KR101248988B1 - Environmental-friendly treating agent of textiles and the textiles treated by the agent and treating method thereof - Google Patents
Environmental-friendly treating agent of textiles and the textiles treated by the agent and treating method thereof Download PDFInfo
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/32—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond
- D06M11/36—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond with oxides, hydroxides or mixed oxides; with salts derived from anions with an amphoteric element-oxygen bond
- D06M11/38—Oxides or hydroxides of elements of Groups 1 or 11 of the Periodic System
- D06M11/42—Oxides or hydroxides of copper, silver or gold
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B82—NANOTECHNOLOGY
- B82Y—SPECIFIC USES OR APPLICATIONS OF NANOSTRUCTURES; MEASUREMENT OR ANALYSIS OF NANOSTRUCTURES; MANUFACTURE OR TREATMENT OF NANOSTRUCTURES
- B82Y40/00—Manufacture or treatment of nanostructures
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06B—TREATING TEXTILE MATERIALS USING LIQUIDS, GASES OR VAPOURS
- D06B15/00—Removing liquids, gases or vapours from textile materials in association with treatment of the materials by liquids, gases or vapours
- D06B15/09—Removing liquids, gases or vapours from textile materials in association with treatment of the materials by liquids, gases or vapours by jets of gases
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/32—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond
- D06M11/36—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond with oxides, hydroxides or mixed oxides; with salts derived from anions with an amphoteric element-oxygen bond
- D06M11/46—Oxides or hydroxides of elements of Groups 4 or 14 of the Periodic System; Titanates; Zirconates; Stannates; Plumbates
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/77—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with silicon or compounds thereof
- D06M11/78—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with silicon or compounds thereof with silicon; with halides or oxyhalides of silicon; with fluorosilicates
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
- D06M13/345—Nitriles
- D06M13/348—Nitriles unsaturated, e.g. acrylonitrile
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
- D06M2200/10—Repellency against liquids
- D06M2200/11—Oleophobic properties
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
- D06M2200/10—Repellency against liquids
- D06M2200/12—Hydrophobic properties
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- D—TEXTILES; PAPER
- D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B2401/00—Physical properties
- D10B2401/02—Moisture-responsive characteristics
- D10B2401/021—Moisture-responsive characteristics hydrophobic
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- D—TEXTILES; PAPER
- D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B2401/00—Physical properties
- D10B2401/13—Physical properties anti-allergenic or anti-bacterial
Abstract
본 발명은 친환경 섬유원단 처리제와 친환경 섬유원단 처리제로 처리한 섬유 원단 및 그 처리방법에 관한 것으로서, 더욱 상세하게는 발수제와 나노물질을 물에 혼합하여 이루어지는 친환경 섬유원단 처리제와, 친환경 섬유원단 처리제로 처리한 섬유원단, 그리고 친환경 섬유원단 처리제의 섬유원단 처리방법에 관한 것이다.
본 발명은 상기한 바와 같은 문제점을 완벽하게 해결하고 상기와 같은 섬유산업에 있어서의 시대적 흐름에 맞추기 위하여 안출된 것으로서, 섬유원단에 처리함으로써 발수, 발유의 기능성을 물론 항균성, 항곰팡이, 방오성, 진드기 기피성 등의 효과로 환경적 피해 요소를 최소화 시켜주며, 무엇보다도 무기 바인더의 우수한 접착력 때문에 섬유원단의 조직을 감싸든가 흡수되고 열풍으로 섬유원단에 고착화되어 일체화됨으로써 기존 발수섬유와는 달리 20회까지 세탁해도(손빨래는 50회) 그대로 발수 기능이 유지되는 우수한 제품인 친환경 섬유원단 처리제와 상기 친환경 섬유원단 처리제로 처리한 섬유원단 및 상기 친환경 섬유원단 처리제를 이용하여 섬유원단을 처리하는 방법을 제공하는 것을 그 목적으로 한다.The present invention relates to a textile fabric treated with an environmentally friendly textile fabric treatment agent and an environmentally friendly textile fabric treatment agent, and more particularly, to an environmentally friendly textile fabric treatment agent formed by mixing a water repellent and a nanomaterial with water, and an environmentally friendly textile fabric treatment agent. The present invention relates to a fiber fabric treated, and a fiber fabric treatment method of an environmentally friendly fiber fabric treatment agent.
The present invention was devised in order to completely solve the problems described above and to meet the trend of the times in the textile industry as described above, by treating the fabric to the water repellent, oil repellency as well as antibacterial, anti-fungal, antifouling, mite It minimizes the environmental damage factor by the effect of repellency, and most of all, it is absorbed by wrapping the tissue of the fiber fabric due to the excellent adhesive strength of the inorganic binder, and is fixed to the fiber fabric by hot air to be integrated and integrated up to 20 times. Provides a method for treating fiber fabrics using an eco-friendly fiber fabric treatment agent, a fiber product treated with the eco-friendly fiber fabric treatment agent, and the eco-friendly fiber fabric treatment agent, which is an excellent product that maintains a water repellent function even after washing (50 times hand washing). For that purpose.
Description
본 발명은 친환경 섬유원단 처리제와 친환경 섬유원단 처리제로 처리한 섬유원단 및 그 처리방법에 관한 것으로서, 더욱 상세하게는 발수제와 나노물질을 물에 혼합하여 이루어지는 친환경 섬유원단 처리제와, 상기 친환경 섬유원단 처리제로 처리한 섬유원단, 그리고 친환경 섬유원단 처리제의 섬유원단 처리방법에 관한 것이다.The present invention relates to a fiber fabric treated with an environmentally friendly fiber fabric treatment agent and an environmentally friendly fiber fabric treatment agent, and more particularly, an environmentally friendly fiber fabric treatment agent formed by mixing a water repellent agent and a nanomaterial in water, and the environmentally friendly fiber fabric treatment. The present invention relates to a textile fabric treated with a zero treated textile fabric and an environmentally friendly textile fabric treatment agent.
1960, 1970년대 저임금을 앞세워 산업을 주도한 섬유산업은, 임금인상 및 낙후된 기술 그리고 소재의 부재에 따라 갈수록 경쟁력을 잃어버려 이미 값싼 노동력을 앞세운 중국과 동남아 시장제품과, 고품질의 유럽제품에 시장을 빼앗기고, 하향산업으로 전락하였다.
The textile industry, which led the industry in the 1960s and 1970s with low wages, lost its competitive edge due to wage hikes, lack of technology, and the absence of materials. It was taken away and fell into a downward industry.
정부에서도 수천억대의 예산을 투여해 대구지역의 섬유산업 활성화를 위해 "밀레니엄 프로젝트"를 추진한 바 있으나, 국내의 원료 및 소재의 한계성 때문에, 신소재 및 신제품 개발보다는 주로 하드웨어(설비개선, 폐수부분 등) 부분의 개선으로, 중소섬유업체에서는 신제품 개발에 많은 어려움을 겪고 있다.
The government has put in a budget of hundreds of billions to promote the millennium project in order to revitalize the textile industry in Daegu.However, due to the limitations of domestic raw materials and materials, hardware (maintaining equipment, wastewater, etc.) is used rather than new and new products ), Small and medium-sized textile companies are having difficulty in developing new products.
