KR101382140B1 - Air pollutants removal equipment with multifunction for effective scrubbing of particulate matter and gas absorption - Google Patents

Air pollutants removal equipment with multifunction for effective scrubbing of particulate matter and gas absorption Download PDF

Info

Publication number
KR101382140B1
KR101382140B1 KR1020130103611A KR20130103611A KR101382140B1 KR 101382140 B1 KR101382140 B1 KR 101382140B1 KR 1020130103611 A KR1020130103611 A KR 1020130103611A KR 20130103611 A KR20130103611 A KR 20130103611A KR 101382140 B1 KR101382140 B1 KR 101382140B1
Authority
KR
South Korea
Prior art keywords
gas
cleaning
absorption
cleaning absorption
module
Prior art date
Application number
KR1020130103611A
Other languages
Korean (ko)
Inventor
왕창근
김상진
Original Assignee
주식회사두합크린텍
충남대학교산학협력단
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by 주식회사두합크린텍, 충남대학교산학협력단 filed Critical 주식회사두합크린텍
Priority to KR1020130103611A priority Critical patent/KR101382140B1/en
Application granted granted Critical
Publication of KR101382140B1 publication Critical patent/KR101382140B1/en

Links

Images

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/14Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by absorption
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D47/00Separating dispersed particles from gases, air or vapours by liquid as separating agent
    • B01D47/02Separating dispersed particles from gases, air or vapours by liquid as separating agent by passing the gas or air or vapour over or through a liquid bath
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34Chemical or biological purification of waste gases
    • B01D53/74General processes for purification of waste gases; Apparatus or devices specially adapted therefor
    • B01D53/75Multi-step processes
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34Chemical or biological purification of waste gases
    • B01D53/74General processes for purification of waste gases; Apparatus or devices specially adapted therefor
    • B01D53/77Liquid phase processes
    • B01D53/78Liquid phase processes with gas-liquid contact
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02ATECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
    • Y02A50/00TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE in human health protection, e.g. against extreme weather
    • Y02A50/20Air quality improvement or preservation, e.g. vehicle emission control or emission reduction by using catalytic converters
    • Y02A50/2351Atmospheric particulate matter [PM], e.g. carbon smoke microparticles, smog, aerosol particles, dust
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P70/00Climate change mitigation technologies in the production process for final industrial or consumer products
    • Y02P70/10Greenhouse gas [GHG] capture, material saving, heat recovery or other energy efficient measures, e.g. motor control, characterised by manufacturing processes, e.g. for rolling metal or metal working

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Environmental & Geological Engineering (AREA)
  • Analytical Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Health & Medical Sciences (AREA)
  • Biomedical Technology (AREA)
  • Treating Waste Gases (AREA)
  • Gas Separation By Absorption (AREA)

Abstract

The present invention relates to an air pollutant removal apparatus with multifunction for the effective cleaning of particulates and gas absorption for removing exhaust gas from waste incinerator, polluting gas from industrial process, and bad smell substances in the air. The air pollutant removal apparatus with multifunction for the effective cleaning of particulates and gas absorption includes multiple cleaning absorption modules each of which consists of a cleaning absorption solution inlet, a cleaning absorption solution outlet, a gas-liquid separator, and a gas-liquid contact in a horizontal direction. The air pollutant removal apparatus with multifunction for the effective cleaning of particulates and gas absorption includes a polluting gas inlet, a treated gas outlet, and an undercurrent wall for the cleaning absorption modules so that the polluting gas can passes through the cleaning absorption modules in order, but the cleaning absorption solutions independently put in and out each cleaning absorption module so that various pollutants can be treated in one reactor according to the use of various cleaning absorption solutions. The gas-liquid contact includes a perforated plate, a gas-liquid contact media, and a polluting gas collision and undercurrent device so air pollutants such as bad smell substances, sulfur oxides, nitrogen oxides, carbon monoxide, carbon dioxide, volatile organic chemical materials, and lead can be effectively removed. [Reference numerals] (AA) Treated gas; (BB) Polluting gas; (CC) Blower; (DD) Cleaning absorption module 1; (EE) Cleaning absorption module 2; (FF) Cleaning absorption module 3; (GG) Cleaning absorption solution 1; (HH) Cleaning absorption solution 2; (II) Cleaning absorption solution 3

Description

분진 세정 및 가스 흡수가 효율적인 다기능 대기오염처리장치 {Air pollutants removal equipment with multifunction for effective scrubbing of particulate matter and gas absorption}Air pollutants removal equipment with multifunction for effective scrubbing of particulate matter and gas absorption}

본 발명은 보일러 및 폐기물 소각로의 배기가스, 산업공정으로부터의 오염가스, 공기 중의 악취물질 등의 처리 및 청정공기의 생산을 위한 다기능 대기오염 처리장치에 관한 것으로, 분진, 악취물질, 황산화물(SOx), 질소산화물(NOx), 일산화탄소(CO), 이산화탄소(CO2), 휘발성유기화합물질(VOC), 납과 같은 대기오염물질을 단시간에 고효율로 여러 종류의 세정흡수용액에 세정하거나 흡수시킴으로서 다양한 대기오염물질을 처리하고 장치의 소형화 및 운전의 용이성을 달성하고자 한 기술이다.The present invention relates to a multi-functional air pollution treatment apparatus for the treatment of exhaust gases from boilers and waste incinerators, polluting gases from industrial processes, odorous substances in the air, and the production of clean air, and includes dust, odorous substances, and sulfur oxides (SOx). Air pollutants such as nitrogen oxides (NOx), carbon monoxide (CO), carbon dioxide (CO 2 ), volatile organic compounds (VOC), and lead in a variety of cleaning and absorption solutions It is a technology that treats air pollutants and achieves compactness and ease of operation.

다기능 대기오염처리장치는 세정흡수모듈이 수평방향으로 여러개 연속하여 배열되어있고 세정흡수모듈별로 각각 다른 세정흡수용액을 유입시킬 수 있어 대기오염물질 종류별로 최적의 세정 및 흡수 효율을 달성할 수 있으며 세정흡수모듈과 세정흡수모듈 사이에는 세정흡수모듈분리용 수직저류벽을 설치하여 세정흡수용액의 섞임을 방지한다. The multifunctional air pollution treatment device has several cleaning absorption modules arranged in a row in the horizontal direction, and each cleaning absorption module can introduce different cleaning absorption solutions to achieve optimal cleaning and absorption efficiency for each type of air pollutant. A vertical reservoir wall is installed between the absorption module and the cleaning absorption module to prevent mixing of the cleaning absorption solution.

따라서, 여러 종류의 대기오염물질이 복합적으로 섞여있는 오염가스를 하나의 반응기 내에서 최적의 처리가 가능하게 되어 장치의 소형화와 운전의 용이성이 있는 기술이다.Therefore, the contaminated gas mixed with various types of air pollutants can be optimally processed in one reactor, and thus the device can be miniaturized and easily operated.

예로서, 발전소나 산업체 보일러 배기가스를 처리함에 있어서 분진과 아황산가스(SO2)는 물을 세정흡수용액으로 하여 제거하고, 이산화탄소(CO2)는 아민액과 같은 세정흡수용액을 이용하여 제거할 경우 매우 효과적인 기술이다.For example, in the treatment of exhaust gas from power plants or industrial boilers, dust and sulfur dioxide (SO 2 ) are removed using water as a cleaning absorption solution, and carbon dioxide (CO 2 ) is removed using a cleaning absorption solution such as an amine solution. If it is a very effective technique.

발전소나 공업용 보일러, 폐기물 소각로에서의 연소 과정에서 발생하거나 산업공정에서 배출되는 대기오염물질은 분진(Particulate matter), 황산화물(SOx), 질소산화물(NOx), 일산화탄소(CO), 이산화탄소(CO2), 휘발성유기화합물질(VOC), 납, 악취물질 등으로 다양하며 통상 복합적으로 존재한다.Air pollutants generated during combustion in industrial power plants, industrial boilers, waste incinerators, or emitted by industrial processes include particulate matter, sulfur oxides (SOx), nitrogen oxides (NOx), carbon monoxide (CO), and carbon dioxide (CO 2). ), Volatile organic compounds (VOC), lead, and odorous substances.

