KR101137260B1 - Method for absorbing panel comprising artificial lightweight aggregate with ash - Google Patents

Method for absorbing panel comprising artificial lightweight aggregate with ash Download PDF

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KR101137260B1
KR101137260B1 KR20110088292A KR20110088292A KR101137260B1 KR 101137260 B1 KR101137260 B1 KR 101137260B1 KR 20110088292 A KR20110088292 A KR 20110088292A KR 20110088292 A KR20110088292 A KR 20110088292A KR 101137260 B1 KR101137260 B1 KR 101137260B1
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South Korea
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weight
sound absorbing
absorbing panel
mixing
ash
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KR20110088292A
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Korean (ko)
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심구식
김순재
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한국전력공사
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Priority to KR20110088292A priority Critical patent/KR101137260B1/en
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Priority to DE112012003658.1T priority patent/DE112012003658B4/en
Priority to CN201280042514.2A priority patent/CN103857641B/en
Priority to PCT/KR2012/007012 priority patent/WO2013032288A1/en

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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B28WORKING CEMENT, CLAY, OR STONE
    • B28BSHAPING CLAY OR OTHER CERAMIC COMPOSITIONS; SHAPING SLAG; SHAPING MIXTURES CONTAINING CEMENTITIOUS MATERIAL, e.g. PLASTER
    • B28B23/00Arrangements specially adapted for the production of shaped articles with elements wholly or partly embedded in the moulding material; Production of reinforced objects
    • B28B23/0081Embedding aggregates to obtain particular properties
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    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
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    • C04B18/00Use of agglomerated or waste materials or refuse as fillers for mortars, concrete or artificial stone; Treatment of agglomerated or waste materials or refuse, specially adapted to enhance their filling properties in mortars, concrete or artificial stone
    • C04B18/04Waste materials; Refuse
    • C04B18/06Combustion residues, e.g. purification products of smoke, fumes or exhaust gases
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B28WORKING CEMENT, CLAY, OR STONE
    • B28BSHAPING CLAY OR OTHER CERAMIC COMPOSITIONS; SHAPING SLAG; SHAPING MIXTURES CONTAINING CEMENTITIOUS MATERIAL, e.g. PLASTER
    • B28B1/00Producing shaped prefabricated articles from the material
    • B28B1/14Producing shaped prefabricated articles from the material by simple casting, the material being neither forcibly fed nor positively compacted
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B28WORKING CEMENT, CLAY, OR STONE
    • B28BSHAPING CLAY OR OTHER CERAMIC COMPOSITIONS; SHAPING SLAG; SHAPING MIXTURES CONTAINING CEMENTITIOUS MATERIAL, e.g. PLASTER
    • B28B7/00Moulds; Cores; Mandrels
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    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
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    • C04B14/00Use of inorganic materials as fillers, e.g. pigments, for mortars, concrete or artificial stone; Treatment of inorganic materials specially adapted to enhance their filling properties in mortars, concrete or artificial stone
    • C04B14/02Granular materials, e.g. microballoons
    • C04B14/04Silica-rich materials; Silicates
    • C04B14/10Clay
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    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
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    • C04B18/00Use of agglomerated or waste materials or refuse as fillers for mortars, concrete or artificial stone; Treatment of agglomerated or waste materials or refuse, specially adapted to enhance their filling properties in mortars, concrete or artificial stone
    • C04B18/02Agglomerated materials, e.g. artificial aggregates
    • C04B18/021Agglomerated materials, e.g. artificial aggregates agglomerated by a mineral binder, e.g. cement
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    • C04B28/00Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
    • C04B28/02Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing hydraulic cements other than calcium sulfates
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    • C04B33/00Clay-wares
    • C04B33/02Preparing or treating the raw materials individually or as batches
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    • C04B33/13Compounding ingredients
    • C04B33/132Waste materials; Refuse; Residues
    • C04B33/135Combustion residues, e.g. fly ash, incineration waste
    • EFIXED CONSTRUCTIONS
    • E04BUILDING
    • E04BGENERAL BUILDING CONSTRUCTIONS; WALLS, e.g. PARTITIONS; ROOFS; FLOORS; CEILINGS; INSULATION OR OTHER PROTECTION OF BUILDINGS
    • E04B1/00Constructions in general; Structures which are not restricted either to walls, e.g. partitions, or floors or ceilings or roofs
    • E04B1/62Insulation or other protection; Elements or use of specified material therefor
    • E04B1/74Heat, sound or noise insulation, absorption, or reflection; Other building methods affording favourable thermal or acoustical conditions, e.g. accumulating of heat within walls
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    • C04B2103/00Function or property of ingredients for mortars, concrete or artificial stone
    • C04B2103/52Grinding aids; Additives added during grinding
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    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
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Abstract

PURPOSE: A manufacturing method of a sound absorbing panel including artificial light-weight aggregate which is manufactured by using coal ash for power generation is provided to enhance sound-absorbing power of the sound absorbing panel by mixing optimal ratio of dredged soil, bottom ash, and rejected ash. CONSTITUTION: A manufacturing method of a sound absorbing panel comprises next steps: a first step of mixing 15-48 weight% of dredged soil, 2.5-32.5 weight% of bottom ash, and 52.5-67.5 weight% of rejected ash based on total weight in order to manufacture an artificial light-weight aggregate; a second step of mixing cement, admixture, fluidifier, and water with the artificial light-weight aggregate; and a third step of manufacturing the the sound absorption panel by curing the mixture in the mold frame. In the second step, 25-27 parts by weight of cement, 3-4 parts by weight of admixture, 1-2 parts by weight of fluidifier, and 7-8 parts by weight of water are mixed based on 100.0 parts by weight of the artificial light-weight aggregate. The sound absorption panel(100) comprises acoustical panels(110) which are manufactured with the artificial light-weight aggregate and non-asbestos extrusion molding cemented boards(120) which is combined in the lower part of the sound absorption panel.

