KR102177649B1 - Gel type toilet deodorant containing herbal extract - Google Patents

Abstract

The present invention relates to a gel-type toilet bowl deodorant composition including oriental medicine extract and a method for manufacturing the same, comprising the oriental medicine extract as an active ingredient, and the oriental medicine extract is primrose meat, so as to adsorb and decompose nitrogen compounds and sulfur compounds, which are major odor components. It has been confirmed that it has excellent deodorizing power and deodorizing sustaining power, and it is eco-friendly because it is made of natural ingredients, and has a harmless effect to the human body.

Description

Gel type toilet deodorant containing herbal extract}

The present invention relates to a gel-type toilet deodorant composition and a method for producing the same, including the herbal extract.

In general, a deodorant refers to a drug that removes or weakens odor, and includes a physical removal method, a chemical removal method, a biological removal method, and a sensory deodorization method.

Among them, the physical removal method is a method of removing odor substances by adsorbing or trapping odor components on the surface as compounds with strong adsorption and trapping properties such as activated carbon or silica, and the chemical removal methods are neutralization, addition, polymerization, oxidation, reduction and It is a method of removing odor by decomposing or changing the odor-causing component by applying a strong reactive substance to the odor component by using a chemical reaction such as hydrolysis.

In addition, the biological chemical removal method is a method of blocking the generation of odor components by bacteria through sterilization by cationic surfactants and disinfectants, or by decomposing organic acids, which are odor components, using digestive enzymes, bacteria, yeast, etc. The sensory deodorization method is a odor that neutralizes sensational odors or offsets odors by using scented fragrances for target odor components, and is a method of removing by masking.

The odor components include acidic odor substances (sulfur compounds, organic acids) and alkaline odor substances (nitrogen compounds), but toilet cleaners and fragrances used in conventional toilets are sensationally deodorized when the scent is volatilized. There has been a problem in that it is impossible to remove completely, and causes environmental pollution or contains a large amount of harmful components.

Therefore, it is possible to remove the causative component of the odor through a chemical reaction with the odor component, and to solve the problem of odor in the toilet bowl by manufacturing an eco-friendly toilet deodorant.

Republic of Korea Patent Publication No. 10-2000-0077090

An object of the present invention is to provide an eco-friendly gel-type deodorant composition capable of simultaneously removing nitrogen compounds and sulfur compounds among malodorous components.

In addition, another object of the present invention is to provide a method for preparing a gel-type deodorant composition.

In order to achieve the above object, the present invention includes an herbal extract as an active ingredient, and the herbal extract provides a gel-type deodorant composition, characterized in that the primrose meat.

In addition, the present invention comprises the steps of preparing an herbal extract containing cherry primrose; Preparing a gelling agent; Preparing a mixed solution by mixing the herbal extract, solubilizing agent, food coloring, dispersion stabilizer, flavoring and antifoaming agent with the gelling agent and stirring at a temperature of 60°C to 120°C for 30 minutes to 2 hours; And it provides a method for producing a gel-type deodorant composition comprising a; and the step of preparing a gel composition by cooling the mixture after adding the solution to a mold.

The gel-type deodorant including the herbal extract according to the present invention can simultaneously remove nitrogen compounds and sulfur compounds among malodorous components, and thus is effective in removing odors generated in the bathroom.

In addition, the gel-type deodorant including the herbal extract according to the present invention is immersed in a toilet storage tank so that the deodorant component is released into the stored water, so that when the deodorant component is introduced into the toilet with water after using the toilet, the deodorizing effect and the subsequent water supply As it contains deodorizing ingredients, it can have a lasting deodorizing power.

In addition, the gel-type deodorant including the herbal extract according to the present invention is made of natural ingredients, is harmless to the human body, and has an environmentally friendly effect.

1 is a diagram showing an analysis process of evaluating deodorizing power according to the present invention.

Hereinafter, the present invention will be described in detail.

