KR100920958B1 - Guide plate like a antique and its manufacturing method - Google Patents

Guide plate like a antique and its manufacturing method Download PDF

Info

Publication number
KR100920958B1
KR100920958B1 KR1020090026443A KR20090026443A KR100920958B1 KR 100920958 B1 KR100920958 B1 KR 100920958B1 KR 1020090026443 A KR1020090026443 A KR 1020090026443A KR 20090026443 A KR20090026443 A KR 20090026443A KR 100920958 B1 KR100920958 B1 KR 100920958B1
Authority
KR
South Korea
Prior art keywords
guide plate
copper
copper plate
plate
manufacturing
Prior art date
Application number
KR1020090026443A
Other languages
Korean (ko)
Inventor
이기범
Original Assignee
가남테크 주식회사
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by 가남테크 주식회사 filed Critical 가남테크 주식회사
Priority to KR1020090026443A priority Critical patent/KR100920958B1/en
Application granted granted Critical
Publication of KR100920958B1 publication Critical patent/KR100920958B1/en

Links

Images

Classifications

    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C22/00Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals
    • C23C22/05Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C22/00Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals
    • C23C22/73Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals characterised by the process
    • C23C22/76Applying the liquid by spraying
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C22/00Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals
    • C23C22/78Pretreatment of the material to be coated
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C22/00Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals
    • C23C22/82After-treatment
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C22/00Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals
    • C23C22/82After-treatment
    • C23C22/84Dyeing
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23FNON-MECHANICAL REMOVAL OF METALLIC MATERIAL FROM SURFACE; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL; MULTI-STEP PROCESSES FOR SURFACE TREATMENT OF METALLIC MATERIAL INVOLVING AT LEAST ONE PROCESS PROVIDED FOR IN CLASS C23 AND AT LEAST ONE PROCESS COVERED BY SUBCLASS C21D OR C22F OR CLASS C25
    • C23F1/00Etching metallic material by chemical means
    • C23F1/10Etching compositions
    • C23F1/14Aqueous compositions
    • C23F1/16Acidic compositions
    • C23F1/18Acidic compositions for etching copper or alloys thereof
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23FNON-MECHANICAL REMOVAL OF METALLIC MATERIAL FROM SURFACE; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL; MULTI-STEP PROCESSES FOR SURFACE TREATMENT OF METALLIC MATERIAL INVOLVING AT LEAST ONE PROCESS PROVIDED FOR IN CLASS C23 AND AT LEAST ONE PROCESS COVERED BY SUBCLASS C21D OR C22F OR CLASS C25
    • C23F1/00Etching metallic material by chemical means
    • C23F1/10Etching compositions
    • C23F1/14Aqueous compositions
    • C23F1/32Alkaline compositions
    • C23F1/34Alkaline compositions for etching copper or alloys thereof

Abstract

PURPOSE: An antique copper guide plate and a manufacturing method thereof are provided to offer unusual visual impressions with good match of cultural assets, a site and major inspection request, and etc by offering antique feeling on the copper guide plate. CONSTITUTION: A manufacturing method of an antique copper guide plate includes the following steps of: manufacturing a copper plate to a guide plate shape; removing foreign material of the copper plates by injecting compressed air the sand particles on the surface of the guide plate; forming a corrosion groove by etching a graphic or a letter on the surface of the guide plate; oxidizing the surface of the copper plate; forming a protective layer by applying inorganic paint on the surface of the guide plate; heating the guide plate at a temperature of 120~140°C; filling the paint on the corrosion groove of the guide plate; and heating the guide plate at a temperature of 120~140°C.

Description

고품 느낌의 동판 안내판 및 그 제작방법 {Guide plate like a antique and its manufacturing method}High quality copper plate guide plate and its manufacturing method {Guide plate like a antique and its manufacturing method}

본 발명은 문화재, 유적지 및 주요 사찰 등의 정보를 기록하여 관람자에게 그 내용을 안내하는 안내판에 관한 것으로서 특히, 오래된 문화재와 어울리도록 안내판도 시각적으로 오랜 세월이 흐른 고품의 느낌이 들게끔 동판을 가공하여 제작한 고품(古品) 느낌의 동판 안내판 및 그 제작방법에 관한 것이다.The present invention relates to a guide plate that records information such as cultural assets, historical sites and major temples, and guides the contents to viewers. In particular, the guide plate also processes copper plates so that they feel visually old and old to match the old cultural assets. It relates to a copper plate guide plate of the old-fashioned feeling and the method of manufacturing the same.

