KR20010080851A - Method for surface treating using powder of used-up urethane or rubber - Google Patents

Method for surface treating using powder of used-up urethane or rubber Download PDF

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KR20010080851A
KR20010080851A KR1020000006427A KR20000006427A KR20010080851A KR 20010080851 A KR20010080851 A KR 20010080851A KR 1020000006427 A KR1020000006427 A KR 1020000006427A KR 20000006427 A KR20000006427 A KR 20000006427A KR 20010080851 A KR20010080851 A KR 20010080851A
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urethane
waste
rubber
powder
regenerated
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KR1020000006427A
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Korean (ko)
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KR100369700B1 (en
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박기철
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박기철
(주)알엔씨
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    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02WCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W30/00Technologies for solid waste management
    • Y02W30/50Reuse, recycling or recovery technologies
    • Y02W30/62Plastics recycling; Rubber recycling

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  • Separation, Recovery Or Treatment Of Waste Materials Containing Plastics (AREA)
  • Processing And Handling Of Plastics And Other Materials For Molding In General (AREA)

Abstract

PURPOSE: A method for treating surface by using powder of waste urethane or waste resin is provided to save the resource with increasing recycling of the waste urethane and the waste resin by reclaiming the waste urethane or the waste resin and applying it to the surface of a structure and to reduce the environmental pollution. CONSTITUTION: In the method for treating surface by using powder of waste urethane or waste resin, a few stages are included. In the drying stage, the reclaimed urethane powder or the reclaimed resin powder is dried through an indirect heat wind machine and a dehumidifier in the temperature of 70-120 deg.C for 10-15 minutes and the drying degree over 98 % is maintained. In the combining stage, the reclaimed urethane pulverized material or the reclaimed resin pulverized material of 100Kg, the solvent of 5-10Kg, the adhesive of 20-40Kg and the hardener of 2-5Kg are injected into a combining machine and are stirred. In the surface treating stage, the water and the alien material are removed from the surface and the prima surface treatment is carried out in the clean condition. In the urethane or resin layer forming stage, the reclaimed urethane mixed material or the reclaimed resin mixed material are sprayed on the place, which is to be constructed, and an urethane or resin layer is formed with the appropriate thickness. In the drying stage, the urethane or resin layer is naturally dried.

Description

폐우레탄 또는 폐고무의 분말을 이용한 표면 처리방법 {Method for surface treating using powder of used-up urethane or rubber}{Method for surface treating using powder of used-up urethane or rubber}

본 발명은 폐우레탄 또는 폐고무의 분말을 이용한 표면 처리방법에 관한 것으로, 상세하게는 산업폐기물인 폐우레탄 또는 폐고무를 재활용하여 건축물의 표면 처리재료로 사용할 수 있도록 하고 이로 인하여 자원을 절약하며 환경오염을 억제시킬 수 있도록 하는 폐우레탄 또는 폐고무의 분말을 이용한 표면 처리방법에 관한 것이다.The present invention relates to a surface treatment method using waste urethane or waste rubber powder, and more particularly, to recycle waste urethane or waste rubber, which is an industrial waste, to be used as a surface treatment material of a building, thereby saving resources and environment. The present invention relates to a surface treatment method using powder of waste urethane or waste rubber to suppress contamination.

일반적으로 우레탄과 고무는 탄력성, 내마모성, 내산화성, 내유성, 내노화성, 단열성 및 기계적 강도의 우수성으로 인하여 산업 전반에 걸쳐 널리 사용되고 있고 따라서 많은 량의 폐우레탄과 폐고무가 발생하고 해마다 그 량이 증가하고 있는 추세이다.In general, urethanes and rubbers are widely used throughout the industry due to their excellent elasticity, abrasion resistance, oxidation resistance, oil resistance, aging resistance, thermal insulation, and mechanical strength, so that a large amount of waste urethane and waste rubber are generated, and the amount is increased year by year. There is a trend.

특히, 이러한 폐우레탄과 폐고무는 단순 폐기하므로 자원 재활용도가 크게 떨어져 자원의 낭비를 초래할 뿐 아니라 수입에 의존하고 있는 현실을 감안할 때 국가적으로도 상당한 외화의 낭비를 초래하였다.In particular, since the waste urethane and waste rubber are simply disposed, the recycling of resources is greatly reduced, leading to a waste of resources, and in consideration of the fact that they depend on imports, it also causes a considerable waste of foreign currency in the country.

