KR102190680B1 - Functional building material including low-emissivity coat for windows - Google Patents

Abstract

A transparent substrate and a low-emission coating formed on one surface of the transparent substrate, wherein the low-emission coating is sequentially stacked from the transparent substrate: a first dielectric layer, a second dielectric layer, a lower barrier layer, a third dielectric layer, and a first Including a low-emission protective layer, a low-emission layer, a second low-emission protective layer, a fourth dielectric layer, a fifth dielectric layer, an upper barrier layer, and a sixth dielectric layer, wherein the refractive index of the first dielectric layer and the third dielectric layer are respectively A functional building material for windows and doors is provided that is lower than the refractive index of the second dielectric layer, wherein the refractive index of the fourth dielectric layer and the refractive index of the sixth dielectric layer are lower than that of the fifth dielectric layer, respectively.

Description

Functional building material for windows and doors {FUNCTIONAL BUILDING MATERIAL INCLUDING LOW-EMISSIVITY COAT FOR WINDOWS}

It relates to functional building materials for windows and doors.

Low-emissivity glass refers to glass in which a low-emissivity layer including a metal having high reflectance in the infrared region such as silver (Ag) is deposited as a thin film. Such low-emission glass is a functional material that reflects radiation in the infrared region, blocks outdoor solar radiation in summer, and preserves indoor heating radiation in winter, resulting in energy savings in buildings.

In general, since silver (Ag), which is used as a low-emission layer, is oxidized when exposed to air, a dielectric layer is deposited as an antioxidant film above and below the low-emission layer. This dielectric layer also serves to increase the visible light transmittance.

One embodiment of the present invention provides a functional building material for windows and doors with improved durability, heat resistance, moisture resistance and abrasion resistance while maintaining excellent optical performance.

In one embodiment of the present invention, a transparent substrate and a low-emission coating formed on one surface of the transparent substrate are included, and the low-emission coating is sequentially stacked from the transparent substrate: a first dielectric layer, a second dielectric layer, and a lower barrier Layer, a third dielectric layer, a low-emission layer, a fourth dielectric layer, a fifth dielectric layer, an upper barrier layer, and a sixth dielectric layer, the first low-emission protective layer disposed between the third dielectric layer and the low-emission layer, and the It further comprises at least one of a low-emission layer and a second low-emission protective layer positioned between the fourth dielectric layer, wherein a refractive index of the first dielectric layer and a refractive index of the third dielectric layer are respectively lower than that of the second dielectric layer, , The refractive index of the fourth dielectric layer and the refractive index of the sixth dielectric layer are respectively lower than the refractive index of the fifth dielectric layer to provide a functional building material for windows.

Each of the first dielectric layer, the third dielectric layer, the fourth dielectric layer, and the sixth dielectric layer may have a refractive index of 2.2 or less.

Each of the second and fifth dielectric layers may have a refractive index of 2.3 or more.

The low-emission coating may further include a lowermost barrier layer positioned at the lowermost portion so as to contact the transparent substrate.

The low-emission coating may further include an uppermost protective layer on the sixth dielectric layer.

The low-emission coating may further include an additional high refractive layer and an additional low refractive layer on top of the third dielectric layer, the sixth dielectric layer, or both, in order.

The functional building material for windows and doors is excellent in optical performance, heat resistance, moisture resistance and abrasion resistance.

1 is a schematic cross-sectional view of a functional building material for windows and doors according to an embodiment of the present invention.
2 is a schematic cross-sectional view of a functional building material for windows and doors according to another embodiment of the present invention.
3 is a schematic cross-sectional view of a functional building material for windows and doors according to another embodiment of the present invention.
4 is a schematic cross-sectional view of a functional building material for windows and doors according to another embodiment of the present invention.

Hereinafter, embodiments of the present invention will be described in detail with reference to the accompanying drawings so that those of ordinary skill in the art may easily implement the present invention. The present invention may be implemented in various different forms, and is not limited to the embodiments described herein.

In order to clearly describe the present invention, parts irrelevant to the description have been omitted, and the same reference numerals are assigned to the same or similar components throughout the specification.

In the drawings, the thicknesses are enlarged to clearly express various layers and regions. And in the drawings, for convenience of description, the thickness of some layers and regions is exaggerated.