특히 갈수록 심해지는 환경파괴 문제로 전 세계 인류가 알 수 없는 피부병과 많은 어린이들이 아토피 등에 시달리고 있는 현실에서, 피부와 직접적으로 접촉하는 섬유는 친환경 소재의 개발이 무엇보다 절실히 요구되어지고 있다.
In particular, due to the increasingly severe environmental destruction problem, the world's human skin disease and many children suffer from atopy, the fiber directly contacting the skin is urgently required to develop eco-friendly materials.
최근 이러한 시대적 흐름에 맞추어 섬유원단을 발수제 등으로 처리한 발수섬유가 개발되어 있으나, 이는 세탁(세탁기 또는 손빨래)에 의해 발수제가 섬유원단으로부터 탈착되어 발수기능이 현저히 떨어지고 나아가 발수기능을 상실하게 되는 문제점이 있었다.
Recently, water-repellent fibers have been developed in which the fiber fabric is treated with a water repellent agent in accordance with the trend of the times, but the water-repellent agent is desorbed from the fiber fabric by washing (washing machine or hand washing), so that the water repellent function is significantly decreased, and further, the water repellent function is lost. There was a problem.
또한 섬유원단에 고어텍스라는 필름(막)을 부착하여 빗물은 밖에서 안으로 들어가지 못하나 안쪽에서의 땀이나 증기는 밖으로 내보내게 된 새로운 방수가공품이 개발되었는바, 종래의 방수가공한 옷을 입었을 때 생기는 '더운 습기'의 문제를 해소하게 되었다. 상기 고어텍스의 발수원리는 구멍의 크기에 있는데, 1만분의 2㎜의 구멍은 최소 1㎜의 빗방울을 통하지 못하게 하고, 1000만분의 4㎜의 수증기는 통과할 수 있게 하였다. 그러나 상기 고어텍스의 경우 발수기능을 유지하기 위하여 정기적으로 발수제를 뿌려주어야 하고 깨지거나 구멍이 막히지 않도록 관리를 잘해주어야 하는 문제점이 있었다.
In addition, by attaching a film called Gore-Tex to the fabric fabric, a new waterproofing product has been developed that prevents rainwater from entering from the outside but leaves sweat or steam from the inside out. It solved the problem of 'hot moisture'. The water-repellent principle of the Gore-Tex is in the size of the hole, and the hole of 2 mm in 10,000 prevents passing through at least 1 mm of rain, and the water vapor of 10 mm in 4 mm is allowed to pass. However, in the case of the Gore-tex, in order to maintain the water-repellent function, there is a problem in that it is necessary to spray the water-repellent agent on a regular basis and to manage well so that it is not broken or clogged.
즉, 상기와 같은 고어텍스나 발수섬유의 경우 상기 섬유원단과 일체화되지 못하고 필름과 발수제에 의해 기공만을 형성하는 것에 불과하여 세탁 또는 사용에 의해 발수효능이 현저히 감소하거나 상실되는 크나큰 문제점이 있다.That is, in the case of the Gore-Tex or water-repellent fibers, only the pores are formed by the film and the water-repellent agent without being integrated with the fiber fabric, and there is a significant problem that the water-repellency is significantly reduced or lost by washing or using.
본 발명은 상기한 바와 같은 문제점을 완벽하게 해결하고 상기와 같은 섬유산업에 있어서의 시대적 흐름에 맞추기 위하여 안출된 것으로서, 섬유원단에 처리함으로써 발수, 발유의 기능성은 물론 항균성, 항곰팡이, 방오성, 진드기 기피성 등의 효과로 환경적 피해 요소를 최소화 시켜주며, 무엇보다도 무기 바인더의 우수한 접착력 때문에 섬유원단의 조직을 감싸든가 흡수되고 열풍으로 섬유원단에 고착화되어 일체화됨으로써 기존 발수섬유와는 달리 20회까지 세탁해도(손빨래는 50회) 그대로 발수 기능이 유지되는 우수한 제품인 친환경 섬유원단 처리제와 상기 친환경 섬유원단 처리제로 처리한 섬유원단 및 상기 친환경 섬유원단 처리제를 이용하여 섬유원단을 처리하는 방법을 제공하는 것을 그 목적으로 한다.The present invention has been devised in order to completely solve the problems as described above and to meet the current trend in the textile industry as described above, by treating the fabric to the water repellent, oil repellency as well as antibacterial, anti-fungal, antifouling, mite It minimizes the environmental damage factor by the effect of repellency, and most of all, it is absorbed by wrapping the tissue of the fiber fabric due to the excellent adhesive strength of the inorganic binder, and is fixed to the fiber fabric by hot air to be integrated and integrated up to 20 times. Provides a method for treating fiber fabrics using an eco-friendly fiber fabric treatment agent, a fiber product treated with the eco-friendly fiber fabric treatment agent, and the eco-friendly fiber fabric treatment agent, which is an excellent product that maintains a water repellent function even after washing (50 times hand washing). For that purpose.
본 발명에 의한 친환경 섬유원단 처리제는 발수제와 나노물질을 증류수에 혼합하여 이루어지는 것이 특징이다.
Eco-friendly fiber fabric treatment agent according to the present invention is characterized in that the water repellent and the nano-material is made by mixing in distilled water.
구체적으로, 본 발명에 의한 친환경 섬유원단 처리제는 발수제 10~20 중량부와 나노실버 0.01~0.03 중량부를 증류수 75~85 중량부에 혼합하여 이루어지는 것을 특징으로 한다.
Specifically, the environmentally friendly fiber fabric treatment agent according to the present invention is characterized in that 10 to 20 parts by weight of the water repellent and 0.01 to 0.03 parts by weight of the nano silver mixed by 75 to 85 parts by weight of distilled water.
또한, 본 발명에 의한 친환경 섬유원단 처리제는 상기 발수제가 실리콘계 또는 불소계인 것을 특징으로 한다.
In addition, the environmentally friendly fiber fabric treatment agent according to the invention is characterized in that the water repellent is silicone-based or fluorine-based.
또한, 본 발명에 의한 친환경 섬유원단 처리제는 발수제 2~5 중량부와 나노재료 0.1~2 중량부를 증류수 85~95 중량부에 혼합하여 이루어지는 것을 특징으로 한다.
In addition, the environmentally friendly fiber fabric treatment agent according to the present invention is characterized by mixing 2 to 5 parts by weight of the water repellent and 0.1 to 2 parts by weight of the nanomaterial to 85 to 95 parts by weight of distilled water.
또한, 본 발명에 의한 친환경 섬유원단 처리제는 상기 발수제가 1,1,2,2-테트라하이드로플루오로알킬 아크릴레이트(1,1,2,2-Tetrahydroperfluoroalkyl acrylte)인 것을 특징으로 한다.
In addition, the environmentally friendly fiber fabric treatment agent according to the present invention is characterized in that the water repellent is 1,1,2,2-tetrahydrofluoroalkyl acrylate (1,1,2,2-Tetrahydroperfluoroalkyl acrylte).
