KR101880056B1 - Cosmetic composition containing Chojeong carbonated water for hair damage prevention - Google Patents

Abstract

The present invention relates to a cosmetic composition for preventing damage to hair, and more particularly, to a cosmetic composition for preventing hair damage, which is characterized in that it uses accelerated carbonic acid water containing abundant carbonic acid and mineral components to promote blood circulation and metabolism activity of the scalp, The effect of natural complex extracts including finger root, hoster tail kelp, and golden silkworm extract prevents the damage of hair caused by chemical agents such as hair dye and phthalate, or stress, and hair that contains precious carbonated water that restores damaged hair To a cosmetic composition for preventing damage.

Description

Technical Field [0001] The present invention relates to a cosmetic composition containing carbonated water,

The present invention relates to a cosmetic composition for preventing hair damage, and more particularly, to a cosmetic composition for preventing hair damage containing superhydrophilic water containing abundant carbonic acid and mineral components.

Hair is mostly composed of protein and gelatin. In addition to the natural phenomenon due to aging, damage or hair loss of hair is increasing rapidly due to inherited factors such as genetic factors, harmful environment and various stresses, regardless of age or sex.

In recent years, hair damage due to frequent use of chemical agents such as hair dye and phthalate for cosmetics is serious, and damage to hair caused by stress, nutrient deficiency and other environmental effects is also increasing rapidly. And the scalp becomes thinner, making the hair follicle and hair thin.

As a result, the hair care market has been rapidly growing along with the prevention of hair damage in advance and the recovery of damaged hair.

Hair loss is no longer the exclusive treatment of middle-aged men, especially as a result of increased hair loss among women and young people, and it is regarded as a serious phenomenon in society as a whole.

Also, demand for hair and scalp care is expected to increase steadily, due to the increase in appearance-oriented tendency and interest in hair care for men.

Accordingly, various cosmetic compositions and quasi-drugs for the prevention of hair damage have been developed. However, most of them are caused by chemical products rather than causing troubles on the scalp. Recently, hair care products including herbal ingredients have been developed, There was a problem.

In this connection, Patent Document 1 discloses a non-aqueous personal care product for skin or hair which does not contain water and which contains a water-insoluble support and a non-flowable support and has a functional group capable of covalent bonding with a protein residue. .

However, it uses chemical deliveries, and as mentioned above, it is not enough to block the troubles that occur in hair and skin, and has a feature of not containing water.

On the other hand, if you immerse yourself in a carbonated hot spring, your skin becomes soft and you feel refreshed from your body. This means that carbonic acid bubbles generated from a carbonated hot spring move finely on the skin to easily exhaust waste accumulated in the pores, Is absorbed into the body, the capillary blood vessels are expanded and the amount of blood is increased, so that the oxygen delivery is accelerated.

Patent Document 2 discloses a composition for treating and ameliorating atopic dermatitis, which comprises primary mineral water, rhusi extract, and green mud as an active ingredient, as an example using such a carbonated hot spring effect, And it is not expected to have an effect of preventing hair from being damaged.

That is, in the conventional patent documents, it is difficult to expect to increase the resilience of damaged scalp and hair by promoting blood circulation and metabolic activity of the scalp, to prevent hair damage and to restore damaged hair.

Patent Document 1: Korean Patent No. 867,064 (Registered on October 29, 2008) Patent Document 2: Korean Patent Laid-Open Publication No. 2016-0001112 (Publication Date: January 6, 2016)

Disclosure of Invention Technical Problem [8] Accordingly, the present invention has been made keeping in mind the above problems occurring in the prior art, and it is an object of the present invention to provide a method and apparatus for promoting blood circulation and metabolism of scalp by using carbonated water containing abundant carbonic acid and minerals, The combined effect of natural complex extracts including finger root, hoster tail kelp and golden silkworm extract, while increasing resilience, can prevent hair damage due to chemical agents or stress, and restore damaged hair And to provide a cosmetic composition for preventing damage to hair containing primary carbonated water.

The cosmetic composition for prevention of hair damage containing superhydrophilic water according to the present invention is characterized by comprising superhydrophobic water, purified water and a natural complex extract.

In addition, the natural combination extract is characterized in that 0.1 to 3 parts by weight of each of Finger root extract, Horsetail kelp extract or Golden cocoon extract is mixed.

