KR101890098B1 - 가공 보조제 및 그를 함유하는 중합체 제제 및 그의 제조 방법 - Google Patents
가공 보조제 및 그를 함유하는 중합체 제제 및 그의 제조 방법 Download PDFInfo
- Publication number
- KR101890098B1 KR101890098B1 KR1020187005926A KR20187005926A KR101890098B1 KR 101890098 B1 KR101890098 B1 KR 101890098B1 KR 1020187005926 A KR1020187005926 A KR 1020187005926A KR 20187005926 A KR20187005926 A KR 20187005926A KR 101890098 B1 KR101890098 B1 KR 101890098B1
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- KR
- South Korea
- Prior art keywords
- polymer
- processing aid
- ethylenically unsaturated
- unsaturated monomer
- meth
- Prior art date
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- 229920000642 polymer Polymers 0.000 title claims abstract description 160
- 239000006057 Non-nutritive feed additive Substances 0.000 title claims abstract description 84
- 239000000203 mixture Substances 0.000 title claims description 50
- 238000009472 formulation Methods 0.000 title claims description 17
- 238000004519 manufacturing process Methods 0.000 title abstract description 7
- 239000000178 monomer Substances 0.000 claims abstract description 88
- 238000006243 chemical reaction Methods 0.000 claims abstract description 57
- 125000000524 functional group Chemical group 0.000 claims abstract description 46
- 238000004945 emulsification Methods 0.000 claims abstract description 17
- 125000004971 nitroalkyl group Chemical group 0.000 claims abstract description 11
- 150000003573 thiols Chemical class 0.000 claims abstract description 9
- OFOBLEOULBTSOW-UHFFFAOYSA-L Malonate Chemical compound [O-]C(=O)CC([O-])=O OFOBLEOULBTSOW-UHFFFAOYSA-L 0.000 claims abstract description 6
- 150000001412 amines Chemical class 0.000 claims abstract description 6
- MLIREBYILWEBDM-UHFFFAOYSA-M 2-cyanoacetate Chemical compound [O-]C(=O)CC#N MLIREBYILWEBDM-UHFFFAOYSA-M 0.000 claims abstract description 5
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 62
- -1 thiol- Triazine Chemical class 0.000 claims description 28
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 claims description 19
- 238000007720 emulsion polymerization reaction Methods 0.000 claims description 18
- 239000004908 Emulsion polymer Substances 0.000 claims description 16
- 238000006116 polymerization reaction Methods 0.000 claims description 12
- 229920001577 copolymer Polymers 0.000 claims description 8
- BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 claims description 7
- 238000010094 polymer processing Methods 0.000 claims description 7
- HRPVXLWXLXDGHG-UHFFFAOYSA-N Acrylamide Chemical compound NC(=O)C=C HRPVXLWXLXDGHG-UHFFFAOYSA-N 0.000 claims description 6
- 229940124530 sulfonamide Drugs 0.000 claims description 6
- 150000003456 sulfonamides Chemical class 0.000 claims description 6
- BQCIDUSAKPWEOX-UHFFFAOYSA-N 1,1-Difluoroethene Chemical compound FC(F)=C BQCIDUSAKPWEOX-UHFFFAOYSA-N 0.000 claims description 5
- OEPOKWHJYJXUGD-UHFFFAOYSA-N 2-(3-phenylmethoxyphenyl)-1,3-thiazole-4-carbaldehyde Chemical compound O=CC1=CSC(C=2C=C(OCC=3C=CC=CC=3)C=CC=2)=N1 OEPOKWHJYJXUGD-UHFFFAOYSA-N 0.000 claims description 5
- XUCNUKMRBVNAPB-UHFFFAOYSA-N fluoroethene Chemical compound FC=C XUCNUKMRBVNAPB-UHFFFAOYSA-N 0.000 claims description 5
- 229920001519 homopolymer Polymers 0.000 claims description 5
- 239000004801 Chlorinated PVC Substances 0.000 claims description 4
- 150000001408 amides Chemical class 0.000 claims description 4