또한, 폐우레탄과 폐고무의 단순 폐기로 산업쓰레기의 량을 증가시키고 상기한 특성으로 장기간 분해되지 못하여 환경오염을 가중시킬 뿐 아니라 재활용에 따른 여러 가지 문제점을 발생시켰다.In addition, the simple disposal of waste urethane and waste rubber increases the amount of industrial waste and can not be decomposed for a long time due to the above characteristics, thereby increasing environmental pollution and causing various problems due to recycling.

따라서, 본 발명의 폐우레탄 또는 폐고무를 재생하여 건축물의 표면에 도포하여 표면처리할 수 있도록 함으로써, 폐우레탄과 폐고무의 재활용도를 증대시켜 자원을 절약하고 폐우레탄과 폐고무로 인한 쓰레기 량을 최소화시켜 환경오염을 줄일 수 있도록 하는데 있다.Therefore, by recycling the waste urethane or waste rubber of the present invention to be applied to the surface of the building and surface treatment, to increase the recycling degree of waste urethane and waste rubber to save resources and the amount of waste due to waste urethane and waste rubber To minimize environmental pollution.

위와 같은 목적을 달성하기 위하여 본 발명의 폐우레탄 또는 폐고무의 분말을 이용한 표면 처리방법은 산업폐기물인 폐우레탄 또는 폐고무를 수거하여 색상별로 분리하는 분리단계와, 상기 분리단계에서 분리된 폐우레탄 또는 폐고무에 부착된 오물 등의 이 물질을 제거하는 세척단계와, 상기 세척단계에서 세척된 깨끗한 상태의 폐우레탄 또는 폐고무를 필요한 입자의 크기로 분쇄하는 분쇄단계와, 상기 분쇄단계에서 분쇄된 입자 상태의 폐우레탄 또는 폐고무를 간접열풍으로 건조시키는 건조단계와, 상기 건조단계를 거친 입자 상태의 폐우레탄 또는 폐고무를 혼합하여 배합기에 넣고 착색제와 스테아르산, CaO 및 Ca을 투입하여 교반하는 배합단계와, 상기 배합단계에서 각종 첨가물이 혼합된 입자 상태의 폐우레탄 또는 폐고무를압출기로 용융시키는 용융단계와, 상기 용융단계에서 용융된 폐우레탄 혼합물 또는 폐고무를 강제 냉각시킴과 동시에 필요한 두께로 압착하는 압착단계와, 상기 압착단계에서 압착된 폐우레탄 또는 폐고무 혼합물을 일정크기로 절단한 다음 필요한 입자크기로 분쇄하는 재생단계로 형성한 폐우레탄 재생방법에 있어서; 상기 재생 우레탄 분말 또는 재생고무 분말을 건조시키는 건조단계와, 상기 건조단계에서 건조된 재생 우레탄 분말 또는 재생 고무 분말을 배합기에 넣고 특수 변성 폴리우레탄수지, 경화제, 접착제 및 용해제를 투입하여 골고루 교반하여 혼합하는 배합단계와, 상기 배합단계의 재생 우레탄 또는 재생 고무 혼합물을 도포하고자 하는 건축물 또는 일반타일의 표면에 수분 및 이 물질을 제거한 다음 프라이마 표면처리하는 표면처리 단계와, 상기 배합단계에서의 재생 우레탄 또는 재생 고무 혼합물을 표면처리된 면에 살포하여 도포하는 스프레이단계와, 상기 스프레이단계에서 도포된 재생 우레탄 층 또는 고무 층을 완전 건조시키는 완성단계로 구성함을 그 기술적 구성상의 기본 특징으로 한다.In order to achieve the above object, the surface treatment method using the waste urethane or waste rubber powder of the present invention is a separation step of separating the waste urethane or waste rubber, which is industrial waste by color, and the waste urethane separated in the separation step. Or a washing step of removing foreign matters such as dirt attached to the waste rubber, and a grinding step of grinding waste urethane or waste rubber in a clean state washed in the washing step to the size of the required particles, and The drying step of drying the waste urethane or waste rubber in the form of granules by indirect hot air, and mixing the waste urethane or waste rubber in the granular state after the drying step is added to the blender and stirred by adding colorant, stearic acid, CaO and Ca. The mixing step and the waste urethane or waste rubber in the form of particles in which various additives are mixed in the mixing step are melted by an extruder. After the melting step and the forced urethane mixture or waste rubber melted in the melting step and forced compression at the same time to the required thickness, and cutting the waste urethane or waste rubber mixture compressed in the pressing step to a predetermined size In the waste urethane recycling method formed by the regeneration step of grinding to the required particle size; Drying step of drying the regenerated urethane powder or regenerated rubber powder, and the regenerated urethane powder or regenerated rubber powder dried in the drying step into a blender, mixed with specially mixed polyurethane resin, curing agent, adhesive and dissolving agent And a surface treatment step of removing the moisture and the substance from the surface of the building or the general tile to which the recycled urethane or the regenerated rubber mixture of the compounding step is to be applied and then subjecting the surface to the prima; Or a spraying step of spraying and applying the regenerated rubber mixture onto the surface-treated surface, and a completion step of completely drying the regenerated urethane layer or rubber layer applied in the spraying step.

