KR101994168B1 - Function fertilizer for enriching absorption of germanium and manufacturing method thereof - Google Patents

Abstract

The present invention relates to a functional fertilizer for increasing the germanium absorption rate of plants, and a method for manufacturing the same. More specifically, the present invention relates to: a functional fertilizer, increasing the plant absorption rate by mixing and fermenting microorganisms, inorganic germanium and garlic components containing a large amount of organic germanium, and providing an increase in immunity, and antibacterial, bactericidal and growth promoting effects of crops; and a manufacturing method thereof.

Description

FUNCTION FERTILIZER FOR ENRICHING ABSORPTION OF GERMANIUM AND MANUFACTURING METHOD THEREOF}

The present invention relates to a functional fertilizer for increasing the germanium absorption rate of the plant and a method for producing the same, and more specifically, by mixing and fermenting a garlic component containing a large amount of organic germanium, inorganic germanium and microorganisms to increase the plant absorption rate, the immunity of the crop The present invention relates to a functional fertilizer and a method for producing the same, which provide an increase, an antibacterial effect, a bactericidal effect and a growth promoting effect.

Germanium is distributed evenly in trace amounts in the natural mineral or surface soil layers, and it is confirmed that even some groundwater contains a trace amount. Therefore, some plants growing in the germanium-rich soil or some plants growing in the groundwater containing germanium have been found to contain trace amounts of organic germanium in the plants.

Inorganic germanium is fatal to humans when taken in high doses, and organic germanium has been shown to be effective in treating many modern incurable diseases, as evidenced by various clinical trials. . In addition, biosynthetic organic germanium (GeCH ₂ CH ₂ COOH) ₂ O ₃ ] called Ge-132 or biosynthetic organic germanium using yeast has surprising effects on humans and animals, but the product is 100% organic. Complementary research is being actively conducted since this has not been achieved, and until now, it is known that vegetable organic germanium is excellent in terms of stability and effectiveness.

Korean Patent Laid-Open Publication No. 2003-0021750 (published on March 15, 2003; hereafter referred to as 'Previous Document 1') has proposed an organic germanium composite fertilizer and a method of manufacturing the same. The prior document 1, the step of dissolving the organic germanium in cold or boiling water to make the organic germanium water; Nitrogen 1-5%, water-soluble phosphoric acid 2-10%, water-soluble potassium 2-10%, water-soluble zinc 0.05-2%, boron-soluble boron 0.05-2%, water-soluble copper 0.05-2%, water-soluble calcium 0.05 Dissolving two or more selected from ˜2% by weight and 0.05-2% by weight of water-soluble clay in water to form a composite fertilizer solution; The organic germanium water and the composite fertilizer liquid are mixed in a ratio of 1:10 to 20 by weight to prepare an organic germanium composite fertilizer. However, prior art document 1 uses organic germanium as a fertilizer, which may increase the germanium content of the plant, but the manufacturing cost is excessively consumed, and the amount of absorption of the plant is low compared to the amount of organic germanium to be supplied.

Korean Patent Registration No. 10-0481301 (registered Mar. 28, 2005; hereafter referred to as 'Previous Document 2') has suggested a method of cultivating a crop containing a vegetable natural organic germanium. The prior document 2 is a) to the inorganic germanium or organic germanium water or alkali aqueous solution is added in a ratio of 100: 0.1 ~ 10 based on the weight of the solvent and then stirred for 30 minutes to 24 hours at a temperature of 35 ~ 120 ℃ Thereby liquefying germanium to a direct absorption of the plant, and b) sodium hypophosphite or sodium hydroxide based on the amount of germanium in the solution so that the solution does not readily react to changes in temperature, moisture, and the like. While adding at a rate of 0.5 to 2, while adjusting the pH of the solution in the range of 6 to 8 to prepare a step comprising stabilizing the solution. However, the prior document 2 is to liquefy by mixing and stirring the organic or inorganic germanium in water or an aqueous alkali solution, so that the absorption of the plant is achieved, low production efficiency when using organic germanium, inorganic germanium is water-soluble only by mixing with water This conversion is also less efficient because the conversion to organic germanium is difficult

Therefore, there is a need for research on a new type of functional fertilizer capable of increasing the content of germanium in plants by increasing the absorption of plants by promoting the conversion of inorganic germanium into organic germanium.

