KR102552227B1 - 개선된 특성을 갖는 폴리(비닐 아세탈) 수지 조성물, 층, 및 중간층 - Google Patents
개선된 특성을 갖는 폴리(비닐 아세탈) 수지 조성물, 층, 및 중간층 Download PDFInfo
- Publication number
- KR102552227B1 KR102552227B1 KR1020177018849A KR20177018849A KR102552227B1 KR 102552227 B1 KR102552227 B1 KR 102552227B1 KR 1020177018849 A KR1020177018849 A KR 1020177018849A KR 20177018849 A KR20177018849 A KR 20177018849A KR 102552227 B1 KR102552227 B1 KR 102552227B1
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- South Korea
- Prior art keywords
- resin
- poly
- vinyl acetal
- less
- layer
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- 229920002554 vinyl polymer Polymers 0.000 title claims abstract description 317
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 title claims abstract description 308
- 239000010410 layer Substances 0.000 title claims abstract description 265
- 229920006324 polyoxymethylene Polymers 0.000 title claims abstract description 248
- 239000011229 interlayer Substances 0.000 title claims abstract description 120
- 239000011342 resin composition Substances 0.000 title abstract description 38
- ZTQSAGDEMFDKMZ-UHFFFAOYSA-N Butyraldehyde Chemical compound CCCC=O ZTQSAGDEMFDKMZ-UHFFFAOYSA-N 0.000 claims abstract description 159
- 150000001299 aldehydes Chemical group 0.000 claims abstract description 117
- 229920002037 poly(vinyl butyral) polymer Polymers 0.000 claims abstract description 73
- 230000000052 comparative effect Effects 0.000 claims abstract description 35
- 229920005989 resin Polymers 0.000 claims description 310
- 239000011347 resin Substances 0.000 claims description 310
- 239000004014 plasticizer Substances 0.000 claims description 127
- 230000009477 glass transition Effects 0.000 claims description 90
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims description 76
- -1 5% by weight or more Chemical compound 0.000 claims description 38
- 238000000034 method Methods 0.000 claims description 25
- AMIMRNSIRUDHCM-UHFFFAOYSA-N Isopropylaldehyde Chemical group CC(C)C=O AMIMRNSIRUDHCM-UHFFFAOYSA-N 0.000 claims description 21
- 239000000758 substrate Substances 0.000 claims description 17
- 125000004432 carbon atom Chemical group C* 0.000 claims description 14
- DHKHKXVYLBGOIT-UHFFFAOYSA-N acetaldehyde Diethyl Acetal Natural products CCOC(C)OCC DHKHKXVYLBGOIT-UHFFFAOYSA-N 0.000 claims description 13
- FRQDZJMEHSJOPU-UHFFFAOYSA-N Triethylene glycol bis(2-ethylhexanoate) Chemical compound CCCCC(CC)C(=O)OCCOCCOCCOC(=O)C(CC)CCCC FRQDZJMEHSJOPU-UHFFFAOYSA-N 0.000 claims description 7
- GYHPTPQZVBYHLC-UHFFFAOYSA-N 2-[2-[2-[2-(2-ethylhexanoyloxy)ethoxy]ethoxy]ethoxy]ethyl 2-ethylhexanoate Chemical compound CCCCC(CC)C(=O)OCCOCCOCCOCCOC(=O)C(CC)CCCC GYHPTPQZVBYHLC-UHFFFAOYSA-N 0.000 claims description 5
- 239000000203 mixture Substances 0.000 abstract description 55
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- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 9
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- FTZILAQGHINQQR-UHFFFAOYSA-N 2-Methylpentanal Chemical compound CCCC(C)C=O FTZILAQGHINQQR-UHFFFAOYSA-N 0.000 description 4
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- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 3
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- 239000001893 (2R)-2-methylbutanal Substances 0.000 description 2
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- JEYLQCXBYFQJRO-UHFFFAOYSA-N 2-[2-[2-(2-ethylbutanoyloxy)ethoxy]ethoxy]ethyl 2-ethylbutanoate Chemical compound CCC(CC)C(=O)OCCOCCOCCOC(=O)C(CC)CC JEYLQCXBYFQJRO-UHFFFAOYSA-N 0.000 description 1
- SSKNCQWPZQCABD-UHFFFAOYSA-N 2-[2-[2-(2-heptanoyloxyethoxy)ethoxy]ethoxy]ethyl heptanoate Chemical compound CCCCCCC(=O)OCCOCCOCCOCCOC(=O)CCCCCC SSKNCQWPZQCABD-UHFFFAOYSA-N 0.000 description 1
