KR101221782B1 - multi-layered adhesive tape - Google Patents

multi-layered adhesive tape Download PDF

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KR101221782B1
KR101221782B1 KR1020100077603A KR20100077603A KR101221782B1 KR 101221782 B1 KR101221782 B1 KR 101221782B1 KR 1020100077603 A KR1020100077603 A KR 1020100077603A KR 20100077603 A KR20100077603 A KR 20100077603A KR 101221782 B1 KR101221782 B1 KR 101221782B1
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South Korea
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film
adhesive tape
present
friction
coefficient
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KR1020100077603A
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KR20120015472A (en
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안창덕
나영수
정재현
이민호
김혜진
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세계화학공업(주)
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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J7/00Adhesives in the form of films or foils
    • C09J7/30Adhesives in the form of films or foils characterised by the adhesive composition
    • C09J7/38Pressure-sensitive adhesives [PSA]
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00Layered products comprising a layer of synthetic resin
    • B32B27/06Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material
    • B32B27/08Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B7/00Layered products characterised by the relation between layers; Layered products characterised by the relative orientation of features between layers, or by the relative values of a measurable parameter between layers, i.e. products comprising layers having different physical, chemical or physicochemical properties; Layered products characterised by the interconnection of layers
    • B32B7/04Interconnection of layers
    • B32B7/12Interconnection of layers using interposed adhesives or interposed materials with bonding properties
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J201/00Adhesives based on unspecified macromolecular compounds
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J7/00Adhesives in the form of films or foils
    • C09J7/20Adhesives in the form of films or foils characterised by their carriers
    • C09J7/22Plastics; Metallised plastics
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J7/00Adhesives in the form of films or foils
    • C09J7/20Adhesives in the form of films or foils characterised by their carriers
    • C09J7/29Laminated material
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J7/00Adhesives in the form of films or foils
    • C09J7/30Adhesives in the form of films or foils characterised by the adhesive composition
    • C09J7/38Pressure-sensitive adhesives [PSA]
    • C09J7/381Pressure-sensitive adhesives [PSA] based on macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J2203/00Applications of adhesives in processes or use of adhesives in the form of films or foils
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J2301/00Additional features of adhesives in the form of films or foils
    • C09J2301/10Additional features of adhesives in the form of films or foils characterized by the structural features of the adhesive tape or sheet
    • C09J2301/16Additional features of adhesives in the form of films or foils characterized by the structural features of the adhesive tape or sheet by the structure of the carrier layer
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J2301/00Additional features of adhesives in the form of films or foils
    • C09J2301/30Additional features of adhesives in the form of films or foils characterized by the chemical, physicochemical or physical properties of the adhesive or the carrier
    • C09J2301/302Additional features of adhesives in the form of films or foils characterized by the chemical, physicochemical or physical properties of the adhesive or the carrier the adhesive being pressure-sensitive, i.e. tacky at temperatures inferior to 30°C
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J2301/00Additional features of adhesives in the form of films or foils
    • C09J2301/30Additional features of adhesives in the form of films or foils characterized by the chemical, physicochemical or physical properties of the adhesive or the carrier
    • C09J2301/312Additional features of adhesives in the form of films or foils characterized by the chemical, physicochemical or physical properties of the adhesive or the carrier parameters being the characterizing feature

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Laminated Bodies (AREA)
  • Adhesive Tapes (AREA)
  • Adhesives Or Adhesive Processes (AREA)