Korean Patent Publication No. 2003-0021750 (2003.03.15.Publication): Organic germanium compound fertilizer and its manufacturing method Korean Registered Patent No. 10-0481301 (2005.03.28.registration): Cultivation method of crops containing vegetable natural organic germanium

The functional fertilizer of the present invention and its manufacturing method,

The fermentation process is carried out by mixing garlic components containing a large amount of vegetable organic germanium, inorganic germanium and microorganisms, and converting inorganic germanium to organic germanium during the growth of microorganisms in the fermentation process to increase the content of organic germanium to organic An object of the present invention is to provide a functional fertilizer capable of promoting germanium absorption and a method for producing the same.

Functional fertilizer of the present invention for achieving the above object,

In the functional fertilizer containing germanium, garlic powder containing 600 ~ 800ppm of plant-containing organic germanium; Inorganic germanium; One or two microorganisms selected from photosynthetic bacteria and Bacillus bacteria; One or two or more organic nutrients selected from alginic acid, algae and sugar; And water; characterized in that the fermented product to ferment the mixture.

The mixture is 10 to 15 parts by weight of inorganic germanium with respect to 100 parts by weight of the garlic powder; 20-30 parts by weight of microorganisms; 110 to 120 parts by weight of organic matter nutrient and 2000 to 2500 parts by weight of water; may be mixed.

In addition, the mixture may further be mixed with 0.3 to 1.0 parts by weight of boron 0.003 to 0.008 parts by weight based on 100 parts by weight of garlic powder as a microbial nutrient.

Garlic solution is impregnated with a diameter of 0.1 ~ 1mm with respect to 100 parts by weight of the fermentation, and the outer surface may be mixed with 1 to 2 parts by weight of porous ocher granules coated with protein.

Functional fertilizer manufacturing method according to the present invention,

A method for producing a functional fertilizer containing germanium, comprising: a raw material mixing step of mixing garlic powder containing 600 to 800 ppm of organic germanium containing plants, inorganic germanium (germanium oxide), an organic nutrient and water; Sterilization step by aeration of oxygen in the mixed raw material; A fermentation step of transferring the sterilized mixed raw materials to the fermentation tank and fermenting by further mixing the microorganisms; A fermentation step of transferring the fermentation product having undergone the fermentation step to a aging tank to ferment the remaining unfermented product; A filtration step of filtering the fermented product subjected to the aging step to remove solids of 1 mm or more; It may be made, including; a storage step for storing the filtered liquid fermentation.

In the sterilization step, the aeration tank 20 to 28 hours by aeration with oxygen or air to be sterilized by oxygen, the fermentation step, the fermentation is made while stirring for 20 to 28 hours at 35-40 ℃ heating conditions, The aging step, it may be left for 20 to 28 hours at 35 ~ 40 ℃ heating conditions to make the aging.

The raw material mixing step, 10 to 15 parts by weight of inorganic germanium, alginic acid, algae, sugar, one or two or more selected organic nutrients 110 to 120 parts by weight, 2000 to 2500 parts by weight of water ; In the fermentation step, 20 to 30 parts by weight of one or two selected microorganisms among photosynthetic bacteria and Bacillus bacteria may be mixed with respect to 100 parts by weight of garlic powder.

Next to the storage step, loess granulation step of baking the loess at 150 ~ 250 ℃; A selection step of selectively receiving the porous ocher grains having a diameter of 0.1 to 1.0 mm; Selected ocher grains are impregnated with garlic liquid to impregnate the garlic liquid; Take out the ocher grains impregnated with garlic liquid and mixing the mixture with 1 to 2 parts by weight based on 100 parts by weight of the stored fermentation product;

