KR101398008B1 - A hair-dyeing composition keeping stable foaming form - Google Patents

Abstract

The present invention relates to a hair dye composition which maintains a stable foam form.
The hair dye composition of the present invention comprises a composition of an oxidative type hair dye preparation 1 and a composition of an oxidative type hair dye preparation 2,
The oxidation-type hair dye preparation composition of claim 1,
(a-1) a nonionic surfactant composed of polyoxyethylene lauryl ether, polyoxyethylene alkyl ether and C8-C16 alkyl glucoside;
(a-2) at least one alkoxylate alcohol selected from the group consisting of PEG-4, PEG-6 and PEG-8; And
(a-3) at least one amino acid surfactant selected from the group consisting of potassium cocoyl glutamate, potassium cocoyl glycinate and potassium N-cocoyl-L-glutamate.

Description

[0001] The present invention relates to a hair-dyeing composition containing a stable foaming composition,

The present invention relates to an oxidative dyeing composition comprising an anionic surfactant, a nonionic surfactant, a cationic surfactant, a chelating agent, an antioxidant, an oxidation dye, an alkaline agent and purified water.

More particularly, the present invention relates to an oxidation type hair dye composition capable of easily dyeing by itself. The present invention is an oxidation type hair dye composition which can be easily dyed by itself, and can be produced by removing the conventional hair dye of cream or lotion form and bubbling it to stably attach to hair for 20 to 30 minutes or more, The present invention also relates to a hair dye composition which is stable in shape and easy to apply hair without the help of others.

In general, a hair dye can be distinguished as a temporary hair dye, a semi-permanent hair dye, or a permanent hair dye depending on the durability and durability of the hair color. Among these, permanent hair dyeing agents include oxidation dyeing agents, metal hair dyeing agents, and vegetable hair dyeing agents depending on dyes used. Most of hair dyeing agents currently used are oxidation dyeing agents using oxidation dye precursors and oxidation dyes such as amino compounds.

Conventional oxidative hair dyeing agents have been used for a long time because they are stable in emulsifying various useful ingredient materials and oily materials as well as being good in hair adhesion as formulations of 1 agent (hair dyeing agent) and 2 agent (oxidizing agent). However, in the case of such formulations, brushes are generally applied to the hair evenly, but the portion not coated on the hair, that is, the portion which is not well-combed, is not dyed and it is troublesome to apply it thoroughly. In addition, the less experienced general users are not able to apply precisely, and it takes a long time, so that there is a difference in the application time and thus the degree of dyeing of the first applied portion and the last applied portion also varies.

As described above, the mixed cream of 1 or 2 has some limitations and inconvenience for the user to apply the cream uniformly to the hair, and the use amount of the cream mixed with the unit volume of the hair is also high.

In order to overcome this disadvantage, a method of generating a mousse-like foam by charging LPG gas to the contents of the first and second ingredients was studied instead of the viscous cream or lotion formulation. It has the advantage that it can be easily controlled by itself because it is applied to the hair by hand without brushing. However, in the case of the gas-filled mousse type, there is a risk of gas charging, and the instability of bonding of the contents container and the mixing container for the first and second materials may cause the first and second materials to mix, It has a disadvantage that it is difficult to adjust the amount of the two.

SUMMARY OF THE INVENTION The present invention has been made under the above-mentioned circumstances, and an object of the present invention is to provide a hair-dyeing agent of a foam type for applying a foam produced by mixing a one- or two- The present invention is to provide a hair dye composition which is less time-consuming compared to a permanent hair dye and can dispense with imbalance in degree of dyeing due to a difference in dyeing time,

The hair dye composition for maintaining the stable foam form of the present invention comprises the composition of the oxidized type hair dye formulation 1 and the composition of the oxidized type hair dye formulation 2,

The oxidation-type hair dye preparation composition of claim 1,

(a-1) a nonionic surfactant composed of polyoxyethylene lauryl ether, polyoxyethylene alkyl ether and C8-C16 alkyl glucoside;

(a-2) at least one alkoxylate alcohol selected from the group consisting of PEG-4, PEG-6 and PEG-8; And

(a-3) at least one amino acid surfactant selected from the group consisting of potassium cocoyl glutamate, potassium cocoyl glycinate and potassium N-cocoyl-L-glutamate.

