JP2005253625A - Light emitting golf ball - Google Patents

Light emitting golf ball Download PDF

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JP2005253625A
JP2005253625A JP2004068015A JP2004068015A JP2005253625A JP 2005253625 A JP2005253625 A JP 2005253625A JP 2004068015 A JP2004068015 A JP 2004068015A JP 2004068015 A JP2004068015 A JP 2004068015A JP 2005253625 A JP2005253625 A JP 2005253625A
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core
light emitting
cavity
light
golf ball
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Shiro Harada
士郎 原田
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Nihon Kagaku Hakko KK
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Nihon Kagaku Hakko KK
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Abstract

<P>PROBLEM TO BE SOLVED: To provide a light emitting golf ball which is visible even from far by increasing emitted light luminance compared to a conventional light emitting golf ball and is repeatedly used by replacing a chemical light emitting body without damaging the flying performance by maintaining the balance of the ball. <P>SOLUTION: In the light emitting golf ball, for a ball main body, a plurality of roughly semispherical first void parts are formed from the surface of a core to the inside, second void parts of a diameter smaller than the diameter of the void parts are provided from the bottom parts of the first void parts to the center of the core, narrow holes passed through from the second void parts to the opposite side of the core are opened further, and a transparent cover layer is formed on the core surface. The cylindrical part of the chemical light emitting body formed of the sealing container of a flexible transparent material composed of the cylindrical part and an expanded light emitting part of the diameter larger than that, is densely inserted to the second void part and the light emitting part is fitted to the first void part. <P>COPYRIGHT: (C)2005,JPO&NCIPI

Description

本発明は発光機能を有し、夜間のゴルフプレーに使用し得るボールに関するものであり、更に詳述すると従来の発光ゴルフボールよりも発光性に優れ、従って遠くからでも視認することができ且つボールのバランスを保持しているので、通常のボールと同様の飛行性能を有する発光ゴルフボールに関する。   The present invention relates to a ball that has a light emitting function and can be used for golf play at night. More specifically, the present invention has a light emitting property superior to that of a conventional light emitting golf ball, and can therefore be seen from a distance. Therefore, the present invention relates to a light emitting golf ball having a flight performance similar to that of a normal ball.

近年、照明設備を有するゴルフ場や野球場ができ、夜間にプレーすることが可能となっている。しかしながら通常のボールを用いて夜プレーをすると照明の届く所にボールが飛んで行った場合は良いが、照明の届かない所に飛んだ場合は、ボールを捜すのが困難であったり、紛失してしまうこともあった。   In recent years, golf courses and baseball stadiums having lighting facilities have been established, and it has become possible to play at night. However, when playing at night using a normal ball, it is good if the ball flies to a place where the light reaches, but if it flies out of the light, it is difficult to find the ball or it is lost. Sometimes it happened.

このため夜間のプレーに使用し得るボールとして特開昭62−2974号公報に記載の発光ゴルフボールは自己発光機能を有している点で、本発明と同様であるが断面逆三角形状の空洞部に発光体が配置され、さらにその上から芯球(コア)及び発光体を透明カバーで周囲をおおっている構造が図1に記載されている。これでは発光体を取り替えることができないという欠点がある。また、芯球の中心軸に直交して、すなわち、芯球の表面に発光体を横にして(図1)配置する為、発光体の全長、直径が制限される。つまり実施例にあるように長さ20mm、内径2mm、外径3mmのように、きわめて小さく、発光液が少量にならざるを得ず、したがって発光輝度が向上しない問題があった。又発光体を芯球に配置後、透明カバーを形成する工程で、その成形時の圧力により、発光体中のガラス容器が割れ不良品が発生する要因ともなっていた。
特開昭62−2974号公報
For this reason, the light emitting golf ball described in Japanese Patent Application Laid-Open No. 62-2974 is a ball that can be used for night play. FIG. 1 shows a structure in which a light emitter is disposed in the portion, and a core ball (core) and a light emitter are covered with a transparent cover from above. This has the disadvantage that the light emitter cannot be replaced. Further, since the light emitter is disposed in a direction orthogonal to the central axis of the core sphere, that is, on the surface of the core sphere (FIG. 1), the total length and diameter of the light emitter are limited. That is, as in the example, there was a problem that the length was 20 mm, the inner diameter was 2 mm, and the outer diameter was 3 mm, and the luminescent liquid had to be small, so that the luminance was not improved. Further, in the process of forming the transparent cover after the luminous body is disposed on the core ball, the glass container in the luminous body is also a factor in generating defective cracks due to the pressure during molding.
JP-A-62-2974

