JP2023006942A - Hair dyeing composition - Google Patents
Hair dyeing composition Download PDFInfo
- Publication number
- JP2023006942A JP2023006942A JP2021109831A JP2021109831A JP2023006942A JP 2023006942 A JP2023006942 A JP 2023006942A JP 2021109831 A JP2021109831 A JP 2021109831A JP 2021109831 A JP2021109831 A JP 2021109831A JP 2023006942 A JP2023006942 A JP 2023006942A
- Authority
- JP
- Japan
- Prior art keywords
- hair
- hair dyeing
- dyes
- dye
- dyeing composition
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 238000004043 dyeing Methods 0.000 title claims abstract description 50
- 239000000203 mixture Substances 0.000 title claims abstract description 43
- 239000000975 dye Substances 0.000 claims abstract description 33
- 239000000981 basic dye Substances 0.000 claims abstract description 14
- 239000000980 acid dye Substances 0.000 claims abstract description 13
- 239000000982 direct dye Substances 0.000 claims abstract description 12
- 239000000443 aerosol Substances 0.000 claims abstract description 11
- 239000004088 foaming agent Substances 0.000 claims abstract description 5
- 239000007864 aqueous solution Substances 0.000 claims abstract description 4
- 239000000118 hair dye Substances 0.000 claims description 23
- SJEYSFABYSGQBG-UHFFFAOYSA-M Patent blue Chemical compound [Na+].C1=CC(N(CC)CC)=CC=C1C(C=1C(=CC(=CC=1)S([O-])(=O)=O)S([O-])(=O)=O)=C1C=CC(=[N+](CC)CC)C=C1 SJEYSFABYSGQBG-UHFFFAOYSA-M 0.000 claims description 10
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 claims description 9
- 239000006260 foam Substances 0.000 claims description 8
- 239000007788 liquid Substances 0.000 claims description 8
- 239000004094 surface-active agent Substances 0.000 claims description 8
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 6
- 239000000839 emulsion Substances 0.000 claims description 5
- 239000003921 oil Substances 0.000 claims description 5
- 239000002280 amphoteric surfactant Substances 0.000 claims description 4
- 239000003945 anionic surfactant Substances 0.000 claims description 4
- 239000003093 cationic surfactant Substances 0.000 claims description 4
- 230000037308 hair color Effects 0.000 claims description 4
- 239000002736 nonionic surfactant Substances 0.000 claims description 4
- HZAXFHJVJLSVMW-UHFFFAOYSA-N 2-Aminoethan-1-ol Chemical compound NCCO HZAXFHJVJLSVMW-UHFFFAOYSA-N 0.000 claims description 3
- ATRRKUHOCOJYRX-UHFFFAOYSA-N Ammonium bicarbonate Chemical compound [NH4+].OC([O-])=O ATRRKUHOCOJYRX-UHFFFAOYSA-N 0.000 claims description 3
- 229910000013 Ammonium bicarbonate Inorganic materials 0.000 claims description 3
- VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 claims description 3
- UDMBCSSLTHHNCD-KQYNXXCUSA-N adenosine 5'-monophosphate Chemical compound C1=NC=2C(N)=NC=NC=2N1[C@@H]1O[C@H](COP(O)(O)=O)[C@@H](O)[C@H]1O UDMBCSSLTHHNCD-KQYNXXCUSA-N 0.000 claims description 3
- QGZKDVFQNNGYKY-UHFFFAOYSA-N ammonia Natural products N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 claims description 3
- 235000012538 ammonium bicarbonate Nutrition 0.000 claims description 3
- 239000001099 ammonium carbonate Substances 0.000 claims description 3
- 239000007789 gas Substances 0.000 claims description 3
- 239000003002 pH adjusting agent Substances 0.000 claims description 3
- 238000003860 storage Methods 0.000 claims description 3
- NLXLAEXVIDQMFP-UHFFFAOYSA-N Ammonia chloride Chemical compound [NH4+].[Cl-] NLXLAEXVIDQMFP-UHFFFAOYSA-N 0.000 claims 2
- 235000019270 ammonium chloride Nutrition 0.000 claims 1
- 239000002453 shampoo Substances 0.000 abstract description 17
- 238000002156 mixing Methods 0.000 abstract description 4
- 239000000243 solution Substances 0.000 abstract description 4
- 238000005187 foaming Methods 0.000 abstract description 3
- 230000007794 irritation Effects 0.000 abstract description 3
- 210000004761 scalp Anatomy 0.000 abstract 1
- 230000000052 comparative effect Effects 0.000 description 11
- -1 Red No. 504 Chemical compound 0.000 description 10
- 238000011156 evaluation Methods 0.000 description 8
- 241000283707 Capra Species 0.000 description 6
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 5
- KWIUHFFTVRNATP-UHFFFAOYSA-N Betaine Natural products C[N+](C)(C)CC([O-])=O KWIUHFFTVRNATP-UHFFFAOYSA-N 0.000 description 4
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 4
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 4
- KWIUHFFTVRNATP-UHFFFAOYSA-O N,N,N-trimethylglycinium Chemical compound C[N+](C)(C)CC(O)=O KWIUHFFTVRNATP-UHFFFAOYSA-O 0.000 description 4
- VSCWAEJMTAWNJL-UHFFFAOYSA-K aluminium trichloride Chemical compound Cl[Al](Cl)Cl VSCWAEJMTAWNJL-UHFFFAOYSA-K 0.000 description 4
- 229960003237 betaine Drugs 0.000 description 4