이러한 본 발명의 실시 예를 보다 상세하게 설명하면 다음과 같다.When explaining the embodiment of the present invention in more detail as follows.

(실시예)(Example)

제 1 공정1st process

먼저, 각종 산업쓰레기 등에서 폐우레탄 또는 폐고무를 분리하여 수거한 후 일정장소에 적재한다.First, waste urethane or rubber is separated and collected from various industrial wastes, and then loaded at a predetermined place.

이러한 폐우레탄 또는 폐고무에 혼입된 이물질을 수작업으로 제거하되 자석을 이용하여 각종 금속 또한 제거한다.The foreign substances mixed in such waste urethane or waste rubber are manually removed, but various metals are also removed using a magnet.

여기서 대량의 폐우레탄 또는 폐고무를 세척하는 경우 세척기를 이용하여 세척한 후 금속을 제거함이 바람직하다.Here, when washing a large amount of waste urethane or waste rubber, it is preferable to remove the metal after washing using a washing machine.

이 물질이 제거된 폐우레탄 또는 폐고무는 분쇄기를 통하여 필요한 크기로 선택하여 분쇄한 다음 70℃-120℃의 간접열풍(열 건조식)으로 10분에서 15분 정도 가열하여 건조도가 98%이상 되도록 한다.Waste urethane or rubber from which this substance has been removed is selected and pulverized through a crusher and then heated in an indirect hot air (heat-drying) at 70 ℃ -120 ℃ for 10 to 15 minutes, and the dryness is over 98%. Be sure to

여기서 분쇄되는 폐우레탄 또는 폐고무의 입자크기는 11-2.5mm가 가장 바람직하다.The particle size of the waste urethane or waste rubber to be crushed here is most preferably 11-2.5mm.

상기와 같이 분쇄하여 건조시킨 폐우레탄 또는 폐고무 100Kg에 대하여 유, 무기 착색제인 안료나 염료를 일정량 투입하고 착색 반응과 용융이 원활하도록 포화 지방산인 스테아르산 2-3Kg, 2차 제습을 위한 CaO 2-3Kg 및 폐우레탄 또는 폐고무의 용융이 원활하도록 하고 경도 등을 조절하기 위하여 Ca를 0-15Kg 배합기에 투입한 후 교반하여 골고루 혼합한다.100 Kg of the waste urethane or rubber pulverized and dried as described above is charged with a certain amount of pigments or dyes, which are organic and inorganic colorants, and 2-3Kg of saturated fatty acid stearic acid to facilitate coloring reaction and melting, and CaO 2 for secondary dehumidification. In order to smoothly melt -3Kg and waste urethane or waste rubber, and adjust hardness, etc., Ca is added to a 0-15Kg blender and stirred and mixed evenly.

여기서 배합기 내부는 70℃-100℃ 정도의 가열상태를 유지하면서 10분에서 15분 정도 중속 배합하여 혼합물을 생성시킨다.Here, the inside of the blender is blended at a medium speed of about 10 to 15 minutes while maintaining a heated state of about 70 ° C.-100 ° C. to generate a mixture.

