KR101525582B1 - Novel antibacterial compositions for hood meat - Google Patents

Abstract

The present invention relates to a composition of a cleaning agent for edible meat which has an antibacterial effect and a deodorization effect, and which is used for washing equipment such as a knife, a cutting saw, and the like, or utensil such as a knife, a cutting board, and the like used for processing raw meat or raw fish in order to prevent infection of microorganisms or contaminants. A manufacturing method of the cleaning agent for edible meat comprises the steps of: plasticizing zeolite at a temperature of 800 to 1,100°C and crushing the plasticized zeolite to pass through a sieve having 250 to 300 meshes and to obtain refined zeolite powders as first raw materials; plasticizing shells at a temperature of 900 to 1,200°C and crushing the plasticized shells to pass through a sieve having 250 to 300 meshes and to obtain refined calcium oxide powders as second raw materials; melting citric acid in purified water which is obtained by passing clean water through granite rock formation within a range of 1 to 3 wt% based on purified water so as to prepare cleaning water; putting the zeolite powders, which are the purified, first raw materials, into the cleaning water within a range of 1 to 3 wt% to obtain a cleaning water raw material; and melting the calcium oxide powders, which are the second raw materials, within a range of 0.1 to 0.3 wt% based on the cleaning water raw material while injecting CO_2 into the cleaning water raw material, and filtering the same to obtain a cleaning composition.

Description

Technical Field [0001] The present invention relates to a cleaning agent for edible meat provided in the form of raw meat and fresh meat,

The present invention relates to an apparatus and a method for preventing the transmission of microorganisms or contaminants in handling knives or cutting saws used for the handling of raw meat of raw meat, To a detergent composition for edible meat having an antibacterial and deodorizing function, which is used for cleaning purposes.

More particularly, the present invention relates to an antimicrobial agent having excellent antibacterial activity against Escherichia coli, Staphylococcus aureus, Pseudomonas aeruginosa, Candida albicans and the like, , A hydrogen sulfide and a mercaptan system, and has good formulation stability at low temperature and high temperature preservation.

Further, the present invention can be provided as a liquid detergent composition, and more particularly, it can be provided as a liquid detergent composition, and more particularly, to provide a liquid detergent composition which can be produced by using an environmentally friendly raw material which has undergone physical processing only on a natural product without causing a chemical reaction or using a chemical agent obtained by a chemical process The present invention relates to a kitchen detergent composition having enhanced detergency without stimulation and enhanced antibacterial and deodorizing power.

Generally, Rox, a chlorine-based disinfectant, is a typical product used for antibacterial and deodorization purposes in a butcher or a fish processing factory. Lox is an antimicrobial and deodorizing effect by oxygen generated from hypochlorous acid (HClO) , It exhibits a strong antibacterial ability. However, because of the toxicity of chlorine gas generated during use, it gives unpleasant feeling to the users and anxiety about human safety. Therefore, they are reluctant to use in kitchens of ordinary households, have.

Also, kitchen cleaners such as pomphong are mainly provided with a composition comprising a surfactant, a cleaning aid, a chemical active ingredient, an aroma, etc. Among these cleaning agent components, those having cleaning performance and foaming property are mainly surfactants, Surfactants are widely used.

However, the main cause of kitchen pollution sources is that when an oil pollution and stain of oil pollution source, the anion surfactant generally does not exhibit a sufficient removal effect. Especially, after the cooking of meat such as fish or pork chicken beef, There is no countermeasure against the propagation of many kinds of bacteria due to the water remaining in the food preparation and dishwashing due to the lack of response, and the basic ammonia and the amine compounds such as trimethylamine, acidic hydrogen sulfide, And mercury compounds such as methyl mercaptan evolved into a conventional kitchen cleaning agent.

