KR100788743B1 - Manufacturing Method of Eco-Friendly Elastic Chip Using Waste Elastic Materials - Google Patents
Manufacturing Method of Eco-Friendly Elastic Chip Using Waste Elastic Materials Download PDFInfo
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- KR100788743B1 KR100788743B1 KR1020060092594A KR20060092594A KR100788743B1 KR 100788743 B1 KR100788743 B1 KR 100788743B1 KR 1020060092594 A KR1020060092594 A KR 1020060092594A KR 20060092594 A KR20060092594 A KR 20060092594A KR 100788743 B1 KR100788743 B1 KR 100788743B1
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29B—PREPARATION OR PRETREATMENT OF THE MATERIAL TO BE SHAPED; MAKING GRANULES OR PREFORMS; RECOVERY OF PLASTICS OR OTHER CONSTITUENTS OF WASTE MATERIAL CONTAINING PLASTICS
- B29B9/00—Making granules
- B29B9/16—Auxiliary treatment of granules
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29B—PREPARATION OR PRETREATMENT OF THE MATERIAL TO BE SHAPED; MAKING GRANULES OR PREFORMS; RECOVERY OF PLASTICS OR OTHER CONSTITUENTS OF WASTE MATERIAL CONTAINING PLASTICS
- B29B13/00—Conditioning or physical treatment of the material to be shaped
- B29B13/10—Conditioning or physical treatment of the material to be shaped by grinding, e.g. by triturating; by sieving; by filtering
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J11/00—Recovery or working-up of waste materials
- C08J11/04—Recovery or working-up of waste materials of polymers
- C08J11/06—Recovery or working-up of waste materials of polymers without chemical reactions
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29B—PREPARATION OR PRETREATMENT OF THE MATERIAL TO BE SHAPED; MAKING GRANULES OR PREFORMS; RECOVERY OF PLASTICS OR OTHER CONSTITUENTS OF WASTE MATERIAL CONTAINING PLASTICS
- B29B9/00—Making granules
- B29B9/16—Auxiliary treatment of granules
- B29B2009/163—Coating, i.e. applying a layer of liquid or solid material on the granule
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Abstract
Description
도 1은 본 발명의 실시예의 제조 공정도1 is a manufacturing process diagram of an embodiment of the present invention
본 발명은 폐기물 탄성재를 이용한 친환경 탄성칩의 제조 방법에 관한 것이다.The present invention relates to a method for manufacturing an environmentally friendly elastic chip using waste elastic materials.
본 발명은 버려지는 많은 양의 폐기물 탄성재, 예를 들면 폐타이어와 같은 폐고무, 폐우레탄, 폐pvc, 폐비닐을 비롯하여 합성수지 사출공정에서 발생하는 수지 조각 등을 분쇄하여 우레탄 수지와 같은 탄성 도막재로 도막을 형성하고, 토르마린에 의하여 수질을 정화하고 개선하는 작용을 할 수 있는 탄성칩으로 제조되어 배수가 용이하여 스포츠 시설을 비롯한 각종 용도의 투수성 바닥재로 활용할 수 있게 되는 것이다.The present invention pulverizes a large amount of waste elastic materials, for example, waste rubbers such as waste tires, waste urethanes, waste pvc, waste vinyl, resin fragments generated in the synthetic resin injection process, and the like, and elastic coating films such as urethane resins. It is made of an elastic chip that can form a coating film from ash and purify and improve the water quality by tourmaline, so that it can be easily drained and used as a permeable flooring material for various uses including sports facilities.
근래에 도시개발 및 조경공사를 함에 있어서 빗물을 자연적으로 유입되게 할 목적으로 투수성을 가지는 포장이 요구되어 여러가지 투수성을 갖는 탄성 포장재나투수성 콘크리트 등과 같은 제품들이 개발되었으며 이들 제품에 유색도료를 첨가하여 그동안 도로가 일반적인 아스팔트나 콘크리트에 의하여 포장 되어지던 삭막한 도시 환경을 개선하기 위한 시도가 진행되고 있다.In recent years, urban development and landscaping work require permeable pavement for the purpose of natural inflow of rainwater. Products such as elastic pavement and permeable concrete, which have various permeability, have been developed. In addition, attempts have been made to improve the bleak urban environment in which roads have been paved by general asphalt or concrete.