本発明は上記問題点を鑑みてなされたものであって、従来の発光ゴルフボールより発光輝度を上げ、従って遠くからでも視認でき、且つ化学発光体を付け替えて何度でも使用できるようにし、またボールのバランスを維持することにより、その飛行性能をそこなうことのない発光ゴルフボールを提供することを目的とする。   The present invention has been made in view of the above-mentioned problems, and has higher luminance than conventional light emitting golf balls, and can be viewed from a distance, and can be used any number of times by changing the chemiluminescent material. An object of the present invention is to provide a light emitting golf ball that does not impair its flight performance by maintaining the balance of the ball.

コアのバランス(ボールのバランス)を維持すべく、複数の第一空洞部を設ける最少の数は4ヶである。すなわちコアの内部に仮想の正三角錐を作り(図1)、その4つの頂点に略半球状の空洞を設ける。コアの内部に正立方体を想定し、その頂点表面に、8ヶ所空洞を設けてもよい。これはボールのバランスを保つために重要な条件であり、これにより通常のゴルフボールと変らない良好な飛行性能を有することとなる。このように、少なくとも4ヶ所の第一空洞部に化学発光体の発光部が嵌め込まれている為、どのような位置でボールが静止しても、いずれかの発光部が視界に入る。   In order to maintain the balance of the core (ball balance), the minimum number of the plurality of first cavities is four. That is, a virtual equilateral triangular pyramid is made inside the core (FIG. 1), and approximately hemispherical cavities are provided at the four apexes thereof. A regular cube may be assumed inside the core, and eight cavities may be provided on the apex surface. This is an important condition for maintaining the balance of the ball, and as a result, the flight performance is the same as that of a normal golf ball. As described above, since the light emitting portions of the chemiluminescent body are fitted in at least four first cavities, any light emitting portion enters the field of view regardless of the position of the ball.

略半球状の第一空洞部は図2に示すような曲面を有し、中央の発光部からの光を効率よく、外側に放つための形状であればよく、厳密な意味の半球状を意味するものではない。又曲面上に凹凸を付けて、光を散乱させるものも本発明に属する。コア自体が白色系の素材であれば、光反射層を設けなくてもよいが、光を吸収しやすい素材の場合は塗装したり、アルミ蒸着等を施す。   The substantially hemispherical first cavity portion has a curved surface as shown in FIG. 2 and may be any shape that efficiently emits light from the central light emitting portion to the outside. Not what you want. In addition, the present invention also includes an object that has irregularities on a curved surface to scatter light. If the core itself is a white material, it is not necessary to provide a light reflecting layer. However, if the core is a material that easily absorbs light, it is painted or aluminum evaporated.

この第一空洞部の底部中央からコアの中心に向かって第二空洞部を穿つ、この第二空洞部の内径は前記化学発光体の円筒部の直径よりも、わずかに小さくしたり、第二空洞部にテーパを付けて、円筒部が密に嵌合する構造とする。これにより発光体が固定される。化学発光体の容器は、可撓性を有し、透明又は半透明のポリエチレンかポリプロピレンの合成樹脂でインジェクションブローやブロー成型等の方法で成形する。   The second cavity is drilled from the center of the bottom of the first cavity toward the center of the core. The inner diameter of the second cavity is slightly smaller than the diameter of the cylindrical portion of the chemiluminescent body, The hollow portion is tapered so that the cylindrical portion is closely fitted. Thereby, the light emitter is fixed. The chemiluminescent container is flexible and is formed of a transparent or translucent polyethylene or polypropylene synthetic resin by a method such as injection blow or blow molding.

