CN104011082B - 加工助剂和包含该加工助剂的聚合物制剂以及制备它们的方法 - Google Patents

加工助剂和包含该加工助剂的聚合物制剂以及制备它们的方法 Download PDF

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CN104011082B
CN104011082B CN201180075715.8A CN201180075715A CN104011082B CN 104011082 B CN104011082 B CN 104011082B CN 201180075715 A CN201180075715 A CN 201180075715A CN 104011082 B CN104011082 B CN 104011082B
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polymer
processing aid
pellet
ethylenically unsaturated
methyl
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CN104011082A (zh
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P.范里南
S.布罗德沃特
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Rohm and Haas Co
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    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00—Processes of polymerisation
    • C08F2/001—Multistage polymerisation processes characterised by a change in reactor conditions without deactivating the intermediate polymer
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L33/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
    • C08L33/04—Homopolymers or copolymers of esters
    • C08L33/06—Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, which oxygen atoms are present only as part of the carboxyl radical
    • C08L33/10—Homopolymers or copolymers of methacrylic acid esters
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    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F265/00—Macromolecular compounds obtained by polymerising monomers on to polymers of unsaturated monocarboxylic acids or derivatives thereof as defined in group C08F20/00
    • C08F265/04—Macromolecular compounds obtained by polymerising monomers on to polymers of unsaturated monocarboxylic acids or derivatives thereof as defined in group C08F20/00 on to polymers of esters
    • C08F265/06—Polymerisation of acrylate or methacrylate esters on to polymers thereof
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    • C08F2/00—Processes of polymerisation
    • C08F2/002—Scale prevention in a polymerisation reactor or its auxiliary parts
    • C08F2/005—Scale prevention in a polymerisation reactor or its auxiliary parts by addition of a scale inhibitor to the polymerisation medium
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    • C08F2/00—Processes of polymerisation
    • C08F2/12—Polymerisation in non-solvents
    • C08F2/16—Aqueous medium
    • C08F2/22—Emulsion polymerisation
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    • C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/10—Esters
    • C08F220/26—Esters containing oxygen in addition to the carboxy oxygen
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    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
    • C08J9/0014—Use of organic additives
    • C08J9/0023—Use of organic additives containing oxygen
    • C—CHEMISTRY; METALLURGY
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    • C08L23/26—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers modified by chemical after-treatment
    • C08L23/28—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers modified by chemical after-treatment by reaction with halogens or halogen-containing compounds
    • C08L23/283—Iso-olefin halogenated homopolymers or copolymers
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    • C08L27/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers
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    • C08L27/02—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L27/04—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment containing chlorine atoms
    • C—CHEMISTRY; METALLURGY
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    • C08L27/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers
    • C08L27/02—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L27/04—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment containing chlorine atoms
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    • C08L27/22—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers modified by chemical after-treatment
    • C08L27/24—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers modified by chemical after-treatment halogenated
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    • C08L33/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
    • C08L33/04—Homopolymers or copolymers of esters
    • C08L33/06—Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, which oxygen atoms are present only as part of the carboxyl radical
    • C08L33/10—Homopolymers or copolymers of methacrylic acid esters
    • C08L33/12—Homopolymers or copolymers of methyl methacrylate
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    • C08L51/00—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
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    • C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/10—Esters
    • C08F220/12—Esters of monohydric alcohols or phenols
    • C08F220/16—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms
    • C08F220/18—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms with acrylic or methacrylic acids
    • C08F220/1804—C4-(meth)acrylate, e.g. butyl (meth)acrylate, isobutyl (meth)acrylate or tert-butyl (meth)acrylate
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    • C08L2205/00—Polymer mixtures characterised by other features
    • C08L2205/06—Polymer mixtures characterised by other features having improved processability or containing aids for moulding methods

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
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  • Emergency Medicine (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Polymerisation Methods In General (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
CN201180075715.8A 2011-12-28 2011-12-28 加工助剂和包含该加工助剂的聚合物制剂以及制备它们的方法 Active CN104011082B (zh)

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EP (1) EP2797961B1 (https=)
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KR (2) KR101890098B1 (https=)
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CA3207515A1 (en) 2014-04-21 2015-10-29 Holcim Technology Ltd Foam compositions for multi-functional acetoacetates and multi-functional amines
US10731018B2 (en) 2015-08-11 2020-08-04 Arizona Board Of Regents On Behalf Of The University Of Arizona Antioxidant polydihydropyridazine and polypyridazine foams from 1,2,4,5-tetrazine
US10619023B2 (en) 2015-08-11 2020-04-14 Arizona Board Of Regents On Behalf Of The University Of Arizona Green chemistry method of synthesizing polymer structures that can function as a built-in antioxidant
US10851192B2 (en) 2015-08-11 2020-12-01 Arizona Board Of Regents On Behalf Of The University Of Arizona Dihydropyridazine-based antioxidants and uses thereof
US11655319B2 (en) 2015-08-31 2023-05-23 Rohm And Haas Company Processing aid for foam molding, a vinyl chloride resin-based foam molding composition comprising the same and a foam molded product
CN107922545A (zh) 2015-08-31 2018-04-17 罗门哈斯公司 泡沫成型用加工助剂，包含其的基于氯乙烯树脂的泡沫成型组合物以及泡沫成型产品
US11352475B2 (en) 2016-06-29 2022-06-07 Arizona Board Of Regents On Behalf Of The University Of Arizona Method of formation of a robust network of foam through Diels-Alder reaction
CN106366234B (zh) * 2016-08-30 2019-12-20 山东东临新材料股份有限公司 丙烯酸酯共聚物及其制备方法和用途
US10633517B2 (en) 2017-03-10 2020-04-28 Arizona Board Of Regents On Behalf Of The University Of Arizona Hydrogenated tetrazine-based antioxidants and free radical reaction inhibitors and uses thereof
JP7581764B2 (ja) * 2019-10-17 2024-11-13 三菱ケミカル株式会社 加工助剤および樹脂組成物
WO2021087041A1 (en) * 2019-10-30 2021-05-06 Arkema Inc. Functionalized process aid blends for cellular pvc
CN116947640B (zh) * 2023-09-21 2023-12-15 深圳市普利凯新材料股份有限公司 一种乙酰乙酸基甲基丙烯酸乙酯的提纯方法

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CN101402771A (zh) * 2007-10-05 2009-04-08 罗门哈斯公司 改进的聚合物组合物

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BR112014015830A2 (pt) 2017-06-13
KR20180027616A (ko) 2018-03-14
WO2013100997A1 (en) 2013-07-04
BR112014015830B1 (pt) 2020-12-29
KR20140116076A (ko) 2014-10-01
KR101838344B1 (ko) 2018-03-13
US20140371396A1 (en) 2014-12-18
BR112014015830A8 (pt) 2017-07-04
JP6329908B2 (ja) 2018-05-23
CN104011082A (zh) 2014-08-27
CN105968265A (zh) 2016-09-28
EP2797961B1 (en) 2017-10-04
IN2014CN04779A (https=) 2015-09-18
US9908958B2 (en) 2018-03-06
EP2797961A1 (en) 2014-11-05
KR101890098B1 (ko) 2018-08-20
CN105968265B (zh) 2019-06-21
JP2015503654A (ja) 2015-02-02

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