KR100755525B1 - Hair coloring composition comprising cephalopoda ink extracts - Google Patents

Hair coloring composition comprising cephalopoda ink extracts Download PDF

Info

Publication number
KR100755525B1
KR100755525B1 KR1020060077500A KR20060077500A KR100755525B1 KR 100755525 B1 KR100755525 B1 KR 100755525B1 KR 1020060077500 A KR1020060077500 A KR 1020060077500A KR 20060077500 A KR20060077500 A KR 20060077500A KR 100755525 B1 KR100755525 B1 KR 100755525B1
Authority
KR
South Korea
Prior art keywords
weight
hair
hair dye
dye composition
agent
Prior art date
Application number
KR1020060077500A
Other languages
Korean (ko)
Inventor
이원기
Original Assignee
이원기
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by 이원기 filed Critical 이원기
Priority to KR1020060077500A priority Critical patent/KR100755525B1/en
Priority to PCT/KR2007/003944 priority patent/WO2008020730A1/en
Application granted granted Critical
Publication of KR100755525B1 publication Critical patent/KR100755525B1/en

Links

Images

Classifications

    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/96Cosmetics or similar toiletry preparations characterised by the composition containing materials, or derivatives thereof of undetermined constitution
    • A61K8/98Cosmetics or similar toiletry preparations characterised by the composition containing materials, or derivatives thereof of undetermined constitution of animal origin
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/33Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
    • A61K8/34Alcohols
    • A61K8/345Alcohols containing more than one hydroxy group
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/40Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
    • A61K8/42Amides
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/73Polysaccharides
    • A61K8/731Cellulose; Quaternized cellulose derivatives
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/81Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
    • A61K8/817Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a single or double bond to nitrogen or by a heterocyclic ring containing nitrogen; Compositions or derivatives of such polymers, e.g. vinylimidazol, vinylcaprolactame, allylamines (Polyquaternium 6)
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/84Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
    • A61K8/89Polysiloxanes
    • A61K8/891Polysiloxanes saturated, e.g. dimethicone, phenyl trimethicone, C24-C28 methicone or stearyl dimethicone
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/84Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
    • A61K8/89Polysiloxanes
    • A61K8/891Polysiloxanes saturated, e.g. dimethicone, phenyl trimethicone, C24-C28 methicone or stearyl dimethicone
    • A61K8/894Polysiloxanes saturated, e.g. dimethicone, phenyl trimethicone, C24-C28 methicone or stearyl dimethicone modified by a polyoxyalkylene group, e.g. cetyl dimethicone copolyol
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/96Cosmetics or similar toiletry preparations characterised by the composition containing materials, or derivatives thereof of undetermined constitution
    • A61K8/97Cosmetics or similar toiletry preparations characterised by the composition containing materials, or derivatives thereof of undetermined constitution from algae, fungi, lichens or plants; from derivatives thereof
    • A61K8/9783Angiosperms [Magnoliophyta]
    • A61K8/9789Magnoliopsida [dicotyledons]
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/96Cosmetics or similar toiletry preparations characterised by the composition containing materials, or derivatives thereof of undetermined constitution
    • A61K8/98Cosmetics or similar toiletry preparations characterised by the composition containing materials, or derivatives thereof of undetermined constitution of animal origin
    • A61K8/987Cosmetics or similar toiletry preparations characterised by the composition containing materials, or derivatives thereof of undetermined constitution of animal origin of species other than mammals or birds
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61QSPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q5/00Preparations for care of the hair
    • A61Q5/06Preparations for styling the hair, e.g. by temporary shaping or colouring
    • A61Q5/065Preparations for temporary colouring the hair, e.g. direct dyes
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61QSPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q5/00Preparations for care of the hair
    • A61Q5/10Preparations for permanently dyeing the hair
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K2800/00Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
    • A61K2800/40Chemical, physico-chemical or functional or structural properties of particular ingredients
    • A61K2800/42Colour properties
    • A61K2800/43Pigments; Dyes
    • A61K2800/432Direct dyes
    • A61K2800/4324Direct dyes in preparations for permanently dyeing the hair

Landscapes

  • Life Sciences & Earth Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • General Health & Medical Sciences (AREA)
  • Veterinary Medicine (AREA)
  • Public Health (AREA)
  • Animal Behavior & Ethology (AREA)
  • Epidemiology (AREA)
  • Birds (AREA)
  • Emergency Medicine (AREA)
  • Zoology (AREA)
  • Engineering & Computer Science (AREA)
  • Biotechnology (AREA)
  • Botany (AREA)
  • Microbiology (AREA)
  • Mycology (AREA)
  • Cosmetics (AREA)

Abstract

A hair coloring composition comprising the ink extract of Cephalopoda is provided to minimize hair damage and skin troubles and allergies in the scalp after hair coloring by reducