KR102011368B1 - Cosmetic composition for deodorization comprising extracts of Pelargonium graveolens, Mentha arvensis var. piperascens, Origanum vulgare, Sambucus nigra L. and Salvia officinalis - Google Patents

Abstract

 The present invention is a method for producing a centrifugal geranium, peppermint, oregano, elder, sage complex extract excellent in the deodorizing effect of the chemical odor remaining in the hair during or after the treatment of permanent wave or hair dye and cosmetics for improving odor containing the composite extract It relates to a composition.

Description

Cosmetic composition for deodorization containing extracts of Pelargonium graveolens, containing mented argansis, peppermint, oregano, elder and sage complex extract. piperascens, Origanum vulgare, Sambucus nigra L. and Salvia officinalis}

The present invention relates to a cosmetic composition for improving odor, and specifically relates to a technology for preparing a centrifugal geranium, peppermint, oregano, elder, sage complex extract and using it in a permanent wave agent, hair dye odor improvement cosmetic composition.

As people's living standards improve, interest in environmental hygiene has increased, and deodorization and deodorization have become a great concern. Conventionally, as a method of reducing malodorous components, a method of masking unpleasant malodors by a strong fragrance, physical methods such as adsorbing malodors by porous adsorbents such as activated carbon, alumina, zeolite, etc. Chemical methods, such as oxidation method to oxidize, neutralization method using a chemical agent, or biochemical methods, such as decomposition of a bad smell component by bacteria, are known.

For example, when the permanent wave treatment is performed on the hair in a beauty salon or the like, ammonia, ethanolamine, ammonium thioglycolate and the like are used to improve wave storage. After completion of the perm treatment, such a treatment agent is mostly removed from the hair by acid treatment (pH 3), reduction treatment, or water washing. However, a trace amount of ammonium thioglycolate component still remains in the hair, and therefore, a odor peculiar to the hair can be felt even after 2-3 days. In addition, the hair dye used for hair dyeing may contain ammonia or ethanolamine components, so odor may remain after dyeing.

Such odors that are actually a problem in daily life, including residual odors after permanent wave treatment or dyeing treatment, include basic odors, acidic odors and mixed odors thereof, and are composed of various components. Deodorants having a deodorant effect are also required for components.

The present inventors have been studying to prepare a deodorant of natural ingredients with excellent deodorant effect, the cosmetic composition containing the centrifugal geranium, mint, oregano, elder and sage complex extract by a specific extraction method is ammonia, ethanolamine components, etc. The present invention was completed by confirming the excellent deodorant effect on the permanent wave agent and the hair dye contained.

Republic of Korea Patent No. 10-1679334 (2016.11.24.) Republic of Korea Patent No. 10-0733377 (2007.06.29.)

An object of the present invention is to provide a method for producing a centered geranium, peppermint, oregano, elder and sage complex extract excellent in the deodorizing effect of the chemical odor remaining in the hair during or after the permanent wave or dyeing treatment.

In addition, another object of the present invention is to provide a cosmetic composition for improving odor containing the sentimental geranium, mint, oregano, elder, sage complex extract.

In order to achieve the above object, according to the present invention (A) water in a mixture of centered geranium, mint, oregano, elder and sage, anhydrous or hydrous alcohol having 1 to 4 carbon atoms, ethyl acetate, acetone, glycerin, ethylene glycol, propylene Extracting by adding at least one extraction solvent selected from the group consisting of glycol, dipropylene glycol and butylene glycol; (B) enzymatically treating the solvent extract prepared by the above step with a hydrolase to prepare enzymatically treated complex extracts of sentarinium, mint, oregano, elder and sage; And (C) adding a 5-10-fold volume shell shell solution to the centrifugal geranium, peppermint, oregano, elder and sage enzyme-treated complex extracts, and heating and extracting the resultant by heating to 80-100 ° C. , Peppermint, oregano, elder and sage complex extract is provided.

In the step (A), the centrated geranium, peppermint, oregano, elder and sage are extracted by mixing in a weight ratio of 1 to 3: 1 to 3: 1 to 3: 1 to 3: 1 to 3, respectively.

