KR102207608B1 - Process for producing silicon ion complexes and complexes organicized with carboxylic acid and products using the same - Google Patents

Abstract

The present invention relates to a technique related to ionization of silicon, and relates to a technique of organically ionizing silicon by using a tricarboxylic acid or a dicarboxylic acid and using a water-soluble silicate.
Due to this technology, it is possible to manufacture, manufacture, and supply products containing an organic silicon ion complex to various fields including food and pharmaceutical products including drinking water and beverages, including electrochemical fields. In particular, it is expected that various diseases due to lack of silicon minerals can be treated and prevented by organically supplying silicon, which does not exist as an ion in nature.

Description

Manufacturing method of silicon ion complexes and complexes organicated with carboxylic acid and products using the same {PROCESS FOR PRODUCING SILICON ION COMPLEXES AND COMPLEXES ORGANICIZED WITH CARBOXYLIC ACID AND PRODUCTS USING THE SAME}

The present invention relates to a silicon ion complex organically formed with a carboxylic acid, a method for preparing the complex, and a product using the same.

Among the elements contained in the human body or food, the generic term for elements excluding oxygen (O), carbon (C), hydrogen (H), and nitrogen (N) is called mineral or mineral. In the past, it was also referred to as ash (灰分). About 96% of the elements contained in the human body are the first 4 elements, and only 4% of the total minerals. Among them, the relatively large amounts are calcium (Ca), phosphorus (P), potassium (K), sulfur (S), sodium (Na), chlorine (Cl), magnesium (Mg), and iron (Fe ), copper (Cu), manganese (Mn), iodine (I), cobalt (Co), zinc (Zn), molybdenum (Mo), selenium (Se), chromium (Cr), fluorine (F), boron (B ), arsenic (As), tin (Sn), silicon (Si), vanadium (V), nickel (Ni), titanium (Ti), zirconium (Zr), and the like.

That is, about 96% of the elements contained in the human body are organic substances consisting of oxygen (O), carbon (C), hydrogen (H), and nitrogen (N), and inorganic substances are only about 4% of the total. 4% is what we call minerals.

The present invention relates to silicon among minerals.

Silicon is one of the minerals necessary for the human body, and is known to play a certain role in forgetfulness, lack of patience, osteoporosis, aging phenomena, activation of metabolism, anti-aging of cells, and treatment, but not all functions have been fully identified.

However, it is not toxic, and according to recent reports, it has been reported that silicon is effective in suppressing cognitive decline in dementia patients after a study at a UK university.

If minerals are easily expressed, minerals that exist in the state of ore are inorganic, and there are about 70 kinds of minerals on the earth.

These inorganic minerals are absorbed by plants by agriculture and combined with amino acids, and minerals in this state are organic matter. Most of the minerals taken by humans are organic minerals that exist after being absorbed from food.

For example, minerals such as selenium are not only not absorbed when ingested as inorganic minerals, but may accumulate and have side effects. Therefore, the inorganic selenium can be absorbed normally only by combining it with amino acids and changing it to an organic state. However, not all minerals do.

Silica is also used in the same way, so it is used in the form of making water-soluble silicon from ore and dissolving it in water and drinking it.

Such water-soluble silicon is made soluble in water in the form of Na ₂ SiO _3, Na ₂ SiO ₃ ㅇ5H ₂ O, Na ₂ SiO ₃ ㅇ9H ₂ O, Na ₂ SiO ₃ ㅇ10H ₂ O, and in some cases phosphorus Compounds containing elements that can be used as minerals such as (P), magnesium (Mg), zinc (Zn) are added, and high-purity silicon dioxide and sodium carbonate are used as the main raw materials at a temperature of 1,500℃ to 2,000℃. It is made in powder form.

That is, using silica as a digestive absorber that can be used by both plants, animals and humans is: (1) providing high-purity silicon oxide as a mineral, and (2) synthesizing the provided silicon oxide with sodium carbonate or sodium hydroxide at high temperature. It has been achieved through a step of reacting to form a water-soluble silicon compound and (3) dissolving the prepared water-soluble silicon compound. However, while reacting with water, the ionic state cannot be maintained continuously, and it takes a colloidal or colloidal form.

This water-soluble silicon has a very high alkalinity and is stable in alkali. (If you look at the phenomenon more, it seems to be stable in alkali, but in reality, it begins to form a fine-sized gel, and finally, the particles aggregate with each other. Precipitated.)

However, the water-soluble silicon or water-soluble silicon compounds containing water-soluble silicon as a main material are stable only in alkali and cannot be maintained as ions, and are not stable in acids and alcohols.

In other words, this makes it difficult to digest and absorb in the digestive system of an animal, plant, or human body. Therefore, there is a need to maintain an ionic state without sedimentation from the stomach to the digestive system.

In addition, in order to obtain the possibility of using such silicon in various industries, it is necessary to systematically study from the development of a technology to increase the stability of ions in aqueous solutions in both acids and alkalis.

Minerals are mainly minerals contained in ores (especially mica). There are various elements, such as germanium, iron, manganese, etc. that we are well aware of to make semiconductors, and these elements are gradually dissolved in stones or rock masses as groundwater flows through the ground, and they are incorporated into the water and absorbed into the ground.

These minerals are essential to all living things. However, it is not an exaggeration to say that the amount of minerals on the earth is almost depleted in all lands on the earth now, because the amount that is absorbed and disappeared by plants by large-scale agriculture rather than the amount that gradually permeates the land.

If these minerals are not present in the soil, no matter how abundantly different types of fertilizers are given, plants cannot sufficiently absorb nutrients, their roots are weak, their growth is slow, and the yield is reduced.

The collapse of the soil mineral cycle is serious due to chemical farming. The soil's mineral cycle is maintained by organic fertilizers such as compost and livestock manure. In this way, agricultural products produced in the soil where the mineral cycle is blocked are bound to be deficient in minerals.

The mineral cycle of the modern human body, which has no choice but to eat such agricultural products, is bound to collapse. It can be said that the most profound cause of adult diseases and anti-health (半建康) state of modern people is due to the deficiency of this mineral.

World-renowned health scholars such as Bragg, Walker, and Dr. Vannick say that minerals must be absorbed from food (animals and plants). If you absorb inorganic minerals in water or take mineral undiluted solutions collected from nature in water, It is warning of the fact that it hurts the central organs of our body and causes various diseases.

Currently, the minerals contained in medicines are high in minerals. Of course, the purpose is to consume as much mineral as necessary, and it is not harmful to the human body. Minerals absorbed by the human body, whether organic or inorganic, are temporarily ionized and then recombined into necessary organic substances, acting as enzymes in necessary parts of the body, or being deposited in tissues. That is, it is desirable that at least the human body must be ionized in order to digest (absorb) minerals. Due to the nature of minerals, there are cases in which organic substances have good absorption during absorption.

Therefore, even if it is an inorganic material, there is a need to organicize and ionize minerals.