Hereinafter, when an arbitrary configuration is formed on the “upper (or lower)” or “upper (or lower)” of the substrate, it means that the arbitrary configuration is formed in contact with the upper (or lower) surface of the substrate. However, it is not limited to not including other configurations between the substrate and any configuration formed on (or under) the substrate.

In one embodiment of the present invention, a transparent substrate 100 and a low-emissivity coating 11 formed on one surface of the transparent substrate 10 (coating, coat) provides a functional building material 100 for windows and doors.

The low-emission coating 11, a first dielectric layer 14a, a second dielectric layer 14b, a lower barrier layer 19a, a third dielectric layer 14c, sequentially stacked from the transparent substrate 10 1 low-emission protective layer (13a), low-emission layer (12), second low-emission protective layer (13b), fourth dielectric layer (14d), fifth dielectric layer (14e), upper barrier layer (19b), and sixth And a dielectric layer 14f.

The refractive index of the first dielectric layer 14a and the refractive index of the third dielectric layer 14c are respectively lower than that of the second dielectric layer 14b.

The refractive index of the fourth dielectric layer 14d and the refractive index of the sixth dielectric layer 14f are respectively lower than that of the fifth dielectric layer 14e.

1 is a cross-sectional view showing a functional building material 100 for windows and doors according to an embodiment of the present invention.

The low-emission coating 11 may be formed as shown in FIG. 1 as a multilayer thin film structure based on a low-emission layer 12 that selectively reflects far-infrared rays among solar radiation, and the low-emission coating 11 by lowering the emissivity It gives excellent thermal insulation performance due to low emissivity, that is, low emissivity.

The low-emission coating 11 is formed in the same structure as described above, and when applied as a coating film for window glass, it reflects outdoor solar radiation in summer and preserves indoor heating radiant heat in winter to prevent heat transfer between indoors and outdoors. It is a functional material that minimizes the energy saving effect of buildings.

'Emissivity' refers to the rate at which an object absorbs, transmits, and reflects energy having a specific wavelength. That is, in the present specification, the emissivity indicates the degree of absorption of infrared energy in the infrared wavelength region. Specifically, when far infrared rays corresponding to a wavelength region of about 5 μm to about 50 μm showing a strong thermal action are applied, the applied It means the ratio of absorbed infrared energy to infrared energy.

According to Kirchhoff's law, since the infrared energy absorbed by an object is the same as the infrared energy emitted by the object again, the absorption and emissivity of the object are the same.

In addition, since the infrared energy that has not been absorbed is reflected from the surface of the object, the higher the reflectivity for the infrared energy of the object, the lower the emissivity. If this is expressed numerically, it has a relationship of (emissivity = 1-infrared reflectance).

Such emissivity can be measured through various methods commonly known in the art, and can be measured by equipment such as a Fourier transform infrared spectroscopy (FT-IR), for example, according to the KSL2514 standard.

Absorption to far-infrared rays exhibiting such a strong thermal action of an arbitrary object, for example, low-emission glass, or the like, that is, the emissivity may have a very important meaning in measuring the thermal insulation performance.

The low-emissivity coating 11 is applied as a coating film on the transparent substrate 100, so that excellent light-lighting properties can be achieved by maintaining a predetermined transmittance in the visible light region, while lowering the emissivity in the infrared region to provide excellent heat insulation. Energy-saving functional building materials for windows and doors can be implemented. Such functional building materials for windows and doors are sometimes referred to as'Roy Glass'.

The low-emissivity layer 12 is a layer formed of an electrically conductive material, for example a metal, which can have a low emissivity, that is, has a low sheet resistance and thus has a low emissivity. For example, the low-emissivity layer 12 may have an emissivity of about 0.01 to about 0.3, specifically about 0.01 to about 0.2, more specifically about 0.01 to about 0.1, and more specifically It may be from about 0.01 to about 0.08.

The low-emissivity layer 12 in the emissivity range can simultaneously implement excellent light-emitting properties and heat insulation effects by appropriately controlling visible light transmittance and infrared emissivity. The low-emissivity layer 12 having the emissivity as described above may have a sheet resistance of, for example, about 0.78 Ω/sq to about 6.42 Ω/sq, but is not limited thereto.