In the step (B), the hydrolase is preferably beta-glucanase.

In the step (C), the shell solution is obtained by filtration of the shell shell by calcination of the shell at 1000 to 1500 ° C. for 10 to 30 minutes, followed by heating at 100 to 120 ° C. for 5 to 30 minutes, followed by filtration. It is desirable to.

In order to achieve the above another object, according to the present invention, the odor improvement cosmetics containing the centrifugal geranium, peppermint, oregano, elder and sage complex extract prepared by the manufacturing method with respect to the total weight of the cosmetic composition A composition is provided. The cosmetic composition may be used as a cosmetic for improving the smell of perming wave agent and for improving the smell of hair dye.

The composite extract of the sentidal geranium, peppermint, oregano, elder and sage prepared by the manufacturing method according to the present invention is safe to the human body, and because of its synergistic effect, it shows an excellent odor-improving effect on permanent wave and hair dyes. Useful as

Hereinafter, the present invention will be described in detail.

Sented geranium ( Pelargonium graveolens ) refers to the genus of directional pelargonium, which has essential oils on the leaves and stems, unlike pelargonium inquinans , commonly known as horticultural species. There are over 200 species of varieties in the world, with heights of 30-100 cm, depending on the variety. It is native to Reunion Island, which lies on the eastern sea of Madagascar, southeastern South Africa. Leaves vary in serrated and round serrates, and run differently on branches. At the end of petiole is a honey bucket shaped like a bird's daughter's claw. The petals are 5 at the top, 2 at the top, and 3 at the bottom. Flowers bloom twice in April-July and September-October. The color of flowers varies from white to pink to red and the shape is not uniform. But overall, flowers are smaller and less noticeable than ornamental geraniums. In particular, while ornamentals do not smell, different varieties have a unique scent in the leaves or stems. Most varieties are named after similar flowers, berries, and spices. Rose, lemon, peppermint, apple, pine, royal oak, apple cider are various. Among them, rose geranium is the most representative sentinium, which is used as a fragrance for perfumes, cosmetics, and soaps. It grows well in warm climates, is vulnerable to coldness, and doesn't like humidity. When growing, sunny, well-ventilated, oily land is good. Breeding is done by seeding and folding. Leaves and stems are mainly used as raw materials for perfumes, fragrances for salads, cakes, sweets, etc. In addition, it is used as a medicine such as neuro stabilizers, breast anti-inflammatory drugs, diuretics, and is also planted as an ornamental potted plant. It is widely distributed in South Africa, Europe, and Asia, and is grown in Korea for herbs.

Peppermint ( Mentha arvensis var. Piperascens ) is also known as late night (향 香), Bunhachae, Indancho (仁 丹 草), Gubakha (歐 薄荷). It grows in humid fields. It is 60-100cm in height. Stems are rectangular in cross section with hairs on the surface. The leaves are faced with a single leaf with a sack and the edge is serrated. There is an oil gland on the leaf surface, which secretes oil. Most of the essential oils are stored in this oil gland. From summer to autumn, a pale purple small flower runs in the shape of an ear on the upper leaf axle of the stem. There are 4 stamens, 1 pistil is divided into 2 tips, and 4 ovaries. Flowers usually bloom in the morning, with pistils correcting three to four days after flowering and two to three days after surgery. Seeds are egg-shaped light brown, light and small, and germinate at a temperature of 20 → 30 → 15 ℃. The main ingredient of peppermint oil is menthol, which is medicinal in coatings, painkillers, stimulants, nutrients, insect repellents, or as a refreshing or flavoring agent in toothpaste, jam, candy, cosmetics, tobacco, etc.

