KR101678559B1 - Water-Drop Solid Cosmetic composition if the form of Water in Oil emulsion containing Powders - Google Patents

Water-Drop Solid Cosmetic composition if the form of Water in Oil emulsion containing Powders Download PDF

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Publication number
KR101678559B1
KR101678559B1 KR1020150145661A KR20150145661A KR101678559B1 KR 101678559 B1 KR101678559 B1 KR 101678559B1 KR 1020150145661 A KR1020150145661 A KR 1020150145661A KR 20150145661 A KR20150145661 A KR 20150145661A KR 101678559 B1 KR101678559 B1 KR 101678559B1
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South Korea
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water
powder
oil
weight
dimethicone
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KR1020150145661A
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Korean (ko)
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조인식
구형서
박한웅
김승태
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애경산업(주)
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    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/02Cosmetics or similar toiletry preparations characterised by special physical form
    • A61K8/04Dispersions; Emulsions
    • A61K8/06Emulsions
    • A61K8/064Water-in-oil emulsions, e.g. Water-in-silicone emulsions
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/02Cosmetics or similar toiletry preparations characterised by special physical form
    • A61K8/0216Solid or semisolid forms
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/19Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
    • A61K8/25Silicon; Compounds thereof
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/33Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
    • A61K8/34Alcohols
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/84Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
    • A61K8/89Polysiloxanes
    • A61K8/891Polysiloxanes saturated, e.g. dimethicone, phenyl trimethicone, C24-C28 methicone or stearyl dimethicone
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/92Oils, fats or waxes; Derivatives thereof, e.g. hydrogenation products thereof
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/92Oils, fats or waxes; Derivatives thereof, e.g. hydrogenation products thereof
    • A61K8/922Oils, fats or waxes; Derivatives thereof, e.g. hydrogenation products thereof of vegetable origin
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61QSPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q19/00Preparations for care of the skin
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K2800/00Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
    • A61K2800/80Process related aspects concerning the preparation of the cosmetic composition or the storage or application thereof

Abstract

The present invention is gently applied to the skin and gives good feel to the user. It immediately replenishes the skin and gives a cooling feeling to the skin as soon as it emits moisture. It contains both water-dispersible powder and oil-dispersed powder to makeup effect and sebum control Water-drop solid type water-in-oil type cosmetic composition. The present invention relates to an oil-in-water emulsion composition comprising 10 to 50% by weight of a milk portion comprising 0.5 to 6.0% by weight of a mixed emulsifier comprising an emulsifier and an emulsifying aid, 1 to 40% by weight of an oil and 0.5 to 10% by weight of a solidifying agent; 40 to 70% by weight of water, including water; And 0.05 to 30% by weight of a powder part comprising a modified lipophilic powder and a modified hydrophilic powder; and a water-drop solid type water-in-oil type cosmetic composition containing the powder.

Description

[0001] The present invention relates to a water-drop-type water-drop cosmetic composition,

The present invention is gently applied to the skin and gives good feel to the user. It immediately replenishes the skin and gives a cooling feeling to the skin as soon as it emits moisture. It contains both water-dispersible powder and oil-dispersed powder to makeup effect and sebum control Water-drop solid type water-in-oil type cosmetic composition.

The composition of make-up cosmetics is used to hide skin imperfections or make the human body beautiful. It is gently applied when applied to the skin. It is excellent in skin adhesion and cosmetic effect, has no shine after a lapse of time, and has good skin stability.

Commonly known make-up cosmetic compositions include emulsification type, powder type and oil dispersion type. The powder type has a severe drying tendency and the oil dispersion type contains a large amount of wax, giving a feeling of heavy feeling, and there is a disadvantage that it is felt to be stiff when making up.

The type of emulsion type cosmetic composition is classified into water type (O / W) and water type (W / O). Water type (O / W) is poor in water resistance and make-up when used as a makeup cosmetic, There is a downside to this.

