KR100912673B1 - Environmentally friendly colorful high intensity color clay brikc - Google Patents

Environmentally friendly colorful high intensity color clay brikc Download PDF

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KR100912673B1
KR100912673B1 KR1020090041176A KR20090041176A KR100912673B1 KR 100912673 B1 KR100912673 B1 KR 100912673B1 KR 1020090041176 A KR1020090041176 A KR 1020090041176A KR 20090041176 A KR20090041176 A KR 20090041176A KR 100912673 B1 KR100912673 B1 KR 100912673B1
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clay
color
firing
brick
environmentally friendly
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KR1020090041176A
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전일록
현중석
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(주)선일로에스
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    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B33/00—Clay-wares
    • C04B33/02—Preparing or treating the raw materials individually or as batches
    • C04B33/04—Clay; Kaolin
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B33/00—Clay-wares
    • C04B33/02—Preparing or treating the raw materials individually or as batches
    • C04B33/13—Compounding ingredients
    • C04B33/132—Waste materials; Refuse; Residues
    • C04B33/1321—Waste slurries, e.g. harbour sludge, industrial muds
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B33/00—Clay-wares
    • C04B33/02—Preparing or treating the raw materials individually or as batches
    • C04B33/13—Compounding ingredients
    • C04B33/14—Colouring matters
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B33/00—Clay-wares
    • C04B33/32—Burning methods
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P40/00—Technologies relating to the processing of minerals
    • Y02P40/60—Production of ceramic materials or ceramic elements, e.g. substitution of clay or shale by alternative raw materials, e.g. ashes

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Ceramic Engineering (AREA)
  • Dispersion Chemistry (AREA)
  • Materials Engineering (AREA)
  • Structural Engineering (AREA)
  • Organic Chemistry (AREA)
  • Environmental & Geological Engineering (AREA)
  • Treatment Of Sludge (AREA)
  • Compositions Of Oxide Ceramics (AREA)

Abstract

A high intensity color clay brick of the environmentally friendly variety color is provided to show the various colors without adding the pigment or the other chemicals etc. A high intensity color clay brick of the environmentally friendly variety color comprises the clay of 5~65wt% in which the fire proofing rating is 800‹C~1,300‹C and includes the iron of 1~15wt%; the mixture of the kaolin 30~85wt%; and the poly-silicon waste sludge of 1~10wt%. The compositions of high intensity color clay brick of the environmentally friendly variety color are molded to the brick shape. The titanium oxide of 1~5wt% in mixture is added to show the yellow. The plasticity is performed at the temperature of 800~1,300‹C for 10~20 hours.

Description

친환경 다채색의 고강도 칼라점토벽돌{ENVIRONMENTALLY FRIENDLY COLORFUL HIGH INTENSITY COLOR CLAY BRIKC}Eco-friendly multicolored high-strength color clay bricks {ENVIRONMENTALLY FRIENDLY COLORFUL HIGH INTENSITY COLOR CLAY BRIKC}

안료나 기타 화학약품 등의 첨가없이 원토의 배합과 소성방법의 다양화를 통하여 여러 가지의 색상을 나타내며 폴리실리콘 폐슬러지를 사용하여 제품의 강도를 향상시키고 흡수율을 개선시켜 제조함으로서 자연스럽고 부드러운 색상을 가진 친환경 다채색의 고강도 칼라점토벽돌에 관한 것이다.It shows various colors through the blending of raw materials and the diversification of firing methods without adding pigments or other chemicals, and by using polysilicon waste sludge to improve the product's strength and absorption rate, it produces natural and soft colors. It relates to an eco-friendly multicolored high strength color clay brick.

일반적으로 점토벽돌의 생산은 내화도가 1,000℃ ~ 1,300℃인 황색점토, 고령토, 장석, 도석 등의 원토와 색상과 환무늬를 나타내기 위해 흑연(무연탄), 망간, 티탄 등과 특수색상을 위한 안료, 유약 등을 사용하여 물과 배합하여 성형한 후 건조시킨 제품을 산화소성시켜 제조함으로 색상이 붉은색계열, 아이보리색계열, 쵸코색계열 등을 주로 나타내고 있는바 색상이 자연스럽지 못하고 진하고 탁하거나 단순한 색상이어서 미적 감각이 많이 떨어지게 되며, 각종 발색용 특수원료를 첨가함으로서 비친환경제품이면서 제조원가가 상승하게 되는 문제가 있었다.In general, the production of clay brick is a pigment for graphite (anthracite), manganese, titanium, and special colors to show the raw material and color and ring pattern of yellow clay, kaolin, feldspar, pottery, etc. It is manufactured by mixing with water with a glaze and then molding it and then drying it to produce oxidized and fired color. The color is mainly red color, ivory color and chocolate color. Subsequently, the aesthetics deteriorate a lot, and there is a problem that the manufacturing cost increases while being an unfriendly product by adding various raw materials for coloring.

