KR101677069B1 - 통합된 부탄 이성질체화 및 이온성 액체 촉매화된 알킬화 공정들 - Google Patents

통합된 부탄 이성질체화 및 이온성 액체 촉매화된 알킬화 공정들 Download PDF

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KR101677069B1
KR101677069B1 KR1020147008039A KR20147008039A KR101677069B1 KR 101677069 B1 KR101677069 B1 KR 101677069B1 KR 1020147008039 A KR1020147008039 A KR 1020147008039A KR 20147008039 A KR20147008039 A KR 20147008039A KR 101677069 B1 KR101677069 B1 KR 101677069B1
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ionic liquid
isomerization
butane
alkylation
isobutane
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KR1020147008039A
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Korean (ko)
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KR20140070567A (ko
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혜경 조 팀켄
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셰브런 유.에스.에이.인크.
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    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10GCRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G35/00Reforming naphtha
    • C10G35/04Catalytic reforming
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C5/00Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
    • C07C5/32Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by dehydrogenation with formation of free hydrogen
    • C07C5/373Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by dehydrogenation with formation of free hydrogen with simultaneous isomerisation
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J19/00Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J19/24Stationary reactors without moving elements inside
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2/00Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
    • C07C2/54Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition of unsaturated hydrocarbons to saturated hydrocarbons or to hydrocarbons containing a six-membered aromatic ring with no unsaturation outside the aromatic ring
    • C07C2/56Addition to acyclic hydrocarbons
    • C07C2/58Catalytic processes
    • C07C2/60Catalytic processes with halides
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C5/00Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
    • C07C5/22Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by isomerisation
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C5/00Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
    • C07C5/22Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by isomerisation
    • C07C5/27Rearrangement of carbon atoms in the hydrocarbon skeleton
    • C07C5/2767Changing the number of side-chains
    • C07C5/277Catalytic processes
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C5/00Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
    • C07C5/32Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by dehydrogenation with formation of free hydrogen
    • C07C5/327Formation of non-aromatic carbon-to-carbon double bonds only
    • C07C5/333Catalytic processes
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C9/00Aliphatic saturated hydrocarbons
    • C07C9/02Aliphatic saturated hydrocarbons with one to four carbon atoms
    • C07C9/10Aliphatic saturated hydrocarbons with one to four carbon atoms with four carbon atoms
    • C07C9/12Iso-butane
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C9/00Aliphatic saturated hydrocarbons
    • C07C9/14Aliphatic saturated hydrocarbons with five to fifteen carbon atoms
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C9/00Aliphatic saturated hydrocarbons
    • C07C9/22Aliphatic saturated hydrocarbons with more than fifteen carbon atoms
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10GCRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G29/00Refining of hydrocarbon oils, in the absence of hydrogen, with other chemicals
    • C10G29/20Organic compounds not containing metal atoms
    • C10G29/205Organic compounds not containing metal atoms by reaction with hydrocarbons added to the hydrocarbon oil
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2527/00Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • C07C2527/06Halogens; Compounds thereof
    • C07C2527/125Compounds comprising a halogen and scandium, yttrium, aluminium, gallium, indium or thallium

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Engineering & Computer Science (AREA)
  • General Chemical & Material Sciences (AREA)
  • Materials Engineering (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
KR1020147008039A 2011-09-12 2012-03-29 통합된 부탄 이성질체화 및 이온성 액체 촉매화된 알킬화 공정들 KR101677069B1 (ko)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US13/230,757 US8728301B2 (en) 2011-09-12 2011-09-12 Integrated butane isomerization and ionic liquid catalyzed alkylation processes
US13/230,757 2011-09-12
PCT/US2012/031165 WO2013039566A1 (en) 2011-09-12 2012-03-29 Integrated butane isomerization and ionic liquid catalyzed alkylation processes

Publications (2)

Publication Number Publication Date
KR20140070567A KR20140070567A (ko) 2014-06-10
KR101677069B1 true KR101677069B1 (ko) 2016-11-18

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KR1020147008039A KR101677069B1 (ko) 2011-09-12 2012-03-29 통합된 부탄 이성질체화 및 이온성 액체 촉매화된 알킬화 공정들

Country Status (11)

Country Link
US (1) US8728301B2 (de)
KR (1) KR101677069B1 (de)
CN (1) CN103781747B (de)
AU (1) AU2012309138B2 (de)
BR (1) BR112014005426B1 (de)
CA (1) CA2848073C (de)
DE (1) DE112012003790T5 (de)
GB (1) GB2508535B (de)
MY (1) MY163317A (de)
SG (1) SG11201400584PA (de)
WO (1) WO2013039566A1 (de)