- 229920000457 chlorinated polyvinyl chloride Polymers 0.000 claims description 4
- MLIREBYILWEBDM-UHFFFAOYSA-N cyanoacetic acid Chemical class OC(=O)CC#N MLIREBYILWEBDM-UHFFFAOYSA-N 0.000 claims description 4
- 238000007306 functionalization reaction Methods 0.000 claims description 4
- 150000002690 malonic acid derivatives Chemical class 0.000 claims description 4
- 230000000379 polymerizing effect Effects 0.000 claims description 3
- 239000004094 surface-active agent Substances 0.000 claims description 3
- 239000004709 Chlorinated polyethylene Substances 0.000 claims description 2
- 150000002148 esters Chemical class 0.000 claims description 2
- 238000010556 emulsion polymerization method Methods 0.000 claims 1
- HSVFKFNNMLUVEY-UHFFFAOYSA-N sulfuryl diazide Chemical compound [N-]=[N+]=NS(=O)(=O)N=[N+]=[N-] HSVFKFNNMLUVEY-UHFFFAOYSA-N 0.000 abstract 1
- 239000004800 polyvinyl chloride Substances 0.000 description 34
- 229920000915 polyvinyl chloride Polymers 0.000 description 33
- IBDVWXAVKPRHCU-UHFFFAOYSA-N 2-(2-methylprop-2-enoyloxy)ethyl 3-oxobutanoate Chemical compound CC(=O)CC(=O)OCCOC(=O)C(C)=C IBDVWXAVKPRHCU-UHFFFAOYSA-N 0.000 description 28
- 238000000034 method Methods 0.000 description 25
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 24
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 18
- 239000006260 foam Substances 0.000 description 17
- SOGAXMICEFXMKE-UHFFFAOYSA-N Butylmethacrylate Chemical compound CCCCOC(=O)C(C)=C SOGAXMICEFXMKE-UHFFFAOYSA-N 0.000 description 16
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 description 15
- 229910052757 nitrogen Inorganic materials 0.000 description 13
- 238000002360 preparation method Methods 0.000 description 13
- LCPVQAHEFVXVKT-UHFFFAOYSA-N 2-(2,4-difluorophenoxy)pyridin-3-amine Chemical compound NC1=CC=CN=C1OC1=CC=C(F)C=C1F LCPVQAHEFVXVKT-UHFFFAOYSA-N 0.000 description 12
- XWGJFPHUCFXLBL-UHFFFAOYSA-M rongalite Chemical compound [Na+].OCS([O-])=O XWGJFPHUCFXLBL-UHFFFAOYSA-M 0.000 description 12
- CHQMHPLRPQMAMX-UHFFFAOYSA-L sodium persulfate Substances [Na+].[Na+].[O-]S(=O)(=O)OOS([O-])(=O)=O CHQMHPLRPQMAMX-UHFFFAOYSA-L 0.000 description 12
- 239000000463 material Substances 0.000 description 11
- 239000004604 Blowing Agent Substances 0.000 description 10
- 239000007787 solid Substances 0.000 description 9
- 238000005187 foaming Methods 0.000 description 8
- 238000013459 approach Methods 0.000 description 7
- 239000003109 Disodium ethylene diamine tetraacetate Substances 0.000 description 6
- ZGTMUACCHSMWAC-UHFFFAOYSA-L EDTA disodium salt (anhydrous) Chemical compound [Na+].[Na+].OC(=O)CN(CC([O-])=O)CCN(CC(O)=O)CC([O-])=O ZGTMUACCHSMWAC-UHFFFAOYSA-L 0.000 description 6
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 6
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 6
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 6
- 230000000052 comparative effect Effects 0.000 description 6
- 239000008367 deionised water Substances 0.000 description 6
- 229910021641 deionized water Inorganic materials 0.000 description 6
- 235000019301 disodium ethylene diamine tetraacetate Nutrition 0.000 description 6
- 238000001125 extrusion Methods 0.000 description 6
- 239000004744 fabric Substances 0.000 description 6
- 239000004088 foaming agent Substances 0.000 description 6
- 239000000843 powder Substances 0.000 description 6