Ocher gran firing step of firing ocher to 150 ~ 250 ℃; A selection step of selectively receiving the porous ocher grains having a diameter of 0.1 to 1.0 mm; Selected ocher grains are impregnated with garlic liquid to impregnate the garlic liquid; Dispersing step of taking out the loess grains impregnated with garlic liquid and spread it in a single layer on the vibration screen; Spraying and spraying the liquid gelatin decomposed by mixing the collagen and water in 1: 2 to the dispersed ocher granules; Coated ocher grain mixing step of mixing the coated ocher grains in 1 to 2 parts by weight based on 100 parts by weight of the stored fermentation;

Functional fertilizer to increase the germanium absorption rate of the plant of the present invention by the above solution and its manufacturing method,

Garlic ingredients containing a large amount of organic germanium and inorganic germanium are fermented together with microorganisms, so that part of the inorganic germanium is converted into organic germanium, which is easily absorbed by plants by the decomposition of microorganisms, thereby increasing the germanium content of plants by increasing the germanium content of plants. It is increased. Large amounts of germanium allow plants to increase their immunity against the virus and enhance root growth to promote growth. In addition, it is possible to provide a useful functional fertilizer and its manufacturing method, such as to prevent pests by the antibacterial and bactericidal action by the garlic component added to the fertilizer.

1 is a flow chart showing a functional fertilizer manufacturing method according to an embodiment of the present invention.
Figure 2 is a flow chart illustrating a functional fertilizer manufacturing method mixed with ocher granules according to another embodiment of the present invention.
Figure 3 is a photograph comparing the cross-sectional view strawberry according to an embodiment of the present invention.
Figure 4 is a photograph comparing the size of soybeans according to an embodiment of the present invention.

Hereinafter, the present invention will be described in more detail with reference to Examples. The present invention may be modified in various ways and may have various forms, and specific embodiments will be illustrated in the drawings and described in detail in the present invention. However, this is not intended to limit the present invention to a specific disclosed form, it should be understood to include all modifications, equivalents, and substitutes included in the spirit and scope of the present invention.

Germanium has an excellent effect on mitigating various diseases by activating metabolism, and provides the effect of improving productivity by accelerating fruit or plant growth while accumulating germanium components during plant absorption. However, germanium is in the form of inorganic germanium when ingested into the human body is not well absorbed because the germanium effect can not be obtained and toxic effects are harmful to the human body. Therefore, the beneficial effect of the germanium can be obtained when it is ingested after stabilization through the organic germanium form, in particular through plants.

In order to stably ingest germanium, it is important to increase the amount of germanium accumulated in crops. In particular, in the case of providing organic germanium as a fertilizer to increase the germanium absorption of crops, the price competitiveness is lowered due to an increase in fertilizer manufacturing cost.

Therefore, in the present invention, a method of increasing the absorption rate of crops by increasing the content of organic germanium by fermenting a mixture of garlic containing a large amount of organic germanium and inorganic germanium for conversion into organic germanium by microorganisms is applied.

Functional fertilizer of the present invention is mixed with garlic powder, inorganic germanium, microorganisms, organic nutrients, water to prepare a mixture, fermentation aging the prepared mixture is provided as a fermentation product.

The garlic powder can be used to replace the garlic liquid, the content of the organic germanium 600 ~ 800ppm, and can be used by processing a product that is less commercially available or discarded. The organic germanium contained in the garlic is organic germanium stabilized by the plant absorption. These garlic ingredients include allicin, allin, alinase, scordinin, selenium, zinc, cysteine, metingin, etc., which are included in garlic, in addition to the contained organic germanium. It provides effective functions such as metabolism promotion, sterilization, antibacterial and growth promotion.

The inorganic germanium uses germanium oxide (GeO ₂ ), it is preferable to use a powder state.

As the microorganisms, various microorganisms capable of decomposing inorganic germanium and converting them into organic germanium may be applied. Preferably, red non-sulfur bacteria, which are photosynthetic bacteria, are used to survive regardless of anaerobic conditions, aerobic conditions, or light and dark, to decompose organic matter. To generate amino acids, and Bacillus bacteria can also be used. These microorganisms can increase the plant uptake of germanium by converting some of the inorganic germanium into an absorbable form in the process of decomposing organic matter to produce amino acids.

The organic nutrient may be composed of one or two or more selected from alginic acid, algae, sugar. The organic matter nutrient is provided as a nutrient that the growth of microorganisms are active while the amino acids generated in the decomposition of the microorganisms are absorbed by the plant to promote growth.