Various methods have been used for obtaining the deodorizing effect in the conventional kitchen detergent, and chemical methods such as neutralization, addition, polymerization, oxidation reduction and hydrolysis are used for the antibacterial and odor components As a method of decomposing antimicrobial and odorous substances by acting a strongly reactive substance or converting them into odorless compounds, a method of obtaining an antibacterial effect and removing odorous substances has been used. As the physicochemical removal methods, activated carbon, silica, It is possible to adsorb or collect antibacterial and odorous components on the surface by using a compound having high adsorption and collection performance such as dextrin or to absorb it by using a high boiling point solvent or a surfactant or to use liquid paraffin, A method of removing antimicrobial and odorous substances has been used.

In addition, as a biochemical removal method, a method of blocking the generation of bad odor components by bacteria by a sterilizing action by a positive surfactant, a sterilizing agent and the like, or by decomposing an organic acid as a malodorous component by using digestive enzymes, bacteria, And a basic compound such as ammonia, an amine, an acid, an alcohol, an aldehyde, a ketone, a phenol, an indole, an aromatic and a polyaromatic or a sulfated compound such as a thiol, a mercaptan and a sulfide However, until now, the technology applied to the antibacterial and deodorizing has been mainly focused on the means of masking that the odor is prevented from being expressed by using the fragrance.

In view of the technology disclosed in the related patent application related to cleaning agents having antimicrobial purposes in the processing of food, Patent Application Publication No. 200675756 discloses an organic material such as processed meat, fruits and vegetables, vegetable parts, a non-living surface such as fabric and stainless steel , And products and methods for reducing microbial contamination in oral or dental products. The present invention relates to antibacterial lipids and bacteriocins, antibacterial enzymes, sugars, sugar alcohols, Discloses a method of sterilizing the surface of food using an antimicrobial composition containing an enhancer, and optionally a surfactant, selected from the group consisting of derivatives, siderophores, and combinations thereof.

In addition, as disclosed in Japanese Patent Laid-Open Publication No. 014982, a combination of a surfactant and a plurality of acids as antimicrobial compositions provides a synergistic effect over the antimicrobial effect of each compound, As an application of a technique that allows the preparation of a composition that reduces the number of bacteria on the surface of a food material without altering the sensory properties of the food, the active agent is provided comprising an FDA approved food additive, a surfactant, and an acid, And a food material is selected and applied from among poultry, eggs, fish, seafood, meat or fruits or vegetables.

We use nature-friendly raw materials that have been subjected to physical processing to natural natural products without using chemical agents obtained through chemical reaction or artificial process, ensuring high washing power without skin irritation and toxicity, and having antibacterial and deodorizing power This invention was initiated with a task to obtain a detergent composition for an enhanced edible meat.

The present invention relates to cutting machines, knives and the like which are used directly for food processing of fish such as cattle, pigs, poultry, etc. or for processing fish, or for meat processing or fish processing And to provide a detergent composition for edible meat that is used for preventing transmission of microorganisms or contaminants to processing vessels or apparatuses of processed meat or fish or handling containers or gloves of fishes.

The purpose of the present invention is to provide a processing apparatus and apparatus such as a cutting machine and a knife used for meat processing of an animal such as a cattle or a pig which is edible by a human being or a seafood processing of a fresh fish, The zeolite is calcined and pulverized in the range of 800 to 1100 ° C as a means for preventing the transmission of microorganisms or contaminants, and is passed through a sieve of 250 to 300 mesh to obtain purified zeolite powder as a first raw material,

The shellfish is calcined in the range of 900 to 1200 DEG C, pulverized and passed through a sieve of 250 to 300 mesh to obtain fine powder of calcium oxide as a second raw material,

After washing water was prepared by dissolving citric acid in a range of 1 to 3 wt% based on purified water on purified water obtained by passing clean water through a granite porphyry layer, a range of 3 to 5 wt% of zeolite powder as a first raw material refined was added to the washing water, Wherein the second raw material calcium oxide powder is contained in an amount of 0.1 to 0.3 wt% based on the number of raw materials of the cleaning liquid while CO ₂ is injected into the raw material liquid of the rinse liquid to obtain a rinse liquid raw material water having an oxidation-reduction potential (ORP) (Ca (HCO ₃ ) ₂ ] is obtained because it is melted and filtered in a range of from 0.1 to 5 wt.%, So that the cleaning composition can be used as a microorganism in a knife used for meat processing or fish processing, And confirming the characteristics preventing the transmission of contaminants.

