KR20190028625A - Composition that combines electromagnetic wave shielding and antistatic, flame resistance, antibacterial, antifungal, prevention of corruption, anti-condensation, anti-foaming, and applications using them - Google Patents

Abstract

The present invention relates to a composition having electromagnetic wave shielding, anti-static, anti-bacterial, mildew resistant, flame retardant, corrosion prevention, condensation prevention, humidity control, and anti-freezing functions in a selective or complex manner and an application product thereof. According to an embodiment of the present invention, the material with the above-described functionality has 1-100 wt% of metal chlorides of anhydrous or hydrous nH_O (n=0-99) in a solid powder form such as sodium chloride, magnesium chloride, and calcium chloride or an aqueous solution thereof.

Description

TECHNICAL FIELD [0001] The present invention relates to a composition for combating electromagnetic wave shielding, antistatic and flame retardant, antimicrobial, anti-bacterial, anti-condensation, anti-condensation, anti-foaming, corruption, anti-condensation, anti-foaming, and applications using them)

The present invention relates to a composition that exhibits a combination of electromagnetic wave shielding, antistatic and flame retardant, antimicrobial, anti-bacterial, anti-condensation, anti-condensation, anti- , Prevention of condensation, prevention of dew condensation, and prevention of churning.

The electromagnetic waves radiated in the electric and electronic products and communication means, especially the electric lamps, etc., are accumulated or cut off, and the electromagnetic waves radiated in the space are eliminated or destroyed as a feeble heat in the layer with resistance so as to prevent industrial troubles caused by static electricity, (Dust that is charged in the air will be harmful to the human body if it enters through the respirator or it will not fall on the surface of the product.) Construction, construction, construction, chemical, It is a field that can prevent the phenomenon of freezing of adhesive material before drying and prevent the phenomenon that the adhesive material is frozen during circulation and storage and it is inferior in inherent adhesion ability when it is used in industrial field, manufacturing and interior of materials, etc. It has been applied as a lightweight new material in various industrial fields such as construction, electricity, electronics, and automobile, and the use of plastic foam It is necessary to use flame retardant (hereinafter referred to as flame retardant) foam, which has inherent mechanical properties such as strength, non-rigidity, impact resistance and light weight, In particular, foam products containing a large amount of air layer (air bubbles) are more vulnerable to fire than concrete or metal panel, and are manufactured using a large amount of air bubbles and water vapor In the field of foam insulation where there is a risk of fungi due to moisture, there is a difference in the outside air and the internal temperature, and a humid air sticks to the wall, resulting in a dew drop. It is easy to generate moisture in outer wall, window, wall, floor, bathroom, etc., The main cause of the condensation phenomenon is known to be due to the difference in temperature and humidity inside and outside the winter especially in the condition that the amount of sunshine is low and ventilation is not possible. Or a porous product such as a styrofoam, is known to prevent the occurrence of dew if it gives an effect of insulation inside and outside. However, in the field where the condensation phenomenon is severe, the field which is considered to be the best way to give heat insulation, dew condensation prevention and antimicrobial property to products such as heat insulation, condensation and antibacterial paint, the present invention is applied to prevention of electromagnetic wave and electrification phenomenon, , Dust removal by neutralization action, air purification by elimination of electrification phenomenon, summer pollution prevention, winter prevention prevention. And a technology applicable to various fields such as insect fighting.

In the present invention, it is realized through the following technique. The present invention is based on the electromagnetic wave shielding and antistatic function and has a role of removing electromagnetic waves and static electricity radiated from various electric and electronic products by providing flame resistance, antimicrobial, anti-fogging, anti-condensation, It reduces the adverse effects of various bacteria and fungi. It also has the characteristics of flame retardant for flame and gas, which is a direct cause of human injury due to toxic gas and smoke in fire, construction environment and product storage due to freezing due to cold weather. To prevent electromagnetic interference, antistatic and flame retardancy, antimicrobial and anti-bacterial, anti-condensation, anti-condensation, anti-foaming, and application products using the same.

The present invention will now be described in detail with reference to the accompanying drawings, wherein like reference numerals refer to like elements throughout.

(1) Electromagnetic wave shielding: It is certain that various communication devices and electronic devices will flood everywhere in the world. As the information society becomes more advanced, the use of electric / electronic products is greatly increased and problems caused by unnecessary electromagnetic waves And this will cause the future environment to cause a lot of electromagnetic waves in the atmosphere, causing the electromagnetic waves to be chaotic. In addition, electromagnetic waves, which are called as the fourth pollution resulting from environmental pollution such as air pollution and noise pollution, can not be felt by human senses, which adds to the seriousness and can cause malfunction of peripheral equipment and various diseases . Therefore, the importance of the development of related technologies that can cope with this situation is becoming more important. Already in the European Union (EU), developed countries have enacted EMC (Electromagnetic Compatibility) regulations that add EMS (Electromagnetic Susceptibility) regulations to EMI (Electromagnetic Interference) regulations. In addition, the World Trade Organization (WTO) implements some items as non-tariff trade barriers and is gradually expanding. In the European Union, it is applied not only to auto parts but also to finished cars and new cars. In Korea, the standards and applied products are being expanded.

(2) Antistatic property: Electrification, that is, static electricity is remarkably weak in electric shock due to static electricity, and does not die due to electric shock. However, due to its electrostatic shock, contact with the machine or stress caused by the fear, Secondary failure, malfunction, and damage to electronic components. In the electrostatic phenomenon, which is one of the application fields of the present invention, when the static electricity of the human body is a problem, the resistance of the human body is several k? To several thousands of k ?, which can be regarded as a conductor electrically. However, In a state insulated from the ground, a kind of capacitor is formed between the ground and the ground, so that static electricity on the conductor is easy to increase the capacitance, and the whole electric charge is discharged at one place at a time. There are two types of electric shocks to the human body: a case where a human body charged with static electricity is discharged close to another object that is grounded or charged, and a case where a charged object discharges while approaching a human body. That is, it is known that the static electricity accumulated in the entire body is not caused by the shock of the human body but also by the momentary discharge due to the friction and contact between the materials. In order to prevent such static electricity disturbance, it is necessary to remove, neutralize, and leak generated electric charges. As the information society has been progressing rapidly, there has been a great increase in the use of electric and electronic products, and it has been difficult to eliminate the malfunction of various products due to electromagnetic fields generated from these devices and the noise phenomenon of electric / electronic devices and communication devices. In the meantime, in addition to the use of an electronic component manufactured by using an inductor capacitor or ferrite, measures against this include grounding or shielding. Shields, which are known to be the most effective of the countermeasures, are expensive and heavy metals such as copper, aluminum, and iron for excelling in high attenuation characteristics over a wide frequency band. There arises an inevitable problem that the noise phenomenon must be solved while changing from a metal to a resin. Although materials such as plastics are mostly used as insulating materials in various electric and electronic parts, such insulating properties cause electrostatic charge to accumulate on the plastic surface to cause electrification phenomenon. This charging phenomenon is a cause of defective products in semiconductor, electronic products, fiber, film and the like due to production obstacles and disasters in the industrial field by adsorbing dust and dirt, and it also causes malfunction of circuits in electric and electronic products. In the case of a TV screen (in the case of a cathode ray tube system), for example, a static electricity of 5.000 V to 10 000 V flows during a broadcast when a disturbance due to a static electricity (electric field) or an indirect human body influence is observed. This static electricity is discharged toward the earth, while attracting negative ions in the air, resulting in neutralization of negative ions. Since the anion in the air is consumed at this time, a cationic environment in which the positive ions are relatively increased in the room air is obtained. As a result, the intake of positive ions during respiration dominates in vivo. The composition of this cation is hydrogen ion (H ⁺ ). When the hydrogen ion concentration becomes high, the body fluid including blood tends to be acidic. Especially, the hydroxide ion (OH ^- ) formed by dissociation of water (H ₂ O) molecules is a strong base and easily oxidized. In this way, since the hydroxide ion is decreased, the hydrogen ion concentration is relatively increased, and particularly, the positive static electricity leads the body fluid to the acid. Both static electricity increases the active oxygen in the body and acidifies the living body, which can interfere with the metabolism and weaken the cell function. Therefore, it is known that the decrease of immunity is likely to cause various diseases. Therefore, static electricity and electromagnetic waves may be disturbing the mechanism of the living body. In other words, the lack of electrons is a cation because it has a positive charge, and an excess of electrons is called an anion because it has a negative charge. The anion, which is called the vitamin in the air, is present together with various kinds of mixed substances such as carbon dioxide gas, oxygen, nitrogen, and hydrogen together with the cation in the air. When the cation is large, the negative ion becomes positive static electricity. . A person with a weak constitution in a cation-rich atmosphere is likely to have a chronic illness, and all diseases are likely to become worse. On the contrary, if there are many negative ions, the cell becomes active, and it becomes resistant to the disease and the body can become a healthy weak alkaline body. The phenomena that the human body can feel are: a feeling of freshness when walking through a storm, a feeling of standing in a waterfall, a feeling in a pine forest, a water droplet splitting into an object, And the ambient air may be caused by a large amount of negatively charged oxygen ions (anions) generated by the ionization phenomenon (the Leonard phenomenon), which causes the cathode to be electrically charged. The refreshing feeling of anions is due to the abundance of anions that act to purify fine contaminants in the atmosphere. When the waterfall falls and the rocks collide violently on the surrounding rocks, the water droplets are split into very small clusters (particles), which causes a large amount of negative ions to be generated when the water droplets are finely divided. When the amount of ions in the air is measured, it can be seen that the negative ions are abundant in the forests and near the waterfall. Contact with such nature will sense exhilaration and rest. Cations are found in many places around electrical and electronic products such as buildings, concrete, polluted cities such as automobiles and factories, cigarette smoke, office automation (office automation) office equipment and computers. It is called the Leonard phenomenon after the Nobel laureate physicist Dr. Beverly Leonard to generate anion in nature. In order to minimize the influence of the electrification, an antistatic composition comprising at least one conductive material selected from the group consisting of a conductive polymer, conductive carbon, and graphite, a polymer, a solvent, etc., Attention needs to be paid, and even though the price of conductive polymers is falling, it is still expensive (September 9, 2017) for general use.

(3) Antibacterial and anti-bacterial properties: In order to produce antibacterial products, inorganic antibacterial agents and organic antibacterial agents are used. Antimicrobial products are commercialized by adding organic antibacterial agents or inorganic antibacterial agents to polymers (polyethylene, polypropylene, polyvinyl, epoxy, etc.), tiles, commercialized products such as buckets, sheets, fibers, paints and tiles. It is necessary to add an expensive antimicrobial agent. Therefore, there is a problem (generalization failure) to apply to products such as a case where a large area is applied.

(4) Flammability:

The flame retardant material is called flame retardancy because it is almost the same as the material for flame retardancy or has a very high similarity. As flame retardant materials, flame retardants mainly composed of halogen-based, antimony-based, inorganic, phosphorus-based, nitrogen-phosphorus and the like which are generally used when various polymer flame retardant materials are manufactured are used. In case of fire, the use of flame retardant products is gradually increasing in consideration of safety. Polymers are composed mostly of organic materials and are easy to burn. A substance added to physically or chemically modifying such properties to suppress or alleviate combustion is a flame retardant. Generally, flame retardants are classified according to the method of use and constituents, and are divided into additive type and reactive type depending on the method of use. The addition type is an organic type and the inorganic type, and the reaction type is a flame retardant containing active radicals such as -OH, -H, and -COOH. The organic system is classified into phosphorus, nitrogen system (melamine system), bromine system and chlorine system, and inorganic system is exemplified by antimony system and metal hydroxide system (aluminum hydroxide, magnesium hydroxide) It is classified. Particularly, among the organic flame retardants, brominated flame retardants have excellent flame retardant properties and are used in various plastic products in a large amount. However, due to the release of toxic gaseous compounds such as HBr in burning, the range of use restrictions is gradually widening. First, we will explain the previous flame retardants and explain the excellence through future comparative evaluation. The characteristics of flame retardants mainly used are as follows. ① Flame retardancy among halogen flame retardants and halogen compounds is superior in order of I> Br> Cl> F, but iodine compounds are expensive and have low CI bonding force, so they are easily decomposed at processing temperature and fluorine compounds are inefficient And bromine is more expensive than chlorine but has an excellent flame retardant effect and is widely used in general-purpose and epoxy resin. Typical examples of brominated flame retardants include tribromophenoxyethane, tetrabromobisphenol A (TBBA), and otabromodiphenyl ether (OBDPE), among which TBBA is the most commonly used. Brominated flame retardants are generally used as anti-flame-retardant adjuvants (antimony trioxide, antimony pentoxide, etc.), and the reaction mechanism is as follows.

<General reaction mechanism of halogen-based flame retardant>

HO + HX → HOH + H → inhibition reaction

X + RH → HX + R → regeneration reaction

                      ↓ Stop the chain reaction

XO + OH → HX + O ₂ → Reduce the concentration of active O, OH and stop the chain reaction

                   → Flame retardant effect

X + O → XO + X → Noncombustible gas generated upon decomposition → O ₂ block

 O + OX - &gt; O2 + X

<Mechanism of Reaction of Halogen + Antimony Flame Retardant>

_{Sb 2 O 3 + 2HBr → 2SbOBr} + H 2 O

_{5SBOBr → Sb 4 O 5 O 4} Br + SbBr ↑

4Sb ₄ O ₅ Br ₂ → 5Sb ₈ O ₄ Cl + SbBr ↑

3Sb ₈ O ₄ Br → 4Sb ₂ Cl ₃ + SbBr ₃ ↑

Chlorine-based flame retardants include chlorinated paraffin, chlorinated polyethylene, and alicyclic chlorinated flame retardants. Chlorine paraffin and polyethylene have a disadvantage in that they are inexpensive but have poor thermal stability and the price of alicyclic flame retardants is rather high.

Examples of the inorganic flame retardant include aluminum hydroxide, magnesium hydroxide, antimony oxide and boron-containing compounds. Unlike organic flame retardants, inorganic flame retardants dissolve without being volatilized by heat and release incombustible gases such as H ₂ O, CO ₂ , SO _2, etc., and most of them have endothermic properties. In the gaseous state, the combustible gas is diluted and the plastic surface is coated to prevent the oxygen from approaching, and at the same time, the endothermic reaction on the solid phase surface is effective in reducing the generation of plastic cooling and pyrolysis products. Further, in the case of a boron compound, a glass-like protective layer is formed on the surface of the solid to thereby effect oxygen and heat shielding. Aluminum hydroxide is the cheapest inorganic flame retardant but can only be used in plastics with a decomposition temperature below 200 ℃ and low processing temperature. The reaction mechanism of the inorganic flame retardant is as follows.

<Flame Retarding Mechanism of Inorganic Flame Retardant>

_{2Al (OH) 3 → Al 2} O 3 + 3H 2 O - 298KJ / mol

Mg (OH) ₂ - &gt; MgO + H ₂ O - 328 cal / mol

Phosphorus compounds are generated by pyrolysis at the time of combustion, and polyphosphoric acid produced by the esterification and dehydrogenation reaction generates char to block oxygen and heat. Phosphorous flame retardants are phosphorus, phosphates, phosphine oxide, etc. In case of red phosphorus, the color of the compound is red, so the compound water is red and its use is limited due to color problems. Phosphoric acid ester flame retardants include monomeric triaryl phosphate, alkyldiaryl phosphate, trialkyl phosphate and oligomeric resorcinol bisdiphnyl phosphate. Nitrogen-phosphorous flame retardants include melamine-phosphate and melamine-polyphosphate. Nitrogen-phosphorous flame retardants are produced by thermal polycondensation of polyphosphoric acid and nitrogen source (N ₂ , NH _3, etc.) To prevent diffusion of heat and oxygen. However, it lacks physical properties and price competitiveness due to high usage. And antimony, tin, zinc, and selenium are heavy metals that are used to add flame-retardant function in wallpaper. It is reported that exposure to small amounts of heavy metals induces various neurotoxic effects upon absorption into the body, especially antimony has similar toxicity to arsenic and, if exposed, causes pneumonia, osteoporosis and cancer. (Source: KANALYTICAL SCIENCE & TECHNOLOGY , Vol. 21, No. 2, 135-142, 2008)

In addition, when the plastic is being used in recent years, the surface of the product is coated by using a flame retardant composition, or when the product is a multi-layered product, the flame retardant composition may coat the interior with one or more layers to prevent the fire from further proceeding in the flame retardant coating layer . And products are concerned about the occurrence of mold due to absorption action by large amount of air bubbles (pore) and moisture contained. The object of the present invention is to provide an antimicrobial antimicrobial effect by inhibiting the fungi of a material contained in the composition, thereby suppressing fungi such as fungi. The cause of the generation of static electricity is mainly due to charges charged on the surface of the insulator due to low humidity. , And may also lead to fire and explosion hazards in flammable materials handling plants. The present invention is to provide a pleasant environment and life from harmful factors through various complex selective functions (effect) by suppressing the generation of static electricity with a surface resistance of 10 ¹⁰ to 10 ⁵ Ω / □.

(5) Anti-foaming: The adhesive that contains water is used in the construction process due to the problem of cold weather. (In case of cold weather, it is necessary to use less water than usual in addition to water, It is a product containing water, such as a problem of circulation and storage, etc.), starch (glue), glue, and glue, have. Although this paste (starch powder) has been found to have strengths due to freezing and weight reduction during circulation, it may not be completely solved during use, which may cause aggregation of the paste, and this also requires the use of water, When the paste is applied to the wall, it may freeze before it dries and the wallpaper may fall. Also, in order to prevent a little frost, it is used to reduce the amount of water used in the water blending. ), And the use of the grass in cold weather may increase the use of the grass as compared with the addition of normal water. Even if the pool value is cheap, it is a problem that it can be an economic burden and a disadvantage in use when the area is large. The seawater did not freeze in winter, and was applied to the present invention. In order to confirm the above principle, the following test was carried out first. The water begins to freeze past 0 ° C and completely freezes at -1.0 ° C, but the mixture with 0.24 g of salt and 19.76 g of water begins to freeze at -0.45 ° C and partially freeze (salt 1.12% by weight) at -1.0 ° C. The mixture containing 0.62 g of salt and 19.38 g of water was freezing at -1.0 캜 at all and freezing slightly at -2.0 캜 and remained much water (3.1% by weight of salt) than the previous brine (1.12 wt% of salt). As described above, as the concentration of salt becomes higher, the freezing point becomes lower and it is confirmed that it does not freeze well. The present invention is based on the object of reducing the freezing point, such as antifreeze (liquid used to prevent freezing of cooling water for automobile engine), when it is applied to products with high freezing point such as water-soluble products, And prevents the loss of adhesion and coating power by maintaining the inherent performance.

(6) Insect control: The main ingredient of spray insecticide is pyrethroid compound used for phthalthrin and pesticides. This ingredient is used much because it is less toxic than organochlorine or organophosphorus insecticide. It is said that imidacloprid, which is an ingredient to fight ants, is a colorless, odorless transparent gel. If you spray it on corners of a house, corner cracks, etc., ants will disappear, It is a kind of pesticide that is said to give harm to the nervous system of bees and to raise concern about disturbing the ecosystem.

(7) Insulation and humidity control function as another effect in the composition of the present invention:

It is related to the thermal conductivity. Even a polymer (plastic) with a low thermal conductivity has the heat conduction by the conduction. And the difference between the turtle and the rabbit is that the gas particles move and heat transfer and the heat transfer to the solid particles is as big as the turtle and the rabbit. Porous products such as foam collect the gas by the plastic and have the heat transfer rate and the insulation property. However, it is a disadvantage that foaming products contain a large amount of gas and are very vulnerable to fire. (See Fig. 1, right picture.) It is a general phenomenon that condensation forms mold again due to condensation even when mold is removed. The fundamental solution is to prevent condensation, but heat insulation works should be done to prevent condensation due to moisture, but it is difficult to construct. In order to prevent fungi from condensation or moisture, it is anticipated that antimicrobial activity can be maintained so that molds can not be inhabited, thereby preventing fungi. In addition, There is a technique that uses substances to prevent it. Asbestos is known to be a substance that can cause fatalities if it enters the body through the respiratory tract.

The appropriate humidity in the room is said to be 40 to 60%. Drying due to low humidity in winter is more serious than other seasons, and when it is heated by cold weather, it becomes dry more and more. If dry weather persists, the virus becomes more susceptible to the growth of viruses due to low humidity, leading to a higher frequency of respiratory illnesses (Source: bestbaby, Oct. 2012). Conversely, higher humidity will create a favorable environment for indoor mites and bacteria (Source: bestbaby, November 2012 issue). So, humidifiers are used to control the humidity, plants are raised, or laundry is put on, but all of them are solutions only by local area.

As described above, the present invention was invented in order to solve the problems of the prior arts and techniques, and it is an object of the present invention to provide an apparatus and a method for manufacturing the same, (We are still in the midst of inventing and discovering the possibility of additional functions).

TECHNICAL FIELD The present invention relates to a composition that exhibits a combination of electromagnetic wave shielding, antistatic and flame retardancy, antimicrobial resistance, prevention of condensation, prevention of dew condensation, and antistatic performance, and an application product using the composition. More particularly, , Antimicrobial resistance, prevention of condensation, prevention of dew condensation, anti-foaming ability and additionally insect-fighting ability.

To achieve this,

Acrylic, Epoxy, Polyvinyl Alcohol, Polyvinyl Acetate, Silicone, Polyurethane, Ethylenevinyl Acetate, Polyvinyl Chloride, Vinyl Acetate Acrylic Copolymer, Acrylic Copolymer. Gum Rosin, 2-Ethyl Hexyl Acrylate Monomer, 2-Ethylhexyl 2-Propenoate, 2-Hexyl. 2-EHAM, 2-Ethyl Hexyl Acryl Acid, Butyl Acrylate Monomer, N-Butyl Ester, Butyl 2-Propenoic Chloroprene Rubber, Acid, n-Butylacrylate and Resin of Vinyl Acetate Monomer, Solution or Acid, Primer, Emulsion, Monomer, Copolymer , Or a material made of grains such as Resorcinol, α-Olefin, Isocyanate, Phenolic, Thermosoftening Plastic, Thermosetting Plastic, Starch, Rice, Wheat, Wheat, Corn, Potato, Dextrin, Modified starch,

 Herein, the composition materials, the mixing ratio, and the manufacturing process for forming the composite function of the present invention are as follows.

