KR102085064B1 - Manufacturing method of eco-friendly cleaner composition comprising extract of cianidanol and terpene - Google Patents

Abstract

The present invention relates to a hypoallergenic cleaning agent composition for protecting hair using a low particle cluster solvent of a plant extract impregnated short-term fermentation and long-term matured product, and a method for manufacturing the same. More specifically, provided are a cleaning agent for protecting hair without additives of artificial perfumes, artificial colors, and synthetic chemicals, and a method for manufacturing the same. The composition has an effect of generating a vegetable forest bath. Since the composition uses a natural preservative, antiseptic agent, and additive, and thus does not contain a chemical component as a main component, the composition does not cause secondary side effects and has excellent long-term preservation.

Description

Manufacturing method of eco-friendly cleaner composition comprising extract of cianidanol and terpene

The present invention relates to a powder capsule type detergent composition of 210-230 (mesh) mesh particles using a short-term fermentation long-term fermentation impregnated with a natural vegetable extract, and a method of manufacturing the same, more specifically, artificial flavoring, artificial coloring, methanol, Provided is a safety cleanser in a natural environment that does not contain methyl paraben sulfate, coal, or petroleum emulsifying and extracting substances, and a method for manufacturing the same.

Short-term curing powder cleaner of 210 ~ 230 (mesh) mesh particles of catechin and terpene is designed to clean the scalp and hair, and various products are commercially available. However, the hair and scalp are weak, so they are sensitive to irritation and have low resistance to harmful substances. Conventional detergents include alcohols, methyls, and paraben surfactants, which are harmful substances that irritate such weak and sensitive scalp hair. When such a surfactant is used, lipid peroxide is accumulated in the scalp of the hair, thereby facilitating and cracking the hair of the hair and aging of the scalp, and there is a problem in that hair shrinkage and elasticity are deteriorated. That is, as the unsaturated fatty acid is oxidized in the body, the lipid peroxide increases, and the hair factor fiber that maintains the elasticity of the scalp becomes vulnerable. Thus, aging of the scalp, hair loss occurs, and when there is a disease in the scalp and hair, blood circulation In the case of poor nutrition, insufficient nutrition, fibrous muscles that bond with the elastic fibers in the dermis degenerate and atrophy, free radicals are generated from free radicals caused by a decrease in moisture or hair fat, or lack of collagen And the elasticity of the scalp is deteriorated due to various causes, such as an increase in the activity of elasase, which is a decomposition element of elastic fibers, and the contractility of pore hair is weakened.

In addition, since the use of artificial chemicals causes hair inflammation, the likelihood of swelling and keratin formation is high, and when physical aging such as hair progresses, serious mental pain is also involved, preventing aging and moisturizing and antibacterial properties to the scalp. It is necessary to prevent the formation of causative bacteria.

Commonly used commercially available sampu detergents are methyl alcohol, paraben steroids, chemotherapeutic agents, topical immune modulators, systemic steroids, systemic immune inhibitors, and antihistamines. These drugs have the risk of various side effects. have. The raw materials mainly used in the composition for preventing and alleviating pruritus of the hair scalp, known to date, are antifungal agents such as zinc pyrithione (ZPT) and ketoconazole, and terfenadine, acetemizole, and the like. It is chemically synthesized as an antihistamine. These are insoluble in water and difficult to disperse uniformly due to their high specific gravity, as well as irritation to the eyes, hepatotoxicity, restrictions on the use of pregnant women and scalp of the scalp, cracking of hair, cracking of hair, etc. There are side effects such as the occurrence of, wrinkles, swelling, and pruritus of the hair.

Recently, consumers' preference for products containing natural ingredients rather than neutralized synthetic products has increased significantly. Various methods have been developed to improve scalp itching and hair aging, for example, by removing antigens and enhancing the function of the hair and scalp barriers, or by adrenal cortical hormones, etc., in the external preparation for skin to weaken the allergic reaction. As an antibacterial agent, methods such as preventing secondary infection have been used. However, even though these external agents for scalp hair contain useful ingredients, chemical preservatives, preservatives, thickeners, etc., such as artificial synthetic additives, artificial colors, methylparabensulfate, disodium LED, disodium arolay sulfate, etc. As it is derived from, it may cause problems in that it contains ingredients with stimuli, and these problems are more likely to result in counteracting the unique function of ingredients with therapeutic functions.