Description

발전용 석탄회를 이용하여 제조된 인공경량골재를 포함하는 흡음판넬 제조방법 {METHOD FOR ABSORBING PANEL COMPRISING ARTIFICIAL LIGHTWEIGHT AGGREGATE WITH ASH}Sound absorbing panel manufacturing method including artificial light aggregate manufactured using coal ash for power generation {METHOD FOR ABSORBING PANEL COMPRISING ARTIFICIAL LIGHTWEIGHT AGGREGATE WITH ASH}

본 발명은 흡음판넬 제조방법에 관한 것으로, 보다 상세하게는 발전용 석탄회를 이용하여 제조된 인공경량골재를 포함하는 흡음판넬 제조방법에 관한 것이다.The present invention relates to a sound absorbing panel manufacturing method, and more particularly to a sound absorbing panel manufacturing method comprising an artificial light weight aggregate manufactured using coal ash for power generation.

일반적으로, 발전용 석탄회(ash)란 화력발전소 등에서 소각 또는 연소 후에 남아 있는 잔재물로 정의된다. 발전용 석탄회는 연소물의 잔재물이라는 점에서 재활용이 가능한 재료이지만, 연소공정을 거치기 때문에 항상 미연탄분(unburnt carbon)이 부수적으로 함유되어 있어 기술적으로 응용하는데 어려움이 있었다. In general, ash for power generation is defined as residues remaining after incineration or combustion in a thermal power plant. Coal ash for power generation is a recyclable material in that it is a residue of a combustion product. However, since it is a combustion process, it is difficult to apply it technically since it contains incidental unburnt carbon.

발전용 석탄회는 발생장소에 따라 플라이애쉬(fly ash), 저회(bottom ash)등으로 구분되며, 발전용 석탄회의 80% 가량이 플라이애쉬이고, 나머지가 저회이다. Coal ash for power generation is classified into fly ash and bottom ash according to the generation place. About 80% of the coal ash for power generation is fly ash, and the rest is low ash.

이 중, 상대적으로 품질이 좋은 플라이애쉬의 경우에는 콘크리트 혼화재, 성토재, 토지 개량재, 경량골재 등 다양한 분야에서 재활용되어 사용되고 있어 전체 재활용율의 약 90%를 차지하고 있다. Among them, fly ash, which is relatively high in quality, is recycled and used in various fields such as concrete admixtures, landfills, land improvement materials, and lightweight aggregates, accounting for about 90% of the total recycling rate.

그러나, 중금속을 함유한 저회 및 저품질의 잔사회(rejected ash)의 경우 거의 대부분이 발전소 주변 회사장에 단순 폐기 매립되고 있는 실정이어서, 회처리 용지를 확보하는데 어려움이 따르는 것은 물론이고 환경 오염 문제까지 야기하고 있어, 이와 같은 저회 및 잔사회 등의 활용할 수 있는 방법이 요구되고 있다. However, in most cases of low ash and low quality rejected ash containing heavy metals, they are simply landfilled at the company site near the power plant, which makes it difficult to secure ashed paper and environmental pollution. There is a demand for a method that can utilize such low-end meetings and remnants.

이와 관련하여, 한국등록특허 제10-0676379호(특허문헌 1)에서는 저회의 경량골재를 이용한 흡음형 방음패널의 제조방법을 개시하고 있다. In this regard, Korean Patent No. 10-0676379 (Patent Document 1) discloses a method for manufacturing a sound absorbing soundproof panel using low-weight lightweight aggregate.

그러나, 상기 특허문헌 1에서는 경량골재 제조시 잔사회를 포함하고 있지 않아 잔사회(rejected ash)의 활용방법에 대해서는 개시하고 있지 못하는 문제점이 있을 뿐더러, 특히 입도가 1.25 내지 5mm의 저회만을 사용하므로 상술한 입도 범위에 해당하지 않는 저회의 활용방법에 대해서는 개시하고 있지 못하는 문제점이 있었다.However, in Patent Document 1, there is a problem that does not include the method of utilizing the residual ash because it does not include the residual material in the manufacture of lightweight aggregate, and in particular, since only the low particle size of 1.25 to 5 mm is used, There was a problem in that the method of using the low level that does not fall within the granularity range was not disclosed.

특허문헌 1: 한국등록특허 제10-0676379호 (2008.01.23 등록)Patent Document 1: Korea Patent Registration No. 10-0676379 (registered on Jan. 23, 2008)

본 발명의 실시예들은 저회 및 잔사회를 활용하여 제조된 인공경량골재를 이용한 흠음판넬 제조방법을 제공하고자 한다. Embodiments of the present invention are to provide a method for manufacturing a flaw panel using artificial lightweight aggregate prepared by using low ash and after-hours.

또한, 준설토, 저회 및 잔사회를 적정 비율로 혼합함으로써, 흡음력이 향상된 흡음판넬을 제공하고자 한다.In addition, by mixing the dredged soil, low ash and residue in an appropriate ratio, to provide a sound absorbing panel with improved sound absorption.

본 발명의 일 측면에 따르면, 전체 중량에 대하여 준설토 15 내지 48중량%, 저회(bottom ash) 2.5 내지 32.5중량% 및 잔사회(rejected ash) 52.5 내지 67.5중량%를 혼합하여 인공경량골재를 제조하는 제1 단계; 및 상기 인공경량골재에 시멘트, 혼화제, 유동화제 및 물을 혼합하여 형틀에 주입하여 양생한 후, 상기 형틀에서 분리하여 흡음판넬을 제조하는 제2 단계를 포함하는 흡음판넬 제조방법이 제공될 수 있다. According to an aspect of the present invention, to prepare artificial lightweight aggregate by mixing 15 to 48% by weight of dredged soil, 2.5 to 32.5% by weight bottom ash and 52.5 to 67.5% by weight rejected ash relative to the total weight First step; And mixing the cement, admixture, fluidizing agent, and water into the artificial lightweight aggregate, injecting and curing the mold, and separating the mold from the mold to produce a sound absorbing panel. .

이 때, 상기 제1 단계는, 상기 준설토, 저회 및 잔사회를 혼합하여 혼합물을 제조하는 1-1 단계; 상기 혼합물을 압출성형한 후, 파쇄하여 골재입자들을 제조하는 1-2 단계; 상기 골재입자들을 건조시키는 1-3 단계; 및 상기 건조체를 1050 내지 1200℃에서 소성하여 인공경량골재를 제조하는 1-4 단계를 포함할 수 있다. At this time, the first step, step 1-1 to prepare a mixture by mixing the dredged soil, low ash and residue; Extruding the mixture and then crushing to prepare aggregate particles; 1-3 steps for drying the aggregate particles; And by firing the dried body at 1050 to 1200 ℃ may include steps 1-4 to produce artificial lightweight aggregate.