또한, 본 발명에 의한 친환경 섬유원단 처리제의 상기 나노재료는 20~50 ㎚ 크기의 SiO2, 10~30 ㎚의 TiO2, 50~80 ㎚의 ZnO, 30~60 ㎚의 Al2O3, 및 3~7 ㎚의 TiO2를 각각 20~30 : 15~25 : 20~30 : 15~25 : 15~20의 중량비로 혼합하여 사용하는 것을 특징으로 하는 것을 특징으로 한다.
In addition, the nano-material of the environmentally friendly fiber fabric treatment agent according to the present invention is 20 to 50 nm size SiO 2 , 10 to 30 nm TiO 2 , 50 to 80 nm ZnO, 30 to 60 nm Al 2 O 3 , and 3 to 7 nm of TiO 2 is characterized in that it is used by mixing in a weight ratio of 20 to 30: 15 to 25: 20 to 30: 15 to 25: 15 to 20, respectively.
또한, 또한, 본 발명에 의한 친환경 섬유원단 처리제의 상기 나노재료는 톨루엔(Toluene) 또는 자일렌(Xylene)의 유기용매에 분산 후 테트라플루오로이소프탈로니트릴(Tetrafluoroisophthalonitirile 98%)을 첨가하여 반응시킨 것을 건조하여 유기용매를 제거한 다음 분말화하여 사용하는 것을 특징으로 하는 것을 특징으로 한다.
In addition, the nano-material of the environmentally friendly fiber fabric treatment agent according to the present invention is dispersed in an organic solvent of toluene or xylene and then reacted by adding tetrafluoroisophthalonitirile (98%). It is characterized in that it is dried to remove the organic solvent and then used in powder form.
한편, 본 발명에 의한 친환경 섬유원단 처리제의 섬유원단 처리방법은 섬유원단을 처리하는 방법에 있어서, 상기 섬유원단을 상기의 친환경 섬유원단 처리제에 침지하는 침지단계와; 상기 침지단계를 거친 섬유원단을 로울러 압력 3.5~4.0 ton으로 탈수하는 탈수단계와; 상기 탈수단계를 거친 섬유원단을 150~180℃의 열풍으로 건조하는 열풍건조단계로 이루어지는 것을 특징으로 한다.
On the other hand, the fiber fabric processing method of the environmentally friendly fiber fabric treatment agent according to the present invention comprises a immersion step of immersing the fiber fabric in the environmentally friendly fiber fabric treatment agent; A dehydration step of dewatering the fiber fabric subjected to the immersion step at a roller pressure of 3.5 to 4.0 ton; It characterized by consisting of a hot air drying step of drying the fiber fabric subjected to the dehydration step with hot air of 150 ~ 180 ℃.
또한, 본 발명에 의한 친환경 섬유원단 처리제의 섬유원단 처리방법은 상기 침지단계, 탈수단계, 그리고 열풍건조단계는 처리되는 섬유원단의 길이를 분당 8~9 야드(yard)로 하며, 상기 열풍건조단계는 6 챔버(chamber) 텐타기를 사용하여 각 챔버이 온도를 순차적으로 180, 175, 170, 170, 160, 150℃로 하는 것을 특징으로 한다.
In addition, the fiber fabric treatment method of the environmentally friendly fiber fabric treatment agent according to the present invention, the immersion step, dehydration step, and hot air drying step is the length of the fiber fabric to be treated to 8 ~ 9 yards per minute (yard), the hot air drying step The six-chamber (chamber) is characterized in that the chamber is set to 180, 175, 170, 170, 160, 150 ° C temperature sequentially.
한편, 본 발명의 의한 친환경 섬유원단 처리제로 처리된 섬유원단은 상기 본 발명에 의한 친환경 섬유원단 처리제의 섬유원단 처리방법에 의하여 처리된 것을 특징으로 한다.On the other hand, the fiber fabric treated with an environmentally friendly fiber fabric treatment agent of the present invention is characterized in that the fiber fabric treatment method of the environmentally friendly fiber fabric treatment agent according to the present invention.
본 발명에 의한 친환경 섬유원단 처리제에 의하면, 상기 친환경 섬유원단 처리제는 발수제와 나노물질을 증류수에 혼합하여 이루어져 그 구성물질이 모두 친환경 물질이므로 환경공해에 전혀 문제가 없으며, 또한 본 발명에 의한 친환경 섬유원단 처리제로 처리한 섬유원단 및 그 처리방법에 의하면, 상기 친환경 섬유원단 처리제를 섬유원단에 처리함으로써 발수, 발유의 기능성은 물론 항균성, 항곰팡이, 방오성, 진드기 기피성 등의 효과로 환경적 피해 요소를 최소화 시켜주며, 무엇보다도 무기 바인더의 우수한 접착력 때문에 상기 친환경 섬유원단 처리제가 섬유원단의 조직을 감싸든가 흡수되고 열풍으로 섬유원단에 고착화되어 일체화됨으로써 기존 발수섬유와는 달리 20회까지 세탁해도(손빨래는 50회) 그대로 발수기능이 유지할 수 있게 되며, 세탁 후 150℃의 고온 다림질을 통해 그 발수기능을 극대화시킬 수 있다.According to the eco-friendly fiber fabric treatment agent according to the present invention, the eco-friendly fiber fabric treatment agent is made by mixing a water-repellent agent and nanomaterials in distilled water, so that all of its constituent materials are eco-friendly materials, there is no problem in environmental pollution, and also eco-friendly fiber according to the present invention According to the fiber fabric treated with the fabric treatment agent and the method for treating the same, the environmentally friendly fiber fabric treatment agent is treated with the fiber fabric to protect the environment from water repellency and oil repellency, as well as antibacterial, antifungal, antifouling, and mite repellent effects. It is minimized, and above all, due to the excellent adhesive strength of the inorganic binder, the eco-friendly fiber fabric treatment agent wraps or absorbs the tissue of the fiber fabric and is fixed to the fiber fabric with hot air so that it is integrated, even if it is washed up to 20 times unlike the existing water-repellent fiber (hand 50 times the laundry) water-repellent function can be maintained as it is, And then suspended it to maximize the water-repellent function through the high temperature of the ironing 150 ℃.
그 결과, 본 발명에 의한 친환경 섬유원단 처리제로 처리한 섬유원단은 항균 및 항곰팡이 효과가 우수하여 구명복이나 섬유벽지, 신발소재, 의류, 모자 등에 유용하게 사용될 수 있다.As a result, the fiber fabric treated with an environmentally friendly fiber fabric treatment agent according to the present invention has excellent antibacterial and antifungal effects, and thus may be usefully used in life jackets, fiber wallpaper, footwear materials, clothing, hats, and the like.
도1은 본 발명에 의한 신선도 유지 조성물의 나노캡슐 모형도.
도2는 본 발명에 의한 친환경 섬유원단 처리제의 섬유원단 처리방법의 공정도.
도3a 내지 도3d는 본 발명에 의한 친환경 섬유원단 처리제로 처리한 섬유원단의 실험예로서 실크원단에 대한 실험결과를 나타낸 사진.
