KR101979625B1 - Low-emissivity coat and functional building material including low-emissivity coat for windows - Google Patents
Low-emissivity coat and functional building material including low-emissivity coat for windows Download PDFInfo
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- KR101979625B1 KR101979625B1 KR1020150099652A KR20150099652A KR101979625B1 KR 101979625 B1 KR101979625 B1 KR 101979625B1 KR 1020150099652 A KR1020150099652 A KR 1020150099652A KR 20150099652 A KR20150099652 A KR 20150099652A KR 101979625 B1 KR101979625 B1 KR 101979625B1
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- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
- C03C17/22—Surface treatment of glass, not in the form of fibres or filaments, by coating with other inorganic material
- C03C17/225—Nitrides
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- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
- C03C17/34—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions
- C03C17/36—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal
- C03C17/3602—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal the metal being present as a layer
- C03C17/361—Coatings of the type glass/metal/inorganic compound/metal/inorganic compound/other
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- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
- C03C17/34—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions
- C03C17/36—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal
- C03C17/3602—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal the metal being present as a layer
- C03C17/3681—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal the metal being present as a layer the multilayer coating being used in glazing, e.g. windows or windscreens
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- E—FIXED CONSTRUCTIONS
- E06—DOORS, WINDOWS, SHUTTERS, OR ROLLER BLINDS IN GENERAL; LADDERS
- E06B—FIXED OR MOVABLE CLOSURES FOR OPENINGS IN BUILDINGS, VEHICLES, FENCES OR LIKE ENCLOSURES IN GENERAL, e.g. DOORS, WINDOWS, BLINDS, GATES
- E06B5/00—Doors, windows, or like closures for special purposes; Border constructions therefor
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- Geochemistry & Mineralogy (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Civil Engineering (AREA)
- Structural Engineering (AREA)
- Surface Treatment Of Glass (AREA)
Abstract
Sequentially, a first dielectric layer comprising silicon aluminum nitride; Low radiation layer; And a second dielectric layer comprising silicon aluminum nitride, wherein the refractive index of the first dielectric layer is higher than the refractive index of the second dielectric layer, and a functional building material for a window comprising the same.
Description
Low-emission coatings, and low-emission coatings.
Low-emissivity glass refers to glass in which a low-emission layer containing a metal with a high reflectance in the infrared region is deposited as a thin film, such as silver (Ag). These low-emission glass is a functional material that reflects radiation in the infrared region, shields outdoor solar radiation in summer, and conserves indoor radiant heat in winter, thereby reducing energy consumption of buildings.
Since silver (Ag) used as such a low-emission layer is oxidized when exposed to air, a dielectric layer is deposited on the upper and lower portions of the low-emission layer as an oxidation-resistant layer, but these alone can not effectively prevent oxidation.
In addition, the glass is usually subjected to a tempering process in order to improve the impact strength and the heat resistance to enhance the stability. Such a strengthening process is performed, for example, at a high temperature condition of about 700 캜. Alkali ions such as sodium ions (Na + ) are discharged from the inside of the glass due to the strengthening process at a high temperature condition and moved toward the low radiation coating. Partially pushing out the low radiation layer formed of the alkali ions moved by silver The low-emission coating can be damaged, such as silver oxide being formed on the surface as the silver (Ag) is oxidized to the surface of the low-emission glass.
One embodiment of the present invention provides a low emissivity coating that provides excellent durability by effectively improving heat resistance and abrasion resistance.
Another embodiment of the present invention provides a functional building material for a window comprising the low emissivity coating.
In one embodiment of the present invention, sequentially, a first dielectric layer comprising silicon aluminum nitride; Low radiation layer; And a second dielectric layer comprising silicon aluminum nitride, wherein the refractive index of the first dielectric layer is lower than the refractive index of the second dielectric layer.
The first dielectric layer may have a refractive index of about 2.1 to about 2.3 at a wavelength of 550 nm.
The second dielectric layer may have a refractive index of about 1.8 to about 2.0 at a wavelength of 550 nm.
The thickness of the first dielectric layer may be between about 20 nm and about 60 nm.
The thickness of the second dielectric layer may be between about 20 nm and about 60 nm.