일반적으로 문화재, 유적지 또는 주요 사찰 등의 상세한 정보를 관람자에게 전달하기 위하여 문화재에 대한 상세한 정보가 기록된 안내판을 설치 제공하고 있다.In general, in order to convey detailed information such as cultural properties, historical sites or major temples to the viewers, information boards with detailed information on cultural properties are provided.

상기와 같은 안내판은 일반적으로 스텐레스 스틸 재질의 금속판의 표면을 에칭액으로 부식시켜 그래픽 또는 문자열의 홈을 형성하고, 상기 홈에 페인트를 충전시켜 안내판을 구성하였는데, 이러한 종래의 스테인레스 스틸 재질의 안내판은 녹이 슬지 않고 재료비가 저렴한 장점이 있는 반면에, 문화재, 유적지 또는 주요 사찰 등의 오래된 문화재의 안내판과 잘 어울리지 못하는 문제점이 있다.Such a guide plate generally corrodes the surface of a metal plate made of stainless steel with an etching solution to form a groove of a graphic or string, and fills the groove with paint to form a guide plate. While there is an advantage that the material cost is not sad and cheap, there is a problem that does not fit well with the information board of old cultural assets such as cultural assets, historical sites or main temples.

본 발명은 상기와 같은 문제점을 해결하기 위하여 안출한 것으로서, 문화재, 유적지 또는 주요 사찰등의 정보를 안내하는 안내판이 오랜 세월을 거친 고품(古品)의 느낌이 들도록 가공 성형함으로써 오래된 문화재와 잘 어울릴 수 있는 안내판과 그 제조방법을 제공하는 것이 본 발명의 목적이다.The present invention has been made in order to solve the above problems, the guide plate for guiding information such as cultural properties, historical sites or major temples to work well with the old cultural assets by forming and processing so that the feeling of old products through the ages It is an object of the present invention to provide a guide plate and a method of manufacturing the same.

상기의 목적을 달성하기 위하여 본 발명에 의한 고품 느낌의동판 안내판 제조방법은 동판을 절단, 절곡 및 용접 성형하여 안내판의 형태로 제조하는 용접단계와; 상기 안내판의 표면에 모래입자를 압축공기와 함께 분사하여 동판 표면의 이물지을 제거하는 스크래칭 단계와; 상기 안내판의 표면에 그래픽 또는 문자의 형태로 에칭하여 부식홈을 형성하는 에칭단계와; 상기 안내판을 산화액에 담궈 동판의 표면을 산화부식시키는 산화발색 단계와; 상기 안내판의 표면에 무기질 도료를 도포하여 보호층을 형성하는 표면도장 단계와; 상기 안내판을 120~140℃의 온도에서 40~60분 동안 가열하는 제1열처리 단계와; 상기 안내판의 부식홈에 에나멜 계열의 페인트를 충전하는 충전단계와; 상기 안내판을 120~140℃의 온도에서 40~60분간 가열하는 제2열처리 단계;로 구성된다.In order to achieve the above object, the manufacturing method of the copper plate guide plate of the high-quality impression according to the present invention includes a welding step of manufacturing the guide plate by cutting, bending and welding the copper plate; A scratching step of spraying sand particles on the surface of the guide plate together with compressed air to remove foreign substances on the surface of the copper plate; Etching to form a groove on the surface of the guide plate in the form of a graphic or letter; An oxidation-coloring step of immersing the guide plate in an oxidizing solution to oxidatively corrode the surface of the copper plate; A surface coating step of applying an inorganic paint on the surface of the guide plate to form a protective layer; A first heat treatment step of heating the guide plate at a temperature of 120 to 140 ° C. for 40 to 60 minutes; A filling step of filling enamel-based paint in the corrosion groove of the guide plate; And a second heat treatment step of heating the guide plate at a temperature of 120 to 140 ° C. for 40 to 60 minutes.

이때, 상기 산화발색 단계의 산화액은, 질산철(Fe(NO3)2·6H20) 10~70중량%, 질산구리(Cu(NO3)2) 10~70중량% 및 유화가리(K2S) 10~70중량%를 혼합하고, 상기 혼합액 30~70중량%와 물 30~70중량%를 혼합하여 구성된다.At this time, the oxidation solution of the oxidation-coloring step, iron nitrate (Fe (NO 3 ) 2 · 6H 2 0) 10-70% by weight, copper nitrate (Cu (NO 3 ) 2 ) 10-70% by weight and emulsified ( K 2 S) 10-70% by weight is mixed, and 30-70% by weight of the mixed solution and 30-70% by weight of water are configured.