化学発光体は、円筒部とこの直径より大きい略球型又は楕円球等の発光部よりなっている。例えば球型の場合の体積は4/3×πr3(πは円周率、rは半径)であり、単なる棒型の場合の体積は、πr×L(Lは全長)図2に示すように、球型、棒型の全長は同じとし、球の直径を全長の半分と設定した場合のそれぞれの体積は、球型 πr×1/2×L+4/3×π(1/2×L)、棒型は πr×L。棒型の全長20mm、直径3mmとし、球型の全長20mm、円筒部の直径3mm、球の直径10mmとした場合のそれぞれの体積は、棒型が約0.1413cm、球型が、約0.594cmとなり、約4倍の液量となる。球の直径をもっと小さくしたり、楕円球等としても、棒型に比べて2倍以上の発光液の使用が可能となる。 The chemiluminescent body is composed of a cylindrical portion and a light emitting portion having a substantially spherical shape or an elliptical sphere larger than the diameter. For example, the volume in the case of a sphere type is 4/3 × πr 3 (where π is a circumference ratio, r is a radius), and the volume in the case of a simple rod type is πr 2 × L (L is the total length) as shown in FIG. Thus, the total length of the spherical shape and the rod shape is the same, and the volume when the diameter of the sphere is set to half of the total length is the spherical shape πr 2 × 1/2 × L + 4/3 × π (1/2 × L) 3 , Bar shape is πr 2 × L. The total volume of the rod type when the rod type is 20 mm, the diameter is 3 mm, the spherical type is 20 mm, the cylindrical part is 3 mm, and the diameter of the sphere is 10 mm. The rod type is about 0.1413 cm 3 , and the spherical type is about 0. 594 cm 3 , approximately 4 times the liquid volume. Even if the diameter of the sphere is made smaller or an elliptical sphere or the like, it is possible to use a luminescent solution more than twice as much as the rod type.

第二空洞部の底からコアの中心を通って、反対側まで貫通した細穴を穿つことにより、化学発光体取り外し用穴となる。すなわち細長い棒状のものを反対側の細穴に挿入し、円筒部分を押し進めることにより、化学発光体を外すことができる。第一空洞部及びコアの表面に、透明又は半透明のポリアミド、ポリウレタン、ポリウレア、ポリブタジエン、アイオノマーなる樹脂を射出成型法あるいは圧縮成型法にてカバーする。   A hole for removing the chemiluminescent body is formed by drilling a narrow hole penetrating from the bottom of the second cavity portion to the opposite side through the center of the core. That is, the chemiluminescent material can be removed by inserting a long and thin rod-like object into the narrow hole on the opposite side and pushing the cylindrical portion forward. A transparent or translucent polyamide, polyurethane, polyurea, polybutadiene, or ionomer resin is covered on the surface of the first cavity and the core by an injection molding method or a compression molding method.