And a barrier layer laminated on at least one side of the low-emission layer, wherein the barrier layer includes a metal and may not include a metal oxide.
Wherein the barrier layer is selected from the group consisting of Ni, Cr, Nb, Ni-Cr, Ti, Ni-Ti, And may include at least one metal.
The thickness of the barrier layer may be from about 0.5 nm to about 3.0 nm.
The low-emission layer may include at least one selected from the group consisting of Ag, Au, Cu, Al, Pt, Pd, and combinations thereof.
The thickness of the low emissivity layer may be from about 5 nm to about 25 nm.
A metal layer on the second dielectric layer; A metal oxide layer; And a silicon-based or zirconium-based composite metal oxynitride layer.
The metal layer may include at least one selected from the group consisting of silicon, aluminum, titanium, zirconium, a silicon compound metal, a titanium compound metal, a zirconium compound metal and a combination thereof, and may have a thickness of about 0.5 nm to about 5 nm.
Wherein the metal oxide layer contains at least one selected from the group consisting of silicon oxide, aluminum oxide, titanium oxide, zirconium oxide, silicon compound metal oxide, titanium compound metal oxide, zirconium compound metal oxide, nm to about 5 nm.
The thickness of the silicon-based or zirconium-based composite metal oxynitride layer may be about 2 nm to about 20 nm.
In another embodiment of the present invention, a transparent substrate; And a low-emission coating coated on at least one side of the transparent substrate.
The transparent substrate may be a glass or transparent plastic substrate having a visible light transmittance of about 80% to about 100%.
The low emissivity coating can achieve excellent durability by effectively improving heat resistance, moisture resistance, acid resistance and abrasion resistance.
Figure 1 is a schematic cross-sectional view of a low emissivity coating according to one embodiment of the present invention.
Figure 2 is a schematic cross-sectional view of a low emissivity coating according to one embodiment further comprising a barrier layer.
3 is a schematic cross-sectional view of a low emissivity coating according to one embodiment further comprising a barrier layer and a protective layer.
4 is a schematic cross-sectional view of a functional building material for a window according to another embodiment of the present invention.
5 is an optical microscope image of the surface of the low emissivity coating after evaluation of heat resistance under specific conditions for the low emissivity coating prepared in Example 1 and Comparative Example 1 of the present invention.
6 is an optical microscope image of the surface of the low emissivity coating after evaluation of moisture resistance under specific conditions for the low emissivity coating prepared in Example 1 and Comparative Example 1 of the present invention.
7 is an optical microscope image of the surface of the low emissivity coating after evaluation of chemical resistance under specific conditions for the low emissivity coating prepared in Example 1 and Comparative Example 1 of the present invention.
8 is a graph showing the change in color index of each low-emission coating prepared in Example 1 and Comparative Example 1 after moisture resistance evaluation under specific conditions.
Hereinafter, exemplary embodiments of the present invention will be described in detail with reference to the accompanying drawings, which will be readily apparent to those skilled in the art to which the present invention pertains. The present invention may be embodied in many different forms and is not limited to the embodiments described herein.
In order to clearly illustrate the present invention, parts not related to the description are omitted, and the same or similar components are denoted by the same reference numerals throughout the specification.
In the drawings, the thickness is enlarged to clearly represent the layers and regions. In the drawings, for the convenience of explanation, the thicknesses of some layers and regions are exaggerated.
Hereinafter, the formation of any structure in the "upper (or lower)" or the "upper (or lower)" of the substrate means that any structure is formed in contact with the upper surface (or lower surface) of the substrate However, the present invention is not limited to not including other configurations between the substrate and any structure formed on (or under) the substrate.
In one embodiment of the present invention, sequentially, a first dielectric layer comprising silicon aluminum nitride; Low radiation layer; And a second dielectric layer comprising silicon aluminum nitride, wherein the refractive index of the first dielectric layer is lower than the refractive index of the second dielectric layer.
The low emissivity coating can be formed as a multilayer thin film structure based on a low emissivity layer that selectively reflects far infrared rays among solar radiation and can be formed by lowering the emissivity to a low emissivity, ) Effect.
The low-emission coating is formed as described above. For example, when applied as a coating film of a window glass, it minimizes heat transfer between indoor and outdoor by reflecting outdoor solar radiation in summer and preserving indoor heating radiation in winter, It is a functional material that brings energy saving effect of buildings.
