characteristics of the present invention to prepare a porcelain pool while stirring under but mainly under atmospheric pressure.

Examples 4, 5, 7, 9, 17, 19, and 21, in addition to the starch miscibility in the prepared paper grass, a strong acid of pH < 4 or less, the anti-corrosive agent mentioned in Example 1 100% by weight of the total composition It was prepared by adding 0.0001 to 5% by weight, respectively. Preferably, 0.0001 to 5% by weight of strong acid in 90-99.999% by weight of the prepared dobae grass, as a material exhibiting an anti-corruption effect, among the main components 3-lodo-2 propynyl butyl carbamate, Octylisothiazolinone; By adding 0.0001 to 5% by weight alone or in a mixture of two or more, the anti-mildew effect was maximized. With this composition, the shelf life can be maintained for more than one year. In this case, it was prepared by mixing in the case of pre-production mainly for summer and long-term storage. It is one of the most excellent features of the present invention that long-term storage properties are maintained.

One of the compositions of the present invention according to Examples 1, 4, 5, 7, 8, 9, 11, 17, 19, 21, 22, starch strong flour and wheat flour, or 15 to 35% by weight of corn or potato 15 to 85% by weight of water Weight %, solid content 20-49 wt% CaCl ₂ 3-35 wt%, solid content 10-35 wt% Sea salt solution (salt solution) 1-30 wt%, other strong acids, dispersants, etc.) 0-20 wt% blending conditions 1~103℃, 1~600min. 1 to 20,000 rpm 0.5 to 5 atm A liquid coating composition prepared while stirring, and its manufacturing method, and the liquid composition is diluted 1-1,000 times and then spray-dried and then subdivided or completely dried and then pulverized to form a powder paste, this powder If water is added to the paste again and stirred, it becomes a liquid coating paste and can be used for painting. The powdered paste produced in this way increases the manufacturing cost due to the additional process for producing the powdered paste, but it can be stored for a long time due to the powder state and has the effect of reducing distribution costs due to weight loss.

Unlike the sol-gel (or sol-powder) manufacturing method of the above embodiment, the sol-powder manufacturing method is electromagnetic wave absorption according to the type of additive and the mixing ratio of the additive material, electromagnetic wave blocking, antistatic, antibacterial/mildew, flame retardant, freeze prevention , Corrosion prevention and anti-corrosion performance are compounded or selectively/selectively produced, resulting in excellent long-term storage.

45 is a photograph taken after bonding a wooden floor tile (flooring material) using the composition adhesive prepared in Examples 1, 2, and 3, and is constructed and dried to a level as good as the adhesive for conductive antistatic tile of Example 2; No peeling occurred after that.

In this example, the composition of the products prepared according to Examples 1, 4, 5, 7, 8, 9, 11, 17, 19, 21, 22, and 23, and the commercially purchased preservative S company containing preservatives Figure 46 shows the results of artificially putting a fungal strain into the product (injection) and performing a culture experiment for one week. As shown in the figure, the spread of mold did not occur in the paper grass prepared according to the composition of the present invention, and the spread of fungus was severe in the commercial paper grass containing a preservative, etc. Therefore, it was found that the coating grass containing the functional composition material in the present invention had better (good) anti-mildew effect than the coating grass containing preservatives as it prevented the spread of mold.

As mentioned in Examples 12, 16, and 17, the properties regarding flame retardancy, flame retardancy, and non-flammability are as follows. Flame retardancy is a property that prevents flame combustion from occurring when ignited through chemical or physical treatment of combustible materials, flame retardancy is a property that makes the combustion rate relatively slower than combustible materials, and nonflammability is a property that does not burn even at high temperatures like metal or inorganic materials say that with In other words, flame-retardant burns when exposed to a flame, but does not burn by igniting itself when the flame is removed, and does not spread or expand fire beyond the standard carbonized area by receiving the flame directly. It was made to have (self-extinguishing). Although flame retardant has a flame retardant effect under weak combustion conditions, it can be said that there is no significant difference from general combustible materials under high temperature or strong combustion conditions. (Source: Doosan Encyclopedia) When classified into flame retardant grades, flame retardant grade 1 is a non-combustible material that does not burn, flame retardant grade 2 is a semi-incombustible material that does not burn easily, and flame retardant grade 3 is called a flame retardant material. Materials that are difficult to burn with Therefore, flame-retardant material refers to a material that does not burn well even if it catches fire, and it is a material that burns in a flame but does not burn well. There should be no damage. When sparks are ignited, some toxic gas is generated, and there is no burning phenomenon. Flame-retardant board, flame-retardant fiber board, and flame-retardant plastic board belong to flame-retardant materials. In the building law enforcement ordinance, it is stipulated as 'materials with non-combustible performance', and as a result of testing according to the Korean Industrial Regulations under the Industrial Standardization Act stipulated by the Ordinance of the Ministry of Construction and Transportation, it refers to those that fall into flame retardant class 3. In order to evaluate whether it has a flame retardant property corresponding to such a flame retardant class 3, the paper glue and the general paper glue prepared by Examples 1, 4, 7, 8, 9, 11, 17, 19, 21, 22, 23 It was applied on paper and silk wallpaper with a flame test. Figures 47 and 48 show that general wallpaper and silk wallpaper are coated on both sides or one side with the composition of the present invention, and a commercially available wallpapering paste made of water and starch for painting, or a general wallpapering paste containing a fungicide therein ( Because it is not coated with the composition of the present invention, it is described as "not coated") by capturing a video taken during a flame test and showing it as a photograph. 「The first on the right of the captured photo (paper wallpaper); It was not coated with the paper glue of the present invention, and the second from the right (paper wallpaper); Both sides are coated with the paper paste of the present invention, and the last additional experimental video capture photo (paper wallpaper); Only the back (one side) is applied. And if you look at the captured picture of the same screen, the first on the left (silk wallpaper); Not coated with silk wallpaper, the second from the left (silk wallpaper): only the back (one side) is applied, and the third from the left (in the captured photo, the center is silk wallpaper) ; It was applied on both sides.” As shown in the test, the laminated wallpaper coated with ordinary wallpaper had less flame than silk wallpaper, but it burned completely. It burned while in this psalm, and burned and extinguished when the flame was removed from the psalm. As shown in FIGS. 47 and 48, the silk wallpaper applied had the same results as the laminated wallpaper, but the uncoated silk wallpaper burned better than the laminated wallpaper while generating dark smoke. It can be seen that this product needs flame-retardant properties because the silk wallpaper coated on one side (or both sides) of the paper with a chemical substance PVC and forming a printed layer is good for harmful smoke and combustion due to the combustion of PVC. Therefore, the composition product of the present invention is characterized in that it has very excellent flame retardant properties.