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US9096480B2 (en) 2013-06-28 2015-08-04 Uop Llc Catalytic disproportionation of heptane using ionic liquids
US9102578B2 (en) 2013-06-28 2015-08-11 Uop Llc Catalytic isomerization of paraffins using ionic liquids
US9096485B2 (en) 2013-06-28 2015-08-04 Uop Llc Catalytic isomerization of heptane using ionic liquids
US9126881B2 (en) 2013-06-28 2015-09-08 Uop Llc Catalytic isomerization of pentane using ionic liquids
US9102577B2 (en) 2013-06-28 2015-08-11 Uop Llc Catalytic disproportionation of paraffins using ionic liquids
US20150005554A1 (en) 2013-06-28 2015-01-01 Uop Llc Catalytic isomerization of butane using ionic liquids
US9096483B2 (en) 2013-06-28 2015-08-04 Uop Llc Catalytic isomerization of hexanes using ionic liquids
US9096482B2 (en) 2013-06-28 2015-08-04 Uop Llc Catalytic reverse disproportionation of paraffins using ionic liquids
US9096481B2 (en) 2013-06-28 2015-08-04 Uop Llc Catalytic disproportionation of pentane using ionic liquids
RU2017132466A (ru) 2015-02-19 2019-03-19 Сабик Глобал Текнолоджиз Б.В. Системы и способы, связанные с производством метил-трет-бутилового эфира
RU2017134101A (ru) 2015-03-05 2019-04-05 Сабик Глобал Текнолоджиз Б.В. Системы и способы, связанные с получением этиленоксида, этиленгликоля и/или этаноламинов
US20170007993A1 (en) * 2015-07-08 2017-01-12 Chevron U.S.A. Inc. Sulfur-contaminated ionic liquid catalyzed alklyation
US10384988B2 (en) * 2015-12-23 2019-08-20 Uop Llc Chloride management in ionic liquid alkylation processes
CN106927989B (zh) * 2017-03-07 2021-05-07 惠州宇新化工有限责任公司 一种提高烷基化反应效率及降低产物分离能耗的工艺方法
US10301233B2 (en) * 2017-07-03 2019-05-28 Chevron U.S.A. Inc. Natural gas liquid upgrading by ionic liquid catalyzed alkylation
CN107573964A (zh) * 2017-10-13 2018-01-12 北京赛诺时飞石化科技有限公司 一种正构烷烃低温异构化方法及装置
CN108273551A (zh) * 2018-01-17 2018-07-13 福州大学 一种固载型轻质烷烃异构化催化剂及其制备和应用
US10815166B2 (en) * 2018-06-28 2020-10-27 Uop Llc Integration of an organic chloride decomposition reactor on the isomerization/deisobutanizer C5 drag stream
US10995045B2 (en) 2018-10-09 2021-05-04 Uop Llc Isomerization zone in alkylate complex
CN115608414B (zh) * 2021-07-16 2024-01-26 天津大学 负载型离子液体纳米金属催化剂及其制备方法和应用
CN115181585B (zh) * 2022-08-09 2023-11-07 中国石油大学(北京) 基于离子液体催化的烷烃异构化方法
WO2024107648A1 (en) * 2022-11-18 2024-05-23 Uop Llc Processes and apparatuses for separating chlorides from n-butane

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US4341911A (en) * 1980-12-29 1982-07-27 Uop Inc. Hydrocarbon conversion process for the production of gasoline
FR2802919B1 (fr) * 1999-12-23 2002-05-03 Total Raffinage Distribution Procede et dispositif pour l'alkylation de l'isobutane par des olefines legeres
US7432408B2 (en) * 2004-12-21 2008-10-07 Chevron U.S.A. Inc. Integrated alkylation process using ionic liquid catalysts
US7572943B2 (en) 2005-12-20 2009-08-11 Chevron U.S.A. Inc. Alkylation of oligomers to make superior lubricant or fuel blendstock
US7569740B2 (en) * 2005-12-20 2009-08-04 Chevron U.S.A. Inc. Alkylation of olefins with isoparaffins in ionic liquid to make lubricant or fuel blendstock
US7553999B2 (en) * 2006-12-14 2009-06-30 Chevron U.S.A. Inc. Isomerization of butene in the ionic liquid-catalyzed alkylation of light isoparaffins and olefins
US7439410B1 (en) * 2007-03-30 2008-10-21 Uop Llc Integrated alkylation-isomerization process
US8183425B2 (en) * 2007-12-28 2012-05-22 Chevron U.S.A. Inc. Ionic liquid catalyst alkylation using split reactant streams
US7923593B2 (en) * 2008-07-31 2011-04-12 Chevron U.S.A. Inc. Process for producing a middle distillate

Also Published As

Publication number Publication date
US8728301B2 (en) 2014-05-20
CA2848073C (en) 2016-10-11
GB2508535B (en) 2016-12-28
CA2848073A1 (en) 2013-03-21
US20130062253A1 (en) 2013-03-14
GB2508535A (en) 2014-06-04
GB201402707D0 (en) 2014-04-02
CN103781747B (zh) 2016-03-02
CN103781747A (zh) 2014-05-07
MY163317A (en) 2017-09-15
BR112014005426A2 (pt) 2017-03-28
WO2013039566A1 (en) 2013-03-21
AU2012309138A1 (en) 2014-03-06
AU2012309138B2 (en) 2016-02-04
SG11201400584PA (en) 2014-09-26
DE112012003790T5 (de) 2014-07-31
KR20140070567A (ko) 2014-06-10
BR112014005426B1 (pt) 2019-07-16

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