化学発光を呈する2種類の薬品は蛍光液並びに酸化液と一般に呼ばれている。そのいずれかをガラス容器に封入するものであるが、長期保存性は水分に弱い蛍光液をガラス容器に密封する方が効果的である。一例として酸化液はフタル酸ジメチル、t−ブタノール、過酸化水素水及び触媒であり、蛍光液はフタル酸ジブチル、修酸エステル、蛍光物質よりなる組成物である。なお、長時間発光を持続させる手段として、蛍光液中に修酸エステルをフタル酸ジブチルの溶解度以上加えて固体状で沈殿した状態にすれば、過酸化水素と修酸エステルの反応の進行と共に固体の修酸エステルが溶解し、溶解した分だけ反応することを繰り返すため、持続した発光が得られる。この場合蛍光物質は長時間の発光に十分な量を加えておく、同じく長時間発光を持続させる手段として、無溶媒とし修酸エステル及び蛍光物質を固体状で存在させれば、上記と同様の持続した発光が得られる。   Two types of chemicals that exhibit chemiluminescence are commonly called fluorescent solutions and oxidizing solutions. One of them is sealed in a glass container. For long-term storage, it is more effective to seal a fluorescent solution weak in moisture in a glass container. As an example, the oxidizing solution is dimethyl phthalate, t-butanol, hydrogen peroxide solution and a catalyst, and the fluorescent solution is a composition comprising dibutyl phthalate, oxalic acid ester, and fluorescent material. In addition, as a means of sustaining light emission for a long time, if the oxalic acid ester is added to the fluorescent solution at a solubility higher than that of dibutyl phthalate to precipitate it in a solid state, the solid will be solidified as the reaction of hydrogen peroxide and the oxalic acid ester proceeds. Since the oxalic acid ester is dissolved and the reaction is repeated for the dissolved amount, continuous light emission can be obtained. In this case, the fluorescent material is added in a sufficient amount for long-time emission. Similarly, as a means for maintaining long-time emission, if no solvate and the fluorescent material are present in a solid state, the same as above, Sustained luminescence is obtained.

使用する時は、化学発光体を曲げて、中のガラス容器を割り、2つの薬品を混合すると発光が始まる。この発光体の円筒部分を各第二空洞部に密に嵌合するように発光部を持って押し込む。発光部の先端は第一空洞部より飛び出ないようにする。このボールをクラブで打つと、ボールの飛行曲線や方向がプレーヤーに視認される。なお、予め、各空洞部に化学発光体を配置したゴルフボールを準備し、スタート時のドライバーショットの打撃による衝撃で、化学発光体を発光させる事も出来る。   When in use, the chemiluminescent body is bent, the glass container inside is split, and when the two chemicals are mixed, light emission begins. The light emitting portion is pushed in with the light emitting portion so that the cylindrical portion of the light emitting body is closely fitted to each second cavity portion. The tip of the light emitting part is prevented from jumping out from the first cavity part. When this ball is hit with a club, the flight curve and direction of the ball are visually recognized by the player. It is also possible to prepare a golf ball in which a chemiluminescent body is disposed in each cavity in advance and cause the chemiluminescent body to emit light by an impact caused by hitting a driver shot at the start.

本発明によると、上述のごとく、通常のボールと同様の構造であり、且つ発光部もバランスよく配置されているため飛行性能に優れたものである。また従来の発光ゴルフボールに比べ、発光の輝度の向上及び発光持続時間に必須である発光薬品の液量を、充分に確保でき、且つその発する光を反射面で効率よく外側に向かわせるため、優れた発光性を有し、従って、照明の届かない暗い所は勿論、飛行中においても又、かなり遠い距離からでも視認できる効果がある。   According to the present invention, as described above, the structure is the same as that of a normal ball, and the light emitting parts are arranged in a well-balanced manner, so that the flight performance is excellent. Also, compared to conventional light emitting golf balls, the amount of light emitting chemicals essential for improving the luminance of light emission and the light emission duration can be sufficiently secured, and the emitted light is efficiently directed to the outside on the reflective surface. It has an excellent light-emitting property, so that it can be visually recognized not only in a dark place where the illumination does not reach, but also in a flight and from a considerably long distance.