또한, 상기 산화발색 단계는, 산화액과 안내판을 60℃의 온도까지 가열한 후, 안내판을 산화액에 담궈 산화시킨다.In addition, the oxidation-coloring step, after heating the oxidizing solution and the guide plate to a temperature of 60 ℃, the guide plate is immersed in the oxidizing solution to oxidize.

또한, 상기 산화발색 단계는, 안내판을 산화액에 담궈 산화시킨 후 산화액을 안내판 표면에 스프레이 분사하거나, 산화액을 수세미 또는 거친 천으로 안내판 표면에 불규칙하게 문지르는 것이 바람직하다.In addition, in the oxidation-coloring step, it is preferable to immerse the guide plate in the oxidizing solution and then oxidize the spray to spray the oxidizing solution on the guide plate surface, or to rub the oxidizing solution on the guide plate surface irregularly with a scrubber or a rough cloth.

또한, 상기 표면도장 단계의 무기질 도료는 우레탄 계열의 도료인 것이 바람직하다.In addition, the inorganic coating of the surface coating step is preferably a urethane-based paint.

그리고, 본 발명에 의한 고품 느낌의 부식홈이 형성된 동판은 상부에 부식층이 형성되고, 상기 부식층의 상부에는 보호층이 형성되며, 상기 부식홈에는 다양한 색상의 페인트가 충전되어 구성된다.In addition, the copper plate formed with a high-quality feeling of the corrosion groove according to the present invention, a corrosion layer is formed on the upper portion, a protective layer is formed on the upper portion of the corrosion layer, the corrosion groove is composed of a paint of various colors.

상기와 같이 구성된 본 발명은 안내판의 표면이 오랜 세월동안 산화부식된 것처럼 보이기 때문에 오랜 세월을 지나온 문화재, 유적지 또는 주요 사찰 등의 문화재 안내판으로 잘 어울려 관람객에서 색다른 시각적 효과를 전달할 수 있다.According to the present invention configured as described above, since the surface of the guide plate appears to be oxidized and corroded for a long time, it may be well matched with a cultural property guide plate, such as a cultural property, a historic site, or a main temple, which has passed through many years, thereby delivering a different visual effect from a visitor.

이하 본 발명에 의한 고품 느낌의 동판 안내판 및 그 제작방법에 대하여 상세히 설명한다.Hereinafter, the copper plate guide plate of the high-quality impression according to the present invention and a manufacturing method thereof will be described in detail.

도 1은 본 발명에 의한 동판 제조 단계를 도시한 공정도이고, 도 2는 본 발명에 의해 가공된 동판의 단면도이며, 도 3은 본 발명에 의한 안내판의 사시도이다.1 is a process chart showing the copper plate manufacturing step according to the present invention, Figure 2 is a cross-sectional view of the copper plate processed by the present invention, Figure 3 is a perspective view of the guide plate according to the present invention.

본 발명에 의한 고품 느낌의 동판 안내판의 제작방법은 도 1에 도시한 바와 같이 용접단계, 스크래칭 단계, 에칭 단계, 산화발색 단계, 표면 도장 단계, 제1열처리 단계, 충전 단계 및 제2열처리 단계로 구성된다.The manufacturing method of the high quality copper plate guide plate according to the present invention is as shown in Figure 1 welding step, scratching step, etching step, oxidation coloration step, surface coating step, the first heat treatment step, the filling step and the second heat treatment step It is composed.

우선, 1.5~2.0㎜ 두께의 동판(110)을 절단 및 절곡 성형하고, 이를 용접하여 안내판의 형상을 제조하는 용접단계를 실시한다. 일반적으로 동판(110)을 용접할 때 동판(110)의 용접부위가 휘어지는 현상이 발생하는데, 이를 방지하기 위하여 동판(110)의 용접 접합부위를 충분히 예열한 후, 동-은(Cu-Ag)계열의 환봉을 가열하고 붕소를 묻힌 후 산소용접을 함으로써 동판(110)이 용접할 때 휘는 것을 방지하도록 한다.First, the copper plate 110 having a thickness of 1.5 to 2.0 mm is cut and bent, and a welding step of manufacturing the shape of the guide plate is performed by welding the copper plate 110. In general, when welding the copper plate 110, the welded portion of the copper plate 110 is bent, in order to prevent this, after sufficiently preheating the welded joint of the copper plate 110, Cu-Ag By heating the round bar of the series and buried boron oxygen welding to prevent the copper plate 110 is bent when welding.