The zeolite used as the first raw material herein constitutes a network such as a ring and a polyhedron and forms a gap in the network unit having a diameter of about 2 to 8 Å (onstroem) In this study, it is aimed to investigate the feasibility of reversible dehydration and ion exchange with ion and water molecules, (ORP) in the range of from -5 to -30 in a stabilized range by adding a zeolite powder in a range of 3 to 5 wt% to the purified water and sterilizing the cleaning water containing a small amount of citric acid in a rich amount of purified water, And to provide an effect of increasing the deodorizing power in the final cleaning composition.

The calcined shell powder used as the second raw material herein is prepared by calcining the shellfish at a high temperature (900 to 1200 ° C) for a certain period of time and finely pulverizing (300 meshes) the calcined shell powder. When the calcined shell powder is dissolved in water, pH range 11 to 13) and has high antimicrobial activity and is used as a means for securing bactericidal performance to prevent the propagation of bacteria.

In addition, clean water is passed through granite porphyry layer to obtain purified water containing minerals richly. Granite porphyry is similar to granite in mineral composition and chemical composition, but has a large amount of quartz and quartzite The granite porphyry is characterized by the fact that the size of the granite is less than 1mm. In this study, the granite porphyry was supplied with clean water and purified water The amount of the stabilized cleaning liquid raw material in which the oxidation-reduction potential (ORP) is provided in the range of -5 to -30 by adding the zeolite powder in the range of 3 to 5 wt% is used as the purified and sterilized rinse solution water by adding a small amount of citric acid .

In the present invention, the raw material water of the cleaning liquid is similar to a portion to obtain a kind of hydrogen-reduced water and uses, for example, a water purifier for obtaining hydrogen-reduced water disclosed in Japanese Patent No. 907911 or a hydrogen- In the present invention, it is possible to use the granular porphyry layer as a catalyst layer by using natural mineral rather than electrolysis as a raw material water of a washing solution having a hydrogen reduction characteristic.

In the present invention, a small amount of CO ₂ is slightly added to the washing liquid raw water obtained through the above process, while the second raw material, the calcined shell powder, is dissolved in the range of 0.1 to 0.3 wt% with respect to the washing liquid raw material water and filtered to discard the residue, To obtain a cleaning composition containing calcium hydrogen carbonate [Ca (HCO ₃ ) ₂ ].

In the present invention, the calcium oxide powder obtained from the calcined shell powder as the second raw material absorbs CO ₂ in the atmosphere to become calcium carbonate (CaCO ₃ ), and calcium carbonate (CaCO ₃ ) does not easily dissolve in water. When a small amount of CO ₂ is slightly added to the washing liquid of the nature and the second raw material, the calcined shell powder, is dissolved in the range of 0.1 to 0.3 wt% with respect to the hydrogen reduced water, it is changed into the ion of HCO 3 ^- And can be provided as a detergent composition for edible meat that stably exhibits antibacterial and bactericidal properties.

DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENTS Hereinafter, preferred embodiments of the present invention will be described in detail with reference to the accompanying drawings.

The detergent composition for edible meat provided in the present invention is provided by using a natural-friendly raw material that has undergone only a physical processing process on a natural natural product without using a chemical agent obtained through a chemical reaction or an artificial process, The present invention has an effect of providing a detergent composition for meat having a high detergency without toxicity and high antimicrobial activity and deodorizing power without a serious risk when a small amount of food is consumed by, for example, a kitchen worker or a young child.

The detergent composition for edible meat provided in the present invention is used as meat cleansing agent in the meat processing process of meat, pork, poultry, etc. edited by people or in cutting It is a cleaning solution for a device or a knife. It can be used for various applications such as cutting machines, knives, etc. used for processing fish or fresh seafood, or for transporting microorganisms or contaminated microorganisms And has the effect of providing a biostable detergent composition.