발전소에서는 사용연료에 따라 큰 차이가 있지만 분진, SOx, NOx, CO2를 다량 배출하고 폐기물소각로, 질산공장, 황산공장, 구리제련소, 제철공장 등에서도 다양한 대기오염물질이 배출되며 하수처리장에서는 악취물질 발생이 사회적 문제로 대두되기도 한다. Although there is a big difference depending on the fuel used at the power plant, a large amount of dust, SOx, NOx and CO 2 are emitted, and various air pollutants are emitted from waste incinerators, nitric acid plants, sulfuric acid plants, copper smelters, and steel mills. Outbreaks often become social problems.

대기오염물질의 제거를 위해 건식, 습식 등 매우 다양한 기술이 적용되고 있으며, 습식세정기술은 분진과 같은 입자상물질 뿐만 아니라 아황산가스와 같은 가스상 물질 제거에도 효과적이다. 최근에는 지구온난화의 주요원인 물질인 이산화탄소(CO2)의 포집이 매우 중요하게 되었다.To remove air pollutants, various technologies such as dry and wet are applied. Wet cleaning technology is effective for removing gaseous substances such as sulfurous acid gas as well as particulate matter such as dust. In recent years, the capture of carbon dioxide (CO 2 ), a major source of global warming, has become very important.

분진제거를 위한 습식방법으로 세정집진기(Wet scrubber)가 있다. 세정집진기는 물을 분사시켜 물액적(Liquid droplet)에 분진입자가 부착 제거되고 물액적은 중력에 의해 가스와 분리시키는 충돌과 차단의 원리가 적용된다. 세정집진기의 종류는 살수탑세정기, 원심력살수탑, 오리피스세정기, 충돌세정기, 충진판충돌세정기, 벤츄리세정기, 벤츄리젯트세정기, 기계식습식세정기 등 매우 다양하다. Wet scrubber is a wet method for dust removal. The scrubber is sprayed with water, and dust particles are attached to and removed from the liquid droplets, and the water droplets are applied to the collision and blocking principle of separating from the gas by gravity. The types of scrubbers are very diverse, such as sprinkling tower cleaners, centrifugal sprinkler towers, orifice cleaners, collision cleaners, packed plate collision cleaners, venturi cleaners, venturi jet cleaners, and mechanical wet cleaners.

살수탑세정기에서는 분진을 함유한 공기가 원통형이나 직사각형의 탑을 통과하고 살수노즐(Spray nozzles)에 의해 만들어진 액적(Liquid droplet)과 접촉한다. 액적의 크기는 분진과의 접촉을 최적화하고 공기흐름으로부터 쉽게 액적을 분리할 수 있도록 조절된다.In a sprinkler tower scrubber, air containing dust passes through a cylindrical or rectangular tower and contacts a liquid droplet created by spray nozzles. The droplet size is adjusted to optimize contact with dust and to easily separate the droplet from the air stream.

가스-액체 접촉방식은 향류(Counter current)와 교차류(Cross flow)가 있으며 기액접촉을 향상시키기 위해 차단벽(Baffle)이 사용되기도 한다.Gas-liquid contact has counter current and cross flow, and a baffle is also used to improve gas-liquid contact.

적절한 액적의 크기는 매우 높은 압력 35 ~ 50 Psi(25~30 mH2O)의 살수노즐에서 얻어지며 노즐의 청소와 교체가 살수탑 유지보수 중 중요한 부분을 차지한다. 수직형(Counter current flow)살수탑의 높이는 오염가스와 액적이 충분히 접촉할 수 있도록 6 ~ 9m 로 매우 높은 단점이 있고 수평형(Cross flow)살수탑은 길이가 매우 길어진다.Appropriate droplet sizes are obtained from spray nozzles with very high pressure 35 to 50 Psi (25 to 30 mH 2 O) and cleaning and replacement of nozzles is an important part of the tower maintenance. The counter current flow tower has a high disadvantage of 6 to 9m to allow sufficient contact with the pollutant gas and droplets. The cross flow tower is very long.

살수탑의 에너지 소비는 송풍기 및 세정액 공급펌프의 소요 동력에 따라 결정되며 구조적으로 물과 같은 단일세정액을 사용할 수밖에 없다.The energy consumption of the water tower is determined by the power required of the blower and the cleaning liquid supply pump, and structurally, a single cleaning liquid such as water is used.

원심력살수탑(Cyclone spray chamber)은 오염가스를 반응기내에 접선방향으로 빠르게 유입시키고 세정액은 중앙에서 바깥쪽으로 방사하는 형태로 분사시키며 원심력은 액적분리를 촉진시키나 송풍기에 의한 높은 압력이 요구되며 구조적으로 단일세정액을 사용할 수밖에 없다.The centrifugal spray chamber rapidly introduces contaminant gas into the reactor in a tangential direction and sprays the cleaning liquid from the center to the outside. The centrifugal force promotes droplet separation but requires high pressure by the blower and is structurally single. There is no choice but to use a cleaning solution.

오리피스세정기(Orifice scrubbers)에서는 오염가스가 세정액표면에 충돌한 후 연속적으로 설치된 차단벽(Baffle)에 충돌하도록 구성되어 있으며 습식충돌세정기에서는 기액혼합물이 세정액과 거품으로 뒤덮인 다공판(Perforated plate)을 통과한 후 구멍 상부에 설치된 판에 충돌하도록 되어있다. 송풍압력손실이 20 ~ 30 cmH2O로 높고 구조적으로 단일세정액을 사용할 수밖에 없다.In orifice scrubbers, contaminant gases impinge on the surface of the cleaning liquid and then impinge on the continuously installed baffles. In the wet collision cleaner, the gas-liquid mixture passes through the perforated plate covered with the cleaning liquid and foam. Afterwards, it collides with the plate installed in the upper part of the hole. Blowing pressure loss is high as 20 ~ 30 cmH 2 O, structurally forced to use a single cleaning liquid.

벤츄리세정기(Venturi scrubber)에서는 오염가스가 통과하는 벤츄리의 목부(Ventri throat)의 낮은 압력에 의해 세정액을 빨아들여 섞이면서 세정기로 유입되는 구조를 가지므로 설계가 간단한 반면 압력손실이 매우 큰 단점이 있다.Venturi scrubber has a structure that flows into the scrubber while sucking the scrubbing liquid by the low pressure of Venturi throat through which pollutant gas passes.

앞에서 열거한 선행기술에서는 기본적으로 물과 같은 단일 세정액을 여러 가지 수단으로 액적을 발생시켜 오염가스와 접촉하게 함으로써 빠른 오염가스 유속에 의한 비산액적동반배출(Entrainment)이 일어나게 된다. 따라서, 한줄차단막, 두줄차단막, W형분리기, 파형분리기, 눈물모양분리기 등의 비산액적동반배출방지장치(Entrainment eliminator)를 설치한다.In the above-mentioned prior art, a single cleaning liquid, such as water, is produced by droplets in various ways to come into contact with the polluting gas, thereby causing entrainment of splash droplets due to the rapid pollutant gas flow rate. Therefore, a non-droplet entrainment prevention device (Entrainment eliminator) such as a one-line barrier, two-line barrier, W-type separator, corrugated separator, tear-shaped separator and the like.

가스상 오염물질의 제거를 위해서 건식흡착(Adsorption)과 습식흡수(Absorption)방식이 사용되고 있다. 가스흡착은 건조 상태에서 활성탄, 활성알루미나, 실리카겔과 같은 흡착제를 이용한 악취물질제거, 벤젠, 에탄올과 같은 휘발성유기용매의 회수, 공정가스의 건조에 응용된다. 가스흡수는 처리목표 가스상 오염물질을 흡수용액에 용해시켜 제거하는 공정으로서 연소과정에서 발생되는 황산화물(SOx),비료공장에서의 암모니아 제거와 회수, 유리용광로 배기가스중의 불산(HF)제거, 아세톤, 메틸알콜 등의 수용성용매회수, 하수처리장이나 산업공정에서 발생되는 악취물질제거 등 다양하게 응용되고 있다.Adsorption and absorptive methods are used to remove gaseous contaminants. Gas adsorption is applied to remove odorous substances using adsorbents such as activated carbon, activated alumina, silica gel, recovery of volatile organic solvents such as benzene and ethanol, and drying of process gas in a dry state. Gas absorption is the process of dissolving the target gaseous contaminants in the absorption solution to remove sulfur oxides (SO x ) generated during the combustion process, ammonia removal and recovery from the fertilizer plant, and the removal of hydrofluoric acid (HF) from the glass furnace exhaust gases. It is widely used for water soluble solvent recovery such as acetone and methyl alcohol, and removing odorous substances generated in sewage treatment plant or industrial process.