Water-in-oil type (W / O) creams are excellent in make-up persistence and water resistance because they are oil-in-water. However, they have heavy and frustrating feeling due to oil and low long-term stability of emulsions. In addition, as the water balance in the skin caused by the powder breaks, the skin becomes more dry or sebum secretion increases and the skin condition deteriorates.

Control of the water balance in the skin is very important. Especially when the skin lacks moisture, it is dry, it is easy to keratinize, and it causes skin trouble.

Recently, water drop water cream as a cosmetic for moisture supply has been attracting consumers. Water Drop Moisture Cream has a merit that water drops are formed when it is applied to the skin, and the water drops replenish the moisture on the skin. It has better moisture replenishing power than the existing water cream and excellent long-term retention power.

However, in the case of a cosmetic powder containing powder, it has been difficult to produce such a water drop type cosmetic due to the stability problem of powder dispersion. In addition, water drop cosmetic compositions have problems in that they are poor in long-term storage stability and formulation stability when stored in a cream or liquid type for a long period of time.

An object of the present invention is to provide a powder-containing water drop solid type cosmetic composition which contains powder and is excellent in long-term storage stability and formulation stability.

Another object of the present invention is to provide a method for producing a powder-containing water-drop solid type cosmetic composition which contains a powder and is excellent in long-term storage stability and formulation stability.

Specifically, the object of the present invention is to stabilize the phase of the powder contained in the upper part of the water in addition to the powder contained in the upper part of the water, thereby facilitating the filling operation during mass production and maintaining the water resistance of the existing water- And it emits moisture immediately to maintain the water balance and provides a feeling of moist feeling at the same time as replenishing with water and can secure a higher stability than a general liquid or cream-like water-in-oil type cosmetic material. By containing an aqueous dispersion powder, And to provide a water drop solid type water-in-oil type cosmetic composition which is improved in feeling to be able to block, sebum control, visual appeal of a specific ingredient, and skin adhesion.

In order to accomplish the object of the present invention, the present invention provides a process for producing a modified lipophilic powder, which comprises mixing 0.5 to 6.0% by weight of a mixed emulsifier containing an emulsifier and an emulsifying aid, 1 to 40% by weight of oil, 0.5 to 10% by weight of a solidifying agent, 30 to 50% by weight of an oily portion containing 50% by weight; And 0.01 to 10% by weight of a modified hydrophilic powder and 50 to 70% by weight of an aqueous phase containing water, wherein the total content of the modified lipophilic powder and modified hydrophilic powder is 0.05 - Water-drop solid type water-in-oil type cosmetic composition containing 30% by weight of water.

In order to stabilize the dispersion of each powder, 0.5 to 10% by weight of the total weight of each powder raw material can be surface-treated at the time of powder modification, and the lipophilic powder and the hydrophilic powder are separately treated.

The water drop solid type water-in-oil type cosmetic composition containing the powder according to the present invention can visually confirm the water replenishment and powder inclusion contents to the skin as soon as the inner water layer immediately releases the water immediately after the application, gives a cool and moisturized feeling, The released water is mixed with the powder and the oily part again, and thus, the feeling of skin adhesion is greatly increased.

In addition, since the composition of the present invention is a solid type, it can provide a composition having excellent long-term storage stability and formulation stability when preserved for a longer time than conventional water-in-oil type or liquid type, and having better skin adhesion than cream or liquid type. And consumers can offer differentiated cosmetics with unique and soft feeling.

The present invention relates to a water drop water-in-oil type cosmetic composition containing a large amount of aqua regia, and is intended to impart functions such as makeup and sebum control ultraviolet ray blocking by containing powder for stabilizing formulations and cosmetic effects by solid form.

Hereinafter, the present invention will be described more specifically. However, this is for the purpose of illustration and is not intended to limit the scope of the invention.

According to one embodiment of the present invention, the present invention provides a method for producing a lubricating oil composition comprising 0.5 to 6.0% by weight of a mixed emulsifier comprising an emulsifier and an emulsifying aid, 1 to 40% by weight of oil, 0.5 to 10% by weight of a solidifying agent, 30 to 50% by weight of an oil-in-water portion containing% by weight; And 0.01 to 10% by weight of a modified hydrophilic powder and 50 to 70% by weight of an aqueous phase containing water, wherein the total content of the modified lipophilic powder and modified hydrophilic powder is 0.05 - Water-drop solid type water-in-oil type cosmetic composition containing 30% by weight of water.

