KR100897817B1 - Method for Structuring Gate Of Semiconductor Device - Google Patents
Method for Structuring Gate Of Semiconductor Device Download PDFInfo
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- KR100897817B1 KR100897817B1 KR1020070051295A KR20070051295A KR100897817B1 KR 100897817 B1 KR100897817 B1 KR 100897817B1 KR 1020070051295 A KR1020070051295 A KR 1020070051295A KR 20070051295 A KR20070051295 A KR 20070051295A KR 100897817 B1 KR100897817 B1 KR 100897817B1
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- 238000000034 method Methods 0.000 title claims abstract description 33
- 239000004065 semiconductor Substances 0.000 title claims abstract description 23
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 claims abstract description 37
- 229910052710 silicon Inorganic materials 0.000 claims abstract description 37
- 239000010703 silicon Substances 0.000 claims abstract description 37
- 238000000151 deposition Methods 0.000 claims abstract description 32
- 230000008021 deposition Effects 0.000 claims abstract description 24
- 238000005530 etching Methods 0.000 claims abstract description 23
- 230000002265 prevention Effects 0.000 claims abstract description 18
- 229920002120 photoresistant polymer Polymers 0.000 claims abstract description 12
- 239000000463 material Substances 0.000 claims abstract description 7
- 239000000758 substrate Substances 0.000 claims abstract description 6
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 claims description 12
- KRHYYFGTRYWZRS-UHFFFAOYSA-N Fluorane Chemical compound F KRHYYFGTRYWZRS-UHFFFAOYSA-N 0.000 claims description 10
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 claims description 10
- 150000004767 nitrides Chemical class 0.000 claims description 7
- 238000001039 wet etching Methods 0.000 claims description 6
- 229910000147 aluminium phosphate Inorganic materials 0.000 claims description 5
- 238000000137 annealing Methods 0.000 claims description 4
- 230000009977 dual effect Effects 0.000 abstract description 8
- 230000000295 complement effect Effects 0.000 abstract description 2
- 229910044991 metal oxide Inorganic materials 0.000 abstract description 2
- 150000004706 metal oxides Chemical class 0.000 abstract description 2
- 239000010408 film Substances 0.000 description 40
- MWUXSHHQAYIFBG-UHFFFAOYSA-N Nitric oxide Chemical compound O=[N] MWUXSHHQAYIFBG-UHFFFAOYSA-N 0.000 description 2
- 239000013078 crystal Substances 0.000 description 2
- 238000001312 dry etching Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 230000010354 integration Effects 0.000 description 1
- 238000005468 ion implantation Methods 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 229910021421 monocrystalline silicon Inorganic materials 0.000 description 1
- 238000000206 photolithography Methods 0.000 description 1
- 239000010409 thin film Substances 0.000 description 1
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- H01L21/00—Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
- H01L21/02—Manufacture or treatment of semiconductor devices or of parts thereof
- H01L21/04—Manufacture or treatment of semiconductor devices or of parts thereof the devices having potential barriers, e.g. a PN junction, depletion layer or carrier concentration layer
- H01L21/18—Manufacture or treatment of semiconductor devices or of parts thereof the devices having potential barriers, e.g. a PN junction, depletion layer or carrier concentration layer the devices having semiconductor bodies comprising elements of Group IV of the Periodic Table or AIIIBV compounds with or without impurities, e.g. doping materials
- H01L21/28—Manufacture of electrodes on semiconductor bodies using processes or apparatus not provided for in groups H01L21/20 - H01L21/268
- H01L21/28008—Making conductor-insulator-semiconductor electrodes
- H01L21/28017—Making conductor-insulator-semiconductor electrodes the insulator being formed after the semiconductor body, the semiconductor being silicon