Abstract

다층 점착 테이프가 제공된다.
본 발명에 따른 다층 점착 테이프는 성형물을 가공하기 위해 점착되고 가공 후 박리되는 점착 테이프로서, 점착제가 일면에 도포되며, 폴리에틸렌(PE), 폴리염화비닐(PVC), 에틸렌비닐아세테이트(EVA) 및 폴리우레탄(PU)으로 이루어진 군으로부터 선택된 중합체로 이루어진 제 1 필름; 및 상기 제 1 필름의 이면에 적층되며, 순간적으로 높은 충격강도를 구비하기 위해 배향폴리프로필렌(OPP), 고밀도 폴리에틸렌(HDPE), 폴리프로필렌(PP) 및 폴리에틸렌테레플탈레이트(PET)로 이루어진 군으로부터 선택된 중합체로 이루어진 제 2 필름을 포함하는 것을 특징으로 하는 다층 점착 테이프를 제공한다. 본 발명의 일 실시예에서 상기 제 1 필름의 마찰계수는 상기 제 2 필름의 마찰계수 보다 높으며, 본 발명의 일 실시예에서 제 2 필름의 마찰계수는 0.07 내지 0.2이다.
A multilayer adhesive tape is provided.
The multi-layer adhesive tape according to the present invention is an adhesive tape which is adhered to process a molding and peeled off after processing, wherein the adhesive is applied to one side, and polyethylene (PE), polyvinyl chloride (PVC), ethylene vinyl acetate (EVA) and poly A first film made of a polymer selected from the group consisting of urethanes (PU); And oriented polypropylene (OPP), high density polyethylene (HDPE), polypropylene (PP) and polyethylene terephthalate (PET), which are laminated on the back surface of the first film and have an instantaneous high impact strength. It provides a multi-layer adhesive tape comprising a second film made of the selected polymer. In one embodiment of the present invention, the coefficient of friction of the first film is higher than the coefficient of friction of the second film, in one embodiment of the present invention the coefficient of friction of the second film is 0.07 to 0.2.

Description

다층 점착 테이프 {multi-layered adhesive tape}Multi-layered Adhesive Tape

본 발명은 다층 점착 테이프에 관한 것으로, 보다 상세하게는 상부, 하부층 필름의 마찰력, 연성을 달리 구성함으로써 절곡 특성 등의 점착 테이프 물성을 향상시킨 다층 점착 테이프에 관한 것이다.The present invention relates to a multilayer adhesive tape, and more particularly, to a multilayer adhesive tape having improved adhesive tape physical properties such as bending characteristics by differently configuring frictional forces and ductility of upper and lower layer films.

일반적으로, 점착 테이프라 함은 두께가 얇은 띠 또는 시트 형상의 필름의 한쪽 면에 점착제가 도포된 테이프로서, 이러한 점착 테이프는 금속, 도장용 강판, 유리, 플라스틱 판 등의 표면을 이송작업 시 또는 절단, 곡, 프레스 작업시 보호하는 보호테이프로 널리 사용된다. 현재 일반적으로 사용되는 점착 테이프의 필름물질은 PVC, PE, PET 등이 있다. PVC는 표면 보호력은 우수하나, 가격이 비싸고, 염화물질의 사용 등으로 인한 비환경적이다는 단점이 있다. 반면 PE는 가격이 비교적 저렴하다는 장점이 있으나, 보호테이프의 필수 기능인 보호력이 약하다는 단점이 있다. 또한 PET 재질은 우수한 보호력이라는 장점이 있으나, 가공성이 떨어진다는 단점이 있다. 따라서, 표면 보호력과 함께 우수한 가공성을 갖는 점착 테이프가 절실한 상황이다.
In general, an adhesive tape is a tape in which an adhesive is applied to one side of a thin strip or sheet-like film. It is widely used as a protective tape to protect during cutting, bending and pressing work. Currently, the film material of the adhesive tape generally used is PVC, PE, PET and the like. PVC has excellent surface protection, but has the disadvantages of high price and non-environment due to the use of chloride. On the other hand, PE has the advantage of being relatively inexpensive, but has the disadvantage of weak protection, an essential function of the protective tape. In addition, PET has the advantage of excellent protection, but has the disadvantage of poor workability. Therefore, the adhesive tape which has the outstanding workability with surface protection force is urgently needed.

따라서, 본 발명이 해결하려는 과제는 우수한 가공성 및 표면 보호력을 갖는 다층 구조의 점착 테이프를 제공하는 것이다.Accordingly, the problem to be solved by the present invention is to provide an adhesive tape having a multilayer structure having excellent workability and surface protection.