- 235000019198 oils Nutrition 0.000 description 4
- 239000003223 protective agent Substances 0.000 description 4
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- 102000011782 Keratins Human genes 0.000 description 3
- 108010076876 Keratins Proteins 0.000 description 3
- RFQSMLBZXQOMKK-UHFFFAOYSA-N [3-[(4,8-diamino-6-bromo-1,5-dioxonaphthalen-2-yl)amino]phenyl]-trimethylazanium;chloride Chemical compound [Cl-].C[N+](C)(C)C1=CC=CC(NC=2C(C3=C(N)C=C(Br)C(=O)C3=C(N)C=2)=O)=C1 RFQSMLBZXQOMKK-UHFFFAOYSA-N 0.000 description 3
- UXEAWNJALIUYRH-UHFFFAOYSA-N [8-[(4-aminophenyl)hydrazinylidene]-7-oxonaphthalen-2-yl]-trimethylazanium;chloride Chemical compound [Cl-].C12=CC([N+](C)(C)C)=CC=C2C=CC(=O)\C1=N/NC1=CC=C(N)C=C1 UXEAWNJALIUYRH-UHFFFAOYSA-N 0.000 description 3
- 125000000217 alkyl group Chemical group 0.000 description 3
- 239000001005 nitro dye Substances 0.000 description 3
- 239000000049 pigment Substances 0.000 description 3
- 239000001026 semi permanent hair color Substances 0.000 description 3
- PUPZLCDOIYMWBV-UHFFFAOYSA-N (+/-)-1,3-Butanediol Chemical compound CC(O)CCO PUPZLCDOIYMWBV-UHFFFAOYSA-N 0.000 description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 2
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 2
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- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 2
- HSWXSHNPRUMJKI-UHFFFAOYSA-N [8-[(2-methoxyphenyl)hydrazinylidene]-7-oxonaphthalen-2-yl]-trimethylazanium;chloride Chemical compound [Cl-].COC1=CC=CC=C1N\N=C/1C2=CC([N+](C)(C)C)=CC=C2C=CC\1=O HSWXSHNPRUMJKI-UHFFFAOYSA-N 0.000 description 2
- CMPPYVDBIJWGCB-UHFFFAOYSA-N [8-[(4-amino-3-nitrophenyl)hydrazinylidene]-7-oxonaphthalen-2-yl]-trimethylazanium;chloride Chemical compound [Cl-].C12=CC([N+](C)(C)C)=CC=C2C=CC(=O)\C1=N\NC1=CC=C(N)C([N+]([O-])=O)=C1 CMPPYVDBIJWGCB-UHFFFAOYSA-N 0.000 description 2
- 239000004359 castor oil Substances 0.000 description 2
- 235000019438 castor oil Nutrition 0.000 description 2
- 238000004140 cleaning Methods 0.000 description 2
- 239000003240 coconut oil Substances 0.000 description 2
- 235000019864 coconut oil Nutrition 0.000 description 2
- 235000014113 dietary fatty acids Nutrition 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 239000003623 enhancer Substances 0.000 description 2
- 229930195729 fatty acid Natural products 0.000 description 2
- 239000000194 fatty acid Substances 0.000 description 2
- 150000004665 fatty acids Chemical class 0.000 description 2
- ZEMPKEQAKRGZGQ-XOQCFJPHSA-N glycerol triricinoleate Natural products CCCCCC[C@@H](O)CC=CCCCCCCCC(=O)OC[C@@H](COC(=O)CCCCCCCC=CC[C@@H](O)CCCCCC)OC(=O)CCCCCCCC=CC[C@H](O)CCCCCC ZEMPKEQAKRGZGQ-XOQCFJPHSA-N 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 230000035515 penetration Effects 0.000 description 2
- 239000003961 penetration enhancing agent Substances 0.000 description 2
- 239000001024 permanent hair color Substances 0.000 description 2
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 description 2
- RUTSRVMUIGMTHJ-UHFFFAOYSA-M sodium;tetradec-1-ene-1-sulfonate Chemical compound [Na+].CCCCCCCCCCCCC=CS([O-])(=O)=O RUTSRVMUIGMTHJ-UHFFFAOYSA-M 0.000 description 2
- 239000001027 temporary hair color Substances 0.000 description 2
- DWKARHJHPSUOBW-UHFFFAOYSA-N trimethyl-[3-[(2e)-2-(3-methyl-5-oxo-1-phenylpyrazol-4-ylidene)hydrazinyl]phenyl]azanium;chloride Chemical compound [Cl-].CC1=NN(C=2C=CC=CC=2)C(O)=C1N=NC1=CC=CC([N+](C)(C)C)=C1 DWKARHJHPSUOBW-UHFFFAOYSA-N 0.000 description 2
- QLAJNZSPVITUCQ-UHFFFAOYSA-N 1,3,2-dioxathietane 2,2-dioxide Chemical compound O=S1(=O)OCO1 QLAJNZSPVITUCQ-UHFFFAOYSA-N 0.000 description 1
- 229940058015 1,3-butylene glycol Drugs 0.000 description 1
- YUNHBAIHRNIODP-UHFFFAOYSA-N 2-(2-hydroxyethylamino)-5-nitrophenol Chemical compound OCCNC1=CC=C([N+]([O-])=O)C=C1O YUNHBAIHRNIODP-UHFFFAOYSA-N 0.000 description 1
- LFOUYKNCQNVIGI-UHFFFAOYSA-N 2-(2-nitroanilino)ethanol Chemical compound OCCNC1=CC=CC=C1[N+]([O-])=O LFOUYKNCQNVIGI-UHFFFAOYSA-N 0.000 description 1
- LGZSBRSLVPLNTM-UHFFFAOYSA-N 2-(4-amino-2-methyl-5-nitroanilino)ethanol Chemical compound CC1=CC(N)=C([N+]([O-])=O)C=C1NCCO LGZSBRSLVPLNTM-UHFFFAOYSA-N 0.000 description 1
- AUGYVRQAFGDGQV-UHFFFAOYSA-N 2-(chloromethyl)oxirane;2-(2-hydroxyethylamino)ethanol;2-nitrobenzene-1,4-diamine Chemical compound ClCC1CO1.OCCNCCO.NC1=CC=C(N)C([N+]([O-])=O)=C1 AUGYVRQAFGDGQV-UHFFFAOYSA-N 0.000 description 1
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- 238000004040 coloring Methods 0.000 description 1
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- MQWPIYMKAKYEEQ-UHFFFAOYSA-L dipotassium 2,3,4,5-tetrachloro-6-(2,4,5,7-tetrabromo-3-oxido-6-oxoxanthen-9-yl)benzoate Chemical compound [K+].[K+].[O-]C(=O)c1c(Cl)c(Cl)c(Cl)c(Cl)c1-c1c2cc(Br)c([O-])c(Br)c2oc2c(Br)c(=O)c(Br)cc12 MQWPIYMKAKYEEQ-UHFFFAOYSA-L 0.000 description 1