- H01L21/28026—Making conductor-insulator-semiconductor electrodes the insulator being formed after the semiconductor body, the semiconductor being silicon characterised by the conductor
- H01L21/28035—Making conductor-insulator-semiconductor electrodes the insulator being formed after the semiconductor body, the semiconductor being silicon characterised by the conductor the final conductor layer next to the insulator being silicon, e.g. polysilicon, with or without impurities
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- H01L21/02365—Forming inorganic semiconducting materials on a substrate
- H01L21/02518—Deposited layers
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- H01L21/02365—Forming inorganic semiconducting materials on a substrate
- H01L21/02612—Formation types
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- H01L21/70—Manufacture or treatment of devices consisting of a plurality of solid state components formed in or on a common substrate or of parts thereof; Manufacture of integrated circuit devices or of parts thereof
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- H01L21/78—Manufacture or treatment of devices consisting of a plurality of solid state components or integrated circuits formed in, or on, a common substrate with subsequent division of the substrate into plural individual devices
- H01L21/82—Manufacture or treatment of devices consisting of a plurality of solid state components or integrated circuits formed in, or on, a common substrate with subsequent division of the substrate into plural individual devices to produce devices, e.g. integrated circuits, each consisting of a plurality of components
- H01L21/822—Manufacture or treatment of devices consisting of a plurality of solid state components or integrated circuits formed in, or on, a common substrate with subsequent division of the substrate into plural individual devices to produce devices, e.g. integrated circuits, each consisting of a plurality of components the substrate being a semiconductor, using silicon technology
- H01L21/8232—Field-effect technology
- H01L21/8234—MIS technology, i.e. integration processes of field effect transistors of the conductor-insulator-semiconductor type
- H01L21/8238—Complementary field-effect transistors, e.g. CMOS
- H01L21/823828—Complementary field-effect transistors, e.g. CMOS with a particular manufacturing method of the gate conductors, e.g. particular materials, shapes
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Abstract
본 발명은 반도체 소자의 게이트 형성 방법에 있어서, 특히 씨모스(CMOS: complementary metaloxide semi-conductor) 반도체 소자의 듀얼 게이트 형성시, 게이트의 도핑물질 및 도핑농도에 따라 달라지는 식각속도로 인해 특정 게이트의 산화막 및 액티브 지역이 손상되는 것을 방지하는 방법에 관한 것이다. The present invention relates to a method of forming a gate of a semiconductor device, in particular, when forming a dual gate of a complementary metal oxide semi-conductor (CMOS) semiconductor device, an oxide film of a specific gate due to an etching rate that depends on the doping material and the doping concentration of the gate. And a method for preventing the active area from being damaged.
본 발명에 따른 반도체 소자의 게이트 형성방법은, N-Gate 및 P-Gate 액티브 영역이 형성된 반도체 기판상에 게이트산화막과 게이트실리콘막을 차례로 형성하는 단계, 상기 게이트실리콘막 상에 추가증착 방지막을 형성한 후, 상기 N-Gate 및 P-Gate 영역을 구분하는 감광막 패턴을 형성하는 단계, 상기 N-Gate 영역의 산화막을 제거하는 단계, 상기 산화막이 제거된 N-Gate 영역에 게이트실리콘을 추가증착하는 단계, 상기 P-Gate 영역에 잔존하는 감광막 패턴 및 산화막을 제거하는 단계 및 상기 기판 결과물 상에 실리콘 게이트를 형성하는 단계를 포함하여 이루어진다. In the method of forming a gate of a semiconductor device according to the present invention, the step of sequentially forming a gate oxide film and a gate silicon film on a semiconductor substrate on which the N-Gate and P-Gate active regions are formed, and forming an additional deposition prevention film on the gate silicon film Thereafter, forming a photoresist pattern that separates the N-Gate and P-Gate regions, removing an oxide layer of the N-Gate region, and further depositing gate silicon on the N-Gate region from which the oxide layer is removed. And removing the photoresist pattern and the oxide layer remaining in the P-Gate region and forming a silicon gate on the substrate resultant.