The present inventors have prepared a gel-type deodorant containing herbal extracts, and have confirmed that it is excellent in deodorizing power and deodorizing lasting power because it can adsorb and decompose nitrogen compounds and sulfur compounds, which are major odor components generated in the bathroom, and is made of natural ingredients and is eco-friendly, The present invention was completed by finding that it has a harmless effect on the human body.

The present invention includes an herbal extract as an active ingredient, and the herbal extract provides a gel-type deodorant composition, characterized in that it is primrose meat.

In addition, the herbal extract may further include any one or more selected from the group consisting of Dansam, Chinese quince, Jacaranda, Alum, Bodu, Sangsangcho, Omae, Cheonnyeonja, and landing, and any herbal extract known as a deodorant is all without limitation. Can be used.

In this case, the herbal extract may be an herbal extract extracted from herbal materials using water or an organic solvent including ethanol, hexane, or the like. Preferably, it may be extracted from the herbal material by the hot water extraction method, and more preferably, 10 g of the herbal material is added to 1L of water, and hot water extraction may be performed at 110° C. for 60 minutes, but is not limited thereto.

In addition, the herbal extract is characterized in that it contains 0.1 to 10 parts by weight based on 100 parts by weight of the composition, and the gel-type deodorant composition may further include a gelling agent, a solubilizing agent, a dispersion stabilizer, and an antifoaming agent.

At this time, the gelling agent may include any one or more from the group consisting of carrageenan, agar, konjac, gelatin, pectin, collagen, starch, alginic acid, locust bean gum, guar gum, and xanthan gum, and the solubilizing agent is fatty acid monoglycerin ester , Fatty acid polyglycol esters, fatty acid sorbitan esters, fatty acid sucrose esters, fatty acid alkanolamides, polyhydric alcohol derivatives, polyethylene glycol derivatives, etc., nonionic solubilizing agents, fatty acid soaps, sulfonates, sulfate ester salts, phosphate ester salts, etc. It may include any one or more from the group consisting of a sexual solubilizing agent or an amphoteric solubilizing agent such as coconut amidopropylbetaine, laurylbetaine, imidazoline, amino compound, quaternary ammonium salt, etc., but is not limited thereto.

In addition, the dispersion stabilizer is 3-methyl-3-methoxybutanol, 2-(2-butoxyethoxy) ethanol, pyrrolidone, ethanol, propanol, isopropanol, butanol, ethylene glycol, diethylene glycol, It may include any one or more from the group consisting of triethylene glycol, and the antifoaming agent is a silicone-based or polyethylene glycol, polypropylene glycol, polyalkylvinyl ether, amide ester, tall oil, decanoic acid, lauric acid, such as dimethylpolysiloxane, polysiloxane, and silicon fluoride. Acid, myristic acid, mineral oil, sorbitan monostearate, stearic acid, oxysteain, oleic acid, may include any one or more of non-silicone such as palmitic acid, but is not limited thereto.

In addition, the present invention comprises the steps of preparing an herbal extract containing cherry primrose; Preparing a gelling agent; Preparing a mixed solution by mixing the herbal extract, solubilizing agent, food coloring, dispersion stabilizer, flavoring and antifoaming agent with the gelling agent and stirring at a temperature of 60°C to 120°C for 30 minutes to 2 hours; And it provides a method for producing a gel-type deodorant composition comprising a; and the step of preparing a gel composition by cooling the mixture after adding the solution to a mold.

At this time, the herbal extract may further include any one or more selected from the group consisting of Dansam, Chinese quince, Jacaranda, Alum, Bodu, Sangsangcho, Omae, Cheonnyeonja, and landing, and all herbal extracts known as deodorants are not limited. Can be used.

In this case, the herbal extract may be an herbal extract extracted from herbal materials using water or an organic solvent including ethanol, hexane, or the like. Preferably, it may be extracted from the herbal material by the hot water extraction method, and more preferably, 10 g of the herbal material is added to 1L of water, and hot water extraction may be performed at 110° C. for 60 minutes, but is not limited thereto.

