KR101035112B1 - 스프레이 코팅법 및 자외선 경화법을 이용한 직물 및 이의 제조방법 - Google Patents
스프레이 코팅법 및 자외선 경화법을 이용한 직물 및 이의 제조방법 Download PDFInfo
- Publication number
- KR101035112B1 KR101035112B1 KR1020090009914A KR20090009914A KR101035112B1 KR 101035112 B1 KR101035112 B1 KR 101035112B1 KR 1020090009914 A KR1020090009914 A KR 1020090009914A KR 20090009914 A KR20090009914 A KR 20090009914A KR 101035112 B1 KR101035112 B1 KR 101035112B1
- Authority
- KR
- South Korea
- Prior art keywords
- flame retardant
- weight
- fabric
- spray coating
- parts
- Prior art date
Links
- 238000005507 spraying Methods 0.000 title claims abstract description 38
- 239000000835 fiber Substances 0.000 title description 5
- 239000003063 flame retardant Substances 0.000 claims abstract description 111
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 claims abstract description 110
- 239000004744 fabric Substances 0.000 claims abstract description 93
- 238000001723 curing Methods 0.000 claims abstract description 52
- 238000004519 manufacturing process Methods 0.000 claims abstract description 25
- 238000006243 chemical reaction Methods 0.000 claims abstract description 23
- 239000007788 liquid Substances 0.000 claims abstract description 23
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 claims abstract description 22
- 229910052698 phosphorus Inorganic materials 0.000 claims abstract description 22
- 239000011574 phosphorus Substances 0.000 claims abstract description 22
- 239000002270 dispersing agent Substances 0.000 claims abstract description 21
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 claims abstract description 19
- 239000000178 monomer Substances 0.000 claims abstract description 19
- 239000003431 cross linking reagent Substances 0.000 claims abstract description 18
- 239000003085 diluting agent Substances 0.000 claims abstract description 18
- 238000003848 UV Light-Curing Methods 0.000 claims abstract description 15
- 229920005906 polyester polyol Polymers 0.000 claims abstract description 9
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims abstract description 7
- 238000000034 method Methods 0.000 claims description 48
- 230000008569 process Effects 0.000 claims description 19
- 238000001035 drying Methods 0.000 claims description 10
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 8
- 238000000576 coating method Methods 0.000 claims description 8
- 239000012956 1-hydroxycyclohexylphenyl-ketone Substances 0.000 claims description 6
- 235000010290 biphenyl Nutrition 0.000 claims description 6
- 239000004305 biphenyl Substances 0.000 claims description 6
- 125000006267 biphenyl group Chemical group 0.000 claims description 6
- MQDJYUACMFCOFT-UHFFFAOYSA-N bis[2-(1-hydroxycyclohexyl)phenyl]methanone Chemical compound C=1C=CC=C(C(=O)C=2C(=CC=CC=2)C2(O)CCCCC2)C=1C1(O)CCCCC1 MQDJYUACMFCOFT-UHFFFAOYSA-N 0.000 claims description 6
- 229910052757 nitrogen Inorganic materials 0.000 claims description 6
- 229920002113 octoxynol Polymers 0.000 claims description 6
- ZUOUZKKEUPVFJK-UHFFFAOYSA-N phenylbenzene Natural products C1=CC=CC=C1C1=CC=CC=C1 ZUOUZKKEUPVFJK-UHFFFAOYSA-N 0.000 claims description 6
- 239000011248 coating agent Substances 0.000 claims description 5
- 239000007921 spray Substances 0.000 claims description 5
- 238000002156 mixing Methods 0.000 claims description 4
- 150000002829 nitrogen Chemical class 0.000 claims description 4
- 238000012545 processing Methods 0.000 abstract description 16
- 238000005406 washing Methods 0.000 description 10
- 238000003763 carbonization Methods 0.000 description 9
- 239000000779 smoke Substances 0.000 description 9
- 239000000758 substrate Substances 0.000 description 9
