KR101840943B1 - The compositions for hydrogen emitting - Google Patents

Abstract

The present invention relates to a method for producing a magnesium hydride powder and a magnesium hydride powder, which comprises dry-blending a carrier and / or hydrogen gas carrier of a magnesium hydride powder having a specific gravity slightly higher than water and having a high viscosity and excellent moisturizing property, And the mixture is wet-mixed with the added anhydrous edible fats and oils.
The hydrogen generator composition of the present invention is filled in a tube or a drip bottle or the like, is diluted with water, a beverage product, or an alcohol to carry out hydrogenation with a reducing action and an antioxidant property in water, a drink product or alcohol, Which is dissolved in water or hydrogenated beverage product or hydrogen alcohol, and can be used as an ointment or cream, and when water is applied to the skin even when it is applied to the skin, It is possible to generate hydrogen having antioxidant property and supply it to the skin for a long time.

Description

The composition for hydrogen emitting < RTI ID = 0.0 >

The present invention relates to not only hydrogen having a reducing action and an antioxidative effect on water, a beverage product or an alcohol (alcohol), such as water, a beverage product or an alcohol, It can be made by beverage products, hydrogen alcohol (alcohol), etc., and when used for external ointment / cream on the skin, it can supply hydrogen for a long time by using moisturizing component ≪ / RTI >

The atomic hydrogen (H) and the molecular hydrogen (H ₂ ) (hereinafter referred to as hydrogen in the form of atomic hydrogen and molecular hydrogen and hydrogen gas) are converted into antioxidants such as vitamin C, E and polyphenols Hydrogen is dissolved in hydrogen cosmetics and hydrogen beverage products are being developed. In the medical field, researches are being conducted to prevent and prevent aging as well as to treat and research various diseases.

As a prior art in relation to the present invention, Patent Document 1 discloses a method of reducing the oxidation-reduction potential (ORP) of skin care products such as shampoo rinses and the like in which hydrogen is dissolved, bath water, shower water, (Aging) of the skin due to removal of active oxygen involved in skin aging and damage is disclosed in Patent Document 2. In Patent Document 2, a metal occluding hydrogen is used as an external ointment, (Patent Document 3) discloses that whitening action, prevention of skin aging due to antioxidative action, antiallergic action and anti-inflammatory action (wound healing effect such as wound, burn, etc.) Describes that skin aging is prevented and blood flow is promoted even when dissolved water is used.

On the other hand, as a prior art for obtaining water in which hydrogen is dissolved, that is, hydrogenated water,

(2) an electrolysis method in which water is electrolyzed and water on the cathode side (also referred to as reduced water) is used; (3) a reduced water obtained by reacting metal magnesium or the like with water; (See, for example, Patent Document 4) and 4) a hydrogen occlusion metal utilization method (see, for example, Patent Document 5) obtained by reacting a metal occluding hydrogen, such as a hydrogenated alkaline earth metal, with water .

However, among these methods, in the case of hydrogenated hydrogenated water, the hydrogen itself is so light and small among the existing substances that it is easy to diffuse, so that the amount that can be dissolved in water is very limited. There is a problem in that the product cost is high because it is required to store in an expensive aluminum bottle or the like because it can not be stored in a cheap plastic bottle for a long time. In the case of electrolyzed water, it is necessary to periodically clean the electrodes with the economic burden of purchasing expensive equipment for electrolyzing the water, and the produced hydrogen may be highly alkaline water having a pH of 10 or more Reduced water) because it is manufactured to put a lot of burden on the stomach. In the case of the reducing water adjusting method using metal magnesium, since the metal magnesium reacts with water as well as water, a coating layer of magnesium hydroxide or magnesium oxide is formed on the surface of the magnesium magnesium so that the coating layer thus formed is removed before producing water The hydrogen concentration can not be obtained because the hydrogen concentration is low due to the surface area of the charged metal magnesium even if the hydrogen is produced. Patent Literature 2, for example, discloses a method for producing hydrogenated water by using a hydrogen occlusion metal. In Patent Document 2, very fine hydrogenated magnesium fine particles having an average particle diameter of 2 탆 or less Specific gravity: about 1.7) as glycerol (specific gravity: 1.26). However, since there is a specific gravity difference between magnesium hydride and glycerol, the magnesium hydride powder is precipitated, so that the amount of powder of magnesium hydride which is dropped on a water bottle or the like to produce hydrogen water can not be quantified, The following magnesium hydroxide fine particles maximize the surface area capable of reacting with water, but the reaction time with water is short, so that even if the water is produced, there is a problem in that it is not possible to drink the water by reheating or stirring.

