KR101119712B1 - Liquid fertilizer to improve the absoption of Ca - Google Patents

Liquid fertilizer to improve the absoption of Ca Download PDF

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KR101119712B1
KR101119712B1 KR1020090037298A KR20090037298A KR101119712B1 KR 101119712 B1 KR101119712 B1 KR 101119712B1 KR 1020090037298 A KR1020090037298 A KR 1020090037298A KR 20090037298 A KR20090037298 A KR 20090037298A KR 101119712 B1 KR101119712 B1 KR 101119712B1
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weight
calcium
liquid fertilizer
absorption
composition
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KR20100118442A (en
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정영만
신현진
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제이아그로 주식회사
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    • C—CHEMISTRY; METALLURGY
    • C05—FERTILISERS; MANUFACTURE THEREOF
    • C05G—MIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
    • C05G5/00—Fertilisers characterised by their form
    • C05G5/20—Liquid fertilisers
    • C—CHEMISTRY; METALLURGY
    • C05—FERTILISERS; MANUFACTURE THEREOF
    • C05C—NITROGENOUS FERTILISERS
    • C05C11/00—Other nitrogenous fertilisers
    • C—CHEMISTRY; METALLURGY
    • C05—FERTILISERS; MANUFACTURE THEREOF
    • C05D—INORGANIC FERTILISERS NOT COVERED BY SUBCLASSES C05B, C05C; FERTILISERS PRODUCING CARBON DIOXIDE
    • C05D9/00—Other inorganic fertilisers
    • C—CHEMISTRY; METALLURGY
    • C05—FERTILISERS; MANUFACTURE THEREOF
    • C05G—MIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
    • C05G1/00—Mixtures of fertilisers belonging individually to different subclasses of C05

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Pest Control & Pesticides (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Fertilizers (AREA)

Abstract

본 발명은 칼슘의 흡수와 영양경로에서의 이동성을 증대시킨 액상비료조성물에 관한 것으로서, 영양경로에서의 칼슘의 흡수와 이동성을 증대시키기 위한 액상비료조성물에 있어서, 상기 액상비료조성물은, 칼슘의 흡수, 이동의 조력제로서 붕산을 사용하고, 상기 붕산의 용해제로서 당류와 폴리아민류를 채용하여 조성하며, 특히 상기 액상비료조성물은, 염화칼슘 10-50중량%, 붕산 0.1-8중량%, 몰리브덴산나트륨 0.0005-0.01중량%, 당류 0.1-25중량%, 폴리아민류(Monoethanolamine, Dimethylamino propylamine)의 어느 하나의 0.1-20중량%, 우론산 0.001-0.2중량% 의 범위에서 각 조성성분의 중량%가 선택되고, 잔여 중량%를 물로써 하여 전체 중량100% 로 구성되는 조성물의 하나인 것 을 특징으로 하는 칼슘의 흡수와 영양경로에서의 이동성을 증대시킴으로써, 식물 영양 경로 내의 칼슘의 흡수와 이동을 증진시키며, 과실의 당도와 착색을 증진시킬 수 있는 물질인 붕소, 당류, 폴리아민, 우론산 등과 칼슘을 혼합 용해한 조성물을 제공함으로써 수확기 과실의 칼슘 함량 증가, 과실품질증대, 착색 및 당도 증진, 저장 중 과실연화방지 및 부패방지의 효과를 제공한다.The present invention relates to a liquid fertilizer composition in which calcium absorption and mobility in the nutrient pathway are increased. In a liquid fertilizer composition for increasing the absorption and mobility of calcium in the nutrient pathway, the liquid fertilizer composition includes calcium absorption. Boric acid is used as an adjuvant for migration, and sugars and polyamines are employed as the dissolving agent for boric acid, and the liquid fertilizer composition is 10-50% by weight of calcium chloride, 0.1-8% by weight of boric acid, and sodium molybdate. In the range of 0.0005-0.01% by weight, 0.1-25% by weight of sugar, 0.1-20% by weight of any one of polyamines (Monoethanolamine, Dimethylamino propylamine), 0.001-0.2% by weight of uronic acid , By increasing the uptake of calcium and mobility in the nutrient pathway, characterized in that it is one of the compositions consisting of 100% by weight of the total weight , with the remaining weight% as water . Increasing the calcium content, fruit quality, and coloring of the harvester's fruits by providing a composition in which calcium is mixed with boron, sugars, polyamines, uronic acid, etc., which enhances the absorption and transport of calcium and improves the sugar content and coloring of the fruit. And to enhance the sugar content, to prevent fruit softening and anti-corruption during storage.