또한, 상기 제1 단계는, 상기 준설토 30 중량%, 상기 저회 17.5 중량% 및 상기 잔사회 52.5중량%를 혼합하여 인공경량골재를 제조하는 단계일 수 있다. In addition, the first step may be a step of manufacturing artificial lightweight aggregate by mixing 30% by weight of the dredged soil, 17.5% by weight of low ash and 52.5% by weight of the residue.

한편, 상기 제2 단계는, 시멘트, 물 및 실리카흄을 혼합하여 제1 혼합물을 제조하는 2-1 단계; 상기 제1 혼합물에 상기 인공경량골재를 혼합하여 제2 혼합물을 제조하는 2-2 단계; 상기 제2 혼합물에 혼화재 및/또는 유동화제를 혼합하여 제3 혼합물을 제조하는 2-3 단계; 및 상기 제3 혼합물을 주름부가 형성된 형틀에 주입하는 2-4 단계를 포함할 수 있다. On the other hand, the second step, 2-1 to prepare a first mixture by mixing cement, water and silica fume; Step 2-2 of preparing the second mixture by mixing the artificial light weight aggregate with the first mixture; 2-3 to prepare a third mixture by mixing admixtures and / or fluidizing agents with the second mixture; And injecting the third mixture into the mold in which the pleats are formed.

또한, 상기 제2 단계는, 상기 인공경량골재 100 중량부에 대하여, 시멘트 25 내지 27 중량부, 혼화제 3 내지 4 중량부, 유동화제 1 내지 2 중량부 및 물 7 내지 8 중량부를 혼합하는 단계일 수 있다. In addition, the second step is a step of mixing 25 to 27 parts by weight of cement, 3 to 4 parts by weight of admixture, 1 to 2 parts by weight of fluidizing agent and 7 to 8 parts by weight of water, based on 100 parts by weight of the artificial lightweight aggregate Can be.

본 발명의 다른 측면에 따르면, 상술한 흡음판넬 제조방법에 따라 제조되는 흡음판넬이 제공될 수 있다. According to another aspect of the present invention, there may be provided a sound absorbing panel manufactured according to the sound absorbing panel manufacturing method described above.

또한, 상기 흡음판넬의 하부에 결합되는 무석면 압출성형 시멘트판을 더 포함할 수 있다. In addition, it may further include a non-asbestos extruded cement plate coupled to the lower portion of the sound absorbing panel.

또한, 상기 무석면 압출성형 시멘트판이 결합된 흡음판넬 복수 개가 적층되어 수용되는 프레임을 더 포함할 수 있다. The apparatus may further include a frame in which a plurality of sound absorbing panels to which the non-asbestos extruded cement plate is coupled are stacked and accommodated.

본 발명의 실시예들은 종래 단순 폐기 매립되던 저회 및 잔사회를 모두 활용하여 인공경량골재 및 흡음판넬을 제조함으로써, 발전용 석탄회의 재활용성을 극대화 할 수 있다. Embodiments of the present invention can maximize the recycling of coal ash for power generation by producing artificial lightweight aggregate and sound absorbing panel utilizing both low ash and remnants conventionally simply landfilled.

또한, 준설토, 저회, 잔사회를 적정 비율로 혼합하여 인공경량골재를 제조함으로써, 경량골재 흡음판넬의 흡음력을 향상시킬 수 있다.In addition, by mixing the dredged soil, low ash, and residue in an appropriate ratio to produce an artificial lightweight aggregate, the sound absorbing power of the lightweight aggregate sound absorbing panel can be improved.

도 1은 본 발명의 일 실시예에 따른 흡음판넬 제조방법의 순서도이다.
도 2는 도 1의 흡음판넬 제조방법에서 인공경량골재 제조를 세분화한 순서도이다.
도 3은 도 1의 흡음판넬 제조방법에서 흡음판넬 제조를 세분화한 순서도이다.
도 4는 도 1의 방법에 의해 제조된 흡음판넬의 사시도이다.
도 5는 도 4의 흡음판넬의 활용도이다.
1 is a flow chart of a sound absorbing panel manufacturing method according to an embodiment of the present invention.
Figure 2 is a flow chart that subdivided the artificial lightweight aggregate production in the sound absorbing panel manufacturing method of FIG.
FIG. 3 is a flowchart illustrating subdivided sound absorbing panel manufacturing in the sound absorbing panel manufacturing method of FIG. 1.
4 is a perspective view of a sound absorbing panel manufactured by the method of FIG. 1.
5 is a utilization of the sound absorbing panel of FIG.

이하, 첨부된 도면을 참조하여 본 발명의 실시예들에 대하여 상세히 설명하도록 한다. Hereinafter, exemplary embodiments of the present invention will be described in detail with reference to the accompanying drawings.

도 1은 본 발명의 일 실시예에 따른 흡음판넬 제조방법의 순서도이다. 도 1을 참조하면, 본 발명의 일 실시예에 따른 흡음판넬 제조방법은 전체 중량에 대하여 준설토 15 내지 48중량%, 저회(bottom ash) 2.5 내지 32.5 중량% 및 잔사회(rejected ash) 52.5 내지 67.5 중량%를 혼합하여 인공경량골재를 제조하는 제1단계(S110); 및 상기 인공경량골재에 시멘트, 혼화제, 유동화제 및 물을 혼합하여 형틀에 주입하여 양생한 후, 상기 형틀에서 분리하여 흡음판넬을 제조하는 제2 단계(S120)를 포함한다. 1 is a flow chart of a sound absorbing panel manufacturing method according to an embodiment of the present invention. Referring to Figure 1, the sound absorbing panel manufacturing method according to an embodiment of the present invention 15 to 48% by weight of dredged soil, 2.5 to 32.5% by weight bottom ash (rejected ash) 52.5 to 67.5 with respect to the total weight A first step (S110) of manufacturing artificial lightweight aggregate by mixing the weight%; And a second step (S120) of mixing the cement, admixture, fluidizing agent, and water with the artificial light weight aggregate, injecting the mold into curing, and separating the mold from the mold to produce a sound absorbing panel.