이러한 혼합물은 압출기를 이용하여 용융시킨 다음 강제 냉각을 통하여 필요한 두께로 프레싱하여 압착시킨다.This mixture is melted using an extruder and then pressed to compression to the required thickness through forced cooling.

여기서 압출기 내부는 170℃-230℃의 온도를 유지하도록 한다.Here, the inside of the extruder to maintain a temperature of 170 ℃-230 ℃.

또, 강제 냉각은 0℃-5℃로 직접 냉각하여 냉각시킨다.In addition, forced cooling cools directly by 0 degreeC-5 degreeC.

또한, 프레싱하여 압착시키는 혼합물의 두께는 1.5-7mm 정도가 바람직하다.In addition, the thickness of the mixture pressed and pressed is preferably about 1.5-7 mm.

이렇게 압착시킨 폐우레탄 또는 폐고무는 일정크기 이하로 절단하고, 절단된 폐우레탄 또는 폐고무는 다시 필요한 입자 크기로 선택하여 분쇄한다.Thus compressed waste urethane or waste rubber is cut to a predetermined size or less, and the cut waste urethane or waste rubber is selected and ground again to the required particle size.

여기서 분쇄된 입자와 분쇄로 발생되는 미분을 분리하여 재생우레탄 분말 또는 폐고무 분말을 취득한다.Here, the pulverized particles and the fine powder generated by the pulverization are separated to obtain recycled urethane powder or waste rubber powder.

제2공정2nd process

재생 가공된 재생우레탄 분말 또는 재생고무 분말을 간접 열풍기와 제습기를 통하여 70℃-120℃ 상태에서 약 10분에서 15분 정도 건조시켜 건조도를 98%이상 유지하도록 한다.The recycled regenerated urethane powder or regenerated rubber powder is dried for about 10 to 15 minutes at 70 ° C.-120 ° C. through an indirect hot air blower and a dehumidifier to maintain a dryness of 98% or more.

이렇게 건조된 재생우레탄 분말 또는 재생고무 분말 100Kg에 대하여 특수 변성 폴리우레탄과 경화제를 2-5Kg, 접착제 20-40Kg, 용해제 5-10Kg를 배합기에 투입하여 골고루 교반하여 충분히 배합한다.To this dry regenerated urethane powder or regenerated rubber powder 100Kg, 2-5Kg of specially modified polyurethane and a curing agent, 20-40Kg of adhesive, and 5-10Kg of a dissolving agent are added to the blender, and the mixture is thoroughly stirred to mix well.

여기서 용해제는 토루엔을 사용함이 바람직하다.It is preferable to use toluene here as a solubilizer.

한편, 건축물 등의 시공 부위 표면에 수분과 이 물질을 제거하여 청결한 상태를 유지시킨 상태에서 프라이마 표면처리를 완벽하게 진행시킨다.On the other hand, the surface of the construction site, such as buildings, removes moisture and foreign substances to keep the surface of the prima completely in a clean state.

여기서 일반타일의 경우에는 반가공 상태의 타일표면에 프라이마 표면처리하지 않아도 무방하다.In the case of the general tile, the surface of the tile in the semi-processed state does not have to be treated with a prima.

이러한 상태에서 배합기에서 충분히 교반시킨 재생 우레탄 혼합물 또는 재생 고무 혼합물을 스프레이 건 등으로 이용하여 시공부위 또는 일반타일 표면에 1-3 정도 살포하여 적정 두께로 도포한다.In such a state, the regenerated urethane mixture or regenerated rubber mixture sufficiently stirred in the blender is sprayed on the surface of the construction site or the general tile by using a spray gun, etc., and applied at an appropriate thickness.

건축물의 시공 부위 등에 재생 우레탄 분말 또는 재생 고무 분말 도포가 완료되면 자연 건조시켜 표면에 재생우레탄 층이 형성되게 한다.When the application of the recycled urethane powder or the recycled rubber powder is completed, such as construction site of the building is dried naturally to form a recycled urethane layer on the surface.