- VQHHOXOLUXRQFQ-UHFFFAOYSA-L dipotassium;4,5,6,7-tetrachloro-2',4',5',7'-tetraiodo-3-oxospiro[2-benzofuran-1,9'-xanthene]-3',6'-diolate Chemical compound [K+].[K+].O1C(=O)C(C(=C(Cl)C(Cl)=C2Cl)Cl)=C2C21C1=CC(I)=C([O-])C(I)=C1OC1=C(I)C([O-])=C(I)C=C21 VQHHOXOLUXRQFQ-UHFFFAOYSA-L 0.000 description 1
- LQJVOKWHGUAUHK-UHFFFAOYSA-L disodium 5-amino-4-hydroxy-3-phenyldiazenylnaphthalene-2,7-disulfonate Chemical compound [Na+].[Na+].OC1=C2C(N)=CC(S([O-])(=O)=O)=CC2=CC(S([O-])(=O)=O)=C1N=NC1=CC=CC=C1 LQJVOKWHGUAUHK-UHFFFAOYSA-L 0.000 description 1
- FPAYXBWMYIMERV-UHFFFAOYSA-L disodium;5-methyl-2-[[4-(4-methyl-2-sulfonatoanilino)-9,10-dioxoanthracen-1-yl]amino]benzenesulfonate Chemical compound [Na+].[Na+].[O-]S(=O)(=O)C1=CC(C)=CC=C1NC(C=1C(=O)C2=CC=CC=C2C(=O)C=11)=CC=C1NC1=CC=C(C)C=C1S([O-])(=O)=O FPAYXBWMYIMERV-UHFFFAOYSA-L 0.000 description 1
- 239000002552 dosage form Substances 0.000 description 1
- 239000003814 drug Substances 0.000 description 1
- 235000012732 erythrosine Nutrition 0.000 description 1
- 229960004585 etidronic acid Drugs 0.000 description 1
- 235000011187 glycerol Nutrition 0.000 description 1
- 239000003051 hair bleaching agent Substances 0.000 description 1
- 239000003906 humectant Substances 0.000 description 1
- RNYJXPUAFDFIQJ-UHFFFAOYSA-N hydron;octadecan-1-amine;chloride Chemical compound [Cl-].CCCCCCCCCCCCCCCCCC[NH3+] RNYJXPUAFDFIQJ-UHFFFAOYSA-N 0.000 description 1
- 230000001771 impaired effect Effects 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 125000001449 isopropyl group Chemical group [H]C([H])([H])C([H])(*)C([H])([H])[H] 0.000 description 1
- 229940075468 lauramidopropyl betaine Drugs 0.000 description 1
- SXQCTESRRZBPHJ-UHFFFAOYSA-M lissamine rhodamine Chemical compound [Na+].C=12C=CC(=[N+](CC)CC)C=C2OC2=CC(N(CC)CC)=CC=C2C=1C1=CC=C(S([O-])(=O)=O)C=C1S([O-])(=O)=O SXQCTESRRZBPHJ-UHFFFAOYSA-M 0.000 description 1
- BEGLCMHJXHIJLR-UHFFFAOYSA-N methylisothiazolinone Chemical compound CN1SC=CC1=O BEGLCMHJXHIJLR-UHFFFAOYSA-N 0.000 description 1
- AFAJYBYVKUTWJK-UHFFFAOYSA-N n'-(5-methoxy-2-nitrophenyl)ethane-1,2-diamine;hydrochloride Chemical compound Cl.COC1=CC=C([N+]([O-])=O)C(NCCN)=C1 AFAJYBYVKUTWJK-UHFFFAOYSA-N 0.000 description 1
- DVEKCXOJTLDBFE-UHFFFAOYSA-N n-dodecyl-n,n-dimethylglycinate Chemical compound CCCCCCCCCCCC[N+](C)(C)CC([O-])=O DVEKCXOJTLDBFE-UHFFFAOYSA-N 0.000 description 1
- LLLILZLFKGJCCV-UHFFFAOYSA-M n-methyl-n-[(1-methylpyridin-1-ium-4-yl)methylideneamino]aniline;methyl sulfate Chemical compound COS([O-])(=O)=O.C=1C=CC=CC=1N(C)\N=C\C1=CC=[N+](C)C=C1 LLLILZLFKGJCCV-UHFFFAOYSA-M 0.000 description 1
- JMXROTHPANUTOJ-UHFFFAOYSA-H naphthol green b Chemical compound [Na+].[Na+].[Na+].[Fe+3].C1=C(S([O-])(=O)=O)C=CC2=C(N=O)C([O-])=CC=C21.C1=C(S([O-])(=O)=O)C=CC2=C(N=O)C([O-])=CC=C21.C1=C(S([O-])(=O)=O)C=CC2=C(N=O)C([O-])=CC=C21 JMXROTHPANUTOJ-UHFFFAOYSA-H 0.000 description 1
- CTIQLGJVGNGFEW-UHFFFAOYSA-L naphthol yellow S Chemical compound [Na+].[Na+].C1=C(S([O-])(=O)=O)C=C2C([O-])=C([N+]([O-])=O)C=C([N+]([O-])=O)C2=C1 CTIQLGJVGNGFEW-UHFFFAOYSA-L 0.000 description 1
- 239000002304 perfume Substances 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 239000002244 precipitate Substances 0.000 description 1
- 239000003755 preservative agent Substances 0.000 description 1
- KXXXUIKPSVVSAW-UHFFFAOYSA-K pyranine Chemical compound [Na+].[Na+].[Na+].C1=C2C(O)=CC(S([O-])(=O)=O)=C(C=C3)C2=C2C3=C(S([O-])(=O)=O)C=C(S([O-])(=O)=O)C2=C1 KXXXUIKPSVVSAW-UHFFFAOYSA-K 0.000 description 1
- AZJPTIGZZTZIDR-UHFFFAOYSA-L rose bengal Chemical compound [K+].[K+].[O-]C(=O)C1=C(Cl)C(Cl)=C(Cl)C(Cl)=C1C1=C2C=C(I)C(=O)C(I)=C2OC2=C(I)C([O-])=C(I)C=C21 AZJPTIGZZTZIDR-UHFFFAOYSA-L 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- LGZQSRCLLIPAEE-UHFFFAOYSA-M sodium 1-[(4-sulfonaphthalen-1-yl)diazenyl]naphthalen-2-olate Chemical compound [Na+].C1=CC=C2C(N=NC3=C4C=CC=CC4=CC=C3O)=CC=C(S([O-])(=O)=O)C2=C1 LGZQSRCLLIPAEE-UHFFFAOYSA-M 0.000 description 1
- 229910052938 sodium sulfate Inorganic materials 0.000 description 1
- 235000011152 sodium sulphate Nutrition 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- UEUXEKPTXMALOB-UHFFFAOYSA-J tetrasodium;2-[2-[bis(carboxylatomethyl)amino]ethyl-(carboxylatomethyl)amino]acetate Chemical compound [Na+].[Na+].[Na+].[Na+].[O-]C(=O)CN(CC([O-])=O)CCN(CC([O-])=O)CC([O-])=O UEUXEKPTXMALOB-UHFFFAOYSA-J 0.000 description 1
- 238000011282 treatment Methods 0.000 description 1
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Abstract
Description
本発明は染毛組成物に関するものである。 The present invention relates to hair dyeing compositions.
