KR101318636B1 - Heater using carbon nanotube heating element - Google Patents

Heater using carbon nanotube heating element Download PDF

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Publication number
KR101318636B1
KR101318636B1 KR1020100096229A KR20100096229A KR101318636B1 KR 101318636 B1 KR101318636 B1 KR 101318636B1 KR 1020100096229 A KR1020100096229 A KR 1020100096229A KR 20100096229 A KR20100096229 A KR 20100096229A KR 101318636 B1 KR101318636 B1 KR 101318636B1
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South Korea
Prior art keywords
carbon nanotube
heating element
heater
nanotube heating
tube
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KR1020100096229A
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Korean (ko)
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KR20110136675A (en
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장길상
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한라비스테온공조 주식회사
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    • HELECTRICITY
    • H05ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
    • H05BELECTRIC HEATING; ELECTRIC LIGHT SOURCES NOT OTHERWISE PROVIDED FOR; CIRCUIT ARRANGEMENTS FOR ELECTRIC LIGHT SOURCES, IN GENERAL
    • H05B3/00Ohmic-resistance heating
    • H05B3/40Heating elements having the shape of rods or tubes
    • H05B3/42Heating elements having the shape of rods or tubes non-flexible
    • H05B3/48Heating elements having the shape of rods or tubes non-flexible heating conductor embedded in insulating material
    • H05B3/50Heating elements having the shape of rods or tubes non-flexible heating conductor embedded in insulating material heating conductor arranged in metal tubes, the radiating surface having heat-conducting fins
    • HELECTRICITY
    • H05ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
    • H05BELECTRIC HEATING; ELECTRIC LIGHT SOURCES NOT OTHERWISE PROVIDED FOR; CIRCUIT ARRANGEMENTS FOR ELECTRIC LIGHT SOURCES, IN GENERAL
    • H05B3/00Ohmic-resistance heating
    • H05B3/10Heating elements characterised by the composition or nature of the materials or by the arrangement of the conductor
    • H05B3/12Heating elements characterised by the composition or nature of the materials or by the arrangement of the conductor characterised by the composition or nature of the conductive material
    • H05B3/14Heating elements characterised by the composition or nature of the materials or by the arrangement of the conductor characterised by the composition or nature of the conductive material the material being non-metallic
    • H05B3/145Carbon only, e.g. carbon black, graphite
    • HELECTRICITY
    • H05ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
    • H05BELECTRIC HEATING; ELECTRIC LIGHT SOURCES NOT OTHERWISE PROVIDED FOR; CIRCUIT ARRANGEMENTS FOR ELECTRIC LIGHT SOURCES, IN GENERAL
    • H05B2203/00Aspects relating to Ohmic resistive heating covered by group H05B3/00
    • H05B2203/02Heaters using heating elements having a positive temperature coefficient
    • HELECTRICITY
    • H05ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
    • H05BELECTRIC HEATING; ELECTRIC LIGHT SOURCES NOT OTHERWISE PROVIDED FOR; CIRCUIT ARRANGEMENTS FOR ELECTRIC LIGHT SOURCES, IN GENERAL
    • H05B2214/00Aspects relating to resistive heating, induction heating and heating using microwaves, covered by groups H05B3/00, H05B6/00
    • H05B2214/04Heating means manufactured by using nanotechnology

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Abstract

The present invention relates to a heater using a carbon nanotube heating element, and more specifically, it is possible to heat air quickly using a carbon nanotube heating element, and a fin is interposed between the tubes to increase heat exchange performance with air and to be miniaturized. In addition, the inner wall surface of the tube is provided with a switch for on / off power supply according to the temperature to prevent problems such as fire due to overheating, and relates to a carbon nanotube heating element with higher safety.

Description

Heater using carbon nanotube heating element {HEATER USING CARBON NANOTUBE HEATING ELEMENT}

The present invention relates to a heater using a carbon nanotube heating element, and more specifically, it is possible to heat air quickly using a carbon nanotube heating element, and a fin is interposed between the tubes to increase heat exchange performance with the air and to be miniaturized. In addition, the inner wall surface of the tube is provided with a switch for on / off power supply according to the temperature to prevent problems such as fire due to overheating, and relates to a carbon nanotube heating element with higher safety.