Following Example 20, in order to secure the superiority of the present invention by freezing, a more detailed TEST was additionally performed. The results of the freezing test on the dobae grass and the general dobae grass among the compositions of the present invention are shown in the upper part of FIG. 49 . The paper grass of the present invention did not freeze after 24 hours at -11.8 to -15.6 ° C, but the general paper grass was completely frozen like ice. So, the temperature of the present invention was further lowered for 12 hours at -16.5℃ and then frozen (freeze), but only the surface was frozen. As such, it was found that the composition according to the composition of the present invention becomes antifreeze like antifreeze that does not freeze well at low temperatures, and therefore, for specific evaluation, the temperature -16 ℃ (fixed), depending on the content of the additive of the present invention, To evaluate the degree of change in the product state according to the change in freezing time and the time after freezing and thawing, surface resistance and adhesion, which are the main items of the present invention, were additionally measured. No freezing after freezing at -16℃ for 8hrs at 11% chloride, 6% sea salt relative to total weight, surface resistance 14.8℃ 36%RH 10 ⁶ Ω/□, 17.2℃ 27%RH 10 ⁶ ~10 ⁷ Ω/□, 14.7℃ 33 Based on %RH 10 ⁷ Ω/□, it was completely frozen after freezing at -16℃ for 8hrs in 3% of sea salt, only the surface melted at 2hrs of thawing, and half melted at 3hrs of thawing, and the surface resistance of this sample was 14.8℃ 36 %RH 10 ⁸ Ω/□, 17.2℃ 27%RH 10 ⁸ ~10 ⁹ Ω/□, 14.7℃ 33%RH 10 ⁹ Ω/□; After freezing at -16℃ for 8hrs at 6% sea salt, it was completely frozen, half-melted at 2hrs of thawing, and slushed at 3hrs of thawing, and the surface resistance of this sample was 14.8℃ 36%RH 10 ⁸ Ω/□, 17.2℃ 27 %RH 10 ⁸ Ω/□, 14.7℃ 33%RH 10 ⁸ ~10 ⁹ Ω/□; After freezing at -16℃ for 8hrs at -16℃ in 3% chloride and 3% sea salt, it was half-melted at 2hrs of thawing, and slushed at 3hrs of thawing. The surface resistance of this sample was 14.8℃ 36%RH 10 ⁷ Ω/□, 17.2℃ 27%RH 10 ⁷ ~10 ⁸ Ω/□, 14.7℃ 33%RH 10 ⁸ Ω/□; After freezing at -16℃ for 8hrs at -16℃ with 6% chloride and 6% of sea salt, it was frozen about 3/4 of the way, slushed at 2hrs of thawing, completely thawed at 3hrs, and the surface resistance of this sample was 14.8℃ 36%RH 10 ⁷ Ω/□, 17.2°C 27%RH 10 ⁷ to 10 ⁸ Ω/□, 14.7°C 33%RH 10 ⁸ Ω/□; After freezing at -16℃ 8.5hrs at -16℃ in 6% chloride and 6% sea salt, the slush was slightly more molten at 1hr of thawing, and completely thawed at 2hrs of thawing, and the surface resistance of this sample was 14.7℃ 33%RH 10 ⁸ Ω/□; After freezing at -16℃ 8.5hrs in 8% chloride and 3% sea salt, it was frozen 9/10, more than half melted in 1hr of thawing, completely thawed in 2hrs of thawing, and the surface resistance of this sample was 14.7℃ 33%RH 10 ⁷ ~10 ⁸ Ω/□; In 9% chloride and 3% sea salt, it was frozen 4/5 after freezing at -16℃ 8.5hrs, slightly frozen than slush at 1hr of thawing, completely thawed at 2hrs of thawing, and the surface resistance of this sample was 33% at 14.7℃ RH 10 ⁷ to 10 ⁸ Ω/□; After freezing at -16℃ 8.5hrs at -16℃ in 7% chloride and 4% sea salt, it was frozen at 9/10, half-melted at 1hr of thawing, and thawed 9/10 at 2hrs of thawing, and the surface resistance of this sample was 14.7℃ 33% RH 10 ⁸ to 10 ⁹ Ω/□; In 7% chloride and 5% sea salt, it was frozen 4/5 after freezing at -16℃ for 8.5hrs, slightly more molten than slush at 1hr of thawing, and completely thawed at 2hrs of thawing, and the surface resistance of this sample was 14.7℃ 33% RH 10 ⁸ to 10 ⁸ Ω/□; In 7% chloride and 4% sea salt, it was frozen 4/5 after freezing at -16℃ for 8.5hrs, slightly more molten than slush at 1hr of thawing, and completely thawed at 2hrs of thawing, and the surface resistance of this sample was 14.7℃ 33% RH 10 ⁸ Ω/□; In 6% chloride and 6% sea salt, it was completely frozen at -16℃ for 11hrs, slushed at 1hr of thawing, completely thawed at 2hrs of thawing, and the surface resistance of this sample was 17.2℃ 27%RH 10 ⁸ Ω/□, 14.7 ℃ 33%RH 10 ⁸ Ω/□; In 5% chloride and 3% sea salt, it was completely frozen at -16℃ 11hrs after freezing, only the surface was thawed at 1hr of thawing, half melted at 2hrs of thawing, and slushed at 3hrs of thawing, and the surface resistance of this sample was 17.2℃ 27%RH 10 ⁹ Ω/□, 14.7℃ 33%RH 10 ⁸ ~10 ⁹ Ω/□; -16℃ at 6% chloride, 3% sea salt Completely frozen after 11hrs freezing, only the surface melts in 1hr of thawing, slush in 2hrs of thawing It was completely thawed at 3hr of thawing, and the surface resistance of this sample was 17.2℃ 27%RH 10 ⁸ ~ 10 ⁹ Ω/□, 14.7℃ 33%RH 10 ⁸ Ω/□; In 7% chloride and 3% sea salt, it was completely frozen at -16℃ 11hrs after freezing, slushed at 1hr thawed, slushed at 2hrs thawed, completely thawed at 3hrs thawed, and the surface resistance of this sample was 17.2℃ 27% RH 10 ⁸ Ω/□, 14.7°C 33%RH 10 ⁸ Ω/□; In the above composition, after complete thawing, there was no problem in the adhesive strength of those in which the surface resistance of 10 ⁹ Ω/□ was observed in the present invention. However, if the waiting time for construction after freezing is taken into account, more preferably, a composition having a surface resistance of 10 ⁸ Ω/□ is the most desirable for a compounding ratio in which complete thawing occurs after 2 hours of thawing. However, it is a feature of the present invention that all TEST preparations can be manufactured into anti-freezing composition products because there is no defect in adhesive strength after thawing.