Origanum vulgare , also known as flowering peppermint, is characterized by a scent of mint. It is a herb that stands up to pests and colds and has the strength of wildflowers. The height is 30 ~ 60㎝, the leaves are about 1.5㎝ long and have a good aroma and bitter taste. The flowers are 4mm in diameter, purple-pink in lip, and form a watery inflorescence at the end of the stem from July to October. It is resistant to cold and heat, and does not cover soil and places, so it is good for drainage and grows well in sunny soil. Sowing season is from April to June and September to October. Seeds are scattered in seedlings or pots, covered with a thin layer of soil, and watered. Breeds by folding and giving up, and can be enjoyed for ornamental purposes. Harvest and dry the flowers at the time of flowering and preserve the dried leaves with spices. Its unique aroma and spicy taste go well with tomato, making it an indispensable spice for Italian dishes, especially pizza. It is also used in Mexican dishes such as chili powder and chili con carne, as well as spaghetti, omelette, beef stew, lamb and tomato juice. Many sauces, the basis of French cuisine, are also an advanced form of ancient Roman sauces, with oregano as their main ingredient. It is also used as a dry flower, put dry leaves and flowers in your pocket and is effective when used in hot poultice of rheumatism patients. Oregano leachate, which has been used as a herbal medicine since ancient Greek times, has tonic, diuresis, dryness, appetite boosting, soothing and sterilizing effect. It is also effective for seasickness, nervous headaches and insomnia. It is widely cultivated in many countries along the Mediterranean coast and in the United States.

The elder (Sambucus nigra L.) is also known as the elder tree. It grows up to 7m in height. It is a kind of herb native to Europe, Asia, and North Africa. It is regarded as a sacred tree in many countries and is not treated in vain. The name 'elder' comes from the name 'oelder' which means 'flame'. This is the name given to the fact that a young eggplant was pulled out and made a fire. Stems and bark of old branches are grayish brown with cracks. Newly formed branches have brown and gray spots. The genus in the branch is pale white. The leaves are opposite each other, elliptical, pointed and irregularly sawed. Consists of light green small leaves with sparse hairs. Chin leaves look like threads and fall early. In June-July, creme-colored flowers are closely gathered at the tip of the branch, forming an umbrella shape, and running in a mountainous inflorescence. The flower has a strong fragrance and the calyx is short tubular with five short teeth. The stamen is 5 pieces with yellow pollen bag. Fruits are black, succulent, and seeds are brown oval. Medicinal from root to fruit. Herbal teas made from dried flowers with lime and chamomile are effective for colds and coughs. Flower distilled water is also used as a lotion to make the skin elastic. Fruits are used to make jams, jellies, syrups, vinegars, wines, etc. In particular, elder wines are effective for colds, asthma and rheumatism.

Sage (Salvia officinalis) is also known as medicinal salvia. Sage is also called Common Sage, Garden Sage and is often called Salvia. Stems are rectangular with almost woody bottoms, 30-90 cm high, with scents throughout. The leaves are opposite, the petiole is short, the long oval is dull and the edge is flat. The back side of the leaf is gray with white hairs with the stem, and the surface has reticular fine wrinkles. Flowers bloom in May-July and purple, with gunshot inflorescences on the ends of branches. Flowers have honey, which is a wheat plant in which bees gather. Calyx tube is bell-shaped and corolla is 1.5 ~ 2cm long, and the upper and lower two flowers are split like upper and lower lips at the tip of wide tube. The upper lip is broken and the lower lip is divided into three broadly. There are two stamens and the style is longer than the upper lip of the corolla. Many varieties have blue and white flowers. Sowing in spring or autumn and picking leaves in August and drying in the shade is called salvia leaf (folia salvia) and contains about 2% essential oils (精油). The main components of essential oils are alphapinene, sesquiterpenes, and borneol, which are used as flavoring agents for sauces, curry, and pork dishes. For medicinal purposes, the leaves are boiled and used for sore throat and gastroenteritis. Antiseptic, antiseptic, antiseptic, etc. It is also used as an anti-inflammatory agent for inflammation. It also cleans you from fatigue after a stroke or heavy exercise. Native to southern Europe, it has been widely cultivated as a home herb since ancient times in Europe.

The present invention utilizes that the sentient geranium, peppermint, oregano, elder and sage composite extract prepared by a specific method has an excellent odor improvement effect against ammonia or ethanolamine.

