KR102339484B1 - 탄화수소 공급원료로부터 경질 올레핀 및 방향족 화합물의 생산을 위한 공정 - Google Patents
탄화수소 공급원료로부터 경질 올레핀 및 방향족 화합물의 생산을 위한 공정 Download PDFInfo
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- KR102339484B1 KR102339484B1 KR1020167002651A KR20167002651A KR102339484B1 KR 102339484 B1 KR102339484 B1 KR 102339484B1 KR 1020167002651 A KR1020167002651 A KR 1020167002651A KR 20167002651 A KR20167002651 A KR 20167002651A KR 102339484 B1 KR102339484 B1 KR 102339484B1
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Images
Classifications
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G69/00—Treatment of hydrocarbon oils by at least one hydrotreatment process and at least one other conversion process
- C10G69/02—Treatment of hydrocarbon oils by at least one hydrotreatment process and at least one other conversion process plural serial stages only
- C10G69/06—Treatment of hydrocarbon oils by at least one hydrotreatment process and at least one other conversion process plural serial stages only including at least one step of thermal cracking in the absence of hydrogen
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G65/00—Treatment of hydrocarbon oils by two or more hydrotreatment processes only
- C10G65/02—Treatment of hydrocarbon oils by two or more hydrotreatment processes only plural serial stages only
- C10G65/10—Treatment of hydrocarbon oils by two or more hydrotreatment processes only plural serial stages only including only cracking steps
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G67/00—Treatment of hydrocarbon oils by at least one hydrotreatment process and at least one process for refining in the absence of hydrogen only
- C10G67/02—Treatment of hydrocarbon oils by at least one hydrotreatment process and at least one process for refining in the absence of hydrogen only plural serial stages only
- C10G67/04—Treatment of hydrocarbon oils by at least one hydrotreatment process and at least one process for refining in the absence of hydrogen only plural serial stages only including solvent extraction as the refining step in the absence of hydrogen
- C10G67/0409—Extraction of unsaturated hydrocarbons
- C10G67/0445—The hydrotreatment being a hydrocracking
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G69/00—Treatment of hydrocarbon oils by at least one hydrotreatment process and at least one other conversion process
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
- C10G2300/10—Feedstock materials
- C10G2300/1037—Hydrocarbon fractions
- C10G2300/1044—Heavy gasoline or naphtha having a boiling range of about 100 - 180 °C
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
- C10G2300/10—Feedstock materials
- C10G2300/1037—Hydrocarbon fractions
- C10G2300/1048—Middle distillates
- C10G2300/1059—Gasoil having a boiling range of about 330 - 427 °C
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G2400/00—Products obtained by processes covered by groups C10G9/00 - C10G69/14
- C10G2400/20—C2-C4 olefins
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G2400/00—Products obtained by processes covered by groups C10G9/00 - C10G69/14
- C10G2400/30—Aromatics
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P30/00—Technologies relating to oil refining and petrochemical industry
- Y02P30/40—Ethylene production
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- Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Physics & Mathematics (AREA)
- Thermal Sciences (AREA)
- Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
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| EP13174767 | 2013-07-02 | ||
| EP13174767.7 | 2013-07-02 | ||
| PCT/EP2014/063851 WO2015000843A1 (en) | 2013-07-02 | 2014-06-30 | Process for the production of light olefins and aromatics from a hydrocarbon feedstock. |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| KR20160029812A KR20160029812A (ko) | 2016-03-15 |
