KR100824225B1 - 가스 중의 ｎ2ｏ 및 ｎｏｘ 함량의 감소방법 - Google Patents

가스 중의 ｎ2ｏ 및 ｎｏｘ 함량의 감소방법 Download PDF

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Publication number
KR100824225B1
KR100824225B1 KR1020037011939A KR20037011939A KR100824225B1 KR 100824225 B1 KR100824225 B1 KR 100824225B1 KR 1020037011939 A KR1020037011939 A KR 1020037011939A KR 20037011939 A KR20037011939 A KR 20037011939A KR 100824225 B1 KR100824225 B1 KR 100824225B1
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South Korea
Prior art keywords
gas
catalyst
content
reduction
iron
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KR1020037011939A
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Korean (ko)
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KR20040015066A (ko
Inventor
슈베퍼마인하르트
모츠요아힘
지페르트롤프
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우데 게엠베하
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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/40—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively
    • B01J29/42—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively containing iron group metals, noble metals or copper
    • B01J29/46—Iron group metals or copper
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34—Chemical or biological purification of waste gases
    • B01D53/74—General processes for purification of waste gases; Apparatus or devices specially adapted therefor
    • B01D53/86—Catalytic processes
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34—Chemical or biological purification of waste gases
    • B01D53/74—General processes for purification of waste gases; Apparatus or devices specially adapted therefor
    • B01D53/86—Catalytic processes
    • B01D53/8621—Removing nitrogen compounds
    • B01D53/8625—Nitrogen oxides
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34—Chemical or biological purification of waste gases
    • B01D53/74—General processes for purification of waste gases; Apparatus or devices specially adapted therefor
    • B01D53/86—Catalytic processes
    • B01D53/8621—Removing nitrogen compounds
    • B01D53/8625—Nitrogen oxides
    • B01D53/8628—Processes characterised by a specific catalyst
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B21/00—Nitrogen; Compounds thereof
    • C01B21/20—Nitrogen oxides; Oxyacids of nitrogen; Salts thereof
    • C01B21/24—Nitric oxide (NO)
    • C01B21/26—Preparation by catalytic or non-catalytic oxidation of ammonia
    • C01B21/265—Preparation by catalytic or non-catalytic oxidation of ammonia characterised by the catalyst
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2255/00—Catalysts
    • B01D2255/50—Zeolites
    • B01D2255/504—ZSM 5 zeolites
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2257/00—Components to be removed
    • B01D2257/40—Nitrogen compounds
    • B01D2257/402—Dinitrogen oxide
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2257/00—Components to be removed
    • B01D2257/40—Nitrogen compounds
    • B01D2257/404—Nitrogen oxides other than dinitrogen oxide
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2259/00—Type of treatment
    • B01D2259/40—Further details for adsorption processes and devices
    • B01D2259/401—Further details for adsorption processes and devices using a single bed
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/10—After treatment, characterised by the effect to be obtained
    • B01J2229/16—After treatment, characterised by the effect to be obtained to increase the Si/Al ratio; Dealumination
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02C—CAPTURE, STORAGE, SEQUESTRATION OR DISPOSAL OF GREENHOUSE GASES [GHG]
    • Y02C20/00—Capture or disposal of greenhouse gases
    • Y02C20/10—Capture or disposal of greenhouse gases of nitrous oxide (N2O)
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/151—Reduction of greenhouse gas [GHG] emissions, e.g. CO2

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Environmental & Geological Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Analytical Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Health & Medical Sciences (AREA)
  • Biomedical Technology (AREA)
  • Materials Engineering (AREA)
  • Inorganic Chemistry (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Catalysts (AREA)
  • Exhaust Gas Treatment By Means Of Catalyst (AREA)
  • Treating Waste Gases (AREA)
  • Investigating Or Analyzing Materials By The Use Of Fluid Adsorption Or Reactions (AREA)
KR1020037011939A 2001-03-13 2002-03-06 가스 중의 ｎ2ｏ 및 ｎｏｘ 함량의 감소방법 Expired - Lifetime KR100824225B1 (ko)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE10112444A DE10112444A1 (de) 2001-03-13 2001-03-13 Verfahren zur Verringerung des Gehalts von N¶2¶O und NO¶x¶ in Gasen
DE10112444.9 2001-03-13

Publications (2)