Japanese Patent Application Laid-Open No. 2000-119161 Korean Patent Publication No. 10-2014-0012981 Japanese Patent Laid-Open No. 2000-308891 Japan Patent Office 2004-041949 Japanese Patent No. 4384227

Uesugi, Sugiyama, Nakatsugawa, Ito: Light metal 60th volume of Japan No. 11 (2010), 615 ~ 618.

Therefore, the present invention is intended to solve the above-described problems in the prior art, particularly in Patent Document 2.

Specifically, in a place where water, a beverage product, or an alcohol (alcohol) is present, it is simply diluted with them to generate a hydrogen having a reducing action and an antioxidative action on the spot, (Alcohol), and the like, and it is an object of the present invention to provide a composition for a hydrogen generator which can supply hydrogen constantly without water supply even when it is used for skin as an external ointment, the hydrogen having a reducing action and an antioxidative action on the skin. In achieving such a hydrogen generator composition,

First, in the production of hydrogen peroxide, hydrogenated beverage products, hydrogen alcohol, etc. using the hydrogen generator composition of the present invention, the dissolved hydrogen concentration obtained from these must always be uniformly maintained,

Secondly, in producing hydrogen peroxide by using the hydrogen generator composition of the present invention and drinking it, it is necessary to be able to produce hydrogen peroxide more than re-

Third, even when the hydrogen generator composition of the present invention is used as an external oily hydrogen ointment or the like, the hydrogen generation time can be sustained for a long time by using the excellent moisturizing effect possessed by the composition even without moisture, , And so on.

In order to solve the above problems, the hydrogen generating composition of the present invention is prepared by introducing a magnesium hydride (MgH ₂ ) powder in order to maximize the amount of dissolved hydrogen generated as described later. In order to increase the dispersibility of the magnesium hydride powder, , The dietary fiber of gluconic potato powder derived from konjac potato having excellent moisturizing effect was introduced in order to contribute to increase the dissolved hydrogen concentration by encapsulating the hydrogen gas and to maintain the sustainability of hydrogen generation even without temporarily supplying water.

The magnesium hydride powder and the glucomannan powder were first dry mixed to increase the supporting ratio of the magnesium hydride powder to be supported on the glucomannan powder and then wet mixed with anhydrous glycerin or anhydrous edible oil added with anhydrous glycerin or a food additive emulsifier, Lt; / RTI >

Although the hydrogen generator composition according to the present invention is based on these components, they are only minimum constituents, and other necessary nutrients, functional ingredients and food additives can be added as needed. I will also reveal it.

On the other hand, magnesium hydride used in the present invention is relatively stable in air, unlike metal magnesium, and is very easy to handle. For example, those produced by a method known in the art such as non-patent documents can be used. The mean particle diameter of the magnesium hydride powder is preferably 3 μm or more, preferably 10 μm or more and 100 μm or less, as compared with the case of using fine microparticles of 2 μm or less as shown in Patent Document 2.

The reason for introducing the crude magnesium hydride powder in the present invention is that,

First, it is easy to classify the magnesium hydride powder,

Secondly, when reacting with water, the time of hydrogen generation can be as short as several tens of minutes to several days, for example, even if the hydrogen produced at home is consumed when it is going out, It is possible to drink hydrogenated water by reheating or sanktang by supplementing it, and when it is used as a hydrogen ointment for skin, etc., it is possible to enjoy the hydrogen penetration effect for a long time even for a long time.