| KR102339484B1 true KR102339484B1 (ko) | 2021-12-16 |
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| US (1) | US10465131B2 (enExample) |
| EP (1) | EP3017028B1 (enExample) |
| JP (1) | JP6360553B2 (enExample) |
| KR (1) | KR102339484B1 (enExample) |
| CN (1) | CN105473691B (enExample) |
| EA (1) | EA032112B1 (enExample) |
| ES (1) | ES2671994T3 (enExample) |
| SG (1) | SG11201509589RA (enExample) |
| WO (1) | WO2015000843A1 (enExample) |
Families Citing this family (16)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2015128036A1 (en) * | 2014-02-25 | 2015-09-03 | Saudi Basic Industries Corporation | Process for upgrading refinery heavy hydrocarbons to petrochemicals |
| ES2807525T3 (es) * | 2015-11-30 | 2021-02-23 | Sabic Global Technologies Bv | Procedimiento de producción de materia prima de alta calidad para un proceso de craqueo con vapor |
| US10941360B2 (en) | 2016-09-21 | 2021-03-09 | Hindustan Petroleum Corporation Limited | Process for conversion of hydrocarbons |
| US10472579B2 (en) * | 2016-11-21 | 2019-11-12 | Saudi Arabian Oil Company | Process and system for conversion of crude oil to petrochemicals and fuel products integrating vacuum gas oil hydrocracking and steam cracking |
| US10899979B2 (en) | 2017-08-15 | 2021-01-26 | Sabic Global Technologies, B.V. | Light olefin production via an integrated steam cracking and hydrocracking process |
| US11390572B2 (en) * | 2018-09-20 | 2022-07-19 | Sabic Global Technologies B.V. | Process for producing light olefins (ethylene + propylene) and BTX using a mixed paraffinic C4 feed |
| US10513664B1 (en) * | 2018-12-17 | 2019-12-24 | Saudi Arabian Oil Company | Integrated aromatic separation process with selective hydrocracking and steam pyrolysis processes |
| EP3918033A1 (en) | 2019-01-29 | 2021-12-08 | SABIC Global Technologies B.V. | Methods and systems for upgrading crude oils, heavy oils, and residues |
| US11827857B2 (en) | 2019-01-29 | 2023-11-28 | Sabic Global Technologies B.V. | Conversion of heavy ends of crude oil or whole crude oil to high value chemicals using a combination of thermal hydroprocessing, hydrotreating with steam crackers under high severity conditions to maximize ethylene, propylene, butenes and benzene |
| WO2021019326A1 (en) * | 2019-07-31 | 2021-02-04 | Sabic Global Technologies B.V. | Naphtha catalytic cracking process |
| US11046899B2 (en) | 2019-10-03 | 2021-06-29 | Saudi Arabian Oil Company | Two stage hydrodearylation systems and processes to convert heavy aromatics into gasoline blending components and chemical grade aromatics |
| CN114599629B (zh) * | 2019-10-24 | 2025-09-23 | 托普索公司 | 具有改进的选择性的将轻质烷烃转化为芳族化合物的方法 |
| RU2751701C1 (ru) * | 2020-11-27 | 2021-07-15 | Федеральное государственное бюджетное учреждение науки Институт элементоорганических соединений им. А.Н. Несмеянова Российской академии наук (ИНЭОС РАН) | Катализатор дегидрирования пропана и способ получения пропилена с его использованием |
| EP4288513B1 (en) * | 2021-03-01 | 2025-09-17 | Saudi Arabian Oil Company | Integrated process with a depolyaromatization column for the production of benzene, toluene and xylenes from pyrolysis fuel oil stream |
| US11578276B2 (en) * | 2021-07-01 | 2023-02-14 | Saudi Arabian Oil Company | Two stage catalytic process for pyrolysis oil upgrading to BTX |
| CN118440732B (zh) * | 2023-02-03 | 2025-08-01 | 中国石油化工股份有限公司 | 一种煤油两段加氢裂化方法 |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20010052241A1 (en) * | 2000-04-13 | 2001-12-20 | Ipsi Llc | Flexible reflux process for high NGL recovery |