Korean Patent Application No. 10-2013-0007384 Water-soluble silicate composition for prevention and treatment of dementia and its manufacturing method Korean Patent Application No. 10-2009-0059986 Composition for treating insomnia containing silicon dioxide (SiO2) Korean Patent Application No. 10-2009-0087276 A composition for treating depression containing silicon dioxide (SiO2) as an active ingredient Korean Patent Application No. 10-2007-0037931 Silicon composition and method for producing drinking water containing the same Korean Patent Application No. 10-2010-0090126 Manufacture of silicon water containing minerals and method of using the same Korean Patent Application No. 10-2012-0128322 Method for preparing food additive solution containing silicon composition Korean Patent Application No. 10-2018-0051025 Silicon-based food additive manufacturing method Republic of Korea Patent Application No. 10-2016-0052089 Silicate ((NaSiO3_10H2O) silver (Ag) aqueous solution or silicate (NaSiO3_10H2O) copper (Cu) aqueous solution composition and water-soluble silver silicate salt or water-soluble copper silicate salt and its preparation method Korean Patent Application No. 10-2011-0102639 Water-soluble silicate mixed powder and its manufacturing method Korean Patent Application No. 10-2000-0031185 Cleaning agent for liquid metal pipes containing silicate as the main component and method for manufacturing the same Korean Patent Application No. 10-2010-0064516 Cosmetic composition containing silicate Korean Patent Application No. 10-2006-0047281 Method for manufacturing fine powder of silicate Korean Patent Application No. 10-2005-0105142 Functional cosmetic soap composition with silicate added Korean Patent Application No. 10-2004-0069392 Manufacturing method of alkaline water for drinking water containing silicate component Korean patent application number 10-2017-0034531 silicate beverage and its manufacturing method Korean Patent Application No. 10-2017-0041476 Liquid Silicate Fertilizer Composition and Method for Manufacturing Liquid Silicate Fertilizer Korean Patent Application No. 10-2010-0038626 Hair growth promoter containing silicate mineral as an active ingredient and its manufacturing method Korean Patent Application No. 10-2010-0038612 Wound treatment containing silicate mineral as an active ingredient and its manufacturing method Korean Patent Application No. 10-2010-0071548 A feed additive for antibiotics that regulates the immune function of animals and promotes growth, including special fermented silicate minerals Korean Patent Application No. 10-2004-0022633 Functional rice coated with silicate Korean Patent Application No. 10-2011-0102639 Water-soluble silicate mixed powder and its manufacturing method Korean Patent Application No. 10-2010-0038621 Anti-cancer drug containing silicate mineral as an active ingredient, and its manufacturing method Korean patent application number 10-2016-0105062 water-soluble silicate fertilizer Korean Patent Application No. 10-2010-0038633 Atopic dermatitis treatment containing silicate mineral as an active ingredient and its manufacturing method Korean Patent Application No. 10-2010-0038630 A treatment for bedsores containing silicate mineral as an active ingredient and its manufacturing method Korean Patent Application No. 10-1997-0701852 Silicate granule and its manufacturing method Korean Patent Application No. 10-2015-0163605 Cosmetic composition containing silicate Korean Patent Application No. 10-2005-0100100 Method for manufacturing a growth promoter for flowering and horticultural crops using silicate Korean Patent Application No. 10-2007-0038569 Method for extracting medicinal ingredients from medicinal materials using silicate Korean Patent Application No. 10-2016-0159967 Functional composition having blood circulation and atopic calming effect Korean patent application number 10-2016-0094117 Cosmetic composition for skin improvement Korean Patent Application No. 10-2015-0186814 Cosmetic composition for wrinkle improvement and its manufacturing method Korean Patent Application No. 10-2011-0021125 Method for manufacturing fertilizer containing amino acid bound to silicic acid Korean Patent Application No. 10-2016-7021929 Stabilized silicate composition and its use as an antiperspirant composition. Korean Patent Application No. 10-2016-7024827 Materials and methods related to stabilized polymer silicate compositions.

Accordingly, an object of the present invention is to provide a silicon ion complex organically formed with a carboxylic acid using a water-soluble silicon compound.

Another object of the present invention is to provide a technology for producing a silicon ion complex organically formed with a carboxylic acid that can be used for animal, human and plant growth by organizing a water-soluble silicon compound.

Another object of the present invention is to provide a method of adding titanium, zirconium, and various minerals including the same in the production of a silicon ion complex organically formed with a carboxylic acid stable to change in hydrogen ion (pH).

Another object of the present invention is to provide a variety of products using an organic silicon ion complex produced by using the silicon ion complex manufacturing technology organically carboxylic acid.

The inventor of the present invention is a person who has been continuously developing a technology for stabilizing ions in an aqueous solution of titanium and zirconium, and has been conducting ionization studies of various materials other than this, and has been conducting various titanium and zirconium related studies since 2011. A patent has been filed for using ions.

Meanwhile, looking at the prior art documents of the present invention, various techniques for ingestion of minerals such as silicon and zirconium, application to plants or animals, and drinking are listed.

In particular, Patent Document 0015. Korean Patent Application No. 10-2017-0034531 describes a silicate beverage to which zirconium is added and a method of manufacturing the same in the claims and contents.

In addition, Korean Patent Application No. 10-2002-0071408 describes a liquid composition for promoting plant growth containing titanium dioxide fine particles.

The common point of silicon, zirconium, and titanium to be applied to animals, plants and humans is that they are non-toxic as minerals.

Zirconium does not have a known role in living organisms, but it contains about 250mg on average in the human body, and is also contained in small amounts in various foods. In daily life, it is also used in some products or for purifying tap water. (Source: Wiki Encyclopedia)

In the case of titanium or silicon, it is already used as a plant growth accelerator or liquid fertilizer for plants, and is recognized as a mineral in the human body. As for titanium, the role in the human body has not yet been confirmed, but it is at a level that it has been found to exist in trace amounts in the human body.

However, each of these elements has different properties.

For example, zirconium tends to show a stable appearance at a hydrogen ion concentration lower than pH 4.5 when a water-soluble zirconium compound is dissolved in water, and tends to precipitate in alkali. At low pH, there is a tendency to retain ions without any special additives, but when the pH starts to rise, it becomes rapidly unstable and all precipitates in alkali.

In addition, it is very difficult to exist as ions in water because titanium reacts with water for a very short time (e.g., less than 1 second) when water-soluble titanium compounds such as titanium tetrachloride or titanium sulfate are added to water. . This titanium reacts very quickly with water, whether it is alkali or acid. Of course, if it exists as an ion, it is a material that is more acidic than alkali.

In addition, when water-soluble silicates, sodium silicate, potassium silicate, and calcium silicate, are dissolved in water, they have an alkali, but the pH usually reaches 10.0 to 13.0 depending on the amount dissolved. These substances dissolve in water and become aqueous solutions, but as time goes by, they react with water to increase weight and volume and precipitate at a low pH, or if left for a long time, they are hygroscopic even after dissolution, creating a precipitate. In particular, when the pH is low, acidic or alcohol, it exhibits insoluble insoluble properties.

It shows the hygroscopic property of silica gel.

Looking a little further,

The Korean Patent Application No. 10-2016-7021929 describes a stabilized polysilicate. The properties of the stabilized silicate composition according to the present invention are very suitable for use as an antiperspirant, and the safety of this composition is as excellent as polysilicic acid acceptable to the skin, and unlike aluminum salts, there is no safety problem related to systemic toxicity. Are talking.

Furthermore, the pH of the initial composition (2.5 or 3.0 to 5.0) and the pH at which gel formation occurs, i.e., pH 6 are physiologically acceptable conditions, and furthermore, the gel-forming reaction is within a short time, typically between 5 and 30 minutes. Happens to The gel produced by shifting the pH of the composition is a patent that is odorless and colorless and thus does not leave noticeable stains on the skin or clothing.