The heating means is used for raising the temperature of the outside, and means using various methods have been proposed and are also used for various purposes.

Particularly, among the heating means provided in the vehicle engine room, the heating means for heating the room is configured to heat the outside of the vehicle by heating the outside air while circulating the heater core through the heat exchange medium for lowering the temperature of the engine.

However, since the diesel engine has a high heat exchange rate, it takes a long time to heat the heat exchanging medium for cooling the engine at the initial start of the automobile, compared to the gasoline engine.

Therefore, in a vehicle equipped with a diesel engine in the winter, the heating of the heat exchange medium is delayed after the initial startup and the initial indoor heating performance is deteriorated.

In order to solve the above-mentioned problems, there has been proposed a vehicular air heater which directly heats air blown to a room side by various means.

Such an air heating type heater is advantageous in that the heating performance can be further improved by directly heating the air. However, due to the trend of miniaturization and high efficiency, it takes a space equal to the size of the heater in a situation where it is difficult to secure sufficient space in the engine room Which may cause the miniaturization to be hindered.

Particularly, in the case of a cartridge heater using a nichrome wire, it is difficult to control the temperature, and when air is not blown to the heater side, there is a fear of overheat, insulation problem due to high voltage may occur, There is a problem.

In addition, in the case of a heater using a positive temperature coefficient (PTC) element, even if a voltage is applied, it takes a long time until a sufficient heating performance can be expected, and thus it is difficult to obtain a heating effect quickly, If it is not good, there may be an electrical problem may cause the durability of the entire heater is lowered.

Accordingly, it is possible to improve the heating performance by further improving the heat exchange performance by direct heat exchange with the air, and to develop a heater that can be miniaturized, can be easily controlled, and can prevent problems caused by overheating, .

The present invention has been made to solve the problems described above, the object of the present invention is to heat the air quickly by using a carbon nanotube heating element, the pin is interposed between the tube to increase the heat exchange performance with air To provide a heater using a carbon nanotube heating element that can be reduced in thickness compared to a heater using a PTC element.

In addition, an object of the present invention is a heater using a carbon nanotube heating element that is provided on the inner wall surface of the tube to switch the power supply on / off according to the temperature to prevent problems such as fire due to overheating in advance, and further improved safety To provide.

In addition, an object of the present invention is to provide a heater using a carbon nanotube heating element that is further provided between the frame and the outermost fin to prevent the temperature rise of the frame.

In addition, an object of the present invention is to provide a carbon nanotube heating element inside the tube can be stably protected, the insulating member is provided between the tube and the carbon nanotube heating element is provided carbon nanotube heating element that can be expected to insulate and impact shock It is to provide a heater using.

The heater 1000 using the carbon nanotubes (CNT, CARBON NANOTUBE) heating element of the present invention includes a plurality of tubes 100 into which the carbon nanotube heating element 200 is inserted; A pin 700 interposed between the tubes 100; A pair of frames 300 supporting both sides in the stacking direction of the tube 100 and the fin 700; A first housing 410 for supporting and fixing one end of the tube 100, the fin 700, and the frame 300; A second housing 420 that supports and fixes the other end of the tube 100, the fin 700, and the frame 300, and is openable and closed by a cap 421; And a temperature switch 500 positioned on one inner wall of the tube 100 to turn on / off power applied to the carbon nanotube heating element 200 according to the measured temperature information. Characterized in that it comprises a.

At this time, the carbon nanotube heating element 200 is a plate-shaped conductor 210 formed long in the longitudinal direction; An insulating layer 220 formed on an upper surface of the conductor 210; A pair of electrodes 230 formed to extend in the longitudinal direction at both ends of the upper surface of the insulating layer 220; A carbon nanotube heating layer 240 formed on the upper side of the insulating layer 220 to be energized with the electrode 230; And a protective layer 250 provided on the upper surface of the insulating layer 220 to surround the electrode 230 and the carbon nanotube heating layer 240. And a control unit.

