KR101830326B1 - 대결정 유기물-비함유 차바자이트, 이의 제조 및 사용 방법 - Google Patents

대결정 유기물-비함유 차바자이트, 이의 제조 및 사용 방법 Download PDF

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KR101830326B1
KR101830326B1 KR1020137030394A KR20137030394A KR101830326B1 KR 101830326 B1 KR101830326 B1 KR 101830326B1 KR 1020137030394 A KR1020137030394 A KR 1020137030394A KR 20137030394 A KR20137030394 A KR 20137030394A KR 101830326 B1 KR101830326 B1 KR 101830326B1
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zeolite
copper
sar
potassium
product
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KR20140027280A (ko
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홍-신 리
윌리엄 이. 코르미에
브좀 모덴
데이비드 쿠퍼
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피큐 코포레이션
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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34—Chemical or biological purification of waste gases
    • B01D53/92—Chemical or biological purification of waste gases of engine exhaust gases
    • B01D53/94—Chemical or biological purification of waste gases of engine exhaust gases by catalytic processes
    • B01D53/9404—Removing only nitrogen compounds
    • B01D53/9409—Nitrogen oxides
    • B01D53/9413—Processes characterised by a specific catalyst
    • B01D53/9418—Processes characterised by a specific catalyst for removing nitrogen oxides by selective catalytic reduction [SCR] using a reducing agent in a lean exhaust gas
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/064—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof containing iron group metals, noble metals or copper
    • B01J29/072—Iron group metals or copper
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65
    • B01J29/7015—CHA-type, e.g. Chabazite, LZ-218
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65
    • B01J29/72—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65 containing iron group metals, noble metals or copper
    • B01J29/76—Iron group metals or copper
    • B01J29/763—CHA-type, e.g. Chabazite, LZ-218
    • B—PERFORMING OPERATIONS; TRANSPORTING
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    • B01J37/0009—Use of binding agents; Moulding; Pressing; Powdering; Granulating; Addition of materials ameliorating the mechanical properties of the product catalyst
    • B01J37/0018—Addition of a binding agent or of material, later completely removed among others as result of heat treatment, leaching or washing,(e.g. forming of pores; protective layer, desintegrating by heat)
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
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    • B01J37/08—Heat treatment
    • B01J37/10—Heat treatment in the presence of water, e.g. steam
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
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    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
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    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B39/00—Compounds having molecular sieve and base-exchange properties, e.g. crystalline zeolites; Their preparation; After-treatment, e.g. ion-exchange or dealumination
    • C01B39/02—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof; Direct preparation thereof; Preparation thereof starting from a reaction mixture containing a crystalline zeolite of another type, or from preformed reactants; After-treatment thereof
    • C01B39/46—Other types characterised by their X-ray diffraction pattern and their defined composition
    • C01B39/48—Other types characterised by their X-ray diffraction pattern and their defined composition using at least one organic template directing agent
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    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
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    • B01D2253/10—Inorganic adsorbents
    • B01D2253/106—Silica or silicates
    • B01D2253/108—Zeolites
    • B01D2253/1085—Zeolites characterized by a silicon-aluminium ratio
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    • B01J2229/10—After treatment, characterised by the effect to be obtained
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    • B—PERFORMING OPERATIONS; TRANSPORTING
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    • B01J2229/10—After treatment, characterised by the effect to be obtained
    • B01J2229/18—After treatment, characterised by the effect to be obtained to introduce other elements into or onto the molecular sieve itself
    • B01J2229/186—After treatment, characterised by the effect to be obtained to introduce other elements into or onto the molecular sieve itself not in framework positions
    • B—PERFORMING OPERATIONS; TRANSPORTING
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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Materials Engineering (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Geology (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • General Life Sciences & Earth Sciences (AREA)
  • Environmental & Geological Engineering (AREA)
  • Inorganic Chemistry (AREA)
  • Combustion & Propulsion (AREA)
  • Health & Medical Sciences (AREA)
  • Biomedical Technology (AREA)
  • Analytical Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Thermal Sciences (AREA)
  • Physics & Mathematics (AREA)
  • Silicates, Zeolites, And Molecular Sieves (AREA)
  • Catalysts (AREA)
KR1020137030394A 2011-04-18 2012-04-17 대결정 유기물-비함유 차바자이트, 이의 제조 및 사용 방법 Active KR101830326B1 (ko)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US201161476575P 2011-04-18 2011-04-18
US61/476,575 2011-04-18
PCT/US2012/033948 WO2012145323A1 (en) 2011-04-18 2012-04-17 Large crystal, organic-free chabazite, methods of making and using the same