以下、本発明の発光ゴルフボールの実施の形態を図面を参照しながら詳細に説明する。
図2は本発明の発光ゴルフボールについての一実施例の形態を示すもので、化学発光体の全長が18mm、円筒部の直径は3mm、その長さは9mm、発光部は略卵型とし、その最大直径は7.5mm、長さ9mmとした。また肉厚を0.3〜0.4mmとし、ポリエチレン樹脂にてブロー成形する。この容器の中に直径2.2mm、全長16mm、肉厚0.1mmの密閉ガラス管を入れる。この密閉ガラス管の中には、フタル酸ジブチルにビス(2,4,5−トリクロロ−6−カルボイソペンチルオキシフェニル)オキザレート及び1−クロロ−9,10−ビス(フェニルエチニル)アントラセンが溶解し、かつ固体状でも存在している。これはこの2種類の物質をフタル酸ジブチルに過飽和に加えて、加熱融解し、その状態でガラス容器に注入、溶封した後、室温に戻すことにより容易に製造できる。
Hereinafter, embodiments of the light emitting golf ball of the present invention will be described in detail with reference to the drawings.
FIG. 2 shows an embodiment of the light emitting golf ball of the present invention. The chemiluminescent body has a total length of 18 mm, the cylindrical portion has a diameter of 3 mm, its length is 9 mm, and the light emitting portion has a substantially egg shape. The maximum diameter was 7.5 mm and the length was 9 mm. The wall thickness is 0.3 to 0.4 mm, and blow molding is performed with a polyethylene resin. A sealed glass tube having a diameter of 2.2 mm, a total length of 16 mm, and a wall thickness of 0.1 mm is placed in the container. In this sealed glass tube, bis (2,4,5-trichloro-6-carboisopentyloxyphenyl) oxalate and 1-chloro-9,10-bis (phenylethynyl) anthracene are dissolved in dibutyl phthalate. In addition, it exists in a solid state. This can be easily produced by adding these two substances to dibutyl phthalate in supersaturation, heating and melting them, pouring them into a glass container in that state, sealing them, and then returning them to room temperature.

前記ブロー成形した容器の円筒部6の開口部より酸化液を注入した後、密閉ガラス容器9を入れ、開口部を閉じれば完成する。次に直径が約40mmのブタジエンゴムを主原料とした白色のコア1の表面に直径11mm深さ11mmの半球状第一空洞部2を4ヶ所、互いの間隔がすべて同一になる位置に開ける(図1、図2)。このコアの周囲に透明なアイオノマー樹脂でカバー5する。これは射出成型法にて行った。 After injecting the oxidizing solution from the opening of the cylindrical part 6 of the blow molded container, the sealed glass container 9 is put and the opening is closed to complete. Next, four hemispherical first cavities 2 having a diameter of 11 mm and a depth of 11 mm are formed on the surface of a white core 1 made of butadiene rubber having a diameter of about 40 mm as a main raw material, at positions where the distances between them are all the same ( FIG. 1, FIG. 2). A cover 5 is covered with a transparent ionomer resin around the core. This was done by injection molding.

その後、第一空洞部2に充填されている樹脂層に直径7.5mm深さ10mmの半球状の穴を開けることにより、第一空洞部2の曲面に厚さ1mmの透明な層が形成される。なお、本発明ではこの第一空洞部の透明な樹脂層は必ずしも必要ではない。この第一空洞部の底に直径2.98mmで深さ9mmの第二空洞部3をボールの中心に向かって開ける。さらにこの第二空洞部よりボールの反対側に向かって、直径2.3mmの細穴4を貫通させる。この完成したゴルフボール本体の4ヶ所の第一空洞部2に予め発光をスタートさせた上記化学発光体8をそれぞれ押し込んで装着すると、充分な液量を確保した発光部7から出る光は白色コア1の第一空洞部2の内側曲面に反射して、外側に放出され、強い光が得られる。 Thereafter, a hemispherical hole having a diameter of 7.5 mm and a depth of 10 mm is formed in the resin layer filled in the first cavity 2 to form a transparent layer having a thickness of 1 mm on the curved surface of the first cavity 2. The In the present invention, the transparent resin layer in the first cavity is not always necessary. A second cavity 3 having a diameter of 2.98 mm and a depth of 9 mm is opened at the bottom of the first cavity toward the center of the ball. Further, a narrow hole 4 having a diameter of 2.3 mm is penetrated from the second cavity toward the opposite side of the ball. When the chemiluminescent body 8 that has started to emit light is pushed into the four first cavities 2 of the completed golf ball body, the light emitted from the light emitting section 7 with a sufficient amount of liquid is emitted from the white core. 1 is reflected on the inner curved surface of the first cavity 2 and emitted to the outside, so that strong light is obtained.

