JP2001286794A - Chemiluminescent liquid-containing aerosol product - Google Patents

Abstract

PROBLEM TO BE SOLVED: To provide a chemiluminescent liquid-containing aerosol product capable of being housed and preserved in a high quality state and prevented from the deterioration caused by a shock during transport and preservation by dividing a fluorescent liquid and an oxidizing liquid to remove an element causing the deterioration of capacity. SOLUTION: The chemiluminescent liquid-containing aerosol product consists of a shrinkable inner bag housing the fluorescent liquid, a container main body capable of cutting off ultraviolet rays and moisture and the aerosol product containing the fluorescent liquid comprising a pressurizing agent present between the inner bag and the container main body and/or the shrinkable inner bag housing the fluorescent liquid, a container main body capable of cutting off ultraviolet rays and moisture and the aerosol product containing the oxidizing liquid comprising the pressurizing agent present between the inner bag and the container main body.

Description

DETAILED DESCRIPTION OF THE INVENTION

[0001]

BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention comprises a shrinkable inner bag having a fluorescent solution and an oxidizing solution separately, a container body capable of blocking ultraviolet rays and moisture, and a pressurizing agent present between the inner bag and the container body. Related to aerosol products. More specifically, by storing the fluorescent liquid and the oxidizing liquid separately in a container body capable of blocking ultraviolet rays and moisture, the quality of each liquid can be maintained, and chemiluminescence can be achieved by mixing and emitting light with an injection member. The present invention relates to an aerosol product capable of partially using a liquid.

[0002]

2. Description of the Related Art A chemiluminescent liquid is composed of a fluorescent liquid such as an oxalate or a fluorescent substance, and an oxidizing liquid such as hydrogen peroxide or sodium salicylate, and emits light by a chemical reaction by mixing both. Therefore, either the fluorescent liquid or the oxidizing liquid is housed in a glass ampule, the other liquid is arranged around the ampoule, and the whole is commercialized in a state where the whole liquid is sealed in a transparent plastic pipe.

[0003] Since the chemiluminescent liquid is easily deteriorated by ultraviolet rays and moisture, it has to be put in an aluminum foil or a desiccant must be used, so that the packaging is complicated. In addition, if the sealing degree of the glass ampule or the transparent plastic pipe is defective, it deteriorates immediately and the luminous ability is remarkably reduced, and the glass ampule is damaged in the aluminum foil when shocked during transportation and storage. There were many troubles, such as emission of light and no emission even when the aluminum foil was opened during use.

On the other hand, since the luminous ability is almost proportional to the amount of each liquid, in order to obtain an appropriate amount of luminous power corresponding to the purpose of use, it is necessary to select various capacity sizes, and various varieties are produced. Needed. Nevertheless, it was not possible to obtain the appropriate luminous power as needed.

[0005]

DISCLOSURE OF THE INVENTION The present invention not only stores and preserves in a high-quality state except for an element that degrades performance by separating a fluorescent solution and an oxidizing solution, and also provides a means for preventing shock during transportation or storage. It is to provide a means for solving a defect.
Another object of the present invention is to provide a product which can obtain a free luminous power according to a purpose of use, and to provide a means for expanding a field of use while solving inconvenience for many years.

[0006]

That is, the present invention provides a fluorescent light comprising a shrinkable inner bag having a fluorescent liquid, a container body capable of blocking ultraviolet rays and moisture, and a pressurizing agent present between the inner bag and the container body. Aerosol product containing a liquid, and / or a shrinkable inner bag having an oxidizing liquid, a container body capable of blocking ultraviolet rays and moisture, and an aerosol containing an oxidizing agent comprising a pressurizing agent present between the inner bag and the container body. An aerosol product containing a chemiluminescent liquid comprising a product (Claim 1), and an injection member for simultaneously opening the aerosol valves of the container body of the fluorescent liquid and the oxidizing liquid to eject, mix and emit the respective liquids. (Claim 2).