10 to 50 parts by weight of purified carbonated water, 32 to 42 parts by weight of purified water, 0.1 to 10 parts by weight of a natural complex extract and 0.6 parts by weight of a perfume, 3.0 parts by weight of a surfactant, 6.5 parts by weight of an increasing agent, And 10 parts by weight of the natural complex extract, wherein 0.1 to 3 parts by weight of the Finger root extract, the hoster tail kelp extract and the golden cocoon extract are mixed, respectively.

The cosmetic composition according to the present invention alleviates the side effects of chemical agents that cause hair damage because of the use of natural materials such as superhydrophilic water and natural compound extract. In particular, the cosmetic composition according to the present invention reduces hair damage through alkaline hair dyeing, And can be neutralized through pH. In addition, it is possible to prevent the damage of the hair by supplying the nutrient layer through the natural complex extract to provide nutrition, and to restore the damaged hair without side effects.

Hereinafter, specific embodiments of the present invention will be described in detail.

The cosmetic composition for preventing damage to hair containing superhydrophilic water according to an embodiment of the present invention is characterized by further comprising a natural complex extract in raw water mixed with purified water of carbonated water and purified water.

The carbonated starch water was obtained from the National Institute of Geology and Mineral Resources in 1969 and was officially approved by the US Food and Drug Administration (FDA) in 1980, I was approved.

The concentration of free carbon dioxide contained in the dissolved carbon dioxide is 1,200 ppm, and germanium is 8 to 22 ppm, which is 1,000 times that of commercial water, and 20 kinds of various minerals are abundantly contained. It has excellent efficacy in prevention and treatment, especially in mineral balance.

On the other hand, protein, calcium, and iodine are typical examples of hair nutrients. When the protein intake is insufficient, the body converts the hair in the growth period to the resting state in order to stock protein, causing hair damage, And minerals such as calcium and magnesium do not directly constitute the hair as a protein but are essential for life maintenance and play a very important role in metabolism. If minerals are lacking, nutrition It does not work properly, it also affects the environment of the scalp, and the hair becomes thinner and weaker, causing damage.

Therefore, the carbonated starch water used in the embodiment of the present invention is characterized by containing 500 to 700 ppm of calcium carbonate (CaCO ₃ ) and 20 to 300 ppm of calcium (Ca) and 2 to 50 ppm of magnesium as main minerals (Ge), manganese (Mn), selenium (Se), or the like.

The calcium carbonate reacts with water to generate carbonic acid gas so that the carbonic acid bubbles move finely on the scalp to easily exhaust waste accumulated in the pores of the scalp while the carbonic acid gas is absorbed into the body to expand the capillary blood vessels of the scalp, And oxygen transfer is accelerated to prevent damage to hair and restore damaged hair.

In addition, the calcium promotes metabolism, activates skin cells, contributes to maintenance of skin health, activates moisturizing factors of skin, magnesium plays a key role in cell metabolism, , And activates the moisturizing factor.

In addition, the selenium helps improve immunity, contributes to skin cell activation, antioxidative action, and skin disease improvement, and germanium excretes harmful substances into the body and promotes metabolism, thereby greatly affecting genes and life phenomena It is known that the release of oxygen contained in organic germanium causes a large amount of oxygen to be supplied to the blood vessels, so that the capillaries expand and the blood flow of the scalp is improved and the cells are revitalized to activate the intracellular reaction.

That is, by using the protein, which is a component for maintaining the health of hair, and the supernatant carbonated water containing an appropriate amount of minerals to help synthesize the protein, it is possible to prevent hair from being damaged due to tapering and weakening of hair.

As described above, after a sufficient amount of calcium carbonate and minerals are contained, the selected carbonated water is filtered according to an AOAC (Association of Official Agricultural Chemists) analysis method, and a filtered millipore filter (0.45um ) To remove foreign matters, and purified water is mixed with the filtered carbonated water to prepare a raw water.

At this time, it is preferable that the filtered carbonated water and the purified water are mixed at a ratio of 10: 50: 32 ~ 42.

Meanwhile, the cosmetic composition for preventing damage to hair containing the carbonated starch water according to the present invention comprises the natural complex extract in addition to the carbonated starch water. Hereinafter, the characteristics and manufacturing process of the natural complex extract will be described.