According to the present invention (A) water in the mixture of centered geranium, mint, oregano, elder and sage, anhydrous or hydrous alcohol having 1 to 4 carbon atoms, ethyl acetate, acetone, glycerin, ethylene glycol, propylene glycol, dipropylene glycol And extracting by adding at least one extraction solvent selected from the group consisting of butylene glycol; (B) enzymatically treating the solvent extract prepared by the above step with a hydrolase to prepare enzymatically treated complex extracts of sentarinium, mint, oregano, elder and sage; And (C) adding a shell solution of 5-10 times the volume to the enzyme-treated complex extract of the germinated geranium, peppermint, oregano, elder and sage, and heating and extracting the germinated geranium to 80 to 100 ° C. , Peppermint, oregano, elder and sage complex extract is provided.

In the step (A), it is preferable to use the centrated geranium, mint, oregano outpost, elder flower, sage leaf area.

In addition, the extraction in the step (A) of the temperature of 100 ~ 120 ℃, 2 ~ 3kgf / cm ² More preferably, the mixture is heated by steam for 10 to 15 minutes at a pressure.

According to one embodiment of the present invention, 5-15 hours in a centrifugal geranium starch, peppermint starch, oregano starch, elderflower flower, sage leaves at a temperature of 20 to 30 ° C. and a humidity of 35 to 40%. By drying for a while, the moisture content of the original is maintained to be 30-40% by weight relative to the original weight. Then, the temperature of 120 ℃, 2-3 kgf / cm ² The extract is prepared by heating with steam for 15 minutes at pressure.

In the step (A), the centrated geranium, mint, oregano, elder and sage are extracted by mixing in a weight ratio of 1 to 3: 1 to 3: 1 to 3: 1 to 3: 1 to 3, respectively, preferably Is in the ratio of 2 to 3: 2 to 3: 1 to 2: 1: 2, and more preferably in the ratio of 3: 3: 2: 1: 2 to improve the odor improving effect of the permanent wave agent and the hair dye. Best.

In the step (B), the hydrolase is preferably beta-glucanase, more preferably biscozyme.

In the step (C), the shell solution is obtained by calcination of the shell by firing the shell at 1000 to 1500 ° C. for 10 to 30 minutes in purified water and heating it at 100 to 120 ° C. for 5 to 30 minutes, followed by filtration. It is preferable that the shell dissolution liquid as the said extraction solvent is pH 8-10. In this case, the shell may be a shell of at least one shell selected from the group consisting of oysters, ramie clams, clams, abalone and mussels.

As described above, the centrifuged geranium, peppermint, oregano, elder and sage are mixed in a specific ratio, followed by solvent extraction, followed by enzymatic treatment to prepare an enzyme-treated complex extract, which is then extracted by using a shell solution as an extraction solvent. Sented geranium, peppermint, oregano, elder and sage composite extract of the present invention showed a very excellent permanent wave agent, hair dye odor improvement effect.

The complex extract as an active ingredient may be added to the cosmetic in a proportion of 0.001 to 30% by weight, more preferably 0.001 to 5.0% by weight based on the total weight of the cosmetic composition.

Since the cosmetic composition has excellent odor-improving effect on ammonia and ethanolamine, it may be applied as a formulation of hair dye, permanent wave agent, shampoo, rinse, hair conditioner, hair gel, and the like.

EXAMPLE

Hereinafter, the configuration and effects of the present invention will be described in detail through examples, but the present invention is not limited thereto.

Preparation Example 1: Preparation of Shell Solution

1 kg of oyster shells were calcined for 30 minutes by direct or indirect heat at 1200 ° C., and the shells were crushed into 200 meshes using a grinder. The oyster shell powder was placed in 10-fold volume of purified water and heated for 30 minutes with heat of 100 ° C. The solid powder was separated by a filter to obtain a shell solution.

Example 1 Preparation of Scented Geranium, Peppermint, Oregano, Elderflower and Sage Complex Extract

In a dryer maintained at a temperature of 20 ° C. and a humidity of 35%, an outpost of centrifugal geranium, a peppermint outpost, an oregano outpost, an elderflower flower, and a sage leaf were mixed (total weight 1100 g) in the same weight ratio. 2 kg of 70% ethanol was added and extracted by boiling at 50 ° C. in an extractor equipped with a cooling capacitor. It dried and 150g of extract powders were obtained.