상기 과제를 해결하기 위하여 본 발명은 성형물을 가공하기 위해 점착되고 가공 후 박리되는 점착 테이프로서, 상기 점착 테이프는 점착제가 일면에 도포되며, 폴리에틸렌(PE), 폴리염화비닐(PVC), 에틸렌비닐아세테이트(EVA) 및 폴리우레탄(PU)으로 이루어진 군으로부터 선택된 중합체로 이루어진 제 1 필름; 및In order to solve the above problems, the present invention is a pressure-sensitive adhesive tape for processing a molding and peeled after processing, the pressure-sensitive adhesive tape is coated on one side, polyethylene (PE), polyvinyl chloride (PVC), ethylene vinyl acetate A first film composed of a polymer selected from the group consisting of (EVA) and polyurethane (PU); And

상기 제 1 필름의 이면에 적층되며, 순간적으로 높은 충격강도를 구비하기 위해 배향폴리프로필렌(OPP), 고밀도 폴리에틸렌(HDPE), 폴리프로필렌(PP) 및 폴리에틸렌테레플탈레이트(PET)로 이루어진 군으로부터 선택된 중합체로 이루어진 제 2 필름을 포함하는 것을 특징으로 하는 다층 점착 테이프를 제공한다. 본 발명의 일 실시예에서 상기 제 1 필름의 마찰계수는 상기 제 2 필름의 마찰계수 보다 높으며, 본 발명의 일 실시예에서 제 2 필름의 마찰계수는 0.07 내지 0.2이다. Laminated on the back side of the first film, selected from the group consisting of oriented polypropylene (OPP), high density polyethylene (HDPE), polypropylene (PP) and polyethylene terephthalate (PET) to have an instantaneously high impact strength It provides a multilayer adhesive tape comprising a second film made of a polymer. In one embodiment of the present invention, the coefficient of friction of the first film is higher than the coefficient of friction of the second film, in one embodiment of the present invention the coefficient of friction of the second film is 0.07 to 0.2.

본 발명의 또 다른 일 실시예에서, 상기 제 2 필름의 충격 강도는 제 1 필름의 충격보다 크며, 상기 제 1 필름의 충격강도는 2.0 Ft-Lbs/In 미만이고, 상기 제 2 필름의 충격강도는 2.0 Ft-Lbs/In 이상일 수 있다. In another embodiment of the present invention, the impact strength of the second film is greater than the impact of the first film, the impact strength of the first film is less than 2.0 Ft-Lbs / In, the impact strength of the second film May be 2.0 Ft-Lbs / In or more.

본 발명의 또 다른 일 실시예에서 상기 제 1 필름의 굴곡 탄성 계수는 250,000~480,000, 제 2 필름의 굴곡 탄성 계수는 100,000 내지 250, 0000일 수 있으며, 상기 제 1 필름의 두께는 35 내지 130μm, 상기 제 2 필름의 두께는 15 내지 100μm 일 수 있다. In another embodiment of the present invention, the flexural modulus of the first film may be 250,000 to 480,000, the flexural modulus of the second film may be 100,000 to 250, 0000, and the thickness of the first film is 35 to 130 μm, The second film may have a thickness of about 15 μm to about 100 μm.

또한, 상기 점착제는 합성고무, 천연고무, 아크릴계 또는 우레탄 계 점착제이며, 상기 제 2 필름의 상부에는 이형제가 적층될 수 있다. In addition, the pressure-sensitive adhesive is a synthetic rubber, natural rubber, acrylic or urethane-based pressure-sensitive adhesive, a release agent may be stacked on top of the second film.

본 발명에 따른 다층 구조의 점착 테이프는 낮은 마찰력을 갖는 필름층과 높은 마찰력을 갖는 또 다른 필름층의 다층 구조를 갖는다. 특히 낮은 마찰력에 의한 가공성 향상과 함께 상기 또 다른 필름층에 의한 표면 보호 효과를 동시에 달성할 수 있다.The adhesive tape of the multilayer structure according to the present invention has a multilayer structure of a film layer having a low friction force and another film layer having a high friction force. In particular, the surface protection effect by the said another film layer can be simultaneously achieved with workability improvement by low frictional force.

도 1은 본 발명의 일 실시예에 따른 다층 구조의 점착 테이프의 단면도이다.
도 2 및 3은 비교예의 보호테이프를 보호표면에 접착시킨 후, 표면을 절곡시킨 후의 사진이다.
도 4 및 5는 본 발명에 따른 보호 테이프를 표면에 접착시킨 후, 동일한 방식으로 표면을 절곡시킨 후의 사진이다.
1 is a cross-sectional view of an adhesive tape of a multilayer structure according to an embodiment of the present invention.
2 and 3 are photographs after the protective tape of the comparative example is bonded to the protective surface and then the surface is bent.
4 and 5 are photographs after the protective tape according to the present invention is adhered to the surface, and then the surface is bent in the same manner.