The low-emissivity layer 12 performs a function of selectively transmitting and reflecting solar radiation, and specifically, has a low emissivity due to high reflectance for radiation in the infrared region. The low-emission layer 12 may include at least one selected from the group including Ag, Au, Cu, Al, Pt, ion-doped metal oxides, and combinations thereof, and is not limited thereto, and has low-emissivity performance. Metals known to be embodied may be used without limitation. The ion-doped metal oxide includes, for example, indium tin oxide (ITO), fluorine-doped tin oxide (FTO), Al-doped zinc oxide (AZO), and gallium zinc oxide (GZO). In one embodiment, the low-emission layer 12 may be a layer formed of silver (Ag), and as a result, the low-emission coating 11 can implement high electrical conductivity, low absorption rate in the visible light region, durability, etc. have.

The thickness of the low-emission layer 12 may be, for example, about 5 nm to about 25 nm. The low-emissivity layer 12 having a thickness in the above range is suitable for simultaneously realizing low infrared emissivity and high visible light transmittance.

The low-emission protective layers (13a, 13b) are made of metals with excellent light absorption performance and function to control sunlight, and the color implemented by the low-emission coating (11) can be adjusted by adjusting the material, thickness, etc. have.

In one embodiment, the low-emission protective layers 13a and 13b may have an extinction coefficient in the visible region of about 1.5 to about 3.5. The extinction coefficient is a value derived from an optical constant, which is a characteristic of a material, and the optical constant is expressed as n-ik in an equation. At this time, the real part n is the refractive index, and the imaginary part k is the extinction coefficient (also referred to as the absorption coefficient, extinction coefficient, extinction coefficient, etc.). The extinction coefficient is a function of the wavelength (λ), and in the case of metals, the extinction coefficient is generally greater than zero. The extinction coefficient, k is the absorption coefficient, α and α=(4πk)/λ, and the absorption coefficient, α is the relationship of I=I0exp(-αd) when the thickness of the medium through which light passes is d Due to the absorption of light by the medium, the transmitted light intensity (I) decreases compared to the incident light intensity (I0).

The low-emission protective layers 13a and 13b use a metal having an extinction coefficient in the visible light region in the above range, absorb a certain portion of the visible light, so that the low-emission coating 11 has a predetermined color.

For example, the low-emission protective layer (13a, 13b) is a metal of Ni, Ti, Nb, Cr, Al, Zn or Mo, a composite metal including at least two of the metals, an oxide of the metal, the composite It may include one selected from the group consisting of metal oxides and combinations thereof, but is not limited thereto. The composite metal refers to an alloy type.

In FIG. 1, the low-emission protective layer 13a and the low-emission protective layer 13b are each shown to be formed as a single layer, but each may be formed as a multilayer.

In one embodiment, the low-emission protective layers 13a and 13b may include Ti, Nb, Mo, or an alloy of at least two of them.

The low-emission protective layers 13a and 13b may be included as a single layer or a plurality of layers, and may be located on one or both sides of the low-emission layer 12. 1 shows a case where the low-emission protective layers 13a and 13b are formed as a plurality of layers on both surfaces of the low-emission layer 12.

The thickness of the low-emission protective layers 13a and 13b may be, for example, one layer having a thickness of about 0.5 nm to about 5 nm, but is not limited thereto, and may be appropriately changed according to the use.

The thickness of the low-emission protective layers 13a and 13b may vary depending on the metal material. For example, the thickness of the NiCr layer as the low-emission protective layer (13a, 13b) may be about 0.5nm to about 2nm, the thickness of the ZnAlOx layer as the low-emission protective layer (13a, 13b) is about 1nm to about It may be 8 nm.

The low-emissivity coating 11 is suitable for controlling so as to have a predetermined transmittance and reflectance while performing the role of the low-emission protective layers 13a and 13b by forming the low-emission protective layers 13a and 13b in the thickness range. .

The first dielectric layer 14a, the third dielectric layer 14c, the fourth dielectric layer 14d, and the sixth dielectric layer 14f each have a refractive index of about 2.2 or less, and specifically, may be about 1.8 to about 2.2.

In one embodiment, each of the first dielectric layer 14a, the third dielectric layer 14c, the fourth dielectric layer 14d, and the sixth dielectric layer 14f may include silicon aluminum nitride.