In another evaluation experiment, the results of evaluating the adhesive strength by thawing each of the completely frozen paper plants, applying the paste to the paper wallpaper, and attaching the paste to the wall are shown in the lower part of FIG. 49 . First, after thawing, water and starch are separated from common planters, but the present invention is externally restored to its original state (refer to FIG. 50). After freezing, thawing, coating, and drying 2 hours later, peeling test was performed. The upper coating was made by diluting the grass by adding water to the grass, and the lower coating was made by freezing and thawing the planting grass manufactured in the manufacturing plant without adding water. The left side of the continuous photo of Figure 49 is that the general paper grass #1 is coated after freezing and thawing at -11.8 ° C for 24 hours, and the center is the general paper grass #2 at -11.8 ° C 24 hours after freezing and thawing, and the right side is this According to the invention, it was completely frozen and thawed at -19.3℃ for 50hrs manufactured at the planting plant, and then coated with it. As shown in the results, it can be seen that the wallpaper coated on the wall simply fell off due to loss of adhesion in the general paper glue or fell even with a slight peeling force, but the paper glue of the present invention has no problem in adhesion even when frozen like ice. As shown in the peel test, the paper part between the wall and the wallpaper does not fall, but the paper part shows tearing, indicating that the adhesive strength is good.

These are the test progress results to determine the degree of corrosion on metals such as screws (see FIG. 51) in the papering pool according to the present invention and the two types of papering pools #1 and #2 sold in the general market. According to the present invention, purchase the papering grass manufactured in the papering grass manufacturing plant and two different general papering pools, soak the screws, leave them for a long time (at room temperature for 30 days) until the grass is completely dry, and then observe the appearance of the screws. is a result The screws placed in the general plastering pool were corroded and oxidized, but the coating paste manufactured in the papering pool factory (S company mass production) line according to the present invention did not change the color of the screw surface enough to not know the degree of corrosion of the screws.

0-100 parts by weight of dried solid chloride, dried sea salt (sodium chloride as in Example 1) edible salt, which is the main ingredient, sea salt and industrial substances used as chemicals, from Europe, Africa, and Salt produced in North America, South America, and Oceania, especially in Asia, Europe, and the West Sea such as the United States, Australia (Australia), China, and the Philippines, or alone among salt mines on six continents such as Africa, America, and Tibet or 2 or more types) 1 to 100 parts by weight of the powder alone or mixed with 2 types, the mixing ratio is chloride 1: sea salt 0.1 to 5, the manufacturing method mentioned in Example 1 - The present invention was first invented by the present inventor Invented powdery paste manufacturing method - A composition that exhibits antistatic, antibacterial and anti-mildew, flame retardant abnormality, and anti-freezing performance in a complex manner, and powdered grass was manufactured through this composition. The pool is a solid powder and there is no H2O, so it is advantageous for long-term storage and distribution. Examples 1, 4, 5, 7, 8, 9, 11, 17, 19, 21, 22, 23, and 27 have the same characteristics as the liquid porcelain paste of the present invention, but long-term storage by solid standing and distribution by light weight advantageous to

In addition, powdered grass manufactured with grains such as starch, rice, wheat, bran, corn, potato, dextrin, modified starch, glutinous rice, seaweed such as nori, Gelidium amansii LAMOUROUX, grains such as dextrin, modified starch, etc. or German H company , Korea E company, K company, Y company, etc. 1 to 100 parts by weight of powdered grass, 0 to 100 parts by weight of the solid chloride mentioned in Example 1, dried sea salt or rock salt, refined salt powder alone or two or more 01 to 100 Mix by weight, and here 0.0001~7,000㎛ spherical, plate-like, needle-like Zeolite, siliceous porous material, Silica, Perlite, Clay, talc, Aluminum Hydroxide, Kaolin, Magnesium Hydroxide, Calcium Carbonate, Diatomite, Loess, Bentonite, Quartz sand , Gypsum, Lime, cement, Terra alba, Pozzolan, Diatom, Pupl, etc. alone or in an amount of 0-100 parts by weight of two or more were used to prepare powdery or solid-type plastering finishing materials. In contrast, a photograph of the surface resistance measurement is shown in FIG. 52, and as shown, the measured value was 10 ⁶ Ω/□, which was a level capable of exhibiting electromagnetic wave blocking or antistatic properties.

