KR101045079B1 - Cosmeceutical Cosmetic Composition that Graphic is Applied - Google Patents

Abstract

The present invention relates to a functional cosmetic composition in which a water-soluble gel is made on the outside and oil-in-water (O / W) and water-in-oil (W / O) formulations are graphically imaged in the inner phase. In the functional cosmetic composition introduced, 20 to 99% by weight of the transparent essence phase is contained in the outer phase, and 1 to 80% by weight of the water-in-oil type (W / O) and oil-in-water type (O / W) emulsion is contained in the inner phase. By providing a graphic skin care and makeup cosmetic composition characterized in that the water-soluble transparent essence containing a large amount of moisturizing ingredients contained in a water-in-oil type foundation or a large amount of active ingredients exhibiting the effect of wrinkles, whitening, moisturizing The oil-in-water formulations are visually differentiated by graphic images in the form of twists, spheres, swirls, DNA structures, etc. By the action of the functional ingredients it is possible to prepare a functional cosmetic composition excellent in effect.

Description

Cosmeceutical Cosmetic Composition that Graphic is Applied}

The present invention relates to a functional cosmetic composition in which a water-soluble gel is made on the outside and an oil-in-water (O / W) and water-in-oil (W / O) formulations are imaged graphically. Preferably, oil-in-water type foundation or make-up base and water-in-oil-type formulations containing a large amount of active ingredients exhibiting wrinkles, whitening, and moisturizing effects on water-soluble transparent essences containing a large amount of moisturizing ingredients are twisted, spear (sphere) The present invention relates to a functional cosmetic composition having excellent effects due to the action of functional ingredients.

The present invention relates to a functional cosmetic composition incorporating graphics, and more specifically, to a water-soluble transparent essence containing a large amount of moisturizing ingredients as a trauma and to a water-in-oil type (W / O) or oil-in-water type (O / W) formulations. It is visually differentiated by graphic image in the shape of swirl, DNA structure, twist, sphere, etc., and relates to a functional cosmetic composition excellent in effect by containing a large amount of functional ingredients.

 In the current cosmetic formulation technology, the stabilization of unstable active ingredients (Vitaimn A, C, E), etc. (Korean Patent, 10-0417874-0000) is mainly dominated by the development of formulation, visually differentiated and effective formulation The situation is spurring on.

 Examples of formulation visual differentiation include powder-like compositions containing functional ingredients (Korean patent 10-0502646-0000), granulation of cleansing cosmetics (Korean patent 10-0741824-0000), two-layer emulsifying cleansing cosmetics (Korean Patent 10-0869155-0000) and a convergent cosmetic having a puff shape (Korean Patent 10-0730321-0000).

 As can be seen from the above example, there are not many studies that visually differentiate in makeup and skin care, and there are problems that are difficult to differentiate.

 In addition, as a way of differentiating graphically, formulations graphicized on transparent gels using liquid crystals and waxes have been developed, but they have been limited to specific products due to the drawback of using stickiness and functional ingredients. As such, various formulation technologies for skin care and make-up that can make a formulation and visual differentiation have been demanded. Therefore, the researchers have developed a necessity for research on functional cosmetic development with graphics that can be developed not only for skin care but also for makeup products. It became.

 Currently, cosmetics are considered to be important in efficacy and effect, and as such, they are being researched in the way of visual differentiation.

 Advanced stabilization techniques are required to image the water-in-oil (W / O) or submerged (O / W) formulations graphically on a transparent essence.

 When the O / W formulation is graphicized on a transparent essence, both formulations are water-dispersible, so the two formulations cannot be mixed at a high temperature (40,50 ° C). When the formulation is graphicized, it is better to maintain the two formulations at a higher temperature (40,50 ℃) than the oil-in-water type, but bubbles are generated at the contact of the two formulations, or an oil-in-water (W / O) formulation. This separation phenomenon occurs, and the product cannot be commercialized in appearance.