씨모스(CMOS), 듀얼 게이트(Dual Gate), SEG, 반도체 소자, CMOS, Dual Gate, SEG, Semiconductor Devices,
Description
도 1a 내지 도 1b는 종래기술에 따른 N-Gate 및 P-Gate의 도핑원소와 농도에 따른 식각속도 차이를 나타낸 도면.1a to 1b is a view showing the difference in etching rate according to the doping element and the concentration of N-Gate and P-Gate according to the prior art.
도 2a 내지 도 2b는 종래기술에 따른 N-Gate 및 P-Gate의 게이트산화막의 손상 정도를 나타낸 도면.2a to 2b is a view showing the degree of damage of the gate oxide film of N-Gate and P-Gate according to the prior art.
도 3a 내지 도 3d는 본 발명의 일실시 예에 따른 반도체 소자의 듀얼 게이트 형성방법을 나타낸 공정단면도. 3A to 3D are cross-sectional views illustrating a method of forming a dual gate of a semiconductor device in accordance with an embodiment of the present invention.
본 발명은 반도체 소자의 게이트 형성방법에 있어서, 특히 씨모스 반도체 소자의 듀얼 게이트 형성방법에 관한 것이다. BACKGROUND OF THE
최근 반도체 소자가 고집적화됨에 따라, 상기 반도체 소자의 고집적화에 가장 밀접하게 연관되어 있는 게이트 선폭을 축소시키기 위한 방법들이 제시되고 있다. Recently, as semiconductor devices have been highly integrated, methods for reducing gate line width, which are most closely related to the high integration of semiconductor devices, have been proposed.
상기 게이트 선폭 축소 기술은 게이트 식각 전, 이온주입 등을 통해 게이트 를 도핑시킴으로써, 상기 게이트의 저항을 줄이는 방법 등이 사용되고 있다. In the gate line width reduction technology, a method of reducing the resistance of the gate by doping the gate through ion implantation or the like before the gate etching is used.
특히, 상보형 MOS(CMOS; complementary metal-oxide semiconductor)를 이용한 반도체 소자의 경우, N-TYPE과 P-TYPE으로 각각 도핑된 듀얼 게이트 구조로 형성된다. In particular, a semiconductor device using a complementary metal-oxide semiconductor (MOS) is formed of a dual gate structure doped with N-type and P-type, respectively.
이하, 첨부된 도면을 참조하여 종래기술에 따른 N-Gate 및 P-Gate 식각속도 차이 및 게이트산화막 손상정도를 설명한다. Hereinafter, with reference to the accompanying drawings will be described the difference in the etching rate and gate oxide film N-Gate and P-Gate according to the prior art.
도 1a 내지 도 1b는 종래기술에 따른 N-Gate 및 P-Gate의 도핑원소와 농도에 따른 식각속도 차이를 나타낸 도면이다.1a to 1b is a view showing the difference in etching rate according to the doping element and the concentration of the N-Gate and P-Gate according to the prior art.
도 1a는 N-Gate의 도핑원소 및 도핑농도에 따른 식각속도 차이를 보여주고, 도 1b는 P-Gate의 도핑원소 및 도핑농도에 따른 식각속도 차이를 보여준다. Figure 1a shows the difference in etching rate according to the doping element and the doping concentration of N-Gate, Figure 1b shows the difference in etching rate according to the doping element and doping concentration of the P-Gate.
도 1a 및 도 1b를 비교하면, 상기 N-Gate 영역의 식각속도가 상기 P-Gate 영역의 식각속도 보다 훨씬 빠르다는 것을 알 수 있다. Comparing FIGS. 1A and 1B, it can be seen that the etching rate of the N-Gate region is much faster than that of the P-Gate region.
도 2a 내지 도 2b는 종래기술에 따른 N-Gate 및 P-Gate의 게이트산화막의 손상 정도를 나타낸 도면이다.2a to 2b are views showing the damage degree of the gate oxide film of N-Gate and P-Gate according to the prior art.