The silicon aluminum nitride may well implement a refractive index of about 2.2 or less, and at the same time exhibit excellent durability.

The first dielectric layer (14a), the third dielectric layer (14c), the fourth dielectric layer (14d) and the sixth dielectric layer (14f), for example, the weight ratio of Si: Al is about 85 to 95 parts by weight: 5 to Using 15 parts by weight of the target, it can be prepared by vapor deposition using sputtering equipment in a nitrogen atmosphere. In this case, the refractive index may be adjusted according to the content ratio of nitrogen, and specifically, the smaller the nitrogen content, the lower the refractive index, and the higher the content, the higher the refractive index. Specifically, by controlling the content of nitrogen, a layer of silicon aluminum nitride having a refractive index of about 1.8 to about 2.2 may be prepared.

The functional building material 100 for windows and doors can exhibit excellent durability because it includes at least four or more layers containing silicon nitride aluminum.

The second dielectric layer 14b and the fifth dielectric layer 14e each have a refractive index of about 2.3 or more, and specifically, may be about 2.3 to about 2.5.

In another embodiment, the second dielectric layer 14b and the fifth dielectric layer 14e may each include one oxide, oxynitride, or both selected from the group consisting of Ti, Zr, Nb, Ta, and combinations thereof. have. The combination of Ti, Zr, Nb, and Ta means an alloy of two or more metals.

Specifically, the second dielectric layer 14b and the fifth dielectric layer 14e may each include one oxide selected from the group consisting of titanium, zirconium, tantalum, and combinations thereof. Specifically, the second dielectric layer 14b and the fifth dielectric layer 14e each include TiOx; ZrOx; TaOx; Alternatively, one oxide selected from the group consisting of at least two or more alloys among Ti, Zr, and Ta; may be included, and may be about 1.5≦x≦2.0, and specifically, about 1.6≦x≦1.9.

The exemplified materials may well implement a refractive index of about 2.3 or more, and at the same time exhibit excellent durability.

Since the metal used as the low-emission layer 12 is generally well oxidized, the first dielectric layer 14a to the sixth dielectric layer 14f can act as an antioxidant film of the low-emission layer 12, In addition, the first to sixth dielectric layers 14a to 14f serve to increase visible light transmittance. In addition, the first to sixth dielectric layers 14a to 14f improve the optical performance of the low-emission coating 11.

Optical performances may be variously implemented by adjusting the thickness of each of the first to sixth dielectric layers 14a to 14f. Specifically, the thickness of each of the dielectric layers may be about 5 nm to about 30 nm, respectively, and the sum of the total thicknesses of the first dielectric layers 14a to the sixth dielectric layers 14f is about 30 nm to about It may be 120 nm.

In the low-emission coating 11, the first dielectric layers 14a to the third dielectric layers 14c, and the fourth dielectric layers 14d to sixth dielectric layers 14f have a structure in which a low refractive index layer, a high refractive index layer, and a low refractive index layer are repeated. To form. By forming a structure in which the low-refractive-index layer and the high-refractive-index layer intersect repeatedly, optical performance required for low-emission glass such as transmittance, reflectance, and color index is greatly improved.

The low-emission coating 11 includes a multilayer barrier layer of the upper barrier layer 19b and the lower barrier layer 19a. As shown in FIG. 1, by forming the multilayer barrier layers of the upper barrier layer 19b and the lower barrier layer 19a at respective specific positions, diffusion of oxygen and moisture can be effectively prevented. In addition, the functional building material for windows and doors 10 to which the multi-layered barrier layer is applied has improved heat resistance, improved moisture resistance, and abrasion resistance without deteriorating optical performance.

In the process of manufacturing the functional building material 10 for windows and doors by forming the low-emission coating 11 on one side of the transparent substrate 10, a heat treatment process is performed in which a preliminary stress is applied through a bending or reinforcing process. This, the heat treatment process is performed by heating to a temperature of about 600 to about 700 °C, and while applying such heat, the materials forming the low-emission coating 11 are often oxidized, diffused, or agglomerated, and thus structural There is a risk of undergoing transformation. On the other hand, when the low-emission coating 11 is placed in a high temperature and humid environment, when the low-emission layer 120 comes into contact with components that can act as corrosive agents such as oxygen, chloride, sulfide, sulfur dioxide, etc. , There is a problem in that the coating film is damaged due to corrosion of the low-emission coating 11. In addition, the functional building material for windows 10 has a problem in that the low-emissivity coating 11 is frequently damaged by scratches during transportation or handling.