In addition, the tube 100 is characterized in that the insulating member 110 is further inserted between the protective layer 250 of the carbon nanotube heating element 200 and the inner wall surface of the tube 100.

In addition, the insulating member 110 is characterized in that formed of mica (Mica).

In addition, the heater 1000 using the carbon nanotube heating element is characterized in that the heat shield member 600 is further provided between the frame 300 and the outermost fin 700.

On the other hand, the temperature switch 500 is characterized in that located on the inner wall surface of one of the tubes (100).

In addition, the temperature switch 500 is characterized in that it is provided between the tube 100 is provided with the pin 700, the temperature switch 500 is the tube 100, the pin 700 and the second It is characterized by being supported by the housing 420.

At this time, the temperature switch 500 is characterized in that it comprises a bimetal.

Accordingly, the heater using the carbon nanotube heating element of the present invention can quickly heat the air using the carbon nanotube heating element, the fin is interposed between the tube to increase the heat exchange performance with the air, the heater using the PTC element Compared with that, the thickness can be reduced, so there is an advantage of miniaturization.

In addition, the heater using the carbon nanotube heating element of the present invention is provided with a switch that is responsible for the power supply on / off according to the temperature on the inner wall surface of the tube to prevent problems such as fire due to overheating in advance, the safety advantage There is this.

In addition, the heater using the carbon nanotube heating element of the present invention is further provided with a heat shield member between the frame and the outermost fin has the advantage of preventing the temperature rise of the frame.

In addition, the heater using the carbon nanotube heating element of the present invention can be stably protected by the carbon nanotube heating element is provided inside the tube, the insulation member is provided between the tube and the carbon nanotube heating element is expected to provide insulation and shock mitigation effect. There are advantages to it.

1 is a perspective view of a heater using a carbon nanotube heating element according to the present invention.
Figure 2 is an exploded perspective view of a heater using the carbon nanotube heating element of the present invention shown in FIG.
Figure 3 is an exploded perspective view of the tube of the heater using the carbon nanotube heating element according to the present invention.
4 is a cross-sectional view of a heater using the carbon nanotube heating element of the present invention shown in FIG.
Figure 5 is a step showing a method for producing a carbon nanotube heating element.
6 is a cross-sectional view of another tube of the heater using the carbon nanotube heating element according to the present invention.
7 is another plan view of a heater using a carbon nanotube heating element according to the present invention.
8 and 9 are another perspective view of a heater using a carbon nanotube heating element according to the present invention, respectively.

Hereinafter, the heater 1000 using the carbon nanotube heating element of the present invention having the characteristics as described above will be described in detail with reference to the accompanying drawings.

Heater 1000 using the carbon nanotube heating element of the present invention is a tube 100, fin 700, the frame 300, the first housing 410, the second housing 420, and the temperature switch 500 It is formed to include.

1 and 2 illustrate the carbon nanotube heating element 200 of the present invention, and the tube 100 and the fin 700 are alternately stacked in the horizontal direction.

First, the tube 100 is a portion into which the carbon nanotube heating element 200 is inserted. The tube 100 may be formed of a metal material that can easily transfer heat of the carbon nanotube heating element 200 to the outside.

At this time, the tube 100 is formed in an open state on one side or both sides, the carbon nanotube heating element 200 is inserted through the open side.

The carbon nanotube heating element 200 can increase the performance more than that of the conventional PTC element, and can significantly reduce the thickness of the tube 100 itself, and thus, the carbon nanotube heating element of the present invention The heater 1000 used has an advantage of increasing efficiency and miniaturization.

The fin 700 is to increase the heat transfer performance by increasing the resistance of the air flowing through the outside, is interposed between the tube 100, as shown in Figure 7, the tube 100 and the tube 100 A plurality of pins 700 (in the form of two or more stacked pins) formed between the two layers may be provided.

The carbon nanotube heating element 200 of the present invention shown in Figure 7 is the same as the configuration shown in Figures 1 and 2, the stack number of the fin 700 and the tube 100 is to change More specifically, in the left-to-right direction of the drawing, a single fin 700-a tube 100-three layers of fins 700-a tube 100-three layers of fins 700-a tube 100-a single fin 700 ) Is an example of lamination.