Magnesium Chloride, Calcium Chloride, etc., belonging to a metal chloride of anhydrous or functional nH ₂ O (n = 0 to 99) having a solid content of 1 to 100 wt% 1 to 100% by weight in the form of a single or a mixture of two or more of these substances in the form of a powder or an aqueous solution thereof Salt is an industrial salt used as an edible Salt, a salt and a chemical used as a main component of sodium chloride, , Magnesium Chloride, Magnesium Sulfate, 6-9%, Potassium Chloride 2-4%, Sodium Chloride 2-6%, Magnesium Bromide 0.2-0.4 %, Etc., or 0 to 40% by weight of those obtained by heating these 100 g to 5 to 90% by weight or by treating them with an acid such as calcium chloride or sodium chloride to form a low corrosive or low salt Among them lowered in corrosiveness by fire, 0-40 wt% of these materials alone or two or more of them, or 5 to 80 wt% of solids is used as the ionic compound. The ionic compound used in the present invention is a cationic metal source And the anion element may be at least one element selected from the group consisting of Co, Cu, Ni, Mn, Zn, Fe, Al, Be, Mg, , A chloride anion, a ammonium anion, a hydroxide anion, a sulfate anion, a carbonate anion, a nitrate anion, a phosphate anion, a permanganate anion, acetic acid ion, a hydrogen carbonate anion, a boric acid anion, a chromic acid anion, a bichromate anion, a halogen anion, , Ammonium salts may be further included in consideration of corrosion of equipment and stability of the solution, and salts thereof may be added in the form of a hydrate, an aqueous solution thereof, or a mixture of two or more thereof and 2 to 50 wt% Or a solid content of 5 to 80% by weight, wherein the ionic compound has a cation of +1 and a cation of -1 or -2, May be at least one selected from the group consisting of Li, Na, K and the like, and the anion element may be at least one selected from the group consisting of a fluorinated anion, a bromide anion, an iodide anion, a sulfated anion, a chloride anion, an ammonium anion, , At least one selected from the group consisting of a nitrate anion, a phosphate anion, a permanganate anion, an acetic acid ion, a hydrogen carbonate anion, a boric acid anion, a chromic acid anion, a bichromate anion, a halogen anion, a hydrochloric anion and an organic acid anion, These materials may be used alone or in combination of two or more and 0 to 50% by weight, or 0.1 to 50% by weight of a solid polymer (Conductive Polymer; Polythiophene, PEDOT-PSS, Polyaniline, Polypyrrole)

For increasing, impact reinforcing and goodness, dispersion, cold resistance, viscosity increase, shortening of drying (curing) time, prevention of clogging; 0.0001 ~ 20 ㎛ Zeolite, siliceous porous material, lightweight foam ceramic, Silica, Perlite, Titanium Dioxide, Clay, talc, Aluminum Hydroxide, Kaolin, Magnesium Hydroxide, Calcium Carbonate, Diatomite, Loess, Bentonite and Quartz snad Or more by weight; Ammonium Dodecylbenzenesulfonate, Sodium Dodecylbenzenesulfonate, Sodium Dodecylbenzenesulfonate, Sodium Alkylarylsulfonate, Phosphate Ester, Ammonium, Soda type oil and inorganic dispersant, Silicon dispersant, Acrylic dispersant, Ammonium dodecylbenzenesulfonate, Polyoxyethylenenonylphenyl ether, Polyoxyethyleneoctylphenyl ether, Sodium Dodecylsulfonate, Sodium Dodecylsulfosuccinate, Sodium Polycarboxyl Acid; 0 to 55% by weight of at least one of octylalcohol, cyclohexane, polydimethylsiloxane and other high-grade Alcohol or Ethylene Glycol, spandex nonion activator, and silicone anti-foaming agent; The present invention relates to a method for producing a water-in-oil emulsion, which comprises the steps of: (1) preparing a water-in-oil emulsion, Lactobacillus acidus, Lactobacillus, Lactobacillus, Lactobacillus, Lactobacillus, Lactobacillus, Lactobacillus, Lactobacillus, Lactobacillus, Lactobacillus, Lactobacillus, Lactobacillus, , Pectin, carbomer, high-cell, gelatin, polycarboxylic acid, carboxyvinyl polymer, metal ethylcellulose, potassium alginate, retextrose, sodium carboxymethylstarch, casein, starch; Dioctyl Phthalate, Dibutyl Phthalate, Ester, etc. are preferably used for the anti-adhesion property, and 0 to 10 wt% of Alkyl Ester are preferably mixed, or chlorinated 0 to 3% by weight, preferably 0 to 0.5% by weight, of organic nitrogen sulfides and strong acids (pH <4), respectively, in which 5 Chloro 2 methyl 4 isothiazolin 3 one and 2 Methyl 4 isotiazolin 3 1 not chlorine are mixed together 3-lodo-2 propynyl butyl carbamate (MX-3 Advanced Plus, manufactured by CONNELL FAMILY INC.), C ₁₁ H ₁₉ NOS (TK-800) and UNICOOL-K 14 Copper powder, Cobalt powder, Tin powder, Aluminum powder, Magnesium powder, Titanium powder, Silicon powder, Nickel powder, Zinc powder, Manganese powder . Soft ferrite such as silver powder, Ag coated Cu, Ni coated Cu, Indium tin oxide, Free lead tin-bismuth, Silver chloride, Antimony tin oxide, Stainless steel and Mn-Zn ferrite and hard ferrite such as Ba ferrite conductive carbon powder and fiber, 1.0 to 80.0% by weight of solid content of conductive carbon sol, or 0 to 97.5% by weight of a mixture of two or more kinds, or these metal materials are surface modified by using carboxylic acid, fatty acid or silane system, It is also characterized in that it can have a characteristic that it can be produced with a composition prepared by composing 0 to 90.0% by weight of a modified metal material and a product having a color by its additive material.

1-METHOXY-2-PROPANOL, BC, Diethylene Glycol Monoethyl Ether Acetate, Toluene, Alcohol, Ethanol, Butanol, Ethyllacetate, Hexane, Diethylehter, Acetonitrile, Benznene, Dibasic Ester, H ₂ O, etc., or 5 to 85% by weight of two or more kinds.

Although the order of mixing is not critical, it is preferable to mix and form the resin, solvent, dispersant and filler, initial adhesion-imparting agent, and composite performance material in this order.

In addition, a high-pressure disperser, a high-shear mixer (inline mixer, homomixer), a pre-mixer (stirrer), a homodisperse, a homogenizer, a (high speed) impeller, a paste mixer, (Mixing vessel) and a pulverizer manufacturing apparatus were used in a manufacturing method under the conditions of -15 to 100 ° C, 1 to 600 minutes, and 1 to 20,000 rpm, respectively.

Hereinafter, some of the functional material technologies and related problems which have been conventionally invented so as to have the electromagnetic wave shielding, antistatic, anti-bacterial anti-fogging, flame retardant (flame retardant), prevention of clogging, heat insulation, prevention of condensation phenomenon, , Supplementary and additional inventions shall be described in detail in the description of the technology and claims.

(1) Korean Patent Application No. 10-2000-0068297 discloses that layer separation occurs due to the use of a high-density radio wave absorber, and production of a high-density material as a commercial product is difficult,

(2) Korean Patent Registration No. 10-0591003 has a disadvantage in that long-term attachment properties are deteriorated due to the presence of an adhesive material,

(3) Korean Patent Nos. 10-0526673 and 10-0522267 do not disclose concrete description of the conductive carbon black and the adhesive used as the main material.

Therefore, the above-mentioned patent has a fundamental problem in that it does not take into consideration the ease of operation necessarily required in the method of producing the functional polymer material, the kind and effectiveness of the materials used, and the long-term reliability as a product. However, SUMMARY OF THE INVENTION The present invention has been made in order to overcome the problems of the prior arts and techniques, and the composition product manufactured or used by the present invention is excellent in electromagnetic wave shielding, antistatic and flame proofing, antimicrobial protection, The present invention provides a method and a device for solving the problems of the present invention by providing a property of a product having an efficacy for eliminating or reducing harmful elements of a human body due to the creation of a pleasant workplace and a residential environment, In the contents of technical description and claims I will cooperate.

In order to realize the above object, a composition and an application product using the composition are developed which exhibit a combination of electromagnetic shielding, antistatic and flame retardancy, antimicrobial resistance, prevention of dirt, prevention of dew condensation,

 The composition and the application using the composition of the present invention include a combination of electromagnetism shielding, electrification prevention, flame resistance, dew condensation prevention, antimicrobial protection, prevention of clogging, insulation, humidity control,

Adhesive materials that provide adhesion include: Acrylic, Epoxy, Polyvinyl Alcohol, Polyvinyl Acetate, Silicone, Polyurethane, Ethylenevinyl Acetate, Polyvinyl Chloride, Vinyl Acetate Acrylic Copolymer, Acrylic Copolymer. Gum Rosin, 2-Ethyl Hexyl Acrylate Monomer, 2-Ethylhexyl 2-Propenoate, 2-Hexyl. 2-EHAM, 2-Ethyl Hexyl Acryl Acid, Butyl Acrylate Monomer, N-Butyl Ester, Butyl 2-Propenoic Chloroprene Rubber, Acid, n-Butylacrylate and Resin of Vinyl Acetate Monomer, Solution or Acid, Primer, Emulsion, Monomer, Copolymer , Or a material made of grains such as Resorcinol, α-Olefin, Isocyanate, Phenolic, Thermosoftening Plastic, Thermosetting Plastic, Starch, Rice, Wheat, Wheat, Corn, Potato, Dextrin and Modified starch. % By weight,

Antistatic and flame retardant, antimicrobial anti-fouling, antifouling, anti-condensation, anti-foaming, and the like; Magnesium Chloride, Calcium Chloride, etc., belonging to a metal chloride of anhydrous or functional nH ₂ O (n = 0 to 99) having a solid content of 1 to 100 wt% 1 to 100% by weight in the form of a single or a mixture of two or more of these substances in the form of a powder or an aqueous solution thereof Salt is an industrial salt used as an edible Salt, a salt and a chemical used as a main component of sodium chloride, , Magnesium Chloride, Magnesium Sulfate, 6-9%, Potassium Chloride 2-4%, Sodium Chloride 2-6%, Magnesium Bromide 0.2-0.4 % Or the like, or 0 to 40% by weight of a concentrate obtained by heating 100 g thereof by 5 to 90% (particularly, in the present invention, The product has more antibacterial and antimicrobial effect by using tablets which do not have any bacteria in place of the sun-salt. Especially, it is treated at high temperature of 100 ℃ or higher, The reason for putting the acid in some products when manufacturing the product is not only the compatibility of the adhesive material but also the purpose of removing the self-retaining bacteria of the adhesive material.) (Salt is classified into sun salt and refined salt. It is an untreated salt made of coarse and translucent hexagonal crystals, which is formed by evaporating harmful substances with water and wind by the wind and sunlight. The purified salt is electrolyzed in seawater to remove impurities and heavy metals Is produced in the west coast or the south coast where the depth of the tide is not large and the difference between the tides is large, and it is also produced in the Indian Ocean, the Mediterranean coast, the United States, Australia, etc. In Jeollanamdo, Sinan- 65%, occupies more than half of the salt area, and has excellent quality worldwide In addition, the salt of sulfur produced in the vicinity of Baekryeong Island is also a commodity, and the salt of Korea is usually composed of reservoir, evaporation, and deciduous ground. In the high tide, Create and send the crystals to the crystal. If the wind is heavy and the crystal is small, and the temperature is low, the bitter taste or the quality of the salt will be lowered. It is better to pick the salt with a lot of sunshine and low wind. The salt produced in Korea is alkaline and the salinity is about 88%. It is mainly used for pickling of vegetables or fish because it contains minerals such as Ca, Mg, Zn, K, Fe and moisture and soaking in kimchi and soy sauce and miso. Although it contains a lot of good minerals, it contains some toxic substances, so it needs to be removed. When kimchi is dipped in sun salt, soy sauce and miso are made, the harmful ingredient disappears as it is fermented. In addition, it has high hygroscopicity due to various minerals, and has anti-clogging effect and insect repelling ability by sterilizing power beyond antimicrobial. Source: Doosan encyclopedia, Song Il Tongjeon, Shinan. The calcium chloride and sodium chloride of the above chlorides are treated with an acid to lower their corrosivity by a low corrosive or low salt system and the substances alone or two or more than 0 To 40% by weight, or a solid content of 5 to 80% by weight. As the ionic compound - In the ionic compound used in the present invention, the metal cation and the nonmetal anion are bonded by the electrostatic attraction, and the sum of the charges is electrically neutral. - +2 is at least one cation metal element selected from the group consisting of Co, Cu, Ni, Mn, Zn, Fe, Al, Be, Mg, Ca, and Ba, and the anion element is a fluoride anion, An anion, an iodide anion, a sulfide anion, a chloride anion, an ammonium anion, a hydroxide anion, a sulfate anion, a carbonate anion, a nitrate anion, a phosphate anion, a permanganate anion, Oxyhydrogen anion, there may be mentioned boric acid anions, chromic acid anion, and one or more selected from the group consisting of dichromate anion, a halogen anion, an anion of hydrochloric acid, an organic acid anion and the like. In consideration of corrosion of equipment and solution stability, ammonium salt may be further added. In the form of a hydrate, in the form of an aqueous solution, these substances alone or two or more and 2 to 50 wt% or 5 to 80 wt% And the cation metal element belonging to the cationic metal element is one or more selected from the group consisting of Li, Na, K, and the like. The anionic element may be a fluorinated anion, a brominated Anions such as anions, iodides, sulphide anions, chloride anions, ammonium anions, hydroxide anions, sulfate anions, carbonate anions, nitrate anions, phosphate anions, permanganate anions, acetic acid anions, hydrogen carbonate anions, chromate anions, bichromate anions, halide anions , Hydrochloric acid anion, organic acid anion and the like, and the hydrate form, Use of these materials alone or two or more 0-50% by weight in solution form or solid content 0.1 to 50% by weight of the conductive polymer; using (Conductive Polymer Polythiophene, PEDOT-PSS, Polyaniline, Polypyrrole) 0-50% by weight,

For increasing, impact reinforcing and goodness, dispersion, cold resistance, viscosity increase, shortening of drying (curing) time, prevention of clogging; 0.0001~20㎛ with an alkali metal or an alkaline earth metal functions containing aluminum silicate (Si, Al) O porous structure in which tetrahedrons are bonded to the three-dimensional mesh of ₄ and WmZ _{2n2 n} O O formula, W is Na, Ca, Ba, and Sr, Z = Si + Al, quartz SiO ₂ , and diamond-like tetrahedral structures. In the three-dimensional network structure, a portion of Si is replaced by Al. Zeolite is a porous material capable of adsorbing a large amount of water, a siliceous porous material, lightweight foam ceramic, silica, perlite, titanium dioxide, clay, talc, aluminum hydroxide, kaolin, magnesium hydroxide , Calcium Carbonate, Diatomite, Loess, Bentonite, Quartz snad or the like may be used alone or in an amount of 0 to 50% by weight; Ammonium Dodecylbenzenesulfonate, Sodium Dodecylbenzenesulfonate, Sodium Dodecylbenzenesulfonate, Sodium Alkylarylsulfonate, Phosphate Ester, Ammonium, Soda type oil and inorganic dispersant, Silicon dispersant, Acrylic dispersant, Ammonium dodecylbenzenesulfonate, Polyoxyethylenenonylphenyl ether, Polyoxyethyleneoctylphenyl ether, Sodium Dodecylsulfonate, Sodium Dodecylsulfosuccinate, Sodium Polycarboxyl Acid; 0 to 55% by weight of at least one of octylalcohol, cyclohexane, polydimethylsiloxane and other high-grade Alcohol or Ethylene Glycol, spandex nonion activator, and silicone anti-foaming agent; The present invention relates to a method for producing a water-in-oil emulsion, which comprises the steps of: (1) preparing a water-in-oil emulsion, Lactobacillus acidus, Lactobacillus, Lactobacillus, Lactobacillus, Lactobacillus, Lactobacillus, Lactobacillus, Lactobacillus, Lactobacillus, Lactobacillus, Lactobacillus, Lactobacillus, , Pectin, carbomer, high-cell, gelatin, polycarboxylic acid, carboxyvinyl polymer, metal ethylcellulose, potassium alginate, retextrose, sodium carboxymethylstarch, casein, starch; Dioctyl Phthalate, Dibutyl Phthalate, Ester, etc. are preferably used for the anti-adhesion property, and 0 to 10 wt% of Alkyl Ester are preferably mixed, or chlorinated 0 to 3% by weight, preferably 0 to 0.5% by weight, of organic nitrogen sulfides and strong acids (pH <4), respectively, in which 5 Chloro 2 methyl 4 isothiazolin 3 one and 2 Methyl 4 isotiazolin 3 1 not chlorine are mixed together 3-lodo-2 propynyl butyl carbamate (MX-3 Advanced Plus, manufactured by CONNELL FAMILY INC.), C ₁₁ H ₁₉ NOS (TK-800) and UNICOOL-K 14 Copper powder, Cobalt powder, Tin powder, Aluminum powder, Magnesium powder, Titanium powder, Silicon powder, Nickel powder, Zinc powder, Manganese powder . Silver powder, Ag coated Cu, Ni coated Cu, Indium tin oxide, Free lead tin-bismuth, Silver chloride, Antimony tin oxide, Stainless steel, Mn (or Mg, And hard ferrite such as Ba (or Sr, etc.) ferrite, conductive carbon powder and fiber, 1.0 to 80.0 wt% of conductive solid, or 0 to 97.5 wt% of conductive carbon sol alone or a mixture of two or more of them. modified with a carboxylic acid, a fatty acid and a silane system, and can be produced by a composition prepared from 0 to 90.0% by weight of a surface-modified metal material and a product having a color by the additive material It is also characterized.

The solvent may also be a solvent; Content of 1 to 99.9 wt% Methanol, Ethanol, Butanol, Dichloromethane , Ethylacetate, Hexane, Diethylehter, Acetonitrile, Benznene, Dibasic Ester, 1-METHOXY-2-PROPANOL, BC, Diethylene Glycol Monoethyl Ether Acetate, Toluene, Alcohol, H 2 O and the like, or 5 to 85% by weight of two or more kinds.

Although the order of mixing is not critical, it is preferable to mix and form the resin, solvent, dispersant and filler, initial adhesion-imparting agent, and composite performance material in this order.

In addition, a high-pressure disperser, a high-shear mixer (inline mixer, homomixer), a pre-mixer (stirrer), a homodisperse, a homogenizer, a (high speed) impeller, a paste mixer, (Mixing container), a potting machine, and the like, in the production process under the conditions of -15 to 100 ° C, 1 to 600 minutes, and 1 to 20,000 rpm. Manufacture is possible; In addition to the conventional and current manufacturing methods in which the operator prepares and packages the composition after the composition is prepared through the mixing valve discharge valve, the manufacturing method can be used to feed the raw materials and transport the pellets using advanced equipment, It is also possible to manufacture by the method. Equipment which is designed and manufactured by the present inventor will be brought to future applications or know-how.

In the present invention, the substances and the kinds of components for electromagnetic wave shielding, antistatic and flame resistance, antimicrobial resistance, prevention of condensation, prevention of condensation, and prevention of fogging are described, and the function and effect thereof are described in the detailed description and claims.

As described above, the composition which selectively exhibits electromagnetic wave shielding, electrification preventing and flame proofing, antimicrobial anti-fouling, anti-condensation, anti-condensation, anti-foaming, heat insulating and humidity control, and applications using the same, It suppresses electromagnetic wave suppressed by product, antistatic property easily removes fine dust attached to product surface, removes static electricity, suppresses ignition when fire occurs, suppresses various microorganisms, suppresses dew condensation, reduces temperature difference inside and outside, It has the effect of preventing the damage of the adhesion due to the weather phenomenon, preventing clogging, and preventing worms, thus contributing to improvement of a pleasant environment and life.

Fig. 1 is a photograph of a surface resistance measurement and a sample and a measuring instrument used.
FIG. 2 is a photograph of the surface and ground resistance measurement after the conductive tile is applied to the composition A of the clean room according to the present invention, and the results and mechanism thereof.
FIG. 3 is a photograph and measurement result of the surface resistance and half-life test report obtained from the researcher B with the composition of the present invention.
FIG. 4 is a photograph and measurement result of a surface resistivity test report obtained from a researcher of the present invention with a sample prepared from the composition of the present invention.
FIG. 5 shows electric field measurement results using E-tester equipment before and after internal processing (construction) of the composition of the present invention.
Fig. 6 shows the result of electric field measurement (capturing a moving picture by HI-3604) before application with the composition of the present invention.
FIG. 7 is a graph showing changes in the on-state of the lamp in the frequency counter before application with the composition of the present invention. Light off state Shoots the difference in electric field occurrence (captures a movie as a picture).
FIG. 8 shows the result of electric field measurement (capturing a moving picture by HI-3604) after application with the composition of the present invention.
FIG. 9 is a graph showing the on-state vs. light-on-state of a frequency counter after application with the composition of the present invention. Light off state Shoots the difference in electric field occurrence (captures a movie as a picture).
10 shows the result of electric field measurement using GIGA SOLUTIONS measuring device before and after the application of the apartment wall which is one of the composition of the present invention, using the laminated wallpaper as the flooring.
11 is a photograph of a nonwoven fabric made of an adhesive product which is one of the compositions of the present invention.
12 is a photograph of a site where an apartment is constructed with the composition product of the present invention.
FIG. 13 is a photograph of a fungal strain for an acrylic primer and an acrylic primer according to the present invention.
FIG. 14 is a photograph of a photograph of a fungal strain experiment for a general acrylic emulsion and acrylic emulsion according to the present invention (video). FIG.
Fig. 15 is a result of the fungus test for the composition according to the present invention for the bread.
16 is a photograph of the mold wall of the apartment.
Figure 17 is a photograph of a wall of power house wall mold.
18 shows a sample shot after flame test on a PS foam (polystyrene foam).
Figure 19 is a representative schematic view of a foam made by the present invention.
20 is a schematic view of a foam having a plurality of flame retardant layers produced by the present invention.
21 is a schematic view of a foam having an antistatic flame retardant layer produced by the present invention.
22 is a schematic view of a wallpaper type having a double-sided flame retardant layer without a foam according to the present invention.
23 is a schematic view of a wallpaper type having a one side flameless layer according to the present invention.
Fig. 24 is a photograph showing a condensation phenomenon. Fig.
Fig. 25 is a photograph showing the prevention of condensation phenomenon. Fig.
Fig. 26 shows the flame retardancy comparison test result with the flame retardant specimens and the specimens of the present invention.
Fig. 27 shows the results of gas toxicity test for the specimen of the present invention. Fig.
Fig. 28 is a photograph taken after a flame test of a laminated wallpaper and a general wallpaper produced by the present invention; Fig.
29 shows changes in freezing point according to the weight ratio of ethylene glycol.
30 is a view for explaining the phenomenon of freezing point lowering;
31 is an experiment of antifaturation of the composition according to the present invention.
Fig. 32 is a photograph taken after bonding wood flooring with the composition of the present invention. Fig.
Fig. 33 is a photograph of the fungus infused with the fungus of the present invention and the commercially available fungus (S company). Fig.
FIG. 34 is a photograph of the composition of the present invention taken after a flame test for a general wallpaper and silk wallpaper coated on both sides or one side, and not coated.
Fig. 35 is a photograph of the composition of the present invention taken after a flame test on a two-sided or one-sided coating of ordinary wallpaper and silk wallpaper,
Fig. 36 Adhesion test after thoroughly freezing and thawing two kinds of roots and general roots of the composition of the present invention.
Fig. 37 is a photograph of the state of the external shape frozen and thawed after the composition of the present invention was applied to a general water-based paint and adhesive;
FIG. 38 is a photograph of the external appearance of the present invention in which the gravy pool and the general gravy pool are completely frozen and thawed.
Fig. 39 is a graph showing the results of the corrosion test of the surface of the screw after immersing the screw in the gauze pool and the general gauze of the present invention for a long time.

The present invention relates to a composition product prepared by adding, to a bonding material and a coating material, an electromagnetic wave shielding material, an antistatic material, a flame proofing material, an antimicrobial anti-fouling material, And a variety of functions such as static elimination, flame retarding, fine dust cleaning especially for charging dust, antimicrobial anti-fogging function, prevention of clogging, prevention of adiabatic and condensation due to porosity, humidity control and prevention of water- The present invention relates to a composition product, a method of constructing the product, and an application product.

In order to achieve the above object, a composition and a product using the same are developed in which a combination of flame retardance and antistatic, antimicrobial anti-fog, anti-clogging, heat insulation, anti-condensation, humidity control and anti- First, in the present invention, the components and effects for a material exhibiting flame retardancy and antistatic, antimicrobial anti-fogging, anti-clogging, heat insulation, anti-condensation, humidity control and anti-fogging properties are as follows.