- 229910052938 sodium sulfate Inorganic materials 0.000 description 6
- 235000011152 sodium sulphate Nutrition 0.000 description 6
- 239000007921 spray Substances 0.000 description 6
- CIHOLLKRGTVIJN-UHFFFAOYSA-N tert‐butyl hydroperoxide Chemical compound CC(C)(C)OO CIHOLLKRGTVIJN-UHFFFAOYSA-N 0.000 description 6
- 239000000654 additive Substances 0.000 description 5
- 125000004432 carbon atom Chemical group C* 0.000 description 5
- 239000000839 emulsion Substances 0.000 description 5
- 239000007789 gas Substances 0.000 description 5
- 238000001542 size-exclusion chromatography Methods 0.000 description 5
- 239000000126 substance Substances 0.000 description 5
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 4
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 4
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 4
- 125000000217 alkyl group Chemical group 0.000 description 4
- 239000002666 chemical blowing agent Substances 0.000 description 4
- 239000003795 chemical substances by application Substances 0.000 description 4
- 239000003431 cross linking reagent Substances 0.000 description 4
- 238000001035 drying Methods 0.000 description 4
- 238000002156 mixing Methods 0.000 description 4
- 229920003023 plastic Polymers 0.000 description 4
- 239000004033 plastic Substances 0.000 description 4
- 238000012545 processing Methods 0.000 description 4
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 description 3
- 239000004156 Azodicarbonamide Substances 0.000 description 3
- 239000004594 Masterbatch (MB) Substances 0.000 description 3
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical class CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 description 3
- XOZUGNYVDXMRKW-AATRIKPKSA-N azodicarbonamide Chemical compound NC(=O)\N=N\C(N)=O XOZUGNYVDXMRKW-AATRIKPKSA-N 0.000 description 3
- 235000019399 azodicarbonamide Nutrition 0.000 description 3
- 238000001816 cooling Methods 0.000 description 3
- 238000004132 cross linking Methods 0.000 description 3
- 230000009477 glass transition Effects 0.000 description 3
- 239000000314 lubricant Substances 0.000 description 3
- 238000005259 measurement Methods 0.000 description 3
- 238000000926 separation method Methods 0.000 description 3
- 230000002194 synthesizing effect Effects 0.000 description 3
- 238000010998 test method Methods 0.000 description 3
- YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 description 3
- 229920001169 thermoplastic Polymers 0.000 description 3
- 239000004416 thermosoftening plastic Substances 0.000 description 3
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 3
- 229920002554 vinyl polymer Polymers 0.000 description 3
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 2
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 2
- GAWIXWVDTYZWAW-UHFFFAOYSA-N C[CH]O Chemical group C[CH]O GAWIXWVDTYZWAW-UHFFFAOYSA-N 0.000 description 2
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 2
- JIGUQPWFLRLWPJ-UHFFFAOYSA-N Ethyl acrylate Chemical compound CCOC(=O)C=C JIGUQPWFLRLWPJ-UHFFFAOYSA-N 0.000 description 2
- 239000005977 Ethylene Substances 0.000 description 2
- 239000004609 Impact Modifier Substances 0.000 description 2
- GYCMBHHDWRMZGG-UHFFFAOYSA-N Methylacrylonitrile Chemical compound CC(=C)C#N GYCMBHHDWRMZGG-UHFFFAOYSA-N 0.000 description 2
- 239000004698 Polyethylene Substances 0.000 description 2
- 229920005830 Polyurethane Foam Polymers 0.000 description 2