'Emissivity' is the rate at which an object absorbs, transmits, and reflects energy with a certain wavelength. That is, in this specification, the emissivity refers to the degree of absorption of infrared energy in the infrared wavelength range. Specifically, when the far infrared ray corresponding to the wavelength range of about 5 탆 to about 50 탆 is applied, Means the ratio of infrared energy absorbed to infrared energy.
According to Kirchhoff's law, the infrared energy absorbed by an object is equal to the infrared energy emitted by the object again, so the absorption and emissivity of the object are the same.
Also, because the infrared energy that is not absorbed is reflected from the surface of the object, the higher the reflectance of the object to the infrared energy, the lower the emissivity. Numerically, it has a relation of (emissivity = 1 - infrared reflectance).
Such emissivity can be measured by various methods commonly known in the art, and can be measured by a facility such as a Fourier transform infrared spectroscope (FT-IR) according to the KSL2514 standard.
The absorption rate, that is, the emissivity, of far-infrared rays exhibiting such a strong heat action, such as an arbitrary object, for example, low-emission glass, may have a very important meaning in measuring the heat insulation performance.
As described above, the low-emission coating is used as a coating on a transparent substrate such as, for example, glass to maintain a predetermined transmittance property in the visible light region, thereby realizing excellent light-emitting properties. In the infrared region, It can be used as functional building material for energy-saving window which can provide excellent insulation effect.
In order to improve the impact resistance and heat resistance, a functional building material such as a window glass is inevitably subjected to a tempering process performed at a high temperature of about 700 ° C. or more. Alkali ions such as sodium ion (Na + ) escape and diffuse into the low radiation coating film. As the alkali ions are diffused, the low spinning layer of the low spinning coating film is pressurized by the diffusion of the alkali ions, and the Ag, Au, Cu, Al, Pt, Pd, And oxidation occurs while exposed to the air, thereby damaging the low radiation coating.
Accordingly, the low-emission coating according to an embodiment of the present invention is characterized in that the first dielectric layer and the second dielectric layer include silicon-aluminum nitride (SiAlN x ), and the refractive index of the first dielectric layer is the second By appropriately adjusting the silicon aluminum and nitrogen contents of the silicon aluminum nitride to be relatively higher than the refractive index of the dielectric layer in the respective layers, the first dielectric layer is formed by the migration of the alkali ions by the strengthening process, The second dielectric layer can effectively prevent the damage of the low radiation coating due to the strengthening process while effectively preventing the metal or metal ions such as Ag, Au, Cu, Al, Pt, and Pd contained in the radiation layer from moving So that excellent heat resistance and excellent abrasion resistance can be realized.
Specifically, the first dielectric layer includes a silicon aluminum nitride having a relatively high content of silicon aluminum and a low nitrogen content and a low density so as to have a higher refractive index than the second dielectric layer, And diffusion of oxygen can be effectively suppressed.
At the same time, the second dielectric layer is relatively low in silicon aluminum content so as to have a lower refractive index than the first dielectric layer, but has high nitrogen content and high density silicon aluminum nitride, thereby further improving mechanical durability have.
Accordingly, the low-spin coating effectively prevents damage to the low-spin coating due to a high-temperature tempering process that is essentially required after coating, for example, on a transparent substrate such as glass, thereby improving heat resistance and abrasion resistance, Can be maintained.
Figure 1 schematically illustrates a cross-section of a
The
The
The low-
In one embodiment, the
The thickness of the
The
The
Each of the
For example, the
Specifically, the
The
In addition, for example, the
Specifically, the
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The refractive index of the
The thickness of the
The thickness of the
In one embodiment, the low-
The
Generally, in order to protect the low radiation layer, a metal oxide layer is laminated on both sides or a metal layer and a metal oxide layer are sequentially laminated. In the case where the metal oxide layer is included, the low radiation glass The metal oxide layer at the edge face of the rim has a problem of promoting the corrosion of the low radiation layer.
