KR101178303B1 - Luminescent spray - Google Patents

Abstract

The present invention relates to a luminescent spray in which a sprayed material such as an eye spray or sprayed paint emits light by itself, and it is difficult to identify a sprayed material in a dark place when using a spray such as a conventional eye spray. In order to improve, it is characterized in that the light emitting materials such as hydrogen peroxide and diphenyl oxalate, fluorescent dyes or pigments are combined with the existing sprayed material to be sprayed in the dark and at the same time to emit light.

Description

Luminescent spray {LUMINESCENT SPRAY}

The present invention relates to a luminescent spray in which a sprayed material such as an eye spray or sprayed paint emits light by itself, and improves that the sprayed material does not emit light when using a spray such as a conventional eye spray. It shows the effect of making the material sprayed well. Specifically, in the present invention, a hydrocarbon compound, such as diphenyloxalate-based compound, liquid chlorofluorocarbons (CFC), and liquefied petroleum gas (LPG), which is a main material of chemicals, is added to one spray container. Place a mixture of hydrogen peroxide, a high surface tension solution, and a hydrocarbon solution in the other spray container, which is sprayed at the same time as a double spray gun, causing the chemicals to react and shine, showing the sprayed material. .

In general, the spray can is filled with hydrocarbons such as butane gas, LPG gas, and CFC gas, which are used as propellants, at a pressure higher than atmospheric pressure, and are sprayed with materials suitable for the purpose of use, such as paints, insecticides, and high surface tension solutions. For example, a solution with a high surface tension generally means soapy water, which is used to produce an eye spray. There are two types of spraying methods: pressure spraying paint or insecticide and pressurizing spraying or spraying on plants.

Propellants currently in use are hydrocarbons such as butane, which boil at lower temperatures and easily convert from liquid to steam (or vice versa). The propellant in the spray container is primarily a liquid and acts as a solvent or carrier for the product. When the contents of the can are sprayed into the air, a small amount of liquid propellant in the mixture evaporates because the atmospheric pressure is lower than the pressure in the can, and the spraying contents (eg water or pesticides, etc.) are dispersed and dispersed into small particles. This spray is technically called an aerosol because it contains liquid or solid particles in the gas.

The principle is that the propellant actually foams in an eye spray or foam aerosol, whereby the liquid gas mixed with the soap solution changes into a gas due to the difference in atmospheric pressure, which produces a small droplet, and at the same time the high pressure in the spray As it is sprayed, it is sprayed into the air and spreads like snow. Once the spraying process is completed, the pressure in the can is lowered, but gas begins to regenerate in the remaining liquid propellant, allowing the pressure to recover and ready for aerosol injection.

In general, chemiluminescence is light generated by a chemical reaction. An example of natural chemiluminescence is light emission from a male firefly. Fireflies are made by special cells containing a luminescent substance called luciferin and a luminescent enzyme called luciferase, and when oxygen is supplied, adenosine triphosphate (ATP) is produced, which is excited by luciferase and generates energy and returns to the ground state. Energy appears in the form of light energy. The color of light is usually yellow ~ yellow green and the wavelength is 500 ~ 700mm, and the color depends on the type of luciferase. In another example, a chemical light (glow stick) has a double tube inside, in which the glass tube contains hydrogen peroxide and the outer plastic tube contains a combination of diester, oxalic acid and dye. When the chemical light is bent, the glass tube inside is broken, the hydrogen peroxide inside and the outer chemical meet, and the chemical energy is converted into light energy to make light. This light is an exothermic cold light that emits a continuous chemical reaction at room temperature.

Such chemical light began to be commercialized for military operation and emergency lighting in the 80s and 90s, but it was expensive and relatively large product, and now the miniaturization and low price are in progress. It is widely used as a light stick. [Reference: Malin Emteborg et al., "Influence of Imidazole and Bis (trichlorophenyl) Oxalate in the Oxalyldiimidazole Peroxyoxalate Chemiluminescence Reaction", Anal. Chem. 69 (1997) pp. 2109-2114; Mojtaba Shamsipur et al., "A study of peroxyoxalate-chemiluminescence of 4,4-bis {[4,6-bis (2-hydroxyethyl) amino-1,3,5-triazin-2-yl] amino} stilbene-2.2 -disulfo nic acid-disodium salt as a novel blue fluorescer ", Spectrochimica Acta Part A 66 (2007) pp. 546-551; LJBollyky and MM Rauhut, US Pat. 3,597,362 (1971) to American Cyanamid; Patent Registration No. 10-0514062 (Registration Date; 2005.09.02), Patent Publication No. 10-2009-0087221 (Publication Date; 2009.08.17), Patent Publication No. 10-2007-0019289 (Publication Date; February 15, 2007), Patent Publication No. 10-2008-0022152 (2008.03.10)]

The present invention has been made for the purpose of improving the spraying or spray-type paint, such as the conventional eye spray is less likely to appear in the existing sprayed contents.