이러한 투수성 도로 포장체는 균열과 침하를 방지할 수 있는 강도를 유지하는 기능과 투수성의 효과 탄성을 갖는 포장체에 관하여 개발이 시도되어 시민의 건강을 고려한 바닥 포장체에 관한 개발, 예를 들면 우수의 수질을 개선 정화하여 지하수 자원을 보존하고 인체에 유익한 효과를 제공하며, 폐고무 조각을 분쇄한 칩을 이용함으로써 친환경적 요소 및 자원절감 차원에서보다 효율적으로 사용할 수 있는 방법에 관한 개발이 시도되고 있다.Such permeable road pavement has been attempted to develop a pavement having a function of maintaining strength to prevent cracking and settlement, and a water-permeable effect elasticity. To improve and purify the water quality of rainwater, to conserve groundwater resources and provide beneficial effects to the human body, and to develop methods that can be used more efficiently in terms of eco-friendliness and resource saving by using chips crushed waste rubber. have.
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본 발명은 폐타이어 고무칩과 같은 폐기물을 작게 분쇄하여 탄성 도막재에 의한 탄성 도막층이 형성되어 일반 우레탄 칩과 같은 상태를 나타내는 것이다. 또한 토르마린으로 우수의 수질을 개선하여 지하 수자원과 지중 생태계에 좋은 영향을 줄 수 있게 하는 것이다.According to the present invention, a waste material such as a waste tire rubber chip is pulverized to a small size to form an elastic coating layer made of an elastic coating material, thereby exhibiting a state similar to that of a general urethane chip. In addition, tourmaline improves the quality of rainwater so that it can have a good effect on underground water resources and underground ecosystems.
토르마린(Tourmaline)은 6각 주상형의 결정을 갖는 봉규산염으로 육방정계에 속하는 천연광물로서 결정 자체가 전기를 발생하는 특성을 가지고 있는 것으로,원석이나 분말은 수분에 닿으면 순간적으로 방전이 되면서 분리된 수소이온(H+)이 마이너스 전극에 끌려서 방출되는 전지와 결합 되어 중화되고 수소가스(H2)가 되어 증발하여 물이 알카리 이온화가 된다. 또 수산이온(OH-)은 주변의 물 분자와 결합하여 히드록실(H3O2) 음이온이라고 하는 계면활성 물질이 된다.Tourmaline is a rod silicate with hexagonal columnar crystals. It is a natural mineral belonging to hexagonal system, and crystal itself generates electricity. The hydrogen ions (H + ) are combined with the discharged battery by being attracted to the negative electrode and neutralized, and the hydrogen ions (H 2 ) are evaporated to alkalinize the water. In addition, hydroxyl ions (OH − ) are bonded to the surrounding water molecules to form a surface active substance called a hydroxyl (H 3 O 2 ) anion.
히드록실 이온은 물을 최적의 pH7.4로 약칼리화 시키고, 발생되는 원적외선은 경이적으로 높은 수치를 나타내서, 강력한 열효과와 높은 침투력으로 인체에 혈액순환촉진, 혈액 정화 및 혈전용해 효과가 있고, 인체 내에서 면역기능을 항상 시키면서 자율신경을 자극하여 교감신경의 흥분을 억제하며 산성화된 인체를 환원시키는 역할을 하는 것이다.The hydroxyl ions weakly water to the optimum pH7.4, and the far-infrared rays generated have a surprisingly high value, and have a strong thermal effect and high penetration to promote blood circulation, blood purification and thrombolysis effect on the human body. While stimulating autonomic nerves while always maintaining immune function in the human body to suppress the excitability of the sympathetic nerve and serves to reduce the acidified human body.
따라서 고무계의 각종 폐기물의 분쇄물을 이용하여 원적외선을 방출하는 기능을 가지는 바닥재를 시공할 수 있게 되면 투수가 가능하면서 토르마린에 의하여 친환경적이고 유익한 환경의 도로를 제공할 수 있게 될 것이다.Therefore, when the flooring material having a function of emitting far infrared rays can be constructed by using crushed products of various kinds of rubber-based wastes, it will be possible to provide a road of environmentally friendly and beneficial environment by tourmaline while being pitched.