또한, 종래 대부분의 점토벽돌 제품은 일반적으로 내화도가 1,000℃ 이하의 낮은 점토원료는 강도가 약하다는 문제가 있어 사용을 기피하였다.In addition, in the past, most clay brick products generally avoid the use of low clay materials having a low fire resistance of 1,000 ° C. or less because of their weak strength.

상기 문제를 해결하고자, 본 발명은 점토벽돌 제품에서 주로 사용하는 황색점토 외의 분청토, 흑색점토, 옹기토의 내화도가 800℃ ~ 1,300℃ 사이의 점토를 혼합 사용하고, 점토의 내화도 차이에서 오는 제품의 강도를 향상시키기 위하여 태양전지 생산과정 등에서 발생되는 규소의 가수분해 과정을 통해 정제과정을 거쳐 생산되는 고순도의 다결정 분자구조체 화합물로서 발수성, 내화성, 안정성, 저온안정성 등이 우수한 폴리실리콘 슬러지(탈수케익)를 재활용하고, In order to solve the above problems, the present invention uses a mixture of clay, black clay, ong clay and other clays whose fire resistance is between 800 ° C and 1,300 ° C, mainly in clay brick products, and comes from differences in the fire resistance of clay. Polysilicon sludge (dehydration cake) with high water-repellency, fire resistance, stability and low temperature stability as a high-purity polycrystalline molecular structure compound produced through refining process through hydrolysis of silicon generated in solar cell production process to improve strength Recycle it,

소성방법을 세분화 하여 산화소성을 거친 후 도자기를 굽는 방식의 환원소성 방법을 변형하여 매 분당 2 ~ 4cm씩 서서히 이동하는 터널식 가마의 특성을 이용하여 일정시간 환원소성 후 일정시간 환원소성을 정지하여 순차적으로 소성하는 타임환원을 시간차로 적용한 후 50 ~ 70분 동안의 급냉각과 5 ~ 8시간의 서냉구간을 거침으로써 제품의 흡수율을 개선시키고, 강도를 향상시키며, 화학약품이나 부재료의 첨가 없이 제조원가를 낮추고 부드럽고, 흡수율이 우수한 고급스런 다양한 자연색상을 갖춘 친환경 다채색의 고강도 칼라점토벽돌을 제공하는 것을 발명의 목적으로 한다.The firing method is subdivided and subjected to oxidization, and then the reduction firing method of baking ceramics is changed, and by using the characteristics of the tunnel type kiln, which gradually moves by 2 ~ 4cm per minute, the reduction firing is stopped for a certain time after sequential reduction. After applying the time reduction to firing by the time difference, the product can be absorbed, the strength is improved, and the manufacturing cost can be improved without adding chemicals or subsidiary materials through the rapid cooling for 50 to 70 minutes and the slow cooling section for 5 to 8 hours. It is an object of the invention to provide an environmentally friendly, multicolored, high strength color clay brick with a variety of natural colors that are low, soft, and have excellent water absorption.

상기 목적을 달성하기 위하여, 본 발명은 철분을 1 ~ 15wt%로 함유하는 내화도가 800℃ ~ 1,300℃인 점토 5 ~ 65wt%와,In order to achieve the above object, the present invention is a clay containing a fire resistance of 800 ~ 1,300 ℃ 5 ~ 65wt% containing 1 to 15wt% iron,

고령토 30 ~ 85wt%와,Kaolin 30 ~ 85wt%,

폴리실리콘 폐슬러지 1 ~ 10wt%의 혼합물을 벽돌 형상으로 성형한 후 소성하여 다양한 색상을 발현하는 친환경 다채색의 고강도 칼라점토벽돌을 주요 기술적 구성으로 한다.Polysilicon waste sludge 1 ~ 10wt% of the mixture is molded into a brick shape and then fired to produce a variety of colors to produce a variety of colors of high-strength color clay brick as the main technical configuration.