이하, 상기 흡음판넬 제조방법의 각 단계에 대해서 설명하도록 한다. Hereinafter, each step of the sound absorbing panel manufacturing method will be described.

도 2는 도 2는 도 1의 흡음판넬 제조방법에서 인공경량골재 제조(S110)를 세분화한 순서도이다.FIG. 2 is a flow chart of subdividing artificial lightweight aggregate manufacturing (S110) in the sound absorbing panel manufacturing method of FIG. 1.

도 2를 참조하면, 우선 준설토, 저회 및 잔사회를 혼합하여 혼합물을 제조한다. 상기 준설토는 하천이나 호수, 바다의 바닥에 퇴적된 뻘, 흙, 모래 등을 펌프로 뽑아낸 것으로 15 내지 48 중량%를 포함할 수 있다. 상기 저회는 연소로 내에서 소결에 의해 입자가 형성된 상태에서 보일러 하부로 낙하하여 고형화된 물질로 2.5 내지 32.5 중량%를 포함할 수 있다. 또한, 상기 저회는 별도의 가공을 통해 둥근 형태로 만든 다음 혼합하는 것도 가능하다. 한편, 상기 잔사회는 플라이애쉬를 만드는 과정에서 생성되는 저품질의 발전용 석탄회로 52.5 내지 67.5 중량%를 포함할 수 있다(이상 S111).2, first, the mixture is prepared by mixing dredged soil, low ash and residue. The dredged soil may be 15 to 48% by weight as pumped out of the sand, soil, sand, etc. deposited on the bottom of the river, lake, sea. The low ash may include 2.5 to 32.5 wt% of the solidified material by falling down the boiler in a state in which particles are formed by sintering in a combustion furnace. In addition, the low ash may be mixed in a round form through a separate process. On the other hand, the residue may include 52.5 to 67.5% by weight of low-quality coal-fired power circuit generated in the process of making the fly ash (S111).

다음으로, 상기 혼합물을 압출 성형하여 제1차 성형하고, 압출 성형된 상기 혼합물을 경량골재의 입도분포 기준에 맞게 절단(또는 파쇄)하여 둥근 모양을 갖는 골재입자로 제2차 성형하여 성형체를 제조한다. 상기 압출 성형방법이나 둥근 모양으로 성형하는 방(절단 또는 파쇄)법은 통상의 방법을 이용할 수 있으므로, 설명을 생략하도록 한다(이상 S112).Next, the mixture is first molded by extrusion molding, and the extruded mixture is cut (or crushed) to meet the particle size distribution standard of the lightweight aggregate, and secondly molded into aggregate particles having a round shape to manufacture a molded body. do. Since the extrusion method or the method of forming in a round shape (cutting or crushing) can use a conventional method, the description thereof will be omitted (S112 above).

다음으로, 상기 성형체를 건조시켜 건조체를 제조한다. 건조하는 방법은 로타리 건조기(ROTARY DRYER)를 이용하는 것이 가능하다(이상 S113).Next, the molded body is dried to prepare a dried body. As a drying method, it is possible to use a rotary dryer (ROTARY DRYER) (above S113).

다음으로, 상기 건조체를 1050 내지 1200℃에서 소성하여 인공경량골재를 제조한다. 소성방법은 통상의 방법을 이용할 수 있으며, 소성 시간은 한정되지 않는다. 예를 들어, 상기 건조체를 소성기계에 투입하고 30분 가량 소성시키는 것이 가능하다(이상 S114).Next, by firing the dried body at 1050 to 1200 ℃ to produce an artificial lightweight aggregate. The baking method can use a conventional method, and firing time is not limited. For example, it is possible to put the dry body into a baking machine and to bake for about 30 minutes (above S114).

상술한 공정을 통해 제조되는 인공경량골재는 후술할 흡음판넬의 흡음재료로 사용될 수 있다. Artificial lightweight aggregate produced through the above-described process may be used as a sound absorbing material of the sound absorbing panel to be described later.

도 3은 도 1의 흡음판넬 제조방법에서 흡음판넬 제조(S120)를 세분화한 순서도이다.FIG. 3 is a flow chart of subdividing the sound absorbing panel manufacturing (S120) in the sound absorbing panel manufacturing method of FIG. 1.

도 3을 참조하면, 우선 시멘트, 물 및 실리카흄을 혼합하여 제1 혼합물을 제조하고, 상기 제1 혼합물에 상기 인공경량골재를 혼합하여 제2 혼합물을 제조한다. Referring to FIG. 3, first, cement, water, and silica fume are mixed to prepare a first mixture, and the artificial light aggregate is mixed with the first mixture to prepare a second mixture.

혼합량은 상기 인공경량골재 100 중량부를 기준으로 하여, 상기 시멘트는 25 내지 27 중량부, 상기 물은 7 내지 8 중량부를 혼합하고, 상기 실리카흄은 콘크리트용 혼화재료로 혼합량은 특정되지 않고 소량 투입한다(이상 S121 및 S122).The mixing amount is based on 100 parts by weight of the artificial lightweight aggregate, the cement is 25 to 27 parts by weight, the water is mixed 7 to 8 parts by weight, and the silica fume is mixed with a small amount of concrete mixed material is not specified ( S121 and S122).

다음으로, 상기 제2 혼합물에 혼화재 및/또는 유동화제를 혼합하여 제3 혼합물을 제조한다. 상기 혼화재 및 상기 유동화제는 모르타르, 콘크리트 등에 특별한 품질을 부여하기 위한 감수제, 촉진제, 지연제, 기포제 등으로 통상의 것을 이용할 수 있다. Next, a third mixture is prepared by mixing a admixture and / or a fluidizing agent with the second mixture. The admixture and the fluidizing agent may be conventionally used as a reducing agent, accelerator, retardant, foaming agent, etc. for imparting a special quality to mortar, concrete and the like.