 First, a composition that exhibits a combination of electromagnetic shielding, antistatic and flame retardancy, antimicrobial resistance, prevention of condensation, prevention of condensation,

Adhesive materials that provide adhesion include: Acrylic, Epoxy, Polyvinyl Alcohol, Polyvinyl Acetate, Silicone, Polyurethane, Ethylenevinyl Acetate, Polyvinyl Chloride, Vinyl Acetate Acrylic Copolymer, Acrylic Copolymer. Gum Rosin, 2-Ethyl Hexyl Acrylate Monomer, 2-Ethylhexyl 2-Propenoate, 2-Hexyl. 2-EHAM, 2-Ethyl Hexyl Acryl Acid, Butyl Acrylate Monomer, N-Butyl Ester, Butyl 2-Propenoic Chloroprene Rubber, Acid, n-Butylacrylate and Resin of Vinyl Acetate Monomer, Solution or Acid, Primer, Emulsion, Monomer, Copolymer , Or a material made of grains such as Resorcinol, α-Olefin, Isocyanate, Phenolic, Thermosoftening Plastic, Thermosetting Plastic, Starch, Rice, Wheat, Wheat, Corn, Potato, Dextrin and Modified starch. % By weight,

Antistatic and flame retardant, antimicrobial anti-fouling, antifouling, anti-condensation, anti-foaming, and the like; Magnesium Chloride, Calcium Chloride, etc., belonging to a metal chloride of anhydrous or functional nH ₂ O (n = 0 to 99) having a solid content of 1 to 100 wt% 1 to 100% by weight in the form of a single or a mixture of two or more of these substances in the form of a powder or an aqueous solution thereof Salt is an industrial salt used as an edible Salt, a salt and a chemical used as a main component of sodium chloride, , Magnesium Chloride, Magnesium Sulfate, 6-9%, Potassium Chloride 2-4%, Sodium Chloride 2-6%, Magnesium Bromide 0.2-0.4 % Or the like, or 0 to 40% by weight of a concentrate obtained by heating 100 g thereof by 5 to 90% (particularly, in the present invention, The product has more antibacterial and antimicrobial effect by using tablets which do not have any bacteria in place of the sun-salt. Especially, it is treated at high temperature of 100 ℃ or higher, The reason for putting the acid in some products when manufacturing the product is not only the compatibility of the adhesive material but also the purpose of removing the self-retaining bacteria of the adhesive material.) (Salt is classified into sun salt and refined salt. It is an untreated salt made of coarse and translucent hexagonal crystals, which is formed by evaporating harmful substances with water and wind by the wind and sunlight. The purified salt is electrolyzed in seawater to remove impurities and heavy metals Is produced in the west coast or the south coast where the depth of the tide is not large and the difference between the tides is large, and it is also produced in the Indian Ocean, the Mediterranean coast, the United States, Australia, etc. In Jeollanamdo, Sinan- 65%, occupies more than half of the salt area, and has excellent quality worldwide In addition, the salt of sulfur produced in the vicinity of Baekryeong Island is also a commodity, and the salt of Korea is usually composed of reservoir, evaporation, and deciduous ground. In the high tide, Create and send the crystals to the crystal. If the wind is heavy and the crystal is small, and the temperature is low, the bitter taste or the quality of the salt will be lowered. It is better to pick the salt with a lot of sunshine and low wind. The salt produced in Korea is alkaline and the salinity is about 88%. It is mainly used for pickling of vegetables or fish because it contains minerals such as Ca, Mg, Zn, K, Fe and moisture and soaking in kimchi and soy sauce and miso. Although it contains a lot of good minerals, it contains some toxic substances, so it needs to be removed. When kimchi is dipped in sun salt, soy sauce and miso are made, the harmful ingredient disappears as it is fermented. In addition, it has high hygroscopicity due to various minerals, and has anti-clogging effect and insect repelling ability by sterilizing power beyond antimicrobial. Source: Doosan encyclopedia, Song Il Tongjeon, Shinan. The calcium chloride and sodium chloride of the above chlorides are treated with an acid to lower their corrosivity by a low corrosive or low salt system and the substances alone or two or more than 0 To 40% by weight, or a solid content of 5 to 80% by weight. As the ionic compound - In the ionic compound used in the present invention, the metal cation and the nonmetal anion are bonded by the electrostatic attraction, and the sum of the charges is electrically neutral. - +2 is at least one cation metal element selected from the group consisting of Co, Cu, Ni, Mn, Zn, Fe, Al, Be, Mg, Ca, and Ba, and the anion element is a fluoride anion, An anion, an iodide anion, a sulfide anion, a chloride anion, an ammonium anion, a hydroxide anion, a sulfate anion, a carbonate anion, a nitrate anion, a phosphate anion, a permanganate anion, Oxyhydrogen anion, there may be mentioned boric acid anions, chromic acid anion, and one or more selected from the group consisting of dichromate anion, a halogen anion, an anion of hydrochloric acid, an organic acid anion and the like. In consideration of corrosion of equipment and solution stability, ammonium salt may be further added. In the form of a hydrate, in the form of an aqueous solution, these substances alone or two or more and 2 to 50 wt% or 5 to 80 wt% And the cation metal element belonging to the cationic metal element is one or more selected from the group consisting of Li, Na, K, and the like. The anionic element may be a fluorinated anion, a brominated Anions such as anions, iodides, sulphide anions, chloride anions, ammonium anions, hydroxide anions, sulfate anions, carbonate anions, nitrate anions, phosphate anions, permanganate anions, acetic acid anions, hydrogen carbonate anions, chromate anions, bichromate anions, halide anions , Hydrochloric acid anion, organic acid anion and the like, and the hydrate form, Use of these materials alone or two or more 0-50% by weight in solution form or solid content 0.1 to 50% by weight of the conductive polymer; using (Conductive Polymer Polythiophene, PEDOT-PSS, Polyaniline, Polypyrrole) 0-50% by weight,

For increasing, impact strengthening and goodness, dispersion, cold resistance, viscosity increase, shortening of drying (curing) time, prevention of clogging, insulation; 0.0001 ~ 20㎛ with an alkali metal or an alkaline earth metal functions containing aluminum silicate (Si, Al) O porous structure in which tetrahedrons are bonded to the three-dimensional mesh of ₄ and WmZ _{2n2 n} O O formula, W is Na, Ca, Ba, and Sr, Z = Si + Al, quartz SiO ₂ , and diamond-like tetrahedral structures. In the three-dimensional network structure, a portion of Si is replaced by Al. Zeolite is a porous material capable of adsorbing a large amount of water, a siliceous porous material, lightweight foam ceramic, silica, perlite, titanium dioxide, clay, talc, aluminum hydroxide, kaolin, magnesium hydroxide , Calcium Carbonate, Diatomite, Loess, Bentonite, Quartz snad or the like may be used alone or in an amount of 0 to 50% by weight; Ammonium Dodecylbenzenesulfonate, Sodium Dodecylbenzenesulfonate, Sodium Dodecylbenzenesulfonate, Sodium Alkylarylsulfonate, Phosphate Ester, Ammonium, Soda type oil and inorganic dispersant, Silicon dispersant, Acrylic dispersant, Ammonium dodecylbenzenesulfonate, Polyoxyethylenenonylphenyl ether, Polyoxyethyleneoctylphenyl ether, Sodium Dodecylsulfonate, Sodium Dodecylsulfosuccinate, Sodium Polycarboxyl Acid; 0 to 55% by weight of at least one of octylalcohol, cyclohexane, polydimethylsiloxane and other high-grade Alcohol or Ethylene Glycol, spandex nonion activator, and silicone anti-foaming agent; The present invention relates to a method for producing a water-in-oil emulsion, which comprises the steps of: (1) preparing a water-in-oil emulsion, Lactobacillus acidus, Lactobacillus, Lactobacillus, Lactobacillus, Lactobacillus, Lactobacillus, Lactobacillus, Lactobacillus, Lactobacillus, Lactobacillus, Lactobacillus, Lactobacillus, , Pectin, carbomer, high-cell, gelatin, polycarboxylic acid, carboxyvinyl polymer, metal ethylcellulose, potassium alginate, retextrose, sodium carboxymethylstarch, casein, starch; Dioctyl Phthalate, Dibutyl Phthalate, Ester, etc. are preferably used for the anti-adhesion property, and 0 to 10 wt% of Alkyl Ester are preferably mixed, or chlorinated 0 to 3% by weight, preferably 0 to 0.5% by weight, of organic nitrogen sulfides and strong acids (pH <4), respectively, in which 5 Chloro 2 methyl 4 isothiazolin 3 one and 2 Methyl 4 isotiazolin 3 1 not chlorine are mixed together 3-lodo-2 propynyl butyl carbamate (MX-3 Advanced Plus, manufactured by CONNELL FAMILY INC.), C ₁₁ H ₁₉ NOS (TK-800) and UNICOOL-K 14 Copper powder, Cobalt powder, Tin powder, Aluminum powder, Magnesium powder, Titanium powder, Silicon powder, Nickel powder, Zinc powder, Manganese powder . Silver powder, Ag coated Cu, Ni coated Cu, Indium tin oxide, Free lead tin-bismuth, Silver chloride, Antimony tin oxide, Stainless steel, Mn (or Mg, And hard ferrite such as Ba (or Sr, etc.) ferrite, conductive carbon powder and fiber, 1.0 to 80.0 wt% of conductive solid, or 0 to 97.5 wt% of conductive carbon sol alone or a mixture of two or more of them. modified with a carboxylic acid, a fatty acid and a silane system, and can be produced by a composition prepared from 0 to 90.0% by weight of a surface-modified metal material and a product having a color by the additive material It is also characterized.

The solvent may also be a solvent; Content of 1 to 99.9 wt% Methanol, Ethanol, Butanol, Dichloromethane , Ethylacetate, Hexane, Diethylehter, Acetonitrile, Benznene, Dibasic Ester, 1-METHOXY-2-PROPANOL, BC, Diethylene Glycol Monoethyl Ether Acetate, Toluene, Alcohol, H 2 O and the like, or 5 to 85% by weight of two or more kinds.

Although the order of mixing is not critical, it is preferable to mix and form the resin, solvent, dispersant and filler, initial adhesion-imparting agent, and composite performance material in this order.

In addition, a high-pressure disperser, a high-shear mixer (inline mixer, homomixer), a pre-mixer (stirrer), a homodisperse, a homogenizer, a (high speed) impeller, a paste mixer, (Mixing container), a potting machine, and the like, in the production process under the conditions of -15 to 100 ° C, 1 to 600 minutes, and 1 to 20,000 rpm. Manufacture is possible; In addition to the conventional and current manufacturing methods mentioned above, the above manufacturing method is also a technique that can be manufactured by using a high-tech equipment and manufacturing method in which raw material input and packaging transfer can be performed in an inline outline. Equipment which is designed and manufactured by the present inventor will be brought to future applications or know-how.

 Hereinafter, the composition, evaluation, structural schematic, and performance of the present invention will be described in more detail and in detail based on practical examples.

Acrylic, Epoxy, Polyvinyl Alcohol, Polyvinyl Acetate, Silicone, Polyurethane, Ethylenevinyl Acetate, Polyvinyl Chloride Acetate or Vinyl acrylic copolymer or Primer, Emulsion, Monomer, resin, 1 to 15-25% by weight of two or more of each of the sealant mixture, H ₂ O 65~75% by weight, 0thers 1~10% by weight of the composition to about 2-EHAM: BAM = 2~3: 30~99% by weight ratio of 1, CaCO ₃ 10~50% by weight, H ₂ O 10~60% by weight , others, 0.01 to 5 wt%, or a mixture of acrylic copolymer 45 to 55 wt%, CaCO ₃ 30 to 40 wt%, H ₂ O 10 to 20 wt%, Gum Rosin 5 to 10 wt%, 0thers 1 to 10 wt% Or 1 to 90% by weight of at least two kinds of acrylic sealant or silicone sealant, or 0 to 40% by weight of at least two kinds thereof; - Others are substances corresponding to the abovementioned amounts of increase, impact reinforcement, and goodness, dispersion, cold resistance, viscosity increase, dispersing agent and the like - 0 to 20 wt% of CaCl2 powder, 0 to 5 wt% of salt, Carbon) powder and fiber 0 to 5 wt%, solids 1.0 to 80.0 wt% Conductive carbon sol 0 to 10 wt% Solvents exhibiting electromagnetic wave shielding and antistatic properties, which are the main purpose functions, were manufactured by the following evaluations As a result, excellent electrical properties and adhesive properties were exhibited, and workability and other properties were exhibited. The test result was 1.05 × 10 ^{4 to} 1.23 × 10 ⁴ Ω / □ as measured by a Resistance Meter (manufacturer Trek) Model 152 at 23 ° C. and 50% RH, respectively (see FIG. 1) . Fig. 2 shows the result of measuring the surface resistance after the conductive tile was applied to the present invention. As a result of measuring the surface resistance after the field application, it was confirmed that the characteristics of the tile according to the present invention can be exhibited at 45% RH to 10 ⁵ Ω / □. 2 is a view showing the center of FIG. 2 in which the adhesive for conductive tiles of the present invention is grounded and the resistance is measured in order to confirm the conductivity of the adhesive of the present invention when the A clean room is installed, 2 As shown in the lower part, when the PVC conductive tile is adhered with good electrical property because it is used for floor construction (clean room) for static electricity reduction (clean room), static electricity generated from human body, Conductive adhesive of the onset, and an antistatic floor (clean room) that exits through the grounding terminal and exhibits antistatic characteristics.

And the surface resistivity meter was used to was checked for resistance to Wolfgang Warmbier of Surface Resistance Meter SRM ^ⓡ 110 / EURO Made in such assessment. The adhesion strength of the composition adhesive, which is an important characteristic, was evaluated at 23 ° C room temperature and 10 ° C room temperature for 2 hours, 4 hours, 24 hours and 168 hours after bonding, , And 45% RH. The open time before bonding was 20 minutes, and the results are shown in Table 1.

Item Composition 1 Composition 2 Composition 3 25 ℃ 10 ℃ 25 ℃ 10 ℃ 25 ℃ 10 ℃ 90 ° peel adhesion strength (Kg _f / 25 mm) After 2 hours 1.2 0.9 2.1 1.6 2.9 2.5 After 4 hours 2.6 2.0 3.4 3.0 4.4 4.1 After 24 hours 7.6 5.8 7.9 7.1 77 7.4 168 hours later 9.7 7.8 10.7 9.9 11.9 12.8

As can be seen from Table 1, the adhesive according to the present invention shows good adhesiveness.

[Adhesive Strength Test Method]

(1) Room temperature (23 ° C) Bond strength

① Adhesive was applied to flat cement, plywood, and plastic plate with hera.

② Leave the open time for 10 to 60 minutes, then press the tile specimen on the flat plate, especially the plastic plate.

③ After 2 hours, 4 hours, 24 hours, and 168 hours of drying at room temperature, the specimen was peeled off at 90 °.

(2) Low adhesion strength

(1) The adhesive was applied to the flat plate in a constant temperature oven at 10 ° C.

② Leave the open time for 10 to 60 minutes, then press the tile specimen on the flat plate, especially the plastic plate.

③ After 2 hours, 4 hours, 24 hours, and 168 hours elapsed in a 10 ° C thermostat, 90 ° peeling was measured.

The mixing ratio of the starch, which is one of the mixing ratios of the present invention, the solid content 40 to 60 wt%, the CaCl ₂ 1 to 15 wt%, the solid content 1 to 35 wt%, the salt 1 to 20 wt%, and the water 30 to 95 wt% The composition was heated and stirred to prepare an adhesive material having a viscosity of 100,000 cps (for Brookfield RV DV-II + PRO). Further, 1 to 0.3 of the composition 1 standard was further mixed, RH to 10 ^{5 to 8} Ω / □. The surface resistance meter used here was evaluated by Wolfgang Warmbier's Surface Resistance Meter SRM ^ⓡ 110 / Made in EURO. As shown in FIG. 3, the test conditions were 500 V, 60 seconds, 20 ° C and 65% RH, and the test equipment was a TOA SME-8511, D ₁ = 1.96 cm and D ₂ = 2.41 cm A resistance value of 5.1 × 10 ⁷ Ω / □ (half-life of 1.5 sec) and 4.3 × 10 ⁸ Ω / □ (half-life of 2.1 sec) was obtained. The carbon black composition was prepared by mixing 3 wt% of carbon black in the mixed composition. The result of the measurement was 2.5 × 10 ⁶ Ω / □, which is shown in FIG.

FIG. 5 shows the result of measuring the degree of electric field reduction after the construction (spreading) of each of the four boxes by using the general flooring pool and the flooring of the present invention. As shown in FIG. 5, it was confirmed that the measurement value of PULSE E-tester was 575 V / m before the construction and 0 V / m after the construction. This means that the charge in the conductor does not move, and the electric field inside the conductor is zero. The absence of an electric field in a conductor is not because the electric field can not penetrate the metal, but because the free electrons in the conductor can only stop and 'stop' when the internal electric field is zero. Because the charged metal balls act on each other, the electrons are separated from each other as far as possible, and the electrons are uniformly distributed on the spherical surface. If you put both charges right in the middle, you will not get any power. The electrons in the left part of the sphere pull the charge to the left, but the electrons in the right part of the sphere pull the charge to the right with equal force. The force on the charge is zero. Therefore, the electric field also becomes zero. If the conductor is not spherical, the charge distribution is not uniform, but - if it is a cuboid - most of the charge is on the edge. It is the same principle that charge and force are concentrated in sharp point, but the electron distribution of plane and corner is made so that the electric field is zero everywhere in the cube. If there is an electric field inside the conductor, the free electrons inside the conductor will begin to move. Until equilibrium, the position of all electrons moves until the electric field inside the conductor becomes zero. This is like putting electronic components into a shielding bag such as an aluminum bag to block or shield electrical shocks (triboelectric). Thus, regardless of shape, the interior of the metal is an electric field of zero. In the initial state, assuming that there is a charge and an electric field in the conductor, the presence of an electric field means that there is charge movement. Charges in the conductors begin to move under the influence of the electric field and movements of the charges move in a direction that causes the internal electric field to become zero until they become zero, that is, until the charges no longer move . If the electric field in the conductor is not zero, the charges move and move until the electric field is zero. This movement causes the charges to gather all over the surface of the conductor, and they are in a state of being forced outward, which can no longer move. This is the metal spherical theory (the inventor's first / first-mentioned theory) and is always why the electric field on the conductor surface is perpendicular to the surface. The inside moves continuously so as to become a (-) ion environment.

Figs. 6, 7, 8 and 9 show that HI-3604 is placed at a distance of 1.0 m from the floor, and HI-3604 is installed at a height of 2.3 m, -3604 is connected to the frequency counter (FC-1022), and the captured images are shown after the video recording. It was observed that the electric field was considerably generated even when the electric field was observed at 90 ~ 100V / m and off state. However, the electric field was observed at 5 ~ 6V / m after the measurement. And turned on.

The actual living apartment was manufactured in a pool manufacturing factory by using the composition of the present invention, and the interior of the apartment was sown. As shown in FIG. 10, the degree of occurrence of the before / after electric fields in the apartments 1, 2, 3, the living room, and the kitchen was measured. As shown in FIG. 10, / m. Region 2 has an electric field of 99V / m after electric field of 160 / m before electric power generation and electric field of 73V / m after electric field of 258V / m before electric power of region 3 and electric field of 69V / The electromagnetic field environment was improved at 48 V / m after the irradiation, and the attenuation ratio was decreased in the region where the attenuation ratio was mainly absorbed from the ceiling. However, the area where the lamp was located near the wall was absorbed from the ceiling and wall As a result, it was found that the environment of electromagnetic wave attenuation was improved more and more, and the measuring instrument was measured using GIGA SOLUTIONS / Made in Germany.

FIG. 11 is a cross-sectional view of a conductive paste prepared by gravure printing of a conductive carbon black at the same ratios as in Examples 1 and 2 to a PVA as a glue, followed by roll-80 printing on the paste. And FIG. 12 shows a photograph of a scene in which an apartment is actually installed with a product in which a conductive carbon black is formed as an acrylic emulsion as a main adhesive. As described above, the composition of the present invention is a real example showing diversity of application fields by characterizing that various application products can be practically used.

The antimicrobial test was carried out in accordance with JIS Z 2801-2010, standard film sterilized PP film, Escherichia coli ATCC 8739 in 0.1 mL of the inoculum, , The antimicrobial activity value was 2.7, and the antimicrobial activity value of Staphyococcus aureus ATCC 6538P was 2.2, indicating that the antimicrobial activity was excellent. As a result of the comparison with the acrylic primer (acrylic emulsion) adhesive agent in which the composition material of the present invention was not added and the adhesive agent in which 3.5% of the composition material of the present invention was added, As shown in Fig. Experiments were carried out after one week incubation in a constant temperature and humidity chamber (experimental apparatus). That is, acrylic primer (acrylic emulsion) based adhesive used in construction and the acrylic adhesive produced by the present invention, and then capturing the result after the simultaneous photographing. It has been found that a large amount of mold is generated in the acrylic adhesive system which is currently used for waterproofing or adhesion, but the product of the present invention has a mold prevention property. Fig. 15 is a result of an experiment for evaluating the superiority of the present invention with a bread with good mold generation. Experimental evaluation was carried out in a state in which the moisture was always kept in the bread for 4 days. The bread portion which was not in contact with the surface produced by the above composition produced more mold than the bread portion which was contacted with the present invention. In the composition substance of the present invention, 3.5% of the edible salt was contained, And it was found that the anti - tanning effect was better. FIG. 16 is a photograph of the occurrence of mold on the wall of the apartment, and FIG. 17 is a photograph of the occurrence of mold on the wall of the power house.

18 shows the results of capturing the images of the composition products of the present invention in Examples 1, 2, and 3 (left side) that were not coated with the PS foam on the surface of the PS foam (left side) Respectively. When the sample before and after the coating on the PS foam was ignited, the result was that the right side was completely melted and the PS foam in the area where the spark was present melted away, but the sample coated on the surface did not completely melt and the opposite side remained (Flame retardancy) characteristics of the present invention.

The basic structure of the present invention is such that a flame retardant layer 20 made of the composition of Examples 1 and 2 is formed between a substrate layer (or a printing layer, an embossing layer) 10 and a plastic foam 30, 30, an aluminum foil layer 40 is formed at the lower end, and an adhesive layer 50 and a release paper 60 are formed on the lower surface thereof. The flame retardant layer 20 suppresses or delays ignition upon a fire. The structure is shown in FIG. 19 and not shown in the drawing. However, in the case of a product to be installed in another environment, a nonwoven fabric such as a base material layer 10 / a flame retardant layer 20 / a plastic foam 30 / The aluminum foil layer (30) is formed by the structure of the aluminum foil (30 aluminum layer (40) / adhesive layer (50) / release paper (60) 40) and the adhesive layer (50) to the release paper (60) to the above-mentioned adhesive (coating) material not containing the composition of the present invention.

20 shows a case where both sides of the plastic foam 30 are produced by forming the flame retarded layer 20 and the plastic foam 30 is formed on both sides of the plastic foam 30, In the case of a product to be constructed, when both sides of the plastic foam 30 are subjected to flame treatment, the flame-retardant effect is further enhanced. Although illustrated schematically in the present invention, those skilled in the art can further construct or fabricate multiple layers or multiple layers. For example, when a wallpaper or the like is applied on the plastic foam 30, the base material layer 10 may be formed as shown in Fig. Here, the coating layer can be made of the adhesive (coating) material described in Example 6, except that the upper release paper portion is produced. As shown in Figs. 22 and 23, non-foamed actual wallpaper and paper wallpaper also have electromagnetic wave shielding, antistatic, flame-retarding, and antibacterial properties when they are manufactured in the above-described configuration.

In the case of the flame retardant layer, it is also possible to remove the dust sticking by the antistatic function or to be able to shield the electric field. Electromagnetic shielding, antistatic, flame retardant, antimicrobial protection. The surface resistivity of the composition material having the function of preventing the abrasion and preventing the humidity (humidity control) is 10 ⁵ ~ ^{10 10} Ω / □ depending on the content, and the surface resistance is 10 ⁴ ~ 10 ⁹ Ω / □ when the conductive polymer PEDOT is added , Guard water and salt are 10 ⁵ ~ 10 ⁹ Ω / □, and also show electromagnetic wave shielding performance.

The dew condensation of the general paint is shown in FIG. 24, but the present invention does not show dew condensation on the surface due to the heat insulating property and hygroscopicity due to the added porous material. The synergy of another invention of the present invention through this function is as follows. Anti-static, anti-flammability, anti-fogging, anti-fogging, anti-condensation, anti-condensation, anti-condensation, anti-condensation 13% of materials with anti-fogging function and 13% with anti-condensation and 6% of heat-insulating material, electromagnetic shielding, antistatic, flameproofing, antimicrobial anti- % mixed composition is both a surface resistance of all of 10 ⁷ Ω / □ to a solid content 36.6% emulsion-based electromagnetic wave shielding paint based, antistatic, flame retardant, antibacterial and antifungal, material 13% composition with eorm protection is 10 ^{8 ~ 9} Ω / □. As a result, it can be seen that the insulating porosity prevention and heat insulating properties of the insulator are excellent in electromagnetic wave shielding, antistatic, antistatic, antibacterial, antistatic, Anti-fogging, anti-fogging, anti-clogging, and humidity control. The composition of the present invention was found to have better flame retardancy than the composition containing no functional substance of the present invention. It was improved by 10 ~ 80% according to the content of composition in flame retardant experiment after coating on wood.