가스흡수장치에서는 가스상 오염물질이 흡수용액에 전달되어 용해가 잘 일어날 수 있도록 즉 기액접촉면적을 크게 하기 위하여 여러 가지 모양의 충전재(Packings)를 채운 가스흡수장치의 상부에서 흡수용액을 살포하고 오염가스는 하부에 유입시켜 습윤 상태의 충전상(Packed bed)을 상향 통과하도록 하여 가스상 오염물질을 제거한다. 사용되고 있는 충전재로는 Berl saddle, Intalox saddle, Raschig ring, Lessing ring, Pall ring, Tellerette 등 다양한 모양이 있다. 충전재를 사용하는 가스흡수장치는 충전재에 의해 송풍기 압력손실이 높으며 구조물의 높이가 높고 충전재의 비용이 높은 단점이 있다.In the gas absorption device, the absorption liquid is sprayed from the upper part of the gas absorption device filled with various shapes of packing materials in order to increase the gas-liquid contact area so that the gaseous contaminants are transferred to the absorption solution and can be dissolved well. Flows downward to allow the packed bed in a wet state to pass upward to remove gaseous contaminants. There are various fillings such as Berl saddle, Intalox saddle, Raschig ring, Lessing ring, Pall ring, Tellerette. The gas absorber using the filler has the disadvantages of high blower pressure loss due to the filler, high structure height, and high cost of the filler.

가스유속이 빠르면 구조물 크기는 작아지나 동력비가 높아지게 되고 가스의 유속이 홍수점 또는 익류점(Flooding point)이상으로 높아지면 흡수용액이 상향가스유속에 의해 밀려 올라가는 현상이 발생되므로 가스유속은 홍수점 가스유속의 40 ~ 70% 정도에서 결정된다.If the gas flow rate is fast, the size of the structure will be smaller, but the power cost will be higher. If the gas flow rate is higher than the flood point or the flooding point, the absorbing solution will be pushed up by the upward gas flow rate. It is determined at about 40 to 70% of the flow rate.

선행 가스흡수장치 또한 구조적으로 단일 흡수용액을 사용할 수밖에 없는 단점이 있다. 예를 들어, 연소 후 배기가스중의 아황산가스(SO2)는 물에 잘 용해되어 물을 흡수액으로 사용할 수 있으나 질소산화물(NOx)은 용해율 측면에서 알칼리세정액이 흡수액으로 적합하다. 악취물질은 산화력이 있는 오존용해수나 염소용해수가 효과적이며 악취물질을 흡착제거할 수 있는 분말활성탄 슬러리도 사용될 수 있다. 따라서, 다양한 종류의 대기오염물질을 효과적으로 처리하기 위해서는 오염물질별로 적합한 세정흡수용액의 사용이 필요하다.
The prior gas absorber also has the disadvantage of structurally using a single absorption solution. For example, sulfurous acid gas (SO 2 ) in the exhaust gas after combustion is well dissolved in water, and water can be used as an absorbent, but nitrogen oxide (NOx) is suitable as an absorbent liquid in terms of dissolution rate. Ozone-soluble water and chlorine-soluble water having oxidative power are effective, and powdered activated carbon slurry capable of adsorbing and removing odorous substances can also be used. Therefore, in order to effectively treat various kinds of air pollutants, it is necessary to use an appropriate cleaning absorbing solution for each pollutant.

대한민국 등록특허 10-0349214 의 “다공판을 이용한 수처리 장치 및 방법”은 본원 출원인에 의해 출원된 것으로 반응조에 다단의 다공판을 위치시키고 산기기기에서 배출되는 용존성기체의 기포가 부력에 의해 상승하면서 다공판에 걸려 체류함은 물론 다공판의 구멍을 통과함에 따라 잘게 쪼개져 기체의 용존 효율을 극대화한 기술이다."Water treatment apparatus and method using a porous plate" of the Republic of Korea Patent Registration No. 10-0349214 has been filed by the applicant of the present application to place the porous plate of the multi-stage in the reaction tank and as the bubbles of the dissolved gas discharged from the acid machine rises by buoyancy As well as staying in the perforated plate as well as passing through the hole of the perforated plate is chopped finely to maximize the dissolved efficiency of the gas.

대한민국 등록특허 10-1010893 의 “상수 및 하폐수 처리용 가스용해장치”는 본원 출원인에 의해 출원된 것으로 상기 가스용해 장치는 다공판, 기포포집 및 용해모듈, 기포부탈착 매체로 구성되어 있으며 다공판은 기포의 체류시간을 증대시키고 기포를 작게 쪼갬으로서 가스용해가 효과적으로 일어나도록 하였고 옆면에 다공 구조를 갖는 기포포집 및 용해모듈은 기포를 포집하고 저류할 수 있어 가스의 체류시간을 증가시킴과 동시에 처리대상수와 가스가 혼합될 수 있도록 하였고 기포부 탈착매체에서는 작은 기포가 매체표면에 부착하여 탈착될 때까지 기포의 체류시간을 증가시키고자 한 기술이다."Gas dissolving device for water and sewage treatment" of the Republic of Korea Patent Registration 10-1010893 has been filed by the applicant of the present application, the gas dissolving device is composed of a porous plate, bubble collection and dissolution module, bubble desorption medium and the porous plate is By increasing the residence time of bubbles and splitting the bubbles into small pieces, gas dissolution is effectively caused. Bubble collecting and dissolving modules with a porous structure on the side can collect and store bubbles, increasing the residence time of gases and simultaneously The technique allows water and gas to be mixed and increases the residence time of bubbles until small bubbles adhere to the surface of the media in the bubble desorption medium.

대한민국 등록특허 10-1163097 의 “상수 및 하폐수처리용 틈새구조형 가스용해장치”는 본원 출원인에 의해 출원된 것으로 반응조내에 저류판, 기포포집 및 용해모듈, 저류판과 저류판사이의 틈새, 저류판과 기포포집 및 용해모듈사이의 틈새, 기포포집 및 용해모듈과 기포포집 및 용해모듈사이의 틈새가 형성되어 저류판은 하부로부터 부력에 의해 상승하는 기포가 저류판 하부에 부딪히면서 저류되고 하부로부터 올라오는 상승 기포와 충돌하여 점점 커지는 과정에서 가스체류시간의 증가와 함께 가스용해가 지속되고 기포포집 및 용해모듈은 내부공간에 가스저류공간과 가스용해경계면을 형성시킴으로서 가스체류시간의 증가와 함께 가스용해를 지속시키고자 한 기술이다."Gap structure gas dissolving device for water and sewage treatment" of Korean Patent Registration No. 10-1163097 has been filed by the applicant of the present application, and the gap between the reservoir plate, bubble collection and dissolution module, reservoir plate and reservoir plate, reservoir plate and bubble in the reactor The gap between the trapping and dissolving module, the bubble trapping and the gap between the dissolving module and the bubble trapping and dissolving module is formed so that the reservoir plate rises from the bottom as buoyant bubbles rise by buoyancy from the bottom and rises from the bottom. And gas dissolution continues with increasing gas retention time in the process of colliding with the gas, and the bubble trapping and dissolution module forms gas storage space and gas dissolving boundary in the internal space, thereby continuing gas dissolution with increasing gas residence time. It's a technology.