이하, 본 발명을 도면을 참조하여 상세하게 설명하고자 한다. 다음에 소개되는 실시예들은 당업자에게 본 발명의 사상이 충분히 전달될 수 있도록 하기 위해 예로서 제공되는 것이다. 따라서 본 발명은 이하 설명된 실시예들에 한정되지 않고 다른 형태로 구체화될 수도 있다. 그리고 도면들에 있어서, 구성요소의 폭, 길이, 두께 등은 편의를 위하여 과장되어 표현될 수도 있다. 명세서 전체에 걸쳐서 동일한 참조번호들은 동일한 구성요소들을 나타낸다.DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENTS The present invention will now be described in detail with reference to the drawings. The following embodiments are provided as examples to ensure that the spirit of the present invention can be fully conveyed to those skilled in the art. Therefore, the present invention is not limited to the embodiments described below, but may be embodied in other forms. In the drawings, the width, length, thickness, etc. of the components may be exaggerated for convenience. Like numbers refer to like elements throughout.

본 발명은 상술한 바와 같이 보호력과 가공성이라는 점착 테이프의 주요 성능을 달성하고자, 상이한 물성을 갖는 두 개의 필름으로 이루어진 다층 구조의 점착 테이프를 제공한다. 특히 상부 필름의 마찰력을 하부 필름보다 낮게 하여, 가공성을 향상시키며, 동시에 하부 필름은 우수한 탄성 특성 및 두꺼운 두께를 가짐으로써 표면 보호력을 향상시켰다.
The present invention provides a pressure-sensitive adhesive tape of a multilayer structure consisting of two films having different physical properties, in order to achieve the main performance of the pressure-sensitive adhesive tape of protection and processability as described above. In particular, the frictional force of the upper film is lower than that of the lower film, thereby improving workability, while at the same time the lower film has excellent elastic properties and thick thickness, thereby improving surface protection.

도 1은 본 발명의 일 실시예에 따른 다층 구조의 점착 테이프의 단면도이다.1 is a cross-sectional view of an adhesive tape of a multilayer structure according to an embodiment of the present invention.

도 1을 참조하면, 상기 점착 테이프는 점착제(110)가 일면에 도포된 제 1 필름(120) 및 상기 제 1 필름(120)의 타면에 접합된 제 2 필름(130)을 포함하는 구조이다. 특히 본 발명은 상기 제 2 필름(130)의 마찰계수(COF, coefficient of friction)가 0.07 내지 0.2인 경우, 본 발명에 따른 보호 테이프의 가공 특성이 현저하게 향상되는 점에 기초하여 본 발명에 이르게 되었다. 이때, 상기 하부의 제 1 필름(120)의 마찰력은 제 2 필름(130)보다 높으며, 따라서 상기 제 1 필름(120)의 마찰계수는 제 2 필름(130)의 마찰계수보다 높을 수 있다.
Referring to FIG. 1, the adhesive tape has a structure including a first film 120 having an adhesive 110 applied to one surface and a second film 130 bonded to the other surface of the first film 120. In particular, the present invention leads to the present invention based on the fact that the processing characteristics of the protective tape according to the present invention are significantly improved when the coefficient of friction (COF) of the second film 130 is 0.07 to 0.2. It became. In this case, the frictional force of the lower first film 120 may be higher than that of the second film 130. Therefore, the frictional coefficient of the first film 120 may be higher than the frictional coefficient of the second film 130.