In addition, the step of preparing the gelling agent is prepared by heating and dissolving any one or more from the group consisting of carrageenan, agar, konjac, gelatin, pectin, collagen, starch, alginic acid, locust bean gum, guar gum, and xanthan gum in purified water. The gelling agent may be prepared by adding carrageenan to purified water and heating at 80° C. for 6 hours, but is not limited thereto.

In addition, the solubilizing agent is a nonionic solubilizing agent such as fatty acid monoglycerin ester, fatty acid polyglycol ester, fatty acid sorbitan ester, fatty acid sucrose ester, fatty acid alkanolamide, polyhydric alcohol derivative, polyethylene glycol derivative, etc., fatty acid soap, sulfonate, sulfuric acid Include any one or more from the group consisting of anionic solubilizing agents such as ester salts, phosphate ester salts, etc. or amphoteric solubilizing agents such as coconut amidopropyl betaine, lauryl betaine, imidazoline, amino compounds, quaternary ammonium salts, etc. However, it is not limited thereto.

In addition, the dispersion stabilizer is 3-methyl-3-methoxybutanol, 2-(2-butoxyethoxy)ethanol, pyrrolidone, ethanol, propanol, isopropanol, butanol, ethylene glycol, diethylene glycol, triethylene glycol It may include any one or more from the group consisting of, and the antifoaming agent is a silicone-based or polyethylene glycol, polypropylene glycol, polyalkyl vinyl ether, amide ester, tall oil, decanoic acid, lauric acid, etc. It may include any one or more of non-silicone type such as stickic acid, mineral oil, sorbitan monostearate, stearic acid, oxysteain, oleic acid, palmitic acid, etc., but is not limited thereto.

In addition, the fragrance includes natural and synthetic fragrances commonly used in the art, but nitro-based and polycyclic fragrances are artificial musk materials, and studies on human and environmental pollution due to toxicity and persistence are being conducted. It is preferable not to use nitro-based and polycyclic fragrances because they are warning of harmfulness.

In addition, as the food coloring, any food coloring generally used in the art may be used.

In addition, the gel-type deodorant composition includes 38 to 97.1 parts by weight of purified water, 1 to 10 parts by weight of gelling agent, 0.1 to 10 parts by weight of herbal extract, 0.1 to 2 parts by weight of food coloring, 0.5 to 20 parts by weight of solubilizing agent, based on a total of 100 parts by weight. Parts, 1 to 10 parts by weight of a dispersion stabilizer, 0.1 to 8 parts by weight of a fragrance, and 0.1 to 2 parts by weight of an antifoaming agent.

At this time, if the temperature, time conditions of the gel-type deodorant composition manufacturing method, and the weight part conditions of each component are out, the gel-type deodorant having excellent deodorizing power according to the present invention is not properly formed, or the yield of the target product is significantly lowered, which is not economical Can be caused.

Hereinafter, the present invention will be described in more detail through examples. These examples are only for describing the present invention in more detail, and that the scope of the present invention is not limited by these examples according to the gist of the present invention, to those of ordinary skill in the art. It will be self-evident.

< Example 1> Cherry tree Manufacture of gel-type toilet deodorant containing ingredients

In the case of the herbal extract, dried cherry blossom meat was added in an amount of 10 parts by weight to 1 L purified water, and obtained through hot water extraction at 110° C. for 60 minutes and used.

Then, 8 parts by weight of carrageenan was added to 68.8 parts by weight of purified water based on a total of 100 parts by weight, followed by mixing and heating at 80° C. for 6 hours to completely dissolve. To the mixed solution, 1 part by weight of the cherry tree meat extract, 0.1 part by weight of food coloring, 10 parts by weight of coconut amidopropylbetaine, 8 parts by weight of 2-(2-butoxyethoxy) ethanol, 4 parts by weight of fragrance, 0.1 part by weight of antifoam After the portion was added, the mixture was stirred and mixed at a temperature of 60° C. for 1 hour. After the mixing was completed, the mixture was poured into a molding mold and gelled at room temperature for 12 hours or longer to complete a gel-type deodorant including the herbal extract component.