이하, 상기의 기술적 구성에 대해 상세히 살펴보고자 한다.Hereinafter, the technical configuration will be described in detail.

본 발명에 있어 점토벽돌 제품은 일반적으로 내화도가 낮아 강도문제점 등으로 점토벽돌 제품에는 사용되지 않는 분청토, 흑색점토, 옹기토의 내화도가 800℃ ~ 1,300℃ 사이의 점토 중 선택되는 어느 1종 또는 2종 이상을 혼합 사용하고, 점토 내화도 차이에서 오는 제품의 강도를 향상시키기 위하여 태양전지 생산과정 등에서 발생되는 규소의 가수분해 과정을 통해 정제과정을 거쳐 생산되는 고순도의 다결정 분자구조체 화합물로서 발수성, 내화성, 안정성, 저온안정성 등이 우수한 폴리실리콘 폐슬러지(탈수케익)를 재활용하고, In the present invention, the clay brick product generally has a low fire resistance and any one or two selected from clays having a fire resistance of 800 to 1,300 ° C., which is not used in clay brick products due to strength problems. It is a high-purity polycrystalline molecular structure compound produced by refining process through the hydrolysis process of silicon generated in solar cell production process in order to use more than one species and to improve the strength of the product resulting from the difference in clay fire resistance. Recycle polysilicon waste sludge (dehydration cake) with excellent stability and low temperature stability,

소성방법을 세분화 하여 산화소성을 거친 후 도자기를 굽는 방식의 환원소성 방법을 변형하여 매분당 2 ~ 4㎝씩 서서히 이동하는 터널식가마의 특성을 이용하여 일정시간 환원소성 후 일정시간 환원소성을 정지하여 순차적으로 소성하는 타임환 원을 시간차로 적용한 후 50 ~ 70분의 급냉각과 5 ~ 8시간의 서냉구간을 거침으로써 제품의 흡수율을 개선시키고, 강도를 향상시키며, 화학약품이나 부재료의 첨가없이 제조원가를 낮추고 부드럽고 고급스런 다양한 자연색상을 갖춘 친환경 다채색의 고강도 칼라점토벽돌을 제조한다.The firing method is subdivided and subjected to oxidization, and then the reduction firing method of baking ceramics is modified. After applying the time reduction that is sequentially fired by the time difference, the product is absorbed, the strength is improved, and the manufacturing cost is added without the addition of chemicals or subsidiary materials through the rapid cooling for 50 to 70 minutes and the slow cooling section for 5 to 8 hours. It manufactures eco-friendly, multicolored, high-strength color clay bricks with a variety of natural colors that are soft and luxurious.

상기 점토의 철분 함유량은 1wt% 미만인 경우 붉은계열의 색상을 나타낼 수 없으며, 15wt%를 초과하게 되는 경우에는 소성시에 검게 타는 현상이 발생하게 되므로, 상기 점토는 철분을 1 ~ 15wt%의 범위 내로 함유하는 것이 바람직하다.If the iron content of the clay is less than 1wt%, it may not exhibit a reddish color, and if it exceeds 15wt%, a burning phenomenon occurs at the time of firing, the clay may contain iron in the range of 1 to 15wt%. It is preferable to contain.

상기 점토는 제품 성형시 붉은 색상이나 제품의 점력 강화를 위하여 사용하는 것으로, 그 사용량이 벽돌 전체 혼합물에 대해 5wt% 미만인 경우에는 색상이 붉게 나타나지 않거나 점력이 부족하여 제품의 강도가 약화되거나 표면이 거칠어지는 경향이 있고, 65wt%를 초과하게 되는 경우에는 제품 성형 후 건조시 갈라지는 현상이 발생하게 되므로 상기 점토는 벽돌제조를 위한 성분의 전체 혼합물에 대해 5 ~ 65wt%의 범위 내에서 사용하는 것이 바람직하다.The clay is used to reinforce the viscosity of the product or red color when molding the product, when the amount is less than 5wt% with respect to the entire brick mixture, the color does not appear red or the viscosity is weakened or the surface is rough If it exceeds 65wt%, the cracking occurs when drying after forming the product, so it is preferable to use the clay within the range of 5 to 65wt% with respect to the entire mixture of components for brick production. .