In a
For example, when the
The thickness of the
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In one embodiment, the
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If the thickness of the
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Particularly, when the formation of the
That is, in the case where the
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The silicon-based or zirconium-based composite
For example, the silicon-based composite metal oxynitride may include silicon aluminum oxynitride, and the zirconium-based composite metal oxynitride may include zirconium aluminum oxynitride, , But is not limited thereto.
At this time, the deposition of the silicon-based or zirconium-based composite metal oxynitride can be performed at the same time as forming the metal oxide layer by partially oxidizing the surface of the metal layer, as described above.
The thickness of the silicon-based or zirconium-based composite
In another embodiment of the present invention, a transparent substrate; And the low radiation coating coated on at least one side of the transparent substrate.
4 is a cross-sectional view of the
The
The
The low spin coating can be achieved by controlling the transmittance and the reflectance according to the wavelength of light by adjusting the material and thickness of each layer constituting the low spin coating in order to realize an optical spectrum suitable for the purpose of use. For example, the low spin coating improves light fastness by increasing the visible light transmittance, thereby securing a clear visual field while reducing the infrared emissivity and securing an excellent heat insulating effect.
By controlling the material and thickness of each layer constituting the low spin coating, it is possible to finely control the optical performance such as hue, reflectivity and transmittance of the high reflection surface of the low spin coating as seen from the outside.
Hereinafter, examples and comparative examples of the present invention will be described. The following embodiments are only examples of the present invention, and the present invention is not limited to the following embodiments.
( Example )
Using a magnetron sputtering evaporator (manufacturer Selcos, trade name Cetus-S), a low emissivity coating of a multilayer structure coated on a transparent glass substrate was prepared as follows.
Example One
A SiAl target (manufactured by GfE, Germany) having Si: Al = 9: 1 was deposited on a transparent glass substrate having a thickness of 6 mm under an atmosphere of argon / nitrogen (argon: nitrogen flow rate = 80: A barrier layer is formed by depositing NiCr to a thickness of 0.5 nm on the upper surface of the first dielectric layer in an atmosphere of 100% argon to form a barrier layer, and a 100% argon atmosphere To form a low-emission layer having a thickness of 7 nm, an NiCr layer having a thickness of 0.5 nm was deposited on the upper surface of the low-emission layer in an atmosphere of 100% argon to form a barrier layer, : A SiAl target (manufactured by GfE, Germany) having Al = 9: 1 was deposited under a nitrogen / argon / nitrogene (argon: nitrogen flow rate = 80:20) atmosphere to form a second dielectric layer having a thickness of 35 nm . Subsequently, zirconium is deposited on the upper surface of the second dielectric layer as a protective layer in an atmosphere of 100% argon to form a zirconium layer having a thickness of 4 to 5 nm, and then a post-oxidation process is performed on the surface of the metal layer, The surface of the zirconium layer was partially oxidized to form a zirconium oxide layer having a thickness of 3 to 4 nm. The surface of the zirconium layer was partially oxidized to form a zirconium oxide layer, and silicon aluminum oxynitride was deposited to form a silicon aluminum oxynitride A low emissivity coating coated on a clear glass substrate was prepared by forming a layer.
The low spin coating had a refractive index of 2.15 for the first dielectric layer and a refractive index of 1.94 for the second dielectric layer at a wavelength of 550 nm.
Comparative Example 1 (the refractive index of the first dielectric layer is the same as the refractive index of the second dielectric layer)
A SiAl target (manufactured by GfE, Germany) having Si: Al = 9: 1 was deposited on a transparent glass substrate having a thickness of 6 mm under the atmosphere of argon / nitrogen (argon: nitrogen flow rate = 80:20) Depositing a first dielectric layer having a thickness of 35 nm on the first dielectric layer and depositing a zinc aluminum oxide on the upper surface of the first dielectric layer under an atmosphere of 100% argon to form a zinc aluminum oxide layer having a thickness of 6 nm, A barrier layer was formed by depositing NiCr to a thickness of 0.5 nm in an argon atmosphere of 100%, Ag was deposited on the upper surface of the barrier layer in an atmosphere of 100% argon to form a low-emission layer with a thickness of 7 nm, A barrier layer was formed by depositing NiCr to a thickness of 0.5 nm in an atmosphere of 100% argon to form a barrier layer. On the upper surface of the barrier layer, zinc aluminum oxide A SiAl target (manufactured by GfE, Germany) having Si: Al = 9: 1 was coated on the upper surface of the aluminum oxide layer to form a 6 nm thick zinc oxide layer on the upper surface of the aluminum oxide layer, and a reactive gas containing argon / Under the atmosphere of argon: nitrogen = 80: 20) to form a second dielectric layer with a thickness of 35 nm.