Accordingly, there is a need for the low-emission coating 11 to be protected from a heat treatment process, a high temperature and high humidity surrounding environment, or from physical damage during handling.

The functional building material 10 for windows and doors forms the structure of the multilayer barrier layer as described above, so that the physical and chemical diffusion of alkali ions and oxygen through the lower barrier layer 19a and the upper barrier layer 19b Can be prevented, and accordingly, can serve to protect the low-emissivity coating 11 from the above-described heat treatment process and high-temperature and high-humidity surrounding environment, and the lowermost barrier layer 20 is the glass substrate 100 ) And the abrasion resistance of the low-emission coating 11 is improved by improving the interfacial adhesion between the low-emission coating 11 and the low-emission coating 11.

Accordingly, the functional building material 10 for windows and doors including the multilayer barrier layer is excellent in heat resistance, moisture resistance, and abrasion resistance.

Each of the lower barrier layer (19a) and the upper barrier layer (19b) includes one selected from the group consisting of: a metal, a composite metal, a nitride of the metal, a nitride of the composite metal, and combinations thereof.

The metal may be Si, Zr, Ti, Nb, Ni, or Cr, and the composite metal may mean an alloy including at least two of the metals. The composite metal may be, specifically, SiAl, ZrSi, TiZr, NiCr, NiTi, NbZr, or NiTiNb. The SiAl means an alloy of Si and Al, and the alloy is indicated in the same manner unless otherwise stated in the specification.

In another embodiment, the lower barrier layer 19a and the upper barrier layer 19b are each: zirconium nitride, zirconium silicon nitride, titanium nitride, titanium zirconium nitride, niobium nitride, nickel nitride, chromium nitride, nickel chromium nitride, It may include one selected from the group consisting of nickel titanium nitride, niobium zirconium nitride, nickel titanium niobium nitride, and combinations thereof.

In the functional building material 100 for windows and doors, the low-emission coating 11 may further include an uppermost protective layer 15 on the sixth dielectric layer 14f.

Figure 2 is a cross-sectional view showing a functional building material 200 for windows and doors according to another embodiment of the present invention.

The functional building material 200 for windows and doors 200 has an uppermost protective layer 15 laminated on the sixth dielectric layer 14f in the above-described structure.

The uppermost protective layer 15 is a layer exposed to the outermost layer and may include a zirconium-based compound.

Specifically, the uppermost protective layer 15 may include zinc aluminum oxide.

The uppermost protective layer 15 may implement excellent optical performance together with the first to sixth dielectric layers 14a to 14f.

The low-emission coating 11 is a layer corresponding to the first dielectric layer 14a, the second dielectric layer 14b, and the fifth dielectric layer 14e, and has a refractive index of about 2.3 or more, and specifically, about 2.3 to about 2.5. Phosphorus additional high refractive index layer; and a layer corresponding to the third dielectric layer 14c, the fourth dielectric layer 14d, and the sixth dielectric layer 14f, each having a refractive index of about 2.2 or less, specifically about 1.8 to about 2.2. It may further include a pair of low refractive layers.

The additional high refractive layer and the additional low refractive layer are formed as a pair, and the additional high refractive layer and the additional low refractive layer are sequentially formed on the third dielectric layer 14c and/or the sixth dielectric layer 14f. One more pair may be stacked and included.

In addition, the additional high-refractive-index layer and the additional low-refractive-index layer are paired, and the additional high-refractive-index layer and the additional low-refractive-index layer are formed on top of the third dielectric layer 14c and/or the sixth dielectric layer 14f. Two more pairs may be stacked and included in order.

That is, the additional high refractive layer and the additional low refractive layer are between the third dielectric layer 14c and the first low radiation protective layer 13a, on the top of the sixth dielectric layer 14f, or the sixth dielectric layer 14f. ) May be located between the top and the uppermost protective layer 15 to be described later.

The optical performance such as transmittance is improved as the pair of the additional high refractive layer and the additional low refractive layer are repeatedly stacked, but there is a fear of an increase in unit cost, so it can be adjusted according to the application purpose.