It was confirmed in Example 28 that the functional additive material of the present invention was not more corrosive than general paper glue or adhesive due to its compatibility with the adhesive and chemical action. A more clear reason and principle have been clarified and a long-term test is in progress. Therefore, in the present invention, Figure 53 is a test for evaluating the degree of corrosion over a long period of time - currently in progress on approximately 50 days - (a) The evaluation was carried out by putting creep and nails in the container on the start date of the experiment. The middle two are by the present invention, and the two containers on the left contain water in order to determine the effect of water because the water-soluble adhesive contains water. Also, after one day, the experiment was carried out by inserting a creep and a nail. As shown in FIG. 53 (b), in the creep placed in water, corrosion occurred before 24 hrs, and the degree of corrosion was gradually spread, but the composition of the present invention also caused very little corrosion and was affected by water. it can be seen that there is This resulted as in Example 28 due to the generation of a material that prevents corrosion of iron while the composition of the present invention goes through the mixing process during the manufacturing process, and this material is also a pollutant gas in the atmosphere when neutralizing and painting concrete By reacting first, it is possible to increase the durability of the building by forming blocks. The present invention mentioned in the above and examples is patent application No. 10-2016-0118954, application number 10-2016-0120328, application number 10-2016-0153671, application number 10-0144881, etc. filed by the present inventor By securing specific data for "complementation, further improvement, further improvement, new development (invention) addition, manufacturing method improvement, and new invention of characteristics" rather than the contents invented in .

In Example 29, if the plaster thickness was more than 10 mmm, cracks were likely to occur in the plastered part, and the construction was preferably less than 2mmm smoothly, but as a way to overcome the crack limit in raising the plaster thickness more; Acrylic, Epoxy, Polyvinyl Alcohol, Polyvinyl Acetate, Silicone, Polyurethane, Ethylenevinyl Acetate with a solid content of 1 to 100% by weight , Polyvinyl Chloride, Vinyl Acetate Acrylic Copolymer, Acrylic Copolymer. Gum Rosin, 2-Ethylhexyl 2-Propenoate, 2-Ethyl Hexyl Acryl Acid, N-Butyl Ester, Resin, Solution or Acid, Primer, Emulsion, Copolymer, Resorcinol, α-olefin (Butyl 2-Propenoic Chloroprene Rubber), n-Butylacrylate Grains such as α-Olefin), Isocyanate, Phenolic, Thermosoftening Plastic, Thermosetting Plastic, Starch, Rice, Wheat, Bran, Corn, Potato, Dextrin, Modified Starch, Glutinous Rice, Nori, Gelidium amansii LAMOUROUX Substances manufactured with 15 to 50% by weight of solids made from the same seaweed, grains such as dextrin, modified starch, etc. Sodium Chloride, Magnesium Chloride, Calcium _Chloride (European, African, Asian, North American, South American, Oceania, especially domestic and Chinese products, which are easy to secure, are mainly used), etc., in the form of powder or an aqueous solution thereof in 0-50 wt%; Solid content 1-100 wt% Salt is edible salt whose main ingredient is sodium chloride, sea salt and industrial substances used as chemicals, East Sea, West Sea, South Sea, Mediterranean Sea, Pacific Ocean, Atlantic Ocean, Indian Ocean, Northern Sea, Antarctic Sea, Dead Sea, Black Sea, etc. Produced in Europe, Africa, Asia, North America, South America, Oceania, especially in the United States, Australia (Australia), China, and Asia such as the Philippines, Europe, and the West Sea, etc. 6 such as Africa, America, and Tibet Use 0-50% by weight alone or a mixture of two or more types produced in salt mines on the continent, 15-19% Magnesium Chloride, 6-9% Magnesium Sulfate, 2-4% Potassium Chloride, 2-6% Sodium Chloride, Use 0-50% by weight of 1 to 69% by weight of solid content consisting of Magnesium Bromide 0.2 to 0.4%, or 5 to 90% of boiling water by heating 100 g of these, or Calcium Chloride and Sodium Chloride among these chlorides. Among those whose corrosiveness is lowered by treatment with a low-corrosion or low-chlorination system, 0-50% by weight of these materials alone or two or more are used, or as an ionic compound with a solid content of 5-100% by weight - The ionic compound used in the present invention Silver metal cations and non-metal anions are combined by electrostatic attraction, and the sum of the charges is electrically neutral. and at least one from the group consisting of Mg, Ca, Ba, and the like, and the anion element is a fluoride anion, a bromide anion, an iodide anion, a sulfide anion, a chloride anion, an ammonium anion, a hydroxide anion, a sulfate anion, a carbonate anion, a nitrate anion. , phosphate anion, permanganate anion, acetate ion, hydrogen carbonate anion, borate anion, chromate anion, dichromate anion, halogen anion, hydrochloric acid anion, organic acid anion, etc. may include one or more selected from the group consisting of, and may additionally include an ammonium salt in consideration of equipment corrosion and solution stability, and in the form of an anhydride, hydrate, or aqueous solution, these substances alone or two or more 2~ 50% by weight or 5 to 100% by weight of solid content The ionic compound uses a +1 cation metal and a -1 valent or -2 valent anion, and the cationic metal element belonging to this is from the group consisting of Li, Na, K, etc. and at least one selected from among them, the anion element is a fluoride anion, a bromide anion, an iodide anion, a sulfide anion, a chloride anion, an ammonium anion, a hydroxide anion, a sulfate anion, a carbonate anion, a nitrate anion, a phosphate anion, a permanganate anion, an acetic acid ions, hydrogen carbonate anions, boric acid anions, chromate anions, dichromate anions, halogen anions, hydrochloric acid anions, organic acid anions, etc. were included, and these substances alone in the form of anhydrides, hydrates, and aqueous solutions Or two or more are used in 0-50% by weight, or as a hydrous aluminum silicate mineral containing alkali metals or alkaline earth metals having various shapes such as 0.0001-7,000㎛ spherical, plate-like, needle-like, and (Si,Al)O ₄ tetrahedral The porous structure and WmZnO _2n2 O composition formula combined in a three-dimensional network, W is Na, Ca, Ba, Sr, Z=Si+Al, quartz SiO ₂ , and a part of Si in the three-dimensional network in which the diamond-shaped tetrahedral structure is infinitely connected Zeolite substituted by Al, siliceous porous material, lightweight foamed ceramic, Silica, Perlite, Titanium Dioxide, Clay, talc, Aluminum Hydroxide, Kaolin, Magnesium Hydroxide, Calcium Carbonate, Diatomite, Loess, Bentonite, Quartz sand, Gypsum, Lime , cement, Terra alba, Pozzolan, Diatom, Pupl Or 1 to 100% by weight of water (H ₂ O) dispersed solids Pupl, etc. alone or using 1 to 99% by weight of two or more, plastering that increases the durability of the structure by protecting the interior and exterior walls, ceilings, floors, etc. of the building A surface finish for use was prepared. The plastering material of the present invention is a material that is strongly formed without cracking after drying or curing by applying, and it is preferable to mainly use it as a finishing material for interior decoration. Its strength is that it can achieve fire prevention and insulation over semi-incombustible by mixing it with other materials without background treatment, and that it can form patterns in various shapes due to various finishing methods.