더 나아가, 본 발명에 따른 보호용 점착 테이프의 제 2 필름(130)은 제 1 필름(120)보다 높은 충격강도(Impact Strength)를 갖는 것이 바람직한데, 그 이유는 제 2 필름(130)이 표면 충격으로부터 최초 충격을 흡수하는 층이기 때문이다. 즉, 상부의 필름층으로 동일한 층을 중첩하여 사용하는 종래 기술과 달리, 본 발명은 상부 필름의 마찰력 및 충격 강도를 달리함으로써 보호 테이프의 보호 효과 이외에 가공성 등을 향상시키며, 이러한 제 2 필름(130)의 물질로서 배향폴리프로필렌(OPP), 고밀도 폴리에틸렌(HDPE), 폴리프로필렌(PP) 및 폴리에틸렌테레플탈레이트(PET)로 이루어진 군으로부터 선택된 하나 이상의 중합체를 제공한다. 또한, 점착제가 일면에 도포되며, 보호 표면에 직접 접촉하는 제 1 필름(130)은 제 2 필름(130)보다는 높은 마찰력을 가져도 무방하므로, 본 발명은 제 1 필름(120)의 성분으로 폴리에틸렌(PE), 폴리염화비닐(PVC), 에틸렌비닐아세테이트(EVA) 및 폴리우레탄(PU)으로 이루어진 군으로부터 선택된 중합체를 제공한다. Furthermore, it is preferable that the second film 130 of the protective adhesive tape according to the present invention has a higher impact strength than the first film 120, because the second film 130 has a surface impact. It is because it is a layer which absorbs an initial shock from the. That is, unlike the prior art of using the same layer by overlapping the upper film layer, the present invention improves processability and the like in addition to the protective effect of the protective tape by varying the frictional force and impact strength of the upper film, the second film 130 ), At least one polymer selected from the group consisting of oriented polypropylene (OPP), high density polyethylene (HDPE), polypropylene (PP) and polyethylene terephthalate (PET). In addition, since the pressure-sensitive adhesive is applied to one surface, the first film 130 in direct contact with the protective surface may have a higher friction than the second film 130, the present invention is a polyethylene as a component of the first film 120 (PE), polyvinyl chloride (PVC), ethylene vinyl acetate (EVA) and polyurethane (PU).

본 발명의 일 실시예에서 Notched Izod(73F) 방식으로 측정된 충격 강도는, 제 2 필름(130)은 2.0 이상, 제 1 필름(120)은 2.0이하였다. In one embodiment of the present invention, the impact strength measured by the Notched Izod (73F) method, the second film 130 is 2.0 or more, the first film 120 was 2.0 or less.

또한 제 1 필름(120)의 굴곡탄성계수(Flexural Modules of Elasticity, 73F)는 250,000~480,000(PSI), 제 2 필름(130)의 굴곡탄성계수는 100,000 내지 250, 0000(PSI)인 것이 바람직하다. 즉, 제 2 필름(130)이 보다 탄성이 큰 경우, 외부에서 가해지는 힘에 대하여 제 2 필름(130)은 보다 용이하게 휘어지거나, 변형되므로, 보호필름 전체의 가공성 향상에 기여하게 된다. In addition, the flexural modulus of elasticity (Flexural Modules of Elasticity, 73F) of the first film 120 is 250,000 ~ 480,000 (PSI), the flexural modulus of the second film 130 is preferably 100,000 to 250, 0000 (PSI). . That is, when the second film 130 is more elastic, the second film 130 is more easily bent or deformed with respect to a force applied from the outside, thereby contributing to the improvement of processability of the entire protective film.

또한, 상기 제 1 필름(120)의 두께는 35 내지 130μm, 상기 제 2 필름(130)의 두께는 15 내지 100μm 인 것이 바람직하다. 즉, 상기 제 1 필름(120)의 두께의 가용 범위가 제 2 필름(130)보다는 더 두꺼운 경향을 보이는데, 그 이유는 제 1 필름(120)이 기본적인 표면 보호 역할을 수행하는 저층이기 때문이다. 만약, 상기 제 1 필름(120)의 두께가 상기 범위보다 얇다면 충분한 표면 보호 효과를 기대하기 어렵고, 반대로 상기 범위보다 두꺼우면 가공성이 떨어지기 때문이다. 또한, 본 발명의 일 실시예에서 상기 점착제(110)는 합성고무, 천연고무, 아크릴계 또는 우레탄 계 점착제이며, 상기 제 2 필름(130) 상부에는 보호테이프가 롤 상태로 감긴 뒤 쉽게 풀릴 수 있도록 하는 이형기능을 가지는 층인 이형제가 적층될 수 있다.
In addition, the thickness of the first film 120 is 35 to 130μm, the thickness of the second film 130 is preferably 15 to 100μm. That is, the available range of the thickness of the first film 120 tends to be thicker than the second film 130, because the first film 120 is a low layer that serves as a basic surface protection role. If the thickness of the first film 120 is thinner than the above range, it is difficult to expect a sufficient surface protection effect. On the contrary, if the thickness of the first film 120 is thicker than the above range, the workability is inferior. In addition, in one embodiment of the present invention, the pressure-sensitive adhesive 110 is a synthetic rubber, natural rubber, acrylic or urethane-based pressure-sensitive adhesive, the second film 130, the protective tape is wound on a roll state so that it can be easily released A release agent, which is a layer having a release function, may be laminated.