종래의 세정집진기는 노즐을 이용하여 고압의 단일 세정액을 분사하여 생성되는 액적과 오염가스중의 분진을 접촉시키는 구조로서 구조물 높이가 높거나 길고 노즐의 막힘 문제와 세정액펌프의 에너지 소비가 높은 단점이 있다. 또한, 습식 가스흡수장치도 단일 흡수액을 충전재 위에서 분사시키고 충전재 표면을 흐르는 흡수액에 가스상 오염물질이 용해되어 제거되는 구조로서 구조물 높이가 높고 단일 흡수액을 사용할 수밖에 없는 단점이 있다. 특히, 배기가스로부터 지구온난화의 원인이 되는 이산화탄소(CO2)를 포집할 경우 아황산가스 흡수를 위한 물과 같은 일반 세정흡수용액으로는 포집효율이 낮아 아민액과 같은 특수 용매가 사용되므로 선행기술을 적용할 때는 2개 이상의 흡수시스템을 독립적으로 설치해야하므로 구조물 크기가 커짐에 따라 건설비가 높아지고 운전유지관리가 불편해지는 단점이 있다. 질소산화물(NOx)의 흡수에는 알칼리세정액이 효과적이므로 물 이외에 추가적인 세정용액 분사 시스템이 필요하게 된다. 또한, 종래의 기술에서는 분사된 세정용액 액적이 오염가스의 빠른 상승유속으로 인하여 동반 배출되므로 유출부쪽에 비산액적동반배출방지장치(Entrainment eliminator)를 설치해야 한다.
Conventional cleaning and dust collecting apparatus has a structure in which dusts generated by jetting a single high-pressure cleaning liquid are brought into contact with dust in the polluted gas by using nozzles, and the height of the structure is high or long and the problem of clogging of the nozzles and energy consumption of the cleaning liquid pump are high have. In addition, the wet gas absorber is a structure in which a single absorbent liquid is sprayed on the filler and the gaseous contaminants are dissolved and removed in the absorbent liquid flowing through the filler surface. In particular, when capturing carbon dioxide (CO 2 ) that causes global warming from exhaust gases, a special solvent such as an amine liquid is used as a general cleaning absorption solution such as water for absorbing sulfurous acid gas, so that a special solvent such as an amine liquid is used. When applied, two or more absorption systems must be installed independently. As the size of the structure increases, the construction cost increases and operation maintenance becomes inconvenient. Alkaline cleaning solution is effective for the absorption of nitrogen oxides (NOx), so additional cleaning solution injection system is required in addition to water. In addition, in the prior art, since the sprayed cleaning solution droplets are discharged together due to the rapid rising flow rate of the polluting gas, it is necessary to install an scattering drop entrainment prevention apparatus (Entrainment eliminator) on the outlet side.

따라서, 본 발명은 본 출원인의 선 특허인 대한민국 특허 제10-0349214(“다공판을 이용한 수처리장치 및 방법”), 제10-1010893(“상수 및 하폐수 처리용 가스용해장치”), 제10-1163097(“상수 및 하폐수 처리용 틈새구조형 가스용해장치”)의 기술을 조합하여 오염가스처리에 적합하도록 세정흡수모듈을 구성함과 동시에 수평방향으로 여러개 연속하여 배열하고, 세정흡수모듈분리용 수직저류벽을 설치함으로써 세정흡수용액이 세정흡수모듈별로 독립적으로 유출입 되도록 함에 따라 하나의 반응기내에서 여러 종류의 세정흡수액을 사용할 수 있도록 하여 다양한 대기오염물질을 효율적으로 처리할 수 있도록 개발하였다.Accordingly, the present invention relates to Korean Patent Nos. 10-0349214 (“Water Treatment Apparatus and Method Using Porous Plates”), 10-1010893 (“Gas Dissolving Device for Water and Wastewater Treatment”), 10-03. Combination of the technology of 1163097 (“Gap structure gas dissolving device for water and sewage treatment”) constitutes a cleaning absorption module suitable for pollutant gas treatment, and is arranged in series in the horizontal direction and vertical storage for separation of the cleaning absorption module. By installing the wall, the cleaning absorbent solution can be flowed out independently by each cleaning absorber module, so that various kinds of cleaning absorbent solution can be used in one reactor, so that various air pollutants can be efficiently treated.

본 발명에서는 세정흡수용액 유입구, 세정흡수용액 유출구, 세정흡수용액 기액분리기, 기액접촉부로 구성된 세정흡수모듈을 수평방향으로 여러개 연속하여 배열하고 각 세정흡수모듈을 세정흡수모듈분리용 수직저류벽을 이용하여 분리시켜 오염가스는 각 세정흡수모듈을 차례로 통과할 수 있으나 세정흡수용액은 각 모듈별로 독립적으로 유출입 하도록 하여 여러 종류의 세정흡수용액 사용에 따라 여러 종류의 대기오염물질이 하나의 반응기내에서 처리가 가능해지도록 한다.
In the present invention, a plurality of cleaning absorbent modules consisting of a cleaning absorbent solution inlet, a cleaning absorbent solution outlet, a cleaning absorbent solution gas-liquid separator, and a gas-liquid contact unit are arranged in succession in the horizontal direction, and each cleaning absorbent module uses a vertical reservoir wall for separating the cleaning absorbent module. The pollutant gas can pass through each cleaning absorption module in turn, but the cleaning absorption solution can flow in and out independently for each module, so that various kinds of air pollutants can be treated in one reactor according to the use of various cleaning absorption solutions. Make it possible.

또한, 오염가스와 세정흡수용액간에 효과적인 접촉을 위해 다공판, 틈새, 오염가스충돌 및 저류기, 기액접촉매체를 조합하여 기액접촉부를 구성한다.In addition, the gas-liquid contact unit is constructed by combining a porous plate, a gap, a contaminant gas collision and reservoir, and a gas-liquid contact medium for effective contact between the polluting gas and the cleaning absorbing solution.

본 기액접촉부에서는 오염가스중의 대기오염물질이 분사된 액적으로 이동되는 종래의 세정흡수방식과는 달리 다공판, 틈새 등으로부터 생성되는 오염가스기포중의 대기오염물질이 세정액으로 부착, 용해되는 현상이 이용되므로 다공판에 의한 기포쪼개짐, 난류에 의한 기액혼합, 기액접촉매체에 의한 기액접촉, 오염가스충돌 및 저류기에 의한 기액접촉은 효과적으로 달성되는 반면 비산액적동반배출현상은 매우 낮게 나타나도록 한다.Unlike the conventional cleaning and absorption method in which the air pollutants in the polluted gas are injected into the liquid droplets, the air-liquid contact part attaches and dissolves the air pollutants in the polluted gas bubbles generated from the porous plate and the gap into the cleaning liquid. Because of this use, bubble splitting by porous plates, gas-liquid mixing by turbulent flow, gas-liquid contact by gas-liquid contact medium, contaminated gas collision, and gas-liquid contact by reservoir are effectively achieved while scattering liquid dropping discharge is very low.

종래의 선행기술에서는 습식세정탑 구조물의 높이, 고압노즐유지관리, 비산액적동반배출 문제가 있는 반면 본 발명에서는 장치의 높이가 현저히 낮으며 최소한의 기액접촉부에서 강력한 기액접촉이 단시간에 이루어지는 효과가 있고 특히, 수평방향으로 연속하여 배열된 여러 개의 세정흡수모듈에 여러 종류의 세정흡수용액 사용이 가능해져 여러 종류의 대기오염물질이 하나의 반응기내에서 처리되는 효과가 있다. 또한, 기액접촉원리상 본 발명의 장치에서는 비산액적동반배출현상이 매우 낮게 나타나는 효과가 있다.In the prior art, the height of the wet scrubber structure, high pressure nozzle maintenance, and scattered liquid dropping discharge problems, while in the present invention, the height of the device is significantly lower, and the strong gas-liquid contact in the minimum gas-liquid contact portion is effective in a short time. In particular, it is possible to use several types of cleaning absorbing solutions in a plurality of cleaning absorbing modules arranged in a horizontal direction, so that various types of air pollutants are treated in one reactor. In addition, in the liquid-liquid contact principle, the apparatus of the present invention has an effect of exhibiting very low splash liquid dropping discharge phenomenon.