한편, 상기 혼화재 및 상기 유동화제의 혼합량은 상기 인공경량골재 100중량부를 기준으로 하여, 상기 혼화제는 3 내지 4 중량부를 혼합하고, 상기 유동화제는 1 내지 2 중량부를 혼합한다(이상 S123). On the other hand, the mixing amount of the admixture and the fluidizing agent is based on 100 parts by weight of the artificial lightweight aggregate, the admixture is mixed 3 to 4 parts by weight, the fluidizing agent is mixed 1 to 2 parts by weight (above S123).

다음으로, 상기 제3 혼합물을 주름부가 형성된 형틀에 주입하고, 상기 형틀에 주입된 혼합물을 양생한 후에 다시 형틀에서 분리함으로써 흡음판넬이 제조될 수 있다. Next, a sound absorbing panel may be manufactured by injecting the third mixture into a mold having a wrinkle portion, and curing the mixture injected into the mold and then separating the mold mixture from the mold again.

이하, 상기 방법을 통해 제조된 흡음판넬에 대하여 설명하도록 한다. Hereinafter, the sound absorbing panel manufactured by the above method will be described.

도 4는 도 1의 방법에 의해 제조된 흡음판넬(100)의 사시도이다. 도 4를 참조하면, 흡음판넬(100)은 상부에 코러게이션(corrugation) 형상을 가지며 상기 인공경량골재로 제조되는 흡음패널(110) 및 흡음패널(110) 하부에 결합되는 무석면 압출성형 시멘트판(120)을 포함할 수 있다. 4 is a perspective view of the sound absorbing panel 100 manufactured by the method of FIG. 1. Referring to Figure 4, the sound absorbing panel 100 has a corrugation (corrugation) shape on the top and the non-asbestos extruded cement plate coupled to the sound absorbing panel 110 and the sound absorbing panel 110 made of the artificial lightweight aggregate ( 120).

본 명세서에서 상기 인공경량골재로 제조되는 흡음판넬(100)은 흡음패널(110)과 동일하지만, 설명의 편의를 위하여 이하에서는 흠음패널(110) 및 무석면 압출성형 시멘트판(120)의 결합체를 흡음판넬(100)로 정의하도록 한다. In the present specification, the sound absorbing panel 100 made of the artificial lightweight aggregate is the same as the sound absorbing panel 110, but for convenience of description, the sound absorbing panel 110 and the combination of the non-asbestos extruded cement plate 120 will be absorbed below. It is defined as the panel 100.

한편, 무석면 압출성형 시멘트판(120)은 차음성을 향상시키고 흡음패널(110)이 파손되는 것을 방지하기 위한 것으로, 고온 및 고압에서 양생하여 만든 기포 콘크리트로 규사와 석회를 원료로 하며, 통상적인 것을 이용 가능하다. 이러한 무석면 압출성형 시멘트판(120)으로는 ALC (autoclaved lightweight concrete)판, ECP(Extruded cement panel) 등이 있다.On the other hand, the asbestos-free extruded cement plate 120 is to improve sound insulation and to prevent damage to the sound absorbing panel 110, the foam concrete made by curing at high temperature and high pressure as a raw material of silica sand and lime, It is available. The asbestos-free extruded cement plate 120 includes an autoclaved lightweight concrete (ALC) plate, an extruded cement panel (ECP), and the like.

흡음패널(110) 및 무석면 압출성형 시멘트판(120)을 결합시키는 방법으로는 접착제를 사용하거나, 금구류 체결 방법 또는 밴딩 체결 방법 등을 사용할 수 있다. As a method of bonding the sound absorbing panel 110 and the non-asbestos extruded cement plate 120, an adhesive may be used, or a metal fitting fastening method or a bending fastening method may be used.

도 5는 도 4의 흡음판넬(100)의 활용도이다. 도 5를 참조하면, 흡음판넬(100)은 복수 개의 흡음판넬(100)이 적층되어 수용되는 프레임(130)을 더 포함할 수 있다. 프레임(130)은 I-형강 또는 H-빔일 수 있으며 도 5에 도시된 바와 같이, 두 개의 I-형강 사이에 흡음판넬(100) 복수 개를 끼움체결하여 적층시킬 수 있다. 5 is a utilization of the sound absorbing panel 100 of FIG. Referring to FIG. 5, the sound absorbing panel 100 may further include a frame 130 in which a plurality of sound absorbing panels 100 are stacked and accommodated. The frame 130 may be an I-beam or an H-beam, and as illustrated in FIG. 5, a plurality of sound absorbing panels 100 may be sandwiched and stacked between two I-beams.

이와 같이 프레임(130)을 사용하여 흡음판넬(100)을 시공할 경우, 흡음판넬(100)이 서로 독립적으로 움직이므로 자연재해에 대하여 강한 내구성을 가질 수 있으며, 유지보수가 간편하다는 장점이 있다. When the sound absorbing panel 100 is constructed using the frame 130 as described above, since the sound absorbing panel 100 moves independently of each other, the sound absorbing panel 100 may have a strong durability against natural disasters, and has an advantage of easy maintenance.

상술한 바와 같이, 본 발명의 실시예들은 종래 단순 폐기 매립되던 저회 및 잔사회를 모두 활용하여 인공경량골재 및 흡음판넬을 제조함으로써, 발전용 석탄회의 재활용성을 극대화 할 수 있으며, 준설토, 저회, 잔사회를 적정 비율로 혼합하여 인공경량골재를 제조함으로써, 경량골재 흡음판넬의 흡음력을 향상시킬 수 있다.As described above, the embodiments of the present invention can maximize the recyclability of coal ash for power generation by producing artificial lightweight aggregate and sound absorbing panel utilizing both low ash and remnants that were simply landfilled in the prior art, dredged soil, low ash, By mixing the residue in an appropriate ratio to produce an artificial lightweight aggregate, the sound absorbing power of the light weight aggregate sound absorbing panel can be improved.

이하에서는, 실시예를 통하여 본 발명을 보다 상세히 설명하도록 한다. 그러나, 하기 실시예에 의하여 본 발명의 보호범위가 제한되는 것은 아니다.
Hereinafter, the present invention will be described in more detail with reference to Examples. However, the scope of the present invention is not limited by the following examples.