3 shows a functional building material 300 for windows and doors further including the additional high refractive layer and the additional low refractive layer.

In FIG. 3, the functional building material 300 for windows and doors is a pair of the additional high refractive layer (16a) and the additional low refractive layer (17a), and the additional high refractive layer (16b) and the additional low refractive layer (17b) Includes another pair of.

The low-emission coating 11 may further include the lowermost barrier layer 20 positioned at the lowermost portion to contact the transparent substrate.

Figure 4 is a cross-sectional view showing a functional building material 400 for windows and doors according to another embodiment of the present invention.

In FIG. 4, it was created as a case further including the lowermost barrier layer 20 in the stacked structure of FIG. 3, but the present invention is not limited thereto, and a window and door further including the lowermost barrier layer 20 in the structures of FIGS. 1 to 3 It can provide functional building materials for use.

The lowermost barrier layer 20 is a metal of Si, Zr or Ti, a composite metal including at least two of the metals, an oxide of the metal, an oxynitride of the metal, an oxide of the composite metal, and oxidation of the composite metal. It may include one selected from the group consisting of nitrides and combinations thereof. Specifically, the composite metal included in the lowermost barrier layer 20 may be SiAl, ZrSi, or TiZr.

In one embodiment, the lowermost barrier layer 20 is silicon oxide, silicon aluminum oxide, zirconium oxide, zirconium silicon oxide, titanium oxide, titanium zirconium oxide, silicon oxynitride, silicon aluminum oxynitride, zirconium oxynitride, zirconium silicon acid. It may include one selected from the group consisting of nitride, titanium oxynitride, titanium zirconium oxynitride, and combinations thereof.

The low-emission coating 11 may further include an additional layer other than the above-described structure in order to implement a predetermined optical performance.

The transparent substrate 10 may be a transparent substrate having high visible light transmittance, and for example, may be a glass or transparent plastic substrate having about 80% to about 100% visible light transmittance. The transparent substrate 10, for example, glass used for construction may be used without limitation, for example, may have a thickness of about 2 mm to about 12 mm, and may vary depending on the purpose and function of use, and thus It is not limited.

In order to manufacture the functional building material for windows and doors, first, a transparent substrate 10 is prepared, and then each layer of the low-emission coating 11 may be sequentially formed. Each layer of the low-emission coating 11 may be formed by a method suitable for realizing desired physical properties according to a known method.

Hereinafter, examples and comparative examples of the present invention will be described. The following examples are only examples of the present invention, and the present invention is not limited to the following examples.

( Example )

Example One

Using a magnetron sputtering evaporator, a multi-layered low-emissivity coating coated on a transparent glass substrate was prepared as follows.

Silicon aluminum nitride, which is a first dielectric layer, was deposited on a 5 mm-thick transparent glass substrate in an argon/nitrogen atmosphere, and then, titanium oxide, which is a second dielectric layer, was formed in an argon/oxygen atmosphere. Thereafter, a nickel chromium layer as a lower barrier layer was formed in an argon atmosphere, and silicon aluminum nitride as a third dielectric layer was formed in an argon/nitrogen atmosphere. Next, an aluminum zinc oxide layer in an argon/oxygen atmosphere and a nickel chromium layer in an atmosphere of 100% argon were formed on the upper surface to form a first low-emission protective layer. Then, a silver layer was deposited to form a low-emission layer, a nickel chromium layer was formed on the upper surface of the low-emission layer under an atmosphere of 100% argon, and an aluminum zinc oxide layer was formed in an argon/oxygen atmosphere to form a second low-emission protective layer. Formed. Thereafter, silicon aluminum nitride as a fourth dielectric layer was deposited in an argon/nitrogen atmosphere, and then a nickel chromium layer as an upper barrier layer was formed in an argon atmosphere. Finally, titanium oxide, a fifth dielectric layer, was formed in an argon/oxygen atmosphere. Silicon aluminum nitride, which is a sixth dielectric layer, was formed in an argon/nitrogen atmosphere.

Comparative example One

In Example 1, except for the titanium oxide layer, which is the second dielectric layer and the fifth dielectric layer, the rest of the layers except for the nickel chromium layer, which are upper and lower barrier layers, were all the same.

Experimental example One

The performance analysis of the functional building material for windows and doors produced in Example 1 was conducted for each of the following items.