For example, existing products have a lower risk of disease, such as scalp hair and aging, but have a greater risk of developing secondary side effects. Therefore, there is a need for a natural ingredient composition that is effective for dry scalp salts and has no side effects.

As an example, among conventional products, there are compositions containing ginseng, peach, herb, and extract from Machi Prefecture, but these also contain synthetic or chemical components such as disodium ID, methyl paraben, propyl paraben, and methyl alcohol as additives. Since it contains, there is concern about hair scalp disease when used for a long time.

In addition, even in the case of existing products using natural ingredients such as raw materials, main ingredients, herbal medicines, or compounds that are harmless to the human body, the function of ozone molecules that promote the nutritional components of the hair and scalp is also lacking. There is a limit to the effect of alleviating inflammation of the skin and to sufficiently suppress and alleviate pathogens.

The present invention has been devised to solve the problems of the prior art, and the object of the present invention is to prevent pathogens against scalp and hair health, and to reduce the generation and propagation of causative bacteria by adding convenience when washing the scalp, and softness It is to provide a powder-type detergent composition containing a new natural substance whose main component is a component derived from a natural product that exhibits a sufficient effect in improving hair scalp and does not exhibit secondary side effects that may be caused by an additive component.

The detergent composition according to the present invention is a powder containing a new natural substance excellent in pathogenic bacteria absorption while being usable for a long period of time without causing side effects without using artificial synthetic or chemical components such as artificial flavors, artificial colors, methyl parabens as a main component It is to provide a mold cleaner composition.

In the present invention, as an example, looking at a preservative, a preservative, and an antioxidant using natural raw materials, cinnamon. It contains one or more selected from cinnamon, ginger, and turmeric extracts, so it has a very good soothing effect on the scalp and an effect to remove itching of hair allergies, and excludes various pollutants and synthetic detergents that inhibit the nutritional supply to the scalp of hair. In addition, natural grapefruit extract, citric acid antioxidant, natural cellulose, and preservative mixtures of preservatives containing herbal extracts for the prevention of scalp disease were prepared using aqueous liquid extraction.

The present invention, in order to achieve the above object, a step of warming to 100 parts by weight of the low particle cluster solvent 50 ℃ ~ 70 ℃; Based on 100 parts by weight of the low particle cluster solvent, 29 to 32 parts by weight of pine tree leaf liquid extract, 18 to 20 parts by weight of green tea extract, 2 to 5 parts by weight of natural cellulose and citric acid antioxidant, cinnamon and grapefruit powder mixture 10.3 to 20 Mixing parts by weight; It provides a method for producing an environment-friendly detergent composition comprising a; drying the mixture.

The composition is preferably made of powder and encapsulated.

According to the present invention, the natural fermentation extract short-term fermentation long-term aging composition uses a vegetable extract, a natural preservative, and an additive, and since the chemical component is not contained as a main component, an excellent effect of long-term preservation can be expected without causing secondary side effects. have.

According to the present invention, the effect of hair inflammation on the hair is blocked to prevent exposure to the inflammatory environment, and the effect of blocking or contacting the soft hair or significantly inhibiting or alleviating the generation and reproduction of the causative agent of the scalp disease of the hair itself Can be expected.

According to the present invention, since it is manufactured in a capsule form, it is convenient when going out and traveling, and an effect of reducing the use of water can be expected.

1a and 1b is a view showing the safety test results of the composition according to an embodiment of the present invention.

The present invention includes a plant-based natural extract short-term fermentation composition and a solvent of a small particle cluster as a solvent, and may further include a preservative and an additive. In the composition of the present invention, as a solvent for the above 54 Hz to low particle cluster, a low particle cluster solvent is used entirely.

In addition, it is a pure low particle cluster solvent made by filtering raw water of a low particle cluster through an electrolysis water process by a physical method, and undergoes a process of removing various inorganic substances.

The electrolysis water of the low particle cluster facilitates the mixing of each component and natural components constituting the composition, which is a characteristic of the cluster solvent of the low particle to weaken the hydrogen bond of water so that water molecules are well absorbed, and thus the interface With active tension, the absorption rate of the scalp of cosmetic ingredients can be very high. In addition, there is also an effect of significantly inhibiting bacterial growth by antibacterial ozone substances of the hair scalp by rapidly capturing free radicals.

1. Liquid extract of pine tree leaf and manufacturing method

The present invention includes a liquid fermented extract of pine nut leaf, as described below.