- 239000012224 working solution Substances 0.000 description 7
- 239000000243 solution Substances 0.000 description 5
- 238000003618 dip coating Methods 0.000 description 4
- VFHVQBAGLAREND-UHFFFAOYSA-N diphenylphosphoryl-(2,4,6-trimethylphenyl)methanone Chemical compound CC1=CC(C)=CC(C)=C1C(=O)P(=O)(C=1C=CC=CC=1)C1=CC=CC=C1 VFHVQBAGLAREND-UHFFFAOYSA-N 0.000 description 4
- 238000003672 processing method Methods 0.000 description 4
- 230000000052 comparative effect Effects 0.000 description 3
- 230000009977 dual effect Effects 0.000 description 3
- 238000013007 heat curing Methods 0.000 description 3
- QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 description 3
- 229910052753 mercury Inorganic materials 0.000 description 3
- 229910052751 metal Inorganic materials 0.000 description 3
- 239000002184 metal Substances 0.000 description 3
- 229910001507 metal halide Inorganic materials 0.000 description 3
- 150000005309 metal halides Chemical class 0.000 description 3
- MCONGYNHPPCHSD-UHFFFAOYSA-N 3-dimethoxyphosphoryl-n-(hydroxymethyl)propanamide Chemical compound COP(=O)(OC)CCC(=O)NCO MCONGYNHPPCHSD-UHFFFAOYSA-N 0.000 description 2
- 235000010724 Wisteria floribunda Nutrition 0.000 description 2
- 230000008901 benefit Effects 0.000 description 2
- 230000008859 change Effects 0.000 description 2
- 238000007598 dipping method Methods 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 238000009501 film coating Methods 0.000 description 2
- 239000007888 film coating Substances 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 230000000704 physical effect Effects 0.000 description 2
- 229920005862 polyol Polymers 0.000 description 2
- 150000003077 polyols Chemical class 0.000 description 2
- 238000009987 spinning Methods 0.000 description 2
- 238000009281 ultraviolet germicidal irradiation Methods 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- ARJMTSLMOKRKPM-UHFFFAOYSA-N C(C=C)(=O)O.C(C=C)(=O)O.C(C=C)(=O)O.N=C=O Chemical compound C(C=C)(=O)O.C(C=C)(=O)O.C(C=C)(=O)O.N=C=O ARJMTSLMOKRKPM-UHFFFAOYSA-N 0.000 description 1
- 239000004640 Melamine resin Substances 0.000 description 1
- 229920000877 Melamine resin Polymers 0.000 description 1
- VCUFZILGIRCDQQ-KRWDZBQOSA-N N-[[(5S)-2-oxo-3-(2-oxo-3H-1,3-benzoxazol-6-yl)-1,3-oxazolidin-5-yl]methyl]-2-[[3-(trifluoromethoxy)phenyl]methylamino]pyrimidine-5-carboxamide Chemical compound O=C1O[C@H](CN1C1=CC2=C(NC(O2)=O)C=C1)CNC(=O)C=1C=NC(=NC=1)NCC1=CC(=CC=C1)OC(F)(F)F VCUFZILGIRCDQQ-KRWDZBQOSA-N 0.000 description 1
- 239000006057 Non-nutritive feed additive Substances 0.000 description 1
- YACTZEZVNPAVGJ-UHFFFAOYSA-N P.C(=O)(O)C=C.C(=O)(O)C=C.C(=O)(O)C=C Chemical compound P.C(=O)(O)C=C.C(=O)(O)C=C.C(=O)(O)C=C YACTZEZVNPAVGJ-UHFFFAOYSA-N 0.000 description 1
- 229910019142 PO4 Inorganic materials 0.000 description 1
- JAWMENYCRQKKJY-UHFFFAOYSA-N [3-(2,4,6,7-tetrahydrotriazolo[4,5-c]pyridin-5-ylmethyl)-1-oxa-2,8-diazaspiro[4.5]dec-2-en-8-yl]-[2-[[3-(trifluoromethoxy)phenyl]methylamino]pyrimidin-5-yl]methanone Chemical compound N1N=NC=2CN(CCC=21)CC1=NOC2(C1)CCN(CC2)C(=O)C=1C=NC(=NC=1)NCC1=CC(=CC=C1)OC(F)(F)F JAWMENYCRQKKJY-UHFFFAOYSA-N 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- -1 bis-methacryloyl oxyethyl phosphate Chemical compound 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- 230000015556 catabolic process Effects 0.000 description 1
- 239000003054 catalyst Substances 0.000 description 1
- 239000008199 coating composition Substances 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 238000006731 degradation reaction Methods 0.000 description 1
- 230000006866 deterioration Effects 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 238000005265 energy consumption Methods 0.000 description 1