Related Child Applications (1)

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KR1020187004270A Division KR101948254B1 (ko) 2011-04-18 2012-04-17 대결정 유기물-비함유 차바자이트, 이의 제조 및 사용 방법

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KR20140027280A KR20140027280A (ko) 2014-03-06
KR101830326B1 true KR101830326B1 (ko) 2018-02-20

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KR1020187004270A Expired - Fee Related KR101948254B1 (ko) 2011-04-18 2012-04-17 대결정 유기물-비함유 차바자이트, 이의 제조 및 사용 방법

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Country Link
US (1) US20120269719A1 (https=)
EP (1) EP2699345A4 (https=)
JP (1) JP6169069B2 (https=)
KR (2) KR101830326B1 (https=)
CN (1) CN103561865B (https=)
WO (1) WO2012145323A1 (https=)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR101948254B1 (ko) * 2011-04-18 2019-02-14 피큐 코포레이션 대결정 유기물-비함유 차바자이트, 이의 제조 및 사용 방법

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JP6450521B2 (ja) * 2010-12-02 2019-01-09 ジョンソン、マッセイ、パブリック、リミテッド、カンパニーＪｏｈｎｓｏｎ Ｍａｔｔｈｅｙ Ｐｕｂｌｉｃ Ｌｉｍｉｔｅｄ Ｃｏｍｐａｎｙ 金属含有ゼオライト触媒
JP5895510B2 (ja) * 2010-12-22 2016-03-30 東ソー株式会社 チャバザイト型ゼオライト及びその製造方法、銅が担持されている低シリカゼオライト、及び、そのゼオライトを含む窒素酸化物還元除去触媒、並びに、その触媒を使用する窒素酸化物還元除去方法
JP6324895B2 (ja) * 2011-11-11 2018-05-16 ビーエーエスエフ ソシエタス・ヨーロピアＢａｓｆ Ｓｅ ゼオライト系材料の製造方法、合成ゼオライト系材料及び合成ゼオライト系材料の使用方法
US9527751B2 (en) 2011-11-11 2016-12-27 Basf Se Organotemplate-free synthetic process for the production of a zeolitic material of the CHA-type structure
WO2013082550A1 (en) 2011-12-02 2013-06-06 Pq Corporation Stabilized microporous crystalline material, the method of making the same, and the use for selective catalytic reduction of nox
DE202013012229U1 (de) * 2013-04-05 2015-10-08 Umicore Ag & Co. Kg CuCHA Material für die SCR-Katalyse
GB201421333D0 (en) * 2013-12-02 2015-01-14 Johnson Matthey Plc Mixed template synthesis of high silica cu-cha
JP5732170B1 (ja) * 2014-07-07 2015-06-10 イビデン株式会社 ゼオライト、ハニカム触媒及び排ガス浄化装置
JP5740040B1 (ja) * 2014-07-07 2015-06-24 イビデン株式会社 ゼオライト、ハニカム触媒及び排ガス浄化装置
US9938157B2 (en) * 2014-07-23 2018-04-10 Chevron U.S.A. Inc. Interzeolite transformation and metal encapsulation in the absence of an SDA
US9802831B2 (en) * 2014-07-23 2017-10-31 Chevron U.S.A. Inc. Synthesis of high silica zeolite via interzeolite transformation without OSDAs
JP2016073959A (ja) * 2014-10-09 2016-05-12 イビデン株式会社 ハニカム触媒
JP6546731B2 (ja) * 2014-10-09 2019-07-17 イビデン株式会社 ハニカム触媒
US10173211B2 (en) 2014-10-14 2019-01-08 California Institute Of Technology Organic-free synthesis of small pore zeolite catalysts
CA2989133C (en) * 2015-06-12 2023-12-05 Basf Corporation Exhaust gas treatment system
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