For example, one of the various composition ratios of Example 31, after plastering one side and a square box with a plastering finishing material prepared by mixing 30g of the present invention, 20g of 50% by weight pulp, and 500g of white clay containing sand Resistance and electromagnetic wave attenuation were measured. 54 is a Surface Resistance Meter SRMⓡ110/Made in EURO of Wolfgang Warmbier, a surface resistance meter, in a test environment of 21° C., 38% RH to obtain a resistance of 10 ⁶ Ω/□, and FIG. The inside of the box was plastered. The same electromagnetic wave generation environment was created for the one coated with the general plaster (non-functional plaster) and the one plastered with the composition of the present invention, and the results were measured using the measuring device E-tester (manufacturer: Pulse) at the same time, and the results are as follows. . The electromagnetic environment was improved from 1,848V/m in electric field to 0V/m in case of general coating. In addition, plaster, lime, water, sand, etc. were the main ingredients for plaster, and gypsum was the main ingredient and dolomite. It is a gypsum plaster mixed with clay, the adhesive of the present invention (grass, etc.), and a glue material, and has been developed as a plastering material for walls and ceilings. Therefore, by mixing the functional additive materials described in Example 30 alone or by mixing two or more types, a cosmetic product that exhibits electromagnetic wave blocking, antistatic, antibacterial/mildew, semi-incombustible abnormality, and freezing prevention performance pursued in the present invention was developed, As for the plaster, the performance improves as it is applied 1 to 10 times thinly, not only for one-time plastering, but also for primary plastering, chaebol plastering, and finishing plastering. For example, using the coating paste of the present invention improves adhesion and suppresses the occurrence of plaster cracks due to quick drying, and the pulp used also reduces cracks and reduces the plaster thickness. The advantage is that it is suitable for country houses and detached houses by the color of loess and various colors in the case of loess, which increases the strength of sand, increases the strength of sand, and implements the unique color of the added ceramic. Here, one or two examples of hydraulic hardening, which is cured by evaporating water, and hydraulic hardening, which is hardened by reaction with gas in the atmosphere, and all the materials that are mixed below, as mentioned above, have various shapes such as spherical, plate-shaped, needle-shaped, etc. If you change this to a mesh unit, materials with 3 mesh or more are used. The loess plaster is 30 to 99% by weight of loess, 2 to 50% by weight of pulp, 1 to 50% by weight of the present invention manufacturing grass (25 to 32% by weight of solid content), preferably 80% by weight, 16% by weight, 4% by weight With a composition ratio of 1-50% by weight of gypsum, 10-90% by weight of loess, 5-30% by weight of sand, and 1-50% by weight of pulp, it is a hydraulic product that is hardened by evaporation of water, and limestone 1 45% by weight, 5-30% by weight of silica sand, 5 to 90% by weight of loess, pulp (I decided to use rice bran or rice husk for all of the above-mentioned compositions instead of pulp), 0-15% by weight of calcium chloride, 1-20% by weight of sea salt Weight%, nickel powder 1-90% by weight The composition is a hard product and exhibits electromagnetic wave absorption, electromagnetic wave blocking, antistatic, antibacterial and anti-mildew, semi-incombustible abnormality, and anti-freezing performance.