Another object of the present invention is to provide a method for producing a heat resistant polymer material by modifying a molecular structure, chemically bonding a flame retardant component to a polymer structure (reactive flame retardant), physically adding a flame retardant to a polymer substance ), Other flame retardant coating or painting methods, or a method of improving the heat resistance by changing the product design. Therefore, the flame retardant can be generally divided into a reaction type, an addition type, and a combination type thereof. In the reactive type flame retardant, the flame retardant is chemically bonded to the polymer material to continue the flame retardant effect. The addition type flame retardant is physically dispersed in the polymer material, And if they are compatible with each other, they play a plasticizing role or filler. Unlike reactive flame retardants, additive type flame retardants may cause blooming on the surface of polymer materials due to their structure and external conditions. Combination type flame retardants exhibit flame retarding synergistic effect or inhibitory effect depending on the combination type. The addition type flame retardant can be classified into the following four types according to the flame retardant behavior. First, it relates to the decomposition and ignition behavior of a macro scale as a substance capable of blocking the emission of non-combustible gases or combustible gases and oxygen. For example, there is a phosphorus compound inhibiting the decomposition reaction through formation of char in the solid phase reaction with a halogenated compound inhibiting the generation of highly reactive radicals in a gas phase reaction. Second, as a method of reducing the heat of combustion, it is related to the combustion stage of the macro scale. For example, there is a phosphorus compound which inhibits the decomposition reaction through the formation of char. Third, there is a filler, glass fiber reinforced and phosphorous compounds related to decomposition of the macro scale by maintaining the physical shape of the material through oxygen and heat shielding. Fourth, as a method of increasing the specific heat or the thermal conductivity of a substance, there is a related method of heating the macro scale. (2) Al (OH) ₃ or Ma (OH) ₂ blocks combustion by generating water during combustion, and (3) phosphorus or boron compound ④ Halogen compounds take the heat of vaporization during combustion and cool the combustion process. In the case of (1), the physical strength is lowered. In case (2), aluminum hydroxide is used in a large amount and has a disadvantage of decomposing at a temperature of less than 200 ° C., and in cases (3) and (4), harmful substances such as dioxin are generated. As a flame retardant substance that can overcome the regulated boron and halogen system, chlorinated material and salt and sea water as its kind and white carbon as an additional flame retardant (conduction) were also possible. However, in the case of products requiring a black system, the addition of conductive carbon may provide better results in terms of antistatic properties. Ⓐ Carbon: By using the theory that phosphorus flame retardant plays a role of flame retardant by charcoal formation and oxygen blockage when burning, it can be flame retarded if it is coated with charcoal (carbon, charcoal) to cover polymer material, and carbon can also act as deodorant . The problem is that black carbon can be used in fields limited to color problems, but white carbon is also available and can be used in various fields. Ⓑ If the heat transfer rate is good, if the heat received locally is dispersed within a short time, the flame retardancy will be good. Since synergistic effect of flame retardancy combined with ⓐ, thermal conductivity and electric conductivity are in a proportional relation, synergy effect was obtained by the action of ⓐ and ⓑ when using the carbon shown in (a) as conductive carbon. Ⓒ Na-based or Ca-based materials, this is the Kyushu Institute of Technology, which analyzes the composition of the oxide film by photoelectron spectroscopy and confirms the coating of calcium oxide that can not be observed with an electron microscope. The mechanism of the temperature rise. And ⓓ NaCl, there is no decomposition, but salt containing Mg or Ca ions is harmful. This is why the seawater polymer material has superior antistatic performance. It is a kind of chlorinated material such as CaCl ₂ or MgCl ₂ and chlorinated material, but it becomes a corrosive electrolyte due to abundant minerals such as sun-salt, and it has flame retardance and flame proofing property and electric resistance and antistatic function. The content of the electromagnetic wave shielding, antistatic and flame retardant, antimicrobial anti-fogging, anti-foaming, humidity control (insect repellent function) added materials and the like is preferably from singular to two or more but 30% by weight or less. The results of the flame retardance and flame proofing properties are shown in Fig. 26, and the test conditions are as follows. Specimen 5 mm, heat source methyl alcohol (using alcohol lamp), flame length 5 cm and flame length 1 cm, 10 seconds heating, ② turn off time check (T1), ③ 10 seconds reheating, and ④ turn off time check (T2). From the above results, it was found that flame retardancy test was performed on the specimens prepared by using other flame retardant materials and additives of the present invention for comparison evaluation in the present invention; The nitrogen-phosphorus flame retardant is capable of flame retardancy of UL standard V-0 when the content of flame retardant is more than 40%, and that of V-0 is ensured only when more than 60% of inorganic flame retardant is used. He was busy. The halogen-based flame retardant exhibited flame retardancy at V-0 level and exhibited the best flame retardancy even at a content of 20%. However, it was known that a toxic gas of black occurred and a specific odor of Br compound was produced. Also, flame retardant specimens prepared using nitrogen-phosphorus and inorganic flame retardant did not show dripping phenomenon when heating for 2 minutes continuously without turning off time check, but dripping occurred when using halogen flame retardant. However, in the present invention, it was found that the product of the present invention is equivalent to or superior to other flame retardant specimens as a result of comparison with an adhesive material prepared by adding the composition additive material of the present invention to a starch paste having a solid content of 19 to 21 wt% . The inventors of the present invention found that the additive materials used for demonstrating flame retardancy, which is another secondary function of the present invention, exhibited similar functions to those of the conventional flame retardants through physical and chemical considerations, and further subjected to environmental risk tests. (220mm × thickness (max. 15mm)) was manufactured based on UL-94 (V-0, V-1 standard) for export. A gas haze test, an objective evaluation index for environmental risk, was conducted with the freezing adhesive and coating material of the present invention.

As shown in Fig. 27, the weight loss of the test pieces after the test was 2.5 g and 2.3 g, respectively, and the mouse behavior stopping time was also measured to be higher than the judgment standard of 9 seconds. Thus, Was also excellent.

[Surface test]

◎ Related standard: KS F 2271.

◎ Test method: The specimen with 220mm width and 220mm length is heated by sub heat source and heated for 6 minutes by main heat source and heat source, and the weight loss, temperature time area and fuming coefficient per unit area, Measure.

◎ Criteria:

- Weight loss: less

- Temperature time area: Do not exceed the standard temperature curve within 3 minutes after starting the test.

- Fuming factor per unit area: 350 or less.

- Residual salt time: less than 30 seconds.

- Melting, cracking (less than 1/10 of the thickness), no deformation.

[Gas Hazard Test]

◎ Related standard: KS F 2271.

◎ Test method: Measure the average behavioral stoppage time of eight ICR (female of the Institute of Cancer Research) female mice in the smoke generated by heating the specimens 220 mm long and 220 mm long.

◎ Criterion: Average stopping time is over 9 minutes.

In addition, the mixing ratio is set to 33 wt%, the adhesive material 60 wt%, the condensation prevention and humidity control material 3 wt%, the solid content 50 wt%, the electromagnetic wave shielding, the antistatic and flame proofing, The surface resistance was measured using a composition containing 10% by weight of a surfactant and 20% by weight of a solid content of 20% by weight of electromagnetic wave shielding, antistatic and flame resistance, antimicrobial resistance, ⁶ % ^{~ 8} Ω / □, it was confirmed that there is antistatic property. The results of the flame resistance measurement through the flame retardant research institute are as follows. KS M 2150 (liquefied petroleum gas) was used as the fuel for the flame proof test of the present invention. The flame length of the burner was 45 mm in the micro burner and 65 mm in the Mkel burner, And a burner is installed in such a manner as to contact the burner. The specimens were cut into three pieces each of 35 cm long and 25 cm long cut out from the object to be measured having a size of 2 m 2 or more and dried in a constant temperature drier at 50 ° C for 24 hours and then placed in a desiccator containing silica gel for 2 hours And then at a temperature of 16 캜 and a humidity of 34% RH. After coating the coated and uncoated EVA base in a thickness of 120 mu m on the coated substrate plywood, the same flame resistance test as described above was performed on each of three test specimens. As a result, the area of carbonization was 28.4cm ² , 27.6cm ² , 31.3cm ² , 31cm ² , 7.1cm, 6.7cm, and 8.1cm, respectively. , Specimen ② 0 sec, specimen ③ 0 sec, duration of specimen was 0 sec for specimen, 0 sec for specimen, 0 sec for specimen. In addition, after the coating and the coating material (PVA base) were coated on the plywood of the coating material with a thickness of 120 μm, the flame resistance test was carried out on each of the three test pieces. The results for the carbide area of 38.7cm ² specimens ①, ② 40.3cm ² specimens, specimens ③ 30.8cm ^2, carbonized length of specimen ① 8.9cm, 9.5cm specimen ②, ③ specimens 7.5cm, Remaining flame time of the specimen ① 0 cho , Specimen ② 0 sec, specimen ③ 0 sec, duration of specimen was 0 sec for specimen, 0 sec for specimen, 0 sec for specimen. At this time, the carbonization length was set to the maximum length in the carbonized portion of the specimen, and heating was performed for each specimen for 2 minutes. This test is a result of heating for 2 minutes on the basis of the thick specimen. As can be seen from the results, And the coating material had good flame retardant properties.

[Flame Retardation Test]

◎ Carbonization area: Carbonized area by flame.

Carbonization length: Carbonized length by flower.

◎ Waste time: The time from when the flame of the burner is removed to when the flame is raised and the state of burning stops.

◎ Duration: The time from when the flame is removed from the burner to when the flame is not raised and the burning condition is stopped (excluding the time during which the flame is formed).

◎ Judgment standard: The flame proofing performance for a thick blanket corresponding to the test specimen (coated on paper) of the present invention is within 5 seconds of decay time, within 20 seconds of decay time, within 40cm2 of carbonization area, and within 20cm of carbonization length.

FIG. 28 is a photograph of a specimen taken after a flame test on a composition in which the composition of the present invention is not coated and coated on a wallpaper. FIG. Uncoated general laminated wallpaper was burnt as soon as the flame was applied, and the specimen was completely burnt. However, the coated laminated wallpaper had flame after removing the flame after 10 seconds of flame, and the specimen was turned off within 1 to 2 seconds. Therefore, the composition of the present invention had excellent flame retardancy or flame retardancy.

Solid substances that can dissolve well in water and lower the freezing point, such as chloride, nitrate, ammonium salt, etc., and the larger the ionized water, the greater the degree of freezing. For example, magnesium chloride has less ionic water than calcium chloride but has the same effect of lowering the freezing point at the same mole number, so magnesium chloride is more effective than calcium chloride for the same weight and better than sodium chloride. On the other hand, liquid substances, alcohols and glycols have the same effect. In the case of methyl alcohol, the mass of 1 mole is 32 g, and the freezing point is slightly lower than the freezing point of salt of 24.25. Ethylene glycol is used as an automobile antifreeze. It has a molar mass of 62 and is half of salt, but it is easy to mix in a liquid state and is often used for ease of handling. For reference, freezing point is freezing point. The freezing point constant for freezing point is 1.86 ℃. As described above, the principle of lowering the freezing point is used as the motive of the present invention. As shown in Fig. 29, the freezing temperature of pure ethylene glycol is -12 DEG C, but the freezing point (freezing point) of the liquid containing ethylene glycol and water varies depending on the mixing ratio. When water is mixed, the hydrogen bond of ethylene glycol is disturbed and freezing point is lowered. The freezing point of the liquid mixed with 70% of ethylene glycol and 30% of water goes down to about -50 ° C. An antifreeze solution that has a ratio of water to ethylene glycol of 1: 1 is about -35 to -40 ° C and is an excellent example of an antifreeze which can be used without difficulty in the winter environment of Korea. (Fig. 29: Source: Navercast, , Chemical walk, antifreeze, female lecture)

In addition, the principle of lowering the freezing point is that the ordinary water starts to freeze at 0 ° C, but the composition of the present invention does not freeze at a temperature lower than 0 ° C due to freezing point lowering as the content is higher than that of caustic soda. 30, referenced in Naver Knowledge Window, rsy7979. The red line separates the planes into three areas: the leftmost solid, the middle, and the bottom right. And the red line in the middle of the solid and liquid state is the solidification point = the point of fusion. The solidification point of the solution = parallel to the left because the x axis is the axis indicating the temperature. Which means that the temperature is lowered. Therefore, the freezing point of the composition of the present invention is lower than that of ordinary water, which is advantageous in terms of product storage, distribution, and construction in cold weather due to prevention of freezing phenomenon.

Products containing water, such as water-soluble adhesives, paints, and grass, have problems in freezing (freezing) in freezing temperatures in the winter. In winter, when water is used more than in summer, the cost of materials is higher than that in summer. When the wall of the apartment veranda which is lower than the apartment room or living room is coated with water-soluble paint, The contractor often fails to construct. In addition, there is a need for special care (management) because the adhesiveness is lowered due to the winter movement (product moving step for circulation or construction) and the freezing (freezing) during storage, or the product is discarded due to coagulation / separation. In the case of a product manufactured with circulating water, when it is thawed after freezing, the water and the adhesive component are separated, resulting in agglomeration or a marked decrease in viscosity. To solve this problem, a more detailed freezing test is carried out to prevent freezing by lowering the freezing point.

The water-soluble adhesive, which is the main invention of the present invention, and the product made of water such as paint and glue suffer from the problem of freezing in the freezing weather in the winter, and the two kinds of starch pools As a result, ice phenomenon was observed, and the freezing (freezing) evaluation experiment with the present invention was conducted. As a result of evaluating whether or not the product which is currently on the market and the present invention were frozen together in the freezer, the product containing water was frozen at about -11 ° C for 2 hours and then frozen for 24 hours. After leaving the freezer for 24 hours The product of the present invention did not freeze for 24 hours at -11 to -16 占 폚. In the subsequent evaluation, at -18 占 폚 for 10 hours evaluation, the surface was slightly stiff, but after thawing at 16 占 폚 for about 4 hours -18 to -20 캜 for 48 hours In the additional refrigeration test, the product of the present invention was completely lumpy, but when it was thawed, the original recovery and adhesive strength were improved Respectively. - When the products that are distributed on the market (currently sold products) are completely defrosted, there is a phenomenon in which the adhesiveness inherent to the adhesive such as starch is remarkably deteriorated due to the agglomeration due to the separation of the water and the flour component, Respectively. The pool, PVA, paint, and inventions containing the circulating water were further frozen in the freezer at a lower temperature and thawed. Then, the paper was applied to a paper wallpaper for adhesion test, followed by drying and peeling by hand. The products of the present invention were easily fallen and even the wallpaper adhered to itself fell off. However, the adhesive of the present invention did not change its adhesive force, and there was no problem in adhesion force (adhesive force) Was maintained.

The adhesives are particularly effective in reducing freezing points according to the content of the composition of the present invention as compared with adhesives (in the case of existing existing adhesives sold in the present invention) in which no such substance as the present invention is added among the water-soluble adhesives . The conventional adhesives start to freeze at 0 ° C, but when mixed with one type of electromagnetic shielding and antistatic, flame retardant, antimicrobial anti-fogging and anti-fogging (humidity control) 10% -10% -12%, -20% -13% -15%, and 29% -20% -22% It was confirmed that the adhesive prepared by mixing the two kinds of materials having the same content ratio and the difference in the solid content of about 2: 1 was lower than the freezing point of the above ratio by -2 to -35 ° C. Although the adhesive strength was restored to normal after thawing, there was no problem with the adhesive strength. However, when the thawing solution was frozen after the thawing, the solute and the solvent which gave the adhesive property were separated like islands and the adhesive strength was almost lost . Therefore, when the materials of the present invention are mixed, the freezing point is lowered and the adhesive force is restored when the water is thawed. As a result, the biggest problem of the conventional water-soluble adhesive is the increase in the construction cost due to the problem of winter season, And the use of an additional strong adhesive force. However, according to the present invention, the above-mentioned problems have been solved, and a product that can be easily installed regardless of the season has been invented for the first time. The electromagnetic wave shielding, antistatic, Antifungal and anti-fogging (humidity control) materials, including foam wallpaper, foam sheets, foam papers, adhesives, paints, furniture, partitions, curtains and vertical blinds, film sheets, wallpaper And floor coverings such as silk wallpaper, gooseneck, non-woven nonwoven fabric, PVC flooring, parquet floor, It is also an important feature that it is a product that can be used in all seasons by solving the fundamental problem of the past adhesive with the prevention of frost, because it belongs to the application products that show electromagnetic shielding and antistatic, flame proof and antimicrobial resistance.

Among the above compositions, the products manufactured in Examples 1, 2 and 3 were made to have a structure formed by forming one layer on the back surface of silk wallpaper or impregnated into a layer of the back surface (back surface or back surface) of silk wallpaper, This product structure is characterized by having a combination of three functions, namely, electromagnetic wave shielding and antistatic, flame retardant, antimicrobial anti-fogging, anti-condensation, humidity control and anti-fogging properties, thereby doubling the flammability of the conventional silk wallpaper. It is transparent among the above composition, and it has a product structure which maximizes the flame proofing property when the upper part is coated with 0.01 to 150 mu m, and when it is applied with the conventional silk wallpaper, the back side is coated with the composition product of the present invention, Which is applied to a product group such as Ridge Wallpaper as a method of spreading which maximizes the flame resistance characteristic by being applied to a wall Features featured product manufacturing method, structure and construction method.

Electrolytes are well dissociated into ions and have good electrical conductivity. Salt is one of the essential components of our life. Because if we do not take the salt in the salt, our body can not function. Salinity breaks down food and excretes waste. In addition, harmful substances and germs in the body, even if the intrusion of cells and blood vessels to prevent the role of enhancing the body. So, if the body lacks salinity, toxins accumulate in our body and it is easy to get bad disease, but the heart of the body does not get cancer, because the heart contains the salt most. Not only humans but also all living things on earth can not survive without taking salt. Animals find salt rocks and salt caves to consume salt, and plants absorb salt in the soil. If a horse or horse does not consume salt, he can not use force, and a tree that lacks salt easily decays. Therefore, salt does not give germs, germs and microbes to breed, and has a constant quality over a long period of time. The salt is well dissolved in water and penetrates well with other substances and has a property to give good things to our body and to remove bad things to mix well. And the salt has the property of absorbing the dust, and it is possible to wipe every corner cleanly. It is a nature to purify, so when you have salt in a place where there is mold in every corner of the house from the old days, or when you have lots of ants in your house, you can go to another place if you sprinkle salt. As a good example, the Tripitaka Koreana was completed in 1251, and when the remaining wooden boards were piled up, the height was about 3.2 km and the total weight was about 280 M / T. Well preserved, but well-made, would not have admired the beauty of the Tripitaka today. If you look at the reason why it could be preserved for a long time as a prototype, first of all, if you look at the process of selecting the timber, you will immerse it in seawater for 1-2 years without using the timber tree. After that, it was cut into the size of the plate and boiled in brine and dried. Salt has a property to prevent cracking of wood by the temperature and humidity, and it can reduce the phenomenon that the plate is cracked or twisted. It is also important to store the completed Tripitaka Koreana, which is suitable for the preservation of wooden boards. The temperature is around 20 ℃ and humidity is below 80%. However, the climate of the Tripitaka Koreana does not meet this standard. The humidity inside the panel is 89.09% in summer and 75.91% in winter, which is higher than general wood preservation standards. The average temperature was 19.81 ℃ in summer and 2.74 ℃ in winter. Why would it have been preserved for hundreds of years in an environment that is outside the proper wood conservation environment? Natural ventilation and storage The floor of the building was deeply digging into the ground and sprinkling charcoal, clay, sand, salt and grit. This is because when the rain is heavy and the humidity is low, the bottom sucks the moisture. On the other hand, when the drought occurs, the moisture that is hidden on the floor rises and automatically controls the humidity. In addition, the salt can be an ant. Ants like instinctively sweet smells. I like sugar and sweet candy, but I did not want to squeeze salt or vinegar and sour, so I tested 100 ants with salt and found that the ants did not come in the salt sprayed area. As shown in FIG. 31, it can be confirmed that the salt has an antithetical effect as shown in this actual experiment. Among the adhesives manufactured according to the composition of the present invention of Examples 1, 2, and 3 belonging to the organism, the rouge was superior to the conventional roasting rods in terms of inhibition performance. The temperature was over 30 ℃. In summer, the humidity was 60 ~ 90% RH for more than 1 day. This has been known for a long time in the industry, but the roasted roasted roasted roasted roasted roasted roasted roasted roasted roasted roasted roasted roasted roasted roasted roasted roasted roasted roasted roasted roasted roasted roasted roasted roasted roasted roasted roasted roasted roasted roasted roasted roasted roasted roasted roasted roasted roasted roasted roasted roasted roasted roasted roast roasted roasted roasted roasted roasted roasted roasted roasted roasted roasted roasted roast roasted roasted roasted roast roasted roasted roasted roasted roast roasted roasted roasted roasted roasted roasted ro This was confirmed in antibacterial and antimicrobial results, but in order to judge whether or not the odor was present, each sample in the day-by-day test was opened to confirm whether it was odor. And the odor smell did not occur until the present 270 days since the filing date. In other words, it was confirmed that the products manufactured in November, which is winter, are not deteriorated even in September when they enter the summers and fall through the spring.

Unlike CaCl ₂ powder and CaCl ₂ salt dissolved in H ₂ O as in Examples 1, 2, and 3, respectively, in the case of preparing a pottery by mixing powder into a mixing container for preparing a pottery powder, water is first added, and CaCl 2 ₂ , and sodium salt powder were added, and the mixture was stirred to dissolve the starch. Preferably, CaCl ₂ is first added and dissolved, and then it is preferable to dissolve the salt with the salt. This is advantageous for the production of the composition product by dissolving the mixture in a state of heat using the generated heat when the CaCl ₂ is dissolved, and adding the starch to disperse the mixture. The same physical properties and performance were also achieved when the powder of the present invention was prepared by adding CaCl ₂ powder and sodium chloride to the powder in the same formulation as that of the solution and making the powder. First, 20 to 80 kg of CaCl ₂ powder (CaCl ₂ 100%, 77%, 74%), _{5 to} 100 kg of sun salt, 20 to 160 kg of starch, and other (strong acids, etc.) 0 to 200 kg of H ₂ O And the mixture was agitated at 20 to 100 ° C for 1 to 600 minutes at 1 to 20,000 rpm to prepare a grape seed blend. This means that even if they are made into powders instead of solutions, the same products and the same performance products can be produced in the same mixing ratio and the same manufacturing method.

15 to 70% by weight of water, 15 to 70% by weight of solids, _{3 to} 35% by weight of CaCl2, 15 to 35% by weight of solid content of sunflower solution (small amount) 1 to 30 0 to 5% by weight of other components (such as strong acids) at 20 to 100 ° C for 1 to 600 minutes under the condition of mixing. The liquid composition is prepared by diluting the liquid composition 10 to 1000 times, spray-drying and then finely granulating it, or completely dried at high temperature and then pulverized to obtain a powdery paste. When water is added, it becomes a liquid-phase gypsum paste when it is stirred, and it becomes possible to perform the batching operation. The powder paste thus produced has an effect of increasing the manufacturing cost due to the additional process in the production of the powder paste, but also being capable of long-term storage due to the powder state and reducing the distribution cost due to the weight loss.

In the composition ratio of Examples 1, 2, 3, 13 and 14 which are one of the compositions of the present invention, a composition ratio of 90 to 99.8 wt%, a strong acid concentration of 0.01 to 5 wt%, a material exhibiting a preservative effect, 3-lodo-2 propynyl butyl carbamate (product name: MX-3 advanced Plus, Manufacturer:. CONNELL FAMILY INC), C 11 H 19 NOS (TK-800), UNICOOL-K14 ( Manufacturer: UCC) to the composition in each adding 0.01 to 10 wt%, antifungal Maximizing the effect. This composition was confirmed to maintain the performance of the present invention for more than one year.

32 is a photograph taken after bonding wood parquet tiles (floor material) by the composition adhesive manufactured in Examples 1, 2, and 3, and was better than that of the conductive PVC tile of Example 1. Fig.

This example artificially induces mold fungi in the early stages of the composition roasted products manufactured according to Examples 1, 2, 3, 13, 14, 15 and S roasted roasted products containing commercially available preservatives ), And the result of performing a culture experiment for one week is shown in Fig. As shown in the figure, the diffusion of fungus did not occur in the grafts produced according to the composition of the present invention, and the diffusion of the fungus was severe in the commercially available grafts containing preservatives and the like. However, It was proved that the anti - bacterial effect was excellent (good) because the spread of the mold bacteria was not occurred.