도4는 본 발명에 의한 친환경 섬유원단 처리제로 처리한 섬유원단의 실험예로서 스타킹에 대한 실험결과를 나타낸 사진.1 is a nanocapsule model of the freshness maintenance composition according to the present invention.
Figure 2 is a process chart of the fiber fabric processing method of the environmentally friendly fiber fabric treatment agent according to the present invention.
Figure 3a to Figure 3d is a photograph showing the experimental results for the silk fabric as an experimental example of the fiber fabric treated with an environmentally friendly fiber fabric treatment agent according to the present invention.
Figure 4 is a photograph showing the experimental results for the stockings as an experimental example of the fiber fabric treated with an environmentally friendly fiber fabric treatment agent according to the present invention.
이하, 본 발명에 의한 친환경 섬유원단 처리제와 친환경 섬유원단 처리제로 처리한 섬유원단 및 그 처리방법을 첨부한 도면을 참조하여 상세히 설명하면 다음과 같다.
Hereinafter, with reference to the accompanying drawings, a fiber fabric treated with an environmentally friendly fiber fabric treatment agent and an environmentally friendly fiber fabric treatment agent according to the present invention, and a method for treating the same, are as follows.
도1은 본 발명에 의한 친환경 섬유원단 처리제의 나노캡슐 모형도이고 도2는 본 발명에 의한 친환경 섬유원단 처리제의 섬유원단 처리방법의 공정도이며, 도3a 내지 도3d는 본 발명에 의한 친환경 섬유원단 처리제로 처리한 섬유원단의 실험예로서 실크원단에 대한 실험결과를 나타낸 사진이고 도4는 본 발명에 의한 친환경 섬유원단 처리제로 처리한 섬유원단의 실험예로서 스타킹에 대한 실험결과를 나타낸 사진이다.
1 is a nanocapsule model diagram of an environmentally friendly fiber fabric treatment agent according to the present invention and Figure 2 is a process chart of a fiber fabric treatment method of an environmentally friendly fiber fabric treatment agent according to the present invention, Figures 3a to 3d is an environmentally friendly fiber fabric treatment according to the present invention Experimental example of the silk fabric as an experimental example of the fiber fabric treated with zero, and Figure 4 is a photograph showing the experimental results of the stockings as an experimental example of the fiber fabric treated with an environmentally friendly fiber fabric treatment agent according to the present invention.
본 발명에 의한 친환경 섬유원단 처리제는 발수제 10~20 중량부와 나노실버 0.01~0.03 중량부를 증류수 75~85 중량부에 혼합하여 이루어지는 것을 특징으로 한다.
The environmentally friendly fiber fabric treatment agent according to the present invention is characterized in that it is made by mixing 10 to 20 parts by weight of water repellent and 0.01 to 0.03 parts by weight of nanosilver to 75 to 85 parts by weight of distilled water.
이에 의하면, 상기 발수제는 액상의 유기질 고분자 물질로서 어떤 물질에 도포하면 공극내부에서 경화하여 발수성을 부여함으로써 공기는 통과시키면서 물방울은 통과되지 않는 크기의 미세공을 갖는 막을 형성하는 재료이다. 즉, 물방울은 퉁기고 통과하는 것을 방지하지만 공기가 통과할 만한 틈은 지니고 있는 것이다.
According to this, the water-repellent agent is a liquid organic polymer material, when applied to any material, it is cured in the voids to impart water repellency, thereby forming a film having micropores having a size that does not pass water droplets while passing air. In other words, the water droplets prevent them from penetrating and passing through, but have a gap through which air can pass.
상기 나노실버는 순은(실버, Silver)을 전기분해를 이용하여 나노(Nano) 크기(㎚, 10-9m) 수준의 초미립자로 만든 것으로서 나노화된 은(나노실버)는 강력한 항균 및 살균 작용이 있는 친환경 항균제 및 살균제이다. 이는 650여종의 세균과 바이러스를 멸균할 수 있고 진균류(Fungi)에도 아주 탁월한 효과를 발휘하는 것으로 알려져 있다.
The nano silver is made of pure silver (silver, silver) to ultra-fine particles of the nano (Nano) size (nm, 10 -9 m) level using electrolysis, the nanonized silver (nano silver) has a strong antibacterial and bactericidal action It is an environmentally friendly antibacterial and fungicide. It is able to sterilize over 650 bacteria and viruses and is known to be very effective against fungi.
본 발명에 의한 친환경 섬유원단 처리제는 상기 발수제와 친환경 살균제인 상기 나노실버를 물에 혼합함으로써 발수효과와 동시에 살균 효과를 달성할 수 있는 친환경 섬유원단 처리제가 된다.
The eco-friendly fiber fabric treatment agent according to the present invention becomes an eco-friendly fiber fabric treatment agent which can achieve a water repellent effect and a bactericidal effect by mixing the water repellent agent and the nano-silver which is an eco-friendly fungicide in water.
또한, 본 발명에 의한 친환경 섬유원단 처리제는 상기 발수제가 실리콘계 또는 불소계인 것을 특징으로 한다.
In addition, the environmentally friendly fiber fabric treatment agent according to the invention is characterized in that the water repellent is silicone-based or fluorine-based.
이에 의하면, 상기 실리콘계 발수제는 천연 무기소재인 SiO2에 유기화합물을 첨가한 발수제이고 상기 불소계 발수제는 천연 무기소재인 SiO2에 불소를 첨가한 발수제이며, 도1에서 도시한 바와 같이 마이크로 또는 나노크기의 미세공(11)이 형성되는 다공질성이고 천연소재인 나노 SiO2(12)에 항균물질(11)을 포집, 숙성시켜 제어함으로써 상기 항균물질이 서서히 방출되는 서방(徐放) 타입 형태로 가공하여 살균력의 지속성을 유지함으로써 상기 항균물질의 살균력을 극대화시킨 것이다.
According to the present invention, the silicon-based water repellent is a water repellent in which an organic compound is added to SiO 2 , which is a natural inorganic material, and the fluorine-based water repellent is a water repellent which is added to fluorine, SiO 2 , a natural inorganic material, as shown in FIG. 1. The micropores (11) of the porous and natural material is nano-SiO 2 (12) by collecting and controlling the antimicrobial material (11) in the form of a slow-release (徐 放) type that is slowly released by controlling the antimicrobial material By maximizing the sterilization power of the antimicrobial material by maintaining the persistence of the sterilization power.
이때, 상기 항균물질은 당업계에서 사용되는 것이라면 제한없이 사용할 수 있고, 이는 본 발명을 한정하지 않는다.
At this time, the antimicrobial material can be used without limitation as long as it is used in the art, which does not limit the present invention.
또한, 상기 실리콘계 및 불소계 발수제는 환경호르몬인 APEO(Alkyl phenol ethoxlates)가 첨가되지 않은 환경 기준에 적합한 친환경 발수제를 사용하여 친환경 살균제인 나노물질과 혼합하여 사용함으로써 본 발명에 의한 친환경 섬유원단 처리제가 인체에 무해하고 환경공해에 전혀 문제가 없게 하는 것이 가능하다.