The natural combination extract includes a finger root extract, a laminaria digitata extract, and a golden cocoon extract.

First, the finger root is a native plant native to Indonesia and the like, and is a natural plant which simultaneously contains a body fat reduction and a skin health effect.

Particularly, panduratin, which is a component of finger root, activates AMPK (AMP activated kinase) enzyme and inhibits body fat decomposition and lipogenesis, and thus is used for treating obesity. However, by increasing collagen production and increasing muscle mass , Skin elasticity and wrinkle-improving effect.

The process of extracting panduratin from the finger root can be carried out by directly grinding the plant or extracting the panduratin ingredient from the pulverized product through centrifugation or the like as in the conventional method of Indonesia.

Next, the hortail kelp extract is extracted from marine algae such as seaweed, kelp, and contains minerals and trace elements, which contain a fucoidan component with strong physiological activity.

The fucoidan is a high molecular polysaccharide composed mainly of sugar called a saccharide after being sulfated. It contains galactose, sulfate and the like to form a skin moisturizing film, inhibits blood flow regulating action and formation of active oxygen, It has been known to have a wide range of functions.

It is advantageous that the molecular size of the fucoidan is easily absorbed in the small intestine of the human body through the process of decomposing 200,000 to 300,000 Da (daltons, atomic mass unit) in a natural state to 50,000 Da or less.

Accordingly, the Fucoidans extract can be prepared to be contained in the cosmetic composition according to the present invention by pulverizing the raw material, subjecting it to hot water extraction and precipitation separation in an acidic condition (pH 2 to 3), followed by neutralization and filtration and centrifugation have.

In addition, the above-mentioned golden silkworm extracts sericin and fibroin are included.

Hereinafter, a process for preparing a cosmetic composition for preventing hair damage, which comprises extracting sericin and fibroin from the cocoons of golden silkworms according to the present invention will be described in detail.

The sericin and fibroin are proteins constituting silkworm cocoon fibers, and two fibroins are covered with three layers of sericin.

The sericin and fibroin have a large amount of serine having hair and skin moisturizing effect. The serine is similar to a natural moisturizing factor (NMF) of the human body, and thus has excellent hair and skin moisturizing effect. And the like.

A typical example of the sericin refining method is a hot water extraction method, which uses only distilled water and is treated at a high temperature of 80 to 120 ° C. Since pure water is used purely, additional processes such as a soap refining method and the like are required There is an advantage not.

Accordingly, in the embodiment of the present invention, the hot water extraction method was used as a refining method of sericin.

Generally, sericin is hydrophilic and easily dissolved in water. Sericin, which surrounds actual fibroin, has a layered structure that is less soluble in water as it goes from the outer layer to the inner layer.

Therefore, at a low temperature of 50 to 60 ° C, only a part of the sericin in the outer layer is dissolved in water and sericin in the inner layer is not dissolved. Therefore, the bath ratio and liquor ratio of the raw and distilled water are adjusted to 1:15 to 25, It is preferable to refine at a high temperature of 100 to 120 캜 for 1 to 3 hours.

The process of recovering sericin by the hot water extraction method can be generally summarized as a process of powdering sericin.

On the other hand, sericin is a hydrophilic protein, but sericin prepared by hydrothermal extraction is still a polymer material, and after being powdered, its solubility in water is lowered, so a process of low molecularization through hydrolysis is required.

Therefore, in the embodiment of the present invention, the recovery process of sericin is performed through a hydrolysis step and a pulverization step of sericin.

There is a method of hydrolyzing sericin under acidic or basic conditions by hydrolysis method, but further processing of neutralization desalting is necessary, and hydrolysis of sericin is indiscriminately hydrolyzed, resulting in poor reproducibility of performance.

Accordingly, in the examples of the present invention, a low molecular weight method using an enzyme was used.

When enzymes are used, a specific reaction occurs and sericin molecules having a constant molecular weight can be reproducibly produced, and it can be regarded as a safer process since no harmful substances such as hydrochloric acid (HCl) or sodium hydroxide (NaOH) are used.

Specifically, in the embodiment of the present invention, the hydrolysis is performed by using an alcalase enzyme, a flavorzyme enzyme, and a protamex enzyme in the wastewater obtained in the above-described refining process, that is, in the aqueous solution of sericin Respectively.