- GPZYYYGYCRFPBU-UHFFFAOYSA-N 6-Hydroxyflavone Chemical compound C=1C(=O)C2=CC(O)=CC=C2OC=1C1=CC=CC=C1 GPZYYYGYCRFPBU-UHFFFAOYSA-N 0.000 description 1
- SXKCDRRSQHPBOI-UHFFFAOYSA-N 6-o-cyclohexyl 1-o-hexyl hexanedioate Chemical compound CCCCCCOC(=O)CCCCC(=O)OC1CCCCC1 SXKCDRRSQHPBOI-UHFFFAOYSA-N 0.000 description 1
- 229920001634 Copolyester Polymers 0.000 description 1
- PYGXAGIECVVIOZ-UHFFFAOYSA-N Dibutyl decanedioate Chemical compound CCCCOC(=O)CCCCCCCCC(=O)OCCCC PYGXAGIECVVIOZ-UHFFFAOYSA-N 0.000 description 1
- 239000004609 Impact Modifier Substances 0.000 description 1
- 239000006057 Non-nutritive feed additive Substances 0.000 description 1
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- VMHLLURERBWHNL-UHFFFAOYSA-M Sodium acetate Chemical compound [Na+].CC([O-])=O VMHLLURERBWHNL-UHFFFAOYSA-M 0.000 description 1
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- 125000004036 acetal group Chemical group 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 1
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- 150000001558 benzoic acid derivatives Chemical class 0.000 description 1
- IHTSDBYPAZEUOP-UHFFFAOYSA-N bis(2-butoxyethyl) hexanedioate Chemical compound CCCCOCCOC(=O)CCCCC(=O)OCCOCCCC IHTSDBYPAZEUOP-UHFFFAOYSA-N 0.000 description 1
- ZFMQKOWCDKKBIF-UHFFFAOYSA-N bis(3,5-difluorophenyl)phosphane Chemical compound FC1=CC(F)=CC(PC=2C=C(F)C=C(F)C=2)=C1 ZFMQKOWCDKKBIF-UHFFFAOYSA-N 0.000 description 1
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- 238000007664 blowing Methods 0.000 description 1
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- VPXSRGLTQINCRV-UHFFFAOYSA-N dicesium;dioxido(dioxo)tungsten Chemical compound [Cs+].[Cs+].[O-][W]([O-])(=O)=O VPXSRGLTQINCRV-UHFFFAOYSA-N 0.000 description 1
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- OEIWPNWSDYFMIL-UHFFFAOYSA-N dioctyl benzene-1,4-dicarboxylate Chemical compound CCCCCCCCOC(=O)C1=CC=C(C(=O)OCCCCCCCC)C=C1 OEIWPNWSDYFMIL-UHFFFAOYSA-N 0.000 description 1
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- AMGQUBHHOARCQH-UHFFFAOYSA-N indium;oxotin Chemical compound [In].[Sn]=O AMGQUBHHOARCQH-UHFFFAOYSA-N 0.000 description 1
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Images
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- B32B37/18—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by the properties of the layers with all layers existing as coherent layers before laminating involving the assembly of discrete sheets or panels only
- B32B37/182—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by the properties of the layers with all layers existing as coherent layers before laminating involving the assembly of discrete sheets or panels only one or more of the layers being plastic
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| US14/563,014 US9669605B2 (en) | 2014-12-08 | 2014-12-08 | Poly(vinyl acetal) resin compositions, layers and interlayers having enhanced properties |
| US14/562,865 | 2014-12-08 | ||
| US14/563,077 | 2014-12-08 | ||
| US14/562,865 US9724899B2 (en) | 2014-12-08 | 2014-12-08 | Poly(vinyl acetal) resin compositions, layers and interlayers having enhanced properties |
| US14/563,014 | 2014-12-08 | ||
| US14/563,077 US9926431B2 (en) | 2014-12-08 | 2014-12-08 | Poly(vinyl acetal) resin compositions, layers and interlayers having enhanced properties |
| PCT/US2015/063897 WO2016094216A1 (en) | 2014-12-08 | 2015-12-04 | Poly(vinyl acetal) resin compositions, layers and interlayers having enhanced properties |
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| US11220562B2 (en) * | 2017-10-10 | 2022-01-11 | Solutia Inc. | Poly(vinyl acetal) resin compositions, layers, and interlayers having enhanced properties |