In addition, the silicone-based and fluorine-based water-repellent agent is an environmentally friendly fiber fabric treatment agent according to the present invention by using an eco-friendly water repellent agent suitable for environmental standards that do not add the environmental hormone APEO (Alkyl phenol ethoxlates) is mixed with nanomaterials that are eco-friendly fungicides It is possible to make it harmless and to have no problem in environmental pollution at all.
또한, 본 발명에 의한 친환경 섬유원단 처리제는 나노물질로서 나노크기의 항균재료인 SiO2에 나노 추화(催化)및 나노 표면 호능(耗能)재료 TiO2, 나노 분해재료 ZnO, 및 나노 계면재료 Al2O3를 첨가한 나노재료를 사용하는 것을 특징으로 한다.
In addition, the environmentally friendly fiber fabric treatment agent according to the present invention as a nano-material nano-sized antimicrobial material, SiO 2 nano-sublimation and nano surface active material TiO 2 , nano-decomposition material ZnO, and nano interface material Al It is characterized by using a nanomaterial to which 2O 3 is added.
이에 의하면, 상기 나노재료는 톨루엔(Toluene), 자일렌(Xylene) 등의 유기용매에 분산 후 나노재료 개성 첨가제로서 테트라플루오로이소프탈로니트릴(Tetrafluoroisophthalonitirile 98%) 등과 같은 불탄 표면활성제와 1 : 0.05 내지 1 : 0.1의 중량비로 첨가하여 반응시킨 것을 건조방식으로 유기용매를 제거하여 나노 개성(改性)분말을 수득하며, 이때 상기 불탄 표면활성제는 사용되는 나노재료에 따라 선택 사용할 수 있다.
According to the present invention, the nanomaterial is dispersed in an organic solvent such as toluene, xylene, and the like. The reaction was added by a weight ratio of 1: 0.1 to remove the organic solvent in a dry manner to obtain a nano-modified powder, wherein the burnt surface active agent can be selected depending on the nanomaterials used.
또한, 상기 나노재료는 20~50 ㎚ 크기의 SiO2, 10~30 ㎚의 TiO2, 50~80 ㎚의 ZnO, 30~60 ㎚의 Al2O3, 및 3~7 ㎚의 TiO2를 각각 20~30 : 15~25 : 20~30 : 15~25 : 15~20의 중량비로 혼합하여 사용하는 것이 바람직하다.
In addition, the nanomaterial is SiO 2 having a size of 20 to 50 nm, TiO 2 of 10 to 30 nm, ZnO of 50 to 80 nm, Al 2 O 3 of 30 to 60 nm, and TiO 2 of 3 to 7 nm, respectively. It is preferable to mix and use in the weight ratio of 20-30: 15-25: 20-30: 15-25: 15-20.
또한, 본 발명에 의한 나노 성막을 제조하기 위해서는, 상기 나노 개성 분말 0.1~2중량부, 1,1,2,2-테트라하이드로퍼플루오로알킬 아크릴레이트(1,1,2,2-Tetrahydroperfluoroalkyl acrylate)와 같은 불탄 성막 활성제(즉, 발수제) 2~5 중량부, 분산개질(증류수) 85~95 중량부로 혼합하여 사용하는 것이 바람직하며, 여기에 더하여 당업계에서 통상적으로 사용하는 기능성 첨가제를 0.05~0.1 중량부로 더 첨가할 수도 있다.
In addition, in order to manufacture a nano-film according to the present invention, 0.1 to 2 parts by weight of the nano- individual powder, 1,1,2,2-tetrahydroperfluoroalkyl acrylate (1,1,2,2-Tetrahydroperfluoroalkyl acrylate 2 to 5 parts by weight of a non-elastic film active agent (i.e., water repellent), and 85 to 95 parts by weight of dispersion reforming (distilled water) are preferably used. In addition, the functional additives commonly used in the art are 0.05 to It may also be added in 0.1 parts by weight.
상기와 같이 배합된 원재료와 기능성 첨가제를 증류수에 첨가하고 50~70℃의 온도에서 교반기로 교반하여 분산시킨 다음, 불탄 성막 활성제를 부가한 후 천천히 교반하여 완전하게 반응시켜 제조할 수 있다.
The raw materials and functional additives blended as described above may be added to distilled water and dispersed by stirring with a stirrer at a temperature of 50 to 70 ° C.
본 발명에서 나노구조 코팅막은 기재의 원 위치에서 형성되는 복합현상으로 기재와 분할하지 않는 특징이 있으며, 본 발명의 나노구조 박막재료는 다기능 복합재료로서, 표면 개성을 통해 구성된 코팅막이 기름, 물, 유기물, 무기먼지, 세균 및 광(빛), 전기, 자석의 이기와 분산작용 등의 기능이 우수하다.
In the present invention, the nanostructured coating film is characterized in that it is not divided from the substrate as a composite phenomenon formed at the original position of the substrate, and the nanostructured thin film material of the present invention is a multifunctional composite material, wherein the coating film formed through surface personality is oil, water, It has excellent functions such as organic matter, inorganic dust, bacteria and light (light), electricity, magnetism and dispersion.
또한, 본 발명의 나노재료 개성 첨가제는 불탄 표면활성제를 사용함에 따라 액체의 표면장력을 하강시키고, 불소원자의 독특한 기하수치와 전기부하성 등을 나타내며, 개성 후의 나노재료는 높은 열안정성과 내 황산(强酸)성, 내 고농도 알칼리산과 강산화성을 가진다.
In addition, the nanomaterial personality additive of the present invention lowers the surface tension of the liquid by using a burnt surface active agent, exhibits a unique geometrical value and electrical load of the fluorine atom, the nanomaterial after the personality is high thermal stability and sulfuric acid resistance (Iii) Resistance, high concentration alkali acid and strong oxidizing property.
또한, 본 발명은 불탄 성막재료를 채용함으로써 막의 두께를 최소화 시킬 수 있고, 기재의 물화(物化) 특성과 색채, 투명도, 통풍성을 현저히 제고한다.
In addition, the present invention can minimize the thickness of the film by employing a non-elastic film material, and significantly improves the materialization characteristics, color, transparency, and breathability of the substrate.
한편, 본 발명에 의한 친환경 섬유원단 처리제의 섬유원단 처리방법은 섬유원단을 처리하는 방법에 있어서, 상기 섬유원단을 상기 제1항 내지 제3항 중 어느 하나의 항의 친환경 섬유원단 처리제에 침지하는 침지단계와; 상기 침지단계를 거친 섬유원단을 로울러 압력 3.5~4.0 ton으로 탈수하는 탈수단계와; 상기 탈수단계를 거친 섬유원단을 150~180℃의 열풍으로 건조하는 열풍건조단계로 이루어지는 것을 특징으로 한다.
On the other hand, the fiber fabric treatment method of the environmentally friendly fiber fabric treatment agent according to the present invention, in the method for processing the fiber fabric, immersing the fiber fabric in the environmentally friendly fiber fabric treatment agent of any one of claims 1 to 3. Steps; A dehydration step of dewatering the fiber fabric subjected to the immersion step at a roller pressure of 3.5 to 4.0 ton; It characterized by consisting of a hot air drying step of drying the fiber fabric subjected to the dehydration step with hot air of 150 ~ 180 ℃.