- UIIMBOGNXHQVGW-UHFFFAOYSA-M Sodium bicarbonate Chemical compound [Na+].OC([O-])=O UIIMBOGNXHQVGW-UHFFFAOYSA-M 0.000 description 2
- CQEYYJKEWSMYFG-UHFFFAOYSA-N butyl acrylate Chemical compound CCCCOC(=O)C=C CQEYYJKEWSMYFG-UHFFFAOYSA-N 0.000 description 2
- 229910000019 calcium carbonate Inorganic materials 0.000 description 2
- CJZGTCYPCWQAJB-UHFFFAOYSA-L calcium stearate Chemical compound [Ca+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O CJZGTCYPCWQAJB-UHFFFAOYSA-L 0.000 description 2
- 239000008116 calcium stearate Substances 0.000 description 2
- 235000013539 calcium stearate Nutrition 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 238000000113 differential scanning calorimetry Methods 0.000 description 2
- 239000012530 fluid Substances 0.000 description 2
- 238000013012 foaming technology Methods 0.000 description 2
- 239000012760 heat stabilizer Substances 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 2
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 2
- 239000012948 isocyanate Substances 0.000 description 2
- 150000002513 isocyanates Chemical class 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 239000011159 matrix material Substances 0.000 description 2
- 239000012188 paraffin wax Substances 0.000 description 2
- 239000008188 pellet Substances 0.000 description 2
- PNJWIWWMYCMZRO-UHFFFAOYSA-N pent‐4‐en‐2‐one Natural products CC(=O)CC=C PNJWIWWMYCMZRO-UHFFFAOYSA-N 0.000 description 2
- 229920000098 polyolefin Polymers 0.000 description 2
- 239000011496 polyurethane foam Substances 0.000 description 2
- 239000011347 resin Substances 0.000 description 2
- 229920005989 resin Polymers 0.000 description 2
- 239000000523 sample Substances 0.000 description 2
- 239000012488 sample solution Substances 0.000 description 2
- 239000003381 stabilizer Substances 0.000 description 2
- 150000003440 styrenes Chemical class 0.000 description 2
- 230000008961 swelling Effects 0.000 description 2
- 229920001187 thermosetting polymer Polymers 0.000 description 2
- 239000004408 titanium dioxide Substances 0.000 description 2
- 230000007704 transition Effects 0.000 description 2
- 239000001993 wax Substances 0.000 description 2
- 239000002023 wood Substances 0.000 description 2
- CZGWDPMDAIPURF-UHFFFAOYSA-N (4,6-dihydrazinyl-1,3,5-triazin-2-yl)hydrazine Chemical compound NNC1=NC(NN)=NC(NN)=N1 CZGWDPMDAIPURF-UHFFFAOYSA-N 0.000 description 1
- AHGWAHKJUJDLFS-UHFFFAOYSA-N 16-methylheptadecanoyl 16-methylheptadecanoate Chemical compound CC(C)CCCCCCCCCCCCCCC(=O)OC(=O)CCCCCCCCCCCCCCC(C)C AHGWAHKJUJDLFS-UHFFFAOYSA-N 0.000 description 1
- KJUGUADJHNHALS-UHFFFAOYSA-N 1H-tetrazole Substances C=1N=NNN=1 KJUGUADJHNHALS-UHFFFAOYSA-N 0.000 description 1
- GOXQRTZXKQZDDN-UHFFFAOYSA-N 2-Ethylhexyl acrylate Chemical compound CCCCC(CC)COC(=O)C=C GOXQRTZXKQZDDN-UHFFFAOYSA-N 0.000 description 1
- ISRGONDNXBCDBM-UHFFFAOYSA-N 2-chlorostyrene Chemical compound ClC1=CC=CC=C1C=C ISRGONDNXBCDBM-UHFFFAOYSA-N 0.000 description 1
- BVKZGUZCCUSVTD-UHFFFAOYSA-M Bicarbonate Chemical class OC([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-M 0.000 description 1
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 description 1
- 239000004593 Epoxy Substances 0.000 description 1
- 241000285023 Formosa Species 0.000 description 1
- 238000006845 Michael addition reaction Methods 0.000 description 1
- 229920012485 Plasticized Polyvinyl chloride Polymers 0.000 description 1