Before describing the embodiments of the invention for implementing the technical idea of the present application, the terms or words used in the specification or claims of the present application should not be construed as limited to ordinary or dictionary terms, The scope of protection of the present invention should be construed in accordance with the technical idea of the present invention and the examples described in this specification are only the most preferred embodiments of the present invention and do not represent all the technical ideas of the present invention , It is to be understood that various equivalents and modifications may be substituted for those at the time of the present application.

In addition, the embodiments described below describe the best modes that have been found through numerous trial errors, and the ranges indicating the upper and lower limits of the numerical values are intended to achieve the purpose desired by the inventor when the upper and lower limits of the numerical values are exceeded It should be recognized that it is a fixed number.

Preparation Example of Raw Material for Cleaning Solution Preparation

First, fine zeolite ore was pulverized and put into a firing furnace maintaining a temperature of about 900 ± 50 ° C., and fired for 3 hours to remove impurities, followed by crushing with a ball mill, and then crushed into a 250 mesh sieve to obtain zeolite powder , And the cleaned oblique shell having removed the foreign substances such as seaweed was put into a pulverizer and pulverized to a size of about 10 to 20 mm and put into a firing furnace maintaining a temperature of about 900 賊 50 캜, The impurities were removed by firing, the mixture was crushed with a ball mill, and then squeezed with a 250-mesh sieve to obtain a calcined shell powder refined with a second raw material to prepare a second raw material.

In the present invention, the iridium porphyryite is pulverized to a size of about 10 to 30 mm by means of a means for obtaining a rinse solution raw material having a hydrogen-reduced water characteristic, and the calcined raw material is put into a firing furnace maintaining a temperature of about 400 ± 50 ° C., The structure is such that the round porcelain raw material cooled at room temperature is filled in a chamber type filter medium layer (height * diameter = 100 * 50 cm) and purified water is injected from the lower part of the chamber to overflow the purified water upward through the filter medium layer Min of granular porphyry treatment water was applied to the experiment. The granular porphyritic treatment water was divided into a number of small granules and tested. For example, in Example 1, 9.48 kg of granite porphyry treated water was mixed with 400 gr of zeolite citric acid 100gr was added, and after dissolving, 20gr of fired shell powder was injected at the bottom of the reaction vessel so as to inject CO ₂ gas in units of drops intermittently using a tweezers structure to prepare a detergent composition (Example 1) for edible meat, In the same manner, the detergent compositions of Examples 2 and 3 were prepared. In Comparative Example 1, zeolite was not used. In Comparative Example 2, the samples were applied in a state without using the shell firing powder. To evaluate the detergency, skin irritation, antibacterial activity, and deodorizing ability, the results are shown in Table 1.

 division  Example 1   Example 1   Example 1   Comparative Example 1   Comparative Example 2



Raw materials used



Zeolite  4  3  5  0  4 Citric acid  One  One  One  One  One Shell powder  0.2  0.2  0.2  0.2 Granite porphyry
Treated water  94.8  95.8  93.8  98.8  95.0 CO ₂ Intermittently CO ₂ gas using a tweezers structure in the tank bottom
Injection of firing shell powder is applied while injecting in droplets.  Sum  100  100  100  100  100
Experiment result
 Cleaning rate (%)  ◎  ◎  ◎  △  ○  Skin irritation  radish  radish  radish  radish  radish  Antibacterial activity  ◎  ◎  ◎  ◎  △

(1) Cleaning rate evaluation test

As a method for measuring the detergency against oil pollution, a pollutant mainly composed of tallow and soybean oil was prepared and uniformly coated on a stainless steel plate, followed by natural drying at room temperature for 12 hours, The contaminated specimens were immersed for 2 minutes in a container containing 30 ml of the cleaning liquids of Examples 1 and 2 and Comparative Examples 1 and 2, washed with an ultrasonic washing machine for 5 minutes, washed with water using a sprayer, dried naturally at room temperature for 24 hours, The contents were repeated 5 times and the average value was determined as the cleaning rate (%). The results are shown in Table 1 below.