First, properties of flame retardancy, flame retardancy, and nonflammability are as follows. Flame retardancy is a property that does not cause flame burning when ignited through chemical or physical treatment of a combustible material. Flame retardancy is a property that relatively slows the burning rate compared to a combustible material. Nonflammability is a property that does not burn even at high temperatures such as metals and inorganic materials . In other words, flame-retarding flame does not burn while flame is taken, but flame is not burned by itself when flame is taken off, and it does not burn by direct flame and does not propagate and spread fire more than reference carbonized area, but flame- (Which turns itself off). Flame retardant has a flame retardant effect under a weak combustion condition, but it can be said that there is no big difference from a common flammable material under a high temperature or strong combustion condition. (Source: Doosan encyclopedia) By classifying as flame retardant grade, flame retardant grade 1 is a material that does not ignite as a fire-retardant material. Flame retardant grade 2 is a semi-flammable material that does not burn well. Flame retardant grade 3 is a flame retardant material. Which is difficult to ride. Therefore, a flame retardant material is a material that does not burn well even if it is ignited. It is a material that burns but does not burn well in flame. When it burns, it is deformed, No breakage should occur. When the flame is attached, a little toxic gas is generated, and burning phenomenon does not occur. Flame retardant, plywood, flame retardant, fiber board, flame retardant, plastic plate etc. belong to flame retardant materials, and they are processed with materials that do not burn on burning materials such as plywood, fiber board and plastic plate. The Enforcement Decree of the Building Act stipulates that "materials with performance that do not burn well" and that it is equivalent to Flame Retardant Class 3 as a result of tests conducted by the Korean Industrial Regulations pursuant to the Industrial Standardization Law set forth in the Ordinance of the Ministry of Construction and Transportation. In order to evaluate the flame retardancy corresponding to the flame retardant grade 3, flame and flame tests were carried out on the laminated wallpaper and the silk wallpaper using the flour paste and the general flour paste prepared in Examples 1, 6 and 7, respectively. Figs. 24 and 25 show the composition of the present invention in which a general wallpaper and a silk wallpaper are applied on both sides or on one side, and in a commercially available gauze paste made of water and starch, or a general gauze paste containing a mold inhibitor therein The coating is not coated and therefore the coating is not performed). First on the right side of the capture photo (paper wallpaper); The present invention was not coated with a rosewood paste, the second right (ridge wallpaper); Both sides of the present invention are applied to both sides, and the last additional experiment video capture photograph (ridge wallpaper); Only one side (one side) is applied. And on the same screen capture the first left (silk wallpaper); No silk wallpaper, second left (silk wallpaper): back side (one side only), third left (centered silk wallpaper); Both sides are all right. As shown in the test, the common wallpaper coated with the general gauze paste had less flame than the silk wallpaper but was completely burned. However, when applied to the gauze paste manufactured by the present invention, one side, two sides, When the tara removed the flame from the psalm, the tara was turned off. As shown in Figs. 34 and 35, the silk wallpaper was the same as that of the laminated wallpaper, but the uncoated silk wallpaper was burned better than the laminated wallpaper while generating the smoke. It can be understood that the silk wallpaper coated on one side (or both sides) with the PVC as the chemical substance is required to have the flame resistance characteristic due to the harmful smoke due to the combustion of PVC and the ease of combustion . Therefore, the composition polymer material of the present invention has excellent flame retardancy or flame retardancy.

The results of the refrigeration test for the roasting and general roasting of the composition of the present invention are shown at the top of FIG. The blossom of the present invention did not freeze after 24 hours from -11.8 to -15.6 ° C, but the general blossom pool was completely ice-free. Therefore, when the temperature of the present invention was further lowered to -16.5 DEG C for 12 hours, it was frozen (frozen) but the surface was frozen. Furthermore, it was frozen at -19.3 DEG C for 50 hours. As described above, it was found that the composition according to the present invention is a floating coating solution as a frozen solution which does not easily freeze at a low temperature, and it can be seen that the composition varies depending on the content of the functional material. The same results were confirmed in the aqueous EVA paint and aqueous acrylic adhesive as well as in the starch granules. The paint of ivory color was originally discolored in white upon thawing after frost, but the composition paint and adhesive of the present invention showed no color change (refer to FIG. 37).

Then, the frozen grass was completely thawed, and the paste was applied to a paper wallpaper, and the result was shown in the lower part of FIG. After the thawing, the water / starch was separated from the general seedlings, but the seedlings were originally restored to their original state (see FIG. 37). After freezing, thawing was carried out, and peeling test was carried out 2 hours after drying. The top roasted roasted roasted roasted roasted roasted roasted roasted roasted roasted roasted roasted roasted roasted roasted roasted roasted roasted roasted roasted roasted roasted roasted roasted roasted roasted roasted roasted roasted roasted roasted roasted roasted roasted roasted roasted roasted roasted roasted roasted roasted roasted coffee In the left-hand side of FIG. 36, the general round bottom pool # 1 was frozen after being frozen for 24 hours at -11.8 ° C, and then the whole was roasted at -11.8 ° C for 24 hours, Was prepared by freezing and thawing at -19.3 캜 for 50 hours in accordance with the present invention. As can be seen from the results, it can be seen that, in general, the gravure pulled off due to the loss of adhesion, the wall covered with the wall fell off, or even slightly peeled off. As shown in the peeling test, it can be seen that the adhesive strength is good because it shows that the paper portion is torn rather than falling down the area between the wall and the wallpaper.

Test results for grasping the degree of corrosion of metals such as screws in the grabbing pool and general grabbing pools # 1 and # 2 according to the present invention. According to the present invention, by purchasing a roasted roasted roasted roasted roasted roasted roasted roasted roasted roasted roasted roasted roasted roasted roasted roasted roasted roasted roasted roasted roasted roasted roasted roasted roasted roasted roasted roasted roasted roasted roasted roasted roasted roasted roasted roasted roasted coffee, This is a result. Screws placed in the general gravity pool were corroded and oxidized, but according to the present invention, the gravity pool produced in the gravity failure line had no change in color of the screw surface so that the degree of corrosion of the screw could not be known. Therefore, it has been proved that the function-imparting composition of the present invention is less corrosive than general grafting paste or adhesive when it is mixed with an adhesive.

While the invention has been described in connection with what is presently considered to be the most practical and preferred embodiment, it is to be understood that the invention is not limited to the disclosed embodiments, but, on the contrary, is intended to cover various modifications and equivalent arrangements included within the spirit and scope of the invention. Such variations are not to be understood individually from the technical idea or viewpoint of the present invention, and such modified examples should be included in the appended claims of the present invention.

10: Printed layer (base material layer, embossed layer).
20: Flame-resistant (antistatic) coating layer.
30: foam or sheet (paper, plastics, etc.)
40: aluminum foil layer.
50: adhesive layer.
60: release paper.
70: Polymeric materials.
70 Paper.

Claims (5)