- 230000001747 exhibiting effect Effects 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 238000007654 immersion Methods 0.000 description 1
- 231100000053 low toxicity Toxicity 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 239000011259 mixed solution Substances 0.000 description 1
- 150000002903 organophosphorus compounds Chemical class 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 239000010452 phosphate Substances 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 229920005749 polyurethane resin Polymers 0.000 description 1
- 238000012805 post-processing Methods 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 230000002265 prevention Effects 0.000 description 1
- 238000003908 quality control method Methods 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
- 230000002194 synthesizing effect Effects 0.000 description 1
- 239000012209 synthetic fiber Substances 0.000 description 1
- 229920002994 synthetic fiber Polymers 0.000 description 1
- 239000004753 textile Substances 0.000 description 1
- 150000004684 trihydrates Chemical class 0.000 description 1
- 239000002023 wood Substances 0.000 description 1
- 238000004383 yellowing Methods 0.000 description 1
Images
Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/68—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with phosphorus or compounds thereof, e.g. with chlorophosphonic acid or salts thereof
- D06M11/70—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with phosphorus or compounds thereof, e.g. with chlorophosphonic acid or salts thereof with oxides of phosphorus; with hypophosphorous, phosphorous or phosphoric acids or their salts
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06B—TREATING TEXTILE MATERIALS USING LIQUIDS, GASES OR VAPOURS
- D06B1/00—Applying liquids, gases or vapours onto textile materials to effect treatment, e.g. washing, dyeing, bleaching, sizing or impregnating
- D06B1/02—Applying liquids, gases or vapours onto textile materials to effect treatment, e.g. washing, dyeing, bleaching, sizing or impregnating by spraying or projecting
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M10/00—Physical treatment of fibres, threads, yarns, fabrics, or fibrous goods made from such materials, e.g. ultrasonic, corona discharge, irradiation, electric currents, or magnetic fields; Physical treatment combined with treatment with chemical compounds or elements
- D06M10/001—Treatment with visible light, infrared or ultraviolet, X-rays
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
- D06M13/345—Nitriles
- D06M13/348—Nitriles unsaturated, e.g. acrylonitrile
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/21—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/347—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of unsaturated ethers, acetals, hemiacetals, ketones or aldehydes
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
- D06M2200/30—Flame or heat resistance, fire retardancy properties
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S57/00—Textiles: spinning, twisting, and twining
- Y10S57/904—Flame retardant
Landscapes
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
- Chemical Or Physical Treatment Of Fibers (AREA)
Abstract
Description
구 분 |
탄화거리(㎝) | 연기밀도(%) |
세탁 수축율(%) | ||
세탁 전 | 세탁 후 | 경사 | 위사 | ||
실시예 1 | 8 | 17 | 30 | 3 | 1 |
비교예 1 | 10 | 30 | 50 | 6 | 3 |
Claims (10)
- 방염 직물에 있어서,방염 가공액은 방염제, 반응 희석제, 가교제, 광개시제, 분산제로 이루어지는데, 상기 방염 가공액 100 중량부에 대하여 자외선 경화형 인계 방염제 20 내지 40 중량부, 반응 희석제 30 내지 70 중량부, 가교제 1 내지 7 중량부, 광개시제 1 내지 5 중량부 및 분산제 0.1 내지 0.5 중량부가 혼합된 스프레이 코팅법 및 자외선 경화법을 이용한 방염직물.