상기와 같이 용접단계를 통해 동판(110)을 절단 및 굴곡하고 접합하여 안내판으로 가공한 후, 동판(110)의 표면을 스크래칭하는 스크래칭 단계를 실시한다.As described above, the copper plate 110 is cut, bent and bonded through a welding step, and then processed into a guide plate, and a scratching step of scratching the surface of the copper plate 110 is performed.

상기 스크래칭 단계는 동판(110) 표면의 먼지와 이물질을 제거하고, 용접단계를 거치며 동판(110)의 표면에 잔류하는 용접 이물질을 연마기로 제거하며, 고운 모래를 압축공기와 함께 동판(110)의 표면에 분사하여 표면에 잔류하는 이물질을 깨끗이 제거하고, 이후 동판(110)의 표면에 형성될 산화피막층이 더욱 잘 형성되도 록 한다.The scratching step removes dust and foreign matter from the surface of the copper plate 110, removes the welding foreign matter remaining on the surface of the copper plate 110 with a polishing machine through a welding step, and fine sand of the copper plate 110 together with compressed air. By spraying on the surface to remove the foreign matter remaining on the surface, and then to the oxide film to be formed on the surface of the copper plate 110 is better formed.

상기 스크래칭 단계를 통해 동판(110) 표면의 이물질이 제거된 안내판에 미리 준비된 디자인대로 그래픽 또는 문자의 형태대로 에칭(Etching)하여 안내판에 부식홈(150)을 형성하는 에칭단계를 실시한다. 에칭단계에서 사용되는 에칭액은 일반적으로 널리 사용되는 동판 에칭액을 사용한다.Through the scratching step, an etching step of forming a corrosion groove 150 in the guide plate is performed by etching (Getching) in the form of a graphic or a letter according to a design prepared in advance on the guide plate from which foreign substances on the surface of the copper plate 110 are removed. The etchant used in the etching step generally uses copper plate etchant which is widely used.

상기 에칭단계를 통해 부식홈(150)이 형성된 동판(110)을 산화부식시켜 부식층(120)을 형성함으로써 오래된 고품(古品)의 안내판 느낌이 들도록 하는 산화발색 단계를 실시한다.Through the etching step, the copper plate 110 in which the corrosion grooves 150 are formed is oxidized and corroded to form the corrosion layer 120.

산화발색 단계는 질산철(Fe(NO3)2·6H2O) 10~70중량%, 질산구리(Cu(NO3)2) 10~70중량% 및 유화가리(K2S) 10~70중량%를 혼합하여 준비하고, 상기 혼합된 혼합액 30~70중량%와 물 30~70중량%를 혼합하여 산화액을 준비한다. 상기와 같은 비율로 질산철, 질산구리, 유화가리 및 물을 혼합하여 구성한 산화액으로 동판(110)을 산화시켰을 때 오래된 동판의 색상과 가장 비슷하고 자연스럽게 동판(110)이 산화 부식되어 부식층(120)이 형성되는 것이다.Oxidation color development step is 10 to 70% by weight of iron nitrate (Fe (NO 3 ) 2 · 6H 2 O), 10 to 70% by weight of copper nitrate (Cu (NO 3 ) 2 ) and 10 ~ 70 emulsified glass (K 2 S) The mixture is prepared by mixing by weight%, 30 to 70% by weight of the mixed mixture and 30 to 70% by weight of water to prepare an oxidizing solution. When the copper plate 110 is oxidized with an oxidizing solution formed by mixing iron nitrate, copper nitrate, emulsified glass and water in the same ratio as described above, the copper plate 110 is most similar to the color of the old copper plate. ) Is formed.

그리고, 상기 산화액 및 동판(110)을 약 50~70℃의 온도까지 가열한 후, 동판(110)을 산화액에 담구어 동판(110) 표면을 산화시킨다. 이때, 동판(110)과 산화액을 50~70℃의 온도까지 가열하는 이유는 상기 온도에서 동판(110)과 산화액의 부식반응이 활성화되어 발색이 잘 이루어지기 때문이다. 바람직하게는 60℃의 온도로 산화액과 동판(110)을 가열하는 것이 부식반응을 활성화 시킨다.Then, after the oxidizing solution and the copper plate 110 is heated to a temperature of about 50 ~ 70 ℃, the copper plate 110 is immersed in the oxidizing solution to oxidize the surface of the copper plate 110. At this time, the reason for heating the copper plate 110 and the oxidizing solution to a temperature of 50 ~ 70 ℃ is because the corrosion reaction of the copper plate 110 and the oxidizing solution is activated at the above temperature is well formed. Preferably, heating the oxidation liquid and the copper plate 110 to a temperature of 60 ℃ to activate the corrosion reaction.