染毛料と染毛剤は、使用される染料又はメラニンに対する脱色作用の有無によって分類することができる。 Hair dyes and hair dyes can be classified according to the dye used or the presence or absence of bleaching action on melanin.
染毛料の代表例としては、酸性染料、塩基性青９９、塩基性茶１６、塩基性青７５、塩基性青１２４、塩基性赤７６などの塩基性染料、ＨＣ青２、ＨＣ黄２、ＨＣ黄４などのＨＣ染料、ニトロ染料等の直接染料を含む半永久染毛剤が挙げられる。 Typical examples of hair dyes include acid dyes, basic dyes such as basic blue 99, basic brown 16, basic blue 75, basic blue 124, basic red 76, HC blue 2, HC yellow 2, HC Examples include semi-permanent hair dyes including HC dyes such as Yellow 4 and direct dyes such as nitro dyes.
染色方法の代表例としては、永久染毛剤、半永久染毛料、一時染毛料に分類され、カラーシャンプーやカラートリートメントは半永久染毛料に位置付けされる。カラーシャンプーについては特定のカチオン性染料、界面活性剤およびポリマーを含有する染料光沢剤が提案されている（例えば下記特許文献１）。
Typical examples of dyeing methods are classified into permanent hair dyes, semi-permanent hair dyes, and temporary hair dyes, and color shampoos and color treatments are positioned as semi-permanent hair dyes. For color shampoos, dye brighteners containing specific cationic dyes, surfactants and polymers have been proposed (for example,
また、塩基性染料を含有するゲル状カラーシャンプー組成物（例えば下記特許文献２）が提案されている。
A gel-like color shampoo composition containing a basic dye has also been proposed (for example,
しかしながら、カラーシャンプーは界面活性剤の配合量が多く、染料の染着を阻害してしまうため、染着性が悪いといった問題があった。 However, color shampoos have a problem of poor dyeing properties because they contain a large amount of surfactants and hinder the dyeing of dyes.
また、従来のカラーシャンプーは、シャンプーとしての用途も含めた染毛組成物として利便性がある一方、界面活性剤の刺激性や洗浄力の問題があり、連続使用出来ないという問題があった。さらに、染毛しながら洗浄もしてしまうため、色が定着しないという大きな問題があった。 In addition, while conventional color shampoos are convenient as hair dyeing compositions including use as shampoos, they have problems of surfactant irritation and detergency, and they cannot be used continuously. Furthermore, since the hair is washed while being dyed, there is a big problem that the color does not fix.
本発明では、上記従来技術の有する課題に鑑みてなされたものであり、毛髪を鮮やかに染色し、様々な色のバリエーションを表現できる染毛組成物を提供することを目的とする。 The present invention has been made in view of the above problems of the prior art, and an object of the present invention is to provide a hair dyeing composition capable of vividly dyeing hair and expressing various color variations.
本発明の第１の観点における染毛組成物によれば、
ＨＣ染料、塩基性染料、直接染料、酸性染料のうち、いずれか１種類以上の染料を含む染毛組成物であり、起泡剤を含み、使用時に泡を用いて染色する
（水、界面活性剤及び油で乳化された低粘度乳化物は除く）
ことを特徴とする。
According to the hair dye composition in the first aspect of the present invention,
A hair dyeing composition containing at least one dye selected from HC dyes, basic dyes, direct dyes, and acid dyes. (excluding low-viscosity emulsions emulsified with agents and oils)
It is characterized by
より好ましくは、
前記染料は、使用時の配合量が０．０質量％より多く１．０質量％以下である
ことを特徴とする。
More preferably
The amount of the dye when used is more than 0.0% by mass and 1.0% by mass or less.
より好ましくは、
前記起泡剤は、カチオン界面活性剤、アニオン界面活性剤、両性界面活性剤、ノニオン界面活性剤のうち、いずれか１種類以上を含む
ことを特徴とする。
More preferably
The foaming agent is characterized by containing at least one of a cationic surfactant, an anionic surfactant, an amphoteric surfactant, and a nonionic surfactant.
より好ましくは、
単品、又は、使用時に複数を混ぜることで、好きな色を調色し、多彩な色合いを表現する
ことを特徴とする。
More preferably
It is characterized by expressing a variety of shades by toning a favorite color by mixing a single item or a plurality of items when using.
より好ましくは、
浸透促進剤、毛髪保護剤を配合し、毛髪をいたわりながら染色することが出来る
ことを特徴とする。
More preferably
It is characterized by being able to dye the hair while caring for it by blending a penetration enhancer and a hair protecting agent.
より好ましくは、
ｐＨ調整剤として、炭酸水素アンモニウム、アンモニア水、モノエタノールアミン、ＡＭＰ、塩化アルミニウム、クエン酸のうちいずれか１つ以上を含み、好ましくはｐＨ５以上である
ことを特徴とする。
More preferably
It is characterized by containing at least one of ammonium hydrogen carbonate, aqueous ammonia, monoethanolamine, AMP, aluminum chloride, and citric acid as a pH adjuster, and preferably having a pH of 5 or higher.
より好ましくは、
内容物は水と油と界面活性剤を用いた乳化物ではなく、水溶液である
ことを特徴とする。
More preferably
The content is characterized by being an aqueous solution rather than an emulsion using water, oil and a surfactant.
より好ましくは、
使用時にノンエアゾールタイプのポンプフォーマーを用いて泡にする
ことを特徴とする。
More preferably
It is characterized by foaming with a non-aerosol type pump foamer at the time of use.
より好ましくは、
使用時にガスを用いたエアゾールで泡にする
ことを特徴とする。
More preferably
It is characterized by foaming with aerosol using gas at the time of use.
より好ましくは、
液状であり、使用時に泡となれば、保存容器形態は特に限定しない
ことを特徴とする。
More preferably
As long as it is liquid and foams when used, the shape of the storage container is not particularly limited.
より好ましくは、
染毛剤の後に連続して使用することが可能であり、ヘアカラーの施術後に色補正が可能となる
ことを特徴とする。
More preferably
It is characterized in that it can be used continuously after hair dyeing, and color correction can be performed after hair coloring.