상기 고령토는 아이보리 계열의 색상을 나타내기 위하여 사용하는 것으로, 그 사용량이 벽돌 전체 혼합물에 대해 30wt% 미만인 경우에는 제품의 색상이 붉은색 계열로 많이 나타나게 되는 문제가 있고, 85wt%를 초과하게 되는 경우에는 제품의 강도나 흡수율이 떨어지고 표면이 거칠어지는 문제가 있으므로, 상기 고령토는 벽돌제조를 위한 성분의 전체 혼합물에 대해 30 ~ 85wt%의 범위 내에서 사용하는 것이 바람직하다.The kaolin is used to represent the color of the ivory series, when the amount is less than 30wt% with respect to the entire brick mixture, there is a problem that the color of the product appears a lot of red, and exceeds 85wt% Since there is a problem that the strength or absorption rate of the product and the surface is rough, the kaolin is preferably used within the range of 30 to 85wt% with respect to the entire mixture of components for brick production.

상기 폴리실리콘 폐슬러지는 제품의 강도 향상을 위해 사용하는 것으로, 그 사용량이 벽돌 전체 혼합물에 대해 1wt% 미만인 경우에는 제품의 강도가 떨어지는 문제가 있고, 10wt%를 초과하게 되는 경우에는 점토, 고령토 배합량의 감소로 인하여 원적외선 방출량 감소 등 점토벽돌 고유의 특성을 약화시키는 문제가 있으므로, 상기 폴리실리콘 폐슬러지는 벽돌제조를 위한 성분의 전체 혼합물에 대해 1 ~ 10wt의 범위 내에서 사용하는 것이 바람직하다.The polysilicon waste sludge is used to improve the strength of the product, when the amount is less than 1wt% of the total mixture of bricks, there is a problem that the strength of the product falls, when the amount exceeds 10wt% clay, kaolin mixture amount Since there is a problem of weakening the intrinsic characteristics of clay brick, such as a decrease in the amount of far-infrared emission, it is preferable to use the polysilicon waste sludge within the range of 1 to 10wt with respect to the entire mixture of components for brick production.

본 발명의 친환경 다채색의 고강도 칼라점토벽돌은 원토의 배합조건과 소성의 조건에 따라 다양한 색상을 발현하는 것으로서, 붉은색 계열의 색상으로 발색하기 위한 소성조건으로는 800 ~ 1,300℃에서 10 ~ 20시간 산화소성함으로서 목적을 달성할 수 있다.Environment-friendly multi-color high-strength color clay brick of the present invention is to express a variety of colors according to the mixing conditions and firing conditions of the raw material, the firing conditions for the color development of a red-based color 10 ~ 20 at 800 ~ 1,300 ℃ The purpose can be achieved by time oxidizing.

검정색 또는 회색의 색상으로 발색하기 위한 소성조건으로는 800 ~ 1,300℃에서 10 ~ 12시간 산화소성 후 400 ~ 500㎜Aq의 연료압력으로 150 ~ 250초의 환원소성하고, 250 ~ 400초의 환원소성 정지를 반복한 후 900 ~ 980℃에서 50 ~ 70분 동안의 급냉각과 5 ~ 8시간의 서냉구간을 거침으로써 소성로에서 불완전 연소되는 연료의 탄소성분을 점토벽돌에 흡착시켜 제품의 흡수율을 개선시키고, 강도를 향상시키며 검정색 또는 회색으로 발색된다.The firing conditions for color development in black or gray color are 150 ~ 250 seconds reduction firing at 400 ~ 500mmAq fuel pressure after 10-12 hours oxidation at 800 ~ 1,300 ℃, and 250 ~ 400 seconds reduction firing stop. After repeated repetition, rapid cooling for 50 to 70 minutes and slow cooling section for 5 to 8 hours at 900 to 980 ° C allow carbon components of incompletely burned fuel to be adsorbed to clay bricks to improve product absorption and strength. Improves color and develops in black or grey.