상기와 같이 동판(110)을 산화액에 담구면 동판(110)의 표면이 균일하게 갈색을 띄게 되는데, 이때, 수세미나 거친 천 등을 이용하여 표면을 불규칙하게 문지르면서 자연상태에서 부식이 일어난 느낌이 들도록 가공한다. 그리고, 동판(110)을 자연건조한 후, 동판(110)을 50~70℃로 가열하고 산화액을 스프레이 분사함으로써, 동판의 표면을 불균일하게 부식시켜 오랜 세월동안 자연에서 자연스럽게 부식된 것처럼 보이도록 한다.When the copper plate 110 is immersed in the oxidizing solution as described above, the surface of the copper plate 110 is uniformly browned. At this time, the surface of the copper plate 110 is rubbed with a scouring pad or a rough cloth, and the corrosion occurs in a natural state. It is processed to lift. Then, after the copper plate 110 is naturally dried, by heating the copper plate 110 to 50 ~ 70 ℃ and spray spraying the oxidizing solution, the surface of the copper plate is unevenly corroded to look as naturally corroded in nature for many years. .

상기 산화액을 이용하여 동판(110)을 부식시키면 동판(110)의 표면이 구리빛에서 갈색으로 부식되며 발색된다.When the copper plate 110 is corroded using the oxidizing solution, the surface of the copper plate 110 is corroded to brown and colored.

상기 산화발색 단계를 통해 동판(110)의 표면에 부식층(120)이 형성된 후에 표면도장 단계를 실시한다. After the corrosion layer 120 is formed on the surface of the copper plate 110 through the oxidation-coloration step, the surface coating step is performed.

표면도장 단계는 산화발색 단계를 통해 형성된 부식층(120)을 보호하기 위하여 우레탄계열의 무기질 도료를 동판의 표면에 도포함으로써, 부식층(120) 상부에 보호층(130)을 형성하는 것이다. 우레탄 계열의 도료는 열처리를 통해 상기 에칭단계를 통해 형성된 부식홈(150)에 충진되는 에나멜 페인트(140)와 산화발색된 부식층(120) 표면의 보호를 견고하게 하기 때문에 우레탄 계열의 도료를 사용하는 것이 바람직하다.The surface coating step is to form a protective layer 130 on the corrosion layer 120 by applying a urethane-based inorganic paint on the surface of the copper plate in order to protect the corrosion layer 120 formed through the oxidation-coloration step. The urethane-based paint uses a urethane-based paint because it hardens the protection of the enamel paint 140 and the oxide-colored corrosion layer 120 filled in the corrosion groove 150 formed through the etching step through heat treatment. It is preferable.

표면도장 단계를 통해 보호층(130)이 형성된 동판(110)을 120~140℃의 온도에서 40~60분 동안 가열하는 제1열처리 단계를 실시한다. 이러한 표면도장 단계를 통하여 보호층(130)이 동판(110)과 견고하게 결속하도록 하는 것이다. 상기 열처리 단계가 만일 140℃ 온도보다 높은 온도에 이루어지면 동판(110)에 열 변형이 발생 하게 되고, 120℃ 온도보다 낮으면 열처리가 제대로 이루어지지 않기 때문에 120~140℃의 온도범위에서 열처리를 하는 것이 바람직하다.The first heat treatment step of heating the copper plate 110 having the protective layer 130 formed through the surface coating step at a temperature of 120 to 140 ° C. for 40 to 60 minutes. Through the surface coating step, the protective layer 130 is to be firmly bound with the copper plate (110). If the heat treatment step is made at a temperature higher than 140 ℃ temperature heat deformation occurs in the copper plate 110, if lower than 120 ℃ temperature heat treatment is not performed properly because the heat treatment in the temperature range of 120 ~ 140 ℃ It is preferable.

상기와 같이 제1열처리 단계를 거친 동판(110)의 음각부분인 부식홈(150)에 에나멜 계열의 페인트(140)를 충전하는 충전단계를 실시한다. 상기 부식홈(150)에 페인트(140)를 충전할 때 부식홈(150) 외부로 잘못 도색된 페인트(140)는 에나멜신너를 이용하여 닦아내는 것이 바람직한데, 종래의 알콜 또는 신너로 페인트(140)를 닦아내면 부식층(120)이 같이 닦여질 우려가 있기 때문이다.As described above, the filling step of filling the enamel-based paint 140 in the corrosion groove 150 which is the intaglio portion of the copper plate 110 which has been subjected to the first heat treatment step is performed. When the paint 140 is filled in the corrosion groove 150, the paint 140 that is incorrectly painted outside the corrosion groove 150 may be wiped off using an enamel thinner. This is because the corrosion layer 120 may be wiped together.