또한, 본 발명에 의한 친환경 섬유원단 처리제의 섬유원단 처리방법은 상기 침지단계, 탈수단계, 그리고 열풍건조단계는 처리되는 섬유원단의 길이를 분당 8~9 야드(yard)로 하며, 상기 열풍건조단계는 6 챔버(chamber) 텐타기를 사용하여 각 챔버의 온도를 순차적으로 180, 175, 170, 170, 160, 150℃로 하는 것을 특징으로 한다.
In addition, the fiber fabric treatment method of the environmentally friendly fiber fabric treatment agent according to the present invention, the immersion step, dehydration step, and hot air drying step is the length of the fiber fabric to be treated to 8 ~ 9 yards per minute (yard), the hot air drying step The six-chamber (chamber) is characterized in that the temperature of each chamber sequentially using 180, 175, 170, 170, 160, 150 ℃.
한편, 본 발명에 의한 친환경 섬유원단 처리제로 처리된 섬유원단은 상기 본 발명에 의한 친환경 섬유원단 처리제의 섬유원단 처리방법에 의하여 처리된 것을 특징으로 한다.
On the other hand, the fiber fabric treated with an environmentally friendly fiber fabric treatment agent according to the present invention is characterized in that the fiber fabric treatment method of the environmentally friendly fiber fabric treatment agent according to the present invention.
이에 의하면, 본 발명에 의한 친환경 섬유원단 처리제의 섬유원단 처리방법은 섬유원단에 유연제, 발수제, 염색제, 기타 물질을 처리하는 장치로서 침지, 탈수, 건조가 순차적으로 이루어질 수 있는 텐타기를 이용하여 본 발명에 의한 친환경 섬유원단 처리제를 섬유원단에 고착시켜주게 된다.
According to the present invention, the textile fabric treatment method of the environmentally friendly textile fabric treatment agent according to the present invention is a device for treating softeners, water repellents, dyes, and other substances on the textile fabric by using a tenter which can be sequentially immersed, dehydrated, and dried. The environmentally friendly fiber fabric treatment agent according to the invention is fixed to the fiber fabric.
즉, 도2에서 도시한 바와 같이 처리제 수용조(320)와 탈수용 로울러(200), 그리고 열풍건조용 챔버(Chamber, 미도시)로 구성되는 섬유원단 처리용 텐타기를 이용하게 되는데, 상기 처리제 수용조(320)에 본 발명에 의한 친환경 섬유원단 처리제(330)를 채워 상기 섬유원단(310)을 침지하게 된다. 또한, 상기 친환경 섬유원단 처리제(330)는 상기 섬유원단(310)의 종류에 따라 상기한 바와 같이 발수제, 나노물질, 그리고 증류수의 혼합비가 달라지므로 상기 침지단계에서 상기 처리제 수용조(320)는 가능한 한 적은 규모의 것으로 하여 상기 처리제(330)의 손실을 최소화하는 것이 바람직하다.
That is, as shown in FIG. 2, a textile fabric treatment tenter composed of a treatment agent
또한, 상기 로울러(200)에 의한 탈수단계시 로울러 압력은 3.5~4.0 ton으로 탈수함으로써 상기 발수제의 함량 조절과 함께 섬유원단의 부드러움을 유지하게 하는 것이 바람직하다.
In addition, during the dehydration step by the
또한, 상기 침지단계, 탈수단계, 그리고 열풍건조단계는 처리되는 섬유원단의 길이를 분당 8~9 야드(yard)로 하며, 상기 열풍건조단계는 6 챔버(chamber) 텐타기를 사용하여 각 챔버의 온도를 순차적으로 180, 175, 170, 170, 160, 150℃로 한다.
In addition, the immersion step, dehydration step, and hot air drying step is the length of the fiber fabric to be treated is 8 ~ 9 yards per minute (yard), the hot air drying step is used for each chamber using a six-chamber tenter The temperature is sequentially set to 180, 175, 170, 170, 160 and 150 ° C.
이에 의하면, 분당 처리되는 섬유원단의 길이는 통상의 섬유원단 처리공정에서의 13 야드보다 짧게 상기와 같이 8~9 야드로 하여 그 침지단계 및 탈수단계에서의 체류시간을 길게 하고 상기 열풍건조단계에서는 열풍건조용 챔버를 6개 사용하여 상기 각 챔버의 온도가 순차적으로 낮아지게 달리 설정하여 열풍건조함으로써 본 발명에 의한 친환경 섬유원단 처리제를 섬유원단에 완전히 고착시켜 일체화함으로써 우수한 내세탁성을 유지하게 된다.
According to this, the length of the fiber fabric to be treated per minute is shorter than 13 yards in the conventional fiber fabric processing step as 8 ~ 9 yards as described above to lengthen the residence time in the immersion and dehydration step and in the hot air drying step By using six hot air drying chambers, the temperature of each chamber is sequentially set differently so that the temperature of each chamber is dried to maintain excellent washing resistance by completely fixing and integrating the eco-friendly fiber fabric treatment agent according to the present invention to the fiber fabric. .
한편, 본 발명에 의한 친환경 섬유원단 처리제는 면, 마, 실크, 양모, 기타 나일론, 비닐론, 폴리에스테르 등의 합성섬유 등 모든 섬유원단에 적용하여 발수, 발유, 항균, 항곰팡이, 방오성, 집먼지진드기 기피성 등의 기능성 효과를 발휘할 수 있는데 상기 원료(발수제, 나노물질)의 혼합비율은 면과 같이 수분흡수율이 높은 섬유원단이 경우에는 발수제 함량 범위내에서 발수제의 양을 늘려주고, 실크, 합성섬유 등 수분흡수율이 낮은 섬유원단의 경우에는 발수제 양을 상대적으로 적게 하는 것이 바람직하다.
On the other hand, the environmentally friendly fiber fabric treatment agent according to the present invention is applied to all fabrics, such as cotton, hemp, silk, wool, and other synthetic fibers such as nylon, vinylon, polyester, water repellent, oil repellent, antibacterial, anti-fungal, antifouling, house dust mite Functional effects such as repellency can be exerted, but the mixing ratio of the raw material (water repellent, nano material) increases the amount of water repellent within the range of water repellent in the case of the fiber material having high water absorption such as cotton, silk, synthetic fiber For example, in the case of a fiber cloth having a low water absorption, it is preferable to reduce the amount of the water repellent relatively.
한편, 상기와 같은 처리방법으로 본 발명에 의한 친환경 섬유원단 처리제를 섬유원단에 상기와 같이 고착함으로써 우수한 내세탁성을 나타낼 뿐만 아니라 도3a 내지 도3d의 실험결과에서 확인할 수 있는 바와 같이 커피 등 이물질에 의한 얼룩이 발생하지 아니하고 본 발명에 의한 친환경 섬유원단 처리제가 섬유원단에 완전히 고착되어 일체화되는 것이다.