Accordingly, the present invention has been proposed to solve the conventional problems as described above, the object of the present invention is to make the transparent essence phase as an outer phase in the oil-in-water type (W / O), water-in-oil type (O / W) Emulsions of) can be stably graphically imaged, and the active ingredients contained in the inner phase are formulated into liposomes with excellent percutaneous absorption model to provide excellent skin care and makeup compositions.

To achieve these and other advantages and in accordance with the purpose of the present invention,

In the functional cosmetic composition introduced graphics,

It is characterized by containing 20 to 99% by weight of the transparent essence phase as the external phase, and 1 to 80% by weight of the water-in-oil type (W / O) and oil-in-water type (O / W) emulsion.

According to the present invention, a water-in-oil type foundation or a makeup base and a water-in-oil type formulation containing a large amount of active ingredients exhibiting wrinkles, whitening, and moisturizing effects on water-soluble transparent essences containing a large amount of moisturizing ingredients are twisted and speared into the inner box. (sphere), swirl (swirl), such as the structure of the DNA is imaged graphically differentiated, it is possible to provide a functional cosmetic composition with excellent effect by the action of the functional ingredients.

Preferred embodiments according to the present invention configured as described above will be described in detail with reference to the accompanying drawings. In the following description of the present invention, detailed descriptions of well-known functions or configurations will be omitted if it is determined that the detailed description of the present invention may unnecessarily obscure the subject matter of the present invention. In addition, terms to be described below are terms defined in consideration of functions in the present invention, which may vary according to intention or precedent of a user or an operator, and thus, the meaning of each term should be interpreted based on the contents throughout the present specification. will be.

Figure 1 is an exemplary view of the shape of the graphic employed in the present invention, Figure 2 is a stability according to the temperature of the graphic of the inner phase of the water-in-water type (O / W) according to Examples 1 to 3 and Comparative Example 1 of the present invention It is a figure which shows a result, FIG. 3 is a figure which shows the stability result with the temperature of the graphic which makes an inner phase the water-in-oil type (W / O) according to Examples 4-6 and Comparative Example 2 of this invention.

 The present invention is a transparent essence as a trauma and the image of a water-in-oil type (W / O), oil-in-water type (O / W) formulation as a graphic image in the form of swirl, DNA sphere, sphere, etc. Formulating formulations to ensure stability at high temperatures when graphic formulations of the inner phase in the transparent essence, 20 to 99% by weight of the transparent essence of the outer phase in the total composition, water-in-oil (W / O), underwater It is characterized by a cosmetic composition containing 1 to 80% by weight of the type (O / W) formulation. As described above in more detail the present invention.

 The transparent essence used in the present invention is shown in the formulation example as a conventional carbomer or cellulose as a thickener, and the transparent essence is used in the total composition 20 to 99% by weight, but preferably 40 to 80% by weight Use If the amount is less than 20% by weight, the transparent image of the trauma is invisible and only the inner image that draws the graphic exists, and the visual image of the graphic does not appear. It is not desirable to not draw it.

 The oil-in-water type (O / W) formulation used in the present invention may be prepared by containing an oil as an inner phase and a moisturizing agent with water, a surfactant, and a physiologically active ingredient according to the solubility of the inner and outer phases. Most importantly, the thickener is used in the oil phase, and 0.1 to 5.0% by weight of the total O / W formulation content is used, preferably 0.5 to 2.0% by weight.

 As an oil thickener, disteadimonium hectorite, stearalconium hectorite, quaternium-18 bentonite may be used alone or in combination of two or more thereof.

 The bioactive active ingredient and oil in the oil-in-water (O / W) emulsion formulation may contain 2 to 30% by weight based on the total weight of the oil-in-water (O / W) emulsion formulation, preferably in oil-in-water (O / W) emulsion formulation. W) It is good to contain 5 to 20% by weight based on the total weight of the emulsion formulation, but its type and content can be adjusted depending on the purpose and case.

 The oils used in the present invention are selected from animal, vegetable, synthetic, silicone oils and mixtures thereof. More specifically, caprylic / capric triglyceride, cetylethylhexanoate, octyldodecanol, macadamia seed oil, meadowfoam seed oil, jojoba seed oil, hydrogenated polydecene, dimethicone, cyclomethicone You may also use squalane, mineral oil, etc.