상기와 같이 에나멜 신너로 페인트(140)를 닦아 낼때 보호층(130)의 강도가 에나멜 페인트보다 강하기 때문에 보호층(130)과 부식층(120)이 닦여나가지 않고 그대로 남아있게 되는 것이다.When the paint 140 is wiped with the enamel thinner as described above, since the strength of the protective layer 130 is stronger than that of the enamel paint, the protective layer 130 and the corrosion layer 120 remain without being wiped off.

상기의 충전단계를 거친 동판(110) 즉, 안내판을 120~140℃의 온도에서 40~60분간 가열하는 제2열처리 단계를 통하여 부식홈(150)에 충전된 페인트(140)가 부식홈(150)에 견고하게 부착 결속되도록 한다.The paint 140 filled in the erosion grooves 150 through the second heat treatment step of heating the copper plate 110, ie, the guide plate, for 40 to 60 minutes at a temperature of 120 to 140 ° C through the filling step is the erosion grooves 150. ) To be firmly attached.

상기와 같은 여려 단계를 통해 제조된 본 발명의 동판 안내판은 문화재, 유적지 또는 주요 사찰등의 정보를 안내하는 안내판이 오랜 세월을 거친 고품(古品)의 느낌이 들도록 가공 성형함으로써 오래된 문화재와 잘 어울린다.The copper plate guide plate of the present invention manufactured through the various steps as described above is well matched with old cultural assets by processing and molding the guide plate for guiding information such as cultural assets, historical sites or major temples to have a feeling of old products that have passed through many years. .

이상, 본 발명에 의한 동판 안내판 및 그 제조방법에 대해 설명하였다. In the above, the copper guide plate and its manufacturing method which concern on this invention were demonstrated.

상기 본 발명의 기술적 구성은 본 발명이 속하는 기술분야의 당업자가 그 기술적 사상이나 필수적 특징을 변경하지 않고서 다른 구체적인 형태로 실시될 수 있 다는 것을 이해할 수 있을 것이다.The technical configuration of the present invention will be understood by those skilled in the art that the present invention can be implemented in other specific forms without changing the technical spirit or essential features.

그러므로, 이상에서 기술한 실시 예들은 모든 면에서 예시적인 것이며 한정적인 것이 아닌 것으로서 이해되어야 하고, 본 발명의 범위는 전술한 상세한 설명보다는 후술하는 특허청구범위에 의하여 나타내어지며, 특허청구범위의 의미 및 범위 그리고 그 등가 개념으로부터 도출되는 모든 변경 또는 변형된 형태가 본 발명의 범위에 포함되는 것으로 해석되어야 할 것이다.Therefore, the above-described embodiments are to be understood in all respects as illustrative and not restrictive, and the scope of the present invention is indicated by the appended claims rather than the foregoing description, and the meanings of the claims and All changes or modifications derived from the scope and equivalent concepts thereof should be construed as being included in the scope of the present invention.

도 1은 본 발명에 의한 동판 제조 단계를 도시한 공정도.1 is a process chart showing the copper plate manufacturing step according to the present invention.

도 2는 본 발명에 의해 가공된 동판의 단면도.2 is a cross-sectional view of a copper plate processed by the present invention.

도 3은 본 발명에 의한 안내판의 사시도.3 is a perspective view of a guide plate according to the present invention.

<도면의 주요 부분에 대한 부호의 설명><Explanation of symbols for the main parts of the drawings>

110 : 동판110: copper plate

120 : 부식층120: corrosion layer

130 : 보호층130: protective layer

140 : 페인트140: paint

150 : 부식홈150: corrosion groove

Claims (6)