도 2a는 N-Gate의 게이트산화막 손상정도를 나타낸 것이고, 도 2b는 P-Gate의 게이트산화막의 손상 정도를 나타낸 것이다. Figure 2a shows the degree of damage to the gate oxide film of the N-Gate, Figure 2b shows the degree of damage to the gate oxide film of the N-Gate.
도 2a 및 도 2b를 비교하면, 상기 N-Gate 영역의 게이트산화막 손상정도가 상기 P-Gate 영역의 게이트산화막 손상정도보다 훨씬 심하다는 것을 알 수 있다. Comparing FIG. 2A and FIG. 2B, it can be seen that the damage level of the gate oxide film in the N-Gate region is much greater than that of the gate oxide film in the P-Gate region.
따라서, 상기 두 게이트를 한꺼번에 식각할 경우 도핑원소 및 도핑농도에 따라 식각속도의 차이가 크다. 또한, 식각속도가 빠른 N-Gate 영역의 액티브는 얇은 게이트 산화막으로 인해 쉽게 손상되는 문제점이 있다. Therefore, when the two gates are etched at the same time, the difference in etching speed is large according to the doping element and the doping concentration. In addition, the active of the N-Gate region having a high etching rate is easily damaged by a thin gate oxide film.
본 발명의 목적은 상기한 문제점을 감안하여 안출한 것으로서, 특히 반도체 소자의 듀얼 게이트 형성시, 게이트의 도핑물질 및 도핑농도에 따라 달라지는 식각속도로 인해 특정 게이트의 산화막 및 액티브 지역이 손상되는 것을 방지하기 위한 방법을 제공하는 것이다.SUMMARY OF THE INVENTION An object of the present invention has been made in view of the above-described problems, and particularly, when forming a dual gate of a semiconductor device, an oxide film and an active region of a specific gate are prevented from being damaged due to an etching rate that depends on the doping material and the doping concentration of the gate. It is to provide a method for doing so.
상기와 같은 목적을 달성하기 위한 본 발명에 따른 반도체 소자의 게이트 형성 방법의 일 특징은, N-Gate 및 P-Gate 액티브 영역이 형성된 반도체 기판상에 게이트산화막과 게이트실리콘막을 차례로 형성하는 단계, 상기 게이트실리콘막 상에 추가증착 방지막을 형성한 후, 상기 N-Gate 및 P-Gate 영역을 구분하는 감광막 패턴을 형성하는 단계, 상기 감광막 패턴을 이용하여 상기 N-Gate 영역의 추가증착방지막을 제거하는 단계, 상기 추가증착방지막이 제거된 N-Gate 영역에 게이트실리콘을 추가증착하는 단계, 상기 P-Gate 영역에 잔존하는 감광막 패턴 및 추가증착방지막을 제거하는 단계, 및 상기 추가증착된 게이트실리콘을 포함한 상기 게이트실리콘막을 부분식각하는 단계를 포함하여 이루어지는 것이다.According to an aspect of the present invention, there is provided a method of forming a gate of a semiconductor device, the method including sequentially forming a gate oxide film and a gate silicon film on a semiconductor substrate on which N-Gate and P-Gate active regions are formed, After forming a further deposition prevention film on the gate silicon film, forming a photoresist pattern for separating the N-Gate and P-Gate region, by using the photosensitive film pattern to remove the additional deposition prevention film of the N-Gate region The method may further include: depositing gate silicon on the N-gate region from which the additional deposition prevention film has been removed, removing the photoresist pattern and the additional deposition prevention layer remaining on the P-gate region, and including the additional deposition gate silicon. And partially etching the gate silicon film.
보다 바람직하게, 상기 추가증착 방지막은 산화막, 질화막 또는 질산화막을 포함한다. More preferably, the additional deposition prevention film comprises an oxide film, a nitride film or a nitride oxide film.
보다 바람직하게, 상기 추가증착 방지막은 습식식각 공정을 통해 제거되는 것으로서, 상기 습식식각에 사용되는 물질은 불산, 초산 및 인산을 포함한다. More preferably, the additional deposition preventing film is removed through a wet etching process, and the material used for the wet etching includes hydrofluoric acid, acetic acid, and phosphoric acid.