칼슘, 영양경로, 액상비료조성물 Calcium, Nutritional Pathway, Liquid Fertilizer Composition

Description

칼슘의 흡수와 영양경로에서의 이동성을 증대시킨 액상비료조성물{Liquid fertilizer to improve the absoption of Ca}Liquid fertilizer to improve the absoption of Ca

본 발명은 재배지의 토양 중의 칼슘의 흡수를 증진시켜 과수류의 착색성의 증대와 과실의 당도를 향상시킬 수 있는 조성의 친환경 비료의 제공에 관한 것으로서, 더욱 상세하게는 칼슘의 흡수 및 이동을 증진시키는 붕소, 몰리브덴, 당류, 폴리아민류, 우론산을 함유하는 조성물을 제공함으로써,The present invention relates to the provision of an environmentally friendly fertilizer of a composition capable of improving the absorption of calcium in the soil of cultivated land to increase the coloring properties of fruit trees and improve the sweetness of fruits, and more particularly, boron to enhance the absorption and migration of calcium. By providing a composition containing molybdenum, sugars, polyamines, uronic acid,

유기태 친환경비료로서 작용하여 과실의 칼슘의 흡수를 증진시키고, 바람직하지 아니한 재배 환경 하에서 발생하는 각종 과수류의 생리장해 예방 및 방제, 생육 중의 칼슘 결핍과 부족에 따른 저장 중 품질저하의 방지, 저장 중 발생하는 생리장해 및 병해의 경감을 가능하게 하여 과실의 당도향상과 착색 증진에 효과가 우수한 유기태 친환경 비료의 제공에 관한 것이다.It acts as an organic eco-friendly fertilizer to promote the absorption of calcium in fruits, preventing and controlling the physiological disorders of various fruit trees occurring under unfavorable cultivation environment, preventing the deterioration of quality during storage due to calcium deficiency and lack in growth, and occurring during storage. The present invention relates to the provision of an organic, environmentally friendly fertilizer having an excellent effect on improving the sugar content of the fruit and promoting the coloring by enabling the reduction of physiological disorders and diseases.

과수농업이나 시설채소 농업은 협소한 지역의 재배환경상, 일반적으로 연작을 함으로써 토양이 산성화되거나, 염류집적에 의한 재배토양 환경의 악화에 따른 칼슘과 기타 미량원소의 결핍현상발생이 해가 갈수록 심하여 짐으로써 수확 과실의 품질이 낮아지거나, 저장 중의 품질이 급격히 저하되는 원인이 되는 등의 문제점을 가지고 있다.Fruit farming and plant vegetable farming are becoming more severe year after year due to the cultivation environment in a narrow area, which generally lead to acidification of soil due to cultivation, or deficiency of calcium and other trace elements due to deterioration of cultivated soil environment due to salt accumulation. As a result, the quality of the harvested fruit may be lowered, or the quality of the fruit may be rapidly reduced during storage.

종래로부터도 이러한 점을 개선하기 위하여, 미국과 유럽에서는 다양한 액상형태의 칼슘제가 제조 시판되고 있고, 국내에서도 유사한 종류의 많은 칼슘비료가 시판되어 왔다.In order to improve this point, conventionally, various liquid calcium forms are commercially available in the US and Europe, and many similar types of calcium fertilizers have been commercially available in Korea.

그러나, 종래로부터의 액상칼슘의 형태는 단순 칼슘의 함량만을 높인 액상칼슘제의 형태로 제공됨으로써 칼슘흡수에 조력제인 붕소를 함유하지 않거나 거의 소량만을 함유하였다.However, the conventional form of liquid calcium is provided in the form of a liquid calcium agent with only a high content of calcium, so that calcium absorption does not contain boron as an aid or almost only a small amount.

과실에 대하여 칼슘 단용의 시비만으로는 식물체 내로의 흡수 및 흡수 이후의 과실수의 영양경로에서의 칼슘성분의 이동이 용이하지 않으며, 붕소의 존재 하에서 칼슘의 흡수와 이동이 증진된다.Calcium alone fertilization alone does not facilitate the movement of calcium components in the nutritional pathway of fruit water after absorption and absorption into plants, and promotes absorption and movement of calcium in the presence of boron.

붕산은 난용성으로서 물에 거의 녹지 않으나, 폴리아민류의 존재 하에서는 높은 용해도를 가지며, 염화칼슘은 붕산용액 하에서 난용으로 변하거나 반응침전물을 형성하게 된다.Boric acid is poorly soluble in water and hardly soluble in water, but has high solubility in the presence of polyamines, and calcium chloride becomes poorly soluble in boric acid solution or forms a reaction precipitate.