동판을 절단, 절곡 및 용접 성형하여 안내판의 형태로 제조하는 용접단계와;A welding step of cutting, bending and welding the copper plate to manufacture the guide plate; 상기 안내판의 표면에 모래입자를 압축공기와 함께 분사하여 동판 표면의 이물질을 제거하는 스크래칭 단계와;A scratching step of spraying sand particles on the surface of the guide plate together with compressed air to remove foreign substances on the surface of the copper plate; 상기 안내판의 표면에 그래픽 또는 문자의 형태로 에칭하여 부식홈을 형성하는 에칭단계와;Etching to form a groove on the surface of the guide plate in the form of a graphic or letter; 상기 안내판을 산화액에 담궈 동판의 표면을 산화부식시키는 산화발색 단계와;An oxidation-coloring step of immersing the guide plate in an oxidizing solution to oxidatively corrode the surface of the copper plate; 상기 안내판의 표면에 무기질 도료를 도포하여 보호층을 형성하는 표면도장 단계와;A surface coating step of applying an inorganic paint on the surface of the guide plate to form a protective layer; 상기 안내판을 120~140℃의 온도에서 40~60분 동안 가열하는 제1열처리 단계와;A first heat treatment step of heating the guide plate at a temperature of 120 to 140 ° C. for 40 to 60 minutes; 상기 안내판의 부식홈에 에나멜 계열의 페인트를 충전하는 충전단계와;A filling step of filling enamel-based paint in the corrosion groove of the guide plate; 상기 안내판을 120~140℃의 온도에서 40~60분간 가열하는 제2열처리 단계;로 구성된 것을 특징으로 하는 고품 느낌의 동판 안내판 제작방법.A second heat treatment step of heating the guide plate for 40 to 60 minutes at a temperature of 120 ~ 140 ℃; manufacturing method of high quality copper plate guide. 제 1항에 있어서,The method of claim 1, 상기 산화발색 단계의 산화액은,The oxidation solution of the oxidation-coloring step, 질산철(Fe(NO3)2·6H20) 10~70중량%, 질산구리(Cu(NO3)2) 10~70중량% 및 유화가리(K2S) 10~70중량%를 혼합하고, 상기 혼합액 30~70중량%와 물 30~70중량%를 혼합하여 구성된 것을 특징으로 하는 고품 느낌의 동판 안내판 제작방법.10 to 70% by weight of iron nitrate (Fe (NO 3 ) 2 · 6H 2 0), 10 to 70% by weight of copper nitrate (Cu (NO 3 ) 2 ) and 10 to 70% by weight of emulsified glass (K 2 S) And 30-70% by weight of the mixed solution and 30-70% by weight of water. 제 2항에 있어서,The method of claim 2, 상기 산화발색 단계는,The oxidation color development step, 산화액과 안내판을 60℃의 온도까지 가열한 후, 안내판을 산화액에 담궈 산화시키는 것을 특징으로 하는 고품 느낌의 동판 안내판 제작방법.A method for producing a high quality copper plate guide plate, characterized in that the oxidizing solution and the guide plate are heated to a temperature of 60 ° C., and then the guide plate is immersed in the oxidizing liquid. 제 3항에 있어서,The method of claim 3, wherein 상기 산화발색 단계는,The oxidation color development step, 안내판을 산화액에 담궈 산화시킨 후 수세미 또는 거친 천으로 표면을 불규칙하게 문지르고, 자연건조한 후 산화액을 안내판 표면에 불규칙하게 스프레이 분사하는 것을 특징으로 하는 고품 느낌의 동판 안내판 제작방법.After immersing the guide plate in the oxidizing solution and rubbing the surface irregularly with a scrubber or coarse cloth, natural drying and then spraying the oxidizing solution irregularly sprayed on the surface of the guide plate. 제 1항에 있어서,The method of claim 1, 상기 표면도장 단계의 무기질 도료는 우레탄 계열의 도료인 것을 특징으로 하는 고품 느낌의 동판 안내판 제작방법.The inorganic coating of the surface coating step is a high-quality copper plate guide plate manufacturing method, characterized in that the urethane-based paint. 부식홈이 형성된 동판의 상부에 부식층이 형성되고, 상기 부식층의 상부에는 보호층이 형성되며, A corrosion layer is formed on an upper portion of the copper plate on which the corrosion groove is formed, and a protective layer is formed on the corrosion layer. 상기 부식홈에는 다양한 색상의 페인트가 충전되어 구성된 것을 특징으로 하는 고품 느낌의 동판 안내판.The corrugated groove is a copper plate guide plate of a high-quality impression, characterized in that the paint is filled with a variety of colors.
KR1020090026443A 2009-03-27 2009-03-27 Guide plate like a antique and its manufacturing method KR100920958B1 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
KR1020090026443A KR100920958B1 (en) 2009-03-27 2009-03-27 Guide plate like a antique and its manufacturing method

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
KR1020090026443A KR100920958B1 (en) 2009-03-27 2009-03-27 Guide plate like a antique and its manufacturing method

Publications (1)

Publication Number Publication Date
KR100920958B1 true KR100920958B1 (en) 2009-10-09

Family

ID=41572169

Family Applications (1)

Application Number Title Priority Date Filing Date
KR1020090026443A KR100920958B1 (en) 2009-03-27 2009-03-27 Guide plate like a antique and its manufacturing method

Country Status (1)