The present invention relates to a composition for selectively preventing electromagnetic interference, antistatic and flame resistance, antimicrobial resistance, abrasion prevention, humidity control, anti-foaming,
(1) Adhesive materials that provide an adhesive force include: Acrylic, Epoxy, Polyvinyl Alcohol, Polyvinyl Acetate, Silicone, Polyurethane, Ethylenevinyl Acetate, Polyvinyl Chloride, Vinyl Acetate Acrylic Copolymer, Acrylic Copolymer. Gum Rosin, 2-Ethyl Hexyl Acrylate Monomer, 2-Ethylhexyl 2-Propenoate, 2-Hexyl. 2-EHAM, 2-Ethyl Hexyl Acryl Acid, Butyl Acrylate Monomer, N-Butyl Ester, Butyl 2-Propenoic Chloroprene Rubber, Acid, n-Butylacrylate and Resin of Vinyl Acetate Monomer, Solution or Acid, Primer, Emulsion, Monomer, Copolymer , Sealant, Resorcinol, α-Olefin, Isocyanate, Phenolic, Thermosoftening Plastic, Thermosetting Plastic, Starch, Rice, Wheat, Wheat, Corn, Potato, Dextrin and Modified starch. To 99% by weight,
(2) a material which exhibits the above electromagnetic wave shielding, antistatic and flame retardant, antimicrobial anti-fouling, antifouling, anti-condensation, anti-foaming function; Magnesium Chloride, Calcium Chloride, etc., belonging to a metal chloride of anhydrous or functional nH ₂ O (n = 0 to 99) having a solid content of 1 to 100 wt% 1 to 100% by weight in the form of a single or a mixture of two or more of these substances in the form of a powder or an aqueous solution thereof Salt is an industrial salt used as an edible Salt, a salt and a chemical used as a main component of sodium chloride, , Magnesium Chloride, Magnesium Sulfate, 6-9%, Potassium Chloride 2-4%, Sodium Chloride 2-6%, Magnesium Bromide 0.2-0.4 % Or the like, or 0 to 40% by weight of a concentrate obtained by heating 100 g thereof by 5 to 90% (particularly, in the present invention, The product has more antibacterial and antimicrobial effect by using tablets which do not have any bacteria in place of the sun-salt. Especially, it is treated at high temperature of 100 ℃ or higher, The reason for putting the acid in some products when manufacturing the product is not only the compatibility of the adhesive material but also the purpose of removing the self-retaining bacteria of the adhesive material.) (Salt is classified into sun salt and refined salt. It is an untreated salt made of coarse and translucent hexagonal crystals, which is formed by evaporating harmful substances with water and wind by the wind and sunlight. The purified salt is electrolyzed in seawater to remove impurities and heavy metals Is produced in the west coast or the south coast where the depth of the tide is not large and the difference between the tides is large, and it is also produced in the Indian Ocean, the Mediterranean coast, the United States, Australia, etc. In Jeollanamdo, Sinan- 65%, occupies more than half of the salt area, and has excellent quality worldwide In addition, the salt of sulfur produced in the vicinity of Baekryeong Island is also a commodity, and the salt of Korea is usually composed of reservoir, evaporation, and deciduous ground. In the high tide, Create and send the crystals to the crystal. If the wind is heavy and the crystal is small, and the temperature is low, the bitter taste or the quality of the salt will be lowered. It is better to pick the salt with a lot of sunshine and low wind. The salt produced in Korea is alkaline and the salinity is about 88%. It is mainly used for pickling of vegetables or fish because it contains minerals such as Ca, Mg, Zn, K, Fe and moisture and soaking in kimchi and soy sauce and miso. Although it contains a lot of good minerals, it contains some toxic substances, so it needs to be removed. When kimchi is dipped in sun salt, soy sauce and miso are made, the harmful ingredient disappears as it is fermented. In addition, it has high hygroscopicity due to various minerals, and has anti-clogging effect and insect repelling ability by sterilizing power beyond antimicrobial. Source: Doosan encyclopedia, Song Il Tongjeon, Shinan. The calcium chloride and sodium chloride of the above chlorides are treated with an acid to lower their corrosivity by a low corrosive or low salt system and the substances alone or two or more than 0 To 40% by weight, or a solid content of 5 to 80% by weight. As the ionic compound - In the ionic compound used in the present invention, the metal cation and the nonmetal anion are bonded by the electrostatic attraction, and the sum of the charges is electrically neutral. - +2 is at least one cation metal element selected from the group consisting of Co, Cu, Ni, Mn, Zn, Fe, Al, Be, Mg, Ca, and Ba, and the anion element is a fluoride anion, An anion, an iodide anion, a sulfide anion, a chloride anion, an ammonium anion, a hydroxide anion, a sulfate anion, a carbonate anion, a nitrate anion, a phosphate anion, a permanganate anion, Oxyhydrogen anion, there may be mentioned boric acid anions, chromic acid anion, and one or more selected from the group consisting of dichromate anion, a halogen anion, an anion of hydrochloric acid, an organic acid anion and the like. In consideration of corrosion of equipment and solution stability, ammonium salt may be further added. In the form of a hydrate, in the form of an aqueous solution, these substances alone or two or more and 2 to 50 wt% or 5 to 80 wt% And the cation metal element belonging to the cationic metal element is one or more selected from the group consisting of Li, Na, K, and the like. The anionic element may be a fluorinated anion, a brominated Anions such as anions, iodides, sulphide anions, chloride anions, ammonium anions, hydroxide anions, sulfate anions, carbonate anions, nitrate anions, phosphate anions, permanganate anions, acetic acid anions, hydrogen carbonate anions, chromate anions, bichromate anions, halide anions , Hydrochloric acid anion, organic acid anion and the like, and the hydrate form, Use of these materials alone or two or more 0-50% by weight in solution form or solid content 0.1 to 50% by weight of the conductive polymer; using (Conductive Polymer Polythiophene, PEDOT-PSS, Polyaniline, Polypyrrole) 0-50% by weight,
(3) For increasing, impact-strengthening and goodness, dispersion, cold resistance, viscosity increase, shortening of drying (curing) time, prevention of clogging; 0.0001~20㎛ with an alkali metal or an alkaline earth metal functions containing aluminum silicate (Si, Al) O porous structure in which tetrahedrons are bonded to the three-dimensional mesh of ₄ and WmZ _{2n2 n} O O formula, W is Na, Ca, Ba, and Sr, Z = Si + Al, quartz SiO ₂ , and diamond-like tetrahedral structures. In the three-dimensional network structure, a portion of Si is replaced by Al. Zeolite is a porous material capable of adsorbing a large amount of water, a siliceous porous material, lightweight foam ceramic, silica, perlite, titanium dioxide, clay, talc, aluminum hydroxide, kaolin, magnesium hydroxide , Calcium Carbonate, Diatomite, Loess, Bentonite, Quartz snad or the like may be used alone or in an amount of 0 to 50% by weight; Ammonium Dodecylbenzenesulfonate, Sodium Dodecylbenzenesulfonate, Sodium Dodecylbenzenesulfonate, Sodium Alkylarylsulfonate, Phosphate Ester, Ammonium, Soda type oil and inorganic dispersant, Silicon dispersant, Acrylic dispersant, Ammonium dodecylbenzenesulfonate, Polyoxyethylenenonylphenyl ether, Polyoxyethyleneoctylphenyl ether, Sodium Dodecylsulfonate, Sodium Dodecylsulfosuccinate, Sodium Polycarboxyl Acid; 0 to 55% by weight of at least one of octylalcohol, cyclohexane, polydimethylsiloxane and other high-grade Alcohol or Ethylene Glycol, spandex nonion activator, and silicone anti-foaming agent; The present invention relates to a method for producing a water-in-oil emulsion, which comprises the steps of: (1) preparing a water-in-oil emulsion, Lactobacillus acidus, Lactobacillus, Lactobacillus, Lactobacillus, Lactobacillus, Lactobacillus, Lactobacillus, Lactobacillus, Lactobacillus, Lactobacillus, Lactobacillus, Lactobacillus, , Pectin, carbomer, high-cell, gelatin, polycarboxylic acid, carboxyvinyl polymer, metal ethylcellulose, potassium alginate, retextrose, sodium carboxymethylstarch, casein, starch; Dioctyl Phthalate, Dibutyl Phthalate, Ester, etc. are preferably used for the cold adhesion property, and preferably 0 to 50% by weight of Alkyl Ester are mixed, or chlorinated 5-Chloro 2 methyl 4 isothiazolin 3 one and 2 Methyl 4 isotiazolin 3 1 not chlorine can be used in an amount of 0 to 5 wt%, respectively, and 3-lodo-2 propynl 0 to 5% by weight of butyl carbamate (MX-3 Advanced Plus, manufactured by CONNELL FAMILY INC.), C ₁₁ H ₁₉ NOS (TK-800) and UNICOOL-K 14 Iron powder, Copper powder, Cobalt powder, Tin powder, Aluminum powder, Magnesium powder, Titanium powder, Silicon powder, Nickel powder, Zinc powder, Manganese powder. Silver powder, Ag coated Cu, Ni coated Cu, Indium tin oxide, Free lead tin-bismuth, Silver chloride, Antimony tin oxide, Stainless steel, Mn (or Mg, And a ferrite such as Ba (or Sr) ferrite, conductive carbon powder and fiber, a solid content of 1.0 to 80.0% by weight, a conductive carbon sol alone, or 0 to 97.5% characterized in that the composition can be manufactured from a composition prepared by preparing a surface modified metal material with 0 to 90.0 wt% by using a carboxylic acid system, a fatty acid and a silane system, and a product having a color by the additive material.
(4) the solvent is; Content of 1 to 99.9 wt% Methanol, Ethanol, Butanol, Dichloromethane , Ethylacetate, Hexane, Diethylehter, Acetonitrile, Benznene, Dibasic Ester, 1-METHOXY-2-PROPANOL, BC, Diethylene Glycol Monoethyl Ether Acetate, Toluene, Alcohol, H 2 O , etc. are mixed alone or in a mixture of 5 to 85% by weight of two or more kinds,
(5) Although the order of mixing is not a big problem, it is preferable to mix and form the resin, solvent, dispersant and filler, the initial adhesive force-imparting agent, and the composite performance material in order, and a high pressure disperser and a high shear mixer (Mixer), stirrer (mixer), pre-mixer (stirrer), homodisperse, homogenizer, (impeller) high-speed stirrer, paste mixer, Apparatus and the like in a production process under the conditions of -15 to 100 ° C, 1 to 600 minutes, and 1 to 20,000 rpm, respectively; In addition to the conventional and current manufacturing methods in which a worker prepares a composition after the preparation of a composition and then improves the composition of the composition discharged through the mixing valve discharge valve, the manufacturing method can be applied to raw material input and packing transfer using advanced equipment, Composition and a method for producing the same. The method of claim 1,
Applied products formed through these materials are applied to PVC tiles, decorative tiles, wood flooring, flooring, PVC flooring (sheet, laminate), and particularly, tiles having a resistance of 10 ² to 10 ⁶ Ω / The adhesive properties of adhesive products for special purpose products and the electrical characteristics of the conductive adhesive for floor construction for reducing static electricity, the static electricity generated from the human body or the working equipment is transferred to the conductive adhesive layer through the PVC conductive tile, (-) ionization of the space by withdrawing the positive (+) charge in the space by the first-described metal spherical principle according to the present invention in a non-electromagnetic wave (uninterrupted) (Electromagnetic waves) are accumulated → by the difference of electric resistance on the same surface, the static electricity (electromagnetic wave) A conductive adhesive and a removal principle, system, and method of construction, characterized by the ability to quickly remove static electricity through grounding. In the first and second aspects,
10 to 40% by weight of starch (one or two grades, three grades, each alone or 0 to 100%: 0 to 100%: 0 to 100% mixed composition) , 30 to 95 wt% of water, 65 to 100 wt% of solids, 3 to 40 wt% of CaCl ₂ , 70 to 99 wt% of solids, 3 to 40 wt% of salt or purified salt, 0 to 5 wt% , 1 to 600 minutes, 1 to 20,000 rpm with stirring, and a process for producing the same; The composition of another one of the above compositions, 10 to 40% by weight of starch (first class, second class, third class, each alone or 0 to 100%: 0 to 100%: 0 to 100% % by weight, solid content: 50% by weight CaCl ₂ solution of 15 to 30% by weight, solid content 20 to 35% by weight of refined salt or solar salt solution, 5 to 40% by weight, a strong acid stream 0 to 5% of 30~100 ℃ in the composition formulation conditions by weight, 1 To 600 minutes at 1 to 20,000 rpm, and a method for producing the same; Spraying and granulating the composition 10 to 1,000 times, further finely dividing the powder 10 to 1,000 times, or completely drying and pulverizing the mixture at 70 to 400 DEG C for 0.1 to 30 minutes; Among the substances imparting functionality, salts are excellent in miscibility with neutral, acidic, and basic adhesive components. Therefore, when they are mixed with the adhesive material of claim 1, they are excellent in miscibility without agglomeration and can be used at a temperature of -25 to 100 ° C for 1 to 600 minutes, ~ 20,000rpm Mixing with stirring to prevent electromagnetic interference, antistatic, flame retardant, antimicrobial anti-fouling, prevention of clogging. A humidity control function, and an antistatic performance; When the composition ratio of the above-mentioned composition of CaCl _{2 is} 1 to 0.3 to 10 times the amount of the sun salt or the purified salt, it is possible to produce compositions and tributaries which are excellent in antibacterial and anti- A composition that shows the above functionality is put together to produce a branch flow to prevent electromagnetic interference, antistatic, flame retardant, Foam wallpaper, Foam sheet, Foam wallpaper, Foil wallpaper, Silk wall paper, Furniture, Curtain, Blind, Flooring, Fire-retardant adhesive, as well as paper manufacturing, paint, adhesive, Characterized in that the functionalized products are also produced in furniture and general furniture, a method for manufacturing the same, and applied products. In claims 1, 2, and 3,
The composition material is first coated on one side or both sides thereof, and an adhesive material such as an aqueous or oily material, varnish or the like and a coating material are added in an amount of 0.01 to 1,500 m in addition to one of the composition- (1), (2) and (3) to protect the functional parts of claims 1, 2 and 3 by applying a coating on one side or both sides thereof, And products made by coating paints include furniture, curtains, vertical, wallpaper, flooring, blinds, clothes, and the like. The product structure according to claim 1, wherein the product structure is a product of the above-mentioned functions such as a flame retardant layer made of a composition such as electromagnetic shielding, antistatic and flame retardant, antimicrobial anti-fogging, anti-foaming, etc. between the base material layer (or printing layer, embossed layer) An optional function is formed, and an aluminum foil layer is formed on the lower side of a plastic foam or sheet (hereinafter referred to as a sheet or a plastics, hereinafter referred to as a sheet), and the lower surface thereof is constituted by an adhesive layer and a releasing paper, The product is composed of nonwoven fabric such as base material layer / flame retardant layer / plastic foam (or sheet) / polyester long fiber nonwoven fabric / plastic foam (or sheet) / aluminum layer (adhesive layer / release paper) Or in the case of directly using an adhesive, it is preferable that the aluminum foil layer and the release layer without the adhesive layer, (Or sheet) is coated with a coating material and then dried, or only one side of the plastic foam (or sheet) is flame-retarded, or both sides of the plastic foam (or sheet) (Or sheet) is to be flame-treated on both sides of the plastic foam (or sheet), or to be made out of multiple or multiple layers, For example, when a coating material such as a paint is applied, it is manufactured without a base material layer, and a coating layer is formed by an adhesive (coating) material in addition to an upper release material portion. Anti-flammability, anti-bacterial protection, anti-clogging, heat insulation, anti-condensation, humidity control, anti-foaming A flame retardant layer made of the composition of the first aspect is formed between a base layer (or a printing layer, an embossing layer) and a plastic foam (or sheet), and an aluminum foil layer is formed at the bottom of the plastic foam A nonwoven fabric / plastic foam (or sheet) such as a base material layer / a flame retardant layer / a plastic foam (or a sheet) / a polyester long fiber nonwoven fabric in the case of a product formed of an adhesive layer and a releasing paper on the lower surface thereof, / Aluminum layer (/ adhesive layer / releasing paper so as to prevent the product from being warped, or when the adhesive layer is directly applied by using an adhesive, the aluminum foil layer and the release layer without the adhesive layer, It may be manufactured by coating with an adhesive (coating) material and then drying, or when only one side of plastic foam (or sheet) is flame retarded, or both sides of plastic foam In the case of a product in which a plastic foam (or a sheet) is constituted, both sides of the plastic foam (or sheet) are flame treated, When a wallpaper or the like is applied on a plastic foam (or a sheet) manufactured by removing a constituent layer, the structure is constructed such that a coating layer can be formed by an adhesive (coating) material in addition to the case where the resin is manufactured without a base material layer, It is a product that has a product structure characterized by having a combination of electromagnetism shielding, antistatic and flame resistance, antimicrobial resistance, prevention of clogging, heat insulation, condensation prevention, humidity control, , Particularly the adhesives without the addition of the functional imparting substances of the first aspect among the water-soluble adhesives, , Antistatic and anti-flammability, antimicrobial anti-fouling, anti-abrasion, anti-rust prevention, etc., have the effect of freezing point depending on the content of the material. -2 to -3 ° C, 6% -3 to 4 ° C, 10% -7 to 8 ° C, and 15% by weight in case of mixing one type of flame retardant, anti- 20% -13 to -15 ° C, and 29% -20 to -22 ° C, two kinds of substances having a solid content of about 2: 1 difference in the same content ratio are mixed The adhesive prepared by the above process is lower in temperature than the freezing point of the above-mentioned ratio by -2 to -35 ° C, and even though the adhesive force is restored to the original state after thawing, there is no problem with the adhesive strength. However, The solutes and solvents to be added are separated like islands, As a result of conflicting results, the freezing points were lowered when the above materials were mixed, and the adhesive strength was restored when the materials were thawed. As a result, the biggest problem of the conventional water-soluble adhesive was the increase in the construction cost due to the problem of winter season, There has been a serious problem such as loss of adhesive strength and mixing and use of additional strong adhesive force. However, the compositions of the first, second and third aspects have solved the above-mentioned problems and invented a product which can be easily applied regardless of the season, , Antistatic and flame retardant, antimicrobial anti-fogging, anti-foaming and the like. It is a composition including foam wallpaper, foam sheet, foaming paste, adhesive, paint, gypsum, furniture, partitions, curtains and vertical blinds , Film sheets, wallpaper and silk wallpaper, papaya, non-woven nonwoven fabric, PVC flooring, flooring such as flooring, When coating on clothing, it is applied to the application products that show electromagnetic shielding, antistatic and flame proofing, antimicrobial anti-fogging properties, and it is characterized by being able to use the four seasons by solving the fundamental problem of the conventional adhesive by anti- The application of the medium porous material is applicable to various applications such as heat insulation, humidity control, prevention of condensation phenomenon, electromagnetism shielding, electrification prevention and flame proofing, antimicrobial protection, Especially, the prepared gypsum paste was not frozen at -11.8 ~ -15.6 ℃ and frozen even after freezing at -19.3 ℃ for 50 hours to restore the original state and there was no problem in adhesive strength. The flocked wallpaper has flame retardant flame retardant property, which prevents harmful smoke generation and combustion progress, It was also found that the corrosion resistance of the grabbing paste prepared by using the property screw and the general grabbing paste was better than that of the general grabbing grass and the adhesive and was superior to that of the general grabbing paste and the adhesive. The surface resistivity was 10 ² to 10 ⁹ Ω / Combination of antibacterial and anti-bacterial protection, anti-bacterial and moisture control by porosity and deliquescence, prevention of dew condensation by positive (+) and negative (-) ionic bacteria And it can be applied to a variety of applications. It is a product that plays a role of contributing to the creation of a human-friendly environment by neutralizing the product and charged fine dust, and another product structure A paper for wall paper is prepared together with the composition of the present invention in a paper composition used for paper, wallpaper and silk wallpaper, or the composition of the present invention is applied to the back of a silk wallpaper Anti-static, antistatic, antifungal, anti-condensation, anti-condensation, humidity control, anti-foaming, anti-static, anti-static, Which is characterized by having a combination of three or more functions. The product is characterized in that the flame retardancy of the current silk wallpaper is doubled and the printing layer is transparent among the above compositions, In the case of spreading with the conventional silk wallpaper, the rear surface is applied with the composition of claim 1, so that it is impregnated into the wallpaper for 15 to 1,800 seconds, and the flame-retarding characteristic is also maximized by constructing it on the wall. It is characterized by its product manufacturing method, structure and construction method, Composition and application products that are characterized by being worn. Polymer materials for adhesive strength are resins, solutions or primers, emulsions, copolymers, thermosoftening plastic, thermosetting plastic, polyvinyl acetate, silicone, polyurethane, ethylenevinyl acetate and vinyl acetate monomer of 1 ~ 99 wt% starch, additives 0 to 20 wt.%, solids 15 to 80 wt.% adhesive made of grains such as rice, wheat, wheat germ, corn, potato, dextrin or the like and 1 to 99 wt. (Anti-bacterial or anti-bacterial), flame retardant, far infrared ray radiation is mainly used as edible salt and chemicals in the form of salt and chemicals 1 ~ 99 colonies sodium chloride material 0.1 to 34.8 g of water sampled from East Sea, West Sea, South Sea, Pacific Ocean, Atlantic Ocean, Indian Ocean and Dead Sea in Korea are used. Copper powder, cobalt powder, tin powder, aluminum powder, and the like, which are used in an amount of 0.01 to 99% by weight or a salt content of 0 to 99.5% Magnesium powder, Titanium powder, Silicon powder, Nickel powder, Zinc powder, Manganese powder. Silver ferrite such as silver powder, Ag coated Cu, Ni coated Cu, Indium tin oxide, Free lead Tin-Bismuth, Silver chloride, Antimony tin oxide, Conductive carbon) powder and a solid content of 1.0 to 80.0% by weight Conductive carbon sol and 0.01 to 20 μm of loess are used alone or in a mixture of two or more kinds of 0 to 97.5% by weight, or these metal materials are mixed with carboxylic acid, fatty acid and silane Or 0 to 85.0% by weight of a surface-modified metal material, or 1 to 100% by weight of solid calcium chloride is used in an amount of not more than 30% by weight of calcium chloride in a total composition ratio, 2-propanol, 1-METHOXY-2-PROPANOL, BC, Diethylene Glycol Monoethyl Ether Acetate, alcohol, H2O, 99.9 wt% mixed use Three roll mills of three passes or more are passed through a high pressure disperser, a high shear mixer (inline mixer, homomixer), a pre-mixer (stirrer), a ball mill, a homodisperse, (Impeller) high-speed stirrer, a paste mixer, a pre-mixer, a mixer and a stirrer, and a pulverizer, which are commonly used, at 30 to 103 ° C for 3 to 600 min. 1 to 20,000 rpm, 0.5 to 5 atm. A human body-friendly polymer material composition having electric field shielding, antibacterial, antifungal, antifungal, and far-infrared radiation functions dispersed and formed under the production conditions, In preparing the paste, the mixing vessel is first charged with 10 to 95% by weight of water, anhydrous or functional nH ₂ O (n = 0 to 99) metal chloride ₂ To MgCl ₂ (Especially CaCl 2 used in the present invention ₂ 100%, 77%, 74%. Among the products displayed are Australia, Vietnam, South America, North America, Europe, Africa, Asia, Japan, Vietnam, India and the Philippines. 30% by weight or less of solids, 1 to 99% by weight of solid content (salt used in the present invention is at least one kind selected from the group consisting of sun-salt, rock salt, etc.) It is a mixture of one or more of snowmelt, edible, playground / tennis courts, and low corrosivity. It is a mixture of Australian, Vietnamese, South American, North American, European, African, Asian, Japanese, Vietnamese, 1 to 30% by weight of starch, 1 to 30% by weight of starch, and 30 to 30% by weight of starch, (Water) prepared by stirring at -103 ° C for 3 to 60 minutes, 1 to 20,000 rpm, 0.5 to 5 atm while stirring, and a method for producing the same, Manufacture with flame retardant (flame retardant), anti-foil Paint and glue; In applying the function of the present invention to be applied to various products such as heat-insulating wallpaper, sheet, parchment paper, silk wallpaper, furniture, curtain, blind, flooring, , Wallpaper, sheet and film products are laminated and coated with various coating methods such as laminating (roll coating), brush coating, spray coating, impregnation (immersion) (Hereinafter referred to as &quot; paper &quot;) is applied to the composition polymer of the present invention or both sides thereof are flame-treated with the adhesive of the present invention, or grass paper is immersed in the polymer solution of the present invention for flame-retarding treatment , The vinyl wallpaper is coated with flame-retardant coating on the outside of each of the sheet and PVC sheet, the interior film is flame-coated on one side or both sides of the sheet, (MDFMedium Density Fiberboard)) In case of flame-retardant coating on one side or both sides, it is preferable to use a flame retardant resin such as the above-mentioned flame retardant treated, foam, sheet, paste, adhesive, paint, A flooring such as a partition, a curtain and a vertical blind, a film sheet, a paper sheet and a silk wallpaper, an icicle, an acrylic nonwoven fabric, a PVC flooring, a flooring, And a coating thickness of 20 占 퐉 or more and 200 占 퐉 or less on one side or both sides of the substrate; and a method of manufacturing the same; The present invention relates to a composition for selectively exhibiting flame retardancy and antistatic properties, prevention of dew condensation, antimicrobial, anti-fogging, anti-abrasion, heat insulation, humidity control and anti-foaming properties, and an application product using the same. Resorcinol, α-Olefin, Isocyanate, Phenolic resin, Solvent, Solution, or Primer of Acrylic, Epoxy, Polyvinyl alcohol, Polyvinyl acetate, Silicone, Polyurethane, Ethylenevinyl acetate, Polyvinyl chloride and Vinyl Acetate Monomer. of solids, 15 to 50% by weight of solids made of cereals such as rice, wheat, wheat, corn, potato, dextrin, modified starch and the like, thermosetting plastic, thermosetting plastic, starch, additives 0 to 20% Is mixed with 1 to 99 wt%, and the material for controlling heat insulation, preventing condensation, and humidity is used; Aluminum silicate minerals containing alkali metals or alkaline earth metals (Si, Al) O ₄ And a porous structure in which a tetrahedron of W _m Z _n O ₂ n ₂ And Z is Si, and W is Na, Ca, Ba, and Sr, and Z = Si + Al, quartz SiO2, and zeolite in which a part of Si in the three- Zeolite is a porous material capable of adsorbing a large amount of water, a siliceous porous material, a lightweight foam ceramic, a highly hygroscopic silica, a perlite, a diatomaceous earth, 0 to 51% by weight of titanium alone or in combination of two or more is used as a material for controlling flame retardation and electrification, antibacterial, anti-fogging, anti-foaming and humidity control agents; Anhydrous or functional nH with a solids content of 1 to 100% ₂ MgCl2 belonging to the metal chloride of O (n = 0 to 99) ₂ , CaCl ₂ 0 to 30% by weight of these substances alone or in the form of an aqueous solution thereof is used, and 1 to 100% by weight of salt is an industrial substance used as edible salt, sun salt and chemicals in which sodium chloride is a main component, Seawater collected from the South Sea, the Pacific Ocean, the Atlantic Ocean, the Indian Ocean, the Dead Sea and the Black Sea, 15 to 19% of magnesium chloride, 6-9% of magnesium sulfate, 2-4% of potassium chloride, 2-6% of sodium chloride, Or 1 to 69% by weight of a solid component composed of 0.2 to 0.4%, or 0 to 40% by weight of a product obtained by heating 100 g thereof by 5 to 90% ₂ , Sodium chloride, or the like, which are treated with an acid or the like to lower their corrosiveness by a low corrosive or low-salt system, these materials may be used alone or in an amount of 0 to 40% by weight or in the form of microwaves, defoamers, dispersants, thickeners, 0-39 wt.% Each, or the solvent may contain 1 to 99.99 wt.% Methanol, ethanol, butanol, dichloromethane, ethylacetate, hexane, diethylehter, acetonitrile, benznene, dibasic ester, 1-METHOXY-2-PROPANOL , BC, Diethylene Glycol Monoethyl Ether Acetate, alcohol, H ₂ O, etc, alone or in combination of two or more species in an amount of 0.1 to 99.9% by weight; It is commonly used in high-pressure disperser, high-shear mixer (inline mixer, homomixer), pre-mixer (stirrer), homodisperse, homogenizer, high speed stirrer, paste mixer, Mixer and stirring apparatus (mixing vessel), and a pulp pool manufacturing apparatus are used at a temperature of -15 to 100 DEG C for 1 to 600 min. Characterized in that the composition is prepared by the method of manufacture under the production conditions of 1 to 20,000 rpm; It is applied to various products such as foam, wallpaper, foam sheet, foam sheet, silk wallpaper, furniture, curtain, blind, flooring, And is characterized by exhibiting various functions. The composition is characterized by having an average size of 0.01 to 25 mu m and an iron powder, a copper powder, a cobalt powder, a tin powder, an aluminum powder, a magnesium powder, a titanium powder, powder, Nickel powder, Zinc powder, Manganese powder. Silver ferrite such as silver powder, Ag coated Cu, Ni coated Cu, Indium tin oxide, Free lead Tin-Bismuth, Silver chloride, Antimony tin oxide, Conductive carbon) powder and a solid content of 1.0 to 80.0% by weight Conductive carbon sol and 0.01 to 20 m of loess are used alone or in a mixture of two or more, 0 to 97.5% by weight, or these metal materials are mixed with carboxylic acid, fatty acid and silane The surface-modified metal material is 0 to 85.0% by weight, and the product can be made into a product having a color by the additive material, and the like. Further, (1 st grade or 2 nd grade, 3 nd grade, each independently or 0 to 100%: 0 to 100%: 0 to 100%, each of which is one of the compositions of the present invention, Mixed composition) 10 to 40% by weight, water 30 to 95 Wt%, solid content 65 to 100 wt% CaCl ₂ 3 to 40% by weight, solid content 70 to 99% by weight, and 3 to 40% by weight of the salt of the sun salt at 30 to 100 ° C for 1 to 600 minutes. 