본 발명의 칼슘의 흡수와 영양경로에서의 이동성을 증대시킨 액상비료조성물은 상기하는 반응침전물의 형성을 없애면서 칼슘을 완전히 용해시키기 위하여 실험에 의하여 얻어진 선택적인 물질로 '올리영양경로에서의 칼슘의 흡수와 이동성을 증대시키기 위한 액상비료조성물에 있어서, 상기 액상비료조성물은,The liquid fertilizer composition of the present invention, which has enhanced absorption of calcium and mobility in the nutrient route, is an optional substance obtained by experiments to completely dissolve calcium while eliminating the formation of the reaction precipitate described above. In the liquid fertilizer composition for increasing the absorption and mobility, the liquid fertilizer composition,

칼슘의 흡수, 이동의 조력제로서 붕산을 사용하고,Boric acid is used as an aid of absorption and movement of calcium,

상기 붕산의 용해제로서 당류와 폴리아민류를 채용하여 조성한 것을 특징으로 하는 칼슘의 흡수와 영양경로에서의 이동성을 증대시킨 액상비료조성물로서 종래의 조성물과 차이가 있다.The liquid fertilizer composition, which is composed of saccharides and polyamines as a dissolving agent of boric acid, is increased, and has a difference from the conventional composition as a liquid fertilizer composition with increased mobility in the nutritional pathway.

본 발명자들은 상기와 같은 점을 고려하여 고당류, 폴리아민류, 칼슘, 붕산, 몰리브덴, 우론산 등을 함유하는 친환경 유기태 비료로서 종래의 칼슘제와 차별화되는 조성물을 제공함으로써,In view of the above, the present inventors provide an environment-friendly organic fertilizer containing high sugars, polyamines, calcium, boric acid, molybdenum, uronic acid, and the like to provide a composition that is differentiated from conventional calcium agents.

과실 영양경로 내에서의 칼슘의 흡수와 이동을 증진시켜 줌으로써 과실의 품질, 저장 중 과실의 연화방지 및 부패방지, 올리고당, 폴리아민류, 우론산의 함유에 따른 당도와 착색 증진효과를 얻을 수 있는 칼슘의 흡수와 영양경로에서의 이동성을 증대시킨 액상비료조성물을 다년간의 실내와 재배포장에서 비교 시험을 수행한 결과 본 발명을 완성하였다.Calcium, which can improve the absorption and migration of calcium in the fruit nutrition pathway, prevents softening and decay of fruit during storage, and improves sugar and coloration effect by containing oligosaccharides, polyamines and uronic acid. The present invention was completed by performing a comparative test of liquid fertilizer composition with increased absorption and nutritional path in the indoor and cultivation field for many years.

따라서, 본 발명의 목적은 과실의 영양경로 내로의 칼슘을 효과적으로 흡수 증진시키고 영양경로내에서의 칼슘의 원활한 이동을 촉진시켜, 칼슘이 많은 과실과 품질이 우수한 과실을 생산하고, 저장과실의 품질저하를 방지하고, 저장 중 병해발생을 줄이며, 당도와 착색을 증진시키는 친환경 비료를 생산하여 농가소득 증대에 기여하는 데에 있다.Accordingly, an object of the present invention is to effectively absorb and promote calcium in the nutrition pathway and promote the smooth movement of calcium in the nutrition pathway, to produce calcium-rich fruits and fruits of good quality, and to reduce the quality of the storage fruits. It is aimed at contributing to increasing farm household income by producing eco-friendly fertilizers to prevent the disease, reduce the occurrence of pests during storage, and improve sugar and coloring.

이에 본 발명의 칼슘의 흡수와 영양경로에서의 이동성을 증대시킨 액상비료조성물에서는;In the liquid fertilizer composition to increase the absorption of calcium and the mobility in the nutrient path of the present invention;

영양경로에서의 칼슘의 흡수와 이동성을 증대시키기 위한 액상비료조성물에 있어서, 상기 액상비료조성물은, 염화칼슘 10-50중량%, 붕산 0.1-8중량%, 몰리브덴산나트륨 0.0005-0.01중량%, 당류 0.1-25중량%, 폴리아민류(Monoethanolamine, Dimethylaminopropylamine)의 어느 하나의 0.1-20중량%, 우론산 0.001-0.2중량% . 의 범위에서 각 조성성분의 중량%가 선택되고, 잔여 중량%를 물로써 하여 전체 중량100% 로 구성되는 조성물의 하나인 것 을 조성적인 특징으로 한다.In the liquid fertilizer composition for increasing the absorption and mobility of calcium in the nutritional route, the liquid fertilizer composition is 10-50% by weight calcium chloride, 0.1-8% by weight boric acid, 0.0005-0.01% by weight sodium molybdate, 0.1 -25 wt%, 0.1-20 wt% of polyamines (Monoethanolamine, Dimethylaminopropylamine), 0.001-0.2 wt% uronic acid. The composition is characterized in that the weight percentage of each composition component is selected in the range of, and is one of the composition consisting of 100% of the total weight by using the remaining weight% as water .