Country Link
KR (1) KR100920958B1 (en)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR101590143B1 (en) 2015-07-20 2016-01-29 (주)도시와숲 information sign board with wood and metal
KR102133841B1 (en) * 2020-02-13 2020-07-14 주식회사 가연환경디자인 Manufacturing method of a guideboard
KR20230043281A (en) * 2021-09-23 2023-03-31 이혜린 Painting processing method of corrosion metal texture

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR890016209A (en) * 1988-04-09 1989-11-28 김영철 Decorative Copper Plating Manufacturing Method
KR20020089223A (en) * 2002-08-29 2002-11-29 서상환 The process of a copper patina
KR20080105772A (en) * 2007-06-01 2008-12-04 김영희 Method for manufacturing color metallic material having oxide layer with high corrosion-resistance using etching
KR100890607B1 (en) 2007-07-02 2009-03-27 김부현 A oxidized verdigris copper manufacture method

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR890016209A (en) * 1988-04-09 1989-11-28 김영철 Decorative Copper Plating Manufacturing Method
KR20020089223A (en) * 2002-08-29 2002-11-29 서상환 The process of a copper patina
KR20080105772A (en) * 2007-06-01 2008-12-04 김영희 Method for manufacturing color metallic material having oxide layer with high corrosion-resistance using etching
KR100890607B1 (en) 2007-07-02 2009-03-27 김부현 A oxidized verdigris copper manufacture method

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR101590143B1 (en) 2015-07-20 2016-01-29 (주)도시와숲 information sign board with wood and metal
KR102133841B1 (en) * 2020-02-13 2020-07-14 주식회사 가연환경디자인 Manufacturing method of a guideboard
KR20230043281A (en) * 2021-09-23 2023-03-31 이혜린 Painting processing method of corrosion metal texture
KR102655171B1 (en) * 2021-09-23 2024-04-08 이혜린 Painting processing method of corrosion metal texture

Similar Documents

Publication Publication Date Title
US4594111A (en) Liquid phase cleaner-solvent
KR100920958B1 (en) Guide plate like a antique and its manufacturing method
CN105239129B (en) Surface treatment method of aluminum alloy product
CN101384751A (en) Composition and processes of a dry-in-place trivalent chromium corrosion-resistant coating for use on metal surfaces
CN107460465B (en) Silane treatment agent and method for producing silane treatment agent
DE3539047A1 (en) METHOD FOR DECORATING, MARKING AND ENGRAVING OR THE LIKE. OF OBJECTS WITH ENAMELED SURFACES BY LASER BEAM
CN107511312A (en) A kind of fluorocarbon-sprayed method of aluminium alloy extrusions
CN104908504B (en) Metal colored drawing board and manufacturing method thereof
JP6918797B2 (en) Stainless steel sheet with etching pattern formed and its manufacturing method
CN110227978A (en) A kind of galvanized steel sheet surface treatment process
KR101790499B1 (en) The bonded stainless steel plate and method for manufacturing thereof
CN108611639B (en) Steel sheet etching passivation surface process
CN105420719A (en) Metal plate surface blackening process
CN108890228A (en) The two-sided etching of stainless steel ruler made in Great Britain contaminates black-labour process
KR950014787B1 (en) Method and composition for ethchiny
CN105714289A (en) Tin case surface treatment process
US2367939A (en) Process for producing name plates and the like
JP6063088B1 (en) Painted metal plate
KR20060102705A (en) Elevator panel having a pattern on steel plate and manufacturing method thereof
CN111376129A (en) Multiple etching copper imitation process
CN105013682B (en) Method for paint spraying, paint spraying apparatus and the spray painting product of composite members
DE102012006763B4 (en) Method for removing coatings from carcinogenic fibers
EP1022357B1 (en) Surface treatment process for stainless steels
CN114836757A (en) Metal label manufacturing method based on etching process
Kupfer Hygric interactions with antigraffiti systems

Legal Events

Date Code Title Description
A201 Request for examination
A302 Request for accelerated examination
E902 Notification of reason for refusal
E701 Decision to grant or registration of patent right
GRNT Written decision to grant
FPAY Annual fee payment

Payment date: 20130723

Year of fee payment: 5

FPAY Annual fee payment

Payment date: 20140711

Year of fee payment: 6

FPAY Annual fee payment

Payment date: 20150713

Year of fee payment: 7

FPAY Annual fee payment

Payment date: 20160727

Year of fee payment: 8

FPAY Annual fee payment

Payment date: 20180808

Year of fee payment: 10

FPAY Annual fee payment

Payment date: 20190722

Year of fee payment: 11