When the multilayer fin 700 is formed, a plate member 710 for supporting between the fin 700 and the fin 700 may be further provided.

At this time, the plate member 710 is preferably formed of a metal material having high thermal conductivity that does not interfere with the heat transfer between the tube 100 and the fin 700 and the heat transfer between the air.

The frame 300 is provided with a pair and is configured to support both sides in the stacking direction of the tube 100 and the fin 700, which is provided on the left and right in the drawing.

The frame 300 may be formed of a metal material to protect the tube 100 and the pin 700, and the heat blocking member 600 is disposed between the frame 300 and the outermost pin 700. It is preferable to prevent the heat radiated from the tube 100 is transferred to another configuration through the frame 300 and the frame 300. (See FIG. 2 exploded perspective view)

The first housing 410 is a portion for supporting and fixing one end of the tube 100, the fin 700, and the frame 300, and is located below the drawing.

The first housing 410 is preferably made of an insulating material through which heat and electricity do not pass.

The second housing 420 is made of an insulating material like the first housing 410, and supports and fixes the other ends of the tube 100, the fin 700, and the frame 300, and the carbon nanotubes. Built-in configuration for supplying power to the heating element (200).

In this case, the second housing 420 is hollowed so as to correspond to the shape of the tube 100 so that the lower portion of the tube 100 is inserted into a predetermined region and fixed in the drawing, the carbon nanotube heating element 200 One side of the second housing 420 is provided to be opened and closed by a cap 421 in order to facilitate the connection process of supplying power to the furnace, and to perform a process such as maintenance and maintenance inspection after mounting.

In FIG. 2, the lower end of the tube 100 is in a closed state, and an example in which the first housing 410 and the second housing 420 are bolted to each other is illustrated as an example. The heater 1000 using the nanotube heating element is not limited thereto and may be fastened in various ways.

The temperature switch 500 is a means for turning on / off the power applied to the carbon nanotube heating element 200 according to the measured temperature information provided in the heater 1000 using the carbon nanotube heating element of the present invention. When the temperature of the tube 100 is overheated above the temperature, the power applied to the carbon nanotube heating element 200 is turned off.

That is, the temperature switch 500 is a means for supplying current to the carbon nanotube heating element 200. When the temperature is overheated above a predetermined temperature, the flow of current is interrupted and the operation of the heater 1000 is stopped.

At this time, the temperature switch 500 may be a means including a bimetal (bimetal).

The bimetal is a rod-shaped part made of one sheet by stacking two kinds of thin metal plates having very different thermal expansion coefficients, and can be supplied or cut off according to temperature by using a bending property when heat is applied.

Accordingly, the heater 1000 using the carbon nanotube heating element of the present invention prevents overheating by cutting off the current when the temperature rises above a predetermined temperature, and has the advantage of being reusable without replacing parts.

The temperature switch 500 is to control the total power by measuring the temperature of the attached tube 100, the temperature switch 500 is the temperature switch 500 is attached by a heat conductive adhesive, Figure 1 and As shown in FIG. 7, the tube 100 may be positioned on an inner wall surface, or as illustrated in FIGS. 8 and 9, and may be positioned outside the tube 100.

First, as shown in FIGS. 1 and 7, the temperature switch 500 provided in the tube 100 does not interfere with the formation of the carbon nanotube heating element 200 and the heat transfer member 110. As shown in FIG. 1 and FIG. 7, the second housing 420 is preferably provided adjacent to the second housing 420. (Upper side in the drawing)

In addition, the temperature switch 500 may be provided between the tube 100 is provided with the fin 700, as shown in FIGS. 8 and 9.

8 illustrates an example in which a circular type temperature switch 500 is provided, and FIG. 9 illustrates an example in which a rectangular type temperature switch 500 is provided.

When the temperature switch 500 is located outside, the heat generated from the temperature switch 500 may be properly radiated by external air according to the current supply.