이하 절곡실험을 통하여 본 발명에 따른 보호테이프의 효과를 설명한다.
Hereinafter, the effect of the protective tape according to the present invention through the bending test.

실시예Example

본 발명에 따라 제 1 필름(120)으로 PVC, 제 2 필름(130)으로 PE가 순차적으로 적층된 2층의 보호테이프를 제조하였다.
According to the present invention, a protective film of two layers in which PE was sequentially stacked in a PVC and a second film 130 in a first film 120 was prepared.

비교예Comparative example

PVC 단일층의 보호테이프를 실시예와 동일한 두께로 제조하였다.
The protective tape of the PVC single layer was prepared in the same thickness as in Example.

실험결과Experiment result

도 2 및 3은 비교예의 보호테이프를 보호표면에 접착시킨 후, 표면을 절곡시킨 후의 사진이다. 2 and 3 are photographs after the protective tape of the comparative example is bonded to the protective surface and then the surface is bent.

도 2 및 3을 참조하면, 표면 절곡에 따라 보호 테이프의 표면이 불규칙적으로 변화됨을 알 수 있다. 이것은 결국 보호 테이프의 표면 접착력이 약화되는 것을 의미한다. 2 and 3, it can be seen that the surface of the protective tape is irregularly changed as the surface is bent. This in turn means that the surface adhesion of the protective tape is weakened.

도 4 및 5는 본 발명에 따른 보호 테이프를 표면에 접착시킨 후, 동일한 방식으로 표면을 절곡시킨 후의 사진이다. 4 and 5 are photographs after the protective tape according to the present invention is adhered to the surface, and then the surface is bent in the same manner.

도 4 및 5를 참조하면, 표면 절곡이 일어났음에도 불구하고, 이층 구조의 보호 테이프는 균일한 표면 특성을 보이며, 절곡 전과 동일하게 표면과의 균일합 접착 상태를 보이는 것을 알 수 있다. 4 and 5, although the surface bending occurs, it can be seen that the protective tape of the two-layer structure shows a uniform surface characteristics, and evenly bonded state with the surface as before the bending.

Claims (9)