 The bioactive active ingredients may be selected from the group consisting of vitamins A, C, E, collagen, ceramide, peptides, adenosine, arbutin, hyaluronic acid and chondroitin sulfate as those exhibiting moisturizing effect, wrinkle improvement, and whitening effect.

 The physiologically active ingredients are formulated with liposomes with excellent skin penetration effects in order to exhibit excellent efficacy.

Liposomes containing the physiologically active ingredient to promote transdermal absorption include 1 to 5% by weight of hydrogenetirescithin, 0.1 to 4% by weight of polyglyceryl-6polyricinoleate, phytosterol 1 based on the total weight of liposomes. ~ 4% by weight, 1-10% by weight of 1,3-butylene glycol, 0.5-30% by weight of bioactive active ingredient, 1-10% by weight of caprylic / capric triglycerides, and 37-95.4% by weight of purified water It is preferable to contain.

 As a moisturizer, 1.3 or less butylene glycol, glycerin, dipropylene glycol, hyaluronic acid, etc. may be used alone or in mixture of two or more kinds, and may contain 2 to 20% by weight of the total oil-in-water (O / W) formulation content. It may be preferably contained 5 to 15% by weight.

In addition, the water-in-oil type (W / O) formulation used in the present invention may be prepared by containing a moisturizing agent and water as the inner phase, a surfactant and an oil component as the outer phase, and a physiologically active active ingredient according to the solubility of the inner and outer phases. have. The most important thing in water-in-oil (W / O) formulations is the use of thickeners in the oil phase. Use 0.1 to 10% by weight of the total water-in-oil (W / O) formulations, preferably 0.5 to 5% by weight. use.

As an oil thickener, disteadimonium hectorite, stearalconium hectorite, quaternium-18 bentonite may be used alone or in combination of two or more thereof. The active ingredient and the oil in the formulation may contain 2 to 40% by weight of the total water-in-oil (W / O) formulation content, preferably 5 to 30% by weight of the total weight, but the type and content of the And in some cases adjustable.

The types of active ingredients, oils and moisturizers are the same as the oil-in-water type (O / W).

The surfactant used in the oil-in-water (O / W) formulation may contain 0.1 to 8% by weight of the total content, preferably 1 to 4% by weight. Surfactants that can be used include polysorbate 80, polysorbate 60, sorbitan sesquioleate, glyceryl stearate, fiji-100 stearate, cetearyl olivate, sorbitan oleate, arachidyl alcohol , Behenyl alcohol, arachidyl glucoside, polyglyceryl-3 methylglucose distearate alone or in combination of two or more thereof.

The surfactant used in the water-in-oil type (W / O) formulation may contain 0.5 to 5% by weight of the total content, preferably 1 to 3% by weight. Surfactants that can be used include cetyl-fiji / fiji-10 / 1 dimethicone, fiji-9 polydimethylsiloxyethyldimethicone, sorbitan oleate, and sebum / fiji-10 / 3 oleyl It is used alone or as a mixture of two or more kinds.

In addition, the water-in-oil type (W / O) formulations may use inorganic pigments, pearls, etc. for the purpose of makeup, may contain 0.1 to 15% by weight of the total content, preferably 0.5 to 10% by weight.

Types of pigments that can be used include titanium dioxide, zinc oxide, mica, talc, iron oxide, and organic pigments alone or in combination of two or more.

Next, an embodiment of the present invention configured as described above will be described in more detail. The following examples are intended to facilitate the understanding of the present invention and do not limit the scope of the present invention. The numerical value of each component used in the present Example means weight%.

[Prescription Example 1] Preparation of Transparent Essence of Trauma

[Table 1] is a transparent essence used in the external wound when drawing graphics, carbomer, hydroxyethyl cellulose was increased to prepare an essence consisting of a moisturizer, fragrance, preservatives were used in all graphic products. The composition ratio of the composition is weight percent.

[Prescription Example 2] Active ingredient liposome

[Prescription Example 2] is a liposomes of the active ingredient in order to promote transdermal absorption, and in order to make the liposome size constant by cycling twice at a pressure of 1000 bar using a microfludizer, the size is 100 ~. Prepared at 300 nm.