The invention provides a method for producing stabilized polysilicic acid comprising the steps of:;

(a) preparing an alkali silicate solution having a pH ≥ 9.5;

(b) optionally adding a growth retardant to the alkali silicate solution;

(c) lowering the pH to ≤ 4.0 by acid addition to form a composition comprising polysilicic acid;

(d) optionally adding a multivalent cation;

(e) adding a base to raise the pH of the composition to a physiologically acceptable pH to form a stabilized composition comprising polysilicic acid;

(f) optionally adding a growth retarding agent capable of increasing the safety of the composition;

(g) optionally adding a non-aqueous solvent that can increase the safety of the composition; And

(h) optionally introducing into an antiperspirant composition or cosmetic formulation. (c) forming a composition comprising polysilicic acid by lowering the pH to ≤ 4.0 by addition of an acid;

It includes the step of producing a stabilized silicate composition, and provides a stabilized silicate composition obtainable by the method described by this patent.

That is, in summary, Korean Patent Application No. 10-2016-7021929 is aimed at causing a gel-forming reaction in the vicinity of pH 2.5 to pH 3.0, pH 5.0, and pH 6.0, which is a physiologically acceptable condition, and has an average of 20 nm or It aims to control the galling of silicates in smaller forms.

Referring to the specific details for carrying out the invention, the invention is a silicate in the form of nanoparticles or colloids of polysilicic acid, and the cluster radius is less than 10 Å, preferably the colloidal dispersion is less than 100 nm, and between 1 nm and 100 nm, preferably Explains that they are polymeric silicic acid nanoparticles with an average diameter of 20 nm.

The reason why silicic acid has various particle sizes in the aqueous solution is due to the hygroscopicity of the water-soluble silicate in the process of dissolving the silicate in water. This hygroscopicity is also the reason silica gel acts as a dehumidifying agent.

That is, if the water-soluble silicate is first dissolved without any action, the silicate reacts with water and begins to gel, and once gelled, it cannot be re-ionized in the aqueous solution.

On the other hand, (Patent Document 35) Korean Patent Application No. 10-2016-7024827 Looking at the materials and methods related to the stabilized polymer silicate composition in terms of use, it can be seen that the present invention is a similar invention.

In particular, looking at the specification, it can be seen that the carboxylic acid used in the present invention is used. In addition, it is also expected to act as a stabilizer to control the moisture absorption of the polymer silicate composition with ethanol.

The present invention aims to prepare a stabilized polymeric silicate composition comprising polymeric silicic acid and nanosilicate particles having an average diameter of 20 nm or less , wherein stabilization means that the average diameter and size of the particles are continuous. It seems to refer to a form that does not grow larger and is maintained. This is similar to Patent Document 34 in some respects.

The invention comprises the steps of (a) providing an aqueous solution of soluble silicate at a pH of 9.5 or higher;

(b) lowering the pH of the silicate solution to cause polymerization of the silicate to form polymer silicic acid and nanosilicate particles; And

(c) simultaneously or sequentially with steps (a) and/or (b), a stabilizer containing polyalkylene glycol and or sugar is added to the silicate solution, whereby the stabilizer inhibits the formation of condensed silicate. The preparation of silicate compositions is described.

That is, the present invention describes in that a stabilizer is used for the purpose of causing polymerization to form silicic acid and nano silicate particles and to stabilize the size of the formed particles, and carboxylic acid may be used among the stabilizers. There is.

It seems that the inventors of this invention did not have the purpose of making silicon into ions from the beginning, and there was no knowledge about ionizing silicon at the time of invention.

The inventors of the above (Patent Document 35) claim that the polymer silicate composition stabilized in [0068] is intended for use as a pharmaceutical or nutritional composition.

However, as a nutritional composition, for example, silicon is a mineral, but those skilled in the art are well aware that the safest way to ingest minerals by humans or animals is to ingest them as ions.

In particular, in the method of ingesting minerals, inorganic minerals and organic (chelated) minerals are classified, and the fact that ingestion of inorganic minerals can be harmful to the human body, even if it is an ion, is found in data that anyone can easily access through various media. It corresponds. You can easily access inorganic minerals through internet search alone.

What is Chelate?

The word chelate is a chemical bond that refers to a shape that can hold objects tightly with claws.

Mineral is a type of mineral and is also called mineral or inorganic because it is extracted from ore. The minerals that we add to animal feed are also extracted from ore and are called inorganic minerals. However, in the body of animals and plants, minerals exist in a different form. These minerals are called chelate minerals as inorganic minerals are consumed by animals and plants to chelate with organic matter in the body.

In this situation, silicon has a material property that makes it impossible to make inorganic minerals except for the use of non-drinking hydrofluoric acid (HF), so the method of using it as an ion has been completely blocked. In other words, when inorganic minerals enter the human body, they are dissolved in gastric acid and exist as ions, so that they can be digested and absorbed, and organic minerals can naturally guarantee a safer way of ingestion.

However, since silicon becomes polymer silicate particles, which are polymer materials that increase volume and weight by absorbing moisture when it encounters water, stopping this hygroscopic reaction and maintaining the ionic state was a challenge in the industry.

Therefore, the trace amount of SiO2 present in natural water may not have a major problem with human health, but the fact that silicate polymer particles, a high molecular substance, enter the human body and play a role as a nutrient composition, is the claim of the inventor, and has been studying minerals so far. It may be true that it is difficult for developers to stand up and understand.

Amino acids and chelated minerals show a 3 to 4 times higher absorption and utilization rate than various types of minerals that exist in nature. The reason why the absorption and utilization rate of chelated minerals is high is because the mechanism of digestion and absorption is different. When livestock ingested inorganic minerals, ionized rapid ions and integral proteins present in the intestinal membrane chelate and then separate again and carrier. This is because chelate minerals are absorbed through an active absorption method in which amino acids and dipeptides are absorbed directly into the intestinal membrane cells without going through such a complex process of chelating protein and chelating bonds.

In addition, when inorganic minerals are separated into ionic form in the stomach, they exhibit divalent cations. As they become fluorinated substances by combining with phosphoric acid, oxalic acid, phytic acid, and fibrin, which have anions present in the intestine, the absorption and utilization rate is significantly lowered. It becomes.

However, the invention of (Patent Document 35) is a patent for silicon, and the silicate polymer, which is a high molecular substance, is not separated in an ionic form in the stomach, which is the digestive system, regardless of animal or human body. Therefore, it seems that the inventors developed or insisted that silicon, which is a tetravalent ion, is not separated into ions in the gastric acid solution when it becomes a polymer silicate composition to be used as a nutritional composition.

Therefore, since inorganic minerals are separated into ions in the stomach, they are used medically if necessary, or added to animal feed, but using a high molecular substance for such a purpose, even if it is a very small amount, has any effect on the human body or animals. It is not known whether it is crazy, and it is not suitable as a method of ingesting minerals.

Therefore, it can be said that it is an extremely unusual claim, except for natural polymer substances such as starch and cellulose, as data on the fact that living organisms drink polymer substances even in small amounts.

The inventors of the present invention dissolve titanium tetrachloride and titanium sulfate, which are water-soluble titanium compounds, in a solution in which tricarboxylic acid or dicarboxylic acid is first dissolved in the process of organizing titanium and zirconium to exist as ions. In the same way, zirconium oxychloride and zirconium sulfate, which are water-soluble zirconium compounds, were also dissolved in the same way to maintain the organic zirconium ion state.

And it has been proved through experimental examples and examples that it exists in an aqueous solution in an organic ion state through various alloys and single metal plating with metal ions, and has been registered as a patent. In particular, it proved that it can be used electrochemically even if the metal is present as ions in an aqueous solution through a chelate method.