Purified water was added to the extract powder, and 0.5% of Viscozyme enzyme was added and reacted at 50 ° C. for 2 hours. Next, the reaction was concentrated in vacuo after heating to 95 ° C. for 30 minutes to complete the enzyme reaction. The concentrate was dried at 60 ° C. for 30 hours.

The shell solution of Preparation Example 1 was added to the enzyme-treated extract powder 10 times the volume and heated to 80 ~ 100 ℃ in an extractor (Cosmos-660, Gyeongseo machine) was extracted three times a total of 2 hours. After the extraction by the above method, the precipitate obtained by standing at room temperature for 3 days was filtered through a 300 mesh filter paper, and the precipitate was filtered twice with an Adventech No. 5 filter paper and a Whatman GFC 150 mm filter paper. After concentrating at a temperature of 40-50 ° C. using a decompression concentrator (Coolace CCA-1100, EYELA), using a spray dryer (B-290, BUCHI Co., Ltd.), the inlet temperature is 180 ° C. and the inhaler efficiency. 100% (35 cm 3 / hour), Pump efficiency 25% (7.5 ml / min), Nozzle Cleaner 4 and Rotameter: Dry under conditions of 30 mm (357 liters / hour) 100 g of the title extract powder was obtained.

Example 2 Preparation of Scented Geranium, Mint, Oregano, Elderflower and Sage Mixed Extract

In a dryer maintained at a temperature of 20 ° C. and a humidity of 35%, an outpost of centrifugal geranium, a peppermint outpost, an oregano outpost, an elderflower flower, and a sage leaf were mixed in the same weight ratio (total weight 1100 g). The mixture was heated at a temperature of 120 ° C., 2 to 3 kgf / cm ² . The mixture was heated with steam for 15 minutes at a pressure, extracted, and dried to obtain 150 g of an extracted powder.

Purified water was added to the extract powder, and 0.5% of Viscozyme enzyme was added and reacted at 50 ° C. for 2 hours. Next, the reaction was concentrated in vacuo after heating to 95 ° C. for 30 minutes to complete the enzyme reaction. The concentrate was dried at 60 ° C. for 30 hours.

The shell lysate of Preparation Example 1 was added to the enzyme-treated extract powder 10 times by volume and heated to 80 ~ 100 ℃ in an extractor (Cosmos-660, Gyeongseo machine) was extracted three times each 2 hours. After the extraction by the above method, the precipitate obtained by standing at room temperature for 3 days was filtered through a 300 mesh filter paper, and the precipitate was filtered twice with an Adventech No. 5 filter paper and a Whatman GFC 150 mm filter paper. After concentrating at a temperature of 40-50 ° C. using a decompression concentrator (Coolace CCA-1100, EYELA), using a spray dryer (B-290, BUCHI Co., Ltd.), the inlet temperature is 180 ° C., aspirator efficiency. 100% (35 cm 3 / hour), Pump efficiency 25% (7.5 ml / min), Nozzle Cleaner 4 and Rotameter: Dry under conditions of 30 mm (357 liters / hour) 100 g of the title extract powder was obtained.

Examples 3-9: Preparation of centrifugal geranium, mint, oregano, elder and sage complex extract according to the extraction ratio

Scented geranium starch, peppermint starch, oregano starch, elder flowers, sage leaf weight ratio was adjusted as shown in Table 1 (total weight 1100g) to prepare an extract in the same manner as in Example 2.

division Mixing ratio Example 3 2: 2: 1: 1: 2 Example 4 3: 2: 1: 1: 2 Example 5 2: 3: 1: 1: 2 Example 6 3: 3: 1: 1: 2 Example 7 2: 2: 2: 1: 2 Example 8 2: 3: 2: 1: 2 Example 9 3: 3: 2: 1: 2

Comparative Example 1: Preparation of Scented Geranium Extract

Purified and dried 1100 g of centered geranium purchased from a herb retailer with purified water, and then an extract was prepared in the same manner as in Example 2.

Comparative Example 2: Preparation of Mint Extract

After extracting 1100 g of peppermint outpost purchased from Gyeongdong market with purified water and dried, extracts were prepared in the same manner as in Example 2.