The emulsifier may be selected from the group consisting of Cetyl Phosphite / Phosphite-10/1 Dimethicone, Phage-10 Dimethicone, Phage / Phosphite-19/19 Dimethicone, Sorbitan Cesquioleate, Lauryl Phage- Siloxylethyl dimethicone, phage-9 polydimethylsiloxy ethyldimethicone, lauryl phage-10 tris (trimethylsiloxy) silyl ethyldimethicone, phage / piperazine-18/18 dimethicone And combinations of these.

Examples of the emulsifying aid may include elastomers such as dimethicone / phage-10/15 crosspolymer, phage-12 dimethicone / phyphage-20 crosspolymer, dimethicone / vinyl dimethicone crosspolymer, dimethicone Cross-polymers, and combinations thereof.

According to one embodiment, the mixed emulsifier is selected from the group consisting of dimethicone / phage-10/15 crosspolymer and cetylpyridine / phyphage-10/1 dimethicone, phage-10 dimethicone, phage / / 19 dimethicone, sorbitan sesquioleate, lauryl phage-9 polydimethylsiloxyethyl dimethicone, phage-9 polydimethylsiloxy ethyldicichone, lauryl phage-10 tris Siloxyl) silyl chilled dimethicone, and phage / piperidine-18/18 dimethicone, or a mixture thereof may be used.

The smaller the emulsion particle is, the more stabilized it is. However, by using the elastomer, the stability can be enhanced even in the state where the emulsion particle is large, and the phenomenon of water drop through the large emulsion particle can be easily constituted.

In the elastomer, an emulsifying elastomer and a non-emulsifying elastomer are present. These emulsions are difficult to constitute as a single emulsion particle, but they are very useful for stabilizing a large emulsion particle.

It is preferable to use an emulsifiable elastomer in order to reduce the variation with respect to the kind of oil in the oil portion.

The oil is not particularly limited in the present invention, and a non-polar oil such as silicone oil is suitably used to easily implement a water drop.

Preferred examples thereof include cyclomethicone, dimethicone, polyisobutene, squalane, cetyl hexyl hexanoate, caprylic / capric triglyceride, octyldodecanol, dicaprylyl carbonate, triethanol hexanol, olive oil , Macadamia seed oil and the like, and at least one selected from the group consisting of these.

The solidifying agent is preferably selected from carnauba wax, microcrystalline wax, candelilla wax, paraffin wax, beeswax, ozokerite, ceresin, polyethylene, ethylene / propylene copolymer, But are not limited to, lactic acid, lauric acid and other butters, butyl alcohol, behenyl alcohol, stearyl alcohol, cetostearyl alcohol, cetyl alcohol, gelling agents such as trihydroxystearin, stearoyl inulin, dextrin palmitate, , Dextrin palmitate / ethyl hexanoate, glyceryl behenate, glyceryl behenate / eicosadioate, polyglyceryl-6 octa stearate, polyglyceryl-10 behenate / eicosadioate, And combinations thereof, and combinations thereof, and at least one selected from the group consisting of diclofenac, diclofenac, dicyclohexylidene,

The powder may generally be classified into unmodified powder, lipophilic powder (hereinafter referred to as "lipophilic powder") and hydrophilic modified powder (hereinafter referred to as "hydrophilic powder"). Hydrophilic powder is used in the upper part and hydrophilic powder is used in the upper part.

Preferably, in the case of lipophilic powder, it is modified with a hydrophobic raw material such as dimethicone, methicone, triethoxycaprylylsilane or fluorine raw material.