The composition ratio of the mixture is 10 to 15 parts by weight of inorganic germanium with respect to 100 parts by weight of the garlic powder; 20-30 parts by weight of microorganisms; 110 to 120 parts by weight of organic nutrient and 2000 to 2500 parts by weight of water;

When the inorganic germanium is mixed in an amount of 10 parts by weight or less, the conversion to organic germanium is easy to be absorbed, so the content of germanium is low in the plant. When the mixture is mixed in an amount of 15 parts by weight or more, the degree of improvement of the germanium content absorbed by the plant is insufficient. It is therefore preferable to mix in the above range.

In addition, when the microorganism is mixed at 20 parts by weight or less, the conversion rate from inorganic germanium to organic germanium is low, and the germanium content absorbed by plants is low. When the mixture is mixed at 30 parts by weight or more, the degree of improvement of the germanium content absorbed by plants is insufficient. It is preferable to mix in the range.

When the organic nutrient is mixed at less than 110 parts by weight, the amount of amino acids produced by the microbial decomposition effect is low, the growth of the plant is inadequate, and when mixed at 120 parts by weight or more, the amino acid production is increased but the improvement of the plant growth is insufficient. It is preferable to mix with.

By cultivating crops as functional fertilizers to increase the absorption of germanium by the above mixing ratio, the germanium content of the crop can be increased by more than 2 times and up to 8 times compared with the conventional one. For example, in the case of leafy vegetables such as lettuce can maintain the germanium content of more than 4.0 mg / L, preferably to contain germanium in a content of 6.20 ~ 7.8 mg / L. This can increase the germanium content by 2 to 10 times compared to spraying any fertilizer mixed with garlic powder or inorganic germanium in the general fertilizer, it is possible to ingest the germanium which is a beneficial ingredient through the plant.

In addition, a small amount of additives may be further mixed. The additive material may include boron and molybdenum, and 0.3 to 1.0 parts by weight of boron and 0.003 to 0.008 parts by weight of molybdenum based on 100 parts by weight of garlic powder.

The boron is an element necessary for the growth of the plant, it is preferable to mix in the above range by causing various physiological disorders when mixed below or above the above range.

In addition, the molybdenum is combined with an enzyme to the microorganism and the plant provides an antibacterial function, when whitening occurs on the leaves. Therefore, it is preferable that the physiological action is smoothly supplied to the above range.

The present invention may further mix the porous ocher granules to the fermentation fermentation of the mixture. The porous ocher granules can be used that the garlic liquid is impregnated with a diameter of 0.1 ~ 1mm. The porous ocher grains are mixed 1 to 2 parts by weight based on 100 parts by weight of the fermented product. The porous ocher granules may be impregnated with garlic liquid inside, so that the impregnated garlic liquid may be slowly expressed over time to provide continuous antibacterial, bactericidal and repelling effects. At this time, the ocher granules may form a coating layer coated with a material that is easy to decompose on the outer surface to allow the garlic layer to be discharged after the coating layer is decomposed after a predetermined time. At this time, the coating layer is preferably formed of a protein. In addition, ocher granules are less than 0.1mm in diameter, the amount of garlic liquid impregnation is insufficient to provide antimicrobial efficacy, and more than 1mm is settled because it is difficult to evenly spray and may cause problems to block the nozzle during the spraying process. It is formed in a range, preferably 0.2 to 0.5mm to use to minimize the precipitation. In addition, when the mixture is used in an amount of 1 part by weight or less, the antimicrobial function is insufficient, and when the mixture is mixed in an amount of 2 parts by weight or more, it is preferable to use the mixture in the above range. In addition, since the ocher grains are further mixed, it is preferable to supply the mixture while stirring the mixture uniformly by stirring.

1 is a flow chart illustrating a functional fertilizer manufacturing method for increasing the germanium absorption rate of the plant according to the present invention.

Functional fertilizer manufacturing method according to the present invention comprises a raw material mixing step, sterilization step, fermentation step, aging step, filtration step and storage step.