도1은 본 발명의 세정흡수용액 유입구, 세정흡수용액 유출구, 세정흡수용액 기액분리기, 기액접촉부로 구성된 세정흡수모듈과 세정흡수 모듈분리용 수직저류벽을 구비한 다기능 대기오염처리장치의 단면도.
도2는 본 발명의 기액접촉부 구성예시도.
도3은 본 발명의 오염가스 균등유입 유도용 수직저류벽과 수평 다공판의 위치도.
도4는 본 발명의 세정흡수용액 기액분리기 구조도.
1 is a cross-sectional view of a multi-functional air pollution treatment apparatus having a cleaning absorption module consisting of a cleaning absorption solution inlet, a cleaning absorption solution outlet, a cleaning absorption solution gas-liquid separator, and a gas-liquid contact portion, and a vertical storage wall for separating the cleaning absorption module.
Figure 2 is an exemplary configuration of the gas-liquid contact portion of the present invention.
Figure 3 is a position view of the vertical reservoir wall and the horizontal porous plate for inducing the influent pollutant inflow of the present invention.
Figure 4 is a structure of the cleaning absorbing solution gas-liquid separator of the present invention.

본 발명의 실시에 대한 구체적인 내용을 도1 내지 도4를 참조하며 상세히 설명한다. 도1에 예시한 바와 같이 대기오염처리장치(1)는 세정흡수용액 유입구(10), 세정흡수용액 유출구(11), 세정흡수용액 기액분리기(12), 오염가스 균등유입 유도용 수직저류벽(3), 세정흡수모듈 하부공간(4), 기액접촉부(5), 세정흡수모듈 상부공간(9)으로 구성된 세정흡수모듈(2)이 수평방향으로 여러개 연속하여 배열되고 송풍기, 오염가스 유입구(13), 처리가스 유출구(14), 세정흡수모듈분리용 수직저류벽(15)으로 구성된다. Detailed description of the implementation of the present invention will be described in detail with reference to FIGS. As illustrated in FIG. 1, the air pollution treatment device 1 includes a cleaning absorbing solution inlet 10, a cleaning absorbing solution outlet 11, a cleaning absorbing solution gas-liquid separator 12, and a vertical reservoir wall for inducing inflow of polluted gas. 3), the cleaning absorbing module lower space (4), the gas-liquid contacting portion (5), the cleaning absorbing module upper space (9) consisting of a plurality of cleaning absorbing modules arranged in succession in the horizontal direction, blower, polluted gas inlet (13) ), The processing gas outlet 14, and the vertical storage wall 15 for separating the cleaning absorbing module.

송풍기에 의해 상기 대기오염처리장치(1)의 오염가스 유입구(13)로 유입된 오염가스는 송풍압력에 의해 세정흡수모듈(2)의 오염가스 균등유입 유도용 수직저류벽(3)하단과 대기오염처리장치(1)의 바닥면사이의 틈새공간을 통과하여 세정흡수모듈 하부공간(4)으로 균일하게 유입된다. 유입의 균일성확보를 위해 오염가스 균등유입 유도용 수직저류벽(3)의 하단은 수평을 이루도록 설치하는 것이 중요하다.The polluted gas introduced into the polluted gas inlet 13 of the air pollution treatment device 1 by the blower is blown under the vertical reservoir wall 3 for inducing the equal flow of polluted gas of the cleaning absorption module 2 and the atmosphere. It passes evenly through the gap space between the bottom surface of the pollution treatment device 1 into the cleaning absorbing module lower space (4). In order to ensure uniformity of inflow, it is important to install the lower end of the vertical reservoir wall 3 for inducing the inflow of polluted gas equally horizontally.

세정흡수모듈 하부공간(4)으로 유입된 오염가스는 압력에 의해 세정흡수용액 유입구(10)를 통하여 지속적으로 유입,저류,유출되고있는 세정흡수용액을 밀어 올리면서 상승하여 세정흡수모듈(2)의 기액접촉부(5)하부의 수평다공판(6)을 통과하게 된다.The polluted gas introduced into the lower portion of the cleaning absorbing module 4 rises while pushing up the cleaning absorbing solution that is continuously introduced, stored, or discharged through the cleaning absorbing solution inlet 10 by the pressure. It passes through the horizontal porous plate 6 of the lower portion of the gas-liquid contact portion (5).

도3에 나타낸 바와 같이 오염가스 균등유입 유도용 수직저류벽(3)하단과 수평다공판(6)의 위치를 비슷하게 함으로써 구조물의 높이를 최소화할 수 있으며 가스유입 수평틈새 높이는 실험결과 1 ~ 5cm 정도면 충분하다.As shown in Fig. 3, the height of the structure can be minimized by making the position of the bottom of the vertical reservoir wall 3 and the horizontal perforated plate 6 similar for inducing the inflow of polluting gas evenly, and the horizontal clearance height of the gas inflow is about 1 to 5 cm. Is enough.

수평다공판(6)을 통과하는 오염가스는 다공판의 구멍에 의해 작은 기포로 쪼개진다. 구멍의 직경은 0.5 ~ 2mm가 적당하며 단위면적당 구멍의 개수는 송풍압력손실에 영향을 준다. 작게 쪼개진 기포는 부력과 압력에 의해 상승하면서 기액접촉이 이루어지고 이 과정에서 대기오염물질이 세정흡수용액으로 이동하여 제거된다.The polluted gas passing through the horizontal porous plate 6 is split into small bubbles by the holes of the porous plate. The diameter of the hole is suitable for 0.5 ~ 2mm and the number of holes per unit area affects the blowing pressure loss. The small broken bubbles rise by buoyancy and pressure to make gas-liquid contact, and in this process, air pollutants are removed by moving to the cleaning absorbing solution.

도1 및 도2에 나타낸 바와 같이 기액접촉부(5)내 수평다공판(6)을 지지대로 하여 기액접촉매체(7)를 포설할 수 있다. 기액접촉매체(7)는 섬유사, 쇄석, 석회석펠릿(Pellet), 다양한 모양의 충전재(Packings)등으로 용도에 적합하게 선택하여 구성한다. 다양한 기액접촉매체(7)의 표면에 상승하는 기포가 충돌하면 강한 난류가 발생하면서 기액접촉효과가 증대되고, 또한 작은 기포는 충전재 표면에 부착 및 탈착과정을 거치면서 기액접촉시간을 늘려준다.As shown in Figs. 1 and 2, the gas-liquid contact medium 7 can be laid with the support of the horizontal porous plate 6 in the gas-liquid contact portion 5 as a support. The gas-liquid contact medium 7 is made of fiber yarn, crushed stone, limestone pellets, packings of various shapes, and the like. When rising bubbles collide with the surface of the various gas-liquid contact medium 7, strong turbulence occurs, the gas-liquid contact effect is increased, and small bubbles increase the gas-liquid contact time while going through the attachment and desorption process on the filler surface.

기액접촉부(5)내에는 상기 수평다공판(6)이나 기액접촉매체(7)이외에 오염가스충돌 및 저류기(8)를 설치할 수 있다. 오염가스충돌 및 저류기(8)는 “ㄷ”자형 앵글을 뒤집어 놓은 형상으로 하부로부터 상승하는 기포를 오염가스충돌 및 저류기(8)내부 상단에 충돌시키고 포집, 저류시킴으로써 기액접촉을 유발시키는 구조이다.In the gas-liquid contacting portion 5, a contaminant gas collision and a reservoir 8 may be provided in addition to the horizontal porous plate 6 or the gas-liquid contacting medium 7. The polluted gas collision and reservoir (8) is a structure in which gas bubbles are contacted by colliding, collecting, and storing the bubbles rising from the bottom in the shape of the “c” shaped angle upside down on the top of the inside of the pollutant gas collision and the reservoir (8). to be.

수평타공판(6), 기액접촉매체(7), 오염가스충돌 및 저류기(8)는 기포쪼개짐, 기액혼합난류, 가스충돌 및 저류의 기작(Mechanism)에 의해 기액접촉이 효과적으로 일어나므로 지지대(Support)역할을 하는 수평타공판(6)을 설치하고 그 위에 기액접촉매체와 오염가스충돌 및 저류기를 필요에 따라 조합하여 설치하는 것이 바람직하다.Horizontal perforated plate (6), gas-liquid contact medium (7), polluted gas collision and reservoir (8) is effectively supported by the gas-liquid contact by the mechanism of gas splitting, gas-liquid mixed turbulence, gas collision and storage (Support) It is preferable to install the horizontal perforated plate 6, which serves as a combination thereof, and to combine the gas-liquid contact medium, the contaminated gas collision, and the reservoir as necessary.