또한, 바람직한 실험적인 최적의 실시례로서는, 영양경로에서의 칼슘의 흡수와 이동성을 증대시키기 위한 액상비료조성물에 있어서, 상기 액상비료조성물은, 폴리아민류로서 모노에탄올아민(Monoethanolamine(C2H7NO))를 선택하는 경우에는, 상기 액상비료조성물의 조성은 물 30.7중량%, 당류 15중량%이며, 모노에탄올아민(Monoethanolamine(C2H7NO)) 10중량%, 염화칼슘 35중량%, 붕산 8중량%, 몰리브덴산나트륨 0.1중량%, 우론산 0.2중량%, 소포제 1중량%로 한 것으로 하거나,In addition, as a preferred experimental optimum embodiment, in the liquid fertilizer composition for increasing the absorption and mobility of calcium in the nutrient pathway, the liquid fertilizer composition is monoethanolamine (C 2 H 7 NO as polyamines). )), The composition of the liquid fertilizer composition is 30.7% by weight of water, 15% by weight of sugar, 10% by weight of monoethanolamine (C 2 H 7 NO), 35% by weight of calcium chloride, boric acid 8 Weight%, sodium molybdate 0.1% by weight, uronic acid 0.2% by weight, antifoaming agent 1% by weight, or

폴리아민류로서 디메틸아미노프로필아민(Dimethylaminopropylamine(C5H14N2)을 선택하는 경우에는, 디메틸아미노프로필아민(Dimethylaminopropylamine(C5H14N2) 5중량%, 물 35.7중량%, 당류 15중량%이며,, 염화칼슘 35중량%, 붕산 8중량%, 몰리브덴산나트륨 0.1중량%, 우론산 0.2중량%, 소포제 1중량%로 한 것을 특징으로 하고 있으며,When dimethylaminopropylamine (C 5 H 14 N 2 ) is selected as the polyamine, 5 weight% of dimethylaminopropylamine (C 5 H 14 N 2 ) , water 35.7 weight%, sugar 15 weight% 35% by weight of calcium chloride, 8% by weight of boric acid, 0.1% by weight of sodium molybdate, 0.2% by weight of uronic acid, 1% by weight of an antifoaming agent,

상기 당류는 올리고당인 것을 바람직한 특징으로 하고 있다.The saccharide is characterized in that it is an oligosaccharide.

본 발명의 칼슘의 흡수와 영양경로에서의 이동성을 증대시킨 액상비료조성물은 식물 영양경로 내의 칼슘의 흡수와 이동을 증진시키며, 과실의 당도와 착색을 증진시킬 수 있는 물질인 붕소, 당류, 폴리아민, 우론산 등과 칼슘을 혼합 용해한 조성물을 제공함으로써 수확기 과실의 칼슘 함량 증가, 과실품질증대, 착색 및 당도 증진, 저장 중 과실연화방지 및 부패방지의 다양한 효과를 제공한다.Liquid fertilizer composition of the present invention increases the absorption and transport of calcium in the nutritional pathway, and promotes the absorption and migration of calcium in the plant nutritional pathway, boron, sugars, polyamine, By providing a composition in which calcium and uronic acid are mixed and dissolved, it provides various effects of increasing the calcium content of the harvester fruit, increasing fruit quality, enhancing coloring and sugar content, preventing fruit softening and anti-corruption during storage.

이하 첨부되는 도면과 관련하여 상기 목적을 달성하기 위한 본 발명의 바람직한 구성과 작용을 도면과 함께 설명하면 다음과 같다.Hereinafter, with reference to the accompanying drawings, the preferred configuration and operation of the present invention for achieving the above object is as follows.

도 1은 본 발명의 영양경로에서의 칼슘의 흡수와 이동성을 증대시키기 액상비료조성물의 바람직한 제1실시예의 조성을 도시하는 테이블도, 도 2는 바람직한 다른 제2실시예의 조성을 도시하는 테이블도, 도 3은 본 발명의 액상비료조성물을 실험적으로 시비한 성적표의 테이블도, 도 4는 본 발명의 액상비료조성물을 실험적으로 시비한 성적표의 테이블도, 도 5는 본 발명의 액상비료조성물을 실험적으로 시비하여 얻은 과실 부패율의 그래프도, 도 6은 본 발명의 액상비료조성물을 실험적으로 시비하여 얻는 실험 대상구의 사진이다.1 is a table showing the composition of the first preferred embodiment of the liquid fertilizer composition to increase the absorption and mobility of calcium in the nutritional route of the present invention, Figure 2 is a table showing the composition of another preferred second embodiment, Figure 3 Figure 4 is a table of the test report fertilizing the liquid fertilizer composition of the present invention, Figure 4 is a table of the test report fertilizing the liquid fertilizer composition of the present invention, Figure 5 is an experimental fertilization of the liquid fertilizer composition of the present invention Fig. 6 is a photograph of the experimental subject sphere obtained by experimental fertilization of the liquid fertilizer composition of the present invention.