[0007]

DESCRIPTION OF THE PREFERRED EMBODIMENTS The present invention comprises a shrinkable inner bag having a fluorescent liquid, a container body capable of blocking ultraviolet rays and moisture, and a fluorescent liquid comprising a pressurizing agent present between the inner bag and the container body. Chemicals comprising an aerosol product and / or a shrinkable inner bag having an oxidizing solution, a container body capable of blocking ultraviolet light and moisture, and an aerosol product containing an oxidizing solution comprising a pressurizing agent present between the inner bag and the container body. It is an aerosol product containing a luminescent liquid.

By filling the container with a fluorescent solution and an oxidizing solution, the container can be stored without contact with ultraviolet rays and moisture while maintaining the performance of the product. Further, since a required amount can be taken out according to the operation of the injection button, a desired effect can be obtained.

The chemiluminescent liquid of the present invention comprises a fluorescent liquid such as a fluorescent substance and an oxidizing liquid such as hydrogen peroxide. It is said that this light emission is caused by the excitation of a reactant accompanying a chemical reaction, and the excited molecule or excited molecule colliding with another molecule or atom to excite it. For example, JP-A-55-137083 discloses JP-A-59-136781
JP, JP-A-59-160901, JP-A-59-160901
JP-A-169001, JP-A-59-184401, JP-A-59-186201, JP-A-2-15
Japanese Patent Application Laid-Open No. 2101 and Japanese Patent Application Laid-Open No. 4-53894 disclose the utilization techniques.

As the fluorescent liquid, for example, a solution in which a fluorescent substance, an oxalate, a dye or the like is dissolved in a solvent can be used. Phthalic acid compounds (C
PPO), and the dyes include phenylethynylanthracene and phenylethynyltetracene. Examples of the solvent include dibutyl phthalate. The concentration of the fluorescent substance, oxalate or dye in the fluorescent liquid is preferably 110 to 140 g / l.

As the oxidizing solution, a solution in which a catalyst is dissolved in a solvent can be used. Examples of the catalyst include hydrogen peroxide and sodium salicylate. Examples of the solvent include dimethyl phthalate and t-butanol. The concentration of the oxidizing substance in the oxidizing solution is 2 to 4 g /
It is preferably 1.

As the pressurizing agent, for example, nitrogen, carbon dioxide, nitrogen suboxide, compressed air, compressed gas such as argon, liquefied petroleum gas (LPG), dimethyl ether (DM
E), liquefied gases such as chlorofluorocarbons, and mixed gases thereof. Among them, the compressed gas is preferable because the temperature dependence of the pressure is small and the pressure is stable with respect to the inner bag.

The spraying form is not particularly limited to liquid, mist, foam, gel, etc., but liquid or mist is preferable from the viewpoint of easy mixing of the two liquids.

The structure of the chemiluminescent liquid-containing aerosol product of the present invention will be described below with reference to the drawings.

As shown in FIG. 1, an aerosol product containing a chemiluminescent liquid according to one embodiment of the present invention comprises a main body container 1 having a bottomed cylindrical shape, a shrinkable inner bag 2, and the inner bag 2. Aerosol valve 3 fitted on container body 1 to be stored
It is composed of The inner bag 2 is filled with a fluorescent liquid or an oxidizing liquid, and the space between the container 1 and the inner bag 2 is filled with a pressurizing agent.

The container body 1 is not particularly limited, and may be a metal plate made of aluminum, tinplate, or the like in the form of a cylinder with a bottom, and the like, and it is necessary that at least ultraviolet rays and moisture can be blocked. If ultraviolet light and moisture cannot be blocked, the fluorescent solution or oxidizing solution is deteriorated by ultraviolet light and moisture.

The shrinkable inner bag 2 is formed, for example, by blow molding using a synthetic resin having gas barrier properties. The inner bag may be made of linear low-density polyethylene (LLDPE), low-density polyethylene (LDPE), high-density polyethylene (HDPE), polypropylene (P
P), a single layer such as nylon (NY), or a laminate of two or more types. For example, LDPE / NY / LD
A three-layer laminated film of PE may be used. The inner bag 2 may be manufactured by blow molding from the single-layer or laminated sheet, or by folding the bag into a bag shape and bonding the periphery. In the latter case, it can be further produced from a laminated sheet including a metal sheet such as an aluminum foil. In the aerosol product of the present invention, since the inner bag 2 contains the above-mentioned chemical substance and solvent, it is most preferable that the inner bag 2 does not react with these components or does not adsorb or permeate.