The criterion of judgment is ⊚ for a cleaning rate of 90% or more, ∘ for a cleaning rate of 70% or more and less than 90%, and △ for a cleaning rate of 50% or more and less than 70% Respectively.

(2) skin irritation evaluation test

Thirty male and female adults were selected as subjects to be tested and the patches of the rinsing liquid obtained in Examples 1 to 3 and Comparative Examples 1 and 2 were applied to the upper side of the subject. After 24 hours, the rats were removed and the rubella and edema The first stimulus was determined according to the judgment criteria, the second stimulus was judged after 24 hours of removal of the patch, the results were judged based on the formula for calculating the skin averaged response, and classified according to the criteria shown in Table 2, Respectively.

 Display criteria  Symptoms (erythema and edema)  score  -  no response  No erythema  0  ±  Positive  Faint erythema  0.5  +  Mildly positive  Weak erythema  One  ++  Weak positive  Distinct erythema, pus  2  +++  Strong positive  Algebra  3

 Average skin response  Criteria  0.0 ~ 0.9  No stimulation  1.0 to 2.9  Light stimulus  3.0 ~ 4.9  Moderate irritation  5.0 or higher  River stimulation

(3) Evaluation of antibacterial activity

The antibacterial activity of the detergent compositions obtained in Examples 1 to 3 and Comparative Example 1 to 2 was evaluated in the following manner.

A representative test bacterium that can be generated in a residential environment was selected and applied as shown in Table 4, and a solution prepared by diluting the initial number of bacteria to 10 ⁶ cfu / ml was inoculated into a cleaning agent and cultured at 35 ° C for 24 hours. And evaluated according to the criteria shown in Table 5.

 division  Contents
Test bacteria

 bacteria  East  Pseudomonas aeruginosa (ATCC 17759)  Kandada albicans (ATCC 11006)  Escherichia coli (ATCC 8739)  Staphylococcus (ATCC 25923)

 Evaluation results  Very good (◎)  Excellent (O)  Usually (△)  Bad (×)  Amount of microorganism 10 ³ 10 ⁴ 10 ⁵ 10 ⁶

The composition ratios of the raw materials shown in Table 1 are shown by selecting optimal application examples in the process of experiencing a lot of trial errors. As can be seen from the results of the bottom experiments of Examples 1 to 3, Is prepared and calcined at a high temperature to prepare a first raw material. The shell material is calcined and ground at a high temperature to prepare a second raw material. Then, citric acid is dissolved in purified water obtained by passing through a granite porphyry layer to prepare a washing liquid water. Then, zeolite The cleaning agent composition obtained by dissolving the calcined shell powder as the second raw material in the range of 0.1 to 0.3 wt% while obtaining the raw material water of the cleaning liquid by adding the powder to a certain range and injecting CO ₂ into the washing liquid raw water in a minute amount is excellent in washing rate as well as stability against skin irritation And also Escherichia coli, Staphylococcus aureus, Pseudomonas aeruginosa, eruginosa, Candida albicans, and the like.

However, in the test results of Comparative Examples 1 and 2, which are beyond the scope of the present invention, it is confirmed that the washing rate is lowered and the antimicrobial activity is inferior. In the skin irritation portion, all the raw materials used in the present invention are applied as natural products, It is an opinion that is a natural consequence.

(4) Evaluation of deodorizing power

In general, the deodorizing power for the compositions of Examples 1 to 3 and Comparative Examples 1 and 2 was measured by using a detector tube after 24 hours for a constant concentration of four odors of ammonia, trimethylamine, methylmercaptan and hydrogen sulfide, The standard concentration of the odor source is 120 ppm of ammonia, 60 ppm of trimethylamine, 20 ppm of methyl mercaptan, and 79 ppm of hydrogen sulfide. The results are shown in Table 6.

sample
 Dechucking rate (%)  ammonia  Trimethylamine  Methylmercaptan  Hydrogen sulfide  Example 1  98  97  78  62  Example 2  97  97  76  65  Example 3  97  96  77  64  Comparative Example 1  65  62  54  45  Comparative Example 2  88  86  69  53

As can be seen from Table 6, the cleaning compositions of Examples 1 to 3, to which the technical idea of the present application was applied, had higher ammonia, amine, hydrogen sulfide and mercapto And it showed high deodorizing effect.