In the present invention, the liquid extract of pine nut leaf is mainly used for the purpose of relieving itching, and in addition to having various functions such as antibacterial, deodorizing, adsorption, anti-inflammatory, antiviral activity due to the action of terpene, pine nut leaf extract for 3 years It provides a terpene-generating material produced by aging to improve the user's clean and refreshing satisfaction. Pine needles of conifers are well known for their diabetes treatment, blood sugar control and cholesterol control effects, and pine needles are rich in antioxidants of the terpenoids system, giving the feeling of being an eco-friendly forest bath. , It is a material that contains a lot of vitamins and minerals that are beneficial to low-irritation scalp hair. In addition, the terpene component of the pine tree leaf serves to prevent the aging of the soft scalp. In particular, the pinene component contained in the pine tree leaf isomerized to campone, oxidizing the biological tissues to become keratinized, keratinized. It accelerates the process of reducing biological tissue before.

The method of extracting the liquid of pine nut leaf extract and performing short-term fermentation is performed through the following steps.

-1st step: The pine tree leaves are collected every year from February to March (excluding summer) or from October to November (excluding winter harvest period) for 20 hours or more, preferably 24 hours or more, by soaking in a solvent. This is the step to brew Jin.

-2nd step: This is a step of crushing the pine tree leaves to a size of 1.5 to 2 mm after separating the remaining pine tree leaves using a sieve.

-3rd step: Extracting the liquid by compressing the crushed pine tree leaves, and separating and recovering the supernatant from the extracted liquid. In the first step, it is preferable to perform a short-term fermentation at a low temperature of 6 to 6.5 ° C for the first time, and it is preferable to exchange a container when the second fermentation is performed, and a fungal strain may grow during the second fermentation, and in this case, a desired effect cannot be obtained. Bar, it must be disposed of.

If it is used without disposal, it is because not only does not exhibit the effect of the raw material, it is not properly mixed with the additive, and phytoncide may not be formed. If the short-term fermentation period exceeds 1 month, there is a problem of starting to offset the surface particles of the fermentation strain, so it is controlled within the period indicated above.

In the second step, the pulverization may be performed by primary pulverization and secondary pulverization. For example, the dried pine tree leaf may be pulverized first by 7 to 9 mm, and then pulverized by 1.5 to 2 mm. . However, the number of times of grinding is not limited to this, and it is also possible to grind once or several times.

In addition, in the liquid separation method performed in the third step, the crushed pine tree leaves are separated by using a hydraulic compressor and a mincer compressor, for example, and maintained in a stationary state for more than 24 hours, separated into supernatant and slurry. However, by filtering and recovering the slurry, the supernatant can be separated and recovered to obtain a liquid fermented extract of pine nut leaf. In addition, in addition to the liquid separation method, various extraction methods commonly used in the art may be used. For a specific example, about 2 to 10 times the volume of the pine tree leaf sample, preferably about 5 to 15 times .54Hz ~ After mixing pine tree leaves in a solvent of a 65 Hz low particle cluster and compressing them, a liquid fermentation extract can be obtained.

In the composition of the present invention, the amount of the pine tree leaf liquid extract used is 29 to 32 parts by weight, preferably 30 to 31.5 parts by weight, and more preferably 30 to 31 parts by weight based on 100 parts by weight of the low particle cluster solvent. In this case, if the amount of pine tree leaf liquid three-year ripening extract used is less than 29 parts by weight, there may be a problem that the effect of the material is reduced due to insufficient content of raw materials. The impregnation may be excessive and impregnation may not be possible. In addition, it is preferable to use within the above range because there may be a problem that the production cost is increased because an extract is used unnecessarily.

2. Green Tea Leaf Liquid Extract

Next, the present invention includes a plant extract aging product, in which the green tea leaf contains catechin and polyphenol antioxidants. The explanation is as follows.

It is rich in antioxidants and prevents excessive secretion of cytokines (cytokine storms). In addition, it has excellent anti-cancer, anti-cancer and sterilizing functions. In addition, it is rich in vitamin C, vitamin E, beta-carotene, plant fiber, minerals and chlorophyll. Specifically, it is known to have various effects, such as antioxidant action, anti-aging effect, anti-allergic effect, odor removal effect, and radioactive detoxification effect.

In the present invention, the method of preparing a green tea leaf liquid extract is as follows.