The aerosol valve 3 comprises a mounting cup 18 and an injection valve 9 supported inside the center of the mounting cup 18. In this embodiment, the mounting cup 18 is Bead 1 formed at the upper end opening of shoulder 30
0 is fitted to the upper end of the inner bag 2 via a gasket 60.

The material of the gasket 60 is, for example, an elastomer material such as a synthetic rubber such as fluororubber or silicon rubber, or a soft synthetic resin in consideration of the stability to the luminescent liquid.

The injection valve 9 includes a housing 15 and
Stem 16 slidably disposed within housing 15
And the coil spring 1 for urging the stem 16 upward.
1 and a stem rubber 13 that normally seals the communication hole 12 of the stem 16. Considering the stability to the luminescent liquid, the housing and the stem are preferably made of polyacetal or nylon, the coil spring is preferably made of stainless steel, and the stem rubber is made of synthetic rubber such as fluorine rubber or silicon rubber, or a soft synthetic resin, like the gasket. Elastomeric materials such as are preferred.

Next, a method of manufacturing an aerosol product according to the present embodiment will be described.

The inner bag 2 is housed in the main container 1, and the inner bag 2 is filled with a fluorescent liquid or an oxidizing liquid. At this time, a flange formed on the outer periphery of the upper portion of the inner bag 2 is provided so as to protrude above the bead portion 10 in the container body 1.

Next, a gasket 60 is placed in the curled portion 14 of the mounting cup 18 in the aerosol valve 3.
The aerosol valve 3 is held on the container main body 1 so that the flange fits through the.

Next, the pressurizing agent is injected between the inner bag 2 and the container body 1 between the opening of the container body 1 and the inner bag 2, that is, between the bead portion 10 and the flange. Perform

When a predetermined amount of pressurizing agent is injected, the aerosol valve 3 is fitted on the container body 1 and the curl portion 14 is crimped to the bead portion 10. Thereafter, by attaching the spraying member to the upper end of the stem, the aerosol product shown in FIG. 1 is obtained.

In this embodiment, since the fluorescent liquid and the oxidizing liquid are independent aerosol products, when used, each aerosol product is jetted to the jetting surface.

FIG. 2 is a diagram showing the use state of another embodiment of the chemiluminescent liquid-containing aerosol product of the present invention, and FIG. 3 is a sectional view of a main part of the chemiluminescent liquid-containing aerosol product shown in FIG.

As the container used for the aerosol product of the present invention, for example, a double pressurized container described in WO 99/16684 can be used. The aerosol product of the present invention has a relatively small diameter, preferably 1 diameter.
A container body 1 having a diameter of 5 to 35 mm and an aerosol valve for an aerosol product containing a fluorescent liquid and an oxidizing liquid are simultaneously opened, and an ejecting member 4 having a function of simultaneously ejecting and mixing each liquid is provided.

In order to perform chemiluminescence, it is necessary for the luminescent liquid and the oxidizing liquid to undergo a chemical reaction. However, if the injection amount balance between the two liquids is lost, chemiluminescence cannot be sufficiently achieved. The mixing ratio (weight ratio) of the fluorescent liquid and the oxidizing liquid is preferably 1: 1 to 3: 1.

In order to solve this problem, the injection amount is adjusted to a predetermined value according to the hole diameter of the aerosol valve or the injection member, the product pressure, etc. However, since the two aerosol valves are simultaneously pressed down by one operating member, the injection is performed by pressing down. The amount balance may be greatly disrupted. In particular, in the case of a double container product using a compressed gas as a pressurizing agent, the product pressure decreases with the injection, so that the internal pressure changes according to the remaining amount of the contents. Therefore, it is preferable that the ejection member 4 has a means for balancing the discharge amount of the fluorescent liquid and the discharge amount of the oxidizing liquid. There is no particular limitation on such a balancing means.
As described in Japanese Patent Application Publication No. 0-218263, a passage or an ejection port leading from the outlet of the aerosol valve to the ejection port is always closed, and the ejection port is not closed until the operation amount of the operating means reaches a predetermined level. An opening / closing mechanism, an opening / closing valve that is always closed when the pressure in the passage reaches a predetermined level, and a pilot type provided in the middle of a passage communicating with each aerosol valve. A valve and a pilot circuit for opening a pilot type valve on the other side when the pressure at the outlet of one of the aerosol valves reaches a predetermined pressure.