- 239000004793 Polystyrene Substances 0.000 description 1
- 239000004614 Process Aid Substances 0.000 description 1
- UIIMBOGNXHQVGW-DEQYMQKBSA-M Sodium bicarbonate-14C Chemical compound [Na+].O[14C]([O-])=O UIIMBOGNXHQVGW-DEQYMQKBSA-M 0.000 description 1
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 238000004458 analytical method Methods 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 150000001540 azides Chemical class 0.000 description 1
- 229920005601 base polymer Polymers 0.000 description 1
- VJRITMATACIYAF-UHFFFAOYSA-N benzenesulfonohydrazide Chemical compound NNS(=O)(=O)C1=CC=CC=C1 VJRITMATACIYAF-UHFFFAOYSA-N 0.000 description 1
- 239000004566 building material Substances 0.000 description 1
- 238000012662 bulk polymerization Methods 0.000 description 1
- 238000011088 calibration curve Methods 0.000 description 1
- DSSYKIVIOFKYAU-UHFFFAOYSA-N camphor Chemical compound C1CC2(C)C(=O)CC1C2(C)C DSSYKIVIOFKYAU-UHFFFAOYSA-N 0.000 description 1
- 150000007942 carboxylates Chemical class 0.000 description 1
- 210000004027 cell Anatomy 0.000 description 1
- 230000010261 cell growth Effects 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 238000007906 compression Methods 0.000 description 1
- 230000006835 compression Effects 0.000 description 1
- 238000009833 condensation Methods 0.000 description 1
- 230000005494 condensation Effects 0.000 description 1
- 239000000498 cooling water Substances 0.000 description 1
- 238000012937 correction Methods 0.000 description 1
- 238000005520 cutting process Methods 0.000 description 1
- OIWOHHBRDFKZNC-UHFFFAOYSA-N cyclohexyl 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OC1CCCCC1 OIWOHHBRDFKZNC-UHFFFAOYSA-N 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 125000005594 diketone group Chemical group 0.000 description 1
- IRFPIPNMASANJY-UHFFFAOYSA-L dimethyltin(2+);2-(6-methylheptoxy)-2-oxoethanethiolate Chemical compound CC(C)CCCCCOC(=O)CS[Sn](C)(C)SCC(=O)OCCCCCC(C)C IRFPIPNMASANJY-UHFFFAOYSA-L 0.000 description 1
- 125000002573 ethenylidene group Chemical group [*]=C=C([H])[H] 0.000 description 1
- 230000001747 exhibiting effect Effects 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 210000000497 foam cell Anatomy 0.000 description 1
- 238000010528 free radical solution polymerization reaction Methods 0.000 description 1
- 229920001002 functional polymer Polymers 0.000 description 1
- 239000007970 homogeneous dispersion Substances 0.000 description 1
- 150000002429 hydrazines Chemical class 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- WARQUFORVQESFF-UHFFFAOYSA-N isocyanatoethene Chemical compound C=CN=C=O WARQUFORVQESFF-UHFFFAOYSA-N 0.000 description 1
- 239000004611 light stabiliser Substances 0.000 description 1
- 238000004811 liquid chromatography Methods 0.000 description 1
- 238000005461 lubrication Methods 0.000 description 1
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 description 1
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 description 1
- 239000000155 melt Substances 0.000 description 1
- 125000001434 methanylylidene group Chemical group [H]C#[*] 0.000 description 1
- 125000000325 methylidene group Chemical group [H]C([H])=* 0.000 description 1
- 238000000643 oven drying Methods 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 150000002978 peroxides Chemical class 0.000 description 1