- 제1항에 있어서,상기 자외선 경화형 인계 방염제는 하이드록시기 2~40개와 인을 포함하는 분자량 200~4000인 폴리에스테르 폴리올(Polyester Polyol) 50 내지 80 중량%와 다관능성 (메타)아크릴레이트 모노머 20 내지 50 중량%의 반응하여 제조된 것을 특징으로 하는 스프레이 코팅법 및 자외선 경화법을 이용한 방염직물.
- 제1항에 있어서,상기 반응 희석제는 다관능성 (메타)아크릴레이트 모노머의 형태 및 상기 가교제는 질소계 다관능성 (메타)아크릴레이트 모노머 형태인 것을 특징으로 하는 스프레이 코팅법 및 자외선 경화법을 이용한 방염직물.
- 제1항에 있어서,상기 광개시제 및 분산제는 각각 1-하이드록시사이클로헥실페닐케톤과 디페닐(2,4,6-트리메틸벤조힐)-포스핀옥사이드를 중량비 4:1로 혼합한 광개시제 및 Triton-X 100을 이용한 분산제인 것을 특징으로 하는 스프레이 코팅법 및 자외선 경화법을 이용한 방염직물.
- 방염직물의 제조방법에 있어서,방염 가공액 100 중량부에 대하여 자외선 경화형 인계 방염제 20 내지 40 중량부, 반응 희석제 30내지 70 중량부, 가교제 1 내지 7 중량부, 광개시제 1 내지 5 중량부, 분산제 0.1 내지 0.5 중량부를 혼합한 방염 가공액을 제조하는 단계;상기 방염 가공액을 직물에 코팅하는 스프레이 코팅단계;상기 스프레이 코팅된 직물을 적외선 램프에 의해 건조하는 건조단계; 및상기 건조된 직물을 자외선 경화기로 경화시키는 자외선 경화단계를 포함하는 스프레이 코팅법 및 자외선 경화법을 이용한 방염직물의 제조방법.
- 제5항에 있어서,상기 건조단계에서는 적외선 영역 내에서 80 내지 100℃로 1분 내지 2분간 건조하는 것을 특징으로 하는 스프레이 코팅법 및 자외선 경화법을 이용한 방염직물의 제조방법.
- 제5항에 있어서,상기 자외선 경화단계에서는 중고압식 램프가 일렬로 놓인 경화기로 0.6 내지 2.4 J/㎠의 조사에너지로 경화하는 자외선 경화법을 이용한 방염직물의 제조 방법.
- 제5항에 있어서,상기 자외선 경화형 인계 방염제는 하이드록시기 2~40개와 인을 포함하는 분자량 200~4000인 폴리에스테르 폴리올(Polyester Polyol) 50 내지 80 중량%와 다관능성 (메타)아크릴레이트 모노머 20 내지 50 중량%의 반응하여 제조된 것을 특징으로 하는 스프레이 코팅법 및 자외선 경화법을 이용한 방염직물의 제조방법.
- 제5항에 있어서,상기 반응 희석제는 다관능성 (메타)아크릴레이트 모노머의 형태 및 상기 가교제는 질소계 다관능성 (메타)아크릴레이트 모노머 형태인 것을 특징으로 하는 스프레이 코팅법 및 자외선 경화법을 이용한 방염직물의 제조방법.
