KR100803856B1 - 구두 구성 성형품 제조에 적합한, 이산화탄소로 발포된저밀도의 연질 미세다공성 엘라스토머 - Google Patents
구두 구성 성형품 제조에 적합한, 이산화탄소로 발포된저밀도의 연질 미세다공성 엘라스토머 Download PDFInfo
- Publication number
- KR100803856B1 KR100803856B1 KR1020020002643A KR20020002643A KR100803856B1 KR 100803856 B1 KR100803856 B1 KR 100803856B1 KR 1020020002643 A KR1020020002643 A KR 1020020002643A KR 20020002643 A KR20020002643 A KR 20020002643A KR 100803856 B1 KR100803856 B1 KR 100803856B1
- Authority
- KR
- South Korea
- Prior art keywords
- less
- microporous
- density
- isocyanate
- foam
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
- C08J9/04—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent
- C08J9/06—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a chemical blowing agent
- C08J9/08—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a chemical blowing agent developing carbon dioxide
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/40—High-molecular-weight compounds
- C08G18/4009—Two or more macromolecular compounds not provided for in one single group of groups C08G18/42 - C08G18/64
- C08G18/4072—Mixtures of compounds of group C08G18/63 with other macromolecular compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/08—Processes
- C08G18/10—Prepolymer processes involving reaction of isocyanates or isothiocyanates with compounds having active hydrogen in a first reaction step
- C08G18/12—Prepolymer processes involving reaction of isocyanates or isothiocyanates with compounds having active hydrogen in a first reaction step using two or more compounds having active hydrogen in the first polymerisation step
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/40—High-molecular-weight compounds
- C08G18/48—Polyethers
- C08G18/4833—Polyethers containing oxyethylene units
- C08G18/4837—Polyethers containing oxyethylene units and other oxyalkylene units
- C08G18/4841—Polyethers containing oxyethylene units and other oxyalkylene units containing oxyethylene end groups
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/40—High-molecular-weight compounds
- C08G18/48—Polyethers
- C08G18/4866—Polyethers having a low unsaturation value
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/65—Low-molecular-weight compounds having active hydrogen with high-molecular-weight compounds having active hydrogen
- C08G18/6552—Compounds of group C08G18/63
- C08G18/6558—Compounds of group C08G18/63 with compounds of group C08G18/32 or polyamines of C08G18/38
- C08G18/6564—Compounds of group C08G18/63 with compounds of group C08G18/32 or polyamines of C08G18/38 with compounds of group C08G18/3203
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
- C08G18/72—Polyisocyanates or polyisothiocyanates
- C08G18/77—Polyisocyanates or polyisothiocyanates having heteroatoms in addition to the isocyanate or isothiocyanate nitrogen and oxygen or sulfur
- C08G18/78—Nitrogen
- C08G18/79—Nitrogen characterised by the polyisocyanates used, these having groups formed by oligomerisation of isocyanates or isothiocyanates
- C08G18/797—Nitrogen characterised by the polyisocyanates used, these having groups formed by oligomerisation of isocyanates or isothiocyanates containing carbodiimide and/or uretone-imine groups
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
- C08J9/04—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent
- C08J9/12—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a physical blowing agent