본 발명의 칼슘의 흡수와 영양경로에서의 이동성을 증대시킨 액상비료조성물 의 조성 성분은 염화칼슘, 붕산, 몰리브덴산나트륨, 당류, 폴리아민류, 우론산으로 조성되는 화합물을 특징으로 하고 있다.The composition component of the liquid fertilizer composition which has enhanced absorption of calcium and mobility in the nutrient path of the present invention is characterized by a compound composed of calcium chloride, boric acid, sodium molybdate, sugars, polyamines and uronic acid.

식물체 내에서의 칼슘의 흡수와 이동을 증진시키기 위하여 제공되는 조성체로서는, 붕산 4 중량%와 당류 15 중량%를 함유시키고, 나아가서 당도와 착색을 증진시킬 수 있는 폴리아민류, 우론산이 각각 10, 0.2중량%를 전체 중량비에 대하여 제공하여 조성된다.Compositions provided to enhance the absorption and migration of calcium in the plant include 4% by weight of boric acid and 15% by weight of sugars, and furthermore, polyamines and uronic acids, which can enhance sugar and coloring, respectively, 10, It is formulated by providing 0.2% by weight relative to the total weight ratio.

본 발명의 조성물은 과수류, 과채류, 근채류 및 엽채류에 살포할 경우 칼슘의 흡수 및 이동을 증진시킴으로서 과실의 품질 증진, 저장력 증진 등 고품질의 농산물 생산할 수 있다.When the composition of the present invention is sprayed on fruit trees, fruit vegetables, root vegetables, and leaf vegetables can improve the absorption and migration of calcium, it is possible to produce high-quality agricultural products, such as enhancing the quality of the fruit and enhancing storage capacity.

본 발명의 칼슘의 흡수와 영양경로에서의 이동성을 증대시킨 액상비료조성물의 실험적으로 얻은 유효한 조성비는,The experimentally obtained effective composition ratio of the liquid fertilizer composition which increased the absorption of calcium and the mobility in the nutrient path of the present invention,

염화칼슘 10-50중량%, 붕산 0.1-8중량%, 몰리브덴산나트륨 0.0005-0.01중량%, 당류 0.1-25중량%, 폴리아민류(Monoethanolamine, Dimethylaminopropylamine) 0.1-20중량%, 우론산 0.001-0.2중량% 의 범위에서 각 조성성분의 중량%가 선택되고, 잔여 중량%를 물로써 하여 전체 중량100% 로 구성되는 영역에서 유의미한 효과를 발휘하고,10-50% by weight of calcium chloride, 0.1-8% by weight of boric acid, 0.0005-0.01% by weight of sodium molybdate, 0.1-25% by weight of sugar, 0.1-20% by weight of polyamines (Monoethanolamine, Dimethylaminopropylamine), 0.001-0.2% by weight of uronic acid In the range of the weight percent of each composition component is selected , exhibits a significant effect in the region consisting of 100% of the total weight , with the remaining weight percent as water ,

최적의 실시예로서는 물 30.7중량%, 당류 15중량%, 특정한 폴리아민류 10 중량%, 염화칼슘 35중량%, 붕산 8중량%, 몰리브덴산나트륨 0.1중량%, 우론산 0.2중량%, 소포제 1중량%로 선택하였다.Optimal examples include 30.7 wt% water, 15 wt% sugar, 10 wt% specific polyamines, 35 wt% calcium chloride, 8 wt% boric acid, 0.1 wt% sodium molybdate, 0.2 wt% uronic acid, and 1 wt% antifoam. It was.

또 다른 최적의 실시예로서는 물 35.7중량%, 당류 15중량%, 다른 특정한 폴리아민류 5 중량%, 염화칼슘 35중량%, 붕산 8중량%, 몰리브덴산나트륨 0.1중량%, 우론산 0.2중량%, 소포제 1중량%로 선택하였다.Another optimal embodiment includes 35.7% by weight of water, 15% by weight of sugars, 5% by weight of other specific polyamines, 35% by weight of calcium chloride, 8% by weight of boric acid, 0.1% by weight of sodium molybdate, 0.2% by weight of uronic acid, 1 weight of antifoaming agent. Selected in%.