In other words, by showing both the oxidation and reduction processes of metal by electricity by electroplating, it has been reliably proved that titanium and zirconium are present in an ionic state in which titanium and zirconium are combined with carboxylic acid through the behavior of metal ions.

In this process, it was confirmed through an experiment that the stable state of the organicated ions can be further improved compared to the case of using a single carboxylic acid by adding other types of carboxylic acids.

[Experimental Example 1] Tungsten ion stabilization experiment 1.

Experimental Example 1 and Experimental Example 2 were conducted to investigate the ion behavior in aqueous silicate solution through an ion stabilization experiment of tungsten, which is stable in alkali, similar to that of water-soluble silicate.

18 g of sodium tungstate and 18 g of citric acid, one of tricarboxylic acids, were dissolved in 100 ml of water at 60°C.

At the time of dissolution, it was dissolved transparently and cleanly, but after 48 hours in the standing test, a sponge-shaped precipitate began to be formed, and tungsten ions were aggregated and precipitated, making it very difficult to re-dissolve. (The precipitate can be separated from an aqueous solution and reacted with ammonia to de-dissolve. However, if it is an actual silicate, de-dissolution is not possible.)

Assuming the dissolution state of the silicate, the stable state at pH 3.0 was confirmed with tungsten ions stable to alkali, but it was confirmed that it was not completely stable even with tricarboxylic acid. The amount of tricarboxylic acid may have been insufficient.

As such, various variables act on the ionization of substances.

However, according to the inventors' observation, water-soluble silicate appears to be stable in alkali, but in reality, it is not stable in alkali, but it seems that the reaction with water is only slow, and in terms of metal, similar ions as stable in alkali similar to tungsten. It only shows behavior. Actually, it exists in the form of colloidal or colloidal, not ions, but it is transparent enough to be indistinguishable with the naked eye, so it looks like an ion. These can easily be identified as ions through a high-purity ethanol reaction test. When added to high-purity ethanol, the colloidal or colloidal silicate aqueous solution shows all its particles in a transparent state.

The actual form of silicate is that when it encounters water like titanium, it immediately starts to react with water, exhibits endothermic and hygroscopic properties, absorbs water molecules, expands its volume and mass, and once expanded, it is in the solution again. It is not possible to return to the original ionic state by a method such as pH change.

Among the metals, zirconium and titanium have similar properties in that the material precipitated in the solution cannot return to its original ionic state. Once the ionic state is broken in water and once precipitated, it cannot be recovered to the ionic state again by pH adjustment in the solution unless a highly toxic substance such as fluorine is used. Tungsten in the previous experimental example was able to dissolve the precipitate in ammonia to make it ionic again, but titanium and zirconium are impossible.

Eventually, the sediment must be removed through filtration.

Even water-soluble silicates cannot be restored to an ionic state in a colloidal or colloidal form in an aqueous solution. This is similar to the reason that once precipitated titanium became hydrous titanium oxide, it was impossible to dissolve.

In other words, water-soluble silicate seems to show a stable appearance in alkali, similar to a metal that is stable to alkali like tungsten, but in reality, the rate of hygroscopicity with moisture is only slightly slowed, and the ionic state is once again like titanium and zirconium. After cracking, it exists in the form of colloidal or colloidal in an aqueous solution, continuously causing a polymerization reaction at a slow rate, and there is a characteristic that it cannot return to an ionic state again.

The method that the inventors of the present technology have been able to maintain in an ionic state in an aqueous solution of titanium or zirconium is to prepare an aqueous solution in which dicarboxylic acid or tricarboxylic acid is first dissolved, and then dissolve a water-soluble titanium compound or a water-soluble zirconium compound in the aqueous solution. This is because a method of organizing metal ions was used by combining carboxylic acid and metal ions when instantaneous ionic state was established. For this, the carboxylic acid must be dissolved first.

Water-soluble silicate Also, like titanium or zirconium, an aqueous carboxylic acid solution is first prepared using dicarboxylic acid or tricarboxylic acid, and a water-soluble titanium compound or a water-soluble zirconium compound is dissolved in an aqueous carboxylic acid solution. Just as the acid and metal ions form a complex, the water-soluble silicate can be organicized to exist as ions by dissolving the water-soluble silicate in an aqueous carboxylic acid solution and combining it with the carboxylic acid in the process of dissolving it in an ionic state Knowing that, I came to the present invention.

The process of dissolving such carboxylic acid prior to water-soluble silicate is the core of the technology to maintain the ionic state by binding with the carboxylic acid before it becomes a colloidal or colloidal form larger than the ionic state.

[Experimental Example 2] Tungsten ion stabilization experiment 2.

18 g of tungstic acid soda and 18 g of tartaric acid in tricarboxylic acid were added to 9 g of citric acid, followed by addition of pure water, and dissolved in a solution of 100 ml.

It dissolved transparently and cleanly at the time of dissolution, and stabilized transparently even after 48 hours of standing experiment.

The solution was adjusted several times with ammonia and sulfuric acid from pH ≤1.0 to pH ≤11.0, but maintained a stable state.

Through this experiment, it can be seen that different combinations of carboxylic acids help to organicize material ions and stabilize pH. In particular, the more carboxyl groups there are, the more helpful it is to stabilize the material ions in the aqueous solution.

That is, a combination of a tricarboxylic acid and a tricarboxylic acid, or a combination of a tricarboxylic acid further including a dicarboxylic acid may further stabilize the material ions in the aqueous solution. That is, for stabilizing ions, tricarboxylic acid is more preferable than dicarboxylic acid.

For example, through a combination of malic acid-citric acid, glycine-saperic acid, glycine-citric acid-saperic acid, tartaric acid-glycine, tartaric acid-saperic acid, tartaric acid-citric acid-glycine, tartaric acid-citric acid-glycine, and tartaric acid-citric acid You can stabilize it a little more.

In other words, water-soluble silicon compounds, water-soluble titanium compounds, and water-soluble zirconium compounds are organically formed through combination with organic acids through the combination of dicarboxylic acids and tricarboxylic acids such as glycine, citric acid, malic acid, tartaric acid, and succinic acid, and can be stabilized as ions. And, if a single organic acid is used, it is more preferable to use a tricarboxylic acid rather than a dicarboxylic acid.

In addition, it can be adjusted freely from pH 1.0 or less to 13.0.

These changes are made of all the ingredients that can be consumed without harm to humans, animals and plants.

Through this process, silicon ions become organic and can exist as ions in an aqueous solution.

The present invention came to the present invention by discovering that the order of organicization as much as titanium and zirconium is very important in the organic materialization of silicon.

Water-soluble silicon compounds dissolve when dissolved in water, but as soon as they dissolve, they react with water, so the weight and mass begin to increase to a certain extent. The time of not being observed is prolonged, but in the case of low pH, it can be immediately confirmed that the precipitate is completely insoluble and insoluble in water. This gelled state cannot be ionized again in the aqueous solution.

For example, at a pH of 1.5 or less, which corresponds to human stomach acid, water-soluble silicates are already decomposed during digestion in a non-ionic state, making it impossible to exist as ions, and most of them are precipitated. Because of this phenomenon, the water-soluble silicate completely dissolved in an alkaline state becomes gelled when the pH is lowered and changes to a silica gel state. Therefore, no matter how completely water-soluble silicate is completely dissolved in alkali, it is impossible to have confidence that it can be maintained in an ionic state in the digestive system from the stomach of an animal or human body.