Comparative Example 3: Preparation of Oregano Extract

After extracting 1100 g of oregano outpost purchased from a herb vendor with purified water and dried, extracts were prepared in the same manner as in Example 2.

Comparative Example 4: Preparation of Elder Extract

After extracting 1100g elder flowers purchased from Gyeongdong market with purified water and dried, extracts were prepared in the same manner as in Example 2.

Comparative Example 5: Preparation of Sage Extract

The extract was prepared in the same manner as in Example 2 after washing and drying 1100 g of sage leaves purchased from a herb vendor with purified water.

Comparative Example 6: Preparation of Scented Geranium, Mint, Oregano, Elder and Sage Complex Extract

In a dryer maintained at a temperature of 20 ° C. and a humidity of 35%, an outpost of centrifugal geranium, a peppermint outpost, an oregano outpost, an elderflower flower, and a sage leaf were mixed in the same weight ratio (total weight 1100 g). 2 kg of 70% ethanol was added and extracted by boiling at 50 ° C. in an extractor equipped with a cooling capacitor. It dried and 150g of extract powders were obtained.

Comparative Example 7: Preparation of Sented Geranium, Mint, Oregano, Elder and Sage Complex Extract

In a dryer maintained at a temperature of 20 ° C. and a humidity of 35%, an outpost of centrifugal geranium, a peppermint outpost, an oregano outpost, an elderflower flower, and a sage leaf were mixed in the same weight ratio (total weight 1100 g). The mixture was heated at a temperature of 120 ° C., 2 to 3 kgf / cm ² . The mixture was heated with steam for 15 minutes at a pressure, extracted, and dried to obtain 150 g of an extracted powder.

Purified water was added to the extract powder, and 0.5% of Viscozyme enzyme was added and reacted at 50 ° C. for 2 hours. Next, the reaction was concentrated in vacuo after heating to 95 ° C. for 30 minutes to complete the enzymatic reaction. Inlet temperature 180 ℃, Aspirator efficiency 100% (35 cm3 / hour), Pump efficiency 25% (7.5 ml / min), nozzle using spray dryer (B-290, BUCHI Co., Ltd.) Nozzle Cleaner 4 and Rotameter were dried under the conditions of 30 mm (357 liters / hour) to obtain 100 g of the title powder.

Comparative Example 8 Preparation of Sented Geranium, Peppermint, Oregano, Elder and Sage Complex Extract

In a dryer maintained at a temperature of 20 ° C. and a humidity of 35%, an outpost of centrifugal geranium, a peppermint outpost, an oregano outpost, an elderflower flower, and a sage leaf were mixed in the same weight ratio (total weight 1100 g). The mixture was heated at a temperature of 120 ° C., 2 to 3 kgf / cm ² . The mixture was heated with steam for 15 minutes at a pressure, extracted, and dried to obtain 150 g of an extracted powder.

The shell solution of Preparation Example 1 was added to the extract powder 10 times by volume and heated to 80 ~ 100 ℃ in an extractor (Cosmos-660, Gyeongseo machine) was extracted three times a total of 2 hours. After the extraction by the above method, the precipitate obtained by standing at room temperature for 3 days was filtered through a 300 mesh filter paper, and the precipitate was filtered twice with an Adventech No. 5 filter paper and a Whatman GFC 150 mm filter paper. After concentrating at a temperature of 40-50 ° C. using a decompression concentrator (Coolace CCA-1100, EYELA), using a spray dryer (B-290, BUCHI Co., Ltd.), the inlet temperature is 180 ° C., aspirator efficiency. 100% (35 cm 3 / hour), Pump efficiency 25% (7.5 ml / min), Nozzle Cleaner 4 and Rotameter: Dry under conditions of 30 mm (357 liters / hour) 100 g of the title extract powder was obtained.

Test Example 1: Gas Detection Tube Method

For the extracts prepared in Examples and Comparative Examples, the effect of improving hair dye odor was measured.