本発明に係る染毛組成物によれば、従来のカラーシャンプーでは表現することができなかった多彩な色調に染毛することができ、さらには、染毛剤や脱色剤と使用後に使用することで、毛髪を明るくしながら永久染毛剤には難しい高彩度の色に染色することができる。 According to the hair dye composition according to the present invention, it is possible to dye hair in a variety of tones that could not be expressed with conventional color shampoos, and furthermore, it can be used after use with a hair dye or bleaching agent. With this, it is possible to dye the hair in a highly saturated color, which is difficult with permanent hair dyes, while brightening the hair.
また、本発明に係る染毛組成物によれば、酸性染料、塩基性染料、ニトロ染料等の直接染料を配合したカラーシャンプーと比べて安定した染着性を示すことができる。 Moreover, according to the hair dyeing composition of the present invention, it is possible to exhibit stable dyeing properties as compared with color shampoos containing direct dyes such as acid dyes, basic dyes and nitro dyes.
さらに、本発明に係る染毛組成物によれば、泡の剤型を用いることで一人でも手軽にムラなく染色できるばかりか、ヘアカラー後に多彩な色合いを補うこともできる。 Furthermore, according to the hair dye composition of the present invention, by using the foam dosage form, not only can one person easily dye hair without unevenness, but also various shades can be supplemented after hair coloring.
さらに、本発明に係る染毛組成物によれば、カラーシャンプーよりも染着性が高く、短時間で染めることができ、染料の配合量も抑えることができるため、刺激を抑制できる。 Furthermore, according to the hair dyeing composition of the present invention, the dyeing property is higher than that of a color shampoo, the hair can be dyed in a short period of time, and the amount of dye to be blended can be reduced, so irritation can be suppressed.
以下、本発明に係る染毛組成物について説明する。
本発明に係る染毛組成物は、ＨＣ染料、塩基性染料、ニトロ染料（直接染料）、酸性染料のうち、いずれか１種類以上の染料を含む染毛組成物である（水、界面活性剤及び油で乳化された低粘度乳化物は除く）。ただし、当該染料の（染毛組成物使用時の）配合量は、０．０質量％より多く１．０質量％以下、より好ましくは、０．０１質量％以上０．５質量％以下である（１．０質量％を超えると染料が析出する恐れがあるため）。
The hair dye composition according to the present invention will be described below.
The hair dyeing composition according to the present invention is a hair dyeing composition containing at least one dye selected from HC dyes, basic dyes, nitro dyes (direct dyes), and acid dyes (water, surfactant and low-viscosity emulsions emulsified with oil). However, the amount of the dye (when using the hair dye composition) is more than 0.0% by mass and 1.0% by mass or less, more preferably 0.01% by mass or more and 0.5% by mass or less. (Because there is a possibility that the dye may precipitate if it exceeds 1.0% by mass).
本発明に係る染毛組成物は、例えば２－アルキル－Ｎ－カルボキシメチル－Ｎ－ヒドロキシエチルイミダゾリニウムベタインなどの起泡剤を含み、使用時に泡を用いて染色するものであり、洗浄成分は含まれていない。 The hair dye composition according to the present invention contains a foaming agent such as 2-alkyl-N-carboxymethyl-N-hydroxyethylimidazolinium betaine, and is used for dyeing with foam when used, and a cleaning component is not included.
そして、上述の起泡剤については、カチオン界面活性剤、アニオン界面活性剤、両性界面活性剤、ノニオン界面活性剤のうち、いずれか１種類以上が当該検体に含まれていればよい。 As for the foaming agent described above, any one or more of cationic surfactants, anionic surfactants, amphoteric surfactants, and nonionic surfactants may be contained in the sample.
本発明に係る染毛組成物は、ｐＨ５．００～８．００が好ましいが、ＨＣ青１６、塩基性黄８７、塩基性橙３１、塩基性赤５１のうち、いずれか１種類以上を配合して染毛組成物を作る場合は、ｐＨ８．００以上でも問題ない。 The hair dye composition according to the present invention preferably has a pH of 5.00 to 8.00, and contains at least one of HC blue 16, basic yellow 87, basic orange 31, and basic red 51. When the hair dyeing composition is prepared by using the pH of 8.00 or higher, there is no problem.
また、本発明に係る染毛組成物には、浸透促進剤、毛髪保護剤を含有させることにより、より好ましい添加効果、すなわち、毛髪をいたわりながら染色することが出来るという効果が発揮される傾向がある。 In addition, the hair dyeing composition according to the present invention tends to exhibit more preferable additive effect, that is, the effect that the hair can be dyed while caring for the hair, by containing the penetration enhancer and the hair protecting agent. be.
浸透促進剤としては、１，３－ブチレングリコール、ジラウロイルグルタミン酸リシンＮａ、シクロヘキサン－１，４－ジカルボン酸ビスエトキシジグリコール、尿素などが挙げられる。そして、これらは単独で又は必要に応じ２種以上組み合わせて用いられる。ただし、これら以外の浸透促進剤を用いてもよい。 Penetration enhancers include 1,3-butylene glycol, sodium lysine dilauroyl glutamate, bisethoxydiglycol cyclohexane-1,4-dicarboxylate, and urea. And these are used individually or in combination of 2 or more types as needed. However, penetration enhancers other than these may be used.
毛髪保護剤としては、塩化Ｎ－［２－ヒドロキシ－３－（トリメチルアンモニオ）プロピル］加水分解ケラチン液、塩化Ｎ－［２－ヒドロキシ－３－（ラウリルジメチルアンモニオ）プロピル］加水分解ケラチン液等のケラチンなどが挙げられる。ただし、これら以外の毛髪保護剤を用いてもよい。 Hair protecting agents include N-[2-hydroxy-3-(trimethylammonio)propyl]hydrolyzed keratin chloride solution and N-[2-hydroxy-3-(lauryldimethylammonio)propyl]hydrolyzed keratin chloride solution. keratin and the like. However, hair protecting agents other than these may be used.
また、本発明に係る染毛組成物には、必要に応じ、ｐＨの安定性を向上させる効果を目的で、ｐＨ調整剤として、炭酸水素アンモニウム、アンモニア水、モノエタノールアミン、ＡＭＰ、塩化アルミニウム、クエン酸のうちいずれか１つ以上を含有させることができる。 In addition, the hair dye composition according to the present invention may optionally contain ammonium hydrogen carbonate, aqueous ammonia, monoethanolamine, AMP, aluminum chloride, as a pH adjuster for the purpose of improving pH stability. Any one or more of citric acid can be included.