- 239000004014 plasticizer Substances 0.000 description 1
- 229920002285 poly(styrene-co-acrylonitrile) Polymers 0.000 description 1
- 229920000058 polyacrylate Polymers 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 229920003053 polystyrene-divinylbenzene Polymers 0.000 description 1
- 239000004810 polytetrafluoroethylene Substances 0.000 description 1
- 229920001343 polytetrafluoroethylene Polymers 0.000 description 1
- 229920002635 polyurethane Polymers 0.000 description 1
- 239000004814 polyurethane Substances 0.000 description 1
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 description 1
- 229920005604 random copolymer Polymers 0.000 description 1
- 150000003349 semicarbazides Chemical class 0.000 description 1
- 229910000030 sodium bicarbonate Inorganic materials 0.000 description 1
- 235000017557 sodium bicarbonate Nutrition 0.000 description 1
- 239000012279 sodium borohydride Substances 0.000 description 1
- 229910000033 sodium borohydride Inorganic materials 0.000 description 1
- 239000011343 solid material Substances 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 238000001694 spray drying Methods 0.000 description 1
- 125000005504 styryl group Chemical group 0.000 description 1
- 125000001273 sulfonato group Chemical group [O-]S(*)(=O)=O 0.000 description 1
- 239000000725 suspension Substances 0.000 description 1
- 238000010557 suspension polymerization reaction Methods 0.000 description 1
- SJMYWORNLPSJQO-UHFFFAOYSA-N tert-butyl 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OC(C)(C)C SJMYWORNLPSJQO-UHFFFAOYSA-N 0.000 description 1
- 150000003536 tetrazoles Chemical class 0.000 description 1
- 238000005979 thermal decomposition reaction Methods 0.000 description 1
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 1
- ABDKAPXRBAPSQN-UHFFFAOYSA-N veratrole Chemical compound COC1=CC=CC=C1OC ABDKAPXRBAPSQN-UHFFFAOYSA-N 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L33/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
- C08L33/04—Homopolymers or copolymers of esters
- C08L33/06—Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, which oxygen atoms are present only as part of the carboxyl radical
- C08L33/10—Homopolymers or copolymers of methacrylic acid esters
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F265/00—Macromolecular compounds obtained by polymerising monomers on to polymers of unsaturated monocarboxylic acids or derivatives thereof as defined in group C08F20/00
- C08F265/04—Macromolecular compounds obtained by polymerising monomers on to polymers of unsaturated monocarboxylic acids or derivatives thereof as defined in group C08F20/00 on to polymers of esters
- C08F265/06—Polymerisation of acrylate or methacrylate esters on to polymers thereof
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2/00—Processes of polymerisation
- C08F2/001—Multistage polymerisation processes characterised by a change in reactor conditions without deactivating the intermediate polymer
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2/00—Processes of polymerisation
- C08F2/002—Scale prevention in a polymerisation reactor or its auxiliary parts
- C08F2/005—Scale prevention in a polymerisation reactor or its auxiliary parts by addition of a scale inhibitor to the polymerisation medium
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