1) Experiment Method

Insert the appropriate amount of deodorant test substance (ml or g) into the flask, insert NH ₃ into the gas detector tube (No. 3H, GASTEC, Japan), seal it completely, and wait 30 minutes to read the degree of change of the color reagent in the detector tube in%. Measured. As a control, a hair dye containing ammonia and ethanolamine was used.

2) Experiment result

The results are shown in Table 2 below.

sample %(Average) Hair dye 12.6 Example 1 6.6 Example 2 5.8 Example 3 4.8 Example 4 4.4 Example 5 5.0 Example 6 4.2 Example 7 4.6 Example 8 5.0 Example 9 2.2 Comparative Example 1 11.4 Comparative Example 2 11.6 Comparative Example 3 12.1 Comparative Example 4 12.5 Comparative Example 5 12.0 Comparative Example 6 9.2 Comparative Example 7 7.9 Comparative Example 8 7.2

Test Example 2: Sensory Evaluation Method

Bottles with lids were washed and dried to assess odor. After the bottle was completely dry, a piece of odorless tissue was placed in the bottle. The hair dye, and the materials of the compositions of Examples 1 to 9 and Comparative Examples 1 to 8 were dropped onto the tissue using droppers each 2 ml. One hour after the lid was closed, the lid was opened and 10 subjects were smelled 10 each. After that, it was evaluated by classifying from 1 to 10 points according to the strength of the smell. As a control, a hair dye containing ammonia and ethanolamine was used. (1 point: weak smell ~ 10 points: strong smell)

sample Average score Hair dye 9.8 Example 1 5.9 Example 2 5.2 Example 3 4.0 Example 4 3.8 Example 5 3.9 Example 6 3.5 Example 7 3.4 Example 8 3.2 Example 9 1.8 Comparative Example 1 8.2 Comparative Example 2 8.0 Comparative Example 3 7.6 Comparative Example 4 7.0 Comparative Example 5 7.5 Comparative Example 6 7.2 Comparative Example 7 6.3 Comparative Example 8 6.5

As shown in Table 2 and Table 3, after centrifugal solvent extraction of the geranium, peppermint, oregano, elder and sage mixture, the hydrolysis extract prepared by hydrolysis is extracted back to the shell solution to the centimeter of the present invention Degeranium, peppermint, oregano, elder and sage complex extracts were prepared by extracting solvents for each extract (Comparative Examples 1-5), complex extracts prepared by only solvent extraction (Comparative Example 6), followed by enzyme treatment after solvent extraction for the mixture. Compared to the prepared composite extract (Comparative Example 7) and the solvent extraction for the mixture, the extract was extracted with a shell solution to show an excellent odor improvement effect of ammonia and ethanolamine compared to the composite extract (Comparative Example 8).

Scented geranium, peppermint, oregano, elder and sage mixtures are prepared at a temperature of 120 ° C., 2-3 kgf / cm ² . The composite extract of Example 2 prepared by heating with steam at pressure showed an excellent effect compared to the composite extract of Example 1 prepared after ethanol extraction. In relation to the mixing ratio, the centrifuged geranium, peppermint, oregano, elder and sage were mixed at 2 to 3: 2 to 3: 1 to 2: 1: 2, respectively, and the overall excellent effects were obtained in the extracted examples 3 to 9. It was shown in the composite extract of Example 9, which was mixed and extracted in a ratio of 3: 3: 2: 1: 2, respectively, and showed the best effect.

Test Example 3: Gas Detection Tube Method

Permanent wave agent odor improvement effect was measured for the extracts prepared in Examples and Comparative Examples.

1) Experiment Method

Insert the appropriate amount of deodorant test substance (ml or g) into the flask, insert NH ₃ into the gas detector tube (No. 3H, GASTEC, Japan), seal it completely, and wait 30 minutes to read the degree of change of the color reagent in the detector tube in%. Measured. As a control, a permanent wave agent containing ammonia and ethanolamine was used.