보다 바람직하게, 상기 N-Gate 영역의 게이트실리콘은 SEG(Selective Epitaxial Growth of silicon) 공정을 통해 추가증착한다. More preferably, the gate silicon of the N-Gate region is additionally deposited through a selective epitaxial growth of silicon (SEG) process.
보다 바람직하게, 상기 N-Gate 영역의 게이트실리콘은 50 내지 300Å 두께로 추가증착한다. More preferably, the gate silicon of the N-Gate region is further deposited to a thickness of 50 to 300 kHz.
보다 바람직하게, 상기 N-Gate 영역에 게이트실리콘을 추가증착한 후, 200 내지 1300℃ 정도의 온도로 어닐링하는 단계를 더 포함한다. More preferably, further comprising the step of annealing at a temperature of about 200 to 1300 ℃ after further depositing the gate silicon in the N-Gate region.
이하, 첨부된 도면을 참조하여 본 발명의 실시 예의 구성과 그 작용을 설명하며, 도면에 도시되고 또 이것에 의해서 설명되는 본 발명의 구성과 작용은 적어도 하나의 실시 예로서 설명되는 것이며, 이것에 의해서 상기한 본 발명의 기술적 사상과 그 핵심 구성 및 작용이 제한되지는 않는다.Hereinafter, with reference to the accompanying drawings illustrating the configuration and operation of the embodiment of the present invention, the configuration and operation of the present invention shown in the drawings and described by it will be described by at least one embodiment, By the technical spirit of the present invention described above and its core configuration and operation is not limited.
도 3a 내지 도 3d는 본 발명의 일실시 예에 따른 반도체 소자의 듀얼 게이트 형성방법을 나타낸 공정 단면도이다.3A to 3D are cross-sectional views illustrating a method of forming a dual gate of a semiconductor device according to an embodiment of the present invention.
도 3a을 참조하면, N-Gate 및 P-Gate 액티브 영역이 형성된 반도체 기판(미도시)상에 게이트산화막(1)과 게이트실리콘막(2)을 차례로 증착한 상부에 추가증착 방지막(3)을 형성한다. 상기 추가증착 방지막은(3) 산화막, 질화막 또는 질산화막 등으로 이루어진다. Referring to FIG. 3A, an additional
이후, 상기 추가증착 방지막(3) 상부 전면에 감광막을 도포한 후, N-Gate 및 P-Gate 영역을 구분하기 위한 패턴을 마스킹하고, 포토리소그래피(photo-lithography)를 실시하여 감광막 패턴(4)을 형성한다. Subsequently, after the photoresist film is applied to the entire upper surface of the additional
이후, 도 3b에 도시된 바와 같이, 상기 형성된 감광막 패턴(4) 상부 전면에 식각을 실시하여 N-Gate 영역의 추가증착 방지막(3)을 제거한다. 이때, 상기 추가증착 방지막(3)은 습식식각 공정을 통해 제거되는 것으로서, 상기 습식식각에 사용되는 물질로는 불산, 초산 및 인산 등이 포함된다. Thereafter, as illustrated in FIG. 3B, etching is performed on the entire upper surface of the formed
예를 들어, 상기 추가증착 방지막(3)이 산화막이면, 상기 불산 및 초산을 식각물질로 사용하고, 상기 추가증착 방지막(3)이 질화막이면, 상기 인산을 식각물질로 사용한다. 또한, 상기 추가증착 방지막(3)이 질산화막인 경우, 상기 불산 및 인산을 일정량 혼합하여 사용한다. For example, when the additional
상기 추가증착 방지막(3)이 제거된 N-Gate 영역에 게이트실리콘(5)을 추가증착한다. The
이때, 상기 게이트실리콘(5)은 50Å 내지 300Å 두께로 형성되는 것으로서, SEG(Selective Epitaxial Growth of silicon) 공정을 통해 추가증착한다. In this case, the
상기 SEG는 선택적 단결정 실리콘 박막 성장 기술로서, 절연막에서는 실리콘이 성장하지 않고, 실리콘 기판이 드러난 부분에서 실리콘만 선택적으로 결정 방향 관계가 유지된 상태로 성장시키는 기술이다. The SEG is a selective single crystal silicon thin film growth technology, in which silicon is not grown in an insulating layer, and only silicon is selectively grown in a portion in which a silicon substrate is exposed in a state in which crystal orientation is maintained.