More specifically, in the present invention,

(a-1) a nonionic surfactant composed of polyoxyethylene lauryl ether, polyoxyethylene alkyl ether and C8-C16 alkyl glucoside;

(a-2) at least one alkoxylate alcohol selected from the group consisting of PEG-4, PEG-6 and PEG-8;

(a-3) at least one amino acid surfactant selected from the group consisting of potassium cocoyl glutamate, potassium cocoyl glycinate and potassium N-cocoyl-L-glutamate;

(a-4) at least one antioxidant selected from the group consisting of anhydrous sodium sulfite, ascorbic acid, and ammonium thioglycolate;

(a-5) tetrasodium dithiophosphate chelating agent;

(a-6) at least one compound selected from the group consisting of p-phenylenediamine, o-phenylenediamine, resorcinol, 2-methylenetrisinol, m-phenylenediamine, m- At least one oxidation dye selected from the group consisting of diamines, aminonitrophenols, diphenylamines, N-phenyldiamines, and diaminopyridines;

(a-7) at least one alkaline agent selected from the group consisting of monoethanolamine and ammonia water;

(a-8) at least one fatty alcohol selected from the group consisting of lauryl alcohol, myristyl alcohol, cetyl alcohol, stearyl alcohol and behenyl alcohol;

(a-9) set of at least one cationic surfactant selected from the group consisting of remium chloride, stearothermonium chloride and behen trimonium chloride;

(a-10) at least one moisturizing agent selected from the group consisting of glycerin, propylene glycol, butyleneglycol, dipropylene glycol and sorbitol; And

(a-11) purified water,

The oxidation-type hair dye preparation composition contains,

(b-1) at least one nonionic surfactant selected from the group consisting of polyoxyethylene lauryl ether, polyoxyethylene alkyl ether, and C8-C16 alkyl glucoside;

(b-2) at least one anionic surfactant selected from the group consisting of sodium lauryl sulfate, potassium lauryl sulfate, ammonium lauryl sulfate, sodium laureth sulfate, sodium laureth sulfate and ammonium laureth sulfate;

(b-3) at least one fatty alcohol selected from the group consisting of lauryl alcohol, myristyl alcohol, cetyl alcohol and stearyl alcohol;

(b-4) cellulose derivatives such as methylcellulose, hydroxyethylcellulose, hydroxyethylcellulose, carrageenan, carboxymethylcellulose, carboxymethylhydroxyguanine, cetearyl alcohol, stearic acid, polyquaternium- 10 and polyquaternium-22;

(b-5) at least one pH adjusting agent selected from the group consisting of phosphoric acid and sodium phosphate;

(b-6) at least one chelating agent selected from the group consisting of etidronic acid and disodium iditiyl;

(b-7) 35% aqueous hydrogen peroxide oxidant; And

(b-8) purified water.

At this time, the content of each component of the oxidative-type hair dye preparation composition and the oxidative-

The amount of the nonionic surfactant is preferably from 1.0 to 10.0% by weight, more preferably from 0.1 to 5.0% by weight of the alkoxylate alcohol, from 0.1 to 10.0% by weight of the amino acid surfactant, 0.1 to 1.0 wt% of an antioxidant, 0.05 to 0.5 wt% of a chelating agent, 0.1 to 8.0 wt% of an oxidation dye, 1.0 to 15.0 wt% of an alkali agent, 0.1 to 10.0 wt% of a fatty alcohol, 0.1 to 5.0 wt% of a cationic surfactant, 1.0 to 5.0% by weight and purified water 30.50 to 96.35% by weight,