상기 환원소성시 급냉온도가 900℃ 미만인 경우에는 냉파현상으로 벽돌이 깨어지는 문제점이 있으며, 980℃를 초과하게 되는 경우에는 냉각시키게 되면 색상이 어둡고 탁해지게 되는 문제점이 있으므로 900℃ ~ 980℃의 범위 내에서 급냉시키는 것이 바람직하다. 그리고, 급냉각 시간이 50분 미만이거나 70분을 초과하게 되는 경우에는 냉각에 의해 강도가 떨어지고 색상이 어두워져서 탁하게 되는 문제가 있으므로, 50분 ~ 70분 이내로 급냉각 시키는 것이 바람직하다. 또한 환원소성의 가동과 정지를 반복함으로서 검정색과 회색이 교차되거나 혼합된 색상을 나타내게 된다. When the quenching temperature during reduction is less than 900 ℃, there is a problem that the brick breaks due to cold phenomena, and when it exceeds 980 ℃, the color becomes dark and turbid when cooled, so the range of 900 ℃ ~ 980 ℃ It is preferable to quench the inside. In addition, when the quenching time is less than 50 minutes or more than 70 minutes, there is a problem that the strength is lowered due to cooling and the color becomes dark and turbid, so that the rapid cooling within 50 minutes to 70 minutes is preferable. In addition, by repeating the starting and stopping of the reducing firing, black and gray may cross or show mixed colors.

노란색계열의 색상으로 발색하기 위해서는 먼저, 상기 점토 5 ~ 65wt%와, 고령토 30 ~ 85wt%와, 폴리실리콘 폐슬러지 1 ~ 10wt%의 혼합물에 산화티탄 1 ~ 5wt%를 더 첨가하여, 800 ~ 1,300℃에서 산화소성을 함으로써 목적을 달성할 수 있다.In order to develop a yellow color, first, by adding 1-5 wt% of titanium oxide to the mixture of 5 to 65 wt% of clay, 30 to 85 wt% of kaolin, and 1 to 10 wt% of polysilicon waste sludge, 800 to 1,300 The object can be attained by baking at 占 폚.

그리고 노란색, 밝은 주황색, 적갈색, 암갈색, 흑갈색 또는 이러한 색상들이 혼합되거나 부분적으로 발색되는 벽돌을 제조하기 위한 소성조건으로는 800 ~ 1,300℃에서 10 ~ 20시간 산화소성 후 400 ~ 600㎜Aq의 연료압력으로 150 ~ 250초의 환원소성 가동과 250 ~ 400초의 환원소성 정지를 순차적으로 반복한 후 900 ~ 980℃에서 50 ~ 70분 동안 급냉각과 5 ~ 8시간의 서냉구간을 거침으로서, 소성로내에서 불완전 연소되는 연료의 탄소성분을 점토벽돌에 흡착시켜 밝은 노란색, 밝은 주황색, 적갈색, 암갈색, 흑갈색 또는 이러한 색상들이 혼합되거나 부분적으로 발 색된다.And firing conditions for the manufacture of yellow, light orange, reddish brown, dark brown, dark brown or bricks in which these colors are mixed or partially colored. Fuel pressure of 400 to 600 mmAq after 10 to 20 hours oxidizing at 800 to 1,300 ℃ After 150 ~ 250 seconds of reducing firing operation and 250 ~ 400 seconds of reducing firing, it is incomplete in the kiln by going through rapid cooling and slow cooling section for 5 ~ 8 hours at 900 ~ 980 ℃ for 50 ~ 70 minutes. The carbon component of the fuel being burned is adsorbed on clay bricks, resulting in bright yellow, bright orange, reddish brown, dark brown, dark brown, or a mixture of these colors or partially developing them.

상기 환원소성시 급냉 온도가 900℃ 미만인 경우에는 냉파현상으로 벽돌이 깨어지게 되며, 980℃를 초과하여 냉각시키게 되면 색상이 어둡고 탁해지게 되는 문제점이 있으므로, 900℃ ~ 980℃의 범위 내에서 급냉시키는 것이 적절하며, 급냉각 시간을 50분 미만으로 하거나 70분을 초과하여 냉각시키게 되면 강도가 떨어지고 색상이 어두워져서 탁하게 되는 문제가 발생하므로, 50분 ~ 70분 이내로 급냉각 시키는 것이 바람직하다. 또한 환원소성의 가동과 정지를 반복함으로서 밝은 노란색, 밝은 주황색, 적갈색, 암갈색, 흑갈색 또는 이러한 색상들이 혼합되거나 부분적으로 발색된다.When the quenching temperature during the reduction firing is less than 900 ℃ brick breaks due to the cold phenomena, if the cooling is more than 980 ℃ dark color and turbidity, so there is a problem, quench within the range of 900 ℃ ~ 980 ℃ It is appropriate, and if the quenching time is less than 50 minutes or more than 70 minutes to cool down, the strength is reduced and the color becomes dark due to the problem of turbidity, it is preferable to quench within 50 minutes ~ 70 minutes. In addition, by repeating the starting and stopping of the reducing firing, bright yellow, bright orange, reddish brown, dark brown, dark brown or these colors are mixed or partially developed.