| US20190106561A1 (en) * | 2017-10-10 | 2019-04-11 | Solutia Inc. | Poly(vinyl acetal) resin compositions, layers, and interlayers having enhanced properties |
| US10717862B2 (en) * | 2018-07-11 | 2020-07-21 | Solutia Inc. | Poly(vinyl acetal) resin compositions, layers, and interlayers having enhanced properties |
| US20230182448A1 (en) * | 2021-12-10 | 2023-06-15 | Chang Chun Petrochemical Co., Ltd. | Polymer film |
| CN115821084B (zh) * | 2022-11-09 | 2024-01-26 | 安徽铜冠产业技术研究院有限责任公司 | 一种低沸点金属铜基中间合金制备方法及设备 |
| US12291006B2 (en) * | 2023-09-19 | 2025-05-06 | Chang Chun Petrochemical Co., Ltd. | Polymer film and uses of the same |
| TW202532466A (zh) * | 2023-11-17 | 2025-08-16 | 日商積水化學工業股份有限公司 | 聚乙烯縮醛樹脂、導電膏及積層陶瓷電容器 |
| WO2025105458A1 (ja) * | 2023-11-17 | 2025-05-22 | 積水化学工業株式会社 | ポリビニルアセタール樹脂及び該ポリビニルアセタール樹脂を用いた電極用組成物 |
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| JP3050967B2 (ja) * | 1991-10-16 | 2000-06-12 | 積水化学工業株式会社 | 遮音性中間膜 |
| US5290660A (en) * | 1993-04-23 | 1994-03-01 | Minnesota Mining And Manufacturing Company | Dye permeable polymer interlayers |
| US5593786A (en) * | 1994-11-09 | 1997-01-14 | Libbey-Owens-Ford Company | Self-adhering polyvinyl chloride safety glass interlayer |
| US7846532B2 (en) * | 2005-03-17 | 2010-12-07 | Solutia Incorporated | Sound reducing wedge shaped polymer interlayers |
| US20080268270A1 (en) * | 2007-04-30 | 2008-10-30 | Wenjie Chen | High impact polymer interlayers |
| JP2010235432A (ja) * | 2008-07-01 | 2010-10-21 | Sekisui Chem Co Ltd | 合わせガラス用中間膜、及び、合わせガラス |
| EP2153989B1 (de) * | 2008-08-01 | 2021-09-29 | Kuraray Europe GmbH | Mehrschichtfolien aus weichmacherhaltigem Polyvinylacetal mit schalldämpfenden Eigenschaften |
| CN102164872B (zh) * | 2008-09-30 | 2014-04-02 | 积水化学工业株式会社 | 夹层玻璃用中间膜及夹层玻璃 |
| KR101624010B1 (ko) * | 2009-12-25 | 2016-05-24 | 세키스이가가쿠 고교가부시키가이샤 | 합판 유리용 중간막, 합판 유리용 다층 중간막 및 합판 유리 |
| EP2607390B1 (en) * | 2010-08-19 | 2016-06-22 | Kuraray Co., Ltd. | Polyvinyl acetal resin, slurry composition prepared therefrom, ceramic green sheet, and multilayer ceramic capacitor |
| US9649828B2 (en) * | 2010-09-30 | 2017-05-16 | Sekisui Chemical Co., Ltd. | Interlayer for laminated glass and laminated glass |
| CN103140451B (zh) * | 2010-09-30 | 2015-08-05 | 积水化学工业株式会社 | 夹层玻璃用中间膜及夹层玻璃 |
| US8883317B2 (en) * | 2010-09-30 | 2014-11-11 | Sekisui Chemical Co., Ltd. | Intermediate film for laminated glass and laminated glass |
| CN103140450B (zh) * | 2010-09-30 | 2016-07-06 | 积水化学工业株式会社 | 夹层玻璃用中间膜及夹层玻璃 |
| JP5064606B2 (ja) * | 2011-02-10 | 2012-10-31 | 積水化学工業株式会社 | 合わせガラス用中間膜及び合わせガラス |
| EP2548729A1 (de) * | 2011-07-22 | 2013-01-23 | Kuraray Europe GmbH | Folien aus weichmacherhaltigem Polyvinyl(iso)acetal |
| EP2548727A1 (de) * | 2011-07-22 | 2013-01-23 | Kuraray Europe GmbH | Hochfeste Folienlaminate mit Schichten von weichmacherhaltigem Polyvinyl(n)acetal und weichmacherhaltigem Polyvinyl(iso)acetal |
| CN103796967A (zh) * | 2011-09-21 | 2014-05-14 | 积水化学工业株式会社 | 夹层玻璃用中间膜及夹层玻璃 |
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| KR100809198B1 (ko) * | 2001-01-09 | 2008-02-29 | 쿠라라이 유럽 게엠베하 | 가소화된 폴리비닐 부티랄, 그의 제조방법 및 적층 안전유리에 사용될 필름 제조를 위한 그의 용도 |
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| EP3230378A1 (en) | 2017-10-18 |
| JP2018501125A (ja) | 2018-01-18 |
| MX2017006011A (es) | 2017-08-25 |
| CN107000390B (zh) | 2020-07-17 |
| JP6719464B2 (ja) | 2020-07-08 |
| KR20170093930A (ko) | 2017-08-16 |
| EP3230378A4 (en) | 2018-08-15 |
| WO2016094216A1 (en) | 2016-06-16 |
| CN107000390A (zh) | 2017-08-01 |
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