- C08J9/122—Hydrogen, oxygen, CO2, nitrogen or noble gases
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G2110/00—Foam properties
- C08G2110/0008—Foam properties flexible
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G2110/00—Foam properties
- C08G2110/0041—Foam properties having specified density
- C08G2110/0066—≥ 150kg/m3
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G2410/00—Soles
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2205/00—Foams characterised by their properties
- C08J2205/06—Flexible foams
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2375/00—Characterised by the use of polyureas or polyurethanes; Derivatives of such polymers
- C08J2375/04—Polyurethanes
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- General Chemical & Material Sciences (AREA)
- Polyurethanes Or Polyureas (AREA)
- Footwear And Its Accessory, Manufacturing Method And Apparatuses (AREA)
- Manufacture Of Porous Articles, And Recovery And Treatment Of Waste Products (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US09/764,682 | 2001-01-18 | ||
| US09/764,682 US6458861B1 (en) | 2001-01-18 | 2001-01-18 | Carbon dioxide blown low density, flexible microcellular elastomers suitable for preparing shoe components |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| KR20020062180A KR20020062180A (ko) | 2002-07-25 |
| KR100803856B1 true KR100803856B1 (ko) | 2008-02-14 |
Family
ID=25071444
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| KR1020020002643A Expired - Fee Related KR100803856B1 (ko) | 2001-01-18 | 2002-01-17 | 구두 구성 성형품 제조에 적합한, 이산화탄소로 발포된저밀도의 연질 미세다공성 엘라스토머 |
Country Status (15)
| Country | Link |
|---|---|
| US (1) | US6458861B1 (enExample) |
| EP (1) | EP1225199B1 (enExample) |
| JP (1) | JP2002241462A (enExample) |
| KR (1) | KR100803856B1 (enExample) |
| AR (1) | AR038656A1 (enExample) |
| AT (1) | ATE289329T1 (enExample) |
| AU (1) | AU1021802A (enExample) |
| BR (1) | BR0200091A (enExample) |
| CA (1) | CA2367077C (enExample) |
| DE (1) | DE60202975T2 (enExample) |
| HU (1) | HUP0200183A3 (enExample) |
| MX (1) | MXPA02000493A (enExample) |
| PL (1) | PL351735A1 (enExample) |
| RU (1) | RU2002100702A (enExample) |
| SK (1) | SK422002A3 (enExample) |
Families Citing this family (32)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| MXPA05000007A (es) * | 2002-06-21 | 2005-04-08 | Recticel | Material de poliuretano fotoestable microcelular o no celular y metodo para produccion del mismo. |
| DE10319393A1 (de) * | 2003-04-30 | 2004-11-18 | Bayer Materialscience Ag | Flexible Formteile aus geschäumten Polyurethan und ihre Verwendung |
| FR2858622B1 (fr) * | 2003-08-08 | 2007-03-30 | Rhodia Polyamide Intermediates | Mousses polyurethane, polyester-polyols pour l'obtention des mousses et utilisation de ces mousses |
| FR2858623B1 (fr) * | 2003-08-08 | 2006-01-13 | Rhodia Polyamide Intermediates | Mousses polyurethannes, procede de fabrication et utilisation de ces mousses |
| DE102004010809A1 (de) * | 2004-03-05 | 2005-09-22 | Bayer Materialscience Ag | Flexible Formteile aus geschäumtem Polyurethan und ihre Verwendung |
| WO2006040333A1 (en) * | 2004-10-15 | 2006-04-20 | Danisco A/S | A foamed isocyanate-based polymer, a mix and process for production thereof |
| US7465757B2 (en) * | 2004-10-15 | 2008-12-16 | Danisco A/S | Foamed isocyanate-based polymer, a mix and process for production thereof |