In order to minimize the phase change with time, the hydrophilic powder should be considered for surface modification or synthesis of a highly hydrophilic powder. Preferably, the hydrophilic powder is modified with hydrophilic raw materials such as silica, glycerin, polyols, and disodium carboxyethylstilbicone. Specifically, there is a method of coating a normal powder with disodium carboxyethylstilbicone or the like, and there may be a method of composite synthesis of the powder surface with silica having high hydrophilicity.

These methods and the like can be carried out by selecting an efficient method depending on the characteristics of each powder.

According to the present invention, by using the modified lipophilic powder, it is possible to improve the spreadability of the product, to realize a makeup effect, and to provide an ultraviolet shielding function.

Further, according to the present invention, by using the hydrophilic powder, it is possible to realize a color change of a water drop-off water component and functionally contribute to stabilization of an effective ingredient, enhancement of ultraviolet shielding power, and improvement of sebum control ability.

Specifically, examples of the powder used in the present invention include a combination of titanium dioxide, zinc oxide, talc, mica, iron oxide, nylon, polymethylsilsesquioxane, synthetic fluorofluorophosphate, methyl methacrylate crosspolymer, and silica And at least one selected.

The lipophilic powder preferably contains 10 to 50% by weight of the total weight of the oil phase part. If the amount is larger than the above range, it is difficult to fill and form the product, and it is difficult to form the water drop formulation, and if it is included in a small amount, functions such as ultraviolet shielding and makeup can not be sufficiently exhibited.

The hydrophilic powder is preferably contained in an amount of 0.01 to 10% by weight based on the total weight of the aqueous phase. If it is included more than the above range, it is difficult to form a water drop. If it is included less than this range, it is difficult to implement a function such as color implementation in drop formation.

The water receiving part may be added with various kinds of cosmetic water including purified water and representative examples thereof include polyols such as polyglycerin, glycerin, propylene glycol and butylene glycol, which are moisturizing agents, and polyols such as sorbitol, trehalose, erythritol, xylitol maltitol, The present invention is not limited to the specific ingredients of the present invention since it may include Cole, mannan, carrageenan, chondroitin, hyaluronic acid, sodium hyaluronate, collagen, panthenol, gamma phagemy, and fermented products.

In addition to these, fragrance and salts for making emulsified particles hard can be included in the water, and examples thereof include sodium chloride, magnesium sulfate and the like.

According to one embodiment of the present invention, there is provided a process for producing a water-in-oil emulsion, comprising the steps of: heating an emulsifier, an emulsifying aid, an oil and a solidifying agent at a temperature of 60 to 80 ° C to produce an oil- Introducing the modified and pulverized lipophilic powder into the oil phase; Preparing a water phase by heating the mixture of purified water, a humectant and an additive at 60 to 80 캜, adding the modified and ground hydrophilic powder, and dispersing and mixing the mixture; Emulsifying the water phase part at 3,000 to 3,500 rpm for 5 to 30 minutes to the oil phase part; And degassing and filtrating at 65 to 75 DEG C to prepare a powder-containing water-drop solid type water-in-oil type cosmetic composition.

According to an embodiment of the present invention, the dispersion of the lipophilic powder and the hydrophilic powder is preferably performed at 1,000 to 4,000 rpm for 30 to 60 minutes.

Hereinafter, the present invention will be described more specifically by way of examples.

Example  1 and Comparative Example  1 to 5

The cosmetic compositions of Example 1 and Comparative Examples 1 to 5 were prepared with the compositions shown in Table 1 below. The specific manufacturing method is as follows.

[Manufacturing method]

Manufacture of upper part:

 An oil phase, an emulsifying agent, an emulsifying auxiliary agent, an oil, and a wax silicone with a solidifying agent such as a wax or a gelling agent. At this time, in order to facilitate the melting of the wax or the gelling agent, they were separately mixed and melted, and then charged into the oil phase. The emulsion was mixed with a homomixer at 1,000 to 3,500 rpm for about 5 minutes. The powders to be added to the oil phase were pulverized and mixed through a powder mixer such as a Henschel mixer and an atomizer, and a crusher.