And additionally, the effect of far-infrared rays on the loess composition in the composition was measured. As a result of measuring at 40℃ compared to the black body by FT-IR Spectrometer Method, the far-infrared emissivity (5-20㎛) was about 0.902 and the radiant energy was 3.64×10²㎛. The main components of loess of the present invention are kaolinite Al ₂ O _3· 2SiO _2· 2H ₂ O and halloysite Al ₂ O _3· SiO _2· 4H ₂ O, which is a material composed of an excess of Al and Si. Therefore, it is known that materials containing a lot of Al and Si materials have high far-infrared emissivity at high temperatures. 56 shows the measurement results commissioned and evaluated by Test Researcher D. In addition, as mentioned, the loess used in the composition exhibits its unique characteristic ocher color, thereby exhibiting the effect as a beautiful exterior product (see FIG. 57 ), and far-infrared rays, which are a kind of human-friendly wavelength in the ocher product of the present invention. At the same time, it has (+) and (-) ionic properties, so it has an inhibitory effect on (-) and (+) strains. In addition, loess exhibits the effect of having flame retardancy as well as an inorganic flame retardant. As a result of testing the ocher-added sample in the present invention in accordance with KS K 0693-2001, a test result was obtained showing an antibacterial effect of 99.9% against Staphylococcus aureus and pneumococcus, respectively. As shown in FIG. 58, the square box was plastered with the loess plaster composition, and electromagnetic waves were measured using a measuring instrument GIGA SOLUTIONS/Made in Germany. As a result, it was found that the attenuation of the electric field was evident at 8V/m.

Among the above examples and the mixed composition, 0.001 to 100mm carbon fiber or hair, animal hair, or rice bran is used as a substitute for pupl to improve strength and suppress cracking, and to improve coating thickness with one plastering (fiber such as pulp has a synergistic effect ) to shorten the construction period. In particular, the carbon fiber exhibits electrical properties in combination with a (+) charge. -Like silver carrier antibacterial agent- Not only antibacterial effect, but also one stone and six tanks due to electromagnetic wave shielding effect (mechanical strength like fiber, anti-cracking, antibacterial, electromagnetic wave and antistatic, flame retardant effect as it can be dispersed as fibers in the above-mentioned and listed water-soluble substances (Named in anticipation of 6 or more effects from the use of one substance.) With the above effects, price competitiveness was possible.

In Patent No. 1187976, the liquid loess wallpaper composition contains 70 to 90 wt% of loess sediment having a moisture content of 85 to 95% and 60 to 79 wt% of a loess mixture composed of 10 to 30 wt% of diatomaceous earth; 1 to 10% by weight of mulberry powder; Carboxymethyl cellulose sodium (CMC) 0.5 to 3% by weight, propylene glycol (PG) 5 to 10% by weight, terrapin oil 1 to 5% by weight, water 20 to 30% by weight of an aqueous solution containing 72 to 88.5% by weight; comprising; It was a liquid loess wallpaper composition for application, characterized in that 5 to 10% by weight of modified starch is further added to the aqueous solution for quick drying, and in Patent No. 1138128, propylene glycol and terrapin oil are added to the water in the water tank and stirred, , preparing a liquid aqueous solution by adding and stirring sodium carboxymethylcellulose, mixing the mulberry powder in the previously prepared aqueous solution, mixing the ocher mixture consisting of loess sediment and diatomaceous earth with the mulberry powder mixture; It relates to a method for preparing a liquid loess wallpaper composition for applying, characterized in that it comprises a liquid grinding step of grinding a mixture of the loess mixture consisting of the liquid aqueous solution, mulberry powder, loess sediment and diatomaceous earth, and the aqueous solution is 82-88.5 wt% of water, Propylene glycol (PG) 5-10% by weight, terrapin oil 1-5% by weight, carboxymethylcellulose sodium (CMC) 0.5-3% by weight of sodium carboxymethyl cellulose (CMC) in the liquid aqueous solution to contain additional alpha (α) starch Sodium Chloride, Magnesium Chloride, Calcium _Chloride (European, African, Asian, North American, 0-50 wt% of powder or aqueous solution thereof, such as South American, Oceania, especially easily secured domestic and Chinese), used alone or in a mixture composition of two or more; 1~100% by weight Salt is edible salt with sodium chloride as its main ingredient, sun-dried salt and industrial substances used as chemicals, East Sea, West Sea, South Sea, Mediterranean Sea, Pacific Ocean, Atlantic Ocean, Indian Ocean, Northern Sea, Antarctic Sea, Dead Sea, Black Sea, etc. Salts produced in Europe, Africa, Asia, North America, South America, Oceania, especially in Asia such as the United States, Australia (Australia), China and the Philippines, Europe, and the West Sea, or 6 continents such as Africa, America, and Tibet 0-50% by weight alone or in a mixture of two or more products produced in the salt mine of Use 0-50% by weight of 1 to 69% by weight of solid content composed of bromide, such as 0.2 to 0.4%, or 0 to 50% by weight of boiling 100 g of these, or heating and concentrating 5 to 90% of these, or Calcium Chloride, Sodium Chloride, etc. Among those whose corrosive properties have been lowered by treatment with a low-corrosion or low-chlorination system, 0-50% by weight of these substances alone or two or more are used, or as an ionic compound with a solid content of 5-100% by weight - The ionic compound is a metal cation and a non-metal Anions are bound by electrostatic attraction, and the sum of charges is electrically neutral.- Cationic metal elements with a valence of +2 or higher are Co, Cu, Ni, Mn, Zn, Fe, Al, Be, Mg, Ca, Ba. and the like. anion, acetate ion, hydrogen carbonate anion, borate anion, chromate anion, dichromate anion, halogen anion, hydrochloric acid anion, organic acid anion, etc. One or more may be mentioned. In consideration of corrosion of equipment and solution stability, ammonium salt may be additionally included, and 2 to 50% by weight of two or more of these substances are used alone or in the form of an anhydride, hydrate, or aqueous solution, or solid content of 5 to 100% by weight of ions As the sexual compound, a +1-valent cationic metal and a -1 or -2 valent anion are used, and the cationic metal element belonging to this may include at least one selected from the group consisting of Li, Na, K, etc., and the anionic element is fluorine Sulfide anion, bromide anion, iodide anion, sulfide anion, chloride anion, ammonium anion, hydroxide anion, sulfate anion, carbonate anion, nitrate anion, phosphate anion, permanganate anion, acetate ion, hydrogen carbonate anion, borate anion, chromate anion, dichromate anion At least one selected from the group consisting of anions, halogen anions, hydrochloric acid anions, organic acid anions, etc. was included, and 0-50 wt% of these substances alone or two or more were used alone or in the form of an anhydride, hydrate, and aqueous solution, or solid content 0.1 ∼50 wt% Conductive Polymer (Polythiophene, PEDOT-PSS, Polyaniline, Polypyrrole) 0∼50 wt% or 0.0001∼7,000㎛ Iron powder, Copper powder, Cobalt having various shapes such as spherical, plate, and needle-shaped powder, Tin powder, Aluminum powder, Magnesium powder, Titanium powder, Silicon powder, Nickel powder, Zinc powder, Manganese powder. Soft ferrite such as Silver powder, Ag coated Cu, Ni coated Cu, Indium tin oxide, solder ball (Free lead Tin-Bismuth), silver chloride, Antimony tin oxide, Stainless Steel, Mn (or Mg, Ni, etc.)-Zn ferrite and 0-50 wt% of a hard ferrite such as Ba (or Sr, etc.) ferrite, prepared in the composition of Examples 1, 4, 5, 7, 8, 9, 11, 17, 19, 21, 22, 23 So; In a wallpaper composition for simple application, an application product using a composition that exhibits electromagnetic wave blocking, antistatic, antibacterial/mildew, flame retardant abnormality, and antifreeze performance pursued by the present invention was developed.