However, in the process of dissolving water-soluble silicates in water, it was discovered that when a complex was formed in a state in which dicarboxylic acid or tricarboxylic acid was dissolved first, it was no longer hygroscopic and could be stable in an ionic state. It has been reached.

That is, if water-soluble silicates react with carboxylic acid immediately (in a short period of time in the presence of ions) in the process of dissolving in water, they may no longer have hygroscopic properties. This means that the water-soluble silicate reacts with water and is dispersed in a colloidal form or does not exist in a colloidal form, but forms a complex with a carboxylic acid and exists in the smallest ionic state.

The inventors of the present invention have thus far confirmed that materials can be made into an ionic state, and titanium and zirconium are also organicized in this way to maintain the ionic state, and to prove that this is an ionic state, metal It was proved as an invention patent by studying the oxidation and reduction process of

However, since silicon is not a metal, it cannot be proved through such a process, but it can be indirectly explained that a complex with a carboxylic acid can be formed through the conventional process of titanium and zirconium and maintained in an ionic state.

(Definition of Terms)

The term "silicon ion complex" used in the present invention will be described.

In order to make silicon exist as ions, a minimum of essential components are required.

In addition, these essential ingredients are due to the various properties of silicon as follows.

First, silicon is soluble in hydrofluoric acid, but hydrofluoric acid is a very toxic substance, which is difficult and dangerous to use industrially. This is also true of titanium and zirconium. In addition, titanium can be dissolved in a very small amount in boiling sulfuric acid in addition to hydrofluoric acid, but the inventors of this technology could not find scientific evidence that silicon is soluble in boiling sulfuric acid even at the time of the present invention.

Second, silicon becomes soluble in water when it becomes sodium silicate, a synthetic material of sodium-silicon through synthesis with sodium carbonate or sodium hydroxide. (However, although the same tetravalent metal, titanium and zirconium do not dissolve in water even when synthesized with sodium. That is, even with the same tetravalent metal, the properties of each material are different.)

Third, even if silicon is processed into sodium silicate, the time it is dissolved in water as ions is very short, and since silicon itself is close to transparency, it is very difficult to measure the time. However, when titanium and zirconium also meet with water, titanium sulfate and zirconium sulfate exist as ions only in a very short time for less than about 1 second, and are precipitated again. Silicon does not show a form of sedimentation, but the moment it reacts with water, it changes into a colloidal or colloidal form within a short time, gradually absorbs moisture and maintains the state, then aggregates with each other and sinks into an insoluble precipitate over time. (It can be said that this state is a polymeric silicate polymer state.)

This characteristic of silicon is that "sodium" such as sodium carbonate or sodium hydroxide is added and synthesized to make sodium silicate to dissolve silicon in water in the process of obtaining silicon ions as safe ions that can be touched and eaten by humans. In the process of dissolving sodium silicate thus produced in water, at least one selected from tricarboxylic acid and dicarboxylic acid must be first dissolved in water in order to exist as ions, so "sodium", "silicon", " Carboxylic acid" and "water" must be included as essential components in order to exist as ions. For this reason, the term unavoidably chosen is "silicon ion complex" . For example, it is because of the nature of substances that do not exist as ions in water without organic matter, such as sodium chloride.

This is the same in the case of potassium and calcium, and the same result is obtained when potassium silicate or calcium silicate is used.

First, an aqueous carboxylic acid solution is prepared by combining an organic acid selected from dicarboxylic acid and tricarboxylic acid. By dissolving a water-soluble silicate in the prepared aqueous carboxylic acid solution, silicon is an organic acid even when silicon comes into contact with water or at low pH. It exists in the form of organic matter ions combined with.

This can be confirmed through an experiment to see if it maintains a stable state from pH 1.5 to pH 13.0 similar to gastric acid solution. To be more stable against changes in pH, it is possible to maintain the ionic state without gelation or precipitation even at pH ≤ 1.0.

This is very important.

In general, silicon is easy to recognize as a substance that people cannot eat, but the actual surface of the crust was an environment in which a large amount of silicon existed, and humans have been ingesting silicon through plants.

As far as it is known, when silicon deficiency occurs in the body, it is known to cause poor formation of ankle and knee joints, decrease in glycosaminoglycan content in articular cartilage, osteoporosis, lack of elasticity in connective tissue, skin aging, hair, and nail damage. .

Also, looking at the physiological actions of silicon in the human body, it is known as follows.

(1) Collagen, elastin, mucopolysaccharides, hyaluronic aci, etc. are bound to carbon deficiency and are involved in crosslinking.

(2) It is involved in the construction or elasticity of the bonding fabric.

(3) promote bone calcification. (There is a lot of silicon in the area where bone is calcified.)

(4) It is essential for the production of callagen and promotes the absorption of calcium in the initial process of bone formation. (Prevention of osteoporosis)

(5) Makes nails, hair, and skin elastic and moist.

(6) Maintain the elasticity of arterioles (prevent cardiovascular disease)

(7) Prevents the accumulation of aluminum in the body (prevents Alzheimer's disease)

(8) It is necessary to maintain the correct function of prolyhydroxylase, an enzyme that functions in the formation of other connective tissues including bone and cartilage.

In addition, as clinical efficacy, it is known to help maintain the prevention and treatment of osteoporosis, osteoarthritis, rheumatoid arthritis, skin health and skin aging, arteriosclerosis, nails and hair health, and Alzheimer's disease.

Although it is not clear, in civilized countries with a lot of arteriosclerotic disease, refined foods are often consumed, so the intake of silicon is low, and those who consume fiber foods with a large amount of silicon have low serum cholesterol and low arteriosclerosis, but generally age. As a result, the silicon content in the aorta decreases.

Nevertheless, silicon does not exist as an element in nature. It exists as an oxide (silica), and humans were able to ingest silicon, an element that exists in combination with amino acids through the fiber of plants, especially fiber-rich plants.

Among the foods with the highest amount of silicon, alfalfa is rich in calcium, magnesium, potassium, and silicon, so digestive ulcers, gastritis, liver disease, eczema, hemorrhoids, asthma, high blood pressure, anemia, constipation, bleeding gums, inflammation, It is also used for burns, cancer, and swelling.

Silicon supplementation is said to increase the thickness of the dermis and connective tissue support structures just below the skin surface.

The problem is that the amount of silicon that can be consumed as fiber from nature becomes insufficient. In the present invention, instead of the work of plants, silicon is organicized and provided as an ionized complex.

Meanwhile, carboxylic acid. It is collectively referred to as the general formula RCOOH.

It is a kind of organic compound, and the liquid is mostly acidic. Almost all compounds of the carboxyl group have a suffix of'-acid'.

Unlike other hydrocarbons, large-scale compounds are chemically meaningful, and representative ones can be called amino acids and fatty acids.

Desired results can be obtained through various types of reactions with various carboxy compounds according to need, such as for promoting plant growth, including fertilizers used in agriculture, for animals, for human medicine, for food, and for cosmetics.

The hydrogen of the carboxyl group of these carboxy compounds dissociates and shows acidity, so the name carboxylic acid was given.

When divided into carboxylic acids in this way, those having one carboxyl group are referred to as monocarboxylic acids, those having two are referred to as dicarboxylic acids, and those having three are referred to as tricarboxylic acids.

Chain-shaped monocarboxylic acid is widely distributed as a component of fats or fats and oils, so it is especially called fatty acid, and fatty acids can play a role as additives, but it is difficult to stabilize water-soluble silicate, titanium, and zirconium ions in an aqueous solution. .