| US7670501B2 (en) * | 2005-05-27 | 2010-03-02 | Bayer Materialscience Llc | Carbon dioxide blown low density, flexible microcellular polyurethane elastomers |
| ITMI20052257A1 (it) | 2005-11-25 | 2007-05-26 | Basf Ag | Suole intermedie per scarpe dio sicurezza da espanso poliuretano di bassa densita' |
| US20080058468A1 (en) * | 2006-08-31 | 2008-03-06 | Bayer Materialscience Llc | Low density rigid reinforced polyurethanes and a process for their production |
| DE102006042338A1 (de) * | 2006-09-08 | 2008-03-27 | Evonik Goldschmidt Gmbh | Verwendung von Urethan- oder Harnstoffgruppen enthaltenden Polyethern zur Stabilisierung von Polyurethanschäumen |
| WO2009047149A1 (de) * | 2007-10-02 | 2009-04-16 | Basf Se | Niederdichte polyurethanschaumstoffe und deren verwendung in schuhsohlen |
| DE102007050100A1 (de) * | 2007-10-19 | 2009-04-23 | Entwicklungsgesellschaft für Akustik (EfA) mit beschränkter Haftung | Schallisolierung mit CO2-beladener Kompakt-Polyurethan-Schaumstoff (RIM)-Schicht |
| PL2254925T3 (pl) * | 2008-03-14 | 2015-02-27 | Basf Se | Elastomery poliuretanowe o dużych komórkach |
| CN101486788B (zh) * | 2008-12-30 | 2011-09-14 | 浙江华峰新材料股份有限公司 | 一种低密度高硬度聚氨酯微孔弹性体及其制备方法 |
| TWI404739B (zh) * | 2009-04-02 | 2013-08-11 | Chung Hsien Tu | 軟質聚氨酯低回彈發泡體及其製備方法 |
| JP5597380B2 (ja) * | 2009-10-09 | 2014-10-01 | 株式会社ダイフレックス | 手塗り施工用塗工剤 |
| ITMI20110062A1 (it) * | 2011-01-24 | 2012-07-25 | Dow Chemical Co | Poliuretani polieteri con migliore resistenza allo scivolo in condizioni umide |
| US9023910B2 (en) | 2012-01-18 | 2015-05-05 | Basf Se | Low-density polyurethane shoe soles or sole parts with high rebound resilience and low compression set |
| MX2014008617A (es) | 2012-01-18 | 2014-08-21 | Basf Se | Suelas de zapatos de poliuretano de baja densidad o piezas de suelas que tienen alta resiliencia de rebote y un conjunto de compresion baja. |
| US9695266B2 (en) * | 2013-03-06 | 2017-07-04 | Foamtec International Co., Ltd. | Wettable, high strength foam especially for ink holders |
| CN103419371B (zh) * | 2013-08-01 | 2015-06-03 | 四川大学 | 一种具有开孔结构的橡胶泡沫材料的制备方法 |
| CN103627310B (zh) * | 2013-11-01 | 2016-01-06 | 华南理工大学 | 一种环保型聚氨酯塑胶跑道的喷涂面层的制备方法 |
| CN107383322B (zh) * | 2017-08-30 | 2020-12-18 | 中车青岛四方车辆研究所有限公司 | 城轨用低动静刚度比聚氨酯微孔弹性体组合料及制备方法 |
| WO2019057589A1 (en) * | 2017-09-21 | 2019-03-28 | Basf Se | COMPOSITION AND PROCESS FOR PRODUCING MICROCELLULAR POLYURETHANE FOAM SYSTEMS |
| KR101939205B1 (ko) * | 2018-02-22 | 2019-01-17 | 정순구 | 미드솔로 이루어진 기능성 신발 밑창 |
| WO2019178154A1 (en) * | 2018-03-12 | 2019-09-19 | Nike Innovate C.V. | A method for making a thermoplastic foam article |
| GB2600855B (en) | 2019-09-12 | 2024-05-29 | Nike Innovate Cv | A cushioning element for an article of footwear |
| US11447615B2 (en) * | 2019-09-12 | 2022-09-20 | Nike, Inc. | Foam compositions and uses thereof |
| US20230250220A1 (en) * | 2020-07-10 | 2023-08-10 | Basf Se | Process for preparing a crosslinked thermoplastic polyurethane and articles thereof |
| EP4308620A1 (en) * | 2021-03-15 | 2024-01-24 | Toscana Gomma S.p.A. | Process for making a polyurethane gel |
| CN114395105A (zh) * | 2021-12-31 | 2022-04-26 | 广东粤港澳大湾区黄埔材料研究院 | 一种聚氨酯微孔弹性体及应用该弹性体的鞋底材料、减震材料 |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2000002940A2 (en) * | 1998-07-09 | 2000-01-20 | Bayer Antwerpen N.V. | Permanent gas blown microcellular polyurethane elastomers |
| WO2000018817A1 (en) * | 1998-09-25 | 2000-04-06 | BAYER ANTWERPEN N.V. Haven 507 Scheldelaan 420 | Process for making microcellular polyurethane elastomers |