한편, 도로 등의 포장에는 아스팔트 층이나 콘크리트 층의 표면에 입자 상태의 재생 우레탄 또는 재생 고무를 일정두께로 도포한 다음 재생우레탄 분말 또는 재생 고무 분말을 상기와 같이 살포하여 도포하는 경우도 있다.On the other hand, pavement such as road may be applied by spraying the regenerated urethane powder or the regenerated rubber powder in the above-described manner on the surface of the asphalt layer or the concrete layer with a certain thickness.

본 발명은 단순히 재생 우레탄 분말 또는 재생 고무 분말만을 사용하는 것이 아니며 필요에 따라 재생 우레탄 분말과 재생 고무 분말을 혼합하여 사용할 수 도 있다.The present invention does not merely use regenerated urethane powder or regenerated rubber powder, but may be used by mixing regenerated urethane powder and regenerated rubber powder, if necessary.

따라서, 이러한 시공은 재생 우레탄 분말 또는 재생 고무 분말을 이용하므로 방수, 방음, 내한성 및 내마모성이 뛰어날 뿐 아니라 범용성이 매우 넓은 특징이 있다.Therefore, such a construction uses regenerated urethane powder or regenerated rubber powder, so it is excellent in water resistance, soundproofing, cold resistance, and abrasion resistance, and has a very wide versatility.

이상에서 살펴본 바와 같이, 본 발명의 폐우레탄 또는 폐고무의 분말을 이용한 표면 처리방법은 재생우레탄 분말 또는 재생고무 분말을 건조시키는 건조단계와, 상기 건조단계에서 건조된 재생우레탄 분말 또는 재생고무 분말에 특수 변성 폴리우레탄수지, 경화제, 접착제 및 용해제를 함께 배합기에 투입하여 혼합하는 배합단계와, 상기 배합단계의 혼합물을 도포하고자 하는 건축물의 표면에 수분 및 이 물질을 제거한 다음 프라이마 표면처리하는 표면처리 단계와, 상기 배합단계에서의 혼합물을 표면처리된 면에 살포하여 도포하는 스프레이단계와, 상기 스프레이단계에서 도포된 재생우레탄 층 또는 재생고무 층을 완전 건조시키는 완성단계로 구성하므로 폐우레탄 또는 폐고무를 재생하여 건축물의 바닥면 또는 일반타일의 표면에 도포하거나 도로의 상면에 도포하여 표면처리할 수 있도록 함으로써, 폐우레탄 또는 폐고무의 재활용도를 증대시켜 자원을 절약하고 폐우레탄 또는 폐고무로 인한 쓰레기 량을 최소화시켜 환경오염을 줄일 수 있는 효과가 있다.As described above, the surface treatment method using the waste urethane or waste rubber powder of the present invention is a drying step of drying the recycled urethane powder or recycled rubber powder, and the regenerated urethane powder or recycled rubber powder dried in the drying step Specially modified polyurethane resin, hardener, adhesive and dissolving agent are added together into the blender to mix and the surface treatment to remove water and foreign substances on the surface of the building to apply the mixture of the above blending step Waste urethane or waste rubber because it comprises a spraying step of applying by spraying the mixture in the compounding step on the surface treated, and a complete drying of the regenerated urethane layer or regenerated rubber layer applied in the spraying step By regenerating and applying to the floor of building or surface of general tile By applying to the upper surface of the furnace surface treatment, it is possible to reduce the environmental pollution by increasing the recycling degree of waste urethane or waste rubber to save resources and minimize the amount of waste caused by waste urethane or waste rubber.

Claims (1)