Since the temperature switch 500 is fixed by a thermally conductive adhesive, the fixing force is firmly fixed and the circumference is supported by the two tubes 100, the fins 700, and the second housing 420 in order to increase the heat radiation efficiency. It is desirable to.

At this time, when the heater 100 using the carbon nanotube heating element is formed of a multi-layer fin 700, the temperature switch 500 is the tube 100, the plate-like member 710, the fin 700 and the second It may be supported by the housing 420.

Heater 1000 using the carbon nanotube heating element of the present invention may be provided with one so that the temperature switch 500 to control the power of the entire carbon nanotube heating element 200, a plurality is provided to individually control the power You can do that.

In addition, the temperature switch 500 may be applied to various positions of the heater 1000 using the carbon nanotube heating element. Since the central portion of the tube 100 is likely to be overheated, the stacking direction of the tube 100 is increased. It is preferable to be provided in the center area.

While the conventional PTC element has a positive temperature characteristic, since the carbon nanotube heating element 200 does not have a positive temperature characteristic, the heater 1000 using the carbon nanotube heating element of the present invention has a temperature switch 500. It is preferred that the entire power supply is provided.

Accordingly, the heater 1000 using the carbon nanotube heating element of the present invention is provided with the temperature switch 500, so that problems due to overheating, such as durability deterioration and fire, which may be caused when air is not blown in advance, may be disclosed. It can be prevented, and there is an advantage to increase the safety.

The carbon nanotube heating element 200 provided inside the tube 100 is provided in a plate shape as shown in FIG. 3, and the detailed configuration thereof is illustrated in FIG. 4, and a manufacturing process is illustrated in FIG. 5.

The carbon nanotube heating element 200 is formed to include a conductor 210, an insulating layer 220, a pair of electrodes 230, a carbon nanotube heating layer 240, and a protective layer 250.

The conductor 210 is a portion that forms a basic body for forming the carbon nanotube heating element 200, and is formed long in the longitudinal direction in a plate shape to be provided inside the tube 100.

The insulating layer 220 is formed of an insulating material on the upper side of the conductor 210, the electrode 230 is formed in the longitudinal direction at both ends of the upper side of the insulating layer 220 is formed in a pair.

The carbon nanotube heating layer 240 is formed to be energized with the electrode 230 on the upper side of the insulating layer 220, and forms a thin layer by using a screen printing method, such that can be manufactured to a thin thickness In addition, the size of the entire heater can also be miniaturized.

Since the discovery of the soccer ball-shaped carbon molecule C60 (60 carbon atoms: fullerene) in 1985, many research institutes around the world have been working on synthesizing new structured carbon. Dr. Ijima, a research institute, discovered an electron microscope that coincided with a long, long, dense carbon structure in 1991, and reported it to Nature, the world's leading scientific journal. . In carbon nanotubes, one carbon atom is bonded to three other carbon atoms and forms a hexagonal honeycomb pattern. If we draw this honeycomb pattern on flat paper and roll the paper round, it becomes a nanotube structure. In other words, one nanotube has the shape of a hollow tube or cylinder. This is called nanotubes because they are extremely small, usually one nanometer (one billionth of a meter) in diameter. The honeycomb pattern on the paper is rounded to form a nanotube. Depending on the angle at which the paper is rolled, the carbon nanotube may be an electrical conductor (Armchair structure) or a semiconductor (Zigzag structure). In addition, depending on the dried form, it may be classified into single-wall nanotubes, multi-wall nanotubes, and bundle nanotubes.

These carbon nanotubes have a high length / diameter ratio, and have a very large surface area per unit area, and have a chemical stability that is physically about 100 times stronger than steel. In particular, carbon nanotubes have been reported to have a higher thermal conductivity (20 to 66 W / cm · K) than diamond (33.3 W / cm · K), which has the highest thermal conductivity at room temperature. Therefore, the thermal conductivity is tens to hundreds of times higher than that of aluminum (0.243 W / cm · K) or copper (4.01 W / cm · K) used in the heat sink.

The carbon nanotube heating layer 240 is formed by transferring the material as described above to form a layer, and generates heat when power is applied to the electrode.