On the other hand, by adhering the environmentally friendly fiber fabric treatment agent according to the present invention to the fiber fabric by the treatment method as described above as well as excellent washing resistance as shown in the experimental results of Figures 3a to 3d foreign matter such as coffee Without staining by the environmentally friendly fiber fabric treatment agent according to the present invention is integrally fixed to the fiber fabric.
이하, 본 발명을 실시예를 통하여 더욱 상세히 설명한다.
Hereinafter, the present invention will be described in more detail with reference to examples.
<실험예 1><Experimental Example 1>
도3a 내지 도3d는 본 발명에 의한 친환경 섬유원단 처리제로 처리한 섬유원단의 실험예로서 실크 원단에 대한 실험결과를 나타낸 사진으로서, 본 발명에 의한 친환경 섬유원단 처리제는 나노 개성복합재료 0.5 ㎏, 불탄 성막물질(1,1,2,2-tetrahydroperfluoro acrylate) 5 ㎏, 기능성 첨가제 0.1 ㎏을 증류수 94.4 ㎏에 혼합하여 제조한 것을 사용하였으며, 이때, 상기 나노 개성복합재료는 나노 항균재료로서 30 ㎚ 크기의 SiO2, 나노 추화재료로서 20 ㎚ 크기의 TiO2, 나노 분해재료로서 60 ㎚ 크기의 ZnO, 나노 계면재료소서 50 ㎚ 크기의 Al2O3 및 나노 표면효능재료로서 5 ㎚ 크기의 TiO2를 각각 23 : 20 : 22 : 20 : 15의 중량비로 혼합하여 유기용매에 분산 후 불탄 표면활성제(Tetrafluoroisophthalonitirile 98%)를 첨가하여 반응시킨 것을 건조방식으로 유기용매를 제거하여 수득하였다. Figure 3a to 3d is a photograph showing the experimental results for the silk fabric as an experimental example of the fiber fabric treated with an environmentally friendly fiber fabric treatment agent according to the present invention, the eco-friendly fiber fabric treatment agent according to the present invention 0.5 kg nano-composite composite material, 5 kg of a non-elastic film (1,1,2,2-tetrahydroperfluoro acrylate) and 0.1 kg of a functional additive were mixed with 94.4 kg of distilled water, and the nano-composite composite material was nano-antibacterial material having a size of 30 nm. SiO 2 , 20 nm TiO 2 as nano-compound material, 60 nm ZnO as nano-decomposable material, Al 2 O 3 with 50 nm size as nano interfacial material and 5 nm TiO 2 as nano surface-effect material Each was mixed in a weight ratio of 23: 20: 22: 20: 15, dispersed in an organic solvent, and reacted by adding a fluorocarbon surfactant (Tetrafluoroisophthalonitirile 98%) to obtain an organic solvent by drying.
섬유원단은 실크를 사용하고 실크에 상기 처리제를 고착시키기 위해서 6 챔버 텐터기를 분당 처리되는 섬유원단의 길이가 8.5 야드(Yard)로 운전하고 각 챔버의 열풍건조온도는 순차적으로 180, 175, 170, 170, 160, 150℃로 운전하였다.
The fiber fabric uses silk, and the fiber fabric treated with 6 chamber tenter per minute is 8.5 yards per minute to fix the treatment agent on the silk, and the hot air drying temperature of each chamber is sequentially 180, 175, 170. , 170, 160, 150 ℃.
상기와 같이 처리된 본 발명의 실크와 미처리된 실크(실크원단)을 대상으로 하여 도3a 내지 도3d와 같은 실험을 실시하였다.
3A to 3D were performed on the silk of the present invention treated as described above and untreated silk (silk fabric).
즉, 도3a는 본 발명의 실크(20)와 실크원단(20')에 커피를 떨어뜨린 상태의 사진으로서 실크원단(20')의 경우에는 커피가 실크원단에 스며들고 흡수되어 퍼져있는 커피얼룩(21')의 상태인 반면에 본 발명 실크(20)의 경우에는 커피가 스며들거나 흡수되지 않고 방울을 형성하여 커피방울(20')의 상태임을 확인할 수 있다.
That is, Figure 3a is a picture of the coffee drop state in the
여기서, 도3b의 사진에서 보는 바와 같이 본 발명 실크(2)에 형성된 커피방울(21)을 두드리면 커피방울이 작아지면서 본 발명 실크에 스며들고 실크원단(20')의 경우 이미 커피가 스며들어 커피얼룩(21')을 형성하고 있음을 확인할 수 있다.
Here, as shown in the photograph of Figure 3b tapping the
나아가, 도3c의 사진에서 보는 바와 같이 두드려 스며든 커피방울(21)은 본 발명 실크(20)를 통과하여 바닥에 묻어나고 본 발명 실크에는 얼룩을 남기지 않는 것을 확인할 수 있다.
Further, as seen in the picture of Figure 3c tapping
도3b 내지 도3c와 달리 본 발명 실크에 형성된 커피방울을 화장지로 직접 찍어내면(탈수하면) 화장지에 완전히 흡수 제거되어 도3d의 사진에서 보는 바와 같이 커피방울이 흡수 제거된 자리(22)에는 전혀 얼룩자국이 남지 않음을 확인할 수 있다.
Unlike Figures 3b to 3c, when the coffee drops formed on the silk of the present invention are directly absorbed and removed by toilet paper (dehydration), they are completely absorbed and removed from the toilet paper as shown in the photograph of FIG. 3d. You can see that no marks are left.
또한, 상기 본 발명 실크에 대한 항균도, 방미도, 방오성, 발수도, 집먼지 진드기 기피성 등의 시험 성적에서도 각각 우수한 결과를 나타내었다.
In addition, the test results of the antimicrobial, anti-microbial, antifouling, water repellent, and house dust mite repellency of the present invention showed excellent results.
<실험예 2><Experimental Example 2>
도4는 본 발명에 의한 친환경 섬유원단 처리제로 처리한 섬유원단의 실험예로서 스타킹에 대한 실험결과를 나타낸 사진으로서, 처리제는 상기 실험예 1과 동일하게 제조하였으며, 섬유원단은 스타킹을 사용하고 스타킹에 상기 처리제를 고착시키기 위해서 6 챔버 텐터기를 분당 처리되는 섬유원단의 길이가 8.5 야드(yard)로 운전하고 각 챔버의 열풍건조온도는 순차적으로 180, 175, 170, 170, 160, 150℃로 운전하였다.
Figure 4 is a photograph showing the experimental results for the stockings as an experimental example of the fiber fabric treated with an environmentally friendly fiber fabric treatment agent according to the present invention, the treatment agent was prepared in the same manner as Experimental Example 1, the fiber fabric using stockings and stockings In order to fix the treatment agent on the fabric, the fiber chamber processed 6 minute tenter per minute was operated to 8.5 yards, and the hot air drying temperature of each chamber was sequentially increased to 180, 175, 170, 170, 160, and 150 ° C. Drive.
상기와 같이 처리된 본 발명 스타킹을 대상으로 하여 도4와 같은 실험을 실시하였다.
An experiment as shown in FIG. 4 was carried out with the present invention treated as described above.