산업폐기물인 폐우레탄 또는 페고무를 수거하여 색상별로 분리하는 분리단계와, 상기 분리단계에서 분리된 폐우레탄 또는 폐고무에 부착된 오물 등의 이 물질을 제거하는 세척단계와, 상기 세척단계에서 세척된 깨끗한 상태의 폐우레탄 또는 폐고무를 필요한 입자의 크기로 분쇄하는 분쇄단계와, 상기 분쇄단계에서 분쇄된 입자 상태의 폐우레탄 또는 폐고무를 간접열풍으로 건조시키는 건조단계와, 상기 건조단계를 거친 입자 상태의 폐우레탄 또는 폐고무를 배합기에 넣고 착색제와 스테아르산, CaO 및 Ca을 투입하여 교반하는 배합단계와, 상기 배합단계에서 각종 첨가물이 혼합된 입자 상태의 폐우레탄 또는 폐고무를 압출기로 용융시키는 용융단계와, 상기 용융단계에서 용융된 폐우레탄 혼합물 또는 폐고무 혼합물을 강제 냉각시키고 이와 동시에 필요한 두께로 압착하는 압착단계와, 상기 압착단계에서 압착된 폐우레탄 혼합물 또는 폐고무를 일정크기로 절단한 다음 필요한 입자크기로 분쇄하는 재생단계로 형성한 폐우레탄 또는 폐고무 재생방법에 있어서;A separation step of collecting waste urethane or pego rubber, which is industrial waste, and separating it by color; a washing step of removing foreign substances such as waste urethane or waste rubber attached to the separation step; and washing in the washing step A grinding step of grinding the waste urethane or waste rubber in a clean state to a required particle size; and a drying step of drying the waste urethane or waste rubber ground in the grinding step with indirect hot air, and the drying step Putting the waste urethane or waste rubber in the granular state into a blender, and mixing the colorant and stearic acid, CaO and Ca, and stirring, and melting the waste urethane or waste rubber in the form of granules mixed with various additives in the blending step with an extruder. Melting step and forced cooling of the waste urethane mixture or waste rubber mixture melted in the melting step In the crimping step of crimping to the required thickness, and the waste urethane or waste rubber recycling method formed by the waste urethane mixture or waste rubber compressed in the crimping step to a predetermined size and then crushed to the required particle size; 상기 재생 가공된 재생우레탄 분말 또는 재생고무 분말을 간접 열풍기와 제습기를 통하여 70℃-120℃ 상태에서 약 10분에서 15분 정도 건조시켜 건조도를 98%이상 유지하도록 하는 건조단계와,A drying step of drying the regenerated processed regenerated urethane powder or regenerated rubber powder by using an indirect hot air blower and a dehumidifier at a temperature of 70 ° C.-120 ° C. for about 10 to 15 minutes to maintain a dryness of at least 98%; 상기 건조단계에서 건조된 재생 우레탄 분말 또는 재생고무 분말 100Kg에 넣고 특수 변성 폴리우레탄과 경화제를 2-5Kg, 접착제 20-40Kg, 용해제 5-10Kg를 배합기에 투입하여 골고루 교반하는 혼합하는 배합단계와,The mixing step of mixing evenly stirred by putting into the regenerated urethane powder or regenerated rubber powder 100Kg dried in the drying step 2-5Kg, 2-40Kg adhesive, 20-40Kg adhesive, 5-10Kg dissolving agent in a blender, 상기 배합단계에서 배합된 재생 우레탄 혼합물 또는 재생 고무 혼합물을 도포할 건축물의 시공 부위 표면에 수분과 이 물질을 제거하여 청결한 상태를 유지시킨 상태에서 프라이마 표면처리하는 표면 처리단계와,A surface treatment step of treating the surface of the prima in a state in which it is kept clean by removing moisture and the substance on the surface of the construction site of the building to which the recycled urethane mixture or recycled rubber mixture blended in the compounding step is applied; 상기 표면 처리단계가 끝난 시공부위에 재생 우레탄 혼합물 또는 재생 고무 혼합물을 스프레이 건 등으로 이용하여 시공부위에 1-3회 정도 살포하여 적정 두께로 형성시키는 우레탄 층 또는 고무 층 형성단계와,Forming a urethane layer or a rubber layer by spraying the regenerated urethane mixture or the regenerated rubber mixture to the construction site by using a spray gun, etc., 1-3 times to the construction site after the surface treatment step is completed, and forming a proper thickness; 상기 우레탄 층 또는 고무 층 형성단계에서 도포된 우레탄 층 또는 고무 층을 자연 건조시키는 건조단계로 구성한 것을 특징으로 하는 폐우레탄 또는 폐고무의 분말을 이용한 표면 처리방법.The surface treatment method using the powder of the waste urethane or waste rubber, characterized in that consisting of a drying step of naturally drying the urethane layer or rubber layer applied in the urethane layer or rubber layer forming step.
KR10-2000-0006427A 2000-02-11 2000-02-11 Method for surface treating using powder of used-up urethane or rubber KR100369700B1 (en)

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