The protective layer 250 is provided to surround the electrode 230 and the carbon nanotube heating layer 240 on the upper side of the insulating layer 220, such as overglaze, the carbon nanotube heating Protect layer 240.

As shown in FIG. 5, the carbon nanotube heating element 200 has an insulating layer 220, an electrode 230, a carbon nanotube heating layer 240, and a protective layer 250 on the upper side of the conductor 210. ), And then sintered to complete.

Meanwhile, in the heater 1000 using the carbon nanotube heating element of the present invention, an insulating member 110 may be further inserted between the inner wall surface of the tube 100 and the protective layer 250 of the carbon nanotube heating element 200. In this case, the insulating member 110 is preferably formed of a mica (Mica) having an insulating effect and a shock absorbing effect.

Accordingly, the heater 1000 using the carbon nanotube heating element of the present invention can quickly heat air using the carbon nanotube heating element 200, and the fins 700 are interposed between the tubes 100 and the air. It is possible to increase the heat exchange performance of the miniaturization, while being provided with a temperature switch 500 for supplying power on / off to prevent problems such as fire due to overheating in advance, and has the advantage of higher safety.

It will be understood by those skilled in the art that various changes in form and details may be made therein without departing from the spirit and scope of the invention as defined by the appended claims.

1000: heater using carbon nanotube heating element
100 tube 110 insulation member
200: carbon nanotube heating element
210: conductor 220: insulating layer
230: electrode 240: carbon nanotube heating layer
250: protective layer
300: frame
410: first housing
420: second housing 421: cap
500: temperature switch
600: heat shield member
700: pin 710: plate member

Claims (9)

A pair of plate-shaped conductors 210 formed long in the longitudinal direction, an insulating layer 220 formed on the upper surface of the conductor 210, and a length formed in both ends of the upper surface of the insulating layer 220 in the longitudinal direction. The electrode 230, the carbon nanotube heating layer 240 formed to be energized with the electrode 230 on an upper surface of the insulating layer 220, and the electrode on an upper surface of the insulating layer 220. 230 and a carbon nanotube (CNT, CARBON NANOTUBE) heating element 200 including a protective layer 250 provided to surround the carbon nanotube heating layer 240 is inserted therein, and a plurality of metallic materials Tube 100;
A pin 700 interposed between the tubes 100;
A pair of frames 300 supporting both sides in the stacking direction of the tube 100 and the fin 700;
A first housing 410 for supporting and fixing one end of the tube 100, the fin 700, and the frame 300;
A second housing 420 that supports and fixes the other end of the tube 100, the fin 700, and the frame 300, and is openable and closed by a cap 421; And
A temperature switch 500 for turning on / off power applied to the carbon nanotube heating element 200 according to the measured temperature information; Heater using a carbon nanotube heating element comprising a.
delete The method of claim 1,
The tube 100 is a heater using a carbon nanotube heating element, characterized in that the insulating member 110 is further inserted between the protective layer 250 of the carbon nanotube heating element 200 and the inner wall surface of the tube (100).
The method of claim 3,
The insulating member 110 is a heater using a carbon nanotube heating element, characterized in that formed of mica (Mica).
The method of claim 1,
The heater (1000) using the carbon nanotube heating element is a heater using a carbon nanotube heating element, characterized in that the heat shield member 600 is further provided between the frame 300 and the outermost fin (700).
The method of claim 1,
The temperature switch 500 is a heater using a carbon nanotube heating element, characterized in that located on the inner wall surface of one of the tubes (100).
The method of claim 1,
The temperature switch 500 is a heater using a carbon nanotube heating element, characterized in that provided between the tube 100 is provided with the fin 700.
The method of claim 7, wherein
The temperature switch 500 is a heater using a carbon nanotube heating element, characterized in that supported by the tube 100, the fin 700 and the second housing (420).
According to any one of claims 1, 3 to 8 ,
The temperature switch 500 is a heater using a carbon nanotube heating element, characterized in that it comprises a bimetal.
KR1020100096229A 2010-06-14 2010-10-04 Heater using carbon nanotube heating element KR101318636B1 (en)

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