구체적인 제조방법은 물 30.7중량%에 우선 당류와 폴리아민류를 먼저 용해시켜 붕산의 용해가 용이한 상태로 만든 이후, 순차적으로 몰리브덴산나트륨, 붕산, 염화칼슘, 우론산을 투입하여 완전히 용해시킨다.In the specific manufacturing method, first, sugars and polyamines are first dissolved in 30.7% by weight of water to make the boric acid easy to dissolve, and then completely dissolved by sequentially adding sodium molybdate, boric acid, calcium chloride, and uronic acid.

따라서, 본 발명의 주요한 관점으로서는 칼슘의 흡수조력제인 붕산의 용해가 용이하도록 당류와 폴리아민류를 먼저 용해시키는 것에도 있다.Therefore, the main aspect of the present invention is to dissolve sugars and polyamines first so that boric acid, which is a calcium absorption aid, is easily dissolved.

마지막으로 혼합 및 교반, 운송과정에서의 거품을 제거하기 위하여 소포제를 첨가하여 거품을 완전히 없어질 때까지 잘 교반하여 pH6.5인 조성물을 조제하여 본 발명의 칼슘의 흡수와 영양경로에서의 이동성을 증대시킨 액상비료조성물을 조성한다.Finally, the antifoaming agent is added to remove the foam during mixing, stirring and transportation, and the mixture is stirred well until the foam disappears completely to prepare a composition having a pH of 6.5. An increased liquid fertilizer composition is formed.

당류의 경우 다양한 종류의 것이 대용이 가능하였으나 올리고당이 가장 바람직한 선택이었다.In the case of saccharides, various kinds of substitutions were possible, but oligosaccharides were the most preferable choice.

폴이아민류의 종류에 따라서는 상기의 조성비가 상이하게 조절되어야 최적의 흡수 및 이동효과를 얻을 수 있었다.Depending on the type of polyamines, the above composition ratios must be controlled differently to obtain an optimum absorption and transfer effect.

[실시예 1-폴리아민의 종류1의 사용 시의 조성비][Example 1-Composition ratio at the time of use of kind 1 of polyamine]

도 1의 표로서 도시하는 바와 같이,As shown in the table of FIG. 1,

폴리아민으로서 모노에탄올아민(Monoethanolamine(C2H7NO))의 경우의 조성비는 물 30.7중량%, 당류 15중량%, 모노에탄올아민(Monoethanolamine(C2H7NO)) 10중량%, 염화칼슘 35중량%, 붕산 8중량%, 몰리브덴산나트륨 0.1중량%, 우론산 0.2중 량%, 소포제 1중량%으로 조성한 것이 바람직하였다.As a polyamine, the composition ratio of monoethanolamine (Monoethanolamine (C 2 H 7 NO)) is 30.7% by weight of water, 15% by weight of saccharides, 10% by weight of monoethanolamine (C 2 H 7 NO), and 35% by weight of calcium chloride. %, Boric acid 8% by weight, sodium molybdate 0.1% by weight, uronic acid 0.2% by weight, antifoaming agent 1% by weight is preferred.

[실시예 2-폴리아민의 종류2의 사용 시의 조성비]로 이루어진다.[Example 2- Composition ratio at the time of use of Type 2 of polyamine].

폴리아민으로서 디메틸아미노프로필아민(Dimethylaminopropylamine(C5H14N2)의 경우의 조성비는, 물 35.7중량%, 당류 15중량%, 디메틸아미노프로필아민(Dimethylaminopropylamine(C5H14N2) 5중량%, 염화칼슘 35중량%, 붕산 8중량%, 몰리브덴산나트륨 0.1중량%, 우론산 0.2중량%, 소포제 1중량%으로 조성한 것이 바람직하였다.The composition ratio in the case of dimethylaminopropylamine (C 5 H 14 N 2 ) as polyamine is 35.7% by weight of water, 15% by weight of saccharides, 5% by weight of dimethylaminopropylamine (C 5 H 14 N 2 ) , It is preferable that the composition is composed of 35% by weight of calcium chloride, 8% by weight of boric acid, 0.1% by weight of sodium molybdate, 0.2% by weight of uronic acid, and 1% by weight of an antifoaming agent.

그 조성이 도 2의 표에 도시한다.The composition is shown in the table of FIG.

[실험예 1]Experimental Example 1

상기와 같이 조성한 본 발명의 액상비료조성물을 시비하여 실험을 수행하였다.The experiment was carried out by fertilizing the liquid fertilizer composition of the present invention prepared as described above.