2) Experiment result

The results are shown in Table 4 below.

sample %(Average) Permanent Wave 14.1 Example 1 7.9 Example 2 7.6 Example 3 6.6 Example 4 6.0 Example 5 7.2 Example 6 6.3 Example 7 6.5 Example 8 7.1 Example 9 4.2 Comparative Example 1 13.2 Comparative Example 2 13.0 Comparative Example 3 14.3 Comparative Example 4 14.7 Comparative Example 5 14.2 Comparative Example 6 11.2 Comparative Example 7 9.8 Comparative Example 8 9.1

Test Example 4: Sensory Evaluation Method

Bottles with lids were washed and dried to assess odor. After the bottle was completely dry, a piece of odorless tissue was placed in the bottle. Permanent waves and the materials of the compositions of Examples 1 to 9 and Comparative Examples 1 to 8 were dropped onto the tissue using droppers each 2 ml. One hour after the lid was closed, the lid was opened and 10 subjects were smelled 10 each. After that, it was evaluated by classifying from 1 to 10 points according to the strength of the smell. As a control, a permanent wave agent containing ammonia and ethanolamine was used. (1 point: weak smell ~ 10 points: strong smell)

sample Average score Permanent Wave 9.3 Example 1 5.4 Example 2 4.2 Example 3 3.2 Example 4 3.0 Example 5 3.3 Example 6 2.9 Example 7 2.5 Example 8 2.3 Example 9 1.5 Comparative Example 1 7.3 Comparative Example 2 7.1 Comparative Example 3 6.7 Comparative Example 4 6.6 Comparative Example 5 6.6 Comparative Example 6 6.3 Comparative Example 7 5.8 Comparative Example 8 5.9

As shown in Table 4 and Table 5, after centrifuged solvent extraction of the geranium, peppermint, oregano, elder and sage mixture, the hydrolysis extract prepared by hydrolysis is extracted back to the shell solution to centi Degeranium, peppermint, oregano, elder and sage complex extracts were prepared by extracting solvents for each extract (Comparative Examples 1-5), complex extracts prepared by only solvent extraction (Comparative Example 6), followed by enzyme treatment after solvent extraction for the mixture. Compared to the prepared composite extract (Comparative Example 7) and the solvent extraction of the mixture, the extract was extracted with a shell solution and showed a superior effect of improving the odor of ammonia and ethanolamine compared to the prepared composite extract (Comparative Example 8).

 Sented geranium, peppermint, oregano, elder and sage were mixed in 2 to 3: 2: 3 to 1 to 2: 1: 2, respectively, and showed better overall effects in Examples 3-9.

Centrifugal geranium, mint, Oregano, elder and sage complex extracts were found to have excellent odor improvement effects for permanent wave and hair dye.

Claims (7)

(A) Sented geranium made by mixing the sentimental geranium starch, peppermint starch, oregano starch, elder flower, and sage leaves in a weight ratio of 2 to 3: 2 to 3: 1 to 2: 1: 2 , Extracting the mint, oregano, elder and sage mixture by heating with water vapor for 10-15 minutes at a temperature of 100-120 ° C., a pressure of 2-3 kgf / cm 2;
(B) preparing an enzymatically treated complex extract of centrazed geranium, peppermint, oregano, elder and sage by treating the extract prepared in step B. And
(C) added to the centrifugal geranium, peppermint, oregano, elder and sage enzyme treatment complex extract 5-10 times the volume of shell dissolution solution, and sentimental geranium comprising the step of heating to 80 ~ 100 ℃, Method for producing peppermint, oregano, elder and sage complex extract. delete delete According to claim 1, wherein the shell solution in step (C) is the shell shell calcined by firing the shell at 10 ~ 30 minutes at 1000 ~ 1500 ℃ put into purified water and heated for 5 to 30 minutes at 100 ~ 120 ℃ , The method for producing a centrifugal geranium, peppermint, oregano, elder and sage complex extract, characterized in that obtained by filtration. Scented geranium, peppermint, oregano, elder and sage composite extract prepared by the method of claim 1 or 4 comprising 0.001 to 30% by weight relative to the total weight of the cosmetic composition. The cosmetic composition for odor improvement according to claim 5, wherein the cosmetic composition is for odor improvement for permanent wave agent. The cosmetic composition for improving odor according to claim 5, wherein the cosmetic composition is for improving odor of hair dye.