Family Cites Families (38)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3172834A (en) * | 1965-03-09 | Process for manufacturing gasoline by blending the hydrocracked gasoline with the dehydrogenated and alkyl- ated products obtained from the hy- drocracking stage | ||
| US3256176A (en) | 1964-10-21 | 1966-06-14 | Phillips Petroleum Co | Hydrocracking heavy hydrocarbons to gasoline and distillate |
| US3433848A (en) | 1966-08-10 | 1969-03-18 | Texaco Inc | Method of controlling selectivity in an aromatic hydrocarbon dealkylation process |
| BE793036A (fr) * | 1971-12-21 | 1973-04-16 | Pierrefitte Auby Sa | Procede de craquage sous pression d'hydrogene pour la production d'olefines |
| FR2366239A1 (fr) | 1976-10-04 | 1978-04-28 | Inst Francais Du Petrole | Procede de fabrication d'ethylene |
| FR2364879A1 (fr) * | 1976-09-16 | 1978-04-14 | Inst Francais Du Petrole | Procede de fabrication d'hydrocarbures olefiniques a deux et trois atomes de carbone par molecule |
| US4137147A (en) * | 1976-09-16 | 1979-01-30 | Institut Francais Du Petrole | Process for manufacturing olefinic hydrocarbons with respectively two and three carbon atoms per molecule |
| US4181601A (en) * | 1977-06-17 | 1980-01-01 | The Lummus Company | Feed hydrotreating for improved thermal cracking |
| FI852865A7 (fi) | 1984-07-25 | 1986-01-26 | Air Prod & Chem | Parannettu katalyytti hiilivetyjen dehydrausta varten. |
| FI860203A7 (fi) | 1985-01-22 | 1986-07-23 | Air Prod & Chem | Hiilivetyjen dehydroisomerointi. |
| US4789457A (en) | 1985-06-03 | 1988-12-06 | Mobil Oil Corporation | Production of high octane gasoline by hydrocracking catalytic cracking products |
| US4827072A (en) | 1986-06-06 | 1989-05-02 | Uop Inc. | Dehydrogenation catalyst composition and hydrocarbon dehydrogenation process |
| US4926005A (en) | 1989-05-17 | 1990-05-15 | Phillips Petroleum Company | Dehydrogenation process |
| US6270654B1 (en) | 1993-08-18 | 2001-08-07 | Ifp North America, Inc. | Catalytic hydrogenation process utilizing multi-stage ebullated bed reactors |
| US5880325A (en) | 1993-09-07 | 1999-03-09 | Exxon Research And Engineering Company | Aromatics extraction from hydrocarbon oil using tetramethylene sulfoxide |
| FR2764902B1 (fr) | 1997-06-24 | 1999-07-16 | Inst Francais Du Petrole | Procede de conversion de fractions lourdes petrolieres comprenant une etape de conversion en lit bouillonnant et une etape d'hydrocraquage |
| DE19949211A1 (de) | 1999-10-13 | 2001-05-31 | Veba Oel Ag | Verfahren zur Herstellung von n-Alkanen aus Mineralölfraktionen und Katalysator zur Durchführung des Verfahrens |
| KR100557558B1 (ko) | 2000-11-30 | 2006-03-03 | 에스케이 주식회사 | 탄화수소 혼합물로부터 방향족 탄화수소 및 액화석유가스를 제조하는 방법 |
| US7214308B2 (en) | 2003-02-21 | 2007-05-08 | Institut Francais Du Petrole | Effective integration of solvent deasphalting and ebullated-bed processing |
| US20050101814A1 (en) | 2003-11-07 | 2005-05-12 | Foley Timothy D. | Ring opening for increased olefin production |
| KR100710542B1 (ko) * | 2005-06-21 | 2007-04-24 | 에스케이 주식회사 | 탄화수소 원료 혼합물로부터 경질 올레핀계 탄화수소의증산방법 |
| US7622623B2 (en) | 2005-09-02 | 2009-11-24 | Sud-Chemie Inc. | Catalytically inactive heat generator and improved dehydrogenation process |
| CA2541051C (en) | 2005-09-20 | 2013-04-02 | Nova Chemicals Corporation | Aromatic saturation and ring opening process |
| WO2007047657A1 (en) | 2005-10-20 | 2007-04-26 | Exxonmobil Chemical Patents Inc. | Hydrocarbon resid processing |
| KR101234448B1 (ko) | 2005-11-14 | 2013-02-18 | 에스케이이노베이션 주식회사 | 탄화수소 혼합물로부터 방향족 탄화수소 및 액화석유가스를제조하는 공정 |
| US7704377B2 (en) | 2006-03-08 | 2010-04-27 | Institut Francais Du Petrole | Process and installation for conversion of heavy petroleum fractions in a boiling bed with integrated production of middle distillates with a very low sulfur content |