In the case of the oxidative dyeing agent composition, it is preferable that 1.0 to 10.0% by weight of the nonionic surfactant (ratio with respect to the total amount of the hair dye preparation composition, hereinafter the same), 0.1 to 5.0% by weight of anionic surfactant, 0.1 to 1.0% 0.01 to 2.0 wt% of a pH adjusting agent, 0.05 to 0.5 wt% of a chelating agent, 8.0 to 17.0 wt% of an oxidizing agent, and 72.5 to 90.64 wt% of purified water.

In the present invention as described above, the first and second formulations are liquid. In order to maintain the clear liquid state by bubbling and solubilizing the components, a nonionic surfactant of polyoxyethylene lauryl ether and polyoxyethylene alkyl ether is added, and C8 to C16 alkyl glucoside The non-ionic surfactant is added as the main surfactant. Also PEG-4, PEG-6, PEG-8, etc. to impart moisturizing and foam densities to the hair, and to provide the hair with a thickening agent such as potassium cocoyl glutamate, potassium cocoyl glycinate, potassium N-cocoyl- Glutamate and the like are applied to secure hair moisturization, stability of foam, and transparency of formulation.

Since the oxidative type hair dyeing agent of the present invention stably adheres to the hair for more than 30 minutes by merely applying the bubbles generated when mixing the liquid 1 composition and the liquid 2 composition to the hair as if shampooing the hair, There is a convenient way to dye hair uniformly without needing a bar.

In addition, since the application time of the conventional lotion and cream formulations is significantly shortened compared to the hair application time of the hair dye formulation, shortening of the procedure time and the problem of hair staining due to the application time difference can be solved. And since it is easily washed out in water, cleaning time after dyeing is also shortened.

The present invention relates to a composition comprising a non-ionic surfactant, an anionic surfactant, an amino acid surfactant, an alkoxylate alcohol, an antioxidant, a chelating agent, an oxidizing dye, an alkaline agent, , a pH adjusting agent, and the like.

As described above, instead of the viscous cream or lotion formulation, a method of generating mousse-like foam by charging LPG gas into the contents of the first and second ingredients has been studied. However, in the case of a mousse type filled with gas, It is dangerous. For example, when a container is filled with a hair dye composition and a gas, when the container is broken during product transportation or storage, the contents and gas are discharged to the outside due to the pressure difference, so that the bottom, wall and other objects are discolored Corrosion may be caused by the oxidizing agent of the two components. In addition, although the first and second precursors must be mixed and discharged at an exact ratio, there is a problem in that, in the case of the gas-filled products, the first and second products are sometimes discharged only at a ratio of 1: 1.

The present invention relates to a cosmetic composition which is transparent in the form of a one-component composition and a two-component composition. The composition is poured into a mixing container immediately before use, and foam is generated using a dispenser to apply the composition to the hair. . In addition, the generated bubbles have the convenience of stably attaching to the hair during normal dyeing time (20 to 40 minutes) and not flowing down.

Further, considering that the hair application time is shortened to 1 to 3 minutes, and the conventional lotion and cream formulations take 5 to 30 minutes to apply to the hair, the shortening of the procedure time and the hair stain due to the difference in application time The problem can be solved and the washing time after dyeing is also possible because it is easily washed out in water.

In the case of the transparent dosage form composition of the present invention, the amount of the oily substance to be solubilized to help hair conditioning is generally limited and the stability of the formulation is lower than that of the cream formulation. As a result, As a material, it is not enough to give hair conditioning. So, hair may become stiff or rough after applying to hair, compared to lotion, cream formulations. To overcome this problem, the present invention applies an alkoxylate alcohol such as PEG-4, PEG-6 or PEG-8 to impart moisturizing properties to the hair, while using potassium cocoyl glutamate, potassium cocoyl glycinate, L-glutamate amino acid surfactant was applied to ensure hair moisturization, stability of foam, and transparency of formulation.