本発明の一実施例におけるコアに第一空洞部を設ける位置を示す説明図。Explanatory drawing which shows the position which provides a 1st cavity part in the core in one Example of this invention. 本発明の一実施例における発光ゴルフボールの断面説明図。BRIEF DESCRIPTION OF THE DRAWINGS Sectional explanatory drawing of the light emission golf ball in one Example of this invention.

符号の説明Explanation of symbols

1.コア、2.第一空洞部、3.第二空洞部、4.細穴、5.透明又は半透明のカバー層、6.円筒部、7.発光部、8.化学発光体、9.ガラス容器 1. Core, 2. 1. first cavity, 2. second cavity, 4. Small hole, 5. Transparent or translucent cover layer, 6. cylindrical part; Light emitting section, 8. 8. chemiluminescent, Glass container

Claims (6)

コアの表面から内部に向けて、略半球状の第一空洞部を複数形成し、それぞれの第一空洞部は互いに同じ間隔を有するように配置され、かつ第一空洞部の底部からコアの中心に向かって、同空洞部の径よりも小さな径の第二空洞部を設け、さらに同第二空洞部からコアの反対側まで貫通した細穴を開けると共に、コア表面に透明又は半透明のカバー層が形成されたボール本体に円筒部と、これより径の大きいふくらんだ発光部よりなる可撓性を有し透明な素材よりなる密封容器内に、混合することにより化学発光を呈する第一の薬品が封入され、かつ同容器内に収容された密封ガラス容器内に第二の薬品が充填されて封入された化学発光体の円筒部を上記、第二空洞部に密に封入して第一空洞部に発光部が嵌合した化学発光体が着脱自在に装着できることを特徴とした発光ゴルフボール。   A plurality of substantially hemispherical first cavities are formed from the surface of the core toward the inside, and the first cavities are arranged so as to have the same distance from each other, and from the bottom of the first cavity to the center of the core A second cavity portion having a diameter smaller than the diameter of the cavity portion is provided, a fine hole penetrating from the second cavity portion to the opposite side of the core is opened, and a transparent or translucent cover is formed on the core surface. In a sealed container made of a transparent and transparent material consisting of a cylindrical part and a light emitting part having a larger diameter than the cylindrical part on the ball body on which the layer is formed, a first that exhibits chemiluminescence by mixing. A cylindrical portion of a chemiluminescent body filled with a second chemical in a sealed glass container enclosed with the chemical and sealed in the second cavity is first sealed. A chemiluminescent body with a light emitting part fitted in the cavity is detachable. A light-emitting golf ball which is characterized in that it can be. コアの表面から内部に向けて、略半球状の第一空洞部を複数形成し、それぞれの第一空洞部は互いに同じ間隔を有するように配置され、かつ第一空洞部の底部からコアの中心に向かって、同空洞部の径よりも小さな径の第二空洞部を設け、さらに同第二空洞部からコアの反対側まで貫通した細穴を開けると共に、コア表面及び第一空洞部の表面に透明又は半透明のカバー層が形成されたボール本体に円筒部と、これより径の大きいふくらんだ発光部よりなる可撓性を有し透明な素材よりなる密封容器内に、混合することにより化学発光を呈する第一の薬品が封入され、かつ同容器内に収容された密封ガラス容器内に第二の薬品が充填されて封入された化学発光体の円筒部を上記、第二空洞部に密に封入して第一空洞部に発光部が嵌合した化学発光体が着脱自在に装着できることを特徴とした発光ゴルフボール。   A plurality of substantially hemispherical first cavities are formed from the surface of the core toward the inside, and the first cavities are arranged so as to have the same distance from each other, and from the bottom of the first cavity to the center of the core A second cavity portion having a diameter smaller than the diameter of the cavity portion is provided, a fine hole penetrating from the second cavity portion to the opposite side of the core is opened, and the core surface and the surface of the first cavity portion By mixing in a sealed container made of a transparent and transparent