In addition, there have been no reports of chemiluminescent substances in the contents sprayed until now, which means that the emission duration is not maintained for a long time when the chemiluminescent substances are mixed. This is because there is a disadvantage in that the performance is drastically reduced while being affected by the same external environment.

The present invention uses a storage method that is stored separately in the spray container inside the spray container, so that the effect of blocking the external environment and the mixing process in the spraying process can be preserved longer than conventional chemical light products It is designed to prevent the performance deterioration even while using the product, and to maintain the light emitting duration for a long time.

The chemiluminescent materials and the materials to be sprayed are stored separately in the first and second spray containers 105 and 106 and co-injected, and the first spray container (in the first and second spray containers 105 and 106 is used). In the 105, the first liquid component 201 (diphenyloxalate, fluorescent dye or pigment) and the gas component 200 (CFC or LPG) are placed, and the second spray container 106 is filled with the second liquid component 202. (Hydrogen peroxide, soapy water) and the gas component 200 (CFC or LPG) are mixed to constitute the first and second liquid mixtures ₂₀₃ and 204.

Each of the spray vessels 105 and 106 is coupled to the fixed shoulder 104, and is operated by pressing the upper injection button 100 and the first and second spray tubes 105 and 108 configured inside the first and second spray vessels 105 and 106. It is characterized in that the injection through the injection tube, and the injection through the injection nozzle (111).

In accordance with the above-described configuration, the present invention uses a conventional chemical luminescent material in a spray container, so that the chemical luminescent material can be easily stored, has a long luminescence time and an expiration date, and unlike the conventional chemical light product, The advantage is that the materials can be used without being exposed.

And the basic idea of developing a spray that emits chemiluminescent materials by combining eye sprays can be extended or applied to the manufacture of various spray-type paints, insecticide sprays, and pen-type writing instruments applied with chemiluminescent materials.

1 is an embodiment of the present invention light emitting spray.
2 is a partial cross-sectional view of the present invention luminescent spray.
3 is an overall cross-sectional view of the present invention luminescent spray.
4 is a cross-sectional view of a liquid mixture for the light emitting spray of the present invention.

To this end, a space is typically formed in a tube made of a flexible material, and an ampule filled with hydrogen peroxide is inserted into the space, and a structure in which a diphenyloxalate and a pigment are filled in the space around the ampoule. Without using a general chemical light having the present invention, as shown in Figure 2 the present invention, the contents of the conventional spraying (for example, soapy water, etc.) containing the two materials in the first, second spray container 105, 106 and It suggests a new way of spraying together.

1 is an embodiment of the spraying the contents in the light emitting spray manufacturing apparatus 10 of the present invention.

2 is a state diagram according to an embodiment of the present invention.

As shown in the figure, the luminescent spray 10 is mounted on top of each of the first spray container 105 and the second spray container 106 and each of the spray containers 105 and 106 containing liquid contents. A pair of connecting fittings 109 for sucking and discharging the contents in the spray containers 105 and 106, a case body cover 103 and a first spray container 105 in which the respective spray containers 105 and 106 are embedded; Fixed shoulder 104 coupled to the open upper end of the case body cover 103 in the state that the second spray container 106 is fastened, a pair of connection fittings 109, the role of connecting to the spray nozzle 111 And it consists of a manual injection pump, an actuator, the spray top 110, including the injection switch box, the injection button 100 and the middle cover 102 of the case.

In addition, FIG. 2 and the upper cover 101 of the case formed in a structure detachable to the middle cover 102 of the case while protecting the spray upper 110 of the first spray 105 and the second spray 106 container and The injection button 100 is further shown.

FIG. 3 is an overall cross-sectional view including a partial cross-sectional view of the light emitting spray 10 of FIG. 2.

Referring to the configuration of FIG. 3, the spray button 100 for simultaneously spraying the first spray container 105, the second spray container 106, the first and second spray pipes 107, 108, and the contents at the same time, It consists of a manual injection pump for spraying, the spray top 110 including the actuator and the injection nozzle 111, the contents of the two spray containers 105, 106 is a spray material that emits light.

Looking at the contents of the light emitting spray 10 is divided into a gas component 200 and the first, second liquid components (201, 202). The gas component 200 is a CFC gas or LPG gas that serves to inert an atmosphere of inert gas into each spray container 105, 106, which is a liquid volatilization of the liquid CFC or liquid LPG as it naturally evaporates. ) Is filled in. The first and second liquid components 105 and 106 are filled with different materials in both the first and second spray containers 105 and 106, respectively. The first liquid component 201 of the first spray container 105 is the core of the light emission characteristic. Diphenyloxalate, fluorescent dye or pigment, and a solvent, which play a role, are present in a mixed state with a liquid CFC (or liquid LPG). The second liquid component 202 of the second spray container 106 is composed of hydrogen peroxide and a substance to be sprayed (for example, a solution having a high surface tension in the case of an eye spray) mixed with a liquid CFC (or liquid LPG). Exists as.