이상에서 살펴본 바와 같이, 본 발명에 따른 원토의 배합과 환원소성을 이용한 친환경 다채색의 고강도 칼라점토벽돌은 기존의 점토벽돌 및 기타 건축자재용 점토제품에서 칼라색상을 나타내기 위하여 주로 사용하는 안료나 기타 화학 약품등의 첨가없이 원토의 배합과 소성방법의 다양화를 통하여 여러가지의 색상을 나타내어, 현장 시공시 밝고 부드러운 유럽풍의 다채색상을 나타내어 단조롭고 획일적인 기존 점토벽돌 대비 주변환경을 고급스럽게 친환경적으로 만든다.As described above, the eco-friendly multicolored high-strength color clay brick using the blending and reducing plasticity of the raw material according to the present invention is a pigment mainly used for displaying color in clay bricks and other clay products for building materials. Various colors are expressed through the mixing of raw materials and the variety of firing methods without addition of other chemicals, and the bright and soft European-colored colors are displayed during the construction of the site, making the surrounding environment luxurious and eco-friendly compared to the monotonous and uniform clay brick. .

그리고, 폴리실리콘 폐슬러지를 재활용함으로서 제품의 강도를 더욱 향상시킴과 동시에 폐자원 재활용이라는 경제적 이점을 갖는다.In addition, by recycling the polysilicon waste sludge, the strength of the product is further improved, and at the same time, there is an economic advantage of recycling waste resources.

또한, 산화소성과 환원소성을 시간차로 변형하여 적용함으로서 산화소성만을 한 점토벽돌제품 대비 제품의 강도와 흡수율을 개선시키는 효과를 갖는다.In addition, by applying the oxidized oxide and reducing fired by the time difference, it has the effect of improving the strength and absorption rate of the product compared to the clay brick product only oxidized.

이하, 상기의 기술적 구성을 실시 예를 통해 더욱 구체적으로 살펴보고자 한다.Hereinafter, the above technical configuration will be described in more detail with reference to the following examples.

본 발명은 소성의 조건에 따라 다양한 색상을 발현하는 것으로서, 색상에 따른 벽돌의 소성과정을 살펴보면 다음과 같다.The present invention is to express a variety of colors according to the conditions of the firing, looking at the firing process of the brick according to the color as follows.

실시 예 1 : 붉은색 계열의 벽돌Example 1 red brick

점토 55㎏과, 고령토 40㎏과, 폴리실리콘 폐슬러지 5㎏의 혼합물을 벽돌 형상으로 성형한 후 1,100℃에서 15 시간 동안 산화소성한다. 그리고 이와 같이 제조된 벽돌은 붉은색 계열의 색상으로 발색된다.A mixture of 55 kg of clay, 40 kg of kaolin, and 5 kg of polysilicon waste sludge is molded into a brick shape and then oxidized and fired at 1,100 ° C. for 15 hours. And the brick thus produced is colored in a reddish color.

실시 예 2 : 검정색 또는 회색 계열의 벽돌Example 2: black or gray brick

점토 55㎏과, 고령토 40㎏과, 폴리실리콘 폐슬러지 5㎏의 혼합물을 벽돌 형상으로 성형한 후 1,000℃에서 10시간 동안 산화소성 한 후 400 ~ 500㎜Aq의 연료압력으로 150초 동안 환원소성하고, 300초 동안 환원소성 정지를 반복한 후 960℃에서 50분 급냉과 6시간 서냉시킴으로서 소성로에서 불완전 연소되는 연료의 탄소성분을 점토벽돌에 흡착시켜 흡수율과 강도가 우수하여 색상이 검정색 또는 회색으 로 발색된다.A mixture of 55 kg of clay, 40 kg of kaolin, and 5 kg of polysilicon waste sludge was formed into a brick shape, followed by oxidizing for 10 hours at 1,000 ° C., and then reducing firing for 150 seconds at a fuel pressure of 400 to 500 mmAq. After repeating the reduction firing for 300 seconds, the quenching and quenching for 50 minutes at 960 ° C and slow cooling for 6 hours are used to adsorb the carbon component of the incompletely burned fuel in the kiln to clay bricks. It is developed.