In the hydrogen generator composition of the present invention, there is a difference in specific gravity between the crude magnesium hydride powder and the glycerin used as the suspending agent and the anhydrous edible oil to which the food additive emulsifier is added. Since the hydrated magnesium powder having a large specific gravity is precipitated as the constitution of only two of them, the dissolved hydrogen concentration will appear different every time when producing hydrogen water, a hydrogenated drink product, hydrogen alcohol, or the like. According to the present invention, a carrier capable of supporting coarse hydrated magnesium powder is constituted in order to compensate for this. Even if the magnesium hydride powder is coarse, even if it is carried by the carrier, uniform suspension is possible, and the amount of the magnesium hydride to be dropped into water, a beverage or alcohol contained in a certain container can be kept constant, (Hydrogen), a hydrogenated beverage product, hydrogen alcohol (alcohol), or the like with a constant hydrogen concentration.

In addition, in addition to supporting the coarse hydrated magnesium powder, the carrier that supports the magnesium hydride powder in the present invention maintains the viscosity of the composition and also reacts with water together with the magnesium hydride powder to collect hydrogen generated thereby to increase the concentration of dissolved hydrogen In addition, even when the hydrogen generator composition of the present invention is used as a hydrogen ointment for skin application, it is assumed that the supply of water is stopped and a sufficient moisturizing effect is required to be exerted considering the continuous supply of hydrogen generation.

In the present invention, water-soluble dietary fiber of glucomannan extracted from konjac potato as a carrier of coarse hydrated magnesium powder was judged to be optimal and used.

Examples of the water-soluble dietary fiber having properties similar to those of glucomannan include pectin, indigestible dextrin, inulin, alginic acid and its salts, and the like. However, they were less viscous or less specific than glucomannan and could not meet the requirements described by themselves. However, when used in combination with glucomannan, some resolution was possible. Therefore, the present invention does not completely exclude them.

As a suspending agent in the present invention, anhydrous copper / vegetable oils and fats and oils are added, together with an anhydrous glycerin and a known emulsifying agent for food (Examples are omitted). It is very difficult to dilute the copper / vegetable oils with no added emulsifier in water, beverage products and alcohol. The conventional technology of Patent Document 2 also refers to edible oils and fats, but this is only possible when it is premised on the use as a skin external ointment. In the technique of Patent Document 2 in which a non-emulsifier-free oil is used, since an oil film is formed between magnesium hydride and water (water), hydrogen selenide, hydrogenated beverage product, hydrogen alcohol I can not do it.

According to the present invention, the following effects are expected.

(1) Glucomannan water-soluble dietary fiber used as a carrier enables homogeneous dispersion in anhydrous liquid suspending agent regardless of the size of the magnesium hydride powder.

(2) In the case of using the hydrogen generator composition of the present invention as an ointment for skin application, since the glucomannan carrier carrying the magnesium hydride powder absorbs water to enhance the moisturizing property, The generated hydrogen can be smoothly supplied to the skin.

(3) Coarse hydrogenated magnesium powder has a long hydrogen generation time when it reacts with water. Therefore, even if it is produced at the time of going out and consumes hydrogen gas, it replaces water by replenishing water on the spot, You can drink your worries.

(4) Since coarse hydrated magnesium powder uniformly dispersed by the glucomannan carrier and the suspending agent can be dropped uniformly in a water bottle or the like, the concentration of hydrogen such as hydrogen, a beverage product or hydrogen alcohol It can be made constantly and drinkable.

(5) When the hydrogen generator composition of the present invention is diluted with water or a beverage or an alcohol, it can be consumed with hydrogen having a reducing action and an antioxidative action, and a nutrient of magnesium and a functional substance called glucomannan are incidentally Can be supplemented.

(6) In addition to the purpose of uniformly dispersing the coarse hydrogenation magnesium in the anhydrous suspension by capturing coarse hydrogenation carrier, the glucomannan carrier can increase the concentration of dissolved hydrogen because the generated hydrogen floats to float / float.