오염가스가 기액접촉부(5)를 통과하는 과정에서 오염가스에 함유된 분진, 악취물질, 황산화물(SOx), 질소산화물(NOx), 일산화탄소(CO), 이산화탄소(CO2), 휘발성유기화합물질(VOC), 납과 같은 대기오염물질이 제거된다.Dust, malodorous substances, sulfur oxides (SOx), nitrogen oxides (NOx), carbon monoxide (CO), carbon dioxide (CO 2 ), volatile organic compounds (VOC), air pollutants such as lead are removed.

기액접촉부(5)를 통과한 가스는 세정흡수모듈 상부공간(9)과 세정흡수모듈분리용 수직저류벽(15)의 상단 열린 공간을 통하여 다음 세정흡수모듈(2)로 이동한다.The gas passing through the gas-liquid contacting part 5 moves to the next cleaning absorption module 2 through the upper space of the upper portion of the cleaning absorption module upper space 9 and the vertical storage wall 15 for separating the cleaning absorption module.

세정흡수모듈(2)의 세정흡수용액 유입구(10)를 통하여 세정흡수모듈(2)내로 유입된 세정흡수용액은 기액접촉부(5)에서 오염가스와의 접촉에 의해 대기오염물질을 교환한 후 적정 체류시간을 거쳐 세정흡수용액 유출구(11)를 통하여 배출된다.The cleaning absorbing solution introduced into the cleaning absorbing module 2 through the cleaning absorbing solution inlet 10 of the cleaning absorbing module 2 is replaced with an air pollutant at the gas-liquid contacting part 5 by an air pollutant. It is discharged through the cleaning absorption solution outlet 11 through the residence time.

체류시간은 기액접촉부(5)의 체적과 세정흡수용액의 유량에 의해 결정되며 제거대상 대기오염물질의 종류와 농도, 사용되는 세정흡수용액, 목표제거율 등을 고려하여 정한다.The residence time is determined by the volume of the gas-liquid contact portion 5 and the flow rate of the cleaning absorbing solution, and is determined in consideration of the type and concentration of the air pollutant to be removed, the cleaning absorbing solution used, and the target removal rate.

세정흡수용액을 배출함에 있어 기액접촉부(5)내의 세정흡수용액은 기액혼합물이므로 배출되기 전에 가스는 배제되어야 한다. 따라서, 도4에 나타낸 바와 같이 상부가 열려있는 상자(Box)형상의 세정흡수용액 기액분리기(12)를 세정흡수모듈(2) 내부에 부착 설치한다.In discharging the cleaning absorbent solution, the cleaning absorbent solution in the gas-liquid contacting portion 5 is a gas-liquid mixture, so that gas must be excluded before being discharged. Therefore, as shown in FIG. 4, the box-shaped box for cleaning absorption solution gas-liquid separator 12 is provided with the cleaning absorption module 2. Attach and install inside.

세정흡수용액 기액분리기(12)의 바닥면은 하부 즉 수평다공판(6)으로부터 세정흡수용액 유출구(11)부근으로 상승하는 기포를 차단한다. 세정흡수용액 기액분리기(12)상부는 열린 형상으로, 기액접촉부(5)내 기액혼합물 중 가스기포는 위쪽으로 상승하고 세정흡수용액은 월류하여 세정흡수용액 기액분리기(12)내부 바닥으로 흘려들어가 고이게 되며 이를 세정흡수용액 유출구(11)를 통하여 배출한다.The bottom surface of the cleaning absorbing solution gas-liquid separator 12 blocks air bubbles rising from the lower portion, that is, the horizontal porous plate 6, to the vicinity of the cleaning absorbing solution outlet 11. The upper portion of the cleaning absorbing solution gas-liquid separator 12 is open, and the gas bubbles in the gas-liquid mixture in the gas-liquid contacting part 5 rise upwards and the cleaning absorbing solution flows over to flow into the bottom of the cleaning absorbing solution gas-liquid separator 12. This is discharged through the cleaning absorbent solution outlet (11).

위에 기술된 사항은 하나의 세정흡수모듈 즉, 도1의 세정흡수모듈1에서 세정흡수용액1을 사용한 예이며 세정흡수모듈1에서 오염가스가 처리된 후 필요에 따라 세정흡수모듈2, 세정흡수용액2를 거치게 함으로써 다양한 대기오염물질을 효과적으로 처리한다.The above-described matter is an example of using the cleaning absorbing solution 1 in the cleaning absorbing module 1, that is, the cleaning absorbing module 1 of FIG. 1. By going through 2, it effectively handles various air pollutants.

전술한 바와 같이 본 발명은 여러 개의 세정흡수모듈별로 기액접촉부의 구성을 필요에 따라 다르게 할 수 있으며 세정흡수용액도 모듈별로 필요에 따라 다르게 선택할 수 있는 장점이 있다.As described above, the present invention can vary the configuration of the gas-liquid contact portion for each of the plurality of cleaning absorption modules, and the cleaning absorption solution can also be selected differently according to the needs of the modules.

각각의 세정흡수모듈(2)의 상부에 처리가스 유출구(14)를 장착하여 처리가스 유출구(14)의 밸브개폐 및 세정흡수용액 공급여부에 따라 개별 세정흡수모듈(2)의 운전여부를 선택할 수도 있다.The treatment gas outlet 14 may be mounted on the upper portion of each cleaning absorption module 2 to select whether to operate the individual cleaning absorption module 2 according to the valve opening and closing of the treatment gas outlet 14 and whether the cleaning absorption solution is supplied. have.

예로서, 도1의 3개의 세정흡수모듈(2)중 1번, 2번의 처리가스 유출구(14)를 닫고 세정흡수용액을 모든 모듈에 공급하면 3개 모듈을 모두 운전하게 되며 처리가스는 3번모듈을 거친 후 최종 배출된다.For example, if one of the three cleaning absorbing modules 2 of FIG. 1 is closed and the processing gas outlet 14 of FIG. 1 is closed and the cleaning absorbing solution is supplied to all the modules, all three modules are operated and the processing gas is 3 times. After passing through the module, it is finally discharged.

반면에 1번 및 2번 처리가스 유출구를 닫고 세정흡수용액을 3번모듈에만 공급하면 3번 세정흡수모듈만 운전하게 된다.On the other hand, if the process gas outlets 1 and 2 are closed and the cleaning absorption solution is supplied only to the module 3, only the cleaning absorption module 3 is operated.

하수처리장 등에서 발생하는 악취물질이나 산업공정에서 발생하는 휘발성유기화합물질(VOC)은 오존과 같은 산화가스에 의해 산화 제거된다. 오염가스 유입구(13)에 산화 또는 환원가스를 주입하면 오염가스와 주입된 가스가 혼합된 상태로 세정흡수모듈로 유입된 후 가스상태 및 물과 같은 세정흡수용액에 용존된 상태에서 산화 또는 환원 반응하여 오염물질을 제거하므로 산화 또는 환원가스의 본 대기오염처리장치로의 유입이 효과적인 경우가 있다.Odor substances generated in sewage treatment plants and the like or volatile organic compounds (VOCs) produced in industrial processes are oxidized and removed by oxidizing gases such as ozone. When the oxidizing or reducing gas is injected into the polluting gas inlet 13, the oxidizing or reducing reaction is introduced into the cleaning absorption module in a state in which the polluting gas and the injected gas are mixed, and then dissolved in a cleaning absorbing solution such as gas and water. In order to remove pollutants, inflow of oxidizing or reducing gas into the air pollution treatment device may be effective.