material consisting of a cylindrical part and a bulging light emitting part with a larger diameter on the ball body on which a transparent or translucent cover layer is formed. The cylindrical portion of the chemiluminescent body filled with the second chemical in the sealed glass container encapsulated with the first chemical exhibiting chemiluminescence and enclosed in the sealed container is filled in the second cavity. Chemistry in which the light-emitting part is fitted in the first cavity with tightly sealed Emitting golf ball which light body is characterized in that can be attached detachably. 上記第一空洞部の曲面に光反射層を形成した請求項1又は2記載の発光ゴルフボール。   3. The light emitting golf ball according to claim 1, wherein a light reflecting layer is formed on the curved surface of the first cavity. 白色又は白色に近い色の素材で成形したコアよりなる請求項1又は2記載の発光ゴルフボール。   The light-emitting golf ball according to claim 1 or 2, comprising a core formed of a material having a white color or a color close to white. 密封ガラス容器内に充填された第二薬品が溶媒中で修酸エステル及び蛍光物質が粉体又は結晶等の固体状で存在し、このガラス容器の外側で容器内の第一薬品を酸化液とした請求項1又は2記載の発光ゴルフボール。   The second chemical filled in the sealed glass container is present in the solvent in the form of a solid such as oxalic acid ester and fluorescent substance in the form of powder or crystals, and the first chemical in the container is defined as the oxidizing solution outside the glass container. The light-emitting golf ball according to claim 1 or 2. 密封ガラス容器内に充填された第二薬品が無溶媒で修酸エステル及び蛍光物質が粉体又は結晶等の固体状で存在し、このガラス容器の外側で容器内の第一薬品を酸化液とした請求項1又は2記載の発光ゴルフボール。   The second chemical filled in the sealed glass container is solvent-free, and the oxalic acid ester and the fluorescent substance are present in a solid form such as powder or crystal. The first chemical in the container outside the glass container is the oxidizing solution. The light-emitting golf ball according to claim 1 or 2.
JP2004068015A 2004-03-10 2004-03-10 Light emitting golf ball Pending JP2005253625A (en)

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Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102614637A (en) * 2012-04-15 2012-08-01 姬志刚 Luminescent softball for performance
CN102614635A (en) * 2012-04-13 2012-08-01 姬志刚 Vibrating luminescent exercise ball
CN102614634A (en) * 2012-04-13 2012-08-01 姬志刚 Luminous football
WO2014092467A1 (en) * 2012-12-12 2014-06-19 Lee Hyung-Seog Golf tee having guideline display function

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102614635A (en) * 2012-04-13 2012-08-01 姬志刚 Vibrating luminescent exercise ball
CN102614634A (en) * 2012-04-13 2012-08-01 姬志刚 Luminous football
CN102614637A (en) * 2012-04-15 2012-08-01 姬志刚 Luminescent softball for performance
WO2014092467A1 (en) * 2012-12-12 2014-06-19 Lee Hyung-Seog Golf tee having guideline display function
CN104884135A (en) * 2012-12-12 2015-09-02 李炯锡 Golf tee having guideline display function
KR20150106886A (en) * 2012-12-12 2015-09-22 이형석 Golf tee having guideline display function
KR101656638B1 (en) * 2012-12-12 2016-09-09 이형석 Golf tee having guideline display function

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