本発明に係る染毛組成物に含有される染毛料には、色素や染料としては、酸性染料、塩基性染料、ＨＣ染料、直接染料等が好ましく、これらは単独で又は必要に応じ２種以上組み合わせて用いられる。これらの色素や染料を含有させることにより、多彩な色調に染毛することが可能である。 Acid dyes, basic dyes, HC dyes, direct dyes, and the like are preferable as pigments and dyes for the hair dye contained in the hair dye composition according to the present invention, and these may be used alone or two or more of them as necessary. Used in combination. By incorporating these pigments and dyes, it is possible to dye hair in a variety of tones.
酸性染料としては、昭和４１年８月３１日公布の厚生省令第３０号「医薬品等に使用することができるタール色素を定める省令」によって指定されている色素が挙げられる。
染毛料に通常用いられ得る酸性染料であれば特に限定されるものでなく、例えば赤色２号、赤色３号、赤色１０２号、赤色１０４号、赤色１０５号、赤色１０６号、黄色４号、黄色５号、緑色３号、青色１号、青色２号、赤色２０１号、赤色２２７号、赤色２２０号、赤色２３０号、赤色２３１号、赤色２３２号、橙色２０５号、橙色２０７号、黄色２０２号、黄色２０３号、緑色２０１号、緑色２０４号、緑色２０６号、青色２０２号、青色２０３号、青色２０５号、赤色４０１号、赤色５０２号、赤色５０３号、赤色５０４号、赤色５０６号、橙色４０２号、黄色４０２号、黄色４０３号、黄色４０６号、黄色４０７号、褐色２０１号、緑色４０１号、緑色４０２号、紫色４０１号、黒色４０１号等が挙げられる。
Examples of acid dyes include dyes designated by the Ministry of Health and Welfare Ordinance No. 30 issued on August 31, 1966, "Ministerial Ordinance Determining Tar Colors Usable in Pharmaceuticals, etc.".
Acid dyes commonly used in hair dyes are not particularly limited, and examples include Red No. 2, Red No. 3, Red No. 102, Red No. 104, Red No. 105, Red No. 106, Yellow No. 4 and yellow. No. 5, Green No. 3, Blue No. 1, Blue No. 2, Red No. 201, Red No. 227, Red No. 220, Red No. 230, Red No. 231, Red No. 232, Orange No. 205, Orange No. 207, Yellow No. 202 , Yellow No. 203, Green No. 201, Green No. 204, Green No. 206, Blue No. 202, Blue No. 203, Blue No. 205, Red No. 401, Red No. 502, Red No. 503, Red No. 504, Red No. 506, Orange No. 402, Yellow No. 402, Yellow No. 403, Yellow No. 406, Yellow No. 407, Brown No. 201, Green No. 401, Green No. 402, Purple No. 401, Black No. 401, and the like.
塩基性染料としては、染毛料に通常用いられ得る塩基性染料であれば特に限定されるものでなく、例えばBasic Blue 75（塩基性青７５）、Basic Red 76（塩基性赤７６）、Basic Blue 99（塩基性青９９）、Basic Brown 16（塩基性茶１６）、Basic Brown 17（塩基性茶１７）、Basic Yellow 57（塩基性黄５７）等が挙げられる。 The basic dye is not particularly limited as long as it is a basic dye that can be commonly used in hair dyes. For example, Basic Blue 75, Basic Red 76, Basic Blue 99 (basic blue 99), Basic Brown 16 (basic brown 16), Basic Brown 17 (basic brown 17), Basic Yellow 57 (basic yellow 57) and the like.
ＨＣ染料としては、染毛料に通常用いられ得るＨＣ染料であれば特に限定されるものでなく、例えばHC Blue No.2、HC Blue No.5、HC Blue No.6、HC Blue no.9、HC Blue No.10、HC Blue No.11、HC Blue No.12、HC Blue No.13、HC Orange No.1、HC Orange No.2、HC Orange No.3、HC Red No.1、HC Red No.3、HC Red No.7、HC Red No.10、HC Red No.11、HC Red No.13、HC Red No.14、HC Violet No.1、HC Violet No.2、HC Yellow No.2、HC Yellow No.4、HC Yellow No.6、HC Yellow No.9、HC Yellow No.10、HC Yellow No.11等が挙げられる。 HC dyes are not particularly limited as long as they are HC dyes commonly used in hair dyes. Examples include HC Blue No.2, HC Blue No.5, HC Blue No.6, HC Blue No.9, HC Blue No.10, HC Blue No.11, HC Blue No.12, HC Blue No.13, HC Orange No.1, HC Orange No.2, HC Orange No.3, HC Red No.1, HC Red No.3, HC Red No.7, HC Red No.10, HC Red No.11, HC Red No.13, HC Red No.14, HC Violet No.1, HC Violet No.2, HC Yellow No. 2, HC Yellow No.4, HC Yellow No.6, HC Yellow No.9, HC Yellow No.10, HC Yellow No.11 and the like.
直接染料としては、２－アミノ－６－クロロ－４ニトロフェノ－ル、２－アミノ－３－ニトロフェノ－ル、４－アミノ－３－ニトロフェノ－ル、ヒドロキシアントラキノンアミノプロピルメチルモルホニウムメトサルフェ－ト、３－メチルアミノ－４－ニトロフェノキシエタノ－ル、２－ニトロ－５－グリセリルメチルアニリン、Ｎ，Ｎ－Ｂｉｓ（２－Ｈｙｄｒｏｘｙｅｔｈｙｌ）－２－Ｎｉｔｒｏ－ｐ－Ｐｈｅｎｙｌｅｎｅｄｉａｍｉｎｅ等のニトロ染料が挙げられる。 Direct dyes include 2-amino-6-chloro-4-nitrophenol, 2-amino-3-nitrophenol, 4-amino-3-nitrophenol, hydroxyanthraquinoneaminopropylmethylmorphonium methosulfate. , 3-methylamino-4-nitrophenoxyethanol, 2-nitro-5-glycerylmethylaniline, N,N-Bis(2-Hydroxyethyl)-2-Nitro-p-phenylenediamine.
上述した色素や染料の含有量は、２重量％以下が好ましく、０．０１～１重量％がより好ましい。２重量％を超えると皮膚への染着性が大きくなる傾向がある。 The content of the pigments and dyes described above is preferably 2% by weight or less, more preferably 0.01 to 1% by weight. If the amount exceeds 2% by weight, the dyeability to the skin tends to increase.
さらに、本発明に係る染毛組成物に含有される染毛料には、本発明の効果を損なわない範囲で、通常、化粧品や染毛料に常用される各種成分を含有させることができる。 Furthermore, the hair dye contained in the hair dyeing composition according to the present invention can contain various components commonly used in cosmetics and hair dyes as long as the effects of the present invention are not impaired.