A prize winner  Produce

Each kind of moisturizing agent and additives including purified water were mixed by heating at about 75 ° C, and the aqueous powders for injection were mixed and dispersed until entering the upper part. A propeller mixer is used, but other mixers such as a disper can be used. Considering the wetting time of the powder, it proceeded for more than 30 minutes. And mixed at about 2,000 to 3,500 rpm.

 The water phase portion was injected and emulsified into the oil phase portion in which the powder was dispersed. This process affects the type of emulsifier, and it is suitable for about 5 minutes to 30 minutes. The emulsification rate has an effect on the particle size and also varies depending on the size and type of the homomixer. Most are applied at around 3,000 ~ 3,500rpm. After emulsification, degassing and filtration were carried out at about 70 ° C. No homomixers or the like which affect the emulsified particles were used, and paddles which can slowly stir the contents were used at a low speed. The container was filled and then cooled. Depending on the container and the characteristics of use, slow cooling and rapid cooling are selected.

[Configuration]

Comparative Example 1 is a general foundation composition excellent in stability, Comparative Example 2 is a foundation capable of being water-dropable, and Comparative Example 3 is a general-purpose water-dropable cosmetic composition. In the case of Comparative Example 4, ceresin and glycerin behenate were added to a water dropable foundation of Comparative Example 2 to solidify the composition. In Comparative Example 5, powder was added to the foundation composition to prepare a foundation composition

For comparison of the same conditions, the same hydrophilic modified powders as in Example 1 were dispersed in water at 1% in both of Comparative Example 4 and Comparative Example 5.

(Unit: wt%) Furtherance Comparative Example 1 Comparative Example 2 Comparative Example 3 Comparative Example 4 Comparative Example 5 Example 1 Floating Three tilipies / piperazine-10/1 dimethicone 3 1.5 Piggy / Pefji - 19/19 Dimethicone 1.5 1.5 Lauryl phage-9 polydimethylsiloxy ethyl dimethicone 1.5 One 1.5 One Dimethicone / Vinyl Dimethicone Crosspolymer 3 3 3 Dimethicone / phage-10/15 cross polymer 5 5 4 Cyclomethicone 10 10 15 10 15 10 Dimethicone 3 3 3 2 Polyisobutene One Neopentyleneglycol diheptanoate 10 10 Ceresin 7 7 7 Glycerin behenate 0.5 0.5 0.5 Candelilla wax 4 Ozokerite One Powder part <Oil-modified silica powder>
Titanium dioxide, iron oxide, talc, mica and more
15
<Hydrophilic modified powder>
Titanium dioxide, iron oxide, talc, mica and more
One One One
<Normal powder>
Titanium dioxide, iron oxide, talc, mica and more
13 13 13 13
Water top Purified water To 100 To 100 To 100 To 100 To 100 To 100 glycerin 2 2 10 2 2 2 Butylene glycol 5 5 5 5 5 5 Sodium chloride One One One One One One Spices 0.1 0.1 0.1 0.1 0.1 0.1

Experimental Example  One:

In order to confirm the stability of the cosmetic compositions of Example 1 and Comparative Examples 1 to 5, evaluation was made according to the evaluation methods and criteria of Table 2 below.

Stability evaluation method and evaluation standard Storage conditions Assessment Methods 43 ℃ Section 43 Evaluation of storage for 3 months in a greenhouse 25 25th storage evaluation in the greenhouse for 3 months 5 Section 5 Evaluation for 3 months in the greenhouse cycling Cycle of 43, 25, 5 in 8-hour cycle in the greenhouse Evaluation of storage for 3 months evaluation Very good: No change in properties, properties and flavor good : There is no change in physical properties and flavor, but less than 5% (per volume) Stain usually : Some properties change (less than 10%) (change in volume), viscosity, hardness, etc. Poor: Discoloration, separation, separation, etc.