Hereinafter, preferred embodiments of the present invention will be described. However, it is to be understood that the invention is not limited to the disclosed embodiments.

[Example 1-1]

The following experiment was conducted on the composition for saline of the present invention.

0.4% by weight of resorcinol, 0.03% by weight of m-aminophenol, 0.7% by weight of toluene-2,5-diamine (toluene diamines), 0.35% by weight of p-aminophenol, 0.15% by weight of o- 0.1 wt% of tetrasodium dithiothreitol as a chelating agent, 0.4 wt% of anhydrous sodium sulfite and 0.4 wt% of ascorbic acid as antioxidants, 1.5 wt% of polyoxyethylene lauryl ether as a nonionic surfactant, 3.0% by weight of water, 3.0% by weight of dipropylene glycol as a moisturizing agent, 0.8% by weight of stearatrimonium chloride as a cationic surfactant, 0.5% by weight of myristyl alcohol as a fatty alcohol, 6.0% by weight of monoethanolamine as an alkaline agent, (Fig. 1). ≪ tb >< TABLE >

[Example # 1-2]

3.0 wt% of PEG-8 was added as the alkoxylate alcohol in # 1-1 above.

[Example # 1-3]

2.0% by weight of N-cocoyl-L-glutamate was added as the amino acid surfactant in # 1-1 above.

[Example # 1-4]

In # 1-1, 4.0 wt% of alkyl (C8-C16) glucoside was added as a nonionic surfactant.

[Example 1-5]

3.0% by weight of PEG-8 as the alkoxylate alcohol, 2.0% by weight of N-cocoyl-L-glutamate as the amino acid surfactant, and alkyl (C8 to C16) glucoside ) Was added.

[Example 2]

0.2% by weight of polyquaternium-10 as a thickening agent,

0.05% by weight of etidronionic acid as a chelating agent,

As a nonionic surfactant, 3.0 wt% of polyoxyethylene alkylether, 1.5 wt% of polyoxyethylene lauryl ether,

0.5% by weight of myristyl alcohol as the fatty alcohol,

0.1% by weight of phosphoric acid and sodium phosphate as pH adjusting agents,

As the oxidizing agent, 35% aqueous hydrogen peroxide 17.0% by weight,

A binary formulation was prepared using purified water as a solvent (fig. 2).

[Experimental Example 1] Evaluation of foaming power

1 and 2 compositions were foamed on a flat glass plate using a foam dispenser at a ratio of 1: 1 and the condition of the foam was evaluated (fig. 3).

1 and 2 compositions were mixed at a ratio of 1: 1 and foamed with a dispenser. As a result, when 3.0 wt% of PEG-8 was added (Example # 1-2), N-cocoyl-L-glutamate When 4.0 wt% of alkyl (C8-C16) glucoside was added (Example # 1-4) when 2.0 wt% of the polymer was added (Example # 1-3) and 3.0 wt% of PEG- It was confirmed that the bubbles were formed evenly and the shape of the bubbles was not deformed in all four cases including addition of 2.0 wt% of L-glutamate and 4.0 wt% of alkyl (C8-C16) glucoside (Example # 5) . On the other hand, in the case of Example # 1-1, it was confirmed that the shape of the bubble was almost eliminated.

Therefore, it was confirmed from the above results that all of Examples # 1-2 to # 1-5 are more effective than Example # 1-1.

In order to confirm this result more precisely, the same experiment as Experimental Example 2 was carried out.

[Experimental Example 2] Evaluation of bubble retention

1 and 2 compositions were mixed at a ratio of 1: 1, foam was generated in a measuring cylinder using a foam generating dispenser, and the amount of liquefied foam was measured over time.

4), and the results were as follows (Fig. 4). The results obtained were as follows. (Fig. 4). 5).