실시예Example

(1) 혼합비를 달리한 (1) different mixing ratio 인공경량골재의Artificial lightweight aggregate 제조 Produce

하기 [표1]은 준설토, 저회 및 잔사회를 다양한 비율로 혼합하여 제조된 인공경량골재의 혼합비율, 절건비중 및 흡수율을 측정하여 정리한 것이다. 한편, 상기 인공경량골재 제조는 1050℃ 내지 1200℃ 범위의 소성온도에서 수행되었다.[Table 1] summarizes by measuring the mixing ratio, dry weight and absorption rate of artificial lightweight aggregate prepared by mixing the dredged soil, low ash and residues in various ratios. On the other hand, the artificial lightweight aggregate production was performed at a firing temperature in the range of 1050 ℃ to 1200 ℃.

준설토(wt%)Dredged soil (wt%) 저회(wt%)Low ash (wt%) 잔사회(wt%)Residual (wt%) 절건비중Weight ratio 흡수율(%)Absorption rate (%) 실험예1Experimental Example 1 3030 17.517.5 52.552.5 0.6~1.40.6 to 1.4 12~2212-22 실험예2Experimental Example 2 2727 20.520.5 52.552.5 0.65~1.410.65 ~ 1.41 14.3~2314.3 ~ 23 실험예3Experimental Example 3 2424 23.523.5 52.552.5 0.69~1.430.69 ~ 1.43 11~24.711-24.7 실험예4Experimental Example 4 2121 26.526.5 52.552.5 0.8~1.50.8-1.5 14.5~25.614.5 ~ 25.6 실험예5Experimental Example 5 1818 29.529.5 52.552.5 0.95~1.480.95-1.48 17.3~26.117.3-26.1 실험예6Experimental Example 6 1515 32.532.5 52.552.5 1.12~1.511.12-1.51 15.5~26.415.5-26.4 실험예7Experimental Example 7 1212 35.535.5 52.552.5 1.38~1.781.38-1.78 17.8~26.517.8-26.5 실험예8Experimental Example 8 3333 14.514.5 52.552.5 0.68~1.450.68-1.45 13.7~24.513.7 ~ 24.5 실험예9Experimental Example 9 3636 11.511.5 52.552.5 0.89~1.440.89-1.44 14.2~28.614.2-28.6 실험예10Experimental Example 10 3939 8.58.5 52.552.5 0.95~1.490.95-1.49 14.5~27.814.5 ~ 27.8 실험예11Experimental Example 11 4242 5.55.5 52.552.5 0.99~1.500.99-1.50 15.3~27.715.3-27.7 실험예12Experimental Example 12 4545 2.52.5 52.552.5 1.23~1.501.23-1.50 16.2~28.716.2 to 28.7 실험예13Experimental Example 13 48.548.5 -- 52.552.5 1.23~1.881.23-1.88 17~2917-29 실험예14Experimental Example 14 2727 17.517.5 55.555.5 0.67~1.450.67-1.45 13.7~25.113.7 ~ 25.1 실험예15Experimental Example 15 2424 17.517.5 58.558.5 0.79~1.480.79-1.48 14.3~26.714.3 ~ 26.7 실험예16Experimental Example 16 2121 17.517.5 61.561.5 0.83~1.490.83-1.49 15.2~27.315.2 ~ 27.3 실험예17Experimental Example 17 1818 17.517.5 64.564.5 0.95~1.500.95-1.50 16.8~27.916.8 ~ 27.9 실험예18Experimental Example 18 1515 17.517.5 67.567.5 1.15~1.501.15-1.50 16.4~27.816.4 ~ 27.8 실험예19Experimental Example 19 1212 17.517.5 70.570.5 1.3~1.851.3 to 1.85 17.2~27.217.2 ~ 27.2 실험예20Experimental Example 20 3333 17.517.5 49.549.5 0.77~1.430.77 ~ 1.43 12.7~24.512.7 ~ 24.5 실험예21Experimental Example 21 3636 17.517.5 46.546.5 0.85~1.490.85-1.49 13.4~25.513.4 ~ 25.5 실험예22Experimental Example 22 3939 17.517.5 43.543.5 0.95~1.480.95-1.48 13.7~26.813.7 ~ 26.8 실험예23Experimental Example 23 4242 17.517.5 40.540.5 1.13~1.491.13-1.49 14.3~28.714.3-28.7 실험예24Experimental Example 24 4545 17.517.5 37.537.5 1.2~1.501.2-1.50 15.3~27.815.3 ~ 27.8 실험예25Experimental Example 25 4848 17.517.5 34.534.5 1.39~1.821.39-1.82 16.3~28.916.3-28.9

상기 [표 1]에서 실험예 1 내지 실험예 12는 잔사회를 52.5wt% 로 고정시킨 다음, 준설토 및 저회의 혼합비를 다양하게 구성하여 제조된 인공경량골재이며, 실험예 13은 저회 없이 제조된 인공경량골재이고, 실험예 14 내지 실험예 25는 저회를 17.5wt%로 고정시킨 다음, 준설토 및 잔사회의 혼합비를 다양하게 구성하여 제조된 인공경량골재이다. In Table 1, Experimental Examples 1 to 12 are artificial light weight aggregates prepared by variously forming dredged soil and low ash mixture ratio after fixing the residue to 52.5wt%, and Experimental Example 13 was prepared without low ash. It is artificial lightweight aggregate, Experimental Example 14 to Experimental Example 25 is an artificial lightweight aggregate prepared by fixing the low ash to 17.5wt%, and then variously constituted the mixing ratio of dredged soil and residue.

흡음판넬로 사용 가능한 인공경량골재의 절건비중은 1.5 이하인 바, 상기 [표 1]에서 실험예 7, 실험예 13, 실험예 19 및 실험예 25에 해당하는 인공경량골재의 경우 상기 절건비중 기준을 충족시키지 못하는 경우가 존재함을 확인할 수 있다. 따라서, 본 발명의 일 실시예에서의 준설토, 저회 및 잔사회의 혼합비는 상기 실험예 7, 13, 19, 25 를 제외한, 준설토 15 내지 48중량%, 저회 2.5 내지 32.5중량% 및 잔사회 52.5 내지 67.5중량% 범위 내에 있다. The dry weight ratio of the artificial lightweight aggregate that can be used as the sound absorbing panel is 1.5 or less, and the artificial lightweight aggregate corresponding to Experimental Example 7, Experimental Example 13, Experimental Example 19 and Experimental Example 25 in Table 1 satisfies the criteria for the ratio of dryness. It can be confirmed that there is a case that can not be. Therefore, the mixing ratio of dredged soil, low ash and residue in one embodiment of the present invention is 15 to 48% by weight of dredged soil, 2.5 to 32.5% by weight and 52.5 to residue, except for Experimental Examples 7, 13, 19 and 25. It is in the 67.5 weight% range.