실시 예 3 : 노란색 계열의 벽돌Example 3: yellow brick

점토 25㎏과, 고령토 68㎏과, 폴리실리콘 폐슬러지 5㎏과, 산화티탄 2㎏의 혼합물을 벽돌 형상으로 성형한 후 1,100℃에서 산화소성을 함으로써 노란색계열의 색상으로 발색된다.A mixture of 25 kg of clay, 68 kg of kaolin, 5 kg of polysilicon waste sludge, and 2 kg of titanium oxide was molded into a brick shape and then colored in a yellowish color by firing at 1,100 ° C.

실시 예 4 : 노란색, 밝은 주황색, 적갈색, 암갈색, 흑갈색의 색상들이 혼합된 색상으로 발색되는 벽돌Example 4: Bricks colored with a mixture of yellow, bright orange, reddish brown, dark brown, and black brown colors

점토 25㎏과, 고령토 68㎏과, 폴리실리콘 폐슬러지 5㎏과, 산화티탄 2㎏의 혼합물을 벽돌 형상으로 성형한 후, 1,100℃에서 15시간 동안 산화 소성 후 500㎜Aq의 연료압력으로 200초 동안의 환원소성 가동과, 300초 동안의 환원소성의 정지를 순차적으로 반복한 후 960℃로 1시간 급냉각시킨 후 6시간 동안 서서히 냉각시킴으로서 흡수율과 강도가 우수하며 소성로 내에서 불완전 연소되는 연료의 탄소성분을 점토벽돌에 흡착시켜 밝은 노란색, 밝은 주황색, 적갈색, 암갈색, 흑갈색의 색상들이 혼합된 색상으로 발색된다.A mixture of 25 kg of clay, 68 kg of kaolin, 5 kg of polysilicon waste sludge, and 2 kg of titanium oxide was molded into a brick shape, and then oxidized and fired at 1,100 ° C. for 15 hours for 200 seconds at a fuel pressure of 500 mmAq. After the repetitive firing operation and the stopping of the reductive firing for 300 seconds were sequentially repeated, it was rapidly cooled to 960 ° C. for 1 hour and then gradually cooled for 6 hours to provide excellent absorption and strength, and to improve the combustion of incomplete combustion in the kiln. By adsorbing carbon to clay bricks, colors of bright yellow, bright orange, reddish brown, dark brown, and blackish brown are colored.

도 1은 본 발명에 따른 실제 제작된 제품의 사진.1 is a photograph of the actual product produced according to the present invention.

Claims (5)