In FIG. 4, when the spray container is shaken before spraying, finely dispersed CFC gas (or LPG gas) bubbles 205 are present in the first and second liquid mixtures 203 and 204. In this state, when the first and second liquid mixtures 203 and 204 in the spray container are not mixed well or bubbles are poorly formed, a surfactant is added to the liquid to form an emulsion or suspension like a lotion or a cream. The spraying properties can be controlled by increasing the density of the bubbles.

In the first liquid mixture 203 contained in the first spray container 105, diphenyloxalate, which plays a key role in luminescent properties, is oxalic acid bis (2,4,6-trichlorophenyl) formed in a liquid form. ), solid bis (2,4,5-trichlorophenyl-6-carbopentoxyphenyl) oxalate (CPPO), bis (2,4,6-trichlorophenyl) oxalate (TCPO) and solid acetate powder (Bis [3, 5,6-trichlorosalicyl iso-pentyl] oxalate (CIPO) and mixtures thereof.

As the pigment or fluorescent dye (Color ring matter), yellow (Yellow; 1-chloro-9, 10-bis (phenylethynyl) -2-chloroanthracene), yellow green (C ₃₀ H ₁₇ U), Green ; C ₃₀ H _18, 9,10-bis (phenylethynyl), Red (N, N'-bis (2,6-diisopropylphenyl) -1, 6, 7, 12-tetrakis (p-tert-butylphenoxy) -3, 4, 9, 10 -perylenetetracarboxydiimide, rubrene), diphenyloxalate using yellow, indigo, blue (Blue; 2-chloro-9,10-bis (p-methoxyphenyl) anthracene) or other dyes (diphenyloxalate) is mixed in a weight ratio of about 0.01 to 0.015% and put in the first spray container 105 above.

The second spray container 106 mainly contains contents (for example, soapy water and the like) and hydrogen peroxide (hydrogenperoxide, H ₂ O ₂ ) for injection purposes. In general, the weight ratio of soapy water to hydrogen peroxide is 7: 3. In addition, catalytic materials such as sodium salicylate (C ₇ H ₅ O ₃ Na), sasalbutylamine salt of persalicylic acid (C ₂₃ H ₄₁ O ₃ N), sodium peroxide (C ₇ H ₅ O ₃ Na) It may be mixed, and may also include solvents such as tert-butanol, dimethyl phthalate (DMP, C ₁₀ H ₁₀ O ₄ ), dibutyl phthalate (DBP, C ₁₆ H ₂₂ O ₄ ), and the like. The catalyst material plays a role of controlling the rate of chemiluminescence reaction and can be mixed at a weight ratio of about 0.00002 to 0.005% with respect to diphenyloxalate, and if the amount is large, it accelerates the reaction to shorten the emission time. The higher the brightness, the lower the addition amount, the lower the reaction speed, the longer the light emission time and the lower the brightness. The solvent dissolves solid materials such as diphenyl oxalate, fluorescent dyes or pigments and catalyst materials in the form of powder to enable various substances to fully react with each other in solution to effectively produce chemiluminescence, and diphenyloxal It can be mixed at a weight ratio of about 0.010 to 0.100% with respect to the diphenyloxalate.

The first and second liquid components 201 and 202 contained in the first spray container 105 and the second spray container 106 are mixed together in each spray container but do not react, and are blocked from the external environment. Preservation is improved by maintaining. In addition, the light emitting reaction occurs as the two materials are sprayed from the two spray containers 105 and 106 and the two materials are mixed.

The basic principle of chemiluminescence reaction is as follows. First, hydrogen peroxide reacts with diphenyloxalate (eg, sialium) and a catalytic material to form two [1,2] Dioxetane-3,4-diones, with two oxygens connecting two carbonyl groups. Phenol is made as a byproduct. [1,2] Dioxetane-3,4-dione is a four-membered square ring compound that is unstable and breaks the square ring, resulting in two molecules of carbon dioxide and energy. At this time, the generated energy is absorbed by the fluorescent dyes in the ground state and becomes an excited state, and then returns to the ground state, where the energy of the ground state and the excited state is lighted again. It will be released as energy. Light generated at this time emits light in a unique visible region according to the fluorescent dye molecules. The fluorescent dye molecules used use only the catalytic amount because energy absorption and emission are repeated.