< Example 2>

A gel-type deodorant including the herbal extract component was completed in the same manner as in Example 1, except that 3 parts by weight of the cherry tree meat extract was included.

< Example 3>

A gel-type deodorant including the herbal extract component was completed in the same manner as in Example 1, except that 5 parts by weight of the cherry tree meat extract was included.

< Example 4> Cherry tree Manufacture of gel-type toilet deodorant containing ingredients of quince, quince, oleum and cheonnyeonja

In the case of herbal extracts, dried herbal raw materials (cherry blossoms, quinces, cucumbers, cheongnyeonja) were added to 1L purified water in an amount of 10 parts by weight, and obtained through hot water extraction at 110°C for 60 minutes and used.

Thereafter, 8 parts by weight of carrageenan was added to 66.8 parts by weight of purified water based on a total of 100 parts by weight, mixed and heated at 80° C. for 6 hours to completely dissolve. In the mixed solution, 1 part by weight of the cherry tree meat extract, 0.5 part by weight of quince extract, 1 part by weight of Omae extract, 0.5 part by weight of Cheonnyeonja extract, 0.1 part by weight of food coloring, 10 parts by weight of coconut amidopropylbetaine, 2-(2 -Butoxyethoxy) ethanol 8 parts by weight, 4 parts by weight of fragrance, and 0.1 parts by weight of antifoaming agent were added, followed by stirring at a temperature of 60° C. for 1 hour to mix. After the mixing was completed, the mixture was poured into a molding mold and gelled at room temperature for 12 hours or longer to complete a gel-type deodorant including the herbal extract component.

<Example 5>

A gel-type deodorant including the herbal extract component was completed in the same manner as in Example 4, except that 3 parts by weight of the cherry tree meat extract was included.

<Example 6>

A gel-type deodorant including the herbal extract component was completed in the same manner as in Example 4, except that 5 parts by weight of the cherry tree meat extract was included.

< Comparative example 1> Preparation of general gel-type toilet deodorant

Based on a total of 100 parts by weight, 8 parts by weight of carrageenan was added to 69.8 parts by weight of purified water, followed by mixing and heating at 80° C. for 6 hours to completely dissolve. 0.1 parts by weight of food coloring, 10 parts by weight of coconut amidopropylbetaine, 8 parts by weight of 2-(2-butoxyethoxy) ethanol, 4 parts by weight of fragrance, 0.1 parts by weight of antifoaming agent were added to the mixture, followed by stirring for 1 hour And mixed. After the mixing was completed, the mixture was poured into a mold and gelled at room temperature for 12 hours or longer to complete a general gel-type toilet deodorant.

< Experimental example 1> Deodorizing power evaluation

The evaluation of the deodorizing power of the gel-type toilet deodorant prepared in Examples 1 to 6 and Comparative Example 1 was a nitrogen compound (NH ₃ , For (CH ₃ ) ₃ N) and sulfur compounds (H ₂ S, CH ₃ SH), the gas in the test container was collected with a gas collector specified in SPS-KCLI2218-6218 to measure the concentration of odor components. At this time, a direct reading detection tube corresponding to the odor component to be measured and the expected concentration range was inserted into the gas collector.

As shown in FIG. 1, 50 g of a gel-type toilet deodorant was added to a 10L Flek bag, and then a contaminant of a predetermined concentration was injected, and after 6 hours, the deodorization rate was checked and analyzed, and the analysis results are shown in Table 1 below. Indicated.