FIG. 1 shows that glucomannan dietary fiber used as a carrier of coarse hydrated magnesium powder appears different in suspended state depending on the added amount. FIG. 1 (a) shows that coarse hydrated magnesium powder is excessively dropped, (C) shows a state in which the amount of coarse hydrated magnesium powder is less than the amount of coarse hydrogenated magnesium powder deposited on the supernatant layer, As shown in Fig.
Fig. 2 shows the change in redox potential when 3 drops (about 0.2 ml) and 6 drops (about 0.4 ml) of the hydrogen generator composition shown in Fig. 1 (b) were dropped into 300 ml of tap water.
Fig. 3 shows the pH change when 3 drops (about 0.2 ml) of the hydrogen generator composition of Fig. 1 (b) are added dropwise to 300 ml of tap water.
4 shows the oxidation-reduction potential and the pH change when 3 drops (about 0.2 ml) of the hydrogen generator composition shown in Fig. 1 (b) were dropped into 350 ml of tap water,
Fig. 5 shows the oxidation-reduction potential and the pH change when 1 wt% citric acid was dropped into hydrogen water produced by using the hydrogen generator composition shown in Fig. 1 (b).
Fig. 6 is a photograph showing a state in which coarse hydrogenated magnesium powder is carried on the glucomannan powder to float on the water surface while generating a large amount of hydrogen when glucomannan is used as a carrier of coarse hydrated magnesium powder.

The magnesium hydride (MgH ₂ ) used in the present invention is an ion-bonded hydride composed of Mg ²⁺ and H ^{- in} the same manner as the hydrate of an alkali metal.

Magnesium hydride powder is relatively stable in air, but releases water while reacting with water in water, which decomposes as shown in the following equation.

Magnesium hydride itself accounts for 7.6% (w / w) of hydrogen, and when magnesium hydride is dissolved in water, it generates more hydrogen and occupies 15.2% (w / w).

MgH ₂ + 2H ₂ O Mg (OH) ₂ + 2H ₂

In the examples of the present invention, a very coarse average particle diameter of 80 mu m was used as the powder of magnesium hydride.

As a carrier for the coarse hydrated magnesium powder, a glucomannan powder (# 80 through 1 wt% aqueous solution, pH 5 to 7, viscosity of about 35,000 mPa · S.) derived from konjak potato was used. The specific gravity is slightly higher than water, so it precipitates when it is dissolved in water. When magnesium hydride is loaded, it reacts with water to float the generated hydrogen and float in water. When the inclusion amount of hydrogen is increased, (See FIG. 6).

<Examples>

After preliminary experiments, three vessels were prepared in which 3.0 g, 3.3 g and 3.5 g of glucomannan powder as a carrier of coarse hydrated magnesium powder were added. Then, 1.6 g (8 wt% / V) of coarse hydrated magnesium powder having an average powder particle size of 80 μm was added thereto, and primary dry mixing was carried out. To prevent oxidation of the product, 2 g each of ascorbic acid was added thereto, Lt; / RTI &gt;

Then, 10 ml of anhydrous glycerin was added to each of these containers, followed by primary liquid phase mixing, followed by addition of anhydrous glycerin to prepare a 20 ml volume of the hydrogen generator composition per one container.

(Conductivity 1: Dispersibility of Coarse Hydrogenated Magnesium)

Three kinds of hydrogen generator compositions prepared with different contents of glucomannan powder were observed for more than 2 weeks at room temperature and in a refrigerator. The results are shown in Fig.

The hydrogen generator composition of FIG. 5 (b) containing 3.3 g of the glucomannan powder showed that the coarse magnesium hydroxide powder was well supported on the glucomannan powder and the entire container was light gray to such an extent that the layers could not be distinguished from each other. (A) shows the formation of a precipitate layer of coarse hydrated magnesium powder showing dark gray color on the lower side of the vessel. In the case of (c) in which 3.5 g is added, on the contrary, &Lt; / RTI &gt; was formed.