| US20080093262A1 (en) | 2006-10-24 | 2008-04-24 | Andrea Gragnani | Process and installation for conversion of heavy petroleum fractions in a fixed bed with integrated production of middle distillates with a very low sulfur content |
| US7951745B2 (en) | 2008-01-03 | 2011-05-31 | Wilmington Trust Fsb | Catalyst for hydrocracking hydrocarbons containing polynuclear aromatic compounds |
| US7938952B2 (en) | 2008-05-20 | 2011-05-10 | Institute Francais Du Petrole | Process for multistage residue hydroconversion integrated with straight-run and conversion gasoils hydroconversion steps |
| DE102009012265A1 (de) | 2009-03-11 | 2010-09-23 | Uhde Gmbh | Verfahren zur Gewinnung von Reinaromaten aus aromatenhaltigen Kohlenwasserstofffraktionen |
| FR2951735B1 (fr) | 2009-10-23 | 2012-08-03 | Inst Francais Du Petrole | Procede de conversion de residu integrant une technologie lit mobile et une technologie lit bouillonnant |
| US9005430B2 (en) | 2009-12-10 | 2015-04-14 | IFP Energies Nouvelles | Process and apparatus for integration of a high-pressure hydroconversion process and a medium-pressure middle distillate hydrotreatment process, whereby the two processes are independent |
| CN102212394B (zh) * | 2010-04-07 | 2013-11-06 | 中国石油天然气股份有限公司 | 一种含轻汽油醚化工艺的催化裂化汽油改质方法 |
| WO2012135111A2 (en) | 2011-03-31 | 2012-10-04 | Uop Llc | Aromatics recovery by extractive distillation |
| FR2981659B1 (fr) | 2011-10-20 | 2013-11-01 | Ifp Energies Now | Procede de conversion de charges petrolieres comprenant une etape d'hydroconversion en lit bouillonnant et une etape d'hydrotraitement en lit fixe pour la production de fiouls a basse teneur en soufre |
| FR3027912B1 (fr) | 2014-11-04 | 2018-04-27 | IFP Energies Nouvelles | Procede de production de combustibles de type fuel lourd a partir d'une charge hydrocarbonee lourde utilisant une separation entre l'etape d'hydrotraitement et l'etape d'hydrocraquage |
| FR3027911B1 (fr) | 2014-11-04 | 2018-04-27 | IFP Energies Nouvelles | Procede de conversion de charges petrolieres comprenant une etape d'hydrocraquage en lit bouillonnant, une etape de maturation et une etape de separation des sediments pour la production de fiouls a basse teneur en sediments |
| FR3033797B1 (fr) | 2015-03-16 | 2018-12-07 | IFP Energies Nouvelles | Procede ameliore de conversion de charges hydrocarbonees lourdes |
-
2014
- 2014-06-30 CN CN201480037272.7A patent/CN105473691B/zh active Active
- 2014-06-30 US US14/902,068 patent/US10465131B2/en active Active
- 2014-06-30 KR KR1020167002651A patent/KR102339484B1/ko active Active
- 2014-06-30 JP JP2016522561A patent/JP6360553B2/ja not_active Expired - Fee Related
- 2014-06-30 ES ES14733659.8T patent/ES2671994T3/es active Active
- 2014-06-30 SG SG11201509589RA patent/SG11201509589RA/en unknown
- 2014-06-30 EP EP14733659.8A patent/EP3017028B1/en active Active
- 2014-06-30 EA EA201690119A patent/EA032112B1/ru not_active IP Right Cessation
- 2014-06-30 WO PCT/EP2014/063851 patent/WO2015000843A1/en not_active Ceased
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20010052241A1 (en) * | 2000-04-13 | 2001-12-20 | Ipsi Llc | Flexible reflux process for high NGL recovery |
Also Published As
| Publication number | Publication date |
|---|---|
| ES2671994T3 (es) | 2018-06-12 |
| JP6360553B2 (ja) | 2018-07-18 |
| EA032112B1 (ru) | 2019-04-30 |
| EP3017028B1 (en) | 2018-03-21 |
| WO2015000843A1 (en) | 2015-01-08 |
| JP2016523307A (ja) | 2016-08-08 |
| CN105473691B (zh) | 2019-03-15 |
| EP3017028A1 (en) | 2016-05-11 |
| EA201690119A1 (ru) | 2016-06-30 |
| US20170009157A1 (en) | 2017-01-12 |
| US10465131B2 (en) | 2019-11-05 |
| KR20160029812A (ko) | 2016-03-15 |
| SG11201509589RA (en) | 2016-01-28 |
| CN105473691A (zh) | 2016-04-06 |
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