FIG. 4 is a sectional view showing a structure for mounting the container opening and the aerosol valve. The container opening 31
Is provided with an annular projection 32 protruding inward.

The inner bag 2 is, as shown in FIG.
A neck 33 inscribed in the opening 31 is provided with a somewhat smaller diameter portion 33a below the neck 33, and further below the somewhat larger body 8 below. The neck 33 and the small-diameter portion 33a are connected to the annular projection 32 of the container body.
Are connected by an inclined surface 33b that engages with the upper surface of.
The lower end portion 34 of the inner bag 2 is sharpened in a conical shape in a natural state as shown in FIG. 5, and is supported by being pressed against the inner bottom surface of the container body 1 in an assembled state. Also in this case, the inside of the inner bag 2 is filled with the fluorescent liquid or the oxidizing liquid G, and the space between the container body 1 and the inner bag 2 is filled with the pressurizing agent PR. Note that a part of the inner bag 2 near the trunk and the opening may be formed in a bellows shape. In that case, it can be easily compressed by pressing downward, and can be recovered.

In this embodiment, as shown in FIG. 4, the mounting cup 18 of the aerosol valve 3 has the plug 3 fitted into the opening 31 of the container body 1 via the inner bag 2.
5 and a cover 36 for attaching the plug to the container body 1. The plug 35 has a cylindrical peripheral portion 37 for attachment to the container body 1 and a housing 15.
And a bottomed cylindrical housing holding section 38 for holding the housing. Both continue in the lower part 39,
An annular groove 40 that opens upward is formed between them. The plug 35 is usually formed of a synthetic resin such as polyethylene, polypropylene, nylon, or polyacetal, but polyacetal is preferable in view of the properties of the luminescent liquid.

From the upper end of the peripheral portion 37, radially outward,
A flange portion 41 is provided which is engaged with the upper end of the opening portion 31 of the container body 1 via a gasket 60, and a lower portion of the flange portion 41 is a rising wall 42 closely fitted to the neck portion 33 of the inner bag 2. The outer diameter of the rising wall 42 is slightly larger than the inner diameter of the neck portion 33 of the inner bag 2 in a natural state, so that a sufficient sealing property is ensured by fitting the two. Further, a step portion 44 is provided below the rising wall 42 so as to be engaged with the annular projection 32 of the container body 1 via the inclined surface 33b of the inner bag 2. Note that an annular gasket may be provided in this portion.

In the aerosol product shown in FIG. 4, a ring-shaped gasket 60 is interposed between the upper end of the opening 31 of the container body 1 and the flange 41 of the plug 35 of the mounting cup 3. The gasket 60 is sandwiched between the flange of the plug 35 and the opening of the container body 1 to provide a sealing action.

In this embodiment, the stopper 35 and the container body 1
Since the gasket 60 is interposed between them, the interior of the container body 1 is tightly sealed from the outside after assembly. Note that the inclined surface 33b of the inner bag 2 is
Is strongly sandwiched between the corner of the side wall step portion 44 and the upper surface of the annular projection 32 of the container body 1. Therefore, the inside of the inner bag 2 maintains a high sealing action for a long period of time. Therefore, there is little possibility that the pressurizing agent may enter the inside of the inner bag 2.

On the inner surface of the housing holding portion 38, an engaging projection 4 for engaging with the engaging step 15a on the upper part of the housing 15 is provided.
6 are provided. The aerosol valve 3 includes a bottomed cylindrical housing 15, a stem 16 housed in the housing so as to be movable up and down, a spring 17 that constantly urges the stem upward, and extends around the upper end of the housing 15. It is a known device comprising a mounting cup 18.

The cover 36 is a cup-shaped molded product made of a thin metal plate, and its upper bottom surface is put on the upper surfaces of the housing holding portion 38 and the peripheral edge portion 37. Further, a fitting portion 36a which is in contact with the inner surface of the annular groove portion 40 is provided on the upper bottom surface. The peripheral portion 36b of the cover 36 is fitted on the outer surface of the opening 31 of the container body 1, and its lower end is crimped to a groove formed on the outer surface side of the annular projection 32 of the container body 1.