Table 1 Stability Evaluation of Composition Storage conditions term Comparative Example 1 Comparative Example 2 Comparative Example 3 Comparative Example 4 Comparative Example 5 Example 1 43 ℃ 1 week 1 month 3 months X X 25 ℃ 1 week 1 month 3 months 5 ℃ 1 week 1 month 3 months cycling 1 week 1 month 3 months X X

※ Evaluation method: See Table 2

Comparative Example 1 to Comparative Example 5 and Example 1 were evaluated for stability, and Comparative Example 1 and Water Drop Foundation Comparative Example 2, Comparative Example 4 wherein the water drop foundation was solidified, and Water Drop Solidification Foundation Example 1, And it was confirmed that it was excellent.

In the case of Comparative Example 3, which is a water drop solid type cosmetic composition, the properties were changed at high temperature, and stability was not changed even when powder was added.

Experimental Example  One: Water drop  Generation and Opacity  exam

For water drop creation, fill the contents in a 12 g aluminum dish and measure the number of drops dropping out of the surface ten times with a spatula. (See Table 4)

For the turbidity test, 0.04 g of titanium dioxide in 100 g of glycerin is diluted with 100%, 50%, 10% glycerin and compared with the standard solution (see Table 4).

Kinds Assessment Methods Water drop creation Very good: More than 2 drops (about 2g) drop formation good : Less than 2 drops (about 1 ~ 2g) Drop formation usually : Drops do not fall off, surface has water Poor: No water formed Opacity Very good: Compared with 100% standard solution in comparison with cylinder good : Compared to cylinder 100% Less than standard solution 50% Standard solution or more usually : Compared to cylinder 50% Less than standard solution 10% Standard solution or more Poor: Compared to cylinder, less than 10% standard solution

Comparative Example Comparative Example 1 Comparative Example 2 Comparative Example 3 Comparative Example 4 Comparative Example 5 Example 1 Water drop formation X X Water cloudiness X X X X X

As shown in Table 5, Comparative Examples 2 to 3 had a water drop effect, and Comparative Example 2, which was a solid type, showed a halved effect.

In the case of Example 1, the amount of the water-dropped aqueous phase was the highest, and in all the comparative examples, no white drop was observed in the water drop

Example  2

A cosmetic composition was prepared in accordance with the production method of Example 1 with the composition of the emulsifier and the composition ratio shown in Table 6 below.

Furtherance Example
2-1
Example
2-2
Example
2-3
Example
2-4
Example
2-5
Example
2-6
Example
2-7
Example
2-8
Floating Three tilipies / piperazine-10/1 dimethicone 2 1.5 1.5 1.5 Piggy-10 Dimethicone 2 1.5 1.5 1.5 Dimethicone / phage-10/15 cross polymer 4 4 4 4 4 4 4 4 Cyclomethicone 10 10 10.5 10.5 8.5 8.5 6.5 6.5 Dimethicone 2 2 2 2 2 2 2 2 Polyisobutene One One One One One One One One Polyethylene wax 2 2 2 2 2 2 2 2 Ceresin 7 7 7 7 7 7 7 7 Powder part <Oil-modified silica powder>
Titanium dioxide, iron oxide, talc, mica and more
15 15 15 15 15 15 15 15
<Hydrophilic modified powder>
Titanium dioxide, iron oxide, talc, mica and more
One One One One One One One One
Water top Purified water To 100 To 100 To 100 To 100 To 100 To 100 To 100 To 100 glycerin 2 2 2 2 2 2 2 2 Butylene glycol 3 3 3 3 3 3 3 3 Sodium glutamate 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 Spices 0.2 0.2 0.2 0.2 0.2 0.2 0.2 0.2

Claims (13)