As a result, it was found that all of Examples # 1-2 to # 1-5 were less liquefied and liquefied than Example # 1-1, and that the bubble retention of Examples # 1-5 was the highest ≪ / RTI >

This seems to be because Example # 1-5 contains both an alkoxylate alcohol and an amino acid-based surfactant.

[Experimental Example 3] Evaluation of hair conditioning after dyeing

Three samples were prepared by taking 3 g of 15 cm long naturally-denatured and labeled with A, B and C, respectively, and treated as follows.

A: Do nothing

B: The compositions of Examples # 1-5 and Example # 2 were mixed at a ratio of 1: 1, and the mixture was bubbled with a dispenser for 20 minutes, followed by washing with running water for 1 minute. It is then dried naturally.

C: A cream type (fig. 6) composed of an oxidizing dye, an alkali agent and hydrogen peroxide in the same amount as B was prepared in order to realize a conventional cream formative hair dyeing agent. The cream form 1 and 2 were mixed at a ratio of 1: 1, After the treatment, rinse for 1 minute in running water. It is then dried naturally.

Sensory tests were performed on the following two items for the unspecified 100 persons.

1. The touch of hair when touched by hand

2. Combination of whole hair when hand combing

The highest score was 5 points and the lowest score was 1 point.

(5 points: very good, 4 points: good, 3 points: normal, 2 points: bad, 1 point: very bad)

Experimental results (fig. 7 and 8) In the case of natural hair without any treatment, tests 1 and 2 yielded the best results. In the case of hair treated with the composition of the present invention, higher results were obtained as compared with the conventional cream formulations, and it was confirmed that the degree of hair damage after dyeing was smaller.

[Experimental Example 4] Evaluation of salt strength

To evaluate the salt strength, a standard white hair sample having a mass of 1.0 g and a length of 5.0 cm was prepared. The sample was treated with a 1: 1 mixture of the hair dye composition prepared in Example 1 and the hair composition prepared in Example 2 for 20 minutes, Washed and dried in water to evaluate the salt strength.

The colorimetric value (ΔE) of each sample was measured using a standard colorimeter (Spectrophotometer CM-5, KONICA MINOLTA SENSING, INC). The ΔE value is a value for the difference between the standard sample (white moth) and the color of the sample. The larger the value, the better the salt strength.

Experimental Results (fig. 9) Although there was no significant difference in the ΔE values for the conditions # 1-1 to # 1-5 of the respective liquid formulations, the value of the conventional cream formulation (content C of Experimental Example 3) , It was found that the hair dyeing effect was excellent by about 11%.

As seen from the above, when 1: 1 mixture of the composition of Example 1 and Example # 1-5 and the composition of Example 2 were mixed through Experimental Examples 1 to 4, the stability of the foam was high, the hair was damaged after dyeing, It was also concluded that the force did not decrease as compared with conventional cream type hair dye.

Claims (3)