-First step: Preferably, after preparing green tea leaves fermented for more than 30 days at a temperature of 6 ℃ to 6.5 ℃ from green tea leaves collected from May to early June every year from October 1 to 10, after 20 hours, Preferably it is a step of soaking the green tea leaf extract liquid in a solvent for more than 24 hours.

-2nd step: This step is to remove the green tea leaves from which the liquid of the green tea leaf extract is brewed, and then crush it to a size of 1.5 to 2 mm.

-The third step: This is a step of separating and recovering the supernatant produced by performing a liquid phase separation method of green tea leaves that have been crushed.

In this way, a green tea leaf liquid extract can be obtained through three steps.

As described above in the liquid fermentation extract of pine nuts, the liquid fermentation extract of green tea leaves can also be obtained by using a general extraction method used in the art in addition to these methods.

In the composition of the present invention, the amount of green tea leaf extract used may be 18 to 20 parts by weight, preferably 18 to 19 parts by weight, and more preferably 18 to 18.8 parts by weight based on 100 parts by weight of the low particle cluster solvent. have. At this time, if the amount of the green tea leaf liquid extract used is less than 18 parts by weight, the amount may be too small, and if it is used in excess of 20% by weight, there may be a problem that the green tea flavor is too strong. good.

3. Liquid extract impregnated with additives

The impregnated ripening natural extract serves to improve antioxidant activity and moisturizing ability, improve aging hair scalp, and relieve itching irritation.

In the present invention, the method for producing the impregnated ripening extract is as follows.

First, the natural vegetable extract is washed and crushed. Then, the pulverized material is injected into a reactor made of a ceramic material, through which air is permeable and liquid components are not permeated, and is preferably left for 1 month or longer under a temperature condition of 6 ° C to 7.5 ° C for short-term fermentation.

After this process, the solid phase and the liquid phase aged by long-term aging are separated, and the solid-liquid separated aged water can be filtered by a filter to obtain a long-term aging extract.

4. Impregnation of long-term aged additives

The long-term aging composition of the natural extract of the present invention includes an extract containing cinnamon (cinnamon) and grapefruit in addition to the aged extract, and it is preferable to use a natural cellulose citric acid antioxidant.

 In the composition of the present invention, the amount of the natural cellulose and citric acid antioxidant may be preferably 2 to 5 parts by weight, more preferably 2.5 to 3 parts by weight, preferably 100 parts by weight of the 54 Hz low particle cluster solvent, wherein When the amount of the natural cellulose and citric acid antioxidant used is 2.5 to 3 parts by weight, the pH may be too low, so it is preferable to use within the above range.

The natural cinnamon, grapefruit has antioxidant and preservative and preservative effects. And, in the composition of the present invention, the amount of natural coco betaine (palm oil extract) surfactant 7 parts by weight and the amount of the cinnamon and grapefruit powder can be preferably 10.3 to 20 parts by weight, wherein cinnamon, cinnamon, grapefruit If the amount used is less than 10.3 parts by weight, there may be a problem that the amount of use is too small to see a preservation effect, and when it is used in excess of 20 parts by weight, there is a problem of entanglement between components of the composition and the viscosity of the natural extract long-term aging composition itself It may be too high, so it is recommended to use it within the above range.

5. The cluster of low particles is 54Hz ~ 64Hz, and is used as the main solvent. Additives used as low particle cluster solvents include cocobetaine, di-panthenol, caprylyl glycol, glycerin, xanthan gum 1-2-3-hydrogenated starch hydrolysate, glucamate, dimethicone, LES ( Ripening disodium laureth .sulfosuccinate, Cocamidopropyl bataine, Lauramide DEA, Sodium lauroyl glu tamate, Hexanediol 1-2-3-, Abeta Glucan, Xanthan gum additive as cabbage extract It may contain water.

The additives preferably include 35.4 to 36 parts by weight, preferably 35.5 to 36% by weight, of the total weight of the natural extract long-term aging composition.

The short-term fermentation long-term fermentation composition of the natural extract of the present invention possessed by such a composition and the composition may be pH 6.3 to 6.9, preferably pH 6.5 to 6.8, which is an appropriate acidity.

The raw material of the present invention includes a liquid fermented extract of pine needles and a liquid fermented extract of green tea leaves, and may further include natural cinnamon and grapefruit powder extracts, and may further include turmeric and ginger.