The raw material mixing step is a step of mixing garlic powder, inorganic germanium organic nutrients and water in the aeration tank. The garlic powder may be used in a liquid phase, and the inorganic germanium may be mixed in water as uniformly as possible using a powder form. In addition, organic nutrients may be used by selecting one or two or more of alginic acid, algae, sugar. At this time, stirring may be performed by a stirrer for homogenization.

The sterilization step is to remove harmful bacteria that may be included in the garlic powder and inorganic germanium by supplying oxygen to the aeration tank. In this step, the aeration is aerated by oxygen or air for 20 to 28 hours, in conjunction with the oxygen dissolving device to increase the amount of dissolved oxygen in the mixed raw material can provide a sterilization effect.

In the fermentation step, the sterilized mixture is introduced into the fermentation tank and the microorganisms are further mixed to make the fermentation. Although the present invention has been described as mixing the organic nutrient in the raw material mixing step, the organic nutrient can be added with the microorganism in the fermentation step. Organic nutrients include alginic acid, algae powder, and sugar, and fermentation takes place in an oxygen-supplied environment to increase protein production by breaking down proteins. At this time, inorganic germanium is also converted into organic germanium form that is easy to absorb plants. In addition, the fermenter is provided with a stirrer to make the agitation at a low speed to agitate the stored mixture so that the oxygen is uniformly supplied, and further aeration of oxygen may increase the internal dissolved oxygen to promote fermentation. This fermentation step is made for 20 to 28 hours at 35 ~ 40 ℃ heating conditions can be made in the oxygen supply environment to promote the fermentation. If the fermentation temperature is higher than the above conditions, the microorganisms are killed and the fermentation efficiency is lowered. If the fermentation temperature is lower than the set temperature, the fermentation takes a long time.

In the aging step, the fermented product, which has undergone the fermentation step, is transferred to a aging tank and left to mature for 20 to 28 hours under heating conditions of 35 to 40 ° C. Through this aging step, a small amount of unfermented fermentation can be further fermented to increase the fermentation efficiency of the fermented product to produce a uniform product.

The filtration step is a step of filtering the fermentation to remove the solid content of 1mm or more. That is, the step of removing the unreacted aggregated lump or foreign matter.

The storing step is a step of storing the filtered fermented product in a storage tank. In this step, the agitator is installed to allow continuous agitation so that solids of 1 mm or less are uniformly mixed. That is, the inorganic germanium may be uniformly distributed so that the remaining amount absorbed by the plant during spraying may act as a soil improver.

Functional fertilizer which is the stored fermentation may further be mixed with ocher grains impregnated with garlic liquid.

As shown in Figure 2, the ocher granules are used through the firing step and the porous granulated ocher granules, in the screening step was used to select the diameter of 0.1 ~ 1.0mm by passing through the mesh. The firing step was made for 1 hour at 150 ~ 250 ℃, the sorting step may include a grinding process.

Subsequently, in the impregnation step, crushed garlic is added to immerse the selected ocher granules in a storage tank in which only the filtered liquid material is stored, and mixed by at least 30 minutes by using a stirrer to inject garlic liquid into the porous ocher granules.

Here, the ocher pellets impregnated with the garlic liquid may be taken out and mixed with a fixed ratio in the fermented product stored after filtration, or the ocher pellets may be mixed and then subjected to a separate coating process.

In other words, the coating step is to take out the loess grains impregnated with garlic liquid to be placed on a flat plate vibration screen and to operate the vibrating screen to spread the loess grains; Spraying the heat-decomposed liquid gelatin by mixing 1: 2 of easy-to-decompose materials such as collagen and water in an unfolded state of the ocher granules to cover the ocher granules and to coat the inside of the ocher granules. Thus coated ocher granules can be produced through the coating ocher grain mixing step of mixing 1 to 2 parts by weight based on 100 parts by weight of the stored fermented product after filtration.

When the coated ocher granules are mixed with the functional fertilizer, the interior is initially sealed by the coating layer, but when the coating layer is decomposed after a certain time, the interior is exposed to provide additional antibacterial and repelling performance of the impregnated garlic liquid. Therefore, the antimicrobial and repelling efficacy can be provided longer than before.