시비대상 작물은 딸기로 하여 본 발명의 액상비료조성물이 시비에 의한 작물의 칼슘 흡수율, 과실품질 및 과실저장력 증진 효과를 입증하기 위하여,In order to prove that the fertilizer crop is strawberry, the liquid fertilizer composition of the present invention improves calcium absorption rate, fruit quality and fruit storage capacity of the crop by fertilization,

어떠한 시비도 하지 아니한 무처리구, 종래와 같은 염화칼슘(CaO:34%) 만의 단용처리구(0.5g/L), 본 발명의 액상비료조성물을 각각 1.0g/L, 2.0g/L로 희석하여 엽면살포한 결과 도 3의 표, 도 4의 표, 도 5의 그래프도, 도 6의 사진과 같은 결과를 얻었다.Untreated, no fertilization, conventional single-use treatment of calcium chloride (CaO: 34%) only (0.5 g / L), the liquid fertilizer composition of the present invention diluted 1.0 g / L, 2.0 g / L, respectively Results The same results as in the photograph of FIG. 6 were obtained from the table of FIG. 3, the table of FIG. 4, and the graph of FIG. 5.

도표 및 사진에서와 같이, 시비하지 아니한 무처리구, 종래와 같은 염화칼슘(CaO:34%) 만의 단용처리구(0.5g/L), 본 발명의 액상비료조성물을 각각 1.0g/L, 2.0g/L로 희석한 시비군의 관찰결과,As shown in the diagrams and photographs, untreated fertilizers were not fertilized, conventionally treated single-use treatments (0.5 g / L) of calcium chloride (CaO: 34%) and liquid fertilizer compositions of the present invention were 1.0 g / L and 2.0 g / L, respectively. Observation of diluted fertilization group,

본 발명의 액상비료조성물을 시비한 쪽이, 잎의 밀도, 과실중량, 당도, 산도, 과중 등의 대부분의 항목에서 향상율을 보이고 있다.Fertilizing the liquid fertilizer composition of the present invention shows the improvement rate in most items, such as leaf density, fruit weight, sugar content, acidity, overweight.

도 1은 본 발명의 영양경로에서의 칼슘의 흡수와 이동성을 증대시키기 액상비료조성물의 바람직한 제1실시예의 조성을 도시하는 테이블도.1 is a table showing the composition of the first preferred embodiment of the liquid fertilizer composition to increase the absorption and mobility of calcium in the nutrition pathway of the present invention.

도 2는 본 발명의 영양경로에서의 칼슘의 흡수와 이동성을 증대시키기 액상비료조성물의 바람직한 다른 제2실시예의 조성을 도시하는 테이블도.2 is a table showing the composition of another preferred second embodiment of the liquid fertilizer composition to increase the absorption and mobility of calcium in the nutrition pathway of the present invention.

도 3은 본 발명의 영양경로에서의 칼슘의 흡수와 이동성을 증대시키기 액상비료조성물을 실험적으로 시비한 성적표의 테이블도.Figure 3 is a table of transcripts experimentally fertilized liquid fertilizer composition to increase the absorption and mobility of calcium in the nutrition pathway of the present invention.

도 4는 본 발명의 영양경로에서의 칼슘의 흡수와 이동성을 증대시키기 액상비료조성물을 실험적으로 시비한 성적표의 테이블도.Figure 4 is a table of transcripts experimentally fertilized liquid fertilizer composition to increase the absorption and mobility of calcium in the nutrition pathway of the present invention.

도 5는 본 발명의 영양경로에서의 칼슘의 흡수와 이동성을 증대시키기 액상비료조성물을 실험적으로 시비하여 얻은 과실 부패율의 그래프도.Figure 5 is a graph of the fruit decay rate obtained by experimental fertilization of the liquid fertilizer composition to increase the absorption and mobility of calcium in the nutrition pathway of the present invention.

도 6은 본 발명의 영양경로에서의 칼슘의 흡수와 이동성을 증대시키기 액상비료조성물을 실험적으로 시비하여 얻는 실험 대상구의 사진이다.Figure 6 is a photograph of the experimental subject sphere obtained by experimental fertilization of the liquid fertilizer composition to increase the absorption and mobility of calcium in the nutrition pathway of the present invention.

Claims (5)