As shown in the figure, the coarse hydrated magnesium powder is dispersed in three forms in the form of a mixture of glucomannan powder (# 80, about 170 μm) having larger particle size than coarse hydrated magnesium powder and As the coarse hydrodynamic magnesium powder undergoes dry mixing and wet mixing, the amount of coarse hydrogenated magnesium powder is larger than that of the carrier and the equilibrium is in equilibrium (a) , And (c) is too small.

In order to quantitatively drop the hydrogen generator composition of FIG. 1 (b) in a state in which the coarse hydrated magnesium powder is well supported and dispersed in a container containing water, a beverage product, or an alcohol, It is believed that providing a product is the preferred method. This is because even if there is no special meter, the loading amount of the hydrogen generator composition can be adjusted more uniformly and constantly.

(Conducted result 2: change in oxidation / reduction potential and pH when the hydrogen generator composition of the present invention was added to tap water)

The hydrogen generator composition of the present invention was put into a 30-ml volumetric flask, and the following experiment was carried out (reference, the amount of one droplet to be dropped in the volumetric flask was about 0.067 ml).

FIG. 2 shows the redox potential for hydrogen water prepared by adding 3 drops and 6 drops of the hydrogen generator composition of the present invention containing 300 ml of tap water to a pressure-resistant PET bottle. 3 shows the pH change when three drops were dropped.

As shown in FIG. 2, when the hydrogen generator composition of the present invention was dropped by dropping three drops or six droplets, the dissolved hydrogen concentration was almost saturated after about 20 minutes of dropping. And the oxidation-reduction potential gradually decreased gradually until 3 hours thereafter. When 6 drops were dropped, the redox potential was about 30% lower than that at 3 drops at each measurement point. When 3 drops were dropped, the redox potential of -300mV in the middle was obtained, and when 6 drops were dropped, the redox potential was in the middle of -400mV.

On the other hand, the pH change was also high with time. The pH of the water used was 6.6. After 3 drops of the hydrogen generator composition of the present invention was added to the tap water, the pH increased to 8.3 after 5 minutes, and then gradually increased to 9.51 after 3 hours. It was weakly alkaline hydrogen water which is not burdensome to drink.

Thus, when the hydrogen generator composition of the present invention is to be used as hydrogen water, hydrogen beverage, hydrogen alcohol or the like, the hydrogen generator composition of the present invention is added to a predetermined water or beverage product or a container containing an alcohol, I drop one / two drops per 100ml and seal it and wait for about 20 minutes for the dissolved hydrogen concentration to saturate. Of course, you can wait for hours or days before drinking. In this case, since the concentration of dissolved hydrogen gradually increases and the container expands, it is preferable to use a pressure-resistant PET bottle if possible.

(Conducted result 3: Change in oxidation-reduction potential and pH when water was re-mixed / sank)

Fig. 4 shows an example of the redox potential and the pH when the hydrogen generator composition of the present invention is used to produce hydrogen over water.

In the experiment, three droplets (about 0.2 ml) of the hydrogen generator composition of the present invention were injected into a pressure-resistant plastic bottle containing 350 ml of water (initial pH 6.92, redox potential + 525 mV) Respectively. At this time, the redox potential of the aqueous solution of hydrogen was -271 mV and the pH was 8.91 (B). When the water was added to the bottle, the oxidation-reduction potential of (F) was -168 mV and the pH was 7.83. In this state, the vessel was closed and the water was re-circulated for 1 hour. At this time, the redox potential of (C) was -272 mV and the pH was 8.62. When the water was replenished, the redox potential of (G) was -161 mV, and the pH was 7.93. Then, this was sealed again, and one hour was waited for, and a small amount of water was prepared as a sludge (D). At this time, the redox potential was -143 mV and the pH was 8.06. When the supernatant was supplemented with water (100 ml), the redox potential of (H) was + 380 mV and the pH was 7.15. Then, it was sealed again and waited for one hour, and a small amount of water was prepared as a candy. At this time, the redox potential of (E) was + 150 mV, and the pH was 7.22.