例えば、界面活性剤としては、塩化ステアリルトリメチルアンモニウム、塩化トリ（ポリオキシエチレン）ステアリルアンモニウム（５Ｅ．Ｏ．）、塩化セチルトリメチルアンモニウム等のカチオン界面活性剤、
テトラデセンスルホン酸ナトリウム液、ラウロイルメチル－β－アラニンナトリウム液、ポリオキシエチレンアルキル（１２，１３）エーテル硫酸ナトリウム（３Ｅ．Ｏ．）等のアニオン性界面活性剤、
アルキルポリグルコシド、ポリオキシエチレンヒマシ油、ポリオキシエチレン硬化ヒマシ油等のノニオン性界面活性剤、
２－アルキル－Ｎ－カルボキシメチル－Ｎ－ヒドロキシエチルイミダゾリニウムベタイン、ヤシ油脂肪酸アミドプロピルベタイン液、ラウリン酸アミドプロピルベタイン液等の両性界面活性剤が挙げられる。
１，３－ＢＧ、ＰＧ、ＤＰＧ、グリセリン等の保湿剤；ＥＤＴＡ、ＥＤＴＡ－２Ｎａ、ＥＤＴＡ－４Ｎａ、ヒドロキシエタンジホスホン酸等のキレート剤：パラベン、メチルイソチアゾリノン等の防腐剤；エタノール、イソプロピルアルコール等の溶剤、
香料等で、
これらは必要に応じ、２種以上組み合わせて適宜配合することができる。
ただし、これら以外の成分を用いても泡が吐出できれば適宜配合することができる。
Examples of surfactants include cationic surfactants such as stearyltrimethylammonium chloride, tri(polyoxyethylene)stearylammonium chloride (5E.O.), and cetyltrimethylammonium chloride;
anionic surfactants such as sodium tetradecenesulfonate liquid, lauroylmethyl-β-alanine sodium liquid, polyoxyethylene alkyl (12,13) ether sodium sulfate (3E.O.);
nonionic surfactants such as alkyl polyglucosides, polyoxyethylene castor oil, polyoxyethylene hydrogenated castor oil;
Examples thereof include amphoteric surfactants such as 2-alkyl-N-carboxymethyl-N-hydroxyethylimidazolinium betaine, coconut oil fatty acid amidopropyl betaine liquid, and lauramidopropyl betaine liquid.
Humectants such as 1,3-BG, PG, DPG, glycerin; chelating agents such as EDTA, EDTA-2Na, EDTA-4Na, hydroxyethanediphosphonic acid; preservatives such as parabens and methylisothiazolinone; ethanol, isopropyl solvents such as alcohol,
Perfume, etc.
If necessary, two or more of these can be combined and blended as appropriate.
However, components other than these may be appropriately blended as long as foam can be discharged.
なお、本発明に係る染毛組成物は、液状で、使用時に泡にする剤型であり、保存容器形態は特に限定しない。 In addition, the hair dyeing composition according to the present invention is in a liquid form that foams at the time of use, and the storage container form is not particularly limited.
また、本発明に係る染毛組成物は、単品、又は、使用時に複数を混ぜることで、好きな色を調色し、多彩な色合いを表現することができる。 In addition, the hair dyeing composition according to the present invention can be used singly or by mixing a plurality of them at the time of use to tone a desired color and express various shades.
さらに、本発明に係る染毛組成物の内容物は、水と油と界面活性剤を用いた乳化物ではなく、水溶液であるものとしてもよい。 Furthermore, the content of the hair dyeing composition according to the present invention may be an aqueous solution instead of an emulsion using water, oil and a surfactant.
そして、本発明に係る染毛組成物は、染毛剤の後に連続して使用することが可能であり、ヘアカラーの施術後に色補正が可能となる。 In addition, the hair dye composition according to the present invention can be used continuously after the hair dye, and color correction can be performed after hair coloring.
以下では、本発明に係る染毛組成物を、実施例及び比較例により具体的に説明する。なお、表中の数値は質量％を示す。 EXAMPLES Hereinafter, the hair dyeing composition according to the present invention will be specifically described with reference to examples and comparative examples. In addition, the numerical value in a table|surface shows the mass %.
表１に示すＡ－１～Ａ－８は、ＨＣ染料、塩基性染料、直接染料、酸性染料で調整したポンプフォーム用の実施例用検体である。Ａ－９，Ａ－１０は、ＨＣ染料、塩基性染料、直接染料、酸性染料で調整したエアゾール用の実施例用検体である。 A-1 to A-8 shown in Table 1 are example specimens for pump foam prepared with HC dye, basic dye, direct dye, and acid dye. A-9 and A-10 are sample samples for aerosol prepared with HC dye, basic dye, direct dye and acid dye.
また、表２に示すＢ－１～Ｂ－８は、ＨＣ染料、塩基性染料、直接染料、酸性染料で調整したカラーシャンプー用の比較例検体である。 B-1 to B-8 shown in Table 2 are comparative samples for color shampoo prepared with HC dyes, basic dyes, direct dyes, and acid dyes.
実施例用検体は、本発明に係る染毛組成物の実施例であるが、このうちポンプフォーム用の実施例用検体Ａ－１～Ａ－８は、使用時にノンエアゾールタイプのポンプフォーマーを用いて泡にするものであり、エアゾール用の実施例検体Ａ－９，Ａ－１０は、使用時にガスを用いたエアゾールで泡にするものである。 Samples for Examples are examples of the hair dyeing composition according to the present invention. Among them, Samples for Examples A-1 to A-8 for pump foams are non-aerosol type pump foamers at the time of use. Example specimens A-9 and A-10 for aerosol use an aerosol that uses a gas to make bubbles.
一方、カラーシャンプー用の比較例用検体Ｂ－１～Ｂ－８は、ラウリルジメチルアミノ酢酸ベタイン、ヤシ油脂肪酸アミドプロピルベタイン液、ポリオキシエチレンアルキル（１２，１３）エーテル硫酸ナトリウム（３Ｅ．Ｏ．）、テトラデセンスルホン酸ナトリウム液などのシャンプー（洗浄）成分を含むものである。 On the other hand, Comparative Samples B-1 to B-8 for Color Shampoo consisted of betaine lauryldimethylaminoacetate, coconut oil fatty acid amidopropyl betaine liquid, and sodium polyoxyethylene alkyl (12,13) ether sulfate (3E.O.D.). ), sodium tetradecene sulfonate solution and other shampoo (cleaning) ingredients.