삭제delete 칼슘의 흡수, 이동의 조력제로서 붕산을 사용하고, 상기 붕산의 용해제로서 당류와 폴리아민류를 채용하여 조성한 액상비료조성물에 있어서;A liquid fertilizer composition comprising boric acid as an aid for absorption and transfer of calcium, and a saccharide and a polyamine as a dissolving agent for boric acid; 상기 액상비료조성물은, 염화칼슘 10-50중량%, 붕산 0.1-8중량%, 몰리브덴산나트륨 0.0005-0.01중량%, 올리고당 0.1-25중량%, 폴리아민류(Monoethanolamine, Dimethylamino propylamine)의 어느 하나의 0.1-20중량%, 우론산 0.001-0.2중량% . 의 범위에서 각 조성성분의 중량%가 선택되고, 잔여 중량%를 물로써 하여 전체 중량100% 로 구성되는 조성물의 하나인 것 을 특징으로 하는 칼슘의 흡수와 영양경로에서의 이동성을 증대시킨 액상비료조성물.The liquid fertilizer composition is 10-50% by weight of calcium chloride, 0.1-8% by weight of boric acid, 0.0005-0.01% by weight of sodium molybdate, 0.1-25% by weight of oligosaccharides , 0.1-any one of polyamines (Monoethanolamine, Dimethylamino propylamine) 20% by weight, uronic acid 0.001-0.2% by weight. The weight percent of each component is selected in the range of, and the liquid fertilizer to increase the absorption and mobility in the nutrient path, characterized in that it is one of the composition consisting of 100% by weight of the remaining weight% as water. Composition. 칼슘의 흡수, 이동의 조력제로서 붕산을 사용하고, 상기 붕산의 용해제로서 당류와 폴리아민류를 채용하여 조성한 액상비료조성물에 있어서;A liquid fertilizer composition comprising boric acid as an aid for absorption and transfer of calcium, and a saccharide and a polyamine as a dissolving agent for boric acid; 상기 액상비료조성물은, 폴리아민류로서 모노에탄올아민(Monoethanolamine(C2H7NO))를 선택하는 경우에는,When the liquid fertilizer composition selects monoethanolamine (C 2 H 7 NO) as polyamines, 상기 액상비료조성물의 조성은 물 30.7중량%, 올리고당 15중량% 이며, 모노에탄올아민(Monoethanolamine(C2H7NO)) 10중량%, 염화칼슘 35중량%, 붕산 8중량%, 몰리브덴산나트륨 0.1중량%, 우론산 0.2중량%, 소포제 1중량%로 한 것을 특징으로 하는 영양경로에서의 칼슘의 흡수와 이동성을 증대시키기 액상비료조성물.The composition of the liquid fertilizer composition is 30.7% by weight of water, 15% by weight of oligosaccharide, 10% by weight of monoethanolamine (C 2 H 7 NO), 35% by weight of calcium chloride, 8% by weight of boric acid, 0.1% of sodium molybdate A liquid fertilizer composition for increasing the absorption and mobility of calcium in the nutritional route, characterized in that%, uronic acid 0.2% by weight, antifoam 1% by weight. 칼슘의 흡수, 이동의 조력제로서 붕산을 사용하고, 상기 붕산의 용해제로서 당류와 폴리아민류를 채용하여 조성한 액상비료조성물에 있어서;A liquid fertilizer composition comprising boric acid as an aid for absorption and transfer of calcium, and a saccharide and a polyamine as a dissolving agent for boric acid; 상기 액상비료조성물의 조성은, 폴리아민류로서 디메틸아미노프로필아민(Dimethylaminopropylamine(C5H14N2)을 선택하는 경우에는,When the composition of the liquid fertilizer composition is selected as dimethylaminopropylamine (C 5 H 14 N 2 ) as polyamines, 디메틸아미노프로필아민(Dimethylaminopropylamine(C5H14N2) 5중량%, 물 35.7중량%, 올리고당 15중량%이며,, 염화칼슘 35중량%, 붕산 8중량%, 몰리브덴산나트륨 0.1중량%, 우론산 0.2중량%, 소포제 1중량%로 한 것을 특징으로 하는 영양경로에서의 칼슘의 흡수와 이동성을 증대시키기 액상비료조성물. Dimethylaminopropylamine (C 5 H 14 N 2 ) 5% by weight, water 35.7% by weight, oligosaccharide 15% by weight , calcium chloride 35%, boric acid 8% by weight, sodium molybdate 0.1% by weight, uronic acid 0.2 A liquid fertilizer composition for increasing the absorption and mobility of calcium in the nutritional route, characterized in that the weight%, antifoam 1% by weight. 삭제delete
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KR20220152703A (en) 2021-05-10 2022-11-17 케이지케미칼 주식회사 High concentrated liquid-type fertilizer composition having suspension functions for drone spraying and method of manufacturing of the same
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JP7173584B2 (en) * 2019-12-29 2022-11-16 Ｏａｔアグリオ株式会社 Irrigation tube anti-clogging agent and fertilizer

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KR101459604B1 (en) * 2013-03-27 2014-11-07 경북대학교 산학협력단 Agent for increasing fruit sugar comtent and color comprising Sucralose
EP4188074A4 (en) * 2020-07-29 2024-09-11 Solugen Inc Methods and compositions for use in agricultural processes
KR20220152703A (en) 2021-05-10 2022-11-17 케이지케미칼 주식회사 High concentrated liquid-type fertilizer composition having suspension functions for drone spraying and method of manufacturing of the same

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