Chemical light composed of conventional plastic and muffle is made of silver foil foil and PP or PE material to block moisture and light, and add moisture desiccant to chemical light to remove moisture inside the paper. There was a need to preserve performance. This means that the lifetime of the chemical light is sensitive to the external environment. Unlike the conventional chemical light which rapidly loses fluorescence performance when exposed to such an external environment, the present invention is likely to be exposed to light or external environment because the chemical emitting material is placed in a very stable state in a spray container in a liquid CFC atmosphere. Therefore, the fluorescence performance is not lost, and thus, the shelf life is significantly increased as compared with the existing chemical light, and thus it can be used for a long time even after opening the package.

The present invention described above can be variously substituted and changed within the scope without departing from the technical spirit of the present invention for those of ordinary skill in the art to which the present invention belongs, it is limited to the above-described embodiments and drawings no.

10. Luminous Spray
100. Injection button 101. Case top cover
102. Middle cover 103. Case body cover
104. Fixed Shoulder 105. First Spray Bottle
106. The second spray container 107. The first spray pipe
108. Second injection pipe 109. Connecting fitting part
110. Spray Top 111. Spray Nozzle
200. Gas component (CFC or LPG)
201.First liquid component
202. Second liquid component
203. First liquid mixture
204. Second Liquid Mixture
205. Bubbles

Claims (11)

A first spray container 105 for storing a mixture of diphenyloxalate and fluorescent dyes or pigments, gas of CFC or LPG, and mixing and spraying them;
A second spray container 106 capable of storing and spraying a gas of hydrogen peroxide, CFC, or LPG, which may form an eye shape when spraying in the air, and the mixture and the chemiluminescent reaction;
A first spray tube (107) for directing the substance to spray the substance in the first spray container (105);
A second spray tube (108) for directing the contents to spray the contents in the second spray container (106);
A simultaneous injection nozzle 111 connected to the first injection pipe 107 and the second injection pipe 108 and capable of simultaneously injecting the contents of the first and second spray containers 105 and 106;
A simultaneous spraying button 100 for simultaneously spraying the contents of the first and second spray containers 105 and 106 to the simultaneous spraying nozzle 111; With
When the co-injection button 100 is operated, the materials of the first and second spray containers 105 and 106 are simultaneously injected into the air, whereby the fluorescent dye molecules absorb energy emitted by chemical reaction between diphenyloxalate and hydrogen peroxide, and then light energy. Can emit a self-luminous material,
Catalytic material added to the second spray container 106 to control the rate of chemiluminescence reaction;
A solvent for inducing a chemiluminescence reaction by dissolving diphenyl oxalate as a solid material of the first spray container 105 and a fluorescent dye or pigment;
A solvent for inducing a chemiluminescence reaction by dissolving a catalyst material that is a solid material of the second spray container 106; And
Surfactant added to the first and second spray vessels (105, 106); Light emitting spray, characterized in that it further comprises.
The method of claim 1,
The diphenyl oxalate is oxalic acid bis (2,4,6-trichlorophenyl) ester or bis (2,4,5-trichlorophenyl-6-carbopentoxyphenyl) oxalate (CPPO) or bis (2,4,6) -Trichlorophenyl) oxalate (TCPO) or a luminescent spray characterized in that a mixture thereof. The method of claim 1,
The fluorescent dye or pigment may be yellow (Yellow; 1-chloro-9,10-bis (phenylethynyl) -2-chloroanthracene), yellow green (C ₃₀ H ₁₇ U), green (Green; C ₃₀ H ₁₈ , 9,10-bis (phenylethynyl), Red (N, N'-bis (2,6-diisopropylphenyl) -1,6,7,12-tetrakis (p-tert-butylphenoxy) -3,4,9 10-perylenetetracarboxydiimide, rubrene), yellow, navy blue, blue (Blue; 2-chloro-9, 10-bis (p-methoxyphenyl) anthracene) or a luminescent spray, characterized in that any one of a known color. The method of claim 1,
The catalyst material is any one of sodium salicylate (C ₇ H ₅ O ₃ Na), sasalbutyric acid succinate amine salt (C ₂₃ H ₄₁ O ₃ N), sodium peroxide (C ₇ H ₅ O ₃ Na) Light emitting spray characterized by the above-mentioned. The method of claim 1,
The fluorescent dye or pigment is a luminescent spray, characterized in that the weight ratio of 0.01 to 0.015% relative to the diphenyl oxalate. The method of claim 1,
The catalyst material is a luminescent spray, characterized in that the weight ratio of 0.00002 to 0.005% to diphenyl oxalate. The method of claim 1,
The solvent is a light emitting spray, characterized in that the weight ratio of 0.010 ~ 0.100% with respect to diphenyl oxalate.


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