The manufacturing process / composition of the composition powder can be prepared as a liquid detergent by mixing and homogenizing the solvent of the 54 Hz to 64 Hz cluster, the long-term aging extract, natural cellulose and citric acid antioxidant, grapefruit, and cinnamon. Additives can be further mixed here.

The method of preparing each extract of pine tree leaf liquid extract 30%, green tea leaf liquid extract 18% parts by weight and cinnamon powder 10.3 parts by weight is as described above. After heating the low particle cluster solvent to 50 ° C to 70 ° C, preferably to 55 ° C to 65 ° C, in the long-term ripening extract under 50 ° C to 70 ° C, after adding natural cellulose and citric acid antioxidant, homogenizer ( Homogenization in the homogenizer) for 30 minutes to 60 minutes can be sufficiently emulsified (or dissolved) to prepare a cosmetic solution. At this time, if the temperature is less than 50 ℃ long-term aging extract, natural cellulose and citric acid antioxidants, etc., there may be a problem that the time for the particles to dissolve in the low particle cluster solvent is too long, and if it exceeds 70 ℃, the cosmetic solution Since viscosity may be too high, it is preferable to perform mixing and stirring under the above temperature.

By maintaining the temperature of the low particle cluster solvent at 50 ° C to 70 ° C, preferably at 55 ° C to 65 ° C, by mixing liquid raw materials and additives, a high temperature short-term curing powder type detergent for 12 hours 89 to 95 ° C can be prepared. have. At this time, if the temperature is less than 50 ° C, there may be a problem that the time for the extract, cellulose, citric acid antioxidant, etc. to dissolve in the low particle cluster solvent becomes too long, and if it exceeds 70 ° C, the viscosity of the solution is too high. Mixing and stirring under the above temperature is preferable because there may be a problem of increasing.

The embodiments will be described in more detail as follows.

<Production Example 1>

A. Preparation of short-term fermentation long-term fermentation extract of vegetable impregnation

① Preparation of liquid extract of pine tree leaf

Wash the pine tree leaves collected in February ~ March, mix 90% parts by weight of pine tree leaves and 6% parts by weight of low particle cluster solvent, and then extract with minchigi (compressor), which is 30 days at 6 ℃ ~ 6.5 ℃ After fermentation at low temperature, it was immersed in an inorganic solvent and aged for 6 months at 6 ° C to 6.5 ° C for 12 months.

Next, it was soaked in water for 28 hours to soak the pine needles, and then the pine needles were dried and allowed to air dry for one day. Next, it was first pulverized to a size of 7 to 9 mm using a first pine nut shredder, and then pulverized to 2 to 3 mm again. Next, the crushed pine tree leaves were put in a mesh mesh of 180 to 200 (mesh), and then pressurized in a minchi (liquid compressor) with a hydraulic compression press (2HP) to perform liquid separation, and the resulting liquid separated was left for 2 hours. The supernatant and precipitate (slurry) were allowed to separate. Then, only the supernatant was secondarily obtained by using the residual slurry filtered as a secondary filter to obtain a liquid extract of pine nut leaf.

② Preparation of green tea leaf liquid extract

After washing the green tea leaves collected from May to early June, allowing them to dry naturally, and then liquefying them with minchi to prepare green tea leaves that were fermented for a short period of time at 6 ℃ to 6.5 ℃ for 1 month. Next, after soaking it in water for about 24 hours, brewing it out, dried it and dried it naturally for one day. Next, it was first pulverized to a size of 6 to 7 mm using a primary crusher, and then pulverized to 1.5 to 2 mm again.

Next, the crushed green tea leaves were pressurized in a minchi with a hydraulic compressor press (2HP) to perform liquid separation, and the resulting liquid separated was left for 2 hours to separate the supernatant and sediment (slurry). Then, only the supernatant was secondarily obtained by using the residual slurry filtered as a secondary filter to obtain a liquid short-term fermented extract of green tea leaves.

③ Preparation of liquid fermentation extract with additive impregnation

The vegetable extract is crushed by washing the leaves and roots, and then the pulverized material is injected into a reactor of a constant material through which air is permeable and the liquid component is not permeated, and then left for 1 day for 30 days at a temperature condition of 6 to 6.5 ° C. Short-term fermentation.

Then, the vegetable extract solution was separated from the solid phase and the liquid phase by aging, and the separated solution was filtered through a filter to obtain grapefruit and cinnamon extracts as natural additives. After washing and drying naturally, the grapefruit was first crushed to a size of 5 to 6 mm using a crusher, and then crushed to a size of 1.5 to 2 mm again.