The process of utilizing the ocher granules, the ocher pellet firing step, the screening step of selecting a certain size of the ocher granules, impregnating the selected ocher granules in the garlic liquid, the dispersion by spreading out by shaking the ocher granules impregnated with garlic liquid Step, the coating step of forming a coating layer by spraying a coating material that is easy to decompose into the unfolded ocher granules, proceeds to the mixing step of producing a mixture of the coated ocher granules to the filtered fermentation.

Example 1 Preparation of Functional Fertilizer

Garlic powder with organic germanium content of 600 ~ 800ppm, inorganic germanium powder, red non-sulfur bacteria as microorganism, sugar as organic nutrient.

In the fertilizer manufacturing method,

100 Kg of garlic powder was mixed with varying amounts of inorganic germanium and microorganisms, and 110 Kg of organic nutrients and 2000 L of water were mixed in an aeration tank, and then aerated with air for 24 hours.

After the aeration, the mixture was introduced into a fermentation tank and fermented with stirring at 37 ° C. for 24 hours in an oxygen supply environment.

The oxygen supply was stopped and allowed to age for 24 hours at 37 ° C., then filtered through a 1 mm mesh, and the filtered fermentation was received.

< Comparative Example 1  -Functional Fertilizer Manufacturing>

A fertilizer was prepared in the same manner as in Example 1 without mixing garlic powder, inorganic germanium powder and microorganisms.

The composition ratio of the garlic powder, inorganic germanium, and microorganisms of Example 1 and Comparative Example 1 was prepared as a functional fertilizer under the conditions shown in Table 1 below.

Experimental Example 1-Comparison of Germanium Content of Lettuce with and without Functional Fertilizer>

Lettuce seeds were sown in soils with an acidity of pH5.8-6.4.

At 3 days of germination, the fertilizers of Example 1 and Comparative Example 1 were diluted by 20 times and cultivated by irrigation.

After 27 days, sowing was planted at a planting density of 20 cm * 20 cm, and cultivated by fertilization for 23 days.

The cultivated lettuce was harvested and the germanium content of the lettuce was measured and shown in Table 2 below.

As shown in Table 2, it can be seen that the germanium content is increased when the garlic powder is included, and the germanium content is increased when an appropriate amount of microorganisms are mixed together rather than the inorganic germanium alone.

In particular, the high germanium content was measured in Examples 1-6 to 1-8, Examples 1-10 to 1-12, and Examples 1-14 to 1-16.

Herein, the contents of the inorganic germanium can be seen that Examples 1-10 to 1-12 mixed with 15 kg and Examples 1-14 to 1-16 mixed with 20 kg exhibit almost similar germanium contents. Therefore, the inorganic germanium was found to be inadequately improved in the absorption of the ingredient over 15kg compared to 100kg garlic powder.

In addition, in Examples 1-1 to 1-4 in which 5 kg of inorganic germanium was mixed, there was an improvement effect of about 2 times compared to Comparative Example 1-6 in which inorganic germanium was not mixed. From 5 to 1-16 the germanium content of more than 5.20 (mg / L) about three times the improvement was measured.

In addition, as shown in Comparative Examples 1-1 to 1-4, regardless of the amount of inorganic germanium added, it can be seen that the germanium content is lower than 2.50 (mg / L) when microorganisms are not mixed.

In addition, when garlic powder and inorganic germanium were mixed in the same amount, it was confirmed that the germanium content of lettuce increased as the amount of microorganisms increased. However, the lettuce of Examples 1-3, 1-7, 1-11, and 1-15, in which 30 kg of the microorganisms were mixed, and Examples 1-4, 1-8, 1-12, and 1-16 of Examples 1-4, 1-8, 1-12, and 1-16, which mixed the microorganisms in 40 kg. The germanium content was found to show almost similar values.

Therefore, it can be seen that mixing 10 to 15 kg of inorganic germanium and 20 to 30 kg of microorganisms compared to 100 kg of garlic powder allows plants to absorb germanium optimally for cost.

<Example 2- Preparation of functional fertilizer mixed with ocher granules impregnated with garlic liquid>

1) Functional Fertilizer Manufacturing

It manufactured by the manufacturing method of Example 1 with the composition ratio of Example 1-6.