Next, a procedure for filling the luminous liquid and the oxidizing liquid as contents will be described with reference to FIG. First, in the stock solution filling step (a) at the left end of FIG. 5, the inner bag 2 is put into the container body 1. In this state, the lower end 34 of the inner bag 2 is
It is in contact with the inner bottom surface. In this state, the stock solution filling nozzle 5
Fill from 0 with stock solution.

Next, the aerosol valve 3 is mounted on the upper end of the inner bag 2 (FIG. 5B). At this time, as described above, the inner surface of the neck portion 33 of the inner bag 2 fits tightly with the rising wall 42 of the plug 35, and exhibits a sealing action. Then, a propellant filling head 51 is provided around the aerosol valve 3 and the container body 1.
And pressurizing agent is filled through a gap between the mounting cup 18 and the container body 1 (FIG. 5C). At this time, as shown by the arrow Q in FIG. 6, the pressurizing agent enters the space S between the inner bag 2 and the container body 1 through the space between the opening 31 of the container body and the small diameter portion 33a of the inner bag. As the pressurizing agent, the above-mentioned compressed gas or liquefied gas can be employed.

Although the pressurizing agent is filled at a high pressure, the neck portion 33 of the inner bag 2 is tightly fitted to the rising wall 42 of the plug 35, and is further intimately contacted by the filling pressure of the high-pressure pressurizing agent. Therefore, the pressurizing agent does not enter the inner bag 2 from the gap between the two.

After filling a predetermined amount of the pressurizing agent, the aerosol valve 3 is fitted to the upper end of the container body 1 and the periphery thereof is crimped (FIG. 5 (d)). At that time, the bottom 3 of the inner bag 2
4 is slightly deformed by being pressed against the inner bottom surface of the container body 1. Thus, the aerosol valve 3 is connected to the container body 1.
Then, the aerosol product shown in FIG. 3 is obtained by attaching the spray member 4 to the aerosol product.

FIG. 7 shows still another embodiment of the chemiluminescent liquid-containing aerosol product of the present invention. The aerosol product has a cap 65 including a container body 1, a connecting portion 63 for holding and holding each container body in parallel, and a standing portion 64 standing upright in a U shape from the periphery of the connecting portion 63, and one end of the cap 65. Supported on the inner surface of each stem 6 of the container body.
6 has an action portion 68 that pushes down and has an opening portion 69 and a pull lever portion 70 on the other end side.
1 and an injection member 73 fitted to each stem 66 of the container body and having an injection nozzle 72 protruding in a horizontal direction from an opening 69 of the operation section 71 (Japanese Patent Application Laid-Open No. HEI 1-1990).
1-11-1554).

The connecting portion 63 surrounds the stem 66 of the mounting cup in each main body container 1 and
It is fitted to.

The operating portion 71 is supported by inserting a notch 75 formed at one end into a hook 77 formed at a rear end inner wall surface 76 of the upright portion 64 of the cap 65, and using the one end as a fulcrum. When the pull lever 70 is pulled with a finger, the action portion 68 pushes down the ejection member 73, so that it is a lever-type lever. That is, the one end is the fulcrum A, the action part 68 is the action point B, and the lever part 70 is the force point C. The material of the operation unit 71 is made of, for example, polyethylene (PE) or polypropylene (PP) in order to partially provide flexibility, and the operation unit 71 is bent by pulling the lever unit 70.

The action portion 68 is formed at a central portion of the stem 66 of the main body container 1 at a substantially equal distance from the stem 66. When the pull lever portion 70 is pulled, the action portion 68 is positioned at an equal distance from the stem 66. It is set so that the ejection member 73 can be pressed down.

The injection member 73 includes a stem fitting main body 78.
The stem fitting body 78 has fitting portions 79 and 80 fitted to the stem 66 and a spray passage 81.

The injection passage 8 located upstream from the injection nozzle 72, that is, above the stem 66 of the container body 1.
1, a mixing chamber 87 is preferably formed. By forming the mixing chamber 87, the liquid ejected from the container body 1 can be surely mixed. Also, by appropriately changing the volume of the mixing chamber 87, the mixing ratio can be changed as appropriate in accordance with the type of liquid in each container body 1.