An oxidation type hair dye 1 composition and an oxidation type hair dye preparation composition,
The oxidation-type hair dye preparation composition of claim 1,
(a-1) a nonionic surfactant composed of polyoxyethylene lauryl ether, polyoxyethylene alkyl ether and C8-C16 alkyl glucoside;
(a-2) at least one alkoxylate alcohol selected from the group consisting of PEG-4, PEG-6 and PEG-8; And
(a-3) at least one amino acid surfactant selected from the group consisting of potassium cocoyl glutamate, potassium cocoyl glycinate and potassium N-cocoyl-L-glutamate.
A hair dye composition which maintains a stable foam form. The method according to claim 1,
The oxidation-type hair dye preparation composition of claim 1,
(a-1) a nonionic surfactant composed of polyoxyethylene lauryl ether, polyoxyethylene alkyl ether and C8-C16 alkyl glucoside;
(a-2) at least one alkoxylate alcohol selected from the group consisting of PEG-4, PEG-6 and PEG-8;
(a-3) at least one amino acid surfactant selected from the group consisting of potassium cocoyl glutamate, potassium cocoyl glycinate and potassium N-cocoyl-L-glutamate;
(a-4) at least one antioxidant selected from the group consisting of anhydrous sodium sulfite, ascorbic acid, and ammonium thioglycolate;
(a-5) tetrasodium dithiophosphate chelating agent;
(a-6) at least one compound selected from the group consisting of p-phenylenediamine, o-phenylenediamine, resorcinol, 2-methylenetrisinol, m-phenylenediamine, m- At least one oxidation dye selected from the group consisting of diamines, aminonitrophenols, diphenylamines, N-phenyldiamines, and diaminopyridines;
(a-7) at least one alkaline agent selected from the group consisting of monoethanolamine and ammonia water;
(a-8) at least one fatty alcohol selected from the group consisting of lauryl alcohol, myristyl alcohol, cetyl alcohol, stearyl alcohol and behenyl alcohol;
(a-9) set of at least one cationic surfactant selected from the group consisting of remium chloride, stearothermonium chloride and behen trimonium chloride;
(a-10) at least one moisturizing agent selected from the group consisting of glycerin, propylene glycol, butyleneglycol, dipropylene glycol and sorbitol; And
(a-11) purified water,
The oxidation-type hair dye preparation composition contains,
(b-1) at least one nonionic surfactant selected from the group consisting of polyoxyethylene lauryl ether, polyoxyethylene alkyl ether, and C8-C16 alkyl glucoside;
(b-2) at least one anionic surfactant selected from the group consisting of sodium lauryl sulfate, potassium lauryl sulfate, ammonium lauryl sulfate, sodium laureth sulfate, sodium laureth sulfate and ammonium laureth sulfate;
(b-3) at least one fatty alcohol selected from the group consisting of lauryl alcohol, myristyl alcohol, cetyl alcohol and stearyl alcohol;
(b-4) cellulose derivatives such as methylcellulose, hydroxyethylcellulose, hydroxyethylcellulose, carrageenan, carboxymethylcellulose, carboxymethylhydroxyguanine, cetearyl alcohol, stearic acid, polyquaternium- 10 and polyquaternium-22;
(b-5) at least one pH adjusting agent selected from the group consisting of phosphoric acid and sodium phosphate;
(b-6) at least one chelating agent selected from the group consisting of etidronic acid and disodium iditiyl;
(b-7) 35% aqueous hydrogen peroxide oxidant; And
(b-8) purified water.
A hair dye composition which maintains a stable foam form. 3. The method of claim 2,
The content of each component of the oxidative-type hair dye preparation composition and the oxidative-
The amount of the nonionic surfactant is preferably from 1.0 to 10.0% by weight, more preferably from 0.1 to 5.0% by weight of the alkoxylate alcohol, from 0.1 to 10.0% by weight of the amino acid surfactant, 0.1 to 1.0 wt% of an antioxidant, 0.05 to 0.5 wt% of a chelating agent, 0.1 to 8.0 wt% of an oxidation dye, 1.0 to 15.0 wt% of an alkali agent, 0.1 to 10.0 wt% of a fatty alcohol, 0.1 to 5.0 wt% of a cationic surfactant, 1.0 to 5.0% by weight and purified water 30.50 to 96.35% by weight,
In the case of the oxidative dyeing agent composition, it is preferable that 1.0 to 10.0% by weight of the nonionic surfactant (ratio with respect to the total amount of the hair dye preparation composition, hereinafter the same), 0.1 to 5.0% by weight of anionic surfactant, 0.1 to 1.0% Wherein the pH adjusting agent is 0.01 to 2.0 wt%, the chelating agent is 0.05 to 0.5 wt%, the oxidizing agent is 8.0 to 17.0 wt%, and the purified water is 72.5 to 90.64 wt%.
A hair dye composition which maintains a stable foam form.