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- C08F220/16—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms
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- C08L2205/06—Polymer mixtures characterised by other features having improved processability or containing aids for moulding methods
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- Medicinal Chemistry (AREA)
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- Engineering & Computer Science (AREA)
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| CA3207515A1 (en) | 2014-04-21 | 2015-10-29 | Holcim Technology Ltd | Foam compositions for multi-functional acetoacetates and multi-functional amines |
| US10731018B2 (en) | 2015-08-11 | 2020-08-04 | Arizona Board Of Regents On Behalf Of The University Of Arizona | Antioxidant polydihydropyridazine and polypyridazine foams from 1,2,4,5-tetrazine |
| US10619023B2 (en) | 2015-08-11 | 2020-04-14 | Arizona Board Of Regents On Behalf Of The University Of Arizona | Green chemistry method of synthesizing polymer structures that can function as a built-in antioxidant |
| US10851192B2 (en) | 2015-08-11 | 2020-12-01 | Arizona Board Of Regents On Behalf Of The University Of Arizona | Dihydropyridazine-based antioxidants and uses thereof |
| US11655319B2 (en) | 2015-08-31 | 2023-05-23 | Rohm And Haas Company | Processing aid for foam molding, a vinyl chloride resin-based foam molding composition comprising the same and a foam molded product |
| CN107922545A (zh) | 2015-08-31 | 2018-04-17 | 罗门哈斯公司 | 泡沫成型用加工助剂，包含其的基于氯乙烯树脂的泡沫成型组合物以及泡沫成型产品 |
| US11352475B2 (en) | 2016-06-29 | 2022-06-07 | Arizona Board Of Regents On Behalf Of The University Of Arizona | Method of formation of a robust network of foam through Diels-Alder reaction |
| CN106366234B (zh) * | 2016-08-30 | 2019-12-20 | 山东东临新材料股份有限公司 | 丙烯酸酯共聚物及其制备方法和用途 |
| US10633517B2 (en) | 2017-03-10 | 2020-04-28 | Arizona Board Of Regents On Behalf Of The University Of Arizona | Hydrogenated tetrazine-based antioxidants and free radical reaction inhibitors and uses thereof |
| JP7581764B2 (ja) * | 2019-10-17 | 2024-11-13 | 三菱ケミカル株式会社 | 加工助剤および樹脂組成物 |
| WO2021087041A1 (en) * | 2019-10-30 | 2021-05-06 | Arkema Inc. | Functionalized process aid blends for cellular pvc |
| CN116947640B (zh) * | 2023-09-21 | 2023-12-15 | 深圳市普利凯新材料股份有限公司 | 一种乙酰乙酸基甲基丙烯酸乙酯的提纯方法 |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2006274266A (ja) | 1995-04-12 | 2006-10-12 | Eastman Chem Co | 水性コーティング組成物 |
| JP2007169630A (ja) | 2005-12-13 | 2007-07-05 | Rohm & Haas Co | ポリマー組成物 |
Family Cites Families (21)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE1595679A1 (de) | 1951-01-28 | 1970-08-20 | Bayer Ag | Mit Licht vernetzbare Polymerisate |
| US2646417A (en) | 1951-02-20 | 1953-07-21 | Goodrich Co B F | Rigid thermoplastic compositions comprising vinyl halide polymers with interpolymersof styrene and acrylonitrile |
| US3261785A (en) | 1963-06-25 | 1966-07-19 | Hercules Inc | Modified vinyl chloride polymers |
| US3833686A (en) * | 1969-10-09 | 1974-09-03 | Rohm & Haas | Sequentially produced alkyl acrylate polymers blended with poly(vinyl halides) |
| US3975315A (en) | 1972-02-14 | 1976-08-17 | The B. F. Goodrich Company | Expandable rigid vinyl chloride polymer compositions |
| FR2602776B1 (fr) | 1986-08-12 | 1988-11-10 | Rhone Poulenc Chimie | Diorganopolysiloxane a fonction beta-cetoester utile comme stabilisant des polymeres a base de polychlorure de vinyle |