선택할 수 있는 세정흡수용액은 매우 다양하다. 예로서, 일반적으로 가장 많이 사용되는 물, 그리고 아민액과 같은 이산화탄소 흡수액, 분말활성탄, 제올라이트, 활성알루미나와 같은 흡착제 슬러리, 황산화물(SOx)제거를 위한 분말석회석 슬러리, NOx제거를 위한 알칼리세정액, 오염물질의 산화 제거를 위한 오존용해수나 염소용해수 등이 있다.There is a wide variety of cleaning and absorption solutions to choose from. For example, most commonly used water and carbon dioxide absorbents such as amine liquids, powdered activated carbon, zeolites, adsorbent slurries such as activated alumina, powdered limestone slurries for SOx removal, alkaline cleaning solutions for NOx removal, Ozone dissolved water or chlorine dissolved water for oxidative removal of pollutants.

1 : 대기오염처리장치 2 : 세정흡수모듈
3 : 오염가스 균등유입 유도용 수직저류벽
4 : 세정흡수모듈 하부공간 5 : 기액접촉부
6 : 수평다공판(기액접촉매체 지지대)
7 : 기액접촉매체 8 : 오염가스충돌 및 저류기
9 : 세정흡수모듈 상부공간 10 : 세정흡수용액 유입구
11 : 세정흡수용액 유출구 12 : 세정흡수용액 기액분리기
13 : 오염가스 유입구 14 : 처리가스 유출구
15 : 세정흡수모듈분리용 수직저류벽
1: air pollution treatment device 2: cleaning absorption module
3: Vertical reservoir wall for inducing inflow of polluted gas uniformly
4: Lower space of cleaning absorption module 5: Gas-liquid contact part
6: horizontal perforated plate (liquid contact medium support)
7: Gas-liquid contact medium 8: Contaminated gas collision and storage
9: upper space of cleaning absorption module 10: cleaning absorption solution inlet
11: cleaning absorption solution outlet 12: cleaning absorption solution gas-liquid separator
13: polluted gas inlet 14: treated gas outlet
15: Vertical storage wall for cleaning absorption module separation

Claims (9)

세정흡수용액 유입구, 세정흡수용액 유출구, 세정흡수용액 기액분리기, 오염가스 균등유입 유도용 수직저류벽, 세정흡수모듈 하부공간, 기액접촉부, 세정흡수모듈 상부공간으로 구성된 세정흡수모듈이 수평방향으로 하나 또는 다수가 연속되게 구비되고 송풍기, 오염가스 유입구, 처리가스 유출구, 세정흡수 모듈분리용 수직저류벽이 형성된 대기오염처리장치에 있어서,
오염가스 유입구로 유입된 오염가스는 송풍압력에 의해 상기 세정흡수모듈의 오염가스 균등유입 유도용 수직저류벽 하부를 통과하여 세정흡수모듈 하부공간으로 균일하게 유입되고, 유입된 오염가스는 압력과 부력에 의해 상승하여 기액접촉부로 이동하면서 기포쪼개짐, 기액혼합난류, 가스충돌 및 저류, 기액접촉매체 등에 의한 효과적인 기액접촉이 이루어지는 과정에서 오염가스에 함유된 분진, 악취물질, 황산화물(SOx), 질소산화물(NOx), 일산화탄소, 이산화탄소, 휘발성유기화합물질(VOC), 납과 같은 대기오염물질이 세정흡수용액 유입구를 통하여 세정흡수모듈 내로 유입된 세정흡수용액으로 빠르게 이동하여 제거되고, 세정흡수용액은 세정흡수용액 기액분리기에 의해 가스가 배제된 후 세정흡수용액 유출구를 통하여 배출되며, 오염가스는 세정흡수모듈분리용 수직저류벽 상부를 통과한 후 다음의 세정흡수모듈로 이동하여 대기오염물질이 제거됨을 반복하고 최종적으로 처리가스 유출구를 통하여 배출되는 구조적 특징을 갖는 다기능 대기오염처리장치.
Cleaning absorption module consisting of cleaning absorption solution inlet, cleaning absorption solution outlet, cleaning absorption solution gas-liquid separator, vertical reservoir wall for inducing inflow of polluting gas, cleaning absorption module lower space, gas-liquid contacting part, and cleaning absorption module upper space Or in the air pollution treatment apparatus is provided with a plurality in series and formed with a blower, polluting gas inlet, processing gas outlet, the vertical reservoir wall for separating the cleaning absorption module,
The polluted gas introduced into the polluted gas inlet is uniformly introduced into the lower space of the cleansing absorbing module through the lower portion of the vertical storage wall for inducing the equal flow of polluting gas of the cleansing absorbing module by the blowing pressure, and the introduced contaminated gas is the pressure and buoyancy force. As it moves up to the gas-liquid contact part, dust, odorous substances, sulfur oxides (SOx) and nitrogen contained in the contaminated gas during the effective gas-liquid contact by bubble splitting, gas-liquid mixed turbulence, gas collision and storage, gas-liquid contact medium, etc. Atmospheric pollutants such as oxides (NOx), carbon monoxide, carbon dioxide, volatile organic compounds (VOC), and lead are quickly removed and removed from the cleaning absorbing solution through the cleaning absorbing solution inlet, and the cleaning absorbing solution is removed. After the gas is removed by the cleaning absorbing solution gas-liquid separator, it is discharged through the cleaning absorbing solution outlet. Multifunctional air pollution treatment device having a structural feature that passes through the upper portion of the vertical storage wall for separation of the absorption module and then moves to the next cleaning absorption module to remove air pollutants and finally discharges through the processing gas outlet.
제 1항에 있어서,
상기 세정흡수모듈별로 유입되는 세정흡수용액 종류를 다르게 함으로써 세정흡수모듈별로 최적 처리되는 대기오염물질이 선택될 수 있는 구조적 특징을 갖는 다기능 대기오염처리장치.
The method according to claim 1,
Multifunctional air pollution treatment device having a structural feature that can be selected by the air absorption material that is optimally processed by each cleaning absorption module by changing the type of cleaning absorption solution for each cleaning absorption module.
제 1항에 있어서,
상기 세정흡수모듈분리용 수직저류벽은 세정흡수모듈과 세정흡수모듈 사이에 위치하여 오염가스는 통과시키되 각 세정흡수모듈로 유입되는 세정흡수용액이 섞이는 것을 방지하는 기능을 수행하는 다기능 대기오염처리장치.
The method according to claim 1,
The vertical storage wall for separating the cleaning absorption module is located between the cleaning absorption module and the cleaning absorption module to pass the polluting gas, and to prevent the mixing of the cleaning absorption solution flowing into each cleaning absorption module. .
삭제delete 제 1항에 있어서,
상기 오염가스 균등유입 유도용 수직저류벽의 하단은 장치바닥면으로부터 일정간격 떨어진 수평 틈새를 구성하도록 설치되어 오염가스가 세정흡수모듈 하부공간으로 균일하고 빠른 유속으로 유입될 수 있도록 하는 구조적 특징을 갖는 다기능 대기오염처리장치.
The method according to claim 1,
The lower end of the vertical reservoir wall for inducing the equal inflow of polluted gas is installed to form a horizontal gap spaced apart from the bottom of the device to have a structural feature to allow the polluted gas to flow into the lower space of the cleaning absorption module at a uniform and fast flow rate. Multifunctional air pollution treatment device.
제 1항에 있어서,
상기 기액접촉부는 세정흡수모듈별로 수평다공판, 틈새와 섬유사, 쇄석, 석회석펠릿, 다양한 모양의 충전재 등으로 구성된 기액접촉매체, 그리고 오염가스충돌 및 저류기 중 하나 또는 둘 이상을 선택하여 독립적으로 형성하는 구조적 특징을 갖는 다기능 대기오염처리장치.
The method according to claim 1,
The gas-liquid contacting unit independently selects one or two or more of a gas-liquid contact medium composed of horizontal perforated plates, crevices and fibers, crushed stone, limestone pellets, fillers of various shapes, and pollutant gas collisions and reservoirs for each cleaning absorption module. Multifunctional air pollution treatment device having a structural feature to form.
제 1항에 있어서,
상기 세정흡수용액 기액분리기는 세정흡수용액 유출구를 통한 가스의 배출을 방지하기 위하여 세정흡수용액 유출구 아래쪽으로부터의 상승기포를 차단하고 기액분리된 세정흡수용액만 세정흡수용액 유출구로 배출시킬 수 있는 형상을 갖는 다기능 대기오염처리장치.
The method according to claim 1,
The cleaning absorbing solution gas-liquid separator blocks a rising bubble from the lower side of the cleaning absorbing solution outlet to prevent the discharge of the gas through the cleaning absorbing solution outlet, and discharges only the cleaning absorbing solution separated from the gas-liquid solution into the cleaning absorbing solution outlet. Having multifunctional air pollution treatment device.
제 1항에 있어서,
상기 세정흡수모듈에 장착된 처리가스 유출구의 개폐 및 세정흡수용액 공급 여부에 따라 세정흡수모듈의 운전조합을 선택할 수 있는 구조적 특징을 갖는 다기능 대기오염처리장치.
The method according to claim 1,
Multifunctional air pollution treatment device having a structural feature that can select the operation combination of the cleaning absorption module according to the opening and closing of the processing gas outlet and the cleaning absorption solution supplied to the cleaning absorption module.
제 1항에 있어서,
상기 오염가스 유입구에 오존가스와 같은 산화가스 또는 환원가스를 주입하여 오염가스와 주입된 가스가 혼합된 상태로 세정흡수모듈로 유입된 후 가스상태 및 물과 같은 세정흡수용액에 용존된 상태에서 악취물질, 휘발성유기화합물질(VOC)과 같은 대기오염물질과 산화 또는 환원 반응하여 처리대상 대기오염물질이 제거되는 기능을 갖는 다기능 대기오염처리장치.
The method according to claim 1,
Injecting oxidizing gas or reducing gas such as ozone gas into the polluting gas inlet, the polluting gas and the injected gas are introduced into the cleaning absorption module, and then odor in the gas state and dissolved in the cleaning absorbing solution such as water. A multifunctional air pollution treatment device having a function of removing an air pollutant to be treated by oxidizing or reducing an air pollutant such as a substance or volatile organic compound (VOC).
KR1020130103611A 2013-08-30 2013-08-30 Air pollutants removal equipment with multifunction for effective scrubbing of particulate matter and gas absorption KR101382140B1 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
KR1020130103611A KR101382140B1 (en) 2013-08-30 2013-08-30 Air pollutants removal equipment with multifunction for effective scrubbing of particulate matter and gas absorption