2) ocher pellet manufacturing

The ocher granules were calcined at 200 ° C. for 1 hour to be porous, and passed through a mesh to select and collect those having a diameter of 0.1 to 1.0 mm. The collected ocher granules were immersed in a garlic solution prepared in advance and mixed for 30 minutes or more by a stirrer. The ocher grains were taken out of the garlic solution and placed on a vibrating sieve to be spread in a thin layer. Subsequently, water-soluble gelatin was prepared by mixing and heating collagen and water at 1: 2, and the prepared water-soluble gelatin was sprayed onto a single layer unfolded ocher granules and coated.

3) Manufacture of ocher granulated fertilizer

The ocher granules were mixed with the prepared functional fertilizer, but the fertilizer was prepared by changing the mixing amount as shown in Table 3 below.

Experimental Example 2-pest avoidance experiment

A variety of Seoraetae cultivation groups are formed by dividing the frosted cultivation in a plastic house with a predetermined width, and each cultivation group is prepared with fertilizers prepared at the composition ratios of Examples 2-1 to 2-5 and Comparative Example 2 of Table 3. Diluted 10 times in water, the foliar sprayed to each cultivation group.

200 stink bugs were released in a closed plastic house, and the accessibility of the stink bugs was checked every 6 hours, and the results are shown in Table 4 (access: ○, non-access: ×).

As shown in Table 4, the present invention provides some avoidance even when fertilizer is prepared only by fermentation, and when the ocher grains are mixed, the insect pest avoidance time can be further increased.

That is, as a whole, the repellency was provided for up to 24 hours, and the repellency providing time was increased in Examples 2-1 to 2-5 in which ocher pellets were mixed than in Comparative Example 2, and commercially useful results were obtained in Examples 2-3. Appeared in.

However, the ocher granules did not provide repellency against pests in about 72 hours regardless of the mixing amount, so it was found that the provision of the repelling effect is limited in time. This can increase the relative avoidance time because the prolonged decomposition time of the coating layer formed on the outer surface of the ocher granules can contain the garlic component for a long time.

Experimental Example 3-Plants (Strawberries, Melons, Peppers, Tomatoes, Soybeans) Cultivation>

The functional fertilizer having the composition ratio of Example 2-2 was diluted 20 times with water and fertilized at intervals of 5 to 7 days from the beginning of green leaves to harvesting of strawberries, melons, peppers, tomatoes, and soybeans.

The pests and their quality were visually observed through the growth and harvesting process after fertilization.

Strawberries, melons, peppers, tomatoes all had no damage caused by pests or pathogens such as nematodes, mites, and the like. In addition, its size and quantity were much superior to the conventional ones, and the yield was increased more than 1.4 times.

Figure 3 is a photograph comparing the cut surface of the strawberry (experimental) cultivated under the conditions of Experimental Example 3 and the strawberry (control) cultivated under the same conditions as Experimental Example 3 with a general fertilizer. As mentioned, it was found that the strawberry in the experimental group was formed tighter than the strawberry in the control. In addition, the sugar content of the experimental group was found to appear 2-3 brix (brix) higher than the control.

Figure 4 is a photograph comparing the internal beans by separating the soybeans (control) of soybeans (control) grown in the same conditions as the soybeans (experimental) grown under the conditions of Experimental Example 3. The size of the soybean beans and soybean pods were confirmed to be larger than the control group.

As described above, the organic germanium contained in the garlic, as well as the inorganic germanium, were converted into an easy-to-absorbable form, so that the final germanium content of the plant was increased. This germanium content increased the resistance to pathogens and increased root growth rate to increase the absorption of nutrients to provide the effect of promoting plant growth.