1 to 20,000 rpm Liquid-phase grafting composition containing anhydrous acid (in particular, no sulfuric acid), no preservative (no formaldehyde in preservative), and a method of preparing the same; In addition, another composition in the above composition, starch (first class, second class, third class, each alone or 0 to 100%: 0 to 100%: 0 to 100% 90% by weight, solid content 50% by weight CaCl ₂ 15 to 30% by weight of a solution, 20 to 35% by weight of a solid component and 5 to 40% by weight of a salt solution of a salt thereof. (1) to (20,000) rpm, (2) a liquid-liquid composition containing unreacted acid (in particular, no sulfuric acid in acid) and a no-opaque agent (in particular, no formaldehyde among preservatives); The liquid composition is further diluted 10 to 1,000 times, spray-dried and then granulated, or dried at 70 to 400 DEG C for 0.1 to 30 min. A method of producing a powdery paste prepared by thoroughly drying and then grinding; Among the above-mentioned composition materials, among the substances imparting functionality to the present invention, CaCl ₂ And salt of sun salt are excellent in compatibility with the adhesive component of neutral or pH 8 or less. Therefore, it is preferable to mix the acidic adhesive agent with the acidic adhesive agent in the above ratio, 1 to 600 min. 1 to 20,000 rpm Mixing and mixing with stirring to prevent flame retardance and electrification, antimicrobial, anti-bacterial, anti-abrasion. It is possible to manufacture adhesive agents and coating compositions with anti-condensation, heat insulation, humidity control, anti-foaming properties; Among the above compositions, CaCl ₂ When the blending ratio of 1 to 20 times the blending ratio of the mannitol is added to the ratio 1, it is possible to manufacture a composition having excellent antibacterial and insect repellent functions by the sterilizing power beyond antimicrobial among the above-mentioned various performances; In addition, a composition that shows the above functionality is added to the composition of the tributary to produce a tributary to prevent flame resistance and antistatic, antimicrobial, anti-bacterial, Condensation prevention, heat insulation, humidity control function tributary becomes possible; It is applied to various products such as foam, wallpaper, foam sheet, foam, wallpaper, silk wallpaper, furniture, curtain, blind, flooring, And one or both sides of the above-mentioned composition material is first coated, and one of the adhesives used for the composition adhesive material and the composition, or the adhesive material listed in the present invention, And the like, to further protect the functional part according to claim 1 by applying a coating treatment of one side or both sides with an additional amount of 0.01 to 1,500 μm, and a method of protecting the functional part, and application products thereof, 1) Products made by coating adhesives and paints include furniture, curtains, vertical, wallpaper, flooring, blinds, clothing, etc. The products and the product structure of the product form a selective function among the above functions such as a flame retardant layer made of a composition such as the flame retardant and antistatic, antimicrobial, anti-fogging, anti-fogging, etc., between the base layer (or the printing layer and the embossed layer) A product made up of an adhesive layer and a releasing paper on the lower surface of the aluminum foil layer, or a product made in another environment (for example, a paper sheet or a plastic sheet) A nonwoven fabric such as a base layer / a flame retardant layer / a plastic foam (or a sheet) / a polyester long fiber nonwoven fabric / a plastic foam (or a sheet) / an aluminum layer (an adhesive layer / a release paper) , When using a direct adhesive, the aluminum foil layer and the release layer without the adhesive layer, or the above-mentioned adhesive (coating) material not containing the composition of the present invention (Or sheet) is produced by flame-retarding only one side, or both sides of a plastic foam (or sheet) are formed by forming a flame retarded layer, and a plastic foam (or sheet) In the case of products, both sides of the plastic foam (or sheet) are flame-retarded, and the product is manufactured by adding multiple layers or plural layers or removing the constituent layers. ), Etc., are manufactured without the base material layer, and in addition to the case where the upper release film portion is manufactured, the coating layer is formed so that the coating layer can be present with the adhesive (coating) material. Product structure, which is characterized by having a complex combination of insulation, anti-condensation, humidity control, A flame retardant layer made of the composition of the first aspect is formed between a substrate layer (or a printing layer, an embossing layer) and a plastic foam (or sheet), and an aluminum foil layer is formed at the bottom of the plastic foam Plastic foams (or sheets) / aluminum foils (or sheets), such as base materials / flame retardant layers / plastic foams (or sheets) / polyester filament nonwoven fabrics, (Adhesive) layer / releasing paper to prevent warping of the product, or when the adhesive is applied by using a direct adhesive, the above-mentioned adhesive (coating) without the aluminum foil layer and the adhesive layer or without the composition of the present invention, (Or sheet), or one side of the plastic foam (or sheet) is flame-retarded, or both sides of the plastic foam (or sheet) are flame-retarded In the case of a product in which a plastic foam (or sheet) is constituted, both of the plastic foam (or sheet) and the plastic foam (or sheet) When a wallpaper is applied on a plastic foam (or a sheet), it is manufactured without a base material layer, and a coating layer is formed with an adhesive (coating) material in addition to the case where the upper release paper portion is manufactured. A product structure characterized by having a combination of flame retardancy and antistatic, antimicrobial, anti-fogging, anti-fogging, heat insulating, anti-condensation, humidity control, anti-fogging properties; The adhesives, particularly those having the functions of anti-flame and antistatic, antimicrobial, antibacterial, anti-abrasion, anti-fogging, etc., compared with the adhesives without the functional imparting substance of the above 1 among the water-soluble adhesives , The former adhesive starts to freeze past 0 ℃, but when it is mixed with 1 kind of anti-flame and antistatic, antimicrobial, antifungal, anti-fouling material, it is about -2 to -3 10 wt% -7 to -8 DEG C, 15 wt% -10 to -12 DEG C, 20 wt% -13 to -15 DEG C, 29 wt% -20 to -22 DEG C , The adhesives prepared by mixing the two kinds of materials having the same content ratio and having a solid content of about 2: 1 differ from the freezing point of the above ratio by -2 to -35 ° C lower than the freezing point temperature, After thawing, the adhesive strength was restored to its original state and there was no problem with the adhesive strength. As a result, the freezing points are lowered when the materials are mixed, and when the materials are mixed and thawed, the adhesive strength is restored, so that the water solubility of the water-soluble adhesive However, in the case of the winter season, there was a serious problem such as an increase in construction cost due to a problem in winter season and an increase in construction cost for maintaining warmth, It is a composition that includes materials such as anti-flame and antistatic, antimicrobial, anti-fogging, anti-fogging, etc., and it can be used as a foam wallpaper, a foam sheet, a foam sheet, an adhesive, a paint, Furniture, partitions, curtains and vertical blinds, film sheets, wallpaper and silk wallpaper, When applied to flooring materials such as paper, PVC nonwoven fabric, PVC flooring, flooring, and clothing, it has become a part of applied products that exhibit flame retardancy, antimicrobial, antifungal and antistatic properties. Wherein the porous material of the first aspect of the present invention is applied to exhibit an optional composite function such as heat insulation, humidity control, prevention of condensation, and flame retardancy, antimicrobial, anti- Various applicable products; As another product structure, it is possible to produce paper for wall paper together with the composition of the present invention in a paper composition used for paper wall paper and silk wallpaper, or to form a single layer by the composition of the present invention on the back side of silk wallpaper, It is made up of structure that is made to permeate into the inside of the stratum, and it has three functions among anti-flammability and antistatic, anti-bacterial, anti-bacterial, anti-clogging, heat insulation, condensation prevention, humidity control and anti- This product structure doubles the flame resistance of the current silk wallpaper. It is transparent among the above composition on the printed layer, and it has the product structure which maximizes the flame proofing property when the upper part is coated with 0.01 ~ 150 ㎛. Applying the composition of Paragraph 1 and applying it to the wallpaper for 15 to 1,800 seconds, In addition to the manufacturing method, structure, and construction method, which is characterized by a construction method that can be applied to a product family such as Ridge Wallpaper, the composition method is also characterized in that it exhibits the ability to combat insects as well; The prepared graft paste was restored to its original state when it was frozen at -11.8 to -15.6 ° C and thawed even at -19.3 ° C for 50 hours, so that there was no problem in the adhesive strength, and no initial color change occurred in the prepared paint or adhesive, It has flame retardant and flame retardant properties and it prevents the generation of harmful smoke and combustion, and it is more resistant to corrosive than ordinary gypsum grass and adhesive even in the degree of corrosion of the gypsum and general gypsum paste manufactured using metallic screws. The antimicrobial activity of antimicrobial agents against antimicrobials (mainly bacteria), antimicrobial resistance against antimicrobials (mainly fungicides) and antimicrobial · It is applicable to composition products with various functions such as anti-fogging and buffing, humidity control by porosity and deliquescence, prevention of dew condensation, and various application products. It is a product that plays a role of contributing to the creation of a human-friendly environment by neutralizing action of the product; Examples of adhesive materials for imparting adhesive strength include; Emulsion, copolymer, Resorcinol, α-Olefin, Isocyanate of acrylic, epoxy, polyvinyl alcohol, polyvinyl acetate, silicone, polyurethane, ethylenevinyl acetate, polyvinyl chloride, 0 to 20% by weight of grains such as rice, wheat, wheat, corn, potato, dextrin, starch, starch, additives, or the like in an amount of 1 to 99% by weight, And anti-flame and anti-static, antimicrobial, antifungal, anti-foaming agent; Aqueous to functional nH with 1 to 99 wt.% Solids ₂ O (n = 0 to 99), MgCl 2 belonging to the metal chloride ₂ , CaCl ₂ , ZnCl ₂ , NH ₄ Cl, Nature &lt; RTI ID = 0.0 &gt; NaCl, KCl, LiCl, ₄ , K ₂ SO ₄ , (NH ₄ ) ₂ SO ₄ NaOH and KOH belonging to the hydroxyl group, Na ₂ CO ₃ , KHCO ₃ , (NH ₄ ) ₂ SO ₄ Cu, Ni, Mn, Zn, Fe, and the like, and the metal cation and the nonmetal anion are bonded by the electrostatic attraction, and the sum of the charges is electrically neutral. Wherein the anion element is at least one element selected from the group consisting of Al, Be, Mg, Ca and Ba, and the anion element is at least one element selected from the group consisting of fluorinated anion, bromide anion, iodide anion, sulfated anion, chloride anion, ammonium anion, At least one selected from the group consisting of an anion, a phosphate anion, a permanganate anion, an acetate ion, a hydrogen carbonate anion, a boric acid anion, a chromic acid anion, a bichromic acid anion, a halogen anion, a hydrochloric acid anion, +1 is a cation metal and -1 is an anion or -2 is an anion, and the cation metal element belonging to this is selected from the group consisting of Li, Na, K and the like An anion element may be at least one selected from the group consisting of a fluorinated anion, a brominated anion, an iodide anion, a sulfated anion, a chloride anion, an ammonium anion, a hydroxide anion, a sulfate anion, a carbonate anion, a nitrate anion, a phosphate anion, a permanganate anion, A hydroboric anion, a boric acid anion, a chromic acid anion, a bichromic acid anion, a halogen anion, a hydrochloric acid anion, an organic acid anion and the like. (PEDOT-PSS, Polyaniline, Polypyrrole), 100% solids of silica and alumina, or a mixture of these substances in an amount of from 2 to 50% by weight of the conductive polymer 1 to 99% by weight of the composition is used alone or in a combination of 2 to 99% by weight, and 1 to 99% 1 to 99% by weight of salt water, 1 to 99% by weight of magnesium chloride, 6 to 9% by weight of magnesium sulfate, 2 to 4% by weight of potassium chloride, 2 ~ 6% of sodium chloride and 0.2 ~ 0.4% of magnesium bromide. 1 ~ 69% by weight of solid materials, which are excellent in the ability to inhibit insects, various bacteria and fungi. The main areas are Donghae, West Sea, South Sea, Pacific Ocean, 1 to 99% by weight of those obtained by concentrating 5 to 90% by heating 100 g of the above materials are used, and the above-mentioned flame retardant and antistatic, antimicrobial, anti-fungal, anti- Materials that have low corrosiveness or low corrosiveness by using a method of treating them with acids or the like among the anti-fouling materials are used. Contents 1 ~ 99.9 wt. Solvents such as methanol, ethanol, butanol, dichloromethane, ethylacetate, hexane, diethylehter, acetonitrile, benznene, dibasic ester, 1-METHOXY-2-PROPANOL, BC, Diethylene Glycol Monoethyl Ether Acetate, alcohol, And 0.1 to 99.9% by weight of at least two kinds thereof are mixed, and the adhesive, flame retardant and antistatic agent, antimicrobial / antifungal agent, antifogging agent and solvent are metered (weighed) in a reaction vessel or a mixing vessel and then heated at 5 to 100 ° C for 5 to 600 min. High-pressure disperser, high-shear mixer (inline mixer, homomixer), pre-mixer (agitator), ball mill, homodisperse, homogenizer, (impeller) high-speed stirrer, paste mixer, presuperative mixer, Apparatus and the like, or by using two or more kinds of them; In the product structure, a flame retardant layer is formed between the substrate layer (or the printing layer and the embossing layer) and the plastic foam, and the aluminum foil layer is formed at the lower end of the plastic foam A nonwoven fabric such as a base material layer / a flame retardant layer / a plastic foam / a polyester long fiber nonwoven fabric / a plastic foam / an aluminum layer (composed of an adhesive layer / a release paper) When the adhesive is applied by direct adhesive, it is coated with the above-mentioned adhesive (coating) material not containing the aluminum foil layer and the adhesive layer or the composition of the present invention after being coated and dried Or when only one side of the plastic foam is flame-retarded, or both sides of the plastic foam are formed by forming a flame retarded layer In the case of a product in which a plastic foam is constituted, both sides of the plastic foam are flame-retarded, and a plurality or a plurality of layers are additionally constituted or manufactured by removing the constituent layer. When a wallpaper is applied on a plastic foam, Products that are manufactured with a structure that is made up of a coating layer made of an adhesive (coating) material in addition to the case where it is manufactured by attaching an upper release paper portion, and is characterized by having flame retardancy and antistatic property, antimicrobial, anti- Structure: Adhesives are used to prevent flame retardant and antistatic, antimicrobial, antifungal and antifouling materials, especially water-soluble adhesives, as compared with adhesives that have no flame retardant and antistatic, antimicrobial, anti- It has the effect of freezing point according to the content, and the past adhesives start to freeze after 0 ℃, 3%, 6% -3% -4%, 10% -7% -8%, and 15% by weight in the case of mixing 3 kinds of antimicrobial, anti- 20% -13 to -15 ° C, and 29% -20 to -22 ° C, two kinds of substances having a solid content of about 2: 1 difference in the same content ratio are mixed The adhesive prepared by the above process is lower in temperature than the freezing point of the above-mentioned ratio by -2 to -35 ° C, and even though the adhesive force is restored to the original state after thawing, there is no problem with the adhesive strength. However, As a result, the freezing point is lowered when the materials of the present invention are mixed, and the adhesive force is restored when the material is mixed with water, In winter season, the problem was the construction disruption caused by the problem, There has been a serious problem such as an increase in the construction cost for the paper, a loss of adhesion after use, and a use of an additional strong adhesive force. However, the composition of claim 1 has solved the problem as described above, Anti-bacterial, anti-fogging, anti-fogging, anti-flame and antistatic, anti-bacterial, anti-fogging, anti-fogging materials. It is a composition containing foams, foams, foam sheets, foams, adhesives, paints, furniture, partitions, curtains and vertical blinds, When applied to flooring materials such as wallpaper, silk wallpaper, parchment paper, nonwoven fabric of nonwoven fabric, PVC flooring, flooring and clothing, it became a part of applied products that show flame retardancy, antimicrobial, antibacterial and antistatic properties. To solve the fundamental problem of the application of the four seasons; The composition for selectively preventing condensation, heat insulation, flame retardancy, antimicrobial, anti-fogging, antistatic, anti-foaming, Resincinol, α-Olefin, Isocyanate, Phenolic, Resin, epoxy resin, Polyvinyl alcohol, Polyvinyl acetate, Silicone, Polyurethane, Ethylenevinyl acetate, Polyvinyl chloride, Vinyl Acetate from 0 to 20% by weight of thermosoftening plastic, thermosetting plastic, starch, additives, 15 to 40% by weight of solids from grains such as rice, wheat, wheat, corn, potato and dextrin, %, As a material for preventing condensation and providing heat insulation; W is a Na, Ca, Ba, Sr, Z = Si + Al, and W is a porous structure in which a tetrahedron of (Si, Al) O4 is bound in a cubic network with a hydrous aluminum silicate mineral containing an alkali metal or an alkaline earth metal. Zeolite in which a part of Si in a three-dimensional network composed of quartz SiO 2 and diamond-like tetrahedral structures is bound by an infinite structure is replaced by Al, and this network structure is broken, and there is a gap in the skeleton. Zeolite is a zeolite which comprises 0 to 51% by weight of a porous material capable of adsorbing a large amount of water, a siliceous porous material, a lightweight foam ceramic, highly hygroscopic silica, perlite, titanium dioxide, Anti-bacterial, antifungal, anti-foaming agent; Anhydrous or functional nH of 1 to 99 wt.% Solids ₂ O (n = 0 to 99), MgCl 2 belonging to the metal chloride ₂ , CaCl ₂ , ZnCl ₂ , NH ₄ Cl, Nature &lt; RTI ID = 0.0 &gt; NaCl, KCl, LiCl, ₄ , K ₂ SO ₄ , (NH ₄ ) ₂ SO ₄ NaOH and KOH belonging to the hydroxyl group, Na ₂ CO ₃ , KHCO ₃ , (NH ₄ ) ₂ SO ₄ Salt in the form of a hydrate, in the form of an aqueous solution, salt is a substance used as edible salt and chemicals mainly composed of sodium chloride, seawater collected from East Sea, West Sea, South Sea, Pacific Ocean, Atlantic Ocean, Indian Ocean, Dead Sea, % Sodium chloride, 15% to 19% of magnesium chloride, 6% to 9% of magnesium sulfate, 2% to 4% of potassium chloride, 2% to 6% of sodium chloride and 0.2% to 0.4% of magnesium bromide. 0 to 49% by weight of these materials are used alone or in combination with other materials such as microwaves, defoamers, dispersants, thickeners, thickeners, 2-propanol, 1-METHOXY-2-PROPANOL, 1-METHOXY-2-PROPANOL, Diethylene Glycol M (inline mixer, homomixer), a free mixer (agitator), a ball mill, and a homodisperse mixer, which are prepared by using a mixture of onoethyl ether acetate, alcohol, H2O, etc. in an amount of 0.1 to 99.9 wt% , A homogenizer, a (Impeller) high-speed stirrer, a paste mixer, a pre-mixer, a mixer and a stirrer which are commonly used, or a mixture of two or more thereof. Products characterized by their application in various products such as foam wallpaper, foam, foam, foam, wallpaper, furniture, curtains, blinds, flooring; 3.39 to 27.83% by weight of a flame retardant and antistatic agent, 3.30 to 27.83% by weight of antibacterial and antifungal agent, anti-fouling agent, 29.02% by weight of solid content and 1.24 to 25.29% by weight of small amount of water in 19.24 to 21.29% by weight of water, 50.89 to 20.59% At 30 to 100 DEG C for 5 to 150 minutes. A method for producing the same, a method for producing the same, a method for producing the liquid composition comprising the step of diluting the liquid composition 10 to 1000 times, Or a method in which a powder is produced by pulverization after complete rolling; Antimicrobial, anti-fogging, antifogging agent 3.63 to 27.83% by weight, solid content 29.02% by weight, small amount of 1.24 to 25.29% by weight, condensation phenomenon 0.1 to 30% by weight of a material for preventing and adiabatting. 30 to 100 占 폚 for 5 to 150 min. A method for producing the same, a method for producing the same, a method for producing the liquid composition comprising the step of diluting the liquid composition 10 to 1000 times, Or completely dried, followed by pulverization; The composition material is first coated on one side or both sides thereof and an adhesive material such as an aqueous or oily material or a varnish or the like is applied in an amount of 0.01 to 1,500 mu m A method of coating the functional part of claim 1 by applying a coating treatment on one side or both sides, and a method of protecting the functional part of the invention, and products applied thereon, A vertical, a wallpaper, a floor, a blind, a garment, and the like; The product structure includes a flame retardant layer formed between the substrate layer (or the print layer and the embossed layer) and the plastic foam, the flame retardant layer being made of the flame retardant and anti-static, antimicrobial anti- A non-woven fabric such as a base layer / a flame retardant layer / a plastic foam / a polyester long-fiber nonwoven fabric / a plastic foam / an aluminum layer (/ adhesive layer / release paper) When the adhesive is applied by using a direct adhesive agent, it is coated with the above-mentioned adhesive (coating) material not containing the aluminum foil layer and the adhesive layer or the composition of the present invention after drying, Or only one side of the plastic foam is flame-retarded, or both sides of the plastic foam are formed by forming a flame retarded layer In the case of a product in which a plastic foam is constituted, both sides of the plastic foam are flame-retarded, and a plurality or a plurality of layers are additionally constituted or manufactured by removing the constituent layer. When a wallpaper is applied on a plastic foam, Products that are manufactured with a structure that is made up of a coating layer made of an adhesive (coating) material in addition to the case where it is manufactured by attaching an upper release paper portion, and is characterized by having flame retardancy and antistatic property, antimicrobial, anti- Structure: The flame retardant layer is formed between the substrate layer (or the printing layer and the embossing layer) and the plastic foam, and the flame retardant layer is formed of the flame retardant and antistatic composition, antimicrobial, anti- In the case of a product which is constituted by an adhesive layer and a releasing paper on the lower surface thereof or a product which is installed in another environment, a base material layer / a flame retardant layer / When formed by a structure formed of a nonwoven fabric such as a tie-foil / polyester long-fiber nonwoven fabric / plastic foam / aluminum layer (/ adhesive layer / releasing paper to prevent twisting of the product, or directly using an adhesive, (Coating) material without the composition of the present invention, or after coating with one of the above-mentioned adhesive (coating) materials without the composition of the present invention, or only one side of the plastic foam is flame-retarded, or both sides of the plastic foam are flame retarded In the case of a product in which a plastic foam is constituted, both the plastic foam and both sides are flame-treated, and when a wallpaper or the like is applied on plastic foam by additionally constituting a plurality or a plurality of layers or removing the constituent layer, (Coating) material in addition to the case where it is manufactured by attaching the upper part of the release paper Characterized in that the product structure tingcheung this configuration has a number of denture fixative arc flame retardancy and antistatic eojin been made of a structure to sex, antibacterial, antifungal, eorm resistance is present; Adhesives, especially those of water-soluble adhesives, contain flame retardant and antistatic agents, anti-flame and antistatic agents, antimicrobial agents, antifungal agents, anti-fouling agents, , The former adhesive starts to freeze past 0 ℃, but when it is mixed with 1 kind of anti-flame and antistatic, antimicrobial, antifungal, anti-fouling material, it is about -2 to -3 10 wt% -7 to -8 DEG C, 15 wt% -10 to -12 DEG C, 20 wt% -13 to -15 DEG C, 29 wt% -20 to -22 DEG C , The adhesives prepared by mixing the two kinds of materials having the same content ratio and having a solid content of about 2: 1 differ from the freezing point of the above ratio by -2 to -35 ° C lower than the freezing point temperature, After thawing, the adhesive strength was restored to its original state and there was no problem with the adhesive strength. However, if the existing adhesive is thawed, As a result, the freezing point was lowered when mixed and the adhesive strength was restored when the mixture was thawed. As a result, the most problem of the water-soluble adhesive in the winter There was a serious problem such as an increase in the construction cost for maintenance of the building due to the problem and a loss of the adhesive strength after the lapse of time and a use of the additional strong adhesive force. However, the composition of claim 1 is easy to install regardless of the season It is a composition that includes anti-flame and antistatic, antimicrobial, anti-fogging and anti-fouling materials. It can be used in various fields such as foam wallpaper, foam sheet, foamed pasteboard, adhesive, paint, Curtains and vertical blinds, film sheets, wallpaper and silk wallpaper, cinnamon, non-woven nonwoven fabric, PVC bar When applied to flooring materials such as ash flooring and clothing, it is applied to products that exhibit flame retardancy, antibacterial and antifouling properties, antistatic properties, and can be used for four seasons by solving the fundamental problems of conventional adhesives by preventing frost Features Applied Products; Emulsion, Copolymer, Resorcinol, α-Olefin, Isocyanate of acrylic resin, epoxy, polyvinyl alcohol, polyvinyl acetate, Silicone, Polyurethane, Ethylenevinyl acetate, Polyvinyl chloride and Vinyl Acetate Monomer 0 to 20% by weight of grains such as rice, wheat, wheat, maize, potato, dextrin, starch, starch and additives, or 1 to 99% by weight of at least two kinds of additives, Examples of the additives of the present invention include freezing point, flame retardancy, antistatic, antibacterial, antifungal and insect repellent functions; Aqueous to hydrous nH having a solids content of 1 to 99 wt% ₂ O (n = 0 to 99), MgCl 2 belonging to the metal chloride ₂ , CaCl ₂ , ZnCl ₂ , NH ₄ Cl, Nature &lt; RTI ID = 0.0 &gt; NaCl, KCl, LiCl, ₄ , K ₂ SO ₄ , (NH ₄ ) ₂ SO ₄ NaOH and KOH belonging to the hydroxyl group, Na ₂ CO ₃ , KHCO ₃ , (NH ₄ ) ₂ SO ₄ Cu, Ni, Mn, Zn, Fe, and the like, and the metal cation and the nonmetal anion are bonded by the electrostatic attraction, and the sum of the charges is electrically neutral. Wherein the anion element is at least one element selected from the group consisting of Al, Be, Mg, Ca and Ba, and the anion element is at least one element selected from the group consisting of fluorinated anion, bromide anion, iodide anion, sulfated anion, chloride anion, ammonium anion, At least one selected from the group consisting of an anion, a phosphate anion, a permanganate anion, an acetate ion, a hydrogen carbonate anion, a boric acid anion, a chromic acid anion, a bichromic acid anion, a halogen anion, a hydrochloric acid anion, +1 is a cation metal and -1 is an anion or -2 is an anion, and the cation metal element belonging to this is selected from the group consisting of Li, Na, K and the like An anion element may be at least one selected from the group consisting of a fluorinated anion, a brominated anion, an iodide anion, a sulfated anion, a chloride anion, an ammonium anion, a hydroxide anion, a sulfate anion, a carbonate anion, a nitrate anion, a phosphate anion, a permanganate anion, A hydroboric anion, a boric acid anion, a chromic acid anion, a bichromic acid anion, a halogen anion, a hydrochloric acid anion, an organic acid anion and the like. (PEDOT-PSS, Polyaniline, Polypyrrole), 100% solid silica and alumina, or a mixture of two or more of these materials in an amount of 2 to 50% by weight 1 to 99% by weight of the composition is used alone or in a combination of 2 to 99% by weight and 1 to 99% On the other hand, 1 to 99% by weight of sea water was directly used, 1 to 99% by weight of solid water was used in an amount of 1 to 69% by weight, and in particular, various bacterial and fungal inhibitory properties This material is used as a major material and collected from East Sea, West Sea, South Sea, Pacific Ocean, Atlantic Ocean, Indian Ocean, Dead Sea, Black Sea, etc., or 100g is heated and concentrated to 5 ~ 90% 1 wt% methanol, ethanol, butanol, dichloromethane, ethylacetate, hexane, diethylehter, acetonitrile, benznene, Dibasic ester, 1-METHOXY-2-PROPANOL, BC, Diethylene Glycol Monoethyl Ether Acetate, ₂ O, etc, alone or in combination of 0.1 to 99.9% by weight of two or more kinds, freezing point, flame retardant and antistatic agent, antimicrobial agent, antibacterial agent, antibacterial function additive substance and salt, magnesium chloride 15 ~ 19%, magnesium sulfate 6 ~ , A multifunctional adhesive and coating material composition using an aqueous solution containing 2 to 4% of potassium chloride, 2 to 6% of sodium chloride, and 0.2 to 0.4% of magnesium bromide, etc., and 3 roll mills of 1 to 5 passes (Impeller) high-speed stirrer, paste mixer, pre-confounder mixer, and the like are commonly used in a high-pressure disperser, a high-pressure disperser, a high-shear mixer (inline mixer, homomixer), a pre-mixer (agitator), a ball mill, a homodisperser, A mixer and a stirrer, or the like, or two or more of them, uniformly dispersed, and then free from freezing at -15 to -18 占 폚, and a method of preparing the same; The composition of the adhesive and coating material which does not freeze at -15 to -18 占 폚 is first coated on one side or both sides thereof, and the adhesive agent used for the composition adhesive material and the composition is applied to the adhesive material listed in the present invention. Or the like can be further coated with 0.01 to 1,200 탆 of one side or both sides of the adhesive material and the coating material is coated with a sheet of paper (coated paper, interior film, heat shielding film, etc.) A coating layer 0.1 to 1,200 mu m thick, and a method of protecting the coating layer of 0.1 to 1,200 mu m, and applications of the same, which are easy to generate wood or fire. Examples of products manufactured by coating the functional adhesives and coatings of the present invention include furniture, curtains, A flooring, a blind, a garment or the like; and a product thereof; In the paint (paint) sold on the market, additives such as freezing point lowering, flame retardant and antistatic, antibacterial, antifungal and insect repellent function are added; Aqueous to hydrous nH having a solids content of 1 to 99 wt% ₂ O (n = 0 to 99), MgCl 2 belonging to the metal chloride ₂ , CaCl ₂ , ZnCl ₂ , NH ₄ Cl, Nature &lt; RTI ID = 0.0 &gt; NaCl, KCl, LiCl, ₄ , K ₂ SO ₄ , (NH ₄ ) ₂ SO ₄ Such as NaOH and KOH belonging to the hydroxyl group, such as aSO ₄ , K ₂ SO ₄ , (NH ₄ ) ₂ SO ₄ Cu, Ni, Mn, Zn, Fe, and the like, and the metal cation and the nonmetal anion are bonded by the electrostatic attraction, and the sum of the charges is electrically neutral. Wherein the anion element is at least one element selected from the group consisting of Al, Be, Mg, Ca and Ba, and the anion element is at least one element selected from the group consisting of fluorinated anion, bromide anion, iodide anion, sulfated anion, chloride anion, ammonium anion, At least one selected from the group consisting of an anion, a phosphate anion, a permanganate anion, an acetate ion, a hydrogen carbonate anion, a boric acid anion, a chromic acid anion, a bichromic acid anion, a halogen anion, a hydrochloric acid anion, +1 is a cation metal and -1 is an anion or -2 is an anion, and the cation metal element belonging to this is selected from the group consisting of Li, Na, K and the like An anion element may be at least one selected from the group consisting of a fluorinated anion, a brominated anion, an iodide anion, a sulfated anion, a chloride anion, an ammonium anion, a hydroxide anion, a sulfate anion, a carbonate anion, a nitrate anion, a phosphate anion, a permanganate anion, A hydroboric anion, a boric acid anion, a chromic acid anion, a bichromic acid anion, a halogen anion, a hydrochloric acid anion, an organic acid anion and the like. (PEDOT-PSS, Polyaniline, Polypyrrole), 100% solid silica and alumina, or a mixture of two or more of these materials in an amount of 2 to 50% by weight 1 to 99% by weight of the composition is used alone or in a combination of 2 to 99% by weight and 1 to 99% On the other hand, 1 to 99% by weight of sea water was directly used, 1 to 99% by weight of solid water was used in an amount of 1 to 69% by weight, and in particular, various bacterial and fungal inhibitory properties This material is used as a major material and collected from East Sea, West Sea, South Sea, Pacific Ocean, Atlantic Ocean, Indian Ocean, Dead Sea, Black Sea, etc., or 100g is heated and concentrated to 5 ~ 90% 2-propanol, 1-METHOXY-2-PROPANOL, Diethylene Glycol Monoethyl Ether Acetate, alcohol, H2O, etc 0.1 to 99.9% by weight of an additive and salt, magnesium chloride of 15 to 19%, magnesium sulfate of 6 to 9%, potassium chloride of 2 to 4% Sodium chloride is 2-6%, brominated Magnesium and 0.2% to 0.4% by weight of a binder and coating material composition according to the present invention, and a method for producing the same; In