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
KR1020130103611A KR101382140B1 (en) 2013-08-30 2013-08-30 Air pollutants removal equipment with multifunction for effective scrubbing of particulate matter and gas absorption

Publications (1)

Publication Number Publication Date
KR101382140B1 true KR101382140B1 (en) 2014-04-07

Family

ID=50656779

Family Applications (1)

Application Number Title Priority Date Filing Date
KR1020130103611A KR101382140B1 (en) 2013-08-30 2013-08-30 Air pollutants removal equipment with multifunction for effective scrubbing of particulate matter and gas absorption

Country Status (1)

Country Link
KR (1) KR101382140B1 (en)

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105032151A (en) * 2015-07-15 2015-11-11 黄国杰 Air purification method and device
KR101946806B1 (en) * 2017-09-15 2019-02-12 유관석 the high efficient air pollutant eliminating device of both bad odorous material and fine dust using multi bubbles
CN110238153A (en) * 2019-06-10 2019-09-17 中国地质大学(武汉) A kind of volatility organic polluted soil salvage shop exhaust treatment system
WO2019245220A1 (en) * 2018-06-19 2019-12-26 김상겸 Vehicle-mounted air purifying device
WO2023121226A1 (en) * 2021-12-21 2023-06-29 주식회사 파나시아 Carbon absorption device
KR102594495B1 (en) 2023-04-12 2023-10-30 송영주 dust absorption treatment equipment
KR102596562B1 (en) * 2023-02-22 2023-11-01 손재덕 Organic pollutant gas purification system using livestock manure

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR100349214B1 (en) * 1999-10-28 2002-08-14 주식회사두합크린텍 Water treatment apparatus using perforated plates
KR101010893B1 (en) * 2010-07-19 2011-01-25 주식회사두합크린텍 Gas dissolution equipment for treatment of drinking water and wastewater
KR101163097B1 (en) * 2012-01-19 2012-07-05 주식회사두합크린텍 Gas dissolution equipment using gaps for treatment of drinking water and wastewater

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR100349214B1 (en) * 1999-10-28 2002-08-14 주식회사두합크린텍 Water treatment apparatus using perforated plates
KR101010893B1 (en) * 2010-07-19 2011-01-25 주식회사두합크린텍 Gas dissolution equipment for treatment of drinking water and wastewater
KR101163097B1 (en) * 2012-01-19 2012-07-05 주식회사두합크린텍 Gas dissolution equipment using gaps for treatment of drinking water and wastewater

Cited By (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105032151A (en) * 2015-07-15 2015-11-11 黄国杰 Air purification method and device
KR101946806B1 (en) * 2017-09-15 2019-02-12 유관석 the high efficient air pollutant eliminating device of both bad odorous material and fine dust using multi bubbles
WO2019245220A1 (en) * 2018-06-19 2019-12-26 김상겸 Vehicle-mounted air purifying device
KR20190142813A (en) * 2018-06-19 2019-12-30 김상겸 Air purifying apparatus for mounting on vehicle
KR102094076B1 (en) * 2018-06-19 2020-03-26 김상겸 Air purifying apparatus for mounting on vehicle
CN110238153A (en) * 2019-06-10 2019-09-17 中国地质大学(武汉) A kind of volatility organic polluted soil salvage shop exhaust treatment system
WO2023121226A1 (en) * 2021-12-21 2023-06-29 주식회사 파나시아 Carbon absorption device
KR102596562B1 (en) * 2023-02-22 2023-11-01 손재덕 Organic pollutant gas purification system using livestock manure
KR102594495B1 (en) 2023-04-12 2023-10-30 송영주 dust absorption treatment equipment

Similar Documents

Publication Publication Date Title
KR101382140B1 (en) Air pollutants removal equipment with multifunction for effective scrubbing of particulate matter and gas absorption
KR101512459B1 (en) Air pollutants removal equipment with multifunction using high performance gas liquid contact module
KR101172708B1 (en) wet type gas scrubber
KR100745810B1 (en) Dust collector
KR102022476B1 (en) Apparatus for dust and water-soluble odor removal and method thereof
KR101827121B1 (en) High efficiency multistage vortex type wet scrubber
KR100519986B1 (en) High perfomance multicone scrubber
US20090169440A1 (en) pollution treatment device for volatile organic gas
KR20160088261A (en) Wet scrubber nozzle system and method of use for cleaning a process gas
JP2015073990A (en) Method and apparatus for wet desulfurization spray towers
KR101722232B1 (en) Exhaust gas purification device of a ship engine
CN1021020C (en) Method and apparatus for treatment of waste gas containing dusts and chemical contaminants
KR101550990B1 (en) Wet gas scrubber
KR102025152B1 (en) Vortex type wet scrubber
KR100858355B1 (en) Wet scrubber
KR100681938B1 (en) Removal scrubber of gaseous and grainy pollutant from exhaust gas
KR100484563B1 (en) A scrubber apparatus for processing noxious gases and fine dusts simultaneously
KR100638517B1 (en) Scrubber having diffraction plate
KR20230151613A (en) Wet purifier of harmful exhaust gas with rotary filtration filter
KR100607862B1 (en) Apparatus for purifying flue gas of smelting furnace for LCDs' substrate glass using low-temperature activated carbon catalyst and the method thereof
KR101843478B1 (en) The offensive odor wet removal apparatus
KR100742131B1 (en) Dust collector by flushing
KR102405585B1 (en) Apparatus for purifying polluted air
KR102027895B1 (en) Voltex type gas-liquid mixing scrubber apparatus using vaccum
WO1997045191A1 (en) Apparatus and method for wet type simultaneous decontaminating and dust-removing gas treatment

Legal Events

Date Code Title Description
A201 Request for examination
A302 Request for accelerated examination
E902 Notification of reason for refusal
E701 Decision to grant or registration of patent right
GRNT Written decision to grant
FPAY Annual fee payment

Payment date: 20180402

Year of fee payment: 5

FPAY Annual fee payment

Payment date: 20190326

Year of fee payment: 6