Therefore, in the present invention, it is preferable to use at least one carboxylic acid selected from tricarboxylic acid and dicarboxylic acid as the carboxyl group compound capable of stabilizing the water-soluble silicate compound in an aqueous solution. More preferably, it is a tricarboxylic acid.

Therefore, a water-soluble silicate compound or a water-soluble titanium compound is prepared by stabilizing a water-soluble silicate compound by using one or more tricarboxylic acids, and dissolving one or more dicarboxylic acids or tricarboxylic acids as necessary. And dissolving the water-soluble zirconium compound.

In this case, the dicarboxylic acid or tricarboxylic acid is characterized in that it further comprises an amino acid.

When you want to make water-soluble silicate into an acidic aqueous solution,

It is characterized in that a water-soluble silicate compound is dissolved in an aqueous carboxylic acid solution prepared by dissolving at least one dicarboxylic acid or tricarboxylic acid first and foremost, thereby preparing an organicized silicon ion complex. (At low temperature, the reaction rate of water-soluble silicate with water is reduced as much as possible to form a complex with carboxylic acid)

In addition, as necessary, by adding titanium and zirconium to be added,

A titanium ion aqueous solution, characterized in that to prepare an organic water-soluble titanium ion aqueous solution prepared by dissolving a water-soluble titanium compound in an aqueous carboxylic acid solution prepared by dissolving at least one dicarboxylic acid or tricarboxylic acid; and

An aqueous solution of zirconium ions, characterized by dissolving a water-soluble zirconium compound in an aqueous carboxylic acid solution made by dissolving one or more dicarboxylic acids or tricarboxylic acids, to prepare an organic water-soluble zirconium ion aqueous solution, as needed It is characterized in that it is prepared by adding to ions.

Therefore, it is a method of producing a silicon ion complex organically formed of a water-soluble silicate compound with a carboxylic acid comprising the following steps.

(1) preparing an aqueous carboxylic acid solution by dissolving at least one carboxylic acid selected from dicarboxylic acid or tricarboxylic acid in distilled water or clean drinking water;

(2) adjusting the pH of the prepared aqueous carboxylic acid solution with acid or alkali as necessary;

(3) dissolving a water-soluble silicate compound in an aqueous carboxylic acid solution whose pH is adjusted;

(4) optionally adding polyvalent ions;

It consists of preparing organicized silicon ions.

It characterized in that it further comprises the step of adding the organicated titanium ion solution and the organic zirconium ion solution in step (4).

Among these steps, in steps (1) to (3), ions used as minerals are further added as needed.

The ions added at this time are magnesium (Mg), potassium (K), iron (Fe), manganese (Mn), sodium (Na), zinc (Zn), sulfur (S), calcium (Ca), and phosphorus (P). .

According to the present invention, water-soluble silicates can be ionized to form a silicon ion complex in a drinkable state, and can be used in various industrial fields.

In particular, it can be used as a source of minerals to plants, animals, and humans lacking minerals, and can be used in medicine and pharmaceutical fields, and solves the problem that it was difficult to expect absorption through the digestive tract in the form of colloidal or colloidal in the past. It was confirmed that it can be prepared in a state capable of digestion and absorption by making it in one ionic form.

Figure 1. Silicate precipitated in a gastric acid environment (pH 1.5) or less
Figure 2. Crystal structure diagram according to evaporation of a saturated solution of an organicated silicon ion complex prepared with tartaric acid
Fig. 3. Crystal structure of an organic silicon ion complex prepared with tartaric acid in a saturated solution.
Fig. 4. Plating surface of an accessory product plated by adding an organic silicon ion complex prepared with tartaric acid of Example 3 to a gold plating solution.
Fig. 5. A product in which a substitution reaction is tested on the surface of a stainless steel with the organic silicon ion complex prepared with tartaric acid of Example 3 (left substitution reaction not performed product, right substitution reaction surface)
Figure 6. Experimental photo confirming the water repellency of the surface after replacing the stainless steel surface with silicon ions

Hereinafter, the present invention will be described in more detail.

In order to explain the silicon ion complex organicized with carboxylic acid according to the present invention

1) Citric acid, malic acid, tartaric acid, which are organic acids having a tricarboxylic or dicarboxylic group

2) glycine, one of the amino acids,

The ionization experiment was conducted through the organicization of the water-soluble silicate.

The water-soluble silicate used to describe the present invention is Na ₂ SiO ₃ ㅇ9H ₂ O, but is not limited thereto, and Na ₂ SiO ₃ , Na ₂ SiO ₃ ㅇ5H ₂ O, Na ₂ SiO ₃ ㅇ10H ₂ O and water-soluble silicate complex materials containing minerals during the manufacturing process of water-soluble silicates are also acceptable. Hydrates containing water molecules in the molecule have some potential to form insoluble precipitates, but when dissolved at a low temperature, it is not unreasonable to make them exist as ions without special problems. In general, in the process of manufacturing water-soluble silicate, a water-soluble silicate composite material including various mineral components is made, and the most commonly used mineral components are magnesium (Mg), potassium (K), iron (Fe), manganese (Mn), and sodium. (Na), zinc (Zn), sulfur (S), calcium (Ca), phosphorus (P).

These mineral components are made by adding substances such as sodium carbonate, potassium carbonate, sodium triphosphate, sodium pyrophosphate, sea salt, magnesium carbonate, calcium carbonate, magnesium oxide, calcium oxide, iron oxide, and manganese oxide.

Hereinafter, it will be described through detailed examples.

[Comparative Example 1] Metasilicate dissolution test.

A dissolution experiment was conducted with metasilicate 9 hydrate (Na ₂ SiO ₃ ㅇ9H ₂ O).

In the process

(1) 1 g of metasilicate 9 hydrate was added to 500 ml of pure water and dissolved. Dissolution was made transparent and the pH was recorded at 12.23. (Digital pH meter measurement deviation exists.)

(2) The condition was checked by lowering the pH of the solution to 1.5 using 37% hydrochloric acid.

(3) The dissolved silicate gelled while agglomerated.

[Comparative Example 2] Metasilicate dissolution test 2. (Stomach acid condition)

(1) 150ml of water was filled in a 250ml beaker, and the pH was adjusted to 1.5 in order to reference the stomach acid of the human body using a 37% hydrochloric acid reagent, and then water was added to make 250ml.

(2) 1 g of metasilicate 9 hydrate was added to the above solution (1).

(3) Although some of the silicate was dissolved, it was not dissolved and precipitated.

Through the above comparative example, it can be confirmed that metasilicate cannot exist singly in an ionic state in gastric acid. (Figure 1)

In addition, it can be seen that even if metasilicate is nano-ized, it is difficult to digest and absorb because it exists in the form of silica gel.

Also, the precipitated material cannot be ionized again in the same solution.

[Example 1] An experiment for preparing a metasilicate organic ion complex using citric acid.

An organic ionization experiment was conducted with metasilicate 9 hydrate (Na ₂ SiO ₃ ㅇ9H ₂ O).

In the process

(1) 20 g of citric anhydride was dissolved in a 500 ml beaker.

(2) And the pH was adjusted to an alkali 8.0 using sodium carbonate. (This is because metasilicate is neutral and easy to dissolve without impact of pH in the alkaline state, and it is to prevent insoluble impurities caused by pH impact.)