- 제5항에 있어서,상기 광개시제 및 분산제는 각각 1-하이드록시사이클로헥실페닐케톤과 디페닐(2,4,6-트리메틸벤조힐)-포스핀옥사이드를 중량비 4:1로 혼합한 광개시제 및 Triton-X 100을 이용한 분산제인 것을 특징으로 하는 스프레이 코팅법 및 자외선 경화법을 이용한 방염직물의 제조방법.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
KR1020090009914A KR101035112B1 (ko) | 2009-02-06 | 2009-02-06 | 스프레이 코팅법 및 자외선 경화법을 이용한 직물 및 이의 제조방법 |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
KR1020090009914A KR101035112B1 (ko) | 2009-02-06 | 2009-02-06 | 스프레이 코팅법 및 자외선 경화법을 이용한 직물 및 이의 제조방법 |
Publications (2)
Publication Number | Publication Date |
---|---|
KR20100090566A KR20100090566A (ko) | 2010-08-16 |
KR101035112B1 true KR101035112B1 (ko) | 2011-05-19 |
Family
ID=42756117
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
KR1020090009914A KR101035112B1 (ko) | 2009-02-06 | 2009-02-06 | 스프레이 코팅법 및 자외선 경화법을 이용한 직물 및 이의 제조방법 |
Country Status (1)
Country | Link |
---|---|
KR (1) | KR101035112B1 (ko) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
KR101234044B1 (ko) | 2010-09-15 | 2013-02-15 | 웅진케미칼 주식회사 | 투습성이 뛰어난 자외선 경화형 투습방수 원단 및 이의 제조방법 |
Families Citing this family (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN105615073B (zh) * | 2014-12-01 | 2017-07-14 | 嘉兴晟合衬布有限公司 | 经编衬纬印花复合服装材料的生产方法及服装材料 |
CN112921640B (zh) * | 2021-02-01 | 2022-07-29 | 石狮锦亮织带有限公司 | 一种阻燃织带的制备方法 |
KR102640713B1 (ko) * | 2023-10-12 | 2024-02-29 | 주식회사 유진레이블 | 항알러지, 항균 및 소취성을 가지는 기능성 매트리스 제조방법 및 그에 의하여 제조되는 항알러지, 항균 및 소취성을 가지는 기능성 매트리스 |
KR102676614B1 (ko) * | 2023-12-12 | 2024-06-19 | 주식회사 브랜뉴머시너리 | Ppf 코팅 시스템 및 그 방법 |
Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH11100419A (ja) | 1997-09-26 | 1999-04-13 | Jsr Corp | 放射線硬化性樹脂組成物 |
US20050209357A1 (en) | 2003-12-02 | 2005-09-22 | Jigeng Xu | Flame retardant radiation curable compositions |
JP2006274106A (ja) | 2005-03-30 | 2006-10-12 | Taiyo Ink Mfg Ltd | 紫外線硬化型樹脂組成物、及びその硬化塗膜 |
KR20090072518A (ko) * | 2007-12-28 | 2009-07-02 | (주)디피아이 홀딩스 | 인을 포함하는 불포화 폴리에스터 수지의 제조방법 및난연성 도료 |
-
2009
- 2009-02-06 KR KR1020090009914A patent/KR101035112B1/ko active IP Right Grant
Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH11100419A (ja) | 1997-09-26 | 1999-04-13 | Jsr Corp | 放射線硬化性樹脂組成物 |
US20050209357A1 (en) | 2003-12-02 | 2005-09-22 | Jigeng Xu | Flame retardant radiation curable compositions |
JP2006274106A (ja) | 2005-03-30 | 2006-10-12 | Taiyo Ink Mfg Ltd | 紫外線硬化型樹脂組成物、及びその硬化塗膜 |
KR20090072518A (ko) * | 2007-12-28 | 2009-07-02 | (주)디피아이 홀딩스 | 인을 포함하는 불포화 폴리에스터 수지의 제조방법 및난연성 도료 |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
KR101234044B1 (ko) | 2010-09-15 | 2013-02-15 | 웅진케미칼 주식회사 | 투습성이 뛰어난 자외선 경화형 투습방수 원단 및 이의 제조방법 |
Also Published As
Publication number | Publication date |
---|---|
KR20100090566A (ko) | 2010-08-16 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
KR101035112B1 (ko) | 스프레이 코팅법 및 자외선 경화법을 이용한 직물 및 이의 제조방법 | |
Ma et al. | Construction of intumescent flame retardant and hydrophobic coating on wood substrates based on thiol-ene click chemistry without photoinitiators | |