성형물을 가공하기 위해 점착되고 가공 후 박리되는 점착 테이프로서, 상기 점착 테이프는
점착제가 일면에 도포되며, 폴리에틸렌(PE), 폴리염화비닐(PVC), 에틸렌비닐아세테이트(EVA) 및 폴리우레탄(PU)으로 이루어진 군으로부터 선택된 중합체로 이루어진 제 1 필름; 및
상기 제 1 필름의 이면에 적층되며, 순간적으로 높은 충격강도를 구비하기 위해 배향폴리프로필렌(OPP), 고밀도 폴리에틸렌(HDPE), 폴리프로필렌(PP) 및 폴리에틸렌테레플탈레이트(PET)로 이루어진 군으로부터 선택된 중합체로 이루어진 제 2 필름을 포함하는 것을 특징으로 하는 다층 점착 테이프.
A pressure-sensitive adhesive tape which is adhered to process a molding and peeled off after processing, wherein the adhesive tape
A pressure-sensitive adhesive is applied to one surface, the first film comprising a polymer selected from the group consisting of polyethylene (PE), polyvinyl chloride (PVC), ethylene vinyl acetate (EVA), and polyurethane (PU); And
Laminated on the back side of the first film, selected from the group consisting of oriented polypropylene (OPP), high density polyethylene (HDPE), polypropylene (PP) and polyethylene terephthalate (PET) to have an instantaneously high impact strength And a second film made of a polymer.
제 1항에 있어서,
상기 제 1 필름의 마찰계수는 상기 제 2 필름의 마찰계수 보다 높은 것을 특징으로 하는 다층 점착 테이프.
The method of claim 1,
The coefficient of friction of the first film is a multilayer adhesive tape, characterized in that higher than the coefficient of friction of the second film.
제 2항에 있어서,
상기 제 2 필름의 마찰계수는 0.07 내지 0.2인 것을 특징으로 하는 다층 점착 테이프.
The method of claim 2,
The coefficient of friction of the second film is a multilayer adhesive tape, characterized in that 0.07 to 0.2.
제 1항에 있어서,
상기 제 2 필름의 충격 강도는 제 1 필름의 충격보다 크며, 상기 제 1 필름의 충격강도는 2.0 Ft-Lbs/In 미만이고, 상기 제 2 필름의 충격강도는 2.0 Ft-Lbs/In 이상인 것을 특징으로 하는 다층 점착 테이프.
The method of claim 1,
The impact strength of the second film is greater than the impact of the first film, the impact strength of the first film is less than 2.0 Ft-Lbs / In, the impact strength of the second film is 2.0 Ft-Lbs / In or more Multilayer adhesive tape.
제 1항에 있어서
상기 제 1 필름의 굴곡 탄성 계수는 250,000~480,000, 제 2 굴곡 탄성 계수는 100,000 내지 250, 0000인 것을 특징으로 하는 다층 점착 테이프.
The method of claim 1, wherein
The flexural modulus of the first film is 250,000 to 480,000, the second flexural modulus is 100,000 to 250, 0000, characterized in that the multilayer adhesive tape.
제 1항 내지 5항 중 어느 한 항에 있어서,
상기 제 1 필름의 두께는 35 내지 130μm 인 것을 특징으로 하는 하는 다층 점착 테이프.
The method according to any one of claims 1 to 5,
The thickness of the first film is a multilayer adhesive tape, characterized in that 35 to 130μm.
제 6항에 있어서,
상기 제 2 필름의 두께는 15 내지 100μm 인 것을 특징으로 하는 하는 다층 점착 테이프.
The method according to claim 6,
The thickness of the second film is a multilayer adhesive tape, characterized in that 15 to 100μm.
제 1항 내지 제 5항 중 어느 한 항에 있어서,
상기 점착제는 합성고무, 천연고무, 아크릴계 또는 우레탄 계 점착제인 것을 특징으로 하는 다층 점착 테이프.
The method according to any one of claims 1 to 5,
The pressure-sensitive adhesive is a multi-layered adhesive tape, characterized in that the synthetic rubber, natural rubber, acrylic or urethane-based adhesive.
제 1항 내지 제 5항 중 어느 한 항에 있어서,
상기 제 2 필름의 상부에는 이형제가 적층된 것을 특징으로 하는 다층 점착 테이프.
The method according to any one of claims 1 to 5,
A multilayer adhesive tape, characterized in that the release agent is laminated on the upper portion of the second film.
KR1020100077603A 2010-08-12 2010-08-12 multi-layered adhesive tape KR101221782B1 (en)

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Citations (4)

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JPH08282722A (en) * 1995-04-13 1996-10-29 Nitto Denko Corp Separator, packaging material or base material for adhesive
KR100270480B1 (en) 1998-10-30 2000-12-01 최좌진 Lamination film having heat-sealing peoperties
JP2001288426A (en) * 2000-04-06 2001-10-16 Kansai Paint Co Ltd Self-adhesive tape
KR100391782B1 (en) 2002-03-12 2003-07-16 Eduwell Com Co Ltd Self-adhesive plastic sheet containing two plastic film layers and preparation method thereof

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH08282722A (en) * 1995-04-13 1996-10-29 Nitto Denko Corp Separator, packaging material or base material for adhesive
KR100270480B1 (en) 1998-10-30 2000-12-01 최좌진 Lamination film having heat-sealing peoperties
JP2001288426A (en) * 2000-04-06 2001-10-16 Kansai Paint Co Ltd Self-adhesive tape
KR100391782B1 (en) 2002-03-12 2003-07-16 Eduwell Com Co Ltd Self-adhesive plastic sheet containing two plastic film layers and preparation method thereof

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