A guide section 8 for guiding the vertical movement of the injection member 73 is provided between the injection member 73 and the connecting portion 63.
It is preferable to provide 2. The guide portion 82 includes, for example, a guide groove (recess) 84 formed in the upper wall surface 83 of the connecting portion 63 and the stem fitting main body 7 in the ejection member 73.
A projection (protrusion) 86 formed on the inner wall surface 85 of 8 can be used. Or, conversely, a projection may be formed on the upper wall surface of the connecting portion, and a guide groove may be formed on the inner wall surface of the injection member. Alternatively, a concave portion for guiding the stem fitting main body from the outer peripheral side may be formed on the upper wall surface of the connecting portion. By providing such a guide portion 82, the ejection member 73 is operated by the operation portion 71.
Can be operated more reliably in the vertical direction.

The injection nozzle 72 employs a mechanical break-up mechanism capable of injecting the contents as shown in FIG.
No. 127991). In this mechanism, a center post chip 91 is inserted inside the injection nozzle, a chip 92 having an ejection hole 93 having a smaller diameter than the inside of the injection nozzle is provided at the outlet 90c of the injection nozzle, and on the inner wall surface of the injection nozzle, It is constituted by forming a plurality of vertical grooves 95 for communicating between the mixing chamber and the ejection holes 93.

Looking at the flow of the contents inside the injection nozzle, the contents introduced from the mixing chamber are distributed to the vertical grooves 95, while bypassing the center post chips 91.
Through to the chip 92. The content that has reached the tip 92 turns between the inner surface of the tip and the tip of the center post tip, and is ejected from the ejection holes 93 to the outside as fine particles.

An inner bag of one container body of such an aerosol product is filled with a first agent containing a fluorescent solution such as an oxalate ester, and an inner bag of the other container body is filled with hydrogen peroxide. And a second agent containing an oxidizing liquid such as sodium salicylate. When the pull lever is pulled, the first agent and the second agent are simultaneously ejected from the container main body, and can be suitably used for a two-component type chemiluminescent liquid.

The pressure of the product is preferably 0.3 to 1.0 MPa (35 ° C.) when a compressed gas is used as the pressurizing agent, and 0.8 MPa (35 ° C.) or less when a liquefied gas is used.

Since the chemiluminescent liquid-containing aerosol product of the present invention can store the chemiluminescent liquid with high quality and can partially use the chemiluminescent liquid,
Emergency light, sign light, accident prevention light at night, night training / action patrol instructions and landmarks, teaching materials for chemistry, light-emitting display using transparent tubes and containers, light-emitting float for measuring river flow velocity, helicopter It can be used for displaying a temporary landing place of the aircraft. In particular, emergency light, sign light and accident prevention light at night
Display of danger points such as bridges and roads, indication of prevention of secondary disasters and accidents, recognition and securing of evidence during investigation, repulsion of robbery and molestation, and securing of evidence.

[0055]

Next, using the aerosol container of the present invention,
EXAMPLES The ability to store a chemiluminescent liquid with high quality will be specifically described based on examples, but the present invention is not limited thereto.

Example 1 A solution in which 140 g / l of CPPO (phthalic acid compound) and 17 g / l of BPEA (dye) were added to dibutyl phthalate as a fluorescent liquid, and 3 g / l of hydrogen peroxide in dimethyl phthalate as an oxidizing liquid Using a solution containing 0.15 g / l of SS (salicylic acid) and nitrogen gas as a pressurizing agent, an aerosol product was prepared by the method described above. The inner bag is LDPE
/ NY / LDPE, product pressure is 0.8
MPa (25 ° C.).

Comparative Example 1 Using the fluorescent liquid, oxidizing liquid and pressurizing agent used in Example 1,
An aerosol product was made without using an inner bag.

The aerosol products prepared in Example 1 and Comparative Example 1 were stored in a 40 ° C. high-humidity accelerator for 30 consecutive days, and the storage stability was evaluated. As a result, the sample of Example 1 had the same light emission ability as the sample that was not placed in the 40 ° C. high humidity accelerator, and the superiority of the preservability was proved. Conversely, the sample of Comparative Example 1 deteriorated and did not emit light.