Publication Number Publication Date
KR20040015066A KR20040015066A (ko) 2004-02-18
KR100824225B1 true KR100824225B1 (ko) 2008-04-24

Family

ID=7677555

Family Applications (1)

Application Number Title Priority Date Filing Date
KR1020037011939A Expired - Lifetime KR100824225B1 (ko) 2001-03-13 2002-03-06 가스 중의 ｎ2ｏ 및 ｎｏｘ 함량의 감소방법

Country Status (13)

Country Link
US (2) US20040109805A1 (https=)
EP (1) EP1370342B1 (https=)
KR (1) KR100824225B1 (https=)
CN (1) CN1269554C (https=)
AT (1) ATE308371T1 (https=)
DE (2) DE10112444A1 (https=)
DK (1) DK1370342T3 (https=)
EA (1) EA005631B1 (https=)
ES (1) ES2252450T3 (https=)
IN (1) IN2003CH01437A (https=)
NO (1) NO334708B1 (https=)
WO (1) WO2002087733A1 (https=)
ZA (1) ZA200306771B (https=)

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DE10215605A1 (de) 2002-04-09 2003-10-30 Uhde Gmbh Entstickungsverfahren
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DE102005022650A1 (de) 2005-05-11 2006-11-16 Uhde Gmbh Verfahren zur Verringerung des Gehaltes an Stickoxiden in Gasen
RU2008128363A (ru) * 2005-12-14 2010-01-20 Басф Каталистс Ллк (Us) ЦЕОЛИТНЫЙ КАТАЛИЗАТОР С УЛУЧШЕННЫМ ВОССТАНОВЛЕНИЕМ NOх В SCR
PL1918016T3 (pl) * 2006-10-24 2012-09-28 Casale S A Katalizator oparty na zeolicie z rodzaju ferrerytu/żelazie stosowany do rozkładu N₂O i redukcji katalitycznej NOx i N₂O
US7736608B2 (en) * 2007-11-29 2010-06-15 General Electric Company Methods and systems for reducing the emissions from combustion gases
DE102008003036B4 (de) * 2008-01-02 2011-07-07 Süd-Chemie AG, 80333 Oxidationskatalysator mit NOx- und N2O-Minderungsaktivität
US7695703B2 (en) * 2008-02-01 2010-04-13 Siemens Energy, Inc. High temperature catalyst and process for selective catalytic reduction of NOx in exhaust gases of fossil fuel combustion
JP5459965B2 (ja) * 2008-02-05 2014-04-02 メタウォーター株式会社 排ガス中のｎ２ｏ除去方法
KR101091705B1 (ko) * 2009-03-24 2011-12-08 한국에너지기술연구원 암모니아 환원제에 의한 아산화질소 단독 혹은 아산화질소와 일산화질소의 동시 저감을 위한 철이온이 담지된 제올라이트 촉매의 제조방법과 그 촉매 그리고 이를이용한 암모니아 환원제에 의한 아산화질소 단독 혹은 아산화질소와 일산화질소의 동시 저감방법
FR2944316A3 (fr) * 2009-04-10 2010-10-15 Renault Sas Procede de diminution du protoxyde d'azote des gaz d'echappement de vehicule automobile
US9109492B2 (en) * 2009-06-16 2015-08-18 Toyota Jidosha Kabushiki Kaisha Exhaust purification system of internal combustion engine
MY160970A (en) * 2010-04-08 2017-03-31 Basf Se A catalyst for use in selective catalytic reduction comprising zeolites of the cha structure type comprising cu and zeolites of the mfi structure type comprising fe, an exhaust gas treatment system comprising this catalyst, a process for the treatment of a gas stream comprising nox using the catalyst
FR2962923B1 (fr) * 2010-07-22 2015-01-02 Peugeot Citroen Automobiles Sa Composition catalytique et dispositif de traitement des gaz comprenant une telle composition
DE102011011881A1 (de) 2011-02-21 2012-08-23 Thyssenkrupp Uhde Gmbh Verfahren zur Beseitigung von N2O und NOX aus dem Prozess zur Salpetersäureherstellung
JP2013099715A (ja) * 2011-11-08 2013-05-23 Hitachi Zosen Corp 燃焼排ガス中の窒素酸化物の除去触媒および同触媒を用いる窒素酸化物の除去方法
DE102011121188A1 (de) * 2011-12-16 2013-06-20 Thyssen Krupp Uhde Gmbh Vorrichtung und Verfahren zur Beseitigung von NOx und N20
US8821818B1 (en) 2013-03-15 2014-09-02 Three D Stack, LLC Cleaning stack gas
US9919269B2 (en) 2013-03-15 2018-03-20 3D Clean Coal Emissions Stack Llc Clean coal stack
CA2914389C (en) 2013-03-15 2019-11-26 3D Clean Coal Emissions Stack, Llc Cleaning stack gas
DE102014210661A1 (de) 2014-06-04 2015-12-17 Thyssenkrupp Ag Verringerung der Emission von Stickoxiden beim Anfahren von Anlagen zur Herstellung von Salpetersäure
CN106999915A (zh) 2014-12-03 2017-08-01 巴斯夫欧洲公司 用于一氧化二氮分解的铑催化剂、其制备及其用途
EP3162427A1 (en) * 2015-10-28 2017-05-03 Casale SA A method and apparatus for removing nox and n2o from a gas
EP3315188A1 (en) * 2016-10-28 2018-05-02 Casale Sa A method for removing nitrogen oxides from a gas using an iron exchanged zeolite catalyst
AU2017267474A1 (en) 2016-05-14 2019-01-03 3 D Clean Coal Emissions Stack, Llc Clean gas stack
EP3532189B1 (en) 2016-10-28 2024-05-15 Casale SA A method for removing nitrogen oxides from a gas using an iron exchanged zeolite catalyst
BR112020005604A2 (pt) 2017-11-30 2020-09-29 Casale Sa processo para a produção de ácido nítrico com redução terciária de n2o e nox
EP3549661A1 (en) 2018-04-06 2019-10-09 Yara International ASA Nox removal from gaseous effluents
EP3689441A1 (en) 2019-02-01 2020-08-05 Casale Sa Process for removing nitrogen oxides from a gas
US20250205641A1 (en) * 2022-03-29 2025-06-26 Mitsubishi Heavy Industries, Ltd. N2o decomposition catalyst