삭제delete
상기 게이트실리콘(5)을 추가증착한 후, 상기 추가증착된 게이트실리콘(5)과 하부의 게이트실리콘막(2)과의 결정상태를 동일하게 유지하기 위해 어닐링 공정을 추가로 실시한다. 상기 어닐링 공정은 이후 실시되는 식각공정을 안정화시키기 위한 것으로서, 200℃ 내지 1300℃의 온도에서 이루어진다. After further depositing the
이후, 도 3c에 도시된 바와 같이, 상기 P-Gate 영역에 잔존하는 감광막 패턴(4) 및 추가증착 방지막(3)을 건식식각 공정을 통해 동시에 제거한다. 그리고, 상기 N-Gate 영역에 게이트실리콘(5)을 추가증착한 상태에서 게이트 마스크를 이용하여 패턴을 형성한 후, 상기 패턴에 따라 게이트실리콘막(2)을 부분식각한다.Thereafter, as shown in FIG. 3C, the
삭제delete
이때, 도핑원소 및 도핑농도에 따른 식각속도가 빨라 게이트실리콘(5)을 추가증착한 N-Gate 지역과 추가증착하지 않은 P-Gate 지역에 남아있는 게이트실리콘량이 거의 동일함을 알 수 있다. At this time, the etching speed according to the doping element and the doping concentration is fast, it can be seen that the amount of gate silicon remaining in the N-Gate region where the
도 3d는 식각을 완료한 것으로, 상기 식각을 통해 N-Gate 영역의 게이트산화막(1)까지 제거하였음에도 불구하고, 액티브 손상이 없는 프로파일을 확보할 수 있다. 3D shows that the etching is completed, and even though the
따라서, N-Gate 영역의 게이트산화막을 사전에 추가증착해 둠으로써, 이후 실행되는 식각공정시, 도핑원소 및 도핑농도에 따라 게이트별로 달라지는 식각정도를 보상할 수 있다. Therefore, by further depositing the gate oxide film in the N-Gate region in advance, the etching degree which varies for each gate according to the doping element and the doping concentration can be compensated for in the subsequent etching process.
이상 설명한 내용을 통해 당업자라면 본 발명의 기술 사상을 일탈하지 아니하는 범위에서 다양한 변경 및 수정 가능함을 알 수 있을 것이다. 따라서, 본 발명의 기술적 범위는 실시 예에 기재된 내용으로 한정하는 것이 아니라 특허 청구의 범위에 의하여 정해져야 한다.Those skilled in the art will appreciate that various changes and modifications can be made without departing from the spirit of the present invention. Therefore, the technical scope of the present invention should not be limited to the contents described in the embodiments, but should be defined by the claims.
이상에서 설명한 바와 같이, 본 발명은 듀얼 게이트 형성시, 특정 게이트에 실리콘을 추가증착함으로써, 식각속도에 의한 산화막 및 액티브 지역의 손상을 사전에 방지할 수 있는 효과가 있다. As described above, the present invention has an effect of preventing damage to the oxide film and the active region due to the etching rate in advance by additionally depositing silicon on a specific gate when forming the dual gate.
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KR20030053217A (en) * | 2001-12-22 | 2003-06-28 | 주식회사 하이닉스반도체 | Method for forming dual gate electrode |
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KR20030053217A (en) * | 2001-12-22 | 2003-06-28 | 주식회사 하이닉스반도체 | Method for forming dual gate electrode |
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