<Calculation of transmittance>

After measuring the optical spectrum with a width of 1 nm in the range of 250 to 2500 nm using a UV-Vis-NIR spectrum measuring device (Shimadzu, Solidspec-3700), the result is measured based on the KS L 2514 standard, and the visible light transmittance is measured. I did.

<Emissivity>

FT-IR (Frontier, Perkin Elmer), a far-infrared spectroscopy measuring device, was used to measure the far-infrared reflectance spectrum of one side of the side coated with the low-emission coating of functional building materials for windows and doors. After calculating the average reflectance, the emissivity was evaluated by the formula of 100%-(average far-infrared reflectance).

<Color Index>

L*, a*, and b* values of the CIE1931 standard were measured using a color difference meter (KONICA MINOLTA SENSING, InC., CM-700d). At this time, the light source was applied as D65 of the KS standard.

The results evaluated as described above are as follows.

division Transmittance (%) Emissivity (%) Color index Transmission Surface reflection on the side of the low-emission coating Surface reflection on the transparent substrate side a* b* a* b* a* b* Example 1 78.6 4.8 -3.0 3.6 2.9 -12.1 0.8 -8.5 Comparative Example 1 74.5 4.8 -3.2 5.4 3.8 -11.4 2.0 -9.5

Typically, the factor affecting the emissivity is the Ag layer, and the emissivity decreases as the thickness of the Ag layer increases, but the transmittance decreases, but in order to implement a neutral color, high transmittance and low emissivity are simultaneously It must be implemented.

In addition, in the use of low-E glass for residential use, an important factor of optical performance is to achieve a neutral color by obtaining high transmittance in the same color.

From the results of Table 1, it can be seen that Example 1 exhibits similar color index and emissivity values compared to Comparative Example 1, while at the same time exhibiting improved transmittance values. Accordingly, it can be seen that Example 1 embodies a more neutral color than Comparative Example 1, and that optical performance is improved.

Experimental example 2: Evaluation of wear resistance

For the functional building materials for windows and doors prepared according to Example 1 and Comparative Example 1, an abrasion resistance test was performed using a washing machine (MANNA, MGR-460), and accordingly, scratches were observed on the surface of each of the low-emission coatings with the naked eye. The time of occurrence was measured.

Experimental example 3: Evaluation of moisture resistance-50°C, 90% RH (Humidity)

The functional building materials for windows and doors manufactured according to Example 1 and Comparative Example 1 were left in a constant temperature and humidity chamber (LS Sanjeon, EBS-35B) under the conditions of 50°C and 90% RH (humidity), and the point at which the corrosion point occurred was evaluated. I did. Using an optical microscope (X50), it was confirmed whether a corrosion point occurred in the functional building materials for windows and doors prepared according to Example 1 and Comparative Example 1.

Experimental example 4: Evaluation of moisture resistance-95°C, 95% RH (Humidity)

The functional building materials for windows and doors manufactured according to Example 1 and Comparative Example 1 were left in a constant temperature and humidity chamber (LS Sanjeon, EBS-35B) under the conditions of 50°C and 90% RH (humidity), and the point at which the corrosion point occurred was evaluated. I did. Using an optical microscope (X50), it was confirmed whether a corrosion point occurred in the functional building materials for windows and doors prepared according to Example 1 and Comparative Example 1.

The results of Experimental Example 2-3 are shown in Table 2 below.

division Wear resistance: washer
(When scratch occurs) Storage performance: humidity chamber, 50℃, 90% RH (humidity)
(When the corrosion point occurs) Storage performance: humidity chamber, 95°C, 95% RH (humidity)
(When the corrosion point occurs) Example 1 15 minutes 14 days 10 days Comparative Example 1 10 minutes 10 days 5 days

From the results of Table 2, it can be seen that Example 1 exhibits excellent abrasion resistance compared to Comparative Example 1, while at the same time exhibiting improved moisture resistance. It is determined that durability performance is improved as the upper and lower barrier layers of Example 1 are stacked.

Accordingly, it can be seen that Example 1 is more excellent than Comparative Example 1, abrasion resistance is secured, moisture resistance is improved, and overall durability performance is improved.