즉, 도4의 (a) 사진과 같이 본 발명 스타킹(30)의 내부 공간에 물(31)을 담는 경우 도4의 (b) 사진과 같이 물이 전혀 새지 않음을 확인할 수 있으며 도4의 ( c) 사진과 같이 본 발명 스타킹을 늘어뜨려 구멍을 키워도 마찬가지로 물이 전혀 새지 않음을 확인할 수 있다.
That is, when
이상에서 확인할 수 있는 바와 같이 본 발명에 의한 친환경 섬유원단 처리제로 처리된 섬유원단을 발수제와 나노물질로 구성되는 본 발명에 의한 친환경 섬유원단 처리제로 처리됨으로써 물은 통과시키지 않고 공기는 통과시키는 미세한 가공이 형성되어 발수 효과를 발휘하는 것이며, 상기 처리제가 침지단계, 탈수단계, 특히 열풍건조단계를 거치면서 섬유원단에 완전히 고착되어 일체화됨으로써 상기 커피, 물과 같은 이물질은 압력을 가하는 경우 기공을 통하여 섬유원단을 통과될 수 있으나 압력이 가해지지 않는 경우에는 섬유원단으로 전혀 스며들거나 흡수되지 않고 분리되어 있는 상태에서 존재하게 되어 전혀 얼룩을 남기지 않고 깨끗하게 처리할 수 있게 되는 것이며 기존 발수섬유와는 우수한 내세탁성을 발휘하게 되는 것이다.
As can be seen from the above, the fiber fabric treated with the eco-friendly fiber fabric treatment agent according to the present invention is treated with the eco-friendly fiber fabric treatment agent according to the present invention consisting of a water repellent and a nanomaterial, so that air is passed without passing water. It is formed to exert a water repellent effect, the treatment agent is completely adhered to the fiber fabric through the immersion step, dehydration step, especially hot air drying step, so that the foreign matter, such as coffee, water through the pores when the pressure is applied to the fiber If it can pass through the fabric but no pressure is applied, it will not penetrate into the fabric or be absorbed and exist in the separated state so that it can be treated cleanly without leaving any stains. Sex will be exerted.
이상에서 설명한 것은 본 발명에 의한 친환경 섬유원단 처리제와 상기 친환경 섬유원단 처리제로 처리한 섬유원단 및 그 처리방법을 실시하기 위한 실시예에 불과한 것으로서, 본 발명은 상기한 실시예에 한정되지 않고, 이하의 특허청구범위에서 청구하는 바와 같이 본 발명의 요지를 벗어남이 없이 당해 발명이 속하는 분야에서 통상의 지식을 가진 자라면 누구든지 다양한 변경 실시가 가능한 범위까지 본 발명의 기술적 정신이 있다고 할 것이다.What has been described above is only an embodiment for implementing the environmentally friendly fiber fabric treatment agent and the fiber fabric treated with the environmentally friendly fiber fabric treatment agent and the treatment method according to the present invention, the present invention is not limited to the above embodiment, As claimed in the claims, any person having ordinary skill in the art without departing from the gist of the present invention will have the technical spirit of the present invention to the extent that various modifications can be made.
11. 항균물질 12. 나노 SiO2
13. 미세공
20. 본 발명 실크 20'. 실크원단
21. 커피방울 21'. 커피얼룩
22. 커피방울이 흡수 제거된 자리
30. 본 발명 스타킹 31. 물
200. 로울러 310. 섬유원단
320. 처리제 수용조 330. 처리제11.
13. Fine pores
20. The present invention silk 20 '. Silk fabric
21. Coffee Drops 21 '. Coffee stain
22. The spot where coffee bubble is absorbed and removed
30.
200.
320.
Claims (10)
2 to 5 parts by weight of 1,1,2,2-tetrahydrofluoroalkyl acrylate (1,1,2,2-Tetrahydrofluoroalkyl acrylate) as a water repellent, 20 to 50 nm SiO 2 , 10 to 30 nm TiO 2 , 50-80 nm ZnO, 30-60 nm Al 2 O 3 , and 3-7 nm TiO 2 , respectively, 20-30: 15-25: 20-30: 15-25: 15-20 0.1 to 2 parts by weight of nanomaterials mixed in a weight ratio of 85 to 95 parts by weight of distilled water mixed with an environmentally friendly fiber fabric treatment agent.
상기 나노재료는 톨루엔(Toluene) 또는 자일렌(Xylene)의 유기용매에 분산 후 테트라플루오로이소프탈로니트릴(Tetrafluoroisophthalonitirile 98%)을 첨가하여 반응시킨 것을 건조하여 유기용매를 제거한 다음 분말화하여 사용하는 것을 특징으로 하는 친환경 섬유원단 처리제.
The method according to claim 6,
The nanomaterial is dispersed in an organic solvent of toluene or xylene and then reacted by adding tetrafluoroisophthalonitrile (98%) to remove the organic solvent, followed by powdering. Eco-friendly textile fabric treatment agent.
상기 섬유원단을 상기 제4항, 제6항 내지 제7항 중 어느 하나의 항의 친환경 섬유원단 처리제에 침지하는 침지단계와;
상기 침지단계를 거친 섬유원단을 로울러 압력 3.5~4.0 ton으로 탈수하는 탄수단계와;
상기 탈수단계를 거친 섬유원단을 150~180℃의 열풍으로 건조하는 열풍건조단계로 이루어지되,
상기 침지단계, 탈수단계, 그리고 열풍건조단계는 처리되는 섬유원단의 길이를 분당 8~9 야드(yard)로 하며, 상기 열풍건조단계는 6 챔버(chamber) 텐타기를 사용하여 각 챔버의 온도를 순차적으로 180, 175, 170, 170, 160, 150℃로 하는 것을 특징으로 하는 친환경 섬유원단 처리제의 섬유원단 처리방법.
In the method of processing the fiber fabric,
An immersion step of immersing the fiber fabric in the environmentally friendly fiber fabric treatment agent of any one of claims 4 and 6;
A carbohydrate step of dewatering the fiber fabric subjected to the immersion step at a roller pressure of 3.5 to 4.0 ton;
The drying process is made of a hot air drying step of drying the fiber fabric subjected to the dehydration step with a hot air of 150 ~ 180 ℃,
The immersion step, dehydration step, and hot air drying step is the length of the fiber fabric to be treated to 8 ~ 9 yards per minute (yard), and the hot air drying step using a six-chamber tenter to determine the temperature of each chamber Textile fabric treatment method of environmentally friendly fiber fabric treatment agent characterized in that sequentially 180, 175, 170, 170, 160, 150 ℃.
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| KR101484893B1 (en) * | 2014-09-02 | 2015-01-22 | 김은숙 | Method for Preparing Knitting Yarn with Water Repellency |
| KR102179482B1 (en) * | 2017-10-29 | 2020-11-30 | 주식회사 포이즈 | The manufacturing method of outdoor fabric treated with hydroxyphenyl-s-triazines polymer uv absorber during dyeing process and coated with one side silicon resin coated |
| KR20190080532A (en) * | 2017-12-28 | 2019-07-08 | 주식회사 쇼미미디어앤트레이딩 | Manufacturing method of Antimicrobial Function Clothes |
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