Next, the crushed grapefruit and cinnamon extracts were pressurized in a minchi with a hydraulic compression press (2HP) to perform liquid separation, and the resultant liquid separation was left for 2 hours to separate the supernatant and sediment (slurry). Then, the second filtered residual slurry was used as a filter to obtain only the supernatant as a second liquid to obtain a liquid extract, and the preservative antioxidant grapefruit and cinnamon extract were fermented at 6 to 6.5 ° C for 30 days for a short period of time, thereby short-term curing the vegetable extract liquid. A liquid phase was prepared.

The short-term cured powder detergent particles are usually composed of a capsule powder type of 210 to 230 mesh particles.

④ 2.5 ~ 3 parts by weight of natural cellulose and citric acid antioxidant

The obtained natural cellulose and citric acid antioxidant were liquefied and sealed at room temperature at 6. ~ 6.5 ° C and then impregnated for a short time to prepare.

B. Preparation of Natural Cleanser Composition

After preparing a low particle cluster solvent of 54 Hz to 64 Hz, it was warmed to 6.5 ° C. Next, after mixing the liquid fermented extract of pine tree leaf, fermented extract of green tea leaf and the low particle cluster solvent of 6,5 ° C, the grapefruit and cinnamon extract powders were additionally added and mixed, and then mixed. It was homogenized for 30 to 45 minutes by using a Niger (microparticle / assembly machine, DH-700), and then cooled to room temperature to prepare raw material additives for a short-term curing powder type natural detergent composition. Plant extract impregnation Short-term fermentation and long-term aging Short-term curing process The content of raw materials used in the natural powder cleaning composition is shown in Table 1 below.

Ingredient Compounding amount (parts by weight) Manufacturing conditions Liquid extract of pine nut leaf 30 1) Short-term aging at 5 ~ 6 ℃ for 30 days 2) Short-term fermentation at 7 ~ 8.5 ℃ for 1 month Cinnamon powder, cinnamon powder, grapefruit 8.2  Scalp dandruff removal anti-inflammatory, antioxidant Green tea leaf liquid fermentation extract 18 Short-term fermentation at 7 ~ 8.5 ℃ for 1 month Grapefruit Powder Ferment Extract 2 Short-term fermentation at 7 ~ 8.5 ℃ for 1 month Turmeric and ginger 1.5 Natural antioxidant plants Natural cellulose and citric acid antioxidant 2.5 ~ 3 Anti-inflammatory antioxidants Solvent in 54 Hz cluster 100 Mixing of impregnated extract and low particle cluster solvent

division//
% Parts by weight Low particle cluster solvent Pine tree leaf liquid
Fermentation extract Green Tea Leaf Extract Cellulose and
Citric acid antioxidant grapefruit cinnamon Cinnamon Example 1 100 30% 18% 2.5 ~ 3 1.5 4.5 3.8 Example 2 100 9 - 2.5 ~ 3 1.5 Example 3 100 7 - 2.5 ~ 3 1.5 Example 4 100 9 - 2.5 ~ 3 4.5 Comparative Example 1 100 9 - 2.5 ~ 3 3.8 Comparative Example 2 100 9 - 2.5 ~ 3 Comparative Example 3 100 7 - Comparative Example 4 100 9 - Comparative Example 5 100 8 -

The results of measuring the acidity (pH) of the above detergent composition and cosmetic composition are shown in Table 3 below. The acidity was measured to be 6.7 to 6.9.

division pH importance Viscosity (cps, 25 ℃) Example 1 6.7 1.02 188 Example 2 6.6 1.03 199 Example 3 6.8 1.08 216 Example 4 6.9 1.03 189

C. Addition of additives

After heating the low particle cluster solvent to 60 ° C., a liquid fermentation composition was prepared by mixing and stirring the additive having the composition and composition ratio as shown in Table 4 below and the liquid fermentation extract prepared in Table 1 above.

 100 parts by weight of a 54 Hz low particle cluster solvent using electrolysis water conditions, 56.8 parts by weight of a aging raw material composition, and 35.4 parts by weight of an additive were mixed. It was further prepared to add 100 parts by weight.