30 to 50% by weight of an oil phase comprising 0.5 to 6.0% by weight of a mixed emulsifier comprising an emulsifier and an emulsifying aid, 1 to 40% by weight of an oil, 0.5 to 10% by weight of a solidifying agent and 10 to 50% by weight of a modified lipophilic powder, ; And
0.01 to 10% by weight of a modified hydrophilic powder and 50 to 70% by weight of an aqueous phase containing water,
Wherein the modified lipophilic powder and the modified hydrophilic powder have a total content of 0.05 to 30% by weight of the composition.
The method according to claim 1,
Wherein the emulsifying aid is an elastomer. The water drop solid type water-in-oil type cosmetic composition according to claim 1,
The method according to claim 1,
The emulsifier may be selected from the group consisting of Cetyl Phosphite / Phosphite-10/1 Dimethicone, Phage-10 Dimethicone, Phage / Phosphite-19/19 Dimethicone, Sorbitan Cesquioleate, Lauryl Phage- Siloxylethyl dimethicone, phage-9 polydimethylsiloxy ethyldimethicone, lauryl phage-10 tris (trimethylsiloxy) silyl ethyldimethicone, phage / piperazine-18/18 dimethicone And a combination thereof. 2. The water drop solid type water-in-oil type cosmetic composition according to claim 1,
3. The method of claim 2,
Wherein the elastomer is selected from the group consisting of a dimethicone / phage-10/15 crosspolymer, a phage-12 dimethicone / piperidine-20 crosspolymer, a dimethicone / vinyl dimethicone crosspolymer, a dimethicone crosspolymer, Water drop solid type water-in-oil type cosmetic composition containing at least one selected powder.
The method according to claim 1,
The oil may be selected from the group consisting of cyclomethicone, dimethicone, polyisobutene, squalane, cetyl hexyl hexanoate, caprylic / capric triglyceride, octyldodecanol, dicaprylyl carbonate, , Macadamia seed oil, etc., and a powder containing at least one selected from the group consisting of water drops, solid type water-in-oil type cosmetic compositions.
The method according to claim 1,
Examples of the solidifying agent include carnauba wax, microcrystalline wax, candelilla wax, paraffin wax, biswax, ozokerite, ceresin, polyethylene, ethylene / propylene copolymer, fatty acids such as stearic acid, myristic acid, Butanol, stearyl alcohol, cetostearyl alcohol, cetyl alcohol, gelling agents such as trihydroxystearin, stearoyl inulin, dextrin palmitate, dextrin myristate, dextrin palmitate / Ethylhexanoate, glyceryl behenate, glyceryl behenate / eicosadioate, polyglyceryl-6 octa stearate, polyglyceryl-10 behenate / eicosadioate, dibutyl lauroylglutamate And dibutyl hexyl hexanoyl glutamide, wherein the water-drop-containing water-drop &lt; RTI ID = 0.0 &gt; Type water-in-oil type cosmetic composition.
The method according to claim 1,
Wherein the modified lipophilic powder is modified with dimethicone, methicone, triethoxycaprylylsilane or a fluorine raw material, wherein the modified lipophilic powder is a water drop solid type water-in-oil type cosmetic composition.
delete delete The method according to claim 1,
Wherein the modified hydrophilic powder is modified with silica, glycerin, or disodium carboxy ethyl capricilate, wherein the water-drop solid type water-in-oil type cosmetic composition comprises:
The method according to claim 1,
Wherein the water-receiving portion is selected from the group consisting of polyglycerin, glycerin, propylene glycol, butylene glycol, sorbitol, trehalose, erythritol, xylitol maltitol, polyethylene glycol, mannan, carrageenan, chondroitin, hyaluronic acid, sodium hyaluronate, collagen, panthenol, Or a water-drop solid type water-in-oil type cosmetic composition containing a powder containing a fermented product.
Heating the emulsifier, the emulsifying aid, the oil and the solidifying agent to a temperature of 60 to 80 ° C, adding the modified and ground lipophilic powder to produce an oily phase;
Preparing a water phase by heating the mixture of purified water, a humectant and an additive at 60 to 80 캜, adding the modified and ground hydrophilic powder, and dispersing and mixing the mixture;
Emulsifying the water phase part at 3,000 to 3,500 rpm for 5 to 30 minutes to the oil phase part; And
Degassing and filtering at 65 to 75 &lt; 0 &gt; C,
The lipophilic powder is contained in an amount of 10 to 50% by weight of the total weight of the oil phase,
Wherein the hydrophilic powder comprises 0.01 to 10% by weight of the total weight of the aqueous phase.
delete
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