Among the currently commercialized insect repellents, the main ingredients of spray insecticides are phthalthrin and pyrethroid compounds used in pesticides. These ingredients are less toxic than organochlorine or organophosphorus insecticides, so they are widely used. imidacloprid, a colorless and odorless transparent gel, is said to disappear when sprayed on corners and crevices of a house, but it is also a drug that is applied to various insects. It is a kind of pesticide that is known to cause a fatal injury to the ecosystem, and is concerned that it may disturb the ecosystem.

However, the composition of the present invention, that is, the salts of the additives of Examples 1, 4, 5, 7, 8, 9, 11, 17, 19, 21, 22, 23, 27, 29, 30, and 31 of the present invention are electrolyte ions. The better the dissociation, the better the electrical conductivity, and it is one of the essential components that we need to live. This is because if we do not consume the salt contained in salt, our body cannot function properly. In addition, even if harmful substances or bacteria invade the body, it also plays a role in increasing the body's resistance to prevent the invasion of cells and blood vessels. So, if the human body lacks salt, toxins accumulate in our body and it is easy to get bad diseases, but only the heart in the body never gets cancer, because the heart contains the most salt. Not only humans, but all living things on Earth cannot survive without salt intake. Animals ingest salt by finding salt rocks or salt caves, and plants absorb salt from the ground. If cattle or horses do not consume salt, they cannot use their strength, and trees that lack salt easily rot. Therefore, salt does not give a chance for various germs, bacteria or microorganisms to reproduce, and has properties that do not change even after a long period of time. Salt dissolves well in water, so it penetrates and mixes well with other substances. And since salt has the property of absorbing dust, you can clean every nook and cranny. It is a purifying property, so it has been said since ancient times that if you put salt in a place where mold is common in every corner of the house, or if there are a lot of ants in the house, if you sprinkle salt on it, it will go somewhere else. As a good example, the Tripitaka Koreana was completed in 1251, and when the remaining wooden blocks are stacked one by one, the height is about 3.2 km, and the total weight is about 280 M/T. Even if it was well made, it would not have been possible to admire the beauty of the Tripitaka Koreana today if it had not been properly preserved. Considering the reason why it was able to be preserved in its original form for a long time, first, looking at the wood selection process, the wood, which will be used as a stencil, is not used immediately, but is soaked in seawater for 1 to 2 years. After that, it was cut to the size of a plate, boiled in brine and dried. Salt has the property of preventing cracks in wood caused by temperature and humidity, so it can reduce the phenomenon of cracking or twisting of the hard plate. The place to store the completed Tripitaka Koreana is also important, so the environment suitable for the preservation of woodblocks is around 20 degrees Celsius and less than 80% humidity. However, the climate of the Tripitaka Koreana does not satisfy this criterion. The average humidity inside Panjeon is 89.09% in summer and 75.91% in winter, which is higher than general wood preservation standards. The average summer temperature was 19.81 ℃ in summer and 2.74 ℃ in winter, which was much lower than the winter indoor temperature standard. What was the reason why the plates were preserved for hundreds of years even in the environment inside the Panjeon that was outside the proper wood preservation environment standards? Natural ventilation and the floor of the storage building were dug deep and sprinkled with charcoal, clay, sand, salt, and sashimi powder. When there is a lot of rain and humidity, the floor absorbs moisture, and when there is a drought, the moisture hidden in the floor rises and automatically adjusts the humidity. Also, salt can get rid of ants. Ants instinctively like sweet smells. I like sugar or sweet candy, but I hate salt or vinegar, etc., so I conducted a reaction experiment on salt with 100 ants, and it was found that the ants did not come to the part sprinkled with salt. As shown in Figure 59, as seen in this actual experiment, it was confirmed that salt has an ant repelling effect.