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US4571329A (en) 1984-08-13 1986-02-18 Babcock-Hitachi Kabushiki Kaisha Ammonia reduction-denitration process and apparatus therefor
US5482692A (en) 1994-07-07 1996-01-09 Mobil Oil Corporation Selective catalytic reduction of nitrogen oxides using a ferrocene impregnated zeolite catalyst
EP0756891A1 (en) * 1995-07-26 1997-02-05 Corning Incorporated Iron zeolite for conversion of NOx
WO2000048715A1 (fr) * 1999-02-18 2000-08-24 Grande-Paroisse S.A. Procede pour abattre simultanement les oxydes nitriques et le protoxyde d'azote dans les gaz qui en contiennent

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US4571329A (en) 1984-08-13 1986-02-18 Babcock-Hitachi Kabushiki Kaisha Ammonia reduction-denitration process and apparatus therefor
US5482692A (en) 1994-07-07 1996-01-09 Mobil Oil Corporation Selective catalytic reduction of nitrogen oxides using a ferrocene impregnated zeolite catalyst
EP0756891A1 (en) * 1995-07-26 1997-02-05 Corning Incorporated Iron zeolite for conversion of NOx
WO2000048715A1 (fr) * 1999-02-18 2000-08-24 Grande-Paroisse S.A. Procede pour abattre simultanement les oxydes nitriques et le protoxyde d'azote dans les gaz qui en contiennent

Also Published As

Publication number Publication date
KR20040015066A (ko) 2004-02-18
IN2003CH01437A (https=) 2005-11-25
US20040109805A1 (en) 2004-06-10
WO2002087733A1 (de) 2002-11-07
US20080044331A1 (en) 2008-02-21
EA200301001A1 (ru) 2004-02-26
DK1370342T3 (da) 2006-02-27
DE10112444A1 (de) 2002-10-02
EP1370342A1 (de) 2003-12-17
ZA200306771B (en) 2004-04-29
CN1507368A (zh) 2004-06-23
NO20033859L (no) 2003-09-01
ATE308371T1 (de) 2005-11-15
EP1370342B1 (de) 2005-11-02
NO334708B1 (no) 2014-05-12
EA005631B1 (ru) 2005-04-28
DE50204774D1 (de) 2005-12-08
ES2252450T3 (es) 2006-05-16
CN1269554C (zh) 2006-08-16
NO20033859D0 (no) 2003-09-01

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