The low spin coating had a refractive index of 1.94 for the first dielectric layer and a refractive index of 1.94 for the second dielectric layer at a wavelength of 550 nm.
Comparative Example 2 ( Comparative Example 1 to the protective layer)
A zinc-aluminum oxide layer, a barrier layer, a low-emission layer, a barrier layer, and a zinc-aluminum-oxide layer were formed in sequence on the upper surface of the second dielectric layer in the same manner as in Comparative Example 1, As a protective layer, zirconium is deposited in a 100% argon atmosphere to form a 4 to 5 nm thick zirconium layer, and a post-oxidation process is performed on the surface of the metal layer to partially oxidize the surface of the zirconium layer to form a 3-4 nm thick zirconium oxide A surface of the zirconium layer is partially oxidized to form a zirconium oxide layer and silicon aluminum oxynitride is deposited to form a silicon aluminum oxynitride layer having a thickness of 10 nm to form a low- Coating.
The low spin coating had a refractive index of 1.94 for the first dielectric layer and a refractive index of 1.94 for the second dielectric layer at a wavelength of 550 nm.
Comparative Example 3 ( Comparative Example In 2 Zinc aluminum oxide layer remove)
A SiAl target (manufactured by GfE, Germany) having Si: Al = 9: 1 was deposited on a transparent glass substrate having a thickness of 6 mm under the atmosphere of argon / nitrogen (argon: nitrogen flow rate = 80:20) A barrier layer is formed by depositing NiCr to a thickness of 0.5 nm on the upper surface of the first dielectric layer in an atmosphere of 100% argon to form a barrier layer, and a 100% argon atmosphere To form a low-emission layer having a thickness of 7 nm, an NiCr layer having a thickness of 0.5 nm was deposited on the upper surface of the low-emission layer in an atmosphere of 100% argon to form a barrier layer, : A SiAl target (manufactured by GfE, Germany) having Al = 9: 1 was deposited under a nitrogen / argon / nitrogene (argon: nitrogen flow rate = 80:20) atmosphere to form a second dielectric layer having a thickness of 35 nm And , Zirconium is deposited on the upper surface of the second dielectric layer as a protective layer in an atmosphere of 100% argon to form a zirconium layer having a thickness of 4 to 5 nm and then a post-oxidation process is performed on the surface of the metal layer, Oxidized to form a zirconium oxide layer having a thickness of 3 to 4 nm, a surface of the zirconium layer is partially oxidized to form a zirconium oxide layer, and silicon aluminum oxynitride is deposited to form a silicon aluminum oxynitride layer having a thickness of 10 nm To produce a low emissivity coating coated on a clear glass substrate.
The low spin coating had a refractive index of 1.94 for the first dielectric layer and a refractive index of 1.94 for the second dielectric layer at a wavelength of 550 nm.
evaluation
The properties of the low emissivity coating coated on the transparent glass substrate of Example 1 and Comparative Example 1-3 were evaluated as described below and are shown in Table 1 below.
1. Evaluation of refractive index
The refractive indices at a wavelength of about 550 nm were calculated for each of the first and second dielectric layers of the low spin coating coated on the transparent glass substrate of Example 1 and Comparative Example 1-3.
Measuring method: The optical spectrum of each dielectric layer as a single layer was measured for a wavelength of 250 to 4500 nm using a spectrophotometer (manufactured by SHIMADZU, manufactured by SolidSpec-3700) to obtain transmission, coating reflection and glass reflection, The refractive index values were calculated by substituting the values into the equations, and the values for the wavelengths of about 550 nm were evaluated as the refractive indexes.
2. Evaluation of heat resistance
The low emissivity coatings coated on the transparent glass substrates of Example 1 and Comparative Example 1-3 were subjected to a strengthening test to measure the heat resistance.