이와 같은 목적을 달성하기 위한 본 발명은 분쇄 선별 및 건조된 폐기물 탄성재 80~90중량%와 프라이머 10~20중량%를 교반하여 폐기물 탄성재의 표면에 프라이머를 도포하고; 프라이머가 도포된 폐기물 탄성재 55~70중량%와 탄성 도막재 30~45중량%를 교반하여 폐기물 탄성재의 표면에 1차 탄성 도막을 형성하면서 탄산칼슘을 뿌려서 알갱이 상태의 폐기물 탄성재가 서로 분리되게 하여 1차 양생시키고; 1차 양생된 폐기물 탄성재 60~75중량%와 탄성 도막재 25~40중량%를 교반하여 2차 탄성도막을 형성하고, 2차 탄성도막이 형성된 폐타이어 탄성재 100중량%에 대하여 탄산칼슘 80~95중량%와 토르마린 분말 5~20중량%를 뿌려서 알갱이 상태의 폐기물 탄성재가 서로 붙지않게 분리하여 2차 양생시켜서 되는 것을 기술적인 특징으로 하는 것이다.
상기 폐기물 탄성재는 폐고무, 폐우레탄, 폐pvc, 폐비닐로부터 선택될 수 있다.
상기 탄성 도막재는 우레탄 수지, 고무계 수지, pvc계 수지, 에폭시계 수지, 비닐계 수지, 플라스틱 수지로부터 선택될 수 있다.The present invention for achieving the above object is to apply a primer on the surface of the waste elastic material by stirring the 80 ~ 90% by weight of the waste elastic material and 10 to 20% by weight of the pulverized sorting and dried; 55-70% by weight of the waste elastic material coated with a primer and 30-45% by weight of the elastic coating material are agitated to form a primary elastic coating film on the surface of the waste elastic material, and sprayed with calcium carbonate to separate the granulated waste elastic material from each other. Primary curing; The secondary elastic coating film is formed by stirring 60 to 75% by weight of the primary cured waste elastic material and 25 to 40% by weight of the elastic coating material, and calcium carbonate 80 to 100% by weight of the waste tire elastic material on which the secondary elastic coating film is formed. 95% by weight and 5 to 20% by weight of tourmaline powder are sprinkled with the waste elastic material of the granular state, so as not to stick to each other by the secondary curing.
The waste elastic material may be selected from waste rubber, waste urethane, waste pvc, waste vinyl.
The elastic coating material may be selected from urethane resin, rubber resin, pvc resin, epoxy resin, vinyl resin, plastic resin.
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이와 같은 본 발명은 폐타이어 고무, 고무조각, 신발밑창, 바퀴, PVC, 사출 잔여물 등을 분쇄한 칩 상태의 폐기물 탄성재에 탄성 도막층을 반복하여 형성하여 탄성칩이 만들어지는 것으로 친환경적이고 폐기물 처리와 자원절감의 차원에서 효율적으로 사용할 수 있게 되는 것이다.The present invention is an environment-friendly and waste to make the elastic chip by repeatedly forming an elastic coating layer on the waste elastic material of the chip state crushed waste tire rubber, rubber pieces, shoe soles, wheels, PVC, injection residues, etc. It can be used efficiently in terms of processing and resource saving.
본 발명의 실시예를 구체적으로 설명한다.Embodiments of the present invention will be described in detail.
<실시예 1>
단계 1 (s1, 폐기물 탄성재 준비) <Example 1>
Step 1 ( s1, preparing waste elastomer)
폐타이어 고무, 고무조각, 신발창, 바퀴, 우레탄 등을 수거하여 입자별로 분쇄한다.Waste tire rubber, rubber pieces, soles, wheels, urethane, etc. are collected and crushed by particles.
단계 2 (s2, 칩 선별과정)Step 2 (s2, chip sorting process)
분쇄된 크기별 입자는 1~2mm, 2~3mm, 3~4mm, 7~8mm 등으로 분류한다.The pulverized particles are classified into 1 ~ 2mm, 2 ~ 3mm, 3 ~ 4mm, 7 ~ 8mm and so on.
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단계 3 (s3, 건조하는 과정) Step 3 ( s3, drying process)
건조기에서 폐기물 탄성재의 수분 상태를 체크하면서 건조시켜서 프라이머의 접착력을 증대시킬 수 있게 준비한다.Prepare to increase the adhesive strength of the primer by drying while checking the moisture state of the waste elastic material in the dryer.
단계 4 (s4, 프라이머 도포) Step 4 ( s4, primer applied)
교반기에 폐기물 탄성재 80~90중량%와 프라이머 10~20중량%을 교반하여 폐기물 탄성재에 프라이머가 골고루 도포되도록 교반한다.Stir 80 to 90% by weight of the waste elastic material and 10 to 20% by weight of the primer in the stirrer and stir so that the primer is evenly applied to the waste elastic material.