56.8% by weight of raw materials
Additive 35.4% by weight Compounding amount
(Parts by weight) Gross weight part 100% /92.2% Low particle cluster solvent 100% 54 Hz to 65 Hz cluster solvent Other additives 4 Anti-inflammatory ibuprofen effect Other additives 4 Allicin antioxidant antibacterial Di-panthenol 2.4 Soft skin nutrient Coco betaine (surfactant) 7 Natural active agent extracted from coconut fruit oil Caprylyl glycol 2 Soft skin antibacterial agent Natural preservative Glycerin glycerin 1.5 Moisturizer Viscosity 1.2.3.propanetriol (100% natural) Xanthan gum 1.5 Cabbage extract thickening. Hydrogenated Starch Hydrolysate 2 Cationic material of natural cellulose starch Glucamate 2 Thickener extracted from corn Dimethicone 2 sodium cocoyl apple amino acids Aloe extract short-term matured (30 days) 2 Skin film protection nutrition ingredient homogenate LES (disodium laureth sulfosuccinate) 2.5 Viscosity made from palm and succinic acid -Ionic Cocamidopropyl bataine 2 Thickener antistatic vegetable Lauramide DEA 2 Natural emulsifier foam accelerator Sodium lauroyl glu tamate- 2 Neutral polymer compound (amino acid) surfactant Other Preservatives and preservatives Hexanediol 1 2.5 Preservative synthetic 90% safety agent  Acasia Honey 2 Natural antibiotic allicin anti-inflammatory

 <Production Example 2>

After heating the composition (solution) to 60 ℃, here was prepared by mixing and stirring the additive having the composition and composition ratio as shown in Table 5 and the liquid aging extract prepared in Preparation Example 1 above. The impregnating composition was used by adding 56.8 to 57 parts by weight of the raw material and 35.5 to 36 parts by weight of the additive to 100 parts by weight of other additives.

Table 5 below shows the content change of the raw material additive of the impregnating detergent composition.

Suggestion of detection standards for prohibited substances contained in regulations related to safety standards for cleaners, etc. Classification / Classification Cleaner raw material% Additive content% Classification %content Preparation Example 1-1 Example 1 56.8 wt% 35.5 wt% Preparation Example 1-2 Example 1 56.8 wt% 35 wt% Preparation Example 1-3 Example 2 56.8% by weight 34.5 wt% Preparation Example 1-4 Example 3 56.8% by weight 35.5 wt% Preparation Example 1-5 Example 4 56.8 wt% 35.5 wt% Preparation Example 2 Example 1 56.8% by weight 35.5 wt% Comparative Production Example 1-1 Comparative Example 1 56.8% by weight 35.5 wt% Comparative Production Example 1-2 Comparative Example 2 56.8% by weight 35.5 wt% Comparative Production Example 1-3 Comparative Example 3 56.8 wt% 35.5 wt% Comparative Production Example 1-4 Comparative Example 4 56.8% by weight 35.5 wt% Comparative Production Example 1-5 Comparative Example 5 56.8% by weight 35.5 wt%

Safety test for prohibited properties of the raw material additive composition prepared in Preparation Example 1-1 2019.05.14. ~ May 28. Commissioned by the Korea Institute for Construction and Environment Testing, a test institution, nickel (Ni), lead, (pb), arsenic (As), cadmium (Cd), mercury (Hg), dioxane (1,4-Dioxane), methanol ( Methanol) The presence and content of formaldehyde (HCHO) and the acidity (pH) were measured. As a result, it was found that nickel, lead, arsenic, cadmium, mercury, dioxane and formaldehyde were not present.

Table 6 below shows a short-term curing powder process. After curing for 12 hours, it can be seen that the powder is 100%.

Short-term curing powder process (room temperature 80 ~ 95 ℃, 3-12 hours) Short-term curing process / time division Powder composition 3 hour short-term curing 26% Short cure for 4 ~ 5 hours 29% 6 Short cure 48 7 hardening 51 8 Hardening 55 9 Long-term curing 81 10 Long-term curing 89 11 long-term curing 90 11.5 Long-term curing 96 12.Long-term curing 100% Short-term curing of impregnated liquid → Powdering (210 ~ 230 Mesh)
Particle hot air drying: chamber 95 ℃ ~ 100 ℃ hot air drying, thin film coating drying

For the trouble measurement experiment of the present invention, a trouble measurement experiment was performed when a low particle 54Hz cluster solvent was used. At this time, in the moisture retention measurement experiment, after applying the low particle cluster solvent of each scalp hair, the change in scalp conductivity over time was measured to evaluate the absorbency and moisturizing power. Compared with pure water, the conductivity value according to the moisturization of absorbed moisture in the preparation example 1-1 was higher, and it was confirmed that the absorption and moisturizing power of weakly acidic hair was higher than that of pure water. In the end, it is judged that by using such a low particle cluster solvent, the absorbency and water retention capacity for the hair scalp will be excellent.