The enzyme added to the sericin aqueous solution was hydrolyzed at 37 ° C for 6 hours by adding 10 μl of the alkaline enzyme, 80 mg of the flavosome enzyme, and 10 mg of the protease per 1 g of sericin.

The molecular weight of sericin extracted with hot water was about 66 kDa (kilo-daltons). On the other hand, when hydrolyzed with an alkaline enzyme, the majority of sericin hydrolyzate , And the peaks of 34 kDa and 27 kDa were particularly strong.

Hydrolysis with Flavobaim enzyme showed a broad molecular weight distribution and peak at 11 kDa. Hydrolysis with protease enzymes showed molecular weights of 13-66 kDa, but 41, 37 and 33 kDa Of the sericin molecule.

Therefore, it is preferable to hydrolyze the sericin aqueous solution by adding one or two kinds of enzymes such as alkaline protease, flavosome enzyme, or protamase enzyme. When two kinds of enzymes are used, a single addition amount of each enzyme It is preferable to mix the two enzymes using 1/2.

Examples of the method for pulverizing sericin from the sericin aqueous solution include a freeze-drying method, a spray drying method, and a freeze-thawing method.

Among them, the frozen defrosting method is a method of defrosting after a certain period of freezing process in a freezer room below -4 ° C, in which sericin protein induces large association behavior in the course of freeze thawing, and thus precipitated sericin can be easily pulverized This is the preferred method.

Therefore, in the embodiment of the present invention, a sericin aqueous solution hydrolyzed by the enzyme is concentrated through a separation process using a tubular ultrafiltration membrane having a cutoff molecular weight of 4,000, and then the concentrated sericin solution is diluted in a freezer After freezing for a time, the saccharin powder was obtained by thawing.

On the other hand, in the embodiment of the present invention, the production of fibroin powder includes a first step of dissolving the refined fibroin fiber in water at high temperature, a step of decomposing the dissolved fibroin solution into an alkaline protease, And a second step of concentrating and drying the decomposed aqueous solution.

To examine the solubility of fibroin in water at high temperature, fibroin was dissolved in water at a temperature of 170 DEG C, 180 DEG C, 190 DEG C, and 200 DEG C at 4% (water 1L: fibroin 40g, bath ratio 1: 25) The solubility was measured after dissolving for 5 or 7 hours. The results are shown in Table 1 below.

The solubility of fibroin in water Temperature time Solubility
170 ℃
3h 10% 5h 43% 7h 60%
180 DEG C
3h 85% 5h 90% 7h 95%
190 ℃
3h 97% 5h 98% 7h 100%
200 ℃
3h 100% 5h 100% 7h 100%

As shown in Table 1, when fibroin was treated at 170 ° C for 3 hours, the solubility was low at 10%. Also, when the fibroin was treated for 5 hours or 7 hours, the solubility was about 43% and 60% The solubility did not increase significantly even after prolonged treatment, which is considered to be inefficient.

On the other hand, at 180 ° C, it was 90% or more when treated for 5 hours or more, 97% or more when treated at 190 ° C for 3 hours or more, and 100% at 200 ° C for 3 hours.

In order to examine the degree of low molecular weight of the fibroin powder prepared according to the embodiment of the present invention, the molecular weight was measured, and the measured molecular weight was as shown in Table 2 below.

Molecular weight measurement results to examine the degree of low molecular weight of fibroin powder Temperature time Average molecular weight Example Comparative Example 170 ℃ 7h 10.9 kDa 13.1 kDa
180 DEG C
3h 9.0kDa 11.4 kDa 5h 7.9 kDa 8.3 kDa 7h 6.9 kDa 8.3 kDa
190 ℃
3h 6.1 kDa 7.8 kDa 5h 5.7 kDa 7.4 kDa 7h 5.3 kDa 6.7 kDa 200 ℃ 3h 5.0 kDa 6.1 kDa 5h 4.7 kDa 5.6 kDa

However, in order to verify the effect of the protease, alcalase, fibroin powder concentrated and dried only through the first step was used as a comparative example. Fibroin powder, which was concentrated and dried through the first and second steps, Powder was used as an example.

The above molecular weight is shown as mean molecular weight instead of molecular weight distribution because it is intended to examine the degree of low molecular weight of the fibroin powder produced.