Although the preferred embodiments of the present invention have been described in detail above, the scope of the present invention is not limited thereto, and various modifications and improvements by those skilled in the art using the basic concept of the present invention defined in the following claims are also present. It belongs to the scope of the invention.

10: transparent substrate
11: low radiation coating
12: low emission layer
13a, 13b: low-emission protective layer
14a, 14b, 14c, 14d, 14e, 14f: dielectric layer
15: top protective layer
16a, 16b: additional high refractive layer
17a, 17b: additional low refractive layer
19a: lower barrier layer
19b: upper barrier layer
20: bottom barrier layer
100, 200, 300, 400: Functional building materials for windows and doors

Claims (12)

Including a transparent substrate and a low-emission coating formed on one surface of the transparent substrate,
The low-emission coating is sequentially stacked from the transparent substrate: a first dielectric layer, a second dielectric layer, a lower barrier layer, a third dielectric layer, a low radiation layer, a fourth dielectric layer, a fifth dielectric layer, an upper barrier layer, and a sixth dielectric layer. Including,
Further comprising at least one of a first low-emission protective layer positioned between the third dielectric layer and the low-emission layer, and a second low-emission protective layer positioned between the low-emission layer and the fourth dielectric layer,
The refractive index of the first dielectric layer and the refractive index of the third dielectric layer are respectively lower than that of the second dielectric layer,
The refractive index of the fourth dielectric layer and the refractive index of the sixth dielectric layer are respectively lower than the refractive index of the fifth dielectric layer.
Functional building material for windows and doors.
The method of claim 1,
The first dielectric layer, the third dielectric layer, the fourth dielectric layer, and the sixth dielectric layer each have a refractive index of 2.2 or less,
The second dielectric layer and the fifth dielectric layer each have a refractive index of 2.3 or more.
Functional building material for windows and doors.
The method of claim 1,
Each of the first dielectric layer, the third dielectric layer, the fourth dielectric layer, and the sixth dielectric layer is a metal of Si, Al, Zn or Sn, a composite metal including at least two of the metals, an oxide of the metal, and a nitride of the metal. , Comprising one selected from the group consisting of oxynitride of the metal, oxide of the composite metal, nitride of the composite metal, oxynitride of the composite metal, and combinations thereof
Functional building material for windows and doors.
The method of claim 1,
Each of the first dielectric layer, the third dielectric layer, the fourth dielectric layer, and the sixth dielectric layer includes silicon aluminum nitride.
Functional building material for windows and doors.
The method of claim 1,
The second dielectric layer and the fifth dielectric layer each contain one oxide, oxynitride, or both selected from the group consisting of Ti, Zr, Nb, Ta, and combinations thereof.
Functional building material for windows and doors.
The method of claim 1,
The lower barrier layer and the upper barrier layer are each: a metal of Si, Zr, Ti, Nb, Ni, or Cr, a composite metal including at least two of the metals, a nitride of the metal, a nitride of the composite metal, and these Including one selected from the group consisting of a combination of
Functional building material for windows and doors.
The method of claim 1,
An additional high refractive layer and an additional low refractive layer are sequentially stacked on top of the third dielectric layer, the sixth dielectric layer, or both, and further included,
The additional low refractive layer has a refractive index of 2.2 or less
The additional high refractive layer has a refractive index of 2.3 or more
Functional building material for windows and doors.
The method of claim 1,
The low-emission coating further includes a lowermost barrier layer positioned at the lowermost portion to be in contact with the transparent substrate,
The lowermost barrier layer is a metal of Si, Zr or Ti, a composite metal including at least two of the metals, an oxide of the metal, an oxynitride of the metal, an oxide of the composite metal, oxynitride of the composite metal, and these Including one selected from the group consisting of a combination of
Functional building material for windows and doors.
The method of claim 1,
Further comprising an uppermost protective layer over the sixth dielectric layer,
The uppermost protective layer comprises a zirconium-based compound
Functional building material for windows and doors.
The method of claim 1,
The low-emissivity layer has an emissivity of 0.01 to 0.3
Functional building material for windows and doors.
The method of claim 1,
The low-emission protective layer has an extinction coefficient of 1.5 to 3.5 in the visible light region.
Functional building material for windows and doors.
The method of claim 1,
The transparent substrate is a glass or transparent plastic substrate having a visible light transmittance of 80% to 100%
Functional building material for windows and doors.

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