단계 5 (s5, 1차 탄성 도막층 형성) Step 5 ( s5, forming the primary elastic coating layer)
프라이머가 도포된 폐기물 탄성재 55~70중량%와 탄성 도막재 30~45중량%를 교반하여 폐기물 탄성재에 탄성 도막층을 형성한다.The elastic coating layer is formed on the waste elastic material by stirring 55-70% by weight of the waste elastic material coated with the primer and 30-45% by weight of the elastic coating material.
단계 6 (s6, 분리 과정) Step 6 ( s6, separation process)
탄성 도막층이 형성된 알갱이 상태의 폐기물 탄성재가 서로 붙지 않도록 교반되는 중에 탄산칼슘을 조금씩 뿌려주면서 교반한다.It is stirred while spraying calcium carbonate little by little while stirring so that the waste elastic materials in the granular state in which the elastic coating layer is formed do not stick together.
단계 7 (s7, 1차 탄성 도막층 양생과정) Step 7 ( s7, primary elastic coating layer curing process)
탄산칼슘에 의하여 분리된 상태에서 자연 경화시켜서 알갱이 상태로 양생한다.It naturally hardens in the state separated by calcium carbonate, and it hardens in a granular state.
단계 8 (s8, 2차 탄성 도막층 형성) Step 8 ( s8, forming the second elastic coating layer)
탄성 도막이 형성된 양생된 폐기물 탄성재 60~75중량%와 탄성 도막재 25~40중량%를 교반기에 교반하여 2차 탄성 도막층을 형성한다.60 to 75% by weight of the cured waste elastic material formed with an elastic coating film and 25 to 40% by weight of the elastic coating film material are agitated to form a secondary elastic coating layer.
단계 9 (s9, 2차 탄산칼슘과 토르마린 분말 도포) Step 9 ( s9, application of secondary calcium carbonate and tourmaline powder)
2차 탄성 도막이 형성된 폐기물 탄성재 100중량%당 탄산칼슘 80~95중량%와 토르마린 분말 5~20중량%를 혼합하여 알갱이 상태에서 2차 탄성 도막이 입혀지게 한다.80 to 95% by weight of calcium carbonate and 5 to 20% by weight of tourmaline powder are mixed per 100% by weight of the waste elastic material on which the secondary elastic coating film is formed, so that the secondary elastic coating film is coated in the granular state.
단계 10 (s10, 2차 양생) Step 10 ( s10, secondary curing)
2차 탄성 도막이 형성된 페기물 탄성재를 건조시켜서 양생한다.
상기 실시예에서 폐기물 탄성재의 상태에 따라 탄성 도막을 3차례 이상 형성할 수도 있으나 2차 탄성 도막을 형성하는 것이 가장 바람직하다.The waste elastic material in which the secondary elastic coating film was formed is dried and cured.
In the above embodiment, the elastic coating film may be formed three or more times according to the state of the waste elastic material, but it is most preferable to form the secondary elastic coating film.
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<실시예 2><Example 2>
상기 실시예 1에서 폐기물 탄성재을 폐우레탄 칩으로 대체하고 동일과정에 따라 완성된 탄성칩을 얻었다.In Example 1, the waste elastic material was replaced with the waste urethane chip to obtain a finished elastic chip according to the same process.
<실시예 3><Example 3>
상기 실시예 1에서 폐기물 탄성재을 폐pvc 칩으로 대체하고 동일과정에 따라 완성된 탄성칩을 얻었다.In Example 1, the waste elastic material was replaced with the waste pvc chip, and the elastic chip completed according to the same process was obtained.
<실시예 4><Example 4>
상기 실시예 1에서 폐기물 탄성재을 사출 잔여물으로 대체하고 동일과정에 따라 완성된 탄성칩을 얻었다.In Example 1, the waste elastic material was replaced with the injection residue, and the elastic chip was obtained according to the same process.
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<실시예 5>Example 5
상기 실시예 1에서 폐기물 탄성재를 장판 폐기물로 대체하고 동일과정에 따라 완성된 탄성칩을 얻었다.In Example 1, the waste elastic material was replaced with the jangpan waste, and the elastic chip completed according to the same process was obtained.
<실시예 6><Example 6>
상기 실시예 1에서 폐기물 탄성재를 폐비닐 칩으로 대체하고 동일 과정에 따라 완성된 탄성칩을 얻었다.In Example 1, the waste elastic material was replaced with the waste vinyl chip, and the finished elastic chip was obtained according to the same process.