(3) Silicate 9 hydrate (Na ₂ SiO ₃ ㅇ9H ₂ O) 20 g was slowly dissolved in a mechanical stirring environment. (During the dissolution process, hygroscopic and endothermic reactions occurred.)

(4) The prepared organic silicon ion complex was stable as a transparent solution, and 20 g was sufficiently dissolved in 500 ml to maintain the ionic state. (Converted to the amount of pure silicon ions, it is equivalent to about 3.954 g/L.)

(5) 100 ml of the prepared organic silicon ion complex was separated, transferred to a 250 ml beaker, and then lowered to pH ≤ 1.5 with a 37% hydrochloric acid reagent to confirm stability. Even after checking for about 20 days, it maintained a stable state. This experiment is to determine whether ions can exist in an environment similar to that of human stomach acid.

(6) The solution 5 was converted to pH 13.0 again using ammonia. Stability was maintained.

In a process for producing and manufacturing a silicon ion complex organically formed with a carboxylic acid, a filtering step is required. This filtration is to filter impurities and impurities in the material caused by pH impact that may occur at the time of dissolution. After precipitation, precipitation filtration using the supernatant or filter filtration can be used.

In addition, sterilization may be required in the manufacturing process. In this case, disinfection may be sterilized by one or more of ultraviolet UV sterilization, high temperature sterilization, chlorine sterilization, dioxide gas sterilization, and ozone treatment.

The organic silicon ion complex made of citric acid may use carboxylic acid, sodium carbonate, sodium hydrogen carbonate, sodium hydroxide, and amino acids to adjust the pH to weakly acidic or weakly alkaline, and the pH adjustment range is 1 to 13.

Through this process, it can be used as drinking water and beverages. However, it did not feel more stable than when tartaric acid was used.

[Example 2] An experiment for preparing a metasilicate organic ion complex using malic acid.

An organic ionization experiment was conducted with metasilicate 9 hydrate (Na ₂ SiO ₃ ㅇ9H ₂ O).

In the process

(1) 20 g of malic acid was dissolved in a 500 ml beaker.

(2) And the pH was adjusted to an alkali 8.0 using sodium carbonate. (This is because metasilicate is neutral and easy to dissolve without impact of pH in alkaline state, and is to prevent insoluble impurities caused by pH impact.)

(3) Silicate 9 hydrate (Na ₂ SiO ₃ ㅇ9H ₂ O) 20 g was slowly dissolved under mechanical stirring. (During the dissolution process, hygroscopic and endothermic reactions occurred.) The higher the temperature at which silicate is dissolved, the faster the dissolution rate. It was judged more suitable to slowly dissolve at a low temperature in order to increase the bonding strength with the organic acid.

(4) The prepared organic silicon ion complex was stable as a transparent solution, and 20 g was sufficiently dissolved in 500 ml to maintain the ionic state. (Converted to the amount of pure silicon ions, it is equivalent to about 3.954 g/L.)

(5) Preparation 100 ml of the organic silicon ion complex was separated, transferred to a 250 ml beaker, and then lowered to pH ≤ 1.5 with a 37% hydrochloric acid reagent to confirm stability. Even after checking for about 20 days, it maintained a stable state.

(6) The solution 5 was converted to pH 13.0 again using ammonia. Stability was maintained. This Example 2 was also relatively less stable than when tartaric acid was used.

[Example 3] An experiment for preparing a metasilicate organic ion complex using tartaric acid.

An organic ionization experiment was conducted with metasilicate 9 hydrate (Na ₂ SiO ₃ ㅇ9H ₂ O).

In the process

(1) 40 g of tartaric acid was dissolved in a 500 ml beaker.

(2) The procedure for adjusting the pH was omitted.

(3) Silicate 9 hydrate (Na ₂ SiO ₃ ㅇ9H ₂ O) 40 g was slowly dissolved under mechanical stirring.

(4) The organic silicon ion complex was stable as a transparent solution, and 40 g was sufficiently dissolved in 500 ml to maintain the ionic state. (Converted to the amount of pure silicon ions, it is equivalent to about 7.908 g/L.) When using tartaric acid, further studies are needed to determine why so much silicate can be dissolved.

(5) 100 ml of the organic silicon ion complex was separated, transferred to a 250 ml beaker, and then lowered to pH ≤ 1.5 with a 37% hydrochloric acid reagent to confirm stability. Even after checking for about 20 days, it maintained a stable state.

(6) The solution 5 was converted to pH 13.0 again using ammonia. Stability was maintained.

(7) The silicon ion complex solution prepared with tartaric acid was prepared in a saturated solution at room temperature, and the gelation was checked. It was confirmed that silica gel was not formed and precipitated into a new needle-shaped structure. (Fig. 2)

[Example 4] Experiment of preparing metasilicate organic ion complex using tartaric acid 2.

An organic ionization experiment was conducted with metasilicate 9 hydrate (Na ₂ SiO ₃ ㅇ9H ₂ O).

The purpose of this experiment is to make a saturated solution at the time of manufacture and to check the gelation phenomenon and crystal structure in the solution.

In the process

(1) 60 g of tartaric acid was dissolved in a 500 ml beaker. (It was confirmed visually that it was completely dissolved.)

(2) The procedure for adjusting the pH was omitted.

(3) Silicate 9 hydrate (Na ₂ SiO ₃ ㅇ9H ₂ O) 60 g was slowly dissolved by mechanical stirring. (During the dissolution process, hygroscopic and endothermic reactions occurred.)

(4) The silicate was completely dissolved and some precipitates were formed in the saturated solution. The resulting precipitate was not in the form of undissolved silicate, but in the form of acicular structure. It was a structure reminiscent of fiber, as if found in vegetable fiber (Fig. 3).

[Example 5] An experiment for preparing a metasilicate organic ion complex using glycine.

An organic ionization experiment was conducted with metasilicate 9 hydrate (Na ₂ SiO ₃ ㅇ9H ₂ O).

(1) 20 g of glycine was dissolved in a 500 ml beaker. (It was confirmed visually that it was completely dissolved.)

(2) The pH was adjusted to 8.0 using sodium carbonate. In the case of glycine, which is neutral, you can easily do it with alkali even if you add a small amount of sodium carbonate.

(3) Silicate 9 hydrate (Na ₂ SiO ₃ ㅇ9H ₂ O) 20 g was slowly dissolved under mechanical stirring. (The hygroscopic and endothermic reactions occurred during the dissolution process.)

(4) The silicate was completely dissolved and showed a pH of 12.25. The pH was lowered with citric acid, malic acid, and tartaric acid, so that it could be made into weak alkaline drinking water.

In the preparation of the silicon ion complex organicized with such a carboxylic acid, magnesium, potassium, iron, manganese, sodium, zinc, sulfur, calcium, phosphorus, titanium, and zirconium cations may be further added. In this case, it is preferable to add titanium and zirconium in the form of organicized ions stable to pH changes in an aqueous solution, as described above.

The remaining mineral components are substances that can be easily ionized in aqueous solutions, such as calcium oxide (CaO), calcium hydroxide (Ca(OH)2), calcium ascorbic acid calcium salt, Ca(C6H7O6)2), calcium carbonate (CaCO3), Calcium chloride (CaCl2), acetic acid calcium magnesium salt, calcium acetate (C4H6CaO4), magnesium acetate (C4H6MgO4), magnesium carbonate-magnesium hydroxide-5 hydrate [(MgCO3)4ㅇMg(OH)2ㅇ5H2O] ,Magnesium chloride (MgCl2), magnesium citrate, magnesium hydroxide (Mg(OH)2), magnesium oxide (MgO), potassium acetate (CH3COOK), potassium chloride (KCl), potassium citrate (Potassium citrate), potassium hydroxide (KOH), potassium carbonate (K2CO3), potassium hydrogen carbonate (KHCO3), sodium hydroxide (NaOH), sodium carbonate (Na2CO3), sodium hydrogen carbonate (NaHCO3), sodium acetate (CH3COONa), sodium citrate, iron oxide, It is a cation that can be obtained by dissolving substances such as iron chloride, zinc chloride, manganese oxide, sodium phosphate, and sodium triphosphate, and it can be obtained through various water-soluble substances.