[Examples 3 to 6] Preparation of oil-in-water (O / W) emulsion

Table 3 summarizes the component ratios of the oil-in-water type (O / W) composition of the inner phase for drawing graphics to be used as examples and comparative examples of the present invention to prepare an emulsion according to a conventional manufacturing method. The composition ratio of each composition is weight%.

[Prescription 7 ~ 10] Preparation of water-in-oil (W / O) emulsion

Table 4 summarizes the component ratios of the water-in-oil type (W / O) composition as an inner phase for drawing graphics to be used as examples and comparative examples of the present invention, to prepare an emulsion according to a conventional manufacturing method. The composition ratio of each composition is weight%.

[Examples 1 to 3 and Comparative Example 1] Graphic cosmetic preparation of oil-in-water type (O / W)

<Table 5> summarizes the composition ratio of the oil-in-water type (O / W) graphically as an example and comparative example for the present invention. The composition ratio of each composition is weight%.

The method for producing a graphic cosmetic product containing 60% by weight of Formulation Example 1 and 40% by weight of Formulation Examples 3 to 6 as an external wound prepares a transparent essence of the external wound and contains a physiologically active ingredient or the physiologically active ingredient. To prepare liposomes, using the prepared physiologically active ingredient or liposomes, an oil-in-water emulsion and an oil-in-water emulsion mixed with an oil thickener are prepared, respectively, the prepared transparent essence of the external wound, and the oil-in-water emulsion or oil-in-water emulsion of the inner phase After the emulsion was filled in each container, the graphic was completed through a graphic machine using a multi-nozzle under the conditions of a pressure of 3 Kg / m ² and a nozzle inner diameter of 2φ. The shape of the graphic used is twist, sphere (sphere), swirl (swirl), DNA structure, and Figure 1 shows a picture of the cosmetics painted graphics.

 [Examples 4 to 6 and Comparative Example 2] Preparation of graphic cosmetics in water-in-oil type (W / O)

<Table 6> summarizes the composition ratio of the water-in-oil type (W / O) emulsion in the examples and comparative examples of the present invention. The composition ratio of each composition is weight%.

60% by weight of the transparent essence of Formulation Example 1, the manufacturing method and the graphic shape of the graphic cosmetics containing the formulations 7 to 10 in 40% by weight of the inner wound is the same as the water-in-oil type (W / O) shown in FIG.

Test Example 1 Stability of Graphic Cosmetics According to Temperature

In order to measure the temperature stability of the graphic cosmetics prepared in Examples 1 to 6 and Comparative Examples 1 to 2 using an incubator (incubator, sanyo, MIR-153, japan) 4 ℃, cycling (-5 ℃ ~ 40 ℃, 2 cycle) stability was measured at 40 ° C. The measurement was performed for 8 weeks through visual observation, and Examples 1 to 3 and Comparative Example 1 used spheres in graphic shapes, and Examples 4 to 6 and Comparative Example 2 used swirl shapes. It was.

O = no change

Δ = change over time

x = separation and severe change

Relative evaluation and storage at room temperature by, and the results are shown in Tables 7 and 8 below.

In the comparative experiments of the stability of the temperature of Examples 1 to 3 and Comparative Example 1 of Table 7 showed much better stability in the examples using the oil thickener, the stability test image is shown in FIG.

In the comparative experiments of the stability of the Examples 4 to 6 and Comparative Example 2 according to the temperature of Table 8, the stability of the water-in-oil type (W / O) formulations using the oil thickener was also excellent, and the image is shown in FIG. Indicated.

Test Example 2 Shock Stability

The impact stability of Examples 1 to 6 and Comparative Examples 1 and 2 was carried out, and the graphic cosmetics filled in a 50 ml container were measured using a method of dropping three times at a height of 70 cm covered with two layers of rubber plates.

O = no change in appearance

Δ = slight graphic distortion

x = graphics are completely distorted

It was evaluated by, and the results are shown in Table 9.

As can be seen from the results of Table 9, it showed excellent impact stability in the embodiments of the present invention.