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이와 같이 상기 방법으로 제조되는 본 발명의 탄성칩은 자전거 도로,스포츠 시설용, 공원, 보행로, 산책로, 놀이터등 다양한 도로 포장용 칩을 제공할 수 있는 것으로 다양한 폐자원을 재활용할 수 있는 친환경적인 제조 방법이다.As described above, the elastic chip of the present invention manufactured by the above method may provide various road pavement chips, such as bicycle roads, sports facilities, parks, pedestrian paths, walkways, and playgrounds. .
토르마린의 일반적인 성분과 특성은 다음의 표 1과 같다.General components and properties of tourmaline are shown in Table 1 below.
탄성 도막재의 일반적인 특성은 표 2와 같다.General characteristics of the elastic coating material are shown in Table 2.
프라이머의 일반적인 특성은 표 3과 같다.General properties of the primers are shown in Table 3.
아스팔트 프라이머의 일반적인 물성 값의 특징은 표 4와 같다.Typical properties of the asphalt primer properties are shown in Table 4.
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이상에서 살펴본 바와 같은 본 발명은 폐타이어와 같은 페고무를 비롯한 폐자원을 이용하여 우레탄 탄성 도막을 입혀 탄성칩으로 제조되며 우수로부터 수질정화, 개선하여 지중생태계 환경에 이로운 효과와 효율적인 재활용 방법으로 폐기처분되는 폐고무를 재활용하게 되어 자원의 효율적 재분배 효과가 크다.As described above, the present invention is made of an elastic chip coated with a urethane elastic coating film using waste resources such as waste rubber such as waste tires, and purified and improved from rainwater to be disposed of by the beneficial effect and efficient recycling method for the underground ecosystem environment. The waste rubber that is disposed of is recycled, and the resource redistribution effect is large.
폐자원 칩을 이용하여 우레탄 탄성 도막을 입혀서 탄성을 갖게 하므로 도로 포장체의 재료 효과와 포장하여 인체에 유익하고 탄성으로 인하여 보행시의 충격을 완화시키고 원적외선 방사 효과와 계면 활성 환원작용에 의하여 인체에 유익하고 지하수 자원을 자원활용과 환경개선으로 이완시켜 주는 효과가 있는 것으로 도로 포장체, 건축용 재료에 효과적으로 사용될 수 있는 것이다.The urethane elastic coating film is used to make elasticity by using waste resources chip, so it is beneficial to the human body by paving the material effect and pavement of the road pavement, and the impact on walking is alleviated due to the elasticity. It is beneficial and can relax groundwater resources through resource utilization and environmental improvement, and can be effectively used for road pavement and building materials.
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Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
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CN102345250A (en) * | 2010-07-29 | 2012-02-08 | 郑镇度 | Method of manufacturing board with leather by-products and board manufactured by adopting the method |
Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH07292238A (en) * | 1994-04-28 | 1995-11-07 | Shikoku Chem Corp | Elastic pavement |
KR20010078548A (en) * | 2000-02-09 | 2001-08-21 | 정해은 | Manufacturing method of guardrail |
KR20010080851A (en) * | 2000-02-11 | 2001-08-25 | 박기철 | Method for surface treating using powder of used-up urethane or rubber |
KR20040110041A (en) * | 2003-06-20 | 2004-12-29 | (주) 이엔비 글로벌 | Method for manufacturing effervescent heat insulating, sound insulating and shielding sheet by liquefying waste tire and synthesizing the same with waste urethane to assure safety of heat and sound insulating |
KR20060081182A (en) * | 2005-01-07 | 2006-07-12 | 이형경 | Manufacture method of sheet using eco-leather |
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2006
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Patent Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH07292238A (en) * | 1994-04-28 | 1995-11-07 | Shikoku Chem Corp | Elastic pavement |
KR20010078548A (en) * | 2000-02-09 | 2001-08-21 | 정해은 | Manufacturing method of guardrail |
KR20010080851A (en) * | 2000-02-11 | 2001-08-25 | 박기철 | Method for surface treating using powder of used-up urethane or rubber |
KR20040110041A (en) * | 2003-06-20 | 2004-12-29 | (주) 이엔비 글로벌 | Method for manufacturing effervescent heat insulating, sound insulating and shielding sheet by liquefying waste tire and synthesizing the same with waste urethane to assure safety of heat and sound insulating |
KR20060081182A (en) * | 2005-01-07 | 2006-07-12 | 이형경 | Manufacture method of sheet using eco-leather |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN102345250A (en) * | 2010-07-29 | 2012-02-08 | 郑镇度 | Method of manufacturing board with leather by-products and board manufactured by adopting the method |
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