When the molecular weight of ordinary fibroin is 300 to 600 kDa, it can be seen that the degree of low molecular weight is large even at 170 DEG C, as shown in Table 2 above.

Also, it can be seen that the higher the temperature as a whole, the lower the molecular weight the longer the treatment time is.

In addition, as shown in the above Comparative Example, it can be seen that even when the fibroin powder is produced through concentration and drying only through the first step, the degree of low molecular weight is large. However, in order to lower the molecular weight, , It can be seen that fibroin powder of lower molecular weight can be prepared by secondary decomposition of the fibroin aqueous solution using proteolytic enzyme.

Therefore, the fibroin powder according to the embodiment of the present invention can be obtained by dissolving a solution of 40 g of fibroin fibers refined in 1 L of water at 170 to 200 ° C for 3 to 7 hours, dissolving the dissolved fibroin solution in a solution of proteolytic enzyme It is preferable to decompose phosphoric acid and concentrate and dry it.

Considering the solubility and low molecular weight of water, a solution obtained by mixing 40 g of refined fibroin with 1 L of water was dissolved at 180 ° C to 200 ° C for 3 hours, and the dissolved fibroin solution was added to the proteinase It is more preferable to decompose and concentrate the colorase and dry it.

Next, a method for producing a cosmetic for preventing hair damage containing super-soft carbonated water according to the present invention will be described.

First, 10 to 50 parts by weight (preferably 20 to 30 parts by weight) of super basic carbonated water and 32 to 42 parts by weight of purified water are mixed to prepare raw water, 0.1 to 3 parts by weight of finger root extract and 0.1 , 3 parts by weight of a horsetail kelp extract and 0.1 to 3 parts by weight of a golden silkworm extract, 0.6 parts by weight of a perfume, 3.0 parts by weight of a surfactant, 6.5 parts by weight of an aging agent, 10 parts by weight of a softening agent, 10 By weight of a hair conditioning agent.

Examples of the surfactant include cetrimonium chloride, cetearyl alcohol, isopropyl myristate, and Xiameter PMX of Dow Corning Inc. as the hair conditioning agent, -1411 can be preferably used.

Accordingly, the cosmetic composition for prevention of hair damage containing superhydrophilic water according to the present invention can improve the blood circulation of the scalp due to the combined effects of the rich carbonic acid and minerals contained in the superhydrophobic water and the natural complex extract, It promotes metabolic activity, which increases the resilience of the damaged scalp and hair, thereby preventing damage to the hair and providing a resilience to damaged hair.

Claims (3)

1. A cosmetic composition for preventing damage to hair comprising superhydrophilic water, purified water and a natural combination extract,
10 to 50 parts by weight of purified carbonated water, 32 to 42 parts by weight of purified water, 0.3 to 9 parts by weight of a natural complex extract and 0.6 parts by weight of a perfume, 3.0 parts by weight of a surfactant, 6.5 parts by weight of a thickening agent, 10 parts by weight of a hair conditioning agent 10 parts by weight,
The carbonated starch water is carbonated water containing 500 to 700 ppm of calcium carbonate (CaCO ₃ ), 20 to 300 ppm of calcium (Ca) and 2 to 50 ppm of magnesium (Mg)
Wherein the natural combination extract comprises 0.1 to 3 parts by weight of a finger root extract containing at least a panduratin ingredient and 0.1 to 3 parts by weight of a hos tail kelp extract containing a fucoidan ingredient of at most 50,000 Da, 0.1 to 3 parts by weight of each of the golden silkworm extracts containing sericin and fibroin,
The sericin is obtained by hydrolysis of the above silkworm by the use of distilled water and distilled water at a temperature of 100 to 120 ° C and then hydrolyzing the saccharin aqueous solution with 10 μl of an alkaline enzyme per 1 g of the sericin, Obtained by separating one sericin aqueous solution using a tubular ultrafiltration membrane having a cut-off molecular weight of 4,000,
The fibroin was prepared by dissolving a solution of fibroin fibers from which the sericin was removed from the golden silkworm cocoa at a ratio of 40 g to 1 L of water at 180 ° C to 200 ° C for 3 hours and then adding the dissolved fibroin solution to the proteinase A cosmetic composition for preventing damage to hair, the composition being obtained by decomposition with azelaic acid. delete delete