| DE3879660T2 (de) | 1987-12-26 | 1993-08-12 | Sumitomo Chemical Co | Vinylchloridharzzusammensetzung fuer pulverformverfahren und verfahren zu ihrer herstellung. |
| JP2887478B2 (ja) * | 1988-03-29 | 1999-04-26 | 三菱レイヨン株式会社 | 熱可塑性樹脂用加工助剤及びそれを用いた熱可塑性樹脂組成物 |
| US5206296A (en) | 1989-04-26 | 1993-04-27 | General Electric Company | New processing aid (8-CB-10.483) |
| DE4125477B4 (de) * | 1990-08-10 | 2004-02-12 | Basf Ag | Polyvinylhalogenidharzmasse mit verbessertem Verarbeitungsverhalten, deren Verwendung sowie Verwendung eines Emulsionspolymerisats als Verarbeitungshilfsmittel |
| DE4041186A1 (de) * | 1990-12-21 | 1992-06-25 | Basf Ag | Zweistufiges emulsionscopolymerisat |
| DE69520916T2 (de) * | 1994-08-30 | 2001-11-08 | Agfa-Gevaert N.V., Mortsel | Neuer Kern-Hülle Latex zur Verwendung in photographischen Materialien |
| ES2308849T3 (es) | 1999-01-18 | 2008-12-01 | Kaneka Corporation | Composicion de resina de cloruro de vinilo expansible. |
| EP1153936B1 (en) | 2000-05-12 | 2004-08-04 | Rohm And Haas Company | Plastics additives, improved process, products, and articles containing same |
| EP1310519B1 (en) | 2000-08-08 | 2008-07-02 | Kaneka Corporation | Expandable vinyl chloride resin composition |
| US6670419B2 (en) | 2000-09-14 | 2003-12-30 | Rohm And Haas Company | Method of toughening thermoplastic polymers and thermoplastic compositions produced thereby |
| US6852800B2 (en) | 2001-03-30 | 2005-02-08 | Rohm And Haas Company | Plastic composition |
| US7557158B2 (en) | 2004-09-15 | 2009-07-07 | Rohm And Haas Company | Gloss reducing polymer composition |
| US7795343B2 (en) | 2005-12-13 | 2010-09-14 | Rohm And Haas Company | Polymer composition |
| JP5346192B2 (ja) * | 2007-10-05 | 2013-11-20 | ローム アンド ハース カンパニー | 改善されたポリマー組成物 |
| US9309397B2 (en) | 2007-10-05 | 2016-04-12 | Rohm And Haas Company | Processing aids and polymer formulations containing the same and method for producing the same |
-
2011
- 2011-12-28 IN IN4779CHN2014 patent/IN2014CN04779A/en unknown
- 2011-12-28 EP EP11811281.2A patent/EP2797961B1/en active Active
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- 2011-12-28 WO PCT/US2011/067655 patent/WO2013100997A1/en not_active Ceased
- 2011-12-28 KR KR1020187005926A patent/KR101890098B1/ko active Active
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- 2011-12-28 BR BR112014015830-4A patent/BR112014015830B1/pt not_active IP Right Cessation
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2006274266A (ja) | 1995-04-12 | 2006-10-12 | Eastman Chem Co | 水性コーティング組成物 |
| JP2007169630A (ja) | 2005-12-13 | 2007-07-05 | Rohm & Haas Co | ポリマー組成物 |
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| BR112014015830A2 (pt) | 2017-06-13 |
| KR20180027616A (ko) | 2018-03-14 |
| WO2013100997A1 (en) | 2013-07-04 |
| BR112014015830B1 (pt) | 2020-12-29 |
| KR20140116076A (ko) | 2014-10-01 |
| KR101838344B1 (ko) | 2018-03-13 |
| US20140371396A1 (en) | 2014-12-18 |
| BR112014015830A8 (pt) | 2017-07-04 |
| JP6329908B2 (ja) | 2018-05-23 |
| CN104011082A (zh) | 2014-08-27 |
| CN105968265A (zh) | 2016-09-28 |
| EP2797961B1 (en) | 2017-10-04 |
| IN2014CN04779A (https=) | 2015-09-18 |
| US9908958B2 (en) | 2018-03-06 |
| EP2797961A1 (en) | 2014-11-05 |
| CN105968265B (zh) | 2019-06-21 |
| CN104011082B (zh) | 2016-07-13 |
| JP2015503654A (ja) | 2015-02-02 |
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