More specifically, the skin moisturizing power was evaluated by measuring the skin conductivity using a skin moisture meter (Corneometer, Courage + Khazaka, GmbH, Germany) as a clinical test for skin moisturizing according to the present invention. Moisturizing power measurement by a skin moisture meter is a device that measures the moisture content of the skin surface (e.g., stratum corneum) by electrostatic load capacity measurement, and the skin surface moisture content measurement is not affected by samples already applied locally It has the advantage of maintaining a constant measurement level 30 to 40 μm deep below the contact area of the probe sensor. For skin moisture measurement, 100 μL of Preparation Example 1-1 in an area of 2 × 2 cm ² for 5 subjects using a skin moisture meter under constant temperature and humidity conditions maintained at a room temperature of 20 to 25 ℃ and a relative humidity of 40 to 55%. It was measured by application.

The skin conductivity increase rate (%) as a moisturizing power was calculated as a numerical value using the following equation and shown in Table 6 below, and one measurement site was measured five times each and expressed as an average value ± standard deviation. In addition, skin conductivity was measured as a default value before application of the sample, and the control group was not applied to both the formulation example and the comparative formulation example.

<Mathematics>

Skin conductivity increase rate (%) = Moisturizing power (%) = (Measurement value after application of Example 1-1-Measurement value before application example 1-1) / Measurement value before application example 1-1 application × 100

Skin moisturizing power (%) Elapsed time Comparative example Preparation Example 1-1 0 100 100 0.5 133.1 202.2 One 104.4 198.8 1.5 102.2 190.6 2 101.6 191.4 2.5 102.5 170.4

As shown in Table 7 above, it can be seen that Preparation Example 1-1 has very excellent moisturizing power.

-Virtual measurement experiment of low particle cluster solvent transmittance

The micro-permeability measurement of the solvent of the 54 Hz cluster was performed, and the permeability measurement was carried out by applying the basic drug, litkine hydrochloride, to a portion of the soft scalp. Looking at the measurement results, when compared with pure water, when the cumulative amount of lutein hydrochloride in powder cleaning agent of Preparation Example 1 is 8 to 9 hours, 610 to 720 μg / cm 2, and when 10 hours is 1,320 to 1,400 μg / cm 2 and 15 hours 1,700 ~ 1,850 ㎍ / ㎠ was high. In the case of pure water, when it was 15 hours, it showed a very low result of 280 μg / cm 2, and thus it was confirmed that the skin permeability of the low particle cluster solvent of the present invention was excellent. As a result, it is judged that the composition of the present invention has excellent transmittance to the skin by using such a low particle solvent.

Claims (2)

Heating 100 parts by weight of the cluster solvent in the range of 54 Hz to 64 Hz to 50 ° C to 70 ° C;
Based on 100 parts by weight of the cluster solvent, 29 to 32 parts by weight of pine tree leaf liquid extract, 18 to 20 parts by weight of green tea extract, 2 to 5 parts by weight of natural cellulose and citric acid antioxidant, 10.3 to 20 parts by weight of cinnamon and grapefruit powder mixture , 2.4 parts by weight of di-panthenol, 7 parts by weight of cocobetaine (surfactant), 2 parts by weight of caprylyl glycol, 1.5 parts by weight of glycerin, 1.5 parts by weight of xanthan gum, 2 parts by weight of hydrogenated starch hydroxylate Part, 2 parts by weight of glucamate, 2 parts by weight of dimethicone, 2 parts by weight of aloe extract short-term product, 2.5 parts by weight of disodium laureth sulfosuccinic acid, 2 parts by weight of cocamidopropyl betaine, 2 parts by weight of lauramiddie , Mixing 2 parts by weight of sodium lauroyl glutamate and 2 parts by weight of acacia honey; And
Drying the mixture; Eco-friendly detergent composition manufacturing method comprising a. According to claim 1,
The composition is a powder capsule environment-friendly detergent composition manufacturing method characterized in that it is made of a powder and encapsulated.

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