Ren et al. | Flame retardant polyacrylonitrile fabrics prepared by organic-inorganic hybrid silica coating via sol-gel technique | |
Kundu et al. | Construction of flame retardant coating on polyamide 6.6 via UV grafting of phosphorylated chitosan and sol–gel process of organo-silane | |
Liu et al. | Multifunctional flame-retarded and hydrophobic cotton fabrics modified with a cyclic phosphorus/polysiloxane copolymer | |
Wang et al. | Durable flame retardant finishing of cotton fabrics with organosilicon functionalized cyclotriphosphazene | |
Cheng et al. | Synthesis of a reactive boron-based flame retardant to enhance the flame retardancy of silk | |
WO2017118619A1 (en) | Fiber reinforced polymer composite material and preparation method thereof | |
Onar et al. | Development of water-, oil-repellent and flame-retardant cotton fabrics by organic-inorganic hybrid materials | |
Kim et al. | Synergistic UV-curable flame-retardant finish of cotton using comonomers of vinylphosphonic acid and acrylamide | |
CN107177979A (zh) | 一种无熔滴阻燃涤纶纤维/织物及其制备方法 | |
Rui et al. | Construction of nano-multilayer coatings on copolyester fabrics using UV-grafting mediated layer-by-layer self-assembly for improved anti-droplet and flame retardent performance | |
Mulge et al. | Phosphorus-containing reactive agent for UV-curable flame-retardant wood coating | |
Dou et al. | Study on curing and flammability properties of UV-curable flame-retardant coating on jute/polypropylene composites surface | |
Zhang et al. | Fabrication of a highly-efficient phosphorus-silicon-containing transparent coating to improve fire safety of poly (methyl methacrylate) | |
CN103526552A (zh) | 一种基于光固化法织物拒水拒油整理方法 | |
Li et al. | The application of a phosphorus nitrogen flame retardant curing agent in epoxy resin | |
Jiang et al. | A novel synthesis of ditrimethylolpropane biphosphoramide diethyleneamine as flame retardant and antistatic textiles | |
KR20100042157A (ko) | 자외선 경화법을 이용한 방염가공 면직물 및 이의 제조방법 | |
Tang et al. | Formaldehyde-free and durable phosphorus-containing cotton flame retardant with-N= P-(N) 3-and reactive ammonium phosphoric acid groups | |
KR101068270B1 (ko) | Uv 경화형 투습방수용 우레탄 아크릴레이트 조성물 및 이를 이용한 섬유의 가공 처리방법 | |
KR101072914B1 (ko) | 자외선 경화형 인계 단량체를 이용한 직물의 방염가공 | |
KR101255033B1 (ko) | 표면처리코팅용 친수성 폴리우레탄 수지의 제조방법 | |
CN108978224B (zh) | 一种赋予纺织品多功能的整理剂的制备方法及整理方法 | |
CN109281154B (zh) | 一种纺织品阻燃剂及其制备方法 |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
A201 | Request for examination | ||
E701 | Decision to grant or registration of patent right | ||
GRNT | Written decision to grant | ||
FPAY | Annual fee payment |
Payment date: 20140512 Year of fee payment: 4 |
|
FPAY | Annual fee payment |
Payment date: 20150508 Year of fee payment: 5 |
|
FPAY | Annual fee payment |
Payment date: 20160509 Year of fee payment: 6 |
|
FPAY | Annual fee payment |
Payment date: 20170502 Year of fee payment: 7 |
|
FPAY | Annual fee payment |
Payment date: 20180531 Year of fee payment: 8 |
|
FPAY | Annual fee payment |
Payment date: 20190430 Year of fee payment: 9 |