Therefore, the detergent for edible meat, which is provided as a technical idea of the present invention, can be used as a detergent to be sprayed on the meat itself during the meat processing or to be used as a cutting device Knife washing liquids are used for processing food such as cutting machines and knives used for food processing such as meat processed fish products such as eggs and seafood, It is an invention that can be used in fields where it is desired to secure antibacterial activity for various uses for preventing transmission of microorganisms and contaminants to containers containing meat.

Claims (3)

A method for producing a detergent for edible meat, which is provided in the form of raw meat (fresh meat) and fish (fresh meat)
Calcining the zeolite at a temperature in the range of 800 to 1100 ° C, grinding it, passing it through a sieve of 250 to 300 mesh to obtain purified zeolite powder;
A second step of calcining and crushing the shellfish at a temperature in the range of 900 to 1200 ° C. and passing the powder through a sieve of 250 to 300 mesh to obtain a calcium oxide powder to obtain a fine powder;
A third step in which purified water is prepared by dissolving citric acid in a range of 1 to 3 wt% based on purified water on purified water obtained by passing clean water through a granite porphyry layer;
A fourth step of adding the zeolite powder obtained in the first step to the washing water having been subjected to the third step in the range of 3 to 5 wt% to obtain the raw material water of the washing liquid;
Wherein a cleaning composition is obtained by dissolving calcium oxide powder obtained through the second step in a range of 0.1 to 0.3 wt% based on the number of raw materials of the cleaning liquid while injecting a small amount of CO ₂ into the washing liquid raw water obtained through the fourth step, A method for producing a detergent composition for edible meat. 1. A detergent for edible meat, which is provided in the form of raw meat (fresh meat) and fish (fresh meat)
The zeolite is calcined in the range of 800 to 1100 DEG C, pulverized and passed through a sieve of 250 to 300 mesh to obtain purified zeolite powder as a first raw material
The shellfish is calcined in the range of 900 to 1200 DEG C, pulverized and passed through a sieve of 250 to 300 mesh to obtain fine powder of calcium oxide as a second raw material,
Purified water is passed through granite porphyry layer, and purified water is prepared by dissolving citric acid in a range of 1 to 3 wt% on the basis of purified water,
3 to 5 wt% of zeolite powder as a refining raw material is added to the washing liquid water to obtain a washing liquid raw water, and while the CO ₂ is injected into the washing liquid raw water, the calcium oxide powder as the second raw material is added in an amount of 0.1 to 0.3 wt%, and is filtered to provide the cleaning composition as a cleaning composition for edible meat. A method of using an edible meat cleaner provided in the form of raw meat and fresh meat,
Calcining the zeolite at a temperature in the range of 800 to 1100 ° C, grinding it, passing it through a sieve of 250 to 300 mesh to obtain purified zeolite powder;
A second step of calcining and crushing the shellfish at a temperature in the range of 900 to 1200 ° C. and passing the powder through a sieve of 250 to 300 mesh to obtain a calcium oxide powder to obtain a fine powder;
A third step in which purified water is prepared by dissolving citric acid in a range of 1 to 3 wt% based on purified water on purified water obtained by passing clean water through a granite porphyry layer;
A fourth step of adding the zeolite powder obtained in the first step to the washing water having been subjected to the third step in the range of 3 to 5 wt% to obtain the raw material water of the washing liquid;
Wherein the gain cleaning compositions by filtration and dissolved calcium oxide powder obtained after the second step, while the small amount of CO ₂ injected in the washing liquid compared to the raw material can be in the range of 0.1 ~ 0.3wt% cleaning liquid raw material obtained through step 4 this meat or fish (Fresh), or used as a cleansing agent for a device or a handling container.