From the above results, it can be concluded that the hydrogen generator composition of the present invention has a long reaction time with water when the coarse hydrated magnesium powder alone is dropped by only 3 drops (about 0.2 ml) dropped into a pressure- Therefore, even if the water is made up to the reflux or the sank, the water quality of the water equivalent to or almost equivalent to that of the initially produced water can be considered.

So, for example, even if you make a handful of water at home and bring it in when you go out and you have exhausted the amount of hydrogen you brought, you can easily drink 2-3 times more easily by supplementing it with water if you are around it.

(Conducting result 4: change in oxidation-reduction potential and pH when 1 wt% of citric acid was treated with hydrogen peroxide)

5, a predetermined 1 wt% solution of citric acid was dropped into a hydrogen peroxide solution (A.-216 mV, pH 8.4) prepared by filling 3 drops of the hydrogen generator composition of the present invention in a 300 ml PET bottle filled with tap water And shows the relationship between the oxidation-reduction potential and the pH when they are left to stand in airtightness.

As shown in the figure, when an acid is added dropwise to an alkaline aqueous solution of hydrogen, the pH value is decreased along with the redox potential. When this was closed again, the crude magnesium hydride powder continuously reacted with water to raise the pH value again and lower the redox potential value.

As a result, for example, referring to point A in FIG. 5, even if the oxidation-reduction potentials are the same, hydrogen numbers A and X having different pH values are present, and even if the pH values are the same, There are also different numbers A and F of water. Therefore, the hydrogen generator composition using the coarse hydrated magnesium powder as in the present invention can utilize a long reaction time between the coarse hydrated magnesium powder and water, and even if it is difficult for the user to drink, for example, alkaline hydrogen fluoride, After making alkaline hydrogen water having a high pH, a predetermined amount of acid is added to the water, and then water can be produced with low pH and low oxidation-reduction potential.

(Conduct result 5: Role of glucomannan carrier)

Fig. 6 shows an example of a photograph of the hydrogen generator composition of the present invention placed in a beaker.

On the bottom and sides of the beaker, there are many hydrogen produced by coarse hydriding magnesium, and on its surface, coarse hydrogen magnesium powder-bearing glucomannan encapsulates a large amount of hydrogen and floats. Glucomannan dietary fiber has a slightly higher specific gravity than water, so it precipitates when diluted to water for the first time, but the coarse hydrated magnesium powder that is supported reacts with water to generate hydrogen and float / float together. Glucomannan dietary fiber swells more and more over time and aggregates between floating or floating glucomannan dietary fibers. Of course, if such a hydrogen is contained in a PET bottle, when it is shaken or impacted, the coagulated glucomannan dietary fiber is separated from each other and the hydrogen is extinguished. And, glucomannan dietary fiber re-precipitates because its specific gravity is higher than water. However, the glucomannan dietary fiber, which has precipitated over time, may resuspend / float while generating hydrogen again if it is loaded with magnesium hydride powder. Glucomannan dietary fiber floated on the surface of water contains a large amount of hydrogen, which can be poured, but it can be as it is.

The hydrogen generator composition of the present invention may be prepared by suspending a coarse hydrogenated magnesium powder and a glucan- manan dietary fiber carrier to be carried thereon in anhydrous suspending agent and filling it with a tube or a drop type container to dilute it with water or a drink or alcohol In the case of producing hydrogen water, a hydrogenated beverage product, hydrogen alcohol or the like, the concentration of hydrogen dissolved in each time can be kept constant. Since coarse hydrated magnesium powder can utilize a long reaction time with water, It is possible to drink even when it is used for rejuvenating or sankang and it is possible to supply hydrogen to the skin for a longer time by using the superior moisturizing effect of glucomannan even when used as an external ointment for skin, It can be easily introduced with prevention etc. And contribute to human health.

Claims (1)

The magnesium hydride powder (MgH ₂ ) and the magnesium hydride powder carrier and / or the water-repellent glucomannan powder as a covering body of hydrogen gas were dry mixed and wet mixed with anhydrous edible fats containing anhydrous glycerin or a food additive emulsifier &Lt; / RTI &gt;

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