한편, 흡음판넬로 사용 가능한 인공경량골재의 흡수율은 30%이하인 바, 상기 [표 1]에서의 모든 실험예는 상기 흡수율 기준을 만족시킴을 확인할 수 있다. On the other hand, the absorption rate of the artificial lightweight aggregate that can be used as the sound absorbing panel is 30% or less, it can be seen that all the experimental examples in the above [Table 1] satisfies the absorption rate criteria.

또한, 절건비중 및 흡수율 모두를 고려하는 경우에는 준설토 30 중량%, 저회 17.5 중량% 및 잔사회 52.5 중량%를 혼합하여 제조된 인공경량골재(실험예 1)가 가장 적합한 것으로 나타났다.
In addition, when considering both dry weight and water absorption, artificial lightweight aggregate (Experimental Example 1) prepared by mixing 30% by weight of dredged soil, 17.5% by weight of ash, and 52.5% by weight of residue was found to be most suitable.

(2) (2) 인공경량골재의Artificial lightweight aggregate 화학성분 Chemical composition

상기 [표 1]에서 실험예1에 해당하는 인공경량골재의 화학성분을 측정하였다. 측정 결과는 하기 [표 2]에 나타내었다. In Table 1, the chemical composition of the artificial light weight aggregate corresponding to Experimental Example 1 was measured. The measurement results are shown in the following [Table 2].

SiO2 SiO 2 Al2O3 Al 2 O 3 Fe2O3 Fe 2 O 3 CaOCaO MgOMgO Na2ONa 2 O K2OK 2 O TiO2 TiO 2 P2O5 P 2 O 5 IgLossIgLoss 기타Etc 인공경량골재Artificial lightweight aggregate 59.359.3 22.522.5 9.89.8 0.90.9 1.71.7 0.90.9 3.23.2 1.21.2 0.20.2 0.170.17 0.130.13

(3) (3) 흡음판넬의Sound absorption panel  흡음력 시험Sound absorption test

상기 [표 1]에서 실험예1에 해당하는 인공경량골재를 이용하여 흡음판넬을 제조하였다. 보다 구체적으로,상기 인공경량골재 836kg, 시멘트 217kg, 혼화제(분말)1050℃, 유동화제(액상) 10kg 및 물 66.7kg을 혼합하여 흡음판넬을 제조하였다. In [Table 1], a sound absorbing panel was manufactured using artificial light weight aggregate corresponding to Experimental Example 1. More specifically, the sound absorbing panel was manufactured by mixing 836 kg of the artificial lightweight aggregate, 217 kg of cement, 1050 ° C. of a admixture (powder), 10 kg of a fluidizing agent (liquid), and 66.7 kg of water.

다음으로,잔향실에서 KS F 2805(잔향실내의 흡음율 측정방법)에 따라 시험을 실시하고, 그 결과를 하기 [표 3]에 나타내었다. Next, the test was carried out in the reverberation chamber according to KS F 2805 (Method of absorption rate in the reverberation chamber), and the results are shown in the following [Table 3].

주파수(Hz)Frequency (Hz) 잔향시간(Sec)Reverberation time (Sec) 흡음계수(NRC)Sound absorption coefficient (NRC) 종래 흡음판넬Conventional Sound Absorption Panel 흡음판넬(실험예1)Sound absorption panel (Experimental Example 1) 100100 31.331.3 26.426.4 0.730.73 125125 29.329.3 22.522.5 0.740.74 160160 1919 17.417.4 0.770.77 200200 17.617.6 15.315.3 0.780.78 250250 13.113.1 11.911.9 0.720.72 315315 12.212.2 1111 0.740.74 400400 10.210.2 8.98.9 0.730.73 500500 9.79.7 7.47.4 0.730.73 630630 8.98.9 6.36.3 0.780.78 800800 7.67.6 5.25.2 0.760.76 10001000 4.94.9 3.93.9 0.730.73 12501250 4.84.8 3.13.1 0.700.70 16001600 4.54.5 3.23.2 0.740.74 20002000 4.24.2 3.73.7 0.730.73 25002500 4.04.0 3.73.7 0.700.70 31503150 3.93.9 3.63.6 0.710.71 40004000 3.63.6 3.03.0 0.710.71 50005000 2.92.9 2.22.2 0.720.72

상기 [표 3]에서 확인되듯이, 본 발명의 일 실시예(실험예 1)에 따른 흡음판넬은 종래 흡음판넬에 비하여 모든 옥타브 밴드 주파수 범위에서 잔향시간이 짧은 것으로 나타나, 흡음판넬의 흡음성능이 향상되었음을 알 수 있다. 잔향시간은 잔향실에 장착된 흡음패널의 흡음률이 높을수록 짧아지기 때문이다. As shown in Table 3, the sound absorbing panel according to an embodiment of the present invention (Experimental Example 1) shows a shorter reverberation time in all octave band frequency ranges as compared to the conventional sound absorbing panel, and the sound absorbing performance of the sound absorbing panel is It can be seen that the improvement. This is because the reverberation time becomes shorter as the sound absorption rate of the sound absorption panel mounted in the reverberation chamber increases.

또한, 방음벽 관련 산업규격에서는 흡음율(흡음계수, NRC)의 최소 기준을 0.7 이상으로 하고 있는데, 본 발명의 일 실시예(실험예 1)에 따른 흡음판넬은 모든 옥타브 밴드 주파수 범위에서 흡음율 0.7 이상으로 나타나므로 산업상 충분히 상용 가능한 흡음판넬인 것으로 사료된다. In addition, in the industrial standards related to soundproof walls, the minimum standard of sound absorption rate (sound absorption coefficient, NRC) is 0.7 or more, and the sound absorption panel according to the embodiment of the present invention (Experimental Example 1) has a sound absorption rate of 0.7 or more in all octave band frequency range As it appears, it is considered to be a sound absorbing panel that is commercially available.