order to facilitate the spreading, a general paste is added to the paste 1 in an amount of 1 to 0.6 parts by weight of water, or a mixture of PVA (polyvinyl alcohol) and polyvinylpyrrolidone (PVA) (19.24 ~ 21.29% by weight), water (40.89 ~ 34.59% by weight), solid content (40 ~ 40% by weight), and the like. 20% to 30% by weight, 20% to 30% by weight, and 30% to 50% by weight of the composition. A method for preparing a pullulan composition containing agaric acid (without sulfuric acid in acid), an unpurified agent (especially no formaldehyde among antiseptics), and a method for producing the same; Emulsion, Copolymer, Resorcinol, α-Olefin, Isocyanate of acrylic resin, epoxy, polyvinyl alcohol, polyvinyl acetate, Silicone, Polyurethane, Ethylenevinyl acetate, Polyvinyl chloride and Vinyl Acetate Monomer 0 to 20% by weight of grains such as rice, wheat, wheat, maize, potato, dextrin, starch, starch and additives, or 1 to 99% by weight of at least two kinds of additives, Flame retardant and antistatic, antibacterial materials; NaCl, CaCl2, ZnCl2, NH4Cl, Nature NaCl, KCl, LiCl and the like belonging to the metal chloride and NaSO4, K2SO4, (NH4) belonging to the sulfuric acid system belonging to the metal chloride of the anhydride to the functional nH2O (n = 0 to 99) Na2CO3, KHCO3, (NH4) 2SO4, etc. belonging to the carbonic acid system such as NaOH and KOH belonging to the hydroxide system and the like and the metal cation and the nonmetal anion are bonded by the electrostatic attraction and the sum of the electric charges is electrically neutral To 80% by weight +2 or more of the cationic metal element is at least one element selected from the group consisting of Co, Cu, Ni, Mn, Zn, Fe, Al, Be, Mg, Ca, and Ba, and the anion element is a fluoride anion, Anions such as anions, iodides, sulphide anions, chloride anions, ammonium anions, hydroxide anions, sulfate anions, carbonate anions, nitrate anions, phosphate anions, permanganate anions, acetic acid anions, hydrogen carbonate anions, chromate anions, bichromate anions, halide anions , Hydrochloric anion, A cationic metal and a cationic metal and an anion of -1 or -2 are used as a cationic metal element, and the cationic metal element belonging to the cationic metal is Li, Na, K And the anion element may be at least one selected from the group consisting of a fluorinated anion, a bromide anion, an iodide anion, a sulfide anion, a chloride anion, an ammonium anion, a hydroxide anion, a sulfate anion, a carbonate anion, , At least one member selected from the group consisting of a permanganate anion, an acetate ion, a hydrogen carbonate anion, a boric acid anion, a chromic acid anion, a bichromate anion, a halogen anion, a hydrochloric anion and an organic acid anion, By weight or more and 2 to 50% by weight, and 0.1 to 50% by weight of a solid content of the conductive polymer. Wherein the adhesive composition is prepared by mixing 1 to 99% by weight of a bonding composition obtained by mixing at least one selected from the group consisting of Polythiophene, PEDOT-PSS, Polyaniline and Polypyrrole, 100% solid silica and alumina, 1 to 99% by weight of salt is used as edible salt and chemical used as a main component of sodium chloride and on the other hand 1 to 99% by weight of seawater is directly used, 1 to 69% It is used especially in various areas such as East Sea, West Sea, South Sea, Pacific Ocean, Atlantic Ocean, Indian Ocean, Dead Sea, Black Sea, etc., or it is heated to 5 ~ 90% 1-METHOXY-2-PROPANOL, BC, Diethylene Glycol Monoethyl Ether Acetate, Alcohol, Ethanol, Ethanol, Ethanol, Ethanol, , H2O, etc, 0.1 ~ 99.9% by weight, or more. Environment friendly flame retardant, antistatic, antibacterial, freezing point. Multifunctional adhesive and coating materials and 3 roll mills 1 ~ 5 pass ~ (Impeller) high-speed stirrer, paste mixer, pre-confocal mixer, mixer and stirring device which are conventionally used, and a mixer Etc .; dispersed evenly using environmentally friendly flame retardant and antistatic agent, freezing point using antimicrobial substance, lowering by -15 ~ 21 ℃ Multifunctional Adhesion and Coating Material and its Preparation Method; Environmentally Friendly Flame Retardant Lowers Freezing Point Multifunctional Adhesive and coating material is first coated on one side or both sides and then adhered to the composition adhesive material and the composition used in the composition or from the adhesive material listed in the present invention such as aqueous or oily, The adhesive material and the coating material may be further coated with one or two sides by coating with 0.01 to 1,500 탆 in order to protect the functional part of claim 1 and the applied products therefrom, Such as furniture, curtains, verticals, wallpaper, flooring, blinds, clothes, and the like; For paints (paints) sold on the market, they are freezing point, flame retardant and antistatic, antimicrobial substances; (MgCl 2) belonging to the metal chloride, of anhydrous to hydrolyzed nH 2 O (n = 0 to 99) with a solid content of 1 to 99 wt% ₂ , CaCl ₂ , ZnCl ₂ , NH ₄ Cl, Nature &lt; RTI ID = 0.0 &gt; NaCl, KCl, LiCl, ₄ , K ₂ SO ₄ , (NH ₄ ) ₂ SO ₄ Such as NaOH and KOH belonging to the hydroxyl group, such as aSO ₄ , K ₂ SO ₄ , (NH ₄ ) ₂ SO ₄ Cu, Ni, Mn, Zn, Fe, and the like, and the metal cation and the nonmetal anion are bonded by the electrostatic attraction, and the sum of the charges is electrically neutral. Wherein the anion element is at least one element selected from the group consisting of Al, Be, Mg, Ca and Ba, and the anion element is at least one element selected from the group consisting of fluorinated anion, bromide anion, iodide anion, sulfated anion, chloride anion, ammonium anion, At least one selected from the group consisting of an anion, a phosphate anion, a permanganate anion, an acetate ion, a hydrogen carbonate anion, a boric acid anion, a chromic acid anion, a bichromic acid anion, a halogen anion, a hydrochloric acid anion, +1 is a cation metal and -1 is an anion or -2 is an anion, and the cation metal element belonging to this is selected from the group consisting of Li, Na, K and the like An anion element may be at least one selected from the group consisting of a fluorinated anion, a brominated anion, an iodide anion, a sulfated anion, a chloride anion, an ammonium anion, a hydroxide anion, a sulfate anion, a carbonate anion, a nitrate anion, a phosphate anion, a permanganate anion, A hydroboric anion, a boric acid anion, a chromic acid anion, a bichromic acid anion, a halogen anion, a hydrochloric acid anion, an organic acid anion and the like. (PEDOT-PSS, Polyaniline, Polypyrrole), 100% solid silica and alumina, or a mixture of two or more of these materials in an amount of 2 to 50% by weight 1 to 99% by weight of the composition, or 1 to 99% by weight of solid content, and sodium chloride 1 to 99% by weight of solid waters and 1 to 99% by weight of solid waters are used, and in particular, various bacteria, fungi, It is used in major regions such as East Sea, West Sea, South Sea, Pacific Ocean, Atlantic Ocean, Indian Ocean, Dead Sea, Black Sea, etc., or 100g is heated to 5 ~ 90% ~ 99.9 wt% methanol, ethanol, butanol, dichloromethane, ethylacetate, hexane, diethylehter, acetonitrile, benznene, Dibasic ester, 1-METHOXY-2-PROPANOL, BC, Diethylene Glycol Monoethyl Ether Acetate, 0.1 ~ 99.9% by weight, more environmentally friendly Flame retardant, antistatic and anti-bacterial materials, -15 ~ 21 ℃ lowering multi-functional adhesive and coating materials; 5 to 59% by weight of solid content As the water-soluble adhesive material, an acrylic emulsion, an epoxy emulsion, a polyvinyl acetate and an emulsion-based adhesive, a urethane-based adhesive, (Ethylene-vinyl acetate) adhesive, resorcinol adhesive,? -Olefin adhesive, polyvinyl chloride adhesive, isocyanate adhesive, isocyanate adhesive, A composition (I) comprising 10 to 95% by weight of a phenolic resin-based adhesive (Phenolic) alone or in combination of two or more thereof, 15 to 40% by weight of a solid component made of grains such as rice, wheat, wheat, maize, potato, dextrin, (II) having 5 to 95% by weight of at least two of the compounds (II) and 10 to 95% by weight of the composition (II) 0 to 50% by weight of water or alcohol, 5 to 80% by weight of solid content in ionic compound I - In the ionic compound used in the present invention, metal cations and nonmetal anions are bonded by electrostatic attraction, and the sum of the charges is electrically neutral. The anion element may be at least one selected from the group consisting of Co, Cu, Ni, Mn, Zn, Fe, Al, Be, Mg, Ca and Ba. Anion, anion, anion, anion, bichromate, halide, anion, anion, anion, anion, anion, anion, anion, anion, anion, anion, nitrate, anion, Etc., and may further include ammonium salts in consideration of equipment corrosion and solution stability. 2 to 50% by weight in the form of a hydrate, in the form of an aqueous solution, and 5 to 80% by weight of a solid component. The ionic compound II has an anionic cationic metal and a -1 or -2 anionic cation. The element may be at least one element selected from the group consisting of Li, Na, K, and the like. The anion element may be a fluorinated anion, And at least one selected from the group consisting of anion, nitrate anion, phosphate anion, permanganate anion, acetic acid ion, hydrogen carbonate anion, boric acid anion, chromic acid anion, bichromate anion, halogen anion, hydrochloric anion, organic acid anion, , 2 to 50% by weight in the form of an aqueous solution, and 3 to 50% by weight of a solid polymer (Conductive Polymer; Polysiloxane, PEDOT-PSS, Polyaniline, Polypyrrole), 100% solid silica and alumina, 0.1-50% by weight of these materials alone or in admixture of two or more thereof are mixed at a stirring speed of 30 to 20,000 rpm for 5 minutes to 3 hours Antistatic, antibacterial, antifungal and flame-retardant compositions prepared by mixing them and a method of producing them; Characterized in that the product is an adhesive, a paint, a wallpaper, a furniture, a flooring, a curtain or a blind; The present invention is filed in order to supplement the Korean Patent Application No. 1-1-2016-0898291-86. When calcium chloride is used as the water-soluble adhesive, the possibility of mold generation due to moisture during coating and coating due to the high water absorption of calcium chloride, Functional adhesives using conventional color have a problem in that the ease of operation such as equipment and equipment used in the case of using carbon black, worker and workplace environment, construction site and the like are problematic due to pollution. Therefore, the above-mentioned patents and techniques have fundamental problems due to the ease of operation required in the method of manufacturing a functional material, the kind and effectiveness of the materials used, and the lack of long-term reliability as a product. Disclosure of Invention Technical Problem [8] The present invention has been made in order to solve the problems of the prior art and the related art as described above, and it is an object of the present invention to provide a multi- In manufacturing an application product, the flame-retardant material used in the present invention is highly flame-retardant, and further, when antistatic and electric-field attenuating functions are solely or in combination, sodium chloride, which is one kind of flame retardant, Etc. have not yet been found in the flame retardant substance which is the main substance used in the present invention due to the antimicrobial activity which is the main function in addition to the antistatic effect but also the mold inhibition role. However, in case of using it as an additional supplement, And the fight against various insects So that it can be used. In addition, the product manufactured or used according to the present invention can be formed so that the flame retardancy, the electric field cutoff (attenuation) in the adhesive region and the adhesive layer, the electric field reduction through the shielding, the accumulation, the extinction, the antibacterial and the antibacterial function can be combined And thus it is possible to exhibit the characteristics of the product having the effect of creating a pleasant environment and eliminating or reducing harmful elements of the human body. In order to realize the above object, a multifunctional adhesive and coating material manufactured by using a non-inflammable flame retardant substance and an antistatic substance alone or in combination in an adhesive material, and an application product using the same are developed. The necessity and principle of flame retarding and flame retarding, antistatic and antistatic, electric field elimination, antibacterial and antifungal suppression, and the effect of the present invention will be discussed first. The main method of the present invention is to produce a heat resistant polymer material by changing the molecular structure, chemically bonding the flame retardant component to the polymer structure (reactive flame retardant), physically adding the flame retardant to the polymer substance (additive type flame retardant) Other flame retardant coating or painting, or a method of improving the heat resistance by changing the design of the product. Therefore, the flame retardant can be generally divided into a reaction type, an addition type, and a combination type thereof. In the reactive type flame retardant, the flame retardant is chemically bonded to the polymer material to continue the flame retardant effect. The addition type flame retardant is physically dispersed in the polymer material, And if they are compatible with each other, they play a plasticizing role or filler. Unlike reactive flame retardants, additive type flame retardants may cause blooming on the surface of polymer materials due to their structure and external conditions. Combination type flame retardants exhibit flame retarding synergistic effect or inhibitory effect depending on the combination type. The addition type flame retardant can be classified into the following four types according to the flame retardant behavior. First, it relates to the decomposition and ignition behavior of a macro scale as a substance capable of blocking the emission of non-combustible gases or combustible gases and oxygen. For example, there is a phosphorus compound inhibiting the decomposition reaction through formation of char in the solid phase reaction with a halogenated compound inhibiting the generation of highly reactive radicals in a gas phase reaction. Second, as a method of reducing the heat of combustion, it is related to the combustion stage of the macro scale. For example, there is a phosphorus compound which inhibits the decomposition reaction through the formation of char. Third, there is a filler, glass fiber reinforced and phosphorous compounds related to decomposition of the macro scale by maintaining the physical shape of the material through oxygen and heat shielding. Fourth, as a method of increasing the specific heat or the thermal conductivity of a substance, there is a related method of heating the macro scale. (2) Al (OH) 3 or Ma (OH) 2 blocks combustion by generating water during combustion, and (3) phosphorus or boron compound ④ Halogen compounds take the heat of vaporization during combustion and cool the combustion process. In the case of (1), the physical strength is lowered. In case (2), aluminum hydroxide is used in a large amount and has a disadvantage of decomposing at a temperature of less than 200 ° C., and in cases (3) and (4), harmful substances such as dioxin are generated. As a flame retardant substance that can overcome the regulated boron and halogen system, chlorinated material and salt and sea water as its kind and white carbon as an additional flame retardant (conduction) were also possible. However, in the case of products requiring a black system, the addition of conductive carbon may provide better results in terms of antistatic properties. Ⓐ Carbon: By using the theory that phosphorus flame retardant plays a role of flame retardant by charcoal formation and oxygen blockage when burning, it can be flame retarded if it is coated with charcoal (carbon, charcoal) to cover polymer material, and carbon can also act as deodorant . The problem is that black carbon can be used in fields limited to color problems, but white carbon is also available and can be used in various fields. Ⓑ If the heat transfer rate is good, if the heat received locally is dispersed within a short time, the flame retardancy will be good. Since synergistic effect of flame retardancy combined with ⓐ, thermal conductivity and electric conductivity are in a proportional relation, synergy effect was obtained by the action of ⓐ and ⓑ when using the carbon shown in (a) as conductive carbon. Ⓒ Na-based or Ca-based materials, this is the Kyushu Institute of Technology, which analyzes the composition of the oxide film by photoelectron spectroscopy and confirms the coating of calcium oxide that can not be observed with an electron microscope. The mechanism of the temperature rise. And ⓓ NaCl is not harmful, but salt containing magnesium ion or calcium ion is harmful. This is why the seawater polymer material has superior antistatic performance. It is a chlorinated material such as calcium chloride or magnesium chloride and is a kind of chlorinating material. However, it is an electrolytic substance due to abundant minerals such as sun-salt, etc., and can have flame retardancy, flame retardancy, electrical resistance, and antistatic function . In addition, static electricity can cause electrical disturbance and shock by adsorbing fine dust in the air or by an instantaneous discharge. The electric field of electromagnetic waves has many effects such as aging of the skin due to heat. However, the flammable substance, , Conductive carbon, etc. However, the antistatic performance is further improved when a small amount of the conductive polymer is mixed with the adhesive. Hereinafter, improvement of the conventional problems through the present invention will be described. Example 1, Korean Patent Application No. 10-2006-0019024 discloses that when calcium chloride is used, due to the high water absorption property of calcium chloride, when exposed to a high humidity environment, the humidity is generated on the surface of the coated surface, You can bring it. This is because calcium chloride melts 74.5 g of calcium chloride in 100 g of water at 20 캜 and is highly deliquescent. In order to overcome this problem, the present invention provides the following solutions. In the case of using calcium chloride alone or in combination, if the composition is adjusted so as not to exceed 30% by weight of the total composition on the basis of the use of an aqueous solution of calcium chloride which is theoretically dissolved to the maximum, that is, if the total amount of calcium chloride is not more than 12.808 g So that the antistatic function is exhibited while exhibiting the flame retardant function. However, in consideration of the wet environment due to the climatic change, the weight ratio of the entire composition, in particular calcium chloride (commercially available anhydrous CaCl 2 ₂ In CaCl ₂₂ O) is preferably 0.5 to 18% by weight. When it is used together with sodium chloride, when the ratio of sodium chloride to calcium chloride in the above composition is 1: 0.5 to 10, the antimicrobial function by sodium chloride, the antistatic function in part, the antistatic function by calcium chloride and the flame retarding function are further promoted . The results of flame retardance and flame resistance are shown in FIG. 2, and FIG. 3 shows test conditions of the flame retardant and flame retardancy. As a result of the flame retardancy test for the specimens produced using the flame retardant substance of the present invention, the nitrogen-phosphorus flame retardant agent was found to have V-0 grade flame retardancy when it was over 40% The V-0 grade flame retardancy was secured only at 60% or more, and the amount of the flame retardant was larger than that of other flame retardants. The halogen-based flame retardant exhibited the flame retardancy of the V-0 grade with the content of 20%, but the flame retardancy was the best, but the toxic gas of black was generated and the odor of the Br compound was found. Also, flame retardant specimens prepared using nitrogen-phosphorus and inorganic flame retardant did not show dripping phenomenon when heating for 2 minutes continuously without turning off time check, but dripping occurred when using halogen flame retardant. However, in the present invention, as compared with the adhesive material prepared by adding 8 wt% of calcium chloride to 20 wt% of PVA and 5 wt% of salt (sun salt) in addition to the above compositions, Was better than the other flame retardant specimens. The inventors of the present invention discovered the possibility of exhibiting similar functions to those of the conventional flame retardants through physical and chemical considerations among the additive materials used for the purpose of exhibiting the flame retardancy which is the main inventive function of the present invention and further conducted an environmental risk test. (220mm × thickness (max. 15mm)) was fabricated based on UL-94 (V-0, V-1 standard) for export. The gas toxicity test, which is an objective evaluation index for environmental risk, was conducted with the multifunctional adhesive and coating material using the environmentally friendly flame retardant material of the present invention. As shown in FIG. 4, the weight loss of the test pieces after the test was 2.3 g and 2.5 g, respectively, and the mouse downtime was also measured at a value higher than 9 sec, which is the judgment standard. . Example 2 The Korean Patent No. 10-0591003 proposes a problem that long-term adhesion force is generated. There is a disadvantage in that the adsorbed water drops easily because it is adsorbed on the surface of the hygroscopic member. For this purpose, resins, solutions or primers, emulsions, copolymers and starch, additives of 0 ~ 20% of acrylic, epoxy, polyvinyl alcohol, polyvinyl acetate, silicone, polyurethane, ethylenevinyl acetate and vinyl acetate monomers with solids content of 1.0 ~ 99.0 wt% Two or more of them were used in an amount of 1 to 99% by weight to solve the adhesive force. When the adhesive strength is 1 to 99% by weight, preferably 0.5 to 18% by weight, depending on the content of the flame retardant, the adhesive strength is 8 to 500 N / 25 mm. Example 3 Black conductive carbon black compensated for color shortcomings through conductive polymers PEDOT and white carbon. The same theory can be applied to white carbon by using conductive carbon black when black products are required (to be used). - The flame retardant property through the formation of line char in the flame retardancy theory and the antistatic performance by conductivity are doubled. In Example 4 and Example 1, a multi-functional adhesive and a flame-retardant adhesive were first applied on one side or both sides of a substrate (product) using a flame retardant substance, a salt and a conductive carbon black coating layer, The coating material is first coated, and 0.01 to 500 탆 of a non-aqueous oily, varnish and heat-resistant adhesive paint is applied to one side of the adhesive composition and the adhesive used for the composition, Coatings such as oil-based adhesives, varnishes, and heat-resistant adhesive coatings are required to be applied to furniture, curtains, and verticals where the functional parts pursued by the present invention can be protected or directly exposed. Hereinafter, the present invention will be described in detail in consideration of a material for functional properties. The ingredients and efficacy for the main functional material are as follows. As the adhesive material giving the adhesive strength firstly; Emulsion, copolymer, thermosoftening plastic, thermosetting plastic, starch, additives 0 ~ 20% of acrylic resin, epoxy, polyvinyl alcohol, polyvinyl acetate, silicone, polyurethane, ethylenevinyl acetate, By weight or from 1 to 99% by weight of at least two kinds of flame retardants; (MgCl 2) belonging to the metal chloride, of anhydrous to hydrolyzed nH 2 O (n = 0 to 99) with a solid content of 1 to 99 wt% ₂ , CaCl ₂ , ZnCl ₂ , NH ₄ Cl, Nature &lt; RTI ID = 0.0 &gt; NaCl, KCl, LiCl, ₄ , K ₂ SO ₄ , (NH ₄ ) ₂ SO ₄ Such as NaOH and KOH belonging to the hydroxyl group, such as aSO ₄ , K ₂ SO ₄ , (NH ₄ ) ₂ SO ₄ And 1 to 99% by weight of at least two kinds thereof are used as the antistatic and electric field attenuating material; 1 to 99% by weight of solid salt used in the present invention is used as edible salt and chemical used as a main component of sodium chloride, and on the other hand, 1 to 99% by weight of direct sea water is used. It has excellent electrical insulation properties as well as excellent ability to inhibit various bacteria and fungi. It has excellent flame retardancy and is used in major regions such as East Sea, West Sea, South Sea, Pacific Ocean, Atlantic Ocean, Indian Ocean and Dead Sea. And materials capable of exhibiting antistatic function The flame retardant listed above exhibits not only flame retardancy but also antistatic performance, and antistatic properties are improved when PEDOT, a conductive polymer is added. This is because the flame-retardant materials have a surface resistance enough to exhibit antistatic performance as a functional material. Usually, the surface resistance varies depending on the exposure environment, but it has a surface resistance of 101 to 109 Ω / □, a salt of 103 to 1012 Ω / □, and a conductive polymer of 102 to 107 Ω / □. Therefore, electromagnetic wave shielding performance was also exhibited depending on the environment. The results of one of them are shown in Fig. The solvent may be selected from the group consisting of methanol, ethanol, butanol, dichloromethane, ethylacetate, hexane, diethylehter, acetonitrile, benznene, dibasic ester, 1-METHOXY-2-PROPANOL, BC, Diethylene Glycol Monoethyl Ether Acetate, 0.1 to 99.9% by weight, and the mixture is passed through three roll mills 1 to 5 passes through a high pressure disperser, a high shear mixer (inline mixer, homomixer), a preliminary mixer (stirrer), a ball mill, , A homogenizer, a (Impeller) high-speed stirrer, a paste mixer, a confetti mixer, a mixer and a stirrer which are commonly used, or two or more of them. 20% by weight of the polymer, 20% by weight of the adhesive, 20% by weight of the solid content, 10% by weight of the flame retardant, 20% by weight of the solid, 5% by weight of the salt and 20% by weight of water. The degree of attenuation of the electric field before and after the treatment (construction) was measured. Under the condition shown in FIG. 6, the PULSE E-tester measurement value was 575 V / m before the construction, and it was confirmed that the internal construction was 0 V / m after the construction. According to the results of the antibacterial test for antibacterial activity, which is another object of the present invention, antibacterial activity was measured by KS K 0693-95. Salt, which is the main ingredient of the present invention, does not give a chance to propagate germs, bacteria or microorganisms, and has a constant property even after a long period of time. As such, the salt (salt) (the present invention) is beneficial to the human body, although it has a similar antibacterial activity to a bactericide as described above. Further, in the experiments of the present invention, the bacterial solution was shake cultured at 25 DEG C for 24 hours, and then the number of bacteria was measured (the number of times of progression was 150 times / minute). Shake Flask method was used for measurement, Escherichia coli ATCC25922 Respectively. The present invention is applied to a multi-functional adhesive and coating material using an environmentally friendly flame retardant material, and it is applicable to a flooring adhesive, a paint for a coating, a furniture or a partition that a desk or a desk is vulnerable to fire, a curtain and a vertical blind requiring flame resistance, Flooring materials such as PVC wallpaper and floor coverings, and garments are manufactured by coating the front surface and the back surface, especially for the garment for the fire protection. In order to prevent the exposure of the hygroscopic coating film, as described above, the coating layer composed of the flame retardant material, salt, and conductive carbon black used in the present invention is applied to the surface of the substrate (product) Resistant adhesiveness and coating material using an environmentally friendly flame retardant material and applying the composition adhesive material and the composition used in the composition to the adhesive material listed in the present invention, 500 탆, it is possible to protect the functional parts pursued by the present invention by coating one side or both sides thereof or to apply it to furniture, curtains, and verticals where direct exposure should be prevented. In this case, oily adhesives, varnishes, heat- Lt; / RTI &gt; Polymer material; Emulsion, copolymer, thermosoftening plastic, thermosetting plastic, starch, additives 0 ~ 20% of acrylic resin, epoxy, polyvinyl alcohol, polyvinyl acetate, silicone, polyurethane, ethylenevinyl acetate, By weight, or 1 to 99% by weight, based on the total weight of the composition. These aqueous solutions of sodium chloride, which is the main component of sodium chloride, and sodium chloride used as chemicals are dissolved in 0.1 to 39.8 g of water in 100 g of water, or 0.1 to 39.8 g of salted 0.1 in water collected from East Sea, West Sea, South Sea, Pacific Ocean, Atlantic Ocean, Indian Ocean, Or 34.0% by weight or a salt content of 0.01 to 99% by weight, or 1.0 to 99.5% by weight of a mixture of two or more of them, or an average size of 0.01 to 25 μm; and the iron powder, the copper powder, the cobalt powder and the tin powder , Aluminum powder, Magnesium powder, Titanium powder, Silicon powder, Nickel powder, Zinc powder, Manganese powder. Silver ferrite such as silver powder, Ag coated Cu, Ni coated Cu, Indium tin oxide, Free lead Tin-Bismuth, Silver chloride, Antimony tin oxide, Conductive carbon) powder and 1.0 to 80.0% by weight of solids, and 1.0 to 97.5% by weight of conductive carbon sols and 0.01-20 [mu] m of loess, respectively, or a mixture of two or more thereof, or using these carboxylic acids and fatty acids and silane Or 0.5 to 85.0% by weight of surface-modified metal material, or calcium chloride is used in an amount of not more than 30% by weight of calcium chloride in the total composition ratio, or a mixture of two or more of the above substances, dichloromethane, ethylacetate, hexane, diethylehter, acetonitrile, benzene, Dibasic ester, 1-METHOXY-2-PROPANOL, BC, Diethylene Glycol Monoethyl Ether Acetate, alcohol, H ₂ O and the like may be used alone or in combination of 0.1 to 99.9% by weight of two or more kinds and mixed with a high pressure disperser, a high shear mixer (inline mixer, a homomixer), a preliminary mixer (Impeller) high-speed stirrer, paste mixer, pre-mixer, mixer and stirrer which are conventionally used, or by using two or more kinds of them. (Flooring, curtains, liquid coatings, liquid adhesives, etc.) which can be well burned and applied to the fire fighting law, Applicable products such as; Polymer material; Emulsion, copolymer, thermosoftening plastic, thermosetting plastic, starch, additives 0 ~ 20% of acrylic resin, epoxy, polyvinyl alcohol, polyvinyl acetate, silicone, polyurethane, ethylenevinyl acetate, By weight, or 1 to 99% by weight, based on the total weight of the composition. These aqueous solutions of sodium chloride, which is the main component of sodium chloride, and sodium chloride used as chemicals are dissolved in 0.1 to 39.8 g of water in 100 g of water, or 0.1 to 39.8 g of salted 0.1 in water collected from East Sea, West Sea, South Sea, Pacific Ocean, Atlantic Ocean, Indian Ocean, Or 34.0% by weight or a salt content of 0.01 to 99% by weight, or 1.0 to 99.5% by weight of a mixture of two or more of them, or an average size of 0.01 to 25 μm; and the iron powder, the copper powder, the cobalt powder and the tin powder , Aluminum powder, Magnesium powder, Titanium powder, Silicon powder, Nickel powder, Zinc powder, Manganese powder. Silver ferrite such as silver powder, Ag coated Cu, Ni coated Cu, Indium tin oxide, Free lead Tin-Bismuth, Silver chloride, Antimony tin oxide, Conductive carbon) powder and 1.0 to 80.0% by weight of solids, and 1.0 to 97.5% by weight of conductive carbon sols and 0.01-20 [mu] m of loess, respectively, or a mixture of two or more thereof, or using these carboxylic acids and fatty acids and silane Or 0.5 to 85.0% by weight of surface-modified metal material, or calcium chloride is used in an amount of not more than 30% by weight of calcium chloride in the total composition ratio, or a mixture of two or more of the above substances, dichloromethane, ethylacetate, hexane, diethylehter, acetonitrile, benzene, Dibasic ester, 1-METHOXY-2-PROPANOL, BC, Diethylene Glycol Monoethyl Ether Acetate, alcohol, H ₂ O and the like may be used alone or in combination of 0.1 to 99.9% by weight of two or more kinds and mixed with a high pressure disperser, a high shear mixer (inline mixer, a homomixer), a preliminary mixer A mixer and a stirrer which are conventionally used, such as a ball mill, a homo disperse, a homogenizer, a (Impeller) high speed stirrer, a paste mixer, a confinement mixer, , A sterilizing agent, a flame retarding function, a far-infrared radiation function, a process for producing the same, and a product therefor.

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