Claims (9)

In the functional fertilizer containing germanium,
Garlic powder containing 600 to 800 ppm of organic germanium containing plants, inorganic germanium, one or two selected microorganisms from photosynthetic bacteria and Bacillus, one or two or more selected organic nutrients from alginic acid, algae, sugar, and water Fermented product which fermented the mixture;
Garlic liquid is impregnated with a diameter of 0.1 ~ 1mm and porous ocher grains coated with a protein on the outer surface; Functional fertilizer characterized in that the mixture. The method of claim 1,
The fermented product is prepared by fermenting a mixture of 10 to 15 parts by weight of inorganic germanium, 20 to 30 parts by weight of microorganisms, 110 to 120 parts by weight of organic nutrients, and 2000 to 2500 parts by weight of water, based on 100 parts by weight of garlic powder. ,
The porous ocher granules, functional fertilizer, characterized in that the composition is mixed by 1 to 2 parts by weight based on 100 parts by weight of fermentation. The method of claim 2,
Functional fertilizer, characterized in that the mixture is further mixed with boron 0.3 ~ 1.0 parts by weight molybdenum 0.003 ~ 0.008 parts by weight based on 100 parts by weight of garlic powder as microbial nutrients. In the manufacturing method of functional fertilizer containing germanium,
A raw material mixing step of mixing garlic powder containing 600 to 800 ppm of plant-containing organic germanium, inorganic germanium, organic nutrients, and water;
Sterilization step by aeration of oxygen in the mixed raw material;
A fermentation step of transferring the sterilized mixed raw materials to the fermentation tank and fermenting by further mixing the microorganisms;
A fermentation step of transferring the fermentation product having undergone the fermentation step to a aging tank to ferment the remaining unfermented product;
A filtration step of filtering the fermented product subjected to the aging step to remove solids of 1 mm or more;
A storage step of storing the filtered liquid fermentation product;
Ocher gran firing step of firing ocher to 150 ~ 250 ℃;
A selection step of selectively receiving the porous ocher grains having a diameter of 0.1 to 1.0 mm;
Selected ocher grains are impregnated with garlic liquid to impregnate the garlic liquid;
Taking out the loess grains impregnated with garlic liquid and mixing the mixture with 1 to 2 parts by weight based on 100 parts by weight of the stored fermented product. In the manufacturing method of functional fertilizer containing germanium,
A raw material mixing step of mixing garlic powder containing 600 to 800 ppm of plant-containing organic germanium, inorganic germanium, organic nutrients, and water;
Sterilization step by aeration of oxygen in the mixed raw material;
A fermentation step of transferring the sterilized mixed raw materials to the fermentation tank and fermenting by further mixing the microorganisms;
A fermentation step of transferring the fermentation product having undergone the fermentation step to a aging tank to ferment the remaining unfermented product;
A filtration step of filtering the fermented product subjected to the aging step to remove solids of 1 mm or more;
A storage step of storing the filtered liquid fermentation product;
Ocher gran firing step of firing ocher to 150 ~ 250 ℃;
A selection step of selectively receiving the porous ocher grains having a diameter of 0.1 to 1.0 mm;
Selected ocher grains are impregnated with garlic liquid to impregnate the garlic liquid;
Dispersing step of taking out the loess grains impregnated with garlic liquid and spread it in a single layer on the vibration screen;
Spraying and coating the liquid gelatin decomposed by mixing collagen and water in a 1: 2 weight ratio to the dispersed loess;
A functional fertilizer manufacturing method characterized in that the coating ocher granules mixing step for mixing the coated ocher granules in 1 to 2 parts by weight based on 100 parts by weight of the stored fermentation. The method according to claim 4 or 5,
In the sterilization step, the aeration tank 20 to 28 hours by aeration with oxygen or air to be sterilized by oxygen,
The fermentation step, the fermentation is made while stirring for 20 to 28 hours at 35 ~ 40 ℃ heating conditions,
The aging step, the functional fertilizer manufacturing method characterized in that the aging is done by leaving for 20 to 28 hours in 35 ~ 40 ℃ heating conditions. The method according to claim 4 or 5,
The raw material mixing step, 10 to 15 parts by weight of inorganic germanium, alginic acid, algae, sugar, one or two or more selected organic nutrients 110 to 120 parts by weight, 2000 to 2500 parts by weight of water ;
In the fermentation step, 20 to 30 parts by weight of one or two selected microorganisms of photosynthetic bacteria and Bacillus bacteria with respect to 100 parts by weight of garlic powder; functional fertilizer manufacturing method characterized in that the mixing.
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