Gas type Gas concentration and deodorization rate Standard gas Comparative Example 1 Example 1 Example 2 Example 3 Example 4 Example 5 Example 6 NH ₃ Concentration (ppm) 50 15 10 6 3 8.5 4.5 1.5 Deodorization rate (%) - 70 80 88 94 83 91 97 (CH ₃ ) ₃ N Concentration (ppm) 5 3 2.5 1.5 One 2.3 1.3 0.5 Deodorization rate (%) - 40 50 70 80 55 75 90 H ₂ S Concentration (ppm) 15 13.5 2.9 2 One 3.3 1.4 0.6 Deodorization rate (%) - 10 81 87 93 78 91 96 CH ₃ SH Concentration (ppm) 3 2.7 2 1.5 0.5 1.2 0.7 0.5 Deodorization rate (%) - 10 33 50 83 60 78 85

As a result, compared to Comparative Example 1 that did not contain the herbal extract, Examples 1 to 6 containing the extracts of primrose meat or primrose, quince, oleander, and cheongnyeonja had a deodorization rate of 10% or more In particular, in Examples 3 and 6, including 5 parts by weight of cherry blossom extract, showed a deodorization rate of 90% or more for nitrogen compounds and sulfur compounds, so that the gel-type deodorant including the herbal extract component prepared according to the present invention removes odor It was confirmed that the effect was excellent.

Claims (10)

Contains herbal extracts as an active ingredient,
The herbal extract is a gel-type deodorant composition, characterized in that the primrose meat extracted with hot water. The method of claim 1,
The herbal extract is a gel-type deodorant composition, characterized in that it further comprises any one or more selected from the group consisting of Dansam, Chinese quince, Jacaranda, Alum, Bodu, Sangcho, Omae, Cheonnyeonja, and landing. The method of claim 1,
The herbal extract is a gel-type deodorant composition comprising 0.1 to 10 parts by weight based on 100 parts by weight of the composition. The method of claim 1,
The composition further comprises a gelling agent, a solubilizing agent, a dispersion stabilizer, and an antifoaming agent. Preparing an herbal extract containing cherry tree meat;
Preparing a gelling agent;
Preparing a mixed solution by mixing the herbal extract, solubilizing agent, food coloring, dispersion stabilizer, flavoring and antifoaming agent with the gelling agent and stirring at a temperature of 60°C to 120°C for 30 minutes to 2 hours; And
The method for producing a gel-type deodorant composition according to claim 1, comprising: injecting the mixed solution into a mold and then cooling to prepare a gel composition. The method of claim 5,
The herbal extract is a method for producing a gel-type deodorant composition, characterized in that it further comprises any one or more selected from the group consisting of Dansam, Chinese quince, Jacaranda, Alum, Bodu, Sangsangcho, Omae, Cheonnyeonja, and landing. The method of claim 5,
The gelling agent is carrageenan, agar, konjac, gelatin, pectin, collagen, starch, alginic acid, locust bean gum, guar gum, xanthan gum. The method of claim 5,
The solubilizing agent is fatty acid monoglycerin ester, fatty acid polyglycol ester, fatty acid sorbitan ester, fatty acid sucrose ester, fatty acid alkanolamide, polyhydric alcohol derivative, polyethylene glycol derivative, fatty acid soap, sulfonate, sulfate ester salt, phosphate ester salt, Coconut amidopropyl betaine, lauryl betaine, imidazoline, amino compound, a method for producing a gel-type deodorant composition comprising any one or more from the group consisting of a quaternary ammonium salt. The method of claim 5,
The dispersion stabilizer consists of 3-methyl-3-methoxybutanol, 2-(2-butoxyethoxy)ethanol, pyrrolidone, ethanol, propanol, isopropanol, butanol, ethylene glycol, diethylene glycol, and triethylene glycol. Method for producing a gel-type deodorant composition comprising at least one of the group. The method of claim 5,
The composition comprises 38 to 97.1 parts by weight of purified water, 1 to 10 parts by weight of gelling agent, 0.1 to 10 parts by weight of herbal extract, 0.1 to 2 parts by weight of food coloring, 0.5 to 20 parts by weight of solubilizer, dispersion stabilizer 1 to 10 parts by weight, 0.1 to 8 parts by weight of fragrance, and 0.1 to 2 parts by weight of an antifoaming agent.

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