Measuring method: Measured using a laboratory box furnace (AJEON HEATING INDUSTRIAL CO. LTD.). Specifically, the inside temperature of the large electric furnace was set at 700 캜 and left for 7 minutes I took it out. Subsequently, the sample was allowed to stand at room temperature to be slowly cooled, and then the degree of defects on the surface of each low-radiated coating was observed using an optical microscope (Nikon,
The surface of each of the low-emission coatings thus observed was photographed with the above-mentioned optical microscope image and is shown in Fig.
3. Evaluation of moisture resistance
Under the conditions of 100 ° C and 98% RH (humidity), 14 (light) was applied to the transparent glass substrate coated with the transparent glass substrate of Example 1 and Comparative Example 1-3 using a constant temperature and humidity chamber (LSISON, And the humidity resistance was measured.
Measurement method: The number of corrosion points was measured using an optical microscope (Nikon, ECLIPSE LV 100) (X200).
Thus, the surface of the low emissivity coating with corrosion after the moisture resistance evaluation was photographed with the above optical microscope image and is shown in Fig.
4. Chemical resistance evaluation
The low emissivity coating coated on the transparent glass substrate of Example 1 and Comparative Example 1-3 was immersed in a Sigma Aldrich HCl solution of
Measurement method: A change in color index before and after immersion was measured using a spectrophotometer (KONICA MINOLTA, model name VTLCM-700).
7 shows a graph of measured change in color index, and the surface of the low-radiated coating having the color index changed after measurement of chemical resistance was photographed with an optical microscope (Nikon, ECLIPSE LV 100) (X200) Respectively.
Specifically, in the graph of Fig. 8, the color (T) on the X axis represents the color transmitted through the transparent glass substrate coated with the low radiation coating, the color (R) represents the color reflected from the low radiation coated surface, S) represents the color reflected from the transparent glass substrate surface, and ΔE = (ΔL 2 + Δa 2 + Δb 2 ) 1/2 on the Y axis represents the color index change value.
5. Evaluation of wear resistance
The abrasion resistance before and after the strengthening test was measured for the low emissivity coatings coated on the clear glass substrates of Example 1 and Comparative Example 1-3, respectively.
Measuring method: A wear resistance test was performed using a washing machine (MANNA, MGR-460), and visually observing whether or not scratches occurred on the surface of each low-radiated coating were observed, and scratches And the mechanical durability was evaluated. The scratches were observed to have a width of at least about 50 탆 which is the minimum size that can be distinguished upon visual observation.
6. Evaluation of edge face corrosion
The low spin coating coated on the transparent glass substrate of Example 1 and Comparative Example 1-3 was allowed to stand for 14 days under the conditions of 98 ° C and 100% RH (humidity) to measure the corrosion depth of the low spinning layer Respectively.
Measurement method: An optical microscope image of the low-emission layer of the end face was photographed using an optical microscope (Nikon,
(Count)
Corrosive depth (㎛)
Coating Reflectance (R): 0.06
Glass reflection (S): 0.05
After fortification: 6 minutes
Coating Reflectance (R): 1.77
Glass reflection (S): 0.98
After fortification: 1 minute
Coating Reflectance (R): 0.23
Glass reflection (S): 0.29
After fortification: 5 minutes
Coating Reflectance (R): 0.06
Glass reflection (S): 0.07
After fortification: 1
As shown in Table 1, the low-emission coating of Example 1 exhibited excellent resistance to moisture due to only a few corrosion points, and a remarkably small change in color index, which was excellent in chemical resistance. In particular, It can be clearly seen that both the heat resistance and the abrasion resistance are remarkably excellent even when the scratches start to occur even after the application of the scratches. In addition, it can be confirmed that the corrosion depth at the end face is significantly reduced to 80 탆, which effectively reduces edge corrosion.
On the other hand, in the low spin coating of Comparative Example 1, the number of corrosion points increased by a factor of 100, the moisture resistance was remarkably inferior, the color index change value was remarkably large and the chemical resistance was inferior, and after the high temperature tempering process was applied, It is found that the low-radiation coating is damaged because the time for starting to start is only one minute, which is inferior in heat resistance and abrasion resistance. In addition, the corrosion depth on the end face increased by 100 times, indicating that the corrosion occurred remarkably on the end face.