Therefore, as the salt used in the present invention, on the one hand, edible salt containing sodium chloride as a main component, chemicals, and materials collected and manufactured from rock salt were used, and on the other hand, seawater was directly collected and used. Salt is naturally present in seawater by 2.8~5.0%, and in land where it exists as rock salt, 3.5~5.0%. Rock salt is mainly produced in Europe, North America, and China. For industrial purposes, it is used as it is, but edible salt is refined salt, which is manufactured by the salt field method or by using an ion exchange resin when it is collected from seawater. When hydrochloric acid and sodium hydroxide are neutralized, sodium chloride (salt) and water are produced by the neutralization reaction. That is, sodium chloride exists as ions (Na+, Cl-) in solution, and when water is evaporated, solid sodium chloride is formed. When it is mixed with water again, it becomes an aqueous electrolyte solution containing Na+ and Cl- and exhibits electrical properties. As shown in Table 15, seawater, that is, ordinary seawater, contains water as the main component, has a salinity of 5.0% or less, and is composed of trace amounts of metals (minerals). The salinity ratio of seawater is higher than the salinity concentration of the living body (about 0.9%), but it can be seen that it has the most similar ratio to humans compared to other organisms (animals) based on Na + 100. Therefore, salt is a substance beneficial to the human body enough to not be harmful to the human body unless eaten in large quantities. As well as the mentioned conductive properties, it is excellent in inhibiting various bacteria and fungi, and it is a material with excellent flame retardancy. , Indian Ocean, Arctic Ocean, Antarctic Ocean, Dead Sea, Black Sea, etc. (European, African, Asian, North American, South American, Oceania) Asia, Europe, USA, Australia (Australia), China, Philippines, Vietnam It is a product manufactured from salt produced in the West Sea or from salt mines on six continents such as Africa, America, and Tibet. Especially, when painting and installing, it is a product that can provide emotional stability in the case of home and domestic products. work will be Therefore, the material of the present invention is friendly, friendly, and beneficial to the human body, and some products manufactured according to the present invention are not harmful to the human body even if eaten, so that they can be used (substitute) as food in an emergency.

division Na+ K+ Ca2+ Mg2+ Cl- sea water 100 3,61 3,91 12.1 181 jellyfish 100 5.18 4.13 11.4 186 Humpback Shark 100 4.61 2.71 2.46 166 Dae-gu 100 9.50 3,93 1.41 150 frog 100 - 3.17 0.75 136 dog 100 6.62 2,80 0.75 139 Person 100 6,75 3.10 0.70 129

(Source: Water and Hananika, 講談社)

The cause of static electricity due to charging is the electric charge charged on the surface of the insulator due to electromagnetic waves in electric and electronic products or friction caused by low humidity, which is the cause of defective products. However, it may lead to fire and explosion hazards in flammable substances handling workplaces such as gas stations. 60 shows the capture principle and scene of ignition by static electricity at the mother gas station. As such, ignition by static electricity frequently occurs in the vicinity. The cause of ignition at a gas station is that friction electricity generated by friction during movement is charged to the insulator, which is an insulator, and then instantly escapes to another nearby object, leading to ignition and explosion. Almost all gas stations are equipped with a lubricator on the floor, which is the surrounding insulator, so the only place to escape in case of static electricity is the lubricator. As a solution to this, when the floor is constructed with the product of the present invention, even if the driver's shoes are an insulator and serve as a charging body, even if the static electricity is not completely eliminated, some drivers and surrounding static electricity is released to the ground to increase the static electricity In addition, if a metal wire is briefly connected to the vehicle body before refueling, if the vehicle body and the ground are connected with a conductor that can disperse and drain static electricity generated during driving through this, the ignition as shown in FIG. It is another feature according to the present invention that can be solved. That is, if a long wire is provided with a lubricator to put the wire on the vehicle body first and then refuel, the static electricity is first released from the driver's clothing, which may have static electricity the moment the driver grabs the wire, and the static electricity of the vehicle body is the result of the present invention. A system capable of dissipating static electricity through the floor is also one of the features of the present invention.

Although the scientific principles, considerations, experiments (tests), and descriptions and illustrations of the present invention have been described above, it is apparent that the present invention may be practiced with various modifications by those skilled in the art. Such modified examples should not be individually understood from the technical spirit or perspective of the present invention, and such modified examples should fall within the scope of the appended claims of the present invention.

10: printed layer (base material layer, embossing layer).
20: Flame-retardant (antistatic) coating layer.
30: Foam or sheet (paper, plastics, etc.).
40: aluminum foil layer.
50: adhesive layer.
60: Lee Hyung-ji.
70: polymer material.
70' paper.

Claims (3)

Adhesives that provide adhesion, metal chlorides, salts, acids, preservatives and solvents;
The adhesive material is polyvinyl alcohol, polyvinyl acetate, acrylic, epoxy, silicone, polyurethane, ethylene vinyl acetate, Polyvinyl chloride (Polyvinyl Chloride), vinyl acetate acrylic copolymer (Vinyl Acetate Acrylic Copolymer), including grain or modified starch alone or two or more, the solid content is 10 to 100% by weight,
The metal chloride includes alone or two or more of ZnCl ₂ , MgCl ₂ , CaCl ₂ , KCl,
The salt includes one or two or more of sea salt, refined salt, and rock salt,
The acid comprises one or two or more of pH 4 or less,
The solvent is methanol, ethanol, butanol, dichloromethane, ethylacetate, hexane, diethylether, acetonitrile, benzene (benzene), 1-methoxy-2-propanol (1-METHOXY-2-PROPANOL), BC (Butyl cellosolve), Diethylene Glycol Monoethyl Ether Acetate, alcohol (alcohol), An adhesive composition comprising one or two or more of water (H ₂ O). The method of claim 1,
The adhesive composition is an adhesive composition obtained by mixing an adhesive material, a metal chloride, salt, an acid, and a preservative with a solvent and heating and stirring it at 45°C to 103°C. 3. The method of claim 2,
The preservative is carboxymethylcellulose sodium (CMC), chlorinated 5 Chloro 2 methyl 4 isothiazolin 3 one, unchlorinated 2 Methyl 4 isothiazolin 3 one, 3-lodo-2 propynyl butyl carbamate, Octylisothiazolinone alone or two or more Adhesive composition comprising.

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