なお、各実施例用検体における染料（ＨＣ染料、塩基性染料、直接染料、酸性染料）の配合量は、それぞれ０．０質量％より多く１．０質量％以下としている。 The amount of dyes (HC dyes, basic dyes, direct dyes, and acid dyes) in each example sample is more than 0.0 mass % and less than or equal to 1.0 mass %.
ここで、実施例用検体Ａ－１～Ａ－１０と比較例用検体Ｂ－１～Ｂ－８とを比較する。 Here, the samples A-1 to A-10 for the examples and the samples B-1 to B-8 for the comparative examples are compared.
［染毛方法］
長さ約１０ｃｍのヤギ毛（ビューラックス社製）毛束１ｇに各検体を泡立てて塗布（検体Ａ－１～Ａ－８はポンプフォーマー容器を用いて約２ｇを吐出。比較用検体Ｂ－１～Ｂ－８は約２ｇを手で泡立てて塗布。検体Ａ－９、Ａ－１０はエアゾール容器に充填し、ＬＰＧを用いて２ｇを塗布）し、２分間放置後、約４０℃の流水で３０秒間水洗、風乾した。
[Hair dyeing method]
Each sample was foamed and applied to 1 g of goat hair (manufactured by Beaulux) hair bundle of about 10 cm in length (Samples A-1 to A-8 discharged about 2 g using a pump former container. Comparative sample B- For 1 to B-8, about 2 g was foamed by hand and applied.For specimens A-9 and A-10, fill an aerosol container and apply 2 g using LPG), leave for 2 minutes, and then run water at about 40 ° C. was washed with water for 30 seconds and air-dried.
［評価方法］
色差計（ミノルタ株式会社製、ＭＩＮＯＬＴＡ ＳＰＥＣＴＲＯＰＨＯＴＯＭＥＴＥＲ ＣＭ－２６００ｄ）を用いてＣＩＥ表色系（Ｌ*ａ*ｂ*）で計測、下記式から染色前のヤギ毛をブランクとした色差ΔＥおよび彩度Ｃ*を算出した。
[Evaluation method]
Measured in the CIE color system (L*a*b*) using a color difference meter (MINOLTA SPECTROPHOTOMETER CM-2600d, manufactured by Minolta Co., Ltd.), color difference ΔE and chroma C using goat hair before dyeing as a blank from the following formula. * was calculated.
色差ΔＥ*＝［（ΔＬ*）２＋（Δａ*）２＋（Δｂ*）2］1/2
彩度Ｃ*＝［（Δａ*）2＋（Δｂ*）2］1/2
ΔＬ*：染毛前後のＬ*値の差
Δａ*：染毛前後のａ*値の差
Δｂ*：染毛前後のｂ*値の差
Color difference ΔE* = [(ΔL*) 2 + (Δa*) 2 + (Δb*) 2 ] 1/2
Saturation C*=[(Δa*) 2 +(Δb*) 2 ] 1/2
ΔL*: difference in L* value before and after hair dyeing Δa*: difference in a* value before and after hair dyeing Δb*: difference in b* value before and after hair dyeing
すなわち、色差（ΔＥ*）、彩度（Ｃ*）は未処理のヤギ毛を０としたとき、数値の大きい方が染着能力が高いことになる。 That is, when the color difference (ΔE*) and chroma (C*) are taken as 0 for untreated goat hair, the larger the values, the higher the dyeing ability.
そして、色差ΔＥ*、彩度Ｃ*の数値の大きい方が染着能力が高いことを踏まえ、下記の基準により染毛力を評価した。
◎：ヤギ毛が非常によく着色していることが目視でわかる。
○：ヤギ毛が着色していることが目視でわかる。
△：ヤギ毛があまり着色していないことが目視でわかる
Based on the fact that the larger the values of the color difference ΔE* and the chroma C*, the higher the dyeing ability, the hair dyeing ability was evaluated according to the following criteria.
⊚: It can be seen visually that the goat hair is very well colored.
◯: Coloring of goat hair can be visually observed.
△: It can be seen visually that the goat hair is not very colored.
［評価結果］
表１～４、及び、グラフ１，２に示すように、ポンプフォーマー用及びエアゾール用に試作した実施用検体Ａ－１～Ａ－１０は、従来品であるカラーシャンプーで試作した比較用検体Ｂ－１～Ｂ－８に比べて格段に染着度合いが高くなっていることがわかった。したがって本発明は、染毛組成物としてカラーシャンプーよりも好適である。
[Evaluation results]
As shown in Tables 1 to 4 and
本発明は、染毛組成物として好適である。 The present invention is suitable as a hair dyeing composition.
Claims (8)
ことを特徴とする染毛組成物（水、界面活性剤及び油で乳化された低粘度乳化物は除く）。 The hair dye composition is an aqueous solution containing at least one dye selected from HC dyes, basic dyes, direct dyes and acid dyes. Hair dyeing compositions (excluding low-viscosity emulsions emulsified with water, surfactants and oils).
ことを特徴とする請求項１に記載の染毛組成物。 2. The hair dyeing composition according to claim 1, which is foamed using a non-aerosol type pump foamer at the time of use.
ことを特徴とする請求項１に記載の染毛組成物。 2. The hair dyeing composition according to claim 1, which is foamed by aerosol using gas at the time of use.
ことを特徴とする請求項１又は２に記載の染毛組成物。 3. The hair dyeing composition according to claim 1 or 2, which is used singly or in combination before use.
ことを特徴とする請求項１から４のいずれか１項に記載の染毛組成物。 5. Any one of claims 1 to 4, wherein the foaming agent contains at least one of a cationic surfactant, an anionic surfactant, an amphoteric surfactant, and a nonionic surfactant. The hair dyeing composition according to .
ことを特徴とする請求項１から５のいずれか１項に記載の染毛組成物。 6. The pH adjuster according to any one of claims 1 to 5, comprising at least one of ammonium hydrogen carbonate, aqueous ammonia, monoethanolamine, AMP, ammonium chloride, and citric acid. Hair dyeing composition.
ことを特徴とする請求項１から６のいずれか１項に記載の染毛組成物。 7. The hair dyeing composition according to any one of claims 1 to 6, wherein the storage container form is not particularly limited as long as it is liquid and foams when used.
ことを特徴とする請求項１から７のいずれかに１項に記載の染毛組成物。
8. The hair dyeing composition according to any one of claims 1 to 7, which can be used continuously after a hair dye and enables color correction after hair coloring. .
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