[0059]

According to the aerosol product of the present invention, the fluorescent liquid and the oxidizing liquid are not only stored and stored in a high quality state except for factors that degrade the performance by separating the oxidizing liquid and the oxidizing liquid, but also shock during transportation and storage. In addition to resolving the defects caused by the light emission, it is also possible to obtain a free luminous power depending on the purpose of use.

[Brief description of the drawings]

FIG. 1 is an overall view of an aerosol product containing a chemiluminescent liquid of the present invention.

FIG. 2 is a view showing a use state of another embodiment of the aerosol product containing a chemiluminescent liquid of the present invention.

FIG. 3 is a sectional view of a main part of another aerosol product containing a chemiluminescent liquid of the present invention.

FIG. 4 is an enlarged sectional view of a mounting structure of an aerosol valve and a container opening of the chemiluminescent liquid-containing aerosol product of the present invention.

FIG. 5 is a process diagram showing an assembling process of a container body of the aerosol product containing a chemiluminescent liquid of the present invention.

FIG. 6 is an enlarged sectional view of a main part of the container body of the present invention when filling the under cup.

FIG. 7 is a partially cutaway front view of still another embodiment of the chemiluminescent liquid-containing aerosol product of the present invention.

FIG. 8 is an enlarged sectional view of the vicinity of a discharge hole in FIG. 7;

[Explanation of symbols]

 DESCRIPTION OF SYMBOLS 1 Container main body 2 Inner bag 3 Aerosol valve 4 Injection member 8 Body 9 Injection valve 10 Bead part 11 Coil spring 12 Communication hole 13 Stem rubber 14 Curl part 15 Housing 15a Engaging step 16 Stem 17 Spring 18 Mounting cup 30 Shoulder DESCRIPTION OF SYMBOLS 31 Opening part 32 Annular projection 33 Neck part 33a Small diameter part 33b Inclined surface 34 Lower end part 35 Plug body 36 Cover 36a Fitting part 36b Peripheral part 37 Peripheral part 38 Housing holding part 39 Lower part 40 Annular groove part 41 Flange part 42 Rising wall 44 Step part 46 Engagement projection 50 Stock solution filling nozzle 51 Propellant filling head 60 Gasket 63 Connecting portion 64 Standing portion 65 Cap 66 Stem 68 Working portion 69 Opening 70 Pulling lever portion 71 Operating portion 72 Injection nozzle 73 Injection member 75 Notch 76 Rear Inner wall surface 77 Hook 78 Stem fitting main body 79, 80 Fitting portion 81 Injection passage 82 Guide portion 83 Upper wall surface 84 Guide groove (recess) 85 Inner wall surface 86 Projection (convex portion) 87 Mixing chamber 91 Center post tip 92 Tip 93 Spout Hole 95 Vertical groove B Action point G Stock solution Q Arrow PR Pressurizing agent S Space

 ──────────────────────────────────────────────────続 き Continued on the front page F term (reference) 3E084 AA02 AA12 AA22 AA23 AA24 AA25 AA26 AB01 BA02 CA01 CB02 CC01 CC03 CC04 CC05 CC08 DA01 DC01 DC03 DC04 DC05 DC08 EA03 EC01 EC03 EC04 EC05 EC09 FA09 FD08 HA03 HB04 HC03 HD01 KB03 KB01 4F033 RA07

Claims (2)

[Claims] 1. A shrinkable inner bag having a fluorescent liquid, a container body capable of blocking ultraviolet light and moisture, an aerosol product containing a fluorescent liquid comprising a pressurizing agent present between the inner bag and the container body, and / or Shrinkable inner bag with oxidizing liquid,
An aerosol product containing a chemiluminescent liquid comprising an aerosol product containing an oxidizing solution comprising a pressurizing agent present between a container body and an inner bag and a container body capable of blocking ultraviolet rays and moisture. 2. The aerosol product containing a chemiluminescent liquid according to claim 1, further comprising an injection member for simultaneously opening the aerosol valves of the container body of the fluorescent liquid and the oxidizing liquid to eject, mix and emit the respective liquids.