As described above, the present invention is a cosmetic in which the water-soluble gel is made as an external wound and the oil-in-water (O / W) and water-in-oil (W / O) emulsions are graphically imaged in the inner phase. It is an invention of the cosmetic that can be used as a skin care and make-up, which ensures the impact stability, and also contains an active ingredient and has functions such as wrinkle improvement, moisturizing, and whitening. It has not only an effect but also a visually superior advantage.

In other words, according to an embodiment of the present invention, the transparent essence phase is made into an outer box, and the oil-in-water type (W / O) and the water-in-oil type (O / W) emulsions can be stably graphic imaged therein. The active ingredients contained in are formulated with liposomes of a model that has excellent percutaneous absorption, so that it is possible to provide a skin care and makeup composition having excellent efficacy.

Although the above has been described as being limited to the preferred embodiment of the present invention, the present invention is not limited thereto and various changes, modifications, and equivalents may be used. Therefore, the present invention can be applied by appropriately modifying the above embodiments, it will be obvious that such application also belongs to the scope of the present invention based on the technical idea described in the claims below.

1 is an exemplary view of the shape of the graphic employed in the present invention;

2 is a view showing the stability results according to the temperature of the graphic according to Examples 1 to 3 and Comparative Example 1 of the present invention, the inner phase of the oil-in-water type (O / W), and

Figure 3 is a view showing the stability results according to the temperature of the graphic of the inner phase of the water-in-oil type (W / O) according to Examples 4 to 6 and Comparative Example 2 of the present invention.

Claims (7)

In the functional cosmetic composition introduced graphics, 20 to 99% by weight of the transparent essence phase as an external phase, 1 to 80% by weight of water-in-oil (W / O), oil-in-water (O / W) emulsion, The water-in-oil type (W / O), oil-in-water type (O / W) emulsion includes an oil thickener, The oil thickener is a skin care and makeup cosmetic composition in a graphic form, characterized in that at least one selected from disteadimonium hectorite, stearalconium hectorite, quaternium-18 bentonite and disteadimonium hectorite. delete The method of claim 1, The oil-in-water (O / W) emulsion formulation contains an oil in the inner phase, a moisturizer, water, a surfactant and a bioactive active ingredient in the outer phase, The water-in-oil (W / O) emulsion formulation is a cosmetic composition, characterized in that it contains a moisturizing agent and water in the inner phase, and contains a surfactant, an oil component and a physiologically active ingredient in the outer phase. Preparing a transparent essence of the trauma; Preparing a liposome containing the bioactive active ingredient or the bioactive active ingredient; Preparing an oil-in-water emulsion and an oil-in-water emulsion, each of which contains an oil thickener, using the prepared bioactive active ingredient or liposome; After filling the prepared transparent transparent essence of the outer phase and the oil-in-water emulsion or water-in-oil emulsion in the inner phase of each vessel, the pressure is 3 kg / ㎡, the nozzle inside diameter of 2 φ using a multiple nozzle to complete the graphic step Method for producing a skin care and makeup cosmetic composition in a graphic form according to claim 1. 5. The method of claim 4, The graphic is a method of producing a cosmetic composition, characterized in that to have one of the form of twist, sphere (swirl), swirl (swirl), and DNA structure. The method of claim 3, The bioactive active ingredient is a cosmetic composition, characterized in that selected from the group consisting of vitamins A, C, E, collagen, ceramide, peptide, adenosine, arbutin, hyaluronic acid, chondroitin sulfate. The method of claim 3, The bioactive active ingredient is formulated as liposomes, Liposomes containing the physiologically active ingredient, based on the total weight of the liposomes 1 to 5% by weight of hydrogenetiresitchin, 0.1 to 4% by weight of polyglyceryl-6 polyricinoleate, 1 to 4% by weight of phytosterol, 1 to 10% by weight of 1,3-butylene glycol, 0.5 to 30% by weight of bioactive active ingredient, 1 to 10% by weight of caprylic / capric triglyceride, and 37 to 95.4% by weight of purified water Cosmetic composition to be.

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