철분을 1 ~ 15wt%로 함유하는 내화도가 800℃ ~ 1,300℃인 점토 5 ~ 65wt%와, 고령토 30 ~ 85wt%와, 폴리실리콘 폐슬러지 1 ~ 10wt%의 혼합물을 벽돌 형상으로 성형한 후 소성하여 다양한 색상을 발현하는 것에 있어서,5 to 65 wt% of clay having a fire resistance of 800 to 1,300 ° C., 30 to 85 wt% of kaolin, and 1 to 10 wt% of polysilicon waste sludge were fired after molding into a brick shape. In expressing various colors, 상기 소성은 혼합물에 산화티탄 1 ~ 5wt%를 더 첨가하여, 800 ~ 1,300℃에서 산화소성을 함으로써 노란색계열의 색상으로 발색되는 것임을 특징으로 하는 친환경 다채색의 고강도 칼라점토벽돌.The firing is an environment-friendly multi-colored high-strength color clay brick, characterized in that the addition of titanium oxide 1 to 5wt% to the mixture, the color of the yellow series by baking at 800 ~ 1,300 ℃. 삭제delete 삭제delete 삭제delete 청구항 1에 있어서,The method according to claim 1, 소성은 800 ~ 1,300℃에서 10 ~ 20시간 산화소성 후 400 ~ 600㎜Aq의 연료압력으로 150 ~ 250초의 환원소성 가동, 250 ~ 400초의 환원소성 정지를 순차적으로 반복한 후 900 ~ 980℃로 50분 ~ 70분 급냉각시킨 후 5 ~ 8시간 서냉시킴으로서 소성로내에서 불완전 연소되는 연료의 탄소성분을 점토벽돌에 흡착시켜 밝은 노란색, 밝은 주황색, 적갈색, 암갈색, 흑갈색 또는 이러한 색상들이 혼합되거나 부분적으로 발색되는 것임을 특징으로 하는 친환경 다채색의 고강도 칼라점토벽돌.Firing is repeated after repeated firing for 150 to 250 seconds and 250 to 400 seconds of reducing firing at a fuel pressure of 400 to 600 mmAq after 10 to 20 hours of oxidizing at 800 to 1,300 ° C. After cooling by slow cooling for 5 ~ 8 hours after quenching for 70 ~ 70 minutes, carbon components of incompletely burned fuel in the kiln are adsorbed to clay bricks, so that bright yellow, bright orange, reddish brown, dark brown, dark brown or these colors are mixed or partially developed. Eco-friendly multicolored high strength color clay brick, characterized in that it is.
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Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR100947494B1 (en) * 2009-09-24 2010-03-17 주식회사 고령기와 The tan tile korean style shape for high density character a composite and korean style shape tile making process
KR101287125B1 (en) 2012-12-20 2013-07-17 (주)산청토기와 Composition for clay roofing tiles comprising construction sludge and method for manufacturing the roofing tiles using the composition
KR101420113B1 (en) * 2013-03-29 2014-07-21 한국세라믹기술원 Sculpture clay composition used for manufacturing large-sized ceramic ware, method for manufacturing large-sized ceramic ware using the same, and large-sized ceramic ware manufactured thereby
KR101450175B1 (en) 2014-06-09 2014-10-14 동부요업 주식회사 Method for manufacturing traditional tile with modified colors
KR101903294B1 (en) * 2017-12-12 2018-10-01 김영래 A brick using waste sludge of solar cell and manufacturing method thereof
CN115572176A (en) * 2022-09-30 2023-01-06 广西欧神诺陶瓷有限公司 Light ceramic tile prepared from metal tailings and preparation method thereof

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH09175851A (en) * 1995-12-26 1997-07-08 邦明 ▲高▼松 Recycling of sludge containing silicon and reclaimed product thereby
KR19980019482A (en) * 1998-03-20 1998-06-05 장상무 A process for preparing bricks using sludges of waste water originating from electronic elements manufacturing plants
KR100671802B1 (en) * 2005-10-11 2007-01-19 최병환 Manufacturing of clay brick using sludge
KR20080010146A (en) * 2006-07-26 2008-01-30 주식회사공간세라믹 Clay brick(flat) using tio2 sludge and manufacturing method of the same

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH09175851A (en) * 1995-12-26 1997-07-08 邦明 ▲高▼松 Recycling of sludge containing silicon and reclaimed product thereby
KR19980019482A (en) * 1998-03-20 1998-06-05 장상무 A process for preparing bricks using sludges of waste water originating from electronic elements manufacturing plants
KR100671802B1 (en) * 2005-10-11 2007-01-19 최병환 Manufacturing of clay brick using sludge
KR20080010146A (en) * 2006-07-26 2008-01-30 주식회사공간세라믹 Clay brick(flat) using tio2 sludge and manufacturing method of the same

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR100947494B1 (en) * 2009-09-24 2010-03-17 주식회사 고령기와 The tan tile korean style shape for high density character a composite and korean style shape tile making process
KR101287125B1 (en) 2012-12-20 2013-07-17 (주)산청토기와 Composition for clay roofing tiles comprising construction sludge and method for manufacturing the roofing tiles using the composition
KR101420113B1 (en) * 2013-03-29 2014-07-21 한국세라믹기술원 Sculpture clay composition used for manufacturing large-sized ceramic ware, method for manufacturing large-sized ceramic ware using the same, and large-sized ceramic ware manufactured thereby
KR101450175B1 (en) 2014-06-09 2014-10-14 동부요업 주식회사 Method for manufacturing traditional tile with modified colors
KR101903294B1 (en) * 2017-12-12 2018-10-01 김영래 A brick using waste sludge of solar cell and manufacturing method thereof
CN115572176A (en) * 2022-09-30 2023-01-06 广西欧神诺陶瓷有限公司 Light ceramic tile prepared from metal tailings and preparation method thereof
CN115572176B (en) * 2022-09-30 2023-06-20 广西欧神诺陶瓷有限公司 Light ceramic tile prepared from metal tailings and preparation method thereof

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