In addition, the low spin coating of Comparative Example 2 has good anti-abrasion properties measured at about 5 minutes before and after strengthening, but the number of corrosion points is 60, which is inferior in moisture resistance and has a large change in color index, which is inferior in chemical resistance. In addition, it can be seen that the corrosion depth on the end face is deep and the corrosion has remarkably occurred.
In addition, the low spin coating of Comparative Example 3 had five corrosion points with good moisture resistance and a small change in color index, which is excellent in chemical resistance. However, after application of a high temperature tempering process, Is only one minute, which is a value corresponding to 1/6 of that of Example 1, so that the low radiation coating is remarkably damaged and the heat resistance and abrasion resistance are remarkably inferior. In addition, it can be confirmed that the corrosion depth of the end face is 100 μm, and the corrosion of the end face is further promoted by the damage of the low radiation coating.
100, 200, 300: low radiation coating
400: low emission glass
110: first dielectric layer
120: second dielectric layer
130: low radiation layer
140: barrier layer
150: protective layer
151: metal layer
152: metal oxide layer
153: a silicon-based or zirconium-based composite metal oxynitride layer
160: substrate
Claims (18)
Further comprising a barrier layer having a refractive index higher than that of the second dielectric layer and stacked on both sides of the lower radiation layer, wherein the barrier layer includes a metal and does not include a metal oxide,
The first dielectric layer is formed by depositing silicon aluminum as a sputtering target in a reactive gas atmosphere having a flow ratio of argon gas to nitrogen gas in a range of 5: 1 to 8: 1,
The second dielectric layer is formed by depositing silicon aluminum as a sputtering target in a reactive gas atmosphere having a flow ratio of argon gas to nitrogen gas of 1: 1 to 4: 1
Low radiation coating.
Wherein the first dielectric layer has a refractive index of 2.1 to 2.3 at a wavelength of 550 nm
Low radiation coating.
Wherein the second dielectric layer has a refractive index of 1.8 to 2.0 at a wavelength of 550 nm
Low radiation coating.
Wherein the barrier layer has a thickness of 0.5 nm to 3.0 nm
Low radiation coating.
A metal layer on the second dielectric layer; A metal oxide layer; And a silicon-based or zirconium-based composite metal oxynitride layer,
Low radiation coating.
Wherein the metal layer comprises at least one selected from the group consisting of silicon, aluminum, titanium, zirconium, a silicon based composite metal, a titanium based composite metal, a zirconium based composite metal and combinations thereof,
Low radiation coating.
Wherein the metal oxide layer contains at least one selected from the group consisting of silicon oxide, aluminum oxide, titanium oxide, zirconium oxide, silicon based composite metal oxide, titanium based composite metal oxide, zirconium based composite metal oxide and combinations thereof, 5 nm
Low radiation coating.
The thickness of the silicon-based or zirconium-based composite metal oxynitride layer is preferably from 2 nm to 20 nm
Low radiation coating.
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KR101934062B1 (en) | 2015-09-14 | 2019-01-02 | (주)엘지하우시스 | Functional building material including low-emissivity coat for windows |
KR101873103B1 (en) * | 2016-09-06 | 2018-06-29 | (주)엘지하우시스 | Functional building material including low-emissivity coat for windows |
KR101968813B1 (en) * | 2017-02-17 | 2019-04-15 | 주식회사 케이씨씨 | Reflective Coated Substrate |
JP6972317B2 (en) * | 2017-09-08 | 2021-11-24 | エルエックス・ハウシス・リミテッドLx Hausys, Ltd. | Functional building materials for window doors |
KR102157540B1 (en) * | 2017-12-06 | 2020-09-18 | (주)엘지하우시스 | Functional building material including low-emissivity coat for windows |
KR102190680B1 (en) * | 2020-09-10 | 2020-12-14 | (주)엘지하우시스 | Functional building material including low-emissivity coat for windows |
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JP2006248871A (en) | 2005-03-14 | 2006-09-21 | Nippon Electric Glass Co Ltd | Peep window member, and its production method |
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KR20090099364A (en) * | 2008-03-17 | 2009-09-22 | 주식회사 케이씨씨 | A temperable low-emissivity glass with enhanced durability and a method for preparing the same |
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