These cations are also preferably dissolved in a dicarboxylic acid or tricarboxylic acid aqueous solution and added, more preferably, dissolved in a tricarboxylic acid aqueous solution and added.

The silicon ion complex organically prepared with the carboxylic acid thus prepared can be used for various purposes. For example, drinking water suitable for drinking water quality standards, amino acid drinks, mineral drinks, amino acid and mineral complex drinks, pharmaceutical compositions for oral administration to supply silicon minerals to animals and humans, pharmaceutical compositions for injection, bakery, confectionery, plant growth promotion It can be used for various purposes such as fertilizers, detergents, cosmetics, and medical ointments.

In the case of a detergent, it can be prepared by adding a certain portion of the silicon ion complex organicized with the carboxylic acid of the present invention to shampoo, conditioner, face wash, soap, dish detergent, laundry soap, toothpaste, etc., and can be used as a detergent for animals and humans .

[Example 6] Plating experiment

Meanwhile, the electrochemical ionic behavior was examined by lowering the sodium silicate concentration per liter by 50% by adding 1 liter of water to the silicon ion complex prepared in Example 3 using tartaric acid.

Conventional titanium or zirconium was also organic (chelated) and made into ions, but it could be used electrochemically.

250 ml of a solution made of 2 liters by adding 1 liter of water to the solution of (1) Example 3

(2) 0.1 g of potassium gold cyanide

(3) A trace amount of 0.01 g or less of sodium lauryl sulfate was added, and 1 liter of gold plating solution was prepared.

Using an iridium-coated titanium electrode as an anode, a 1.5 volt DC current was applied to gold plating on metal accessory parts, and the surface was checked. If gold was insufficient, gold was supplemented in small portions and the changes in color and texture were measured.

This experiment was to confirm whether silicon is behaving ionic by texture and color, although silicon cannot be measured with a plating thickness measuring device. The results can be confirmed in FIG. 4 .

The surface of the gold plated had a slight blue sensation, expressing the texture as if it had been coated with a glass film, and the unique yellow color of gold appeared slightly dark.

It was confirmed that it can be used in plating solutions such as electroplating solutions. This phenomenon was similar in most electroplating solutions. Therefore, the silicon ion composite according to the present invention may be added in the process of reducing and depositing metal in the electrochemical field of plating to additionally obtain the texture of glass, and thus it is likely to be used for various purposes.

[Example 7] Substitution experiment

In addition, a substitution experiment was conducted to check whether the silicon ion complex prepared according to the present invention and present as an ion has a substitution ability.

This substitution experiment is because silicon is a metalloid, so it is necessary to confirm whether it causes the same substitution reaction as other metals because it is in an ionic state.

The substitution experiment was conducted by adding 1 liter of water to the solution prepared in Example 3 and immersing various metals in 250 ml of a solution made of 2 liters.As a result, it was possible to confirm a phenomenon in which stainless steel exhibits surface purification ability and texture such as glass film coating. . In FIG. 5 , when the surface was viewed from various angles in the sunlight, light scattering phenomenon such as glass fragments could be seen, and a slight texture of glass could be felt as a bar was seen. In addition, the surface was hydrophobic to water and was not wet. Fig. 6

Therefore, the present invention not only plays a role as a mineral, but also a variety of industries including electrochemistry (plating), as it was able to be used electrochemically, even though the metals of titanium and zirconium were organically made into ions as metalloid ions. It has been confirmed that it can be used in the field.

The terms used in this specification are used to describe specific embodiments, and are not intended to limit the present invention. As used herein, the singular form may include the plural form unless the context clearly indicates another case. Further, as used herein, "comprise" and/or "comprising" specifies the presence of the mentioned shapes, numbers, steps, actions, members, elements and/or groups thereof. And does not exclude the presence or addition of one or more other shapes, numbers, actions, members, elements, and/or groups.

For example, the organic acid, amino acid, or carboxylic acid used in the present invention does not refer to only the organic acid, amino acid, or carboxylic acid, but includes a sodium compound, potassium compound, or ammonium compound containing such components.

In the above, preferred embodiments of the present invention have been exemplarily described, but the scope of the present invention is not limited to such specific embodiments, and can be appropriately changed within the scope described in the claims.

Claims (9)

In the method for producing a silicon ion composite organicated with a carboxylic acid,
(1) preparing an aqueous carboxylic acid solution by dissolving at least one carboxylic acid selected from dicarboxylic acid or tricarboxylic acid;
(2) adjusting the pH of the carboxylic acid aqueous solution to be acidic or basic within the range of 1.0 to 13.0;
(3) dissolving a water-soluble silicate compound in an aqueous carboxylic acid solution whose pH is adjusted;
(4) optionally adding cations;
A method for producing a silicon ion composite organicated with a carboxylic acid, characterized in that produced by. In step (1) of claim 1,
The method for producing a silicon ion complex organicated with a carboxylic acid, characterized in that the dicarboxylic acid further comprises an amino acid. In step (2) of claim 1,
The acidic or basic pH control within the range of 1.0 to 13.0 is carboxylic acid (Carboxylic acid), sodium carbonate (Na ₂ CO ₃ ), sodium hydrogen carbonate (NaHCO ₃ ), sodium hydroxide (NaOH), amino acid (amino acid). A method for producing a silicon ion composite organicized with a carboxylic acid, characterized in that the control is controlled by selective addition from). In step (3) of claim 1,
The water-soluble silicate compound is selected from one or more of the water-soluble silicate composite materials prepared by further including minerals in the process of preparing the water-soluble silicate sodium silicate, potassium silicate, calcium silicate and water-soluble silicate, which are water-soluble silicates containing sodium, potassium, calcium and silicon. A method for producing a silicon ion composite organicated with a carboxylic acid, characterized in that dissolving. The method of claim 4,
The water-soluble silicate composite material further including minerals in the water-soluble silicate production process is sodium carbonate, potassium carbonate, sodium triphosphate, sodium pyrophosphate, sea salt, magnesium carbonate, calcium carbonate, magnesium oxide, optionally added in the water-soluble silicate production process. A method for producing a silicon ion composite organicated with a carboxylic acid, characterized in that it is a water-soluble silicate composite material prepared from at least one selected from calcium oxide, iron oxide, and manganese oxide. In step (4) of claim 1,
The selectively added cation is selected from magnesium, potassium, iron, manganese, sodium, zinc, sulfur, calcium, phosphorus, titanium, and zirconium. The method of claim 6,
The selectively added cation further comprises dissolving and adding a material containing the cation in an aqueous dicarboxylic acid or tricarboxylic acid solution. The method of claim 1,
After step (4),
Ultraviolet UV sterilization sterilization, high temperature sterilization sterilization, chlorine sterilization, dioxide gas sterilization, ozone treatment, further comprising sterilizing by one or more methods of organizing silicon ion complex with carboxylic acid. delete

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