이상, 본 발명의 실시예들에 대하여 설명하였으나, 해당 기술 분야에서 통상의 지식을 가진 자라면 특허청구범위에 기재된 본 발명의 사상으로부터 벗어나지 않는 범위 내에서, 구성 요소의 부가, 변경, 삭제 또는 추가 등에 의해 본 발명을 다양하게 수정 및 변경시킬 수 있을 것이며, 이 또한 본 발명의 권리범위 내에 포함된다고 할 것이다. While the present invention has been particularly shown and described with reference to exemplary embodiments thereof, many modifications and changes may be made by those skilled in the art without departing from the spirit and scope of the invention as defined in the appended claims. The present invention can be variously modified and changed by those skilled in the art, and it is also within the scope of the present invention.

100: 흡음판넬
110: 흡음패널
120: 무석면 압출성형 시멘트판
130: 프레임
100: Sound absorption panel
110: sound absorption panel
120: asbestos-free extrusion cement plate
130: frame

Claims (8)

전체 중량에 대하여 준설토 15 내지 48중량%, 저회(bottom ash) 2.5 내지 32.5중량% 및 잔사회(rejected ash) 52.5 내지 67.5중량%를 혼합하여 인공경량골재를 제조하는 제1 단계; 및
상기 인공경량골재에 시멘트, 혼화제, 유동화제 및 물을 혼합하여 형틀에 주입하여 양생한 후, 상기 형틀에서 분리하여 흡음판넬을 제조하는 제2 단계를 포함하는 흡음판넬 제조방법.
A first step of preparing artificial lightweight aggregate by mixing 15 to 48% by weight of dredged soil, 2.5 to 32.5% by weight of bottom ash, and 52.5 to 67.5% by weight of rejected ash, based on the total weight; And
A sound absorbing panel manufacturing method comprising a second step of preparing a sound absorbing panel by mixing cement, admixture, fluidizing agent and water in the artificial lightweight aggregate, injecting the mold into a mold, and separating the mold.
삭제delete 제 1항에 있어서,
상기 제1 단계는,
상기 준설토 30 중량%, 상기 저회 17.5 중량% 및 상기 잔사회 52.5중량%를 혼합하여 인공경량골재를 제조하는 단계인 흡음판넬 제조방법.
The method of claim 1,
The first step,
Sound absorbing panel manufacturing method comprising the step of manufacturing artificial lightweight aggregate by mixing 30% by weight of the dredged soil, 17.5% by weight of low ash and 52.5% by weight of the residue.
제 1항에 있어서,
상기 제2 단계는,
시멘트, 물 및 실리카흄을 혼합하여 제1 혼합물을 제조하는 2-1 단계;
상기 제1 혼합물에 상기 인공경량골재를 혼합하여 제2 혼합물을 제조하는 2-2 단계;
상기 제2 혼합물에 혼화재 및/또는 유동화제를 혼합하여 제3 혼합물을 제조하는 2-3 단계; 및
상기 제3 혼합물을 주름부가 형성된 형틀에 주입하는 2-4 단계를 포함하는 흡음판넬 제조방법.
The method of claim 1,
The second step comprises:
Step 2-1 to prepare a first mixture by mixing cement, water and silica fume;
Step 2-2 of preparing the second mixture by mixing the artificial light weight aggregate with the first mixture;
2-3 to prepare a third mixture by mixing admixtures and / or fluidizing agents with the second mixture; And
Sound absorbing panel manufacturing method comprising the step of injecting the third mixture into the mold formed wrinkles.
제 1항에 있어서,
상기 제2 단계는,
상기 인공경량골재 100 중량부에 대하여, 시멘트 25 내지 27 중량부, 혼화제 3 내지 4 중량부, 유동화제 1 내지 2 중량부 및 물 7 내지 8 중량부를 혼합하는 흡음판넬 제조방법.
The method of claim 1,
The second step comprises:
Sound absorbing panel manufacturing method for mixing 25 to 27 parts by weight of cement, 3 to 4 parts by weight of admixture, 1 to 2 parts by weight of fluidizing agent and 7 to 8 parts by weight of water based on 100 parts by weight of the artificial lightweight aggregate.
제 1항 및 제 3항 내지 제 5항 중 어느 한 항에 따른 방법으로 제조되는 흡음판넬.
Sound absorbing panel produced by the method according to any one of claims 1 and 3.
제 6항에 있어서,
상기 흡음판넬의 하부에 결합되는 무석면 압출성형 시멘트판을 더 포함하는 흡음판넬.
The method according to claim 6,
The sound absorbing panel further comprises a non-asbestos extruded cement plate bonded to the lower portion of the sound absorbing panel.
제 7항에 있어서,
상기 무석면 압출성형 시멘트판이 결합된 흡음판넬 복수 개가 적층되어 수용되는 프레임을 더 포함하는 흡음판넬.
The method of claim 7, wherein
The sound absorbing panel further comprises a frame in which a plurality of sound absorbing panels combined with the asbestos-free extrusion cement plate are stacked and accommodated.
KR20110088292A 2011-09-01 2011-09-01 Method for absorbing panel comprising artificial lightweight aggregate with ash KR101137260B1 (en)

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KR20110088292A KR101137260B1 (en) 2011-09-01 2011-09-01 Method for absorbing panel comprising artificial lightweight aggregate with ash
DE112012003658.1T DE112012003658B4 (en) 2011-09-01 2012-08-31 A method of manufacturing a sound absorbing panel including an artificial lightweight aggregate made using coal ash of a power generating system and a sound absorbing panel
CN201280042514.2A CN103857641B (en) 2011-09-01 2012-08-31 Manufacture includes the method for the Suond-absorbing panel of the artificial lightweight aggregate manufactured using the coal ash of electricity generation system
PCT/KR2012/007012 WO2013032288A1 (en) 2011-09-01 2012-08-31 Method for manufacturing a sound absorbing panel including artificial lightweight aggregate manufactured using coal ash of a power generating system

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DE112012003658T5 (en) 2014-06-18

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