Family Cites Families (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4906672A (en) * | 1988-07-29 | 1990-03-06 | Pmc, Inc. | Blowing agents for polyurethane foam |
| US5120770A (en) | 1989-11-29 | 1992-06-09 | Doyle Earl N | Use of liquid carbon dioxide as a blowing agent in the production of open-cell polyurethane foam |
| US5403088A (en) * | 1993-06-18 | 1995-04-04 | The Dow Chemical Company | Apparatus and method for the dispersion of minute bubbles in liquid materials for the production of polymer foams |
| US5500450A (en) * | 1995-04-05 | 1996-03-19 | The United States Of America As Represented By The Department Of Energy | Ultra-low density microcellular polymer foam and method |
| DE19622742C1 (de) | 1996-06-07 | 1998-03-12 | Hennecke Gmbh | Verfahren zur Schaumherstellung mittels unter Druck gelöstem Kohlendioxid |
| CZ20013066A3 (cs) * | 1999-02-26 | 2001-11-14 | Bayer Antwerpen N. V. | Způsob výroby mikrobuněčných polyurethanových elastomerů se zlepąenou zpracovatelností a elastomery vyrobené tímto způsobem |
-
2001
- 2001-01-18 US US09/764,682 patent/US6458861B1/en not_active Expired - Fee Related
-
2002
- 2002-01-10 CA CA2367077A patent/CA2367077C/en not_active Expired - Fee Related
- 2002-01-11 SK SK42-2002A patent/SK422002A3/sk unknown
- 2002-01-14 MX MXPA02000493A patent/MXPA02000493A/es active IP Right Grant
- 2002-01-15 EP EP02000254A patent/EP1225199B1/en not_active Expired - Lifetime
- 2002-01-15 DE DE60202975T patent/DE60202975T2/de not_active Expired - Lifetime
- 2002-01-15 AT AT02000254T patent/ATE289329T1/de not_active IP Right Cessation
- 2002-01-16 PL PL02351735A patent/PL351735A1/xx not_active Application Discontinuation
- 2002-01-17 RU RU2002100702/12A patent/RU2002100702A/ru not_active Application Discontinuation
- 2002-01-17 HU HU0200183A patent/HUP0200183A3/hu unknown
- 2002-01-17 KR KR1020020002643A patent/KR100803856B1/ko not_active Expired - Fee Related
- 2002-01-17 BR BR0200091-1A patent/BR0200091A/pt not_active Application Discontinuation
- 2002-01-18 AU AU10218/02A patent/AU1021802A/en not_active Abandoned
- 2002-01-18 JP JP2002009870A patent/JP2002241462A/ja active Pending
- 2002-01-18 AR ARP020100189A patent/AR038656A1/es unknown
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2000002940A2 (en) * | 1998-07-09 | 2000-01-20 | Bayer Antwerpen N.V. | Permanent gas blown microcellular polyurethane elastomers |
| WO2000018817A1 (en) * | 1998-09-25 | 2000-04-06 | BAYER ANTWERPEN N.V. Haven 507 Scheldelaan 420 | Process for making microcellular polyurethane elastomers |
Also Published As
| Publication number | Publication date |
|---|---|
| CA2367077C (en) | 2011-03-22 |
| BR0200091A (pt) | 2002-10-22 |
| EP1225199A1 (en) | 2002-07-24 |
| JP2002241462A (ja) | 2002-08-28 |
| ATE289329T1 (de) | 2005-03-15 |
| DE60202975D1 (de) | 2005-03-24 |
| KR20020062180A (ko) | 2002-07-25 |
| HU0200183D0 (en) | 2002-03-28 |
| HUP0200183A3 (en) | 2003-12-29 |
| AR038656A1 (es) | 2005-01-26 |
| US6458861B1 (en) | 2002-10-01 |
| US20020132870A1 (en) | 2002-09-19 |
| RU2002100702A (ru) | 2003-07-20 |
| PL351735A1 (en) | 2002-07-29 |
| SK422002A3 (en) | 2003-07-01 |
| CA2367077A1 (en) | 2002-07-18 |
| MXPA02000493A (es) | 2004-05-21 |
| HUP0200183A2 (hu) | 2002-11-28 |
| DE60202975T2 (de) | 2006-04-13 |
| EP1225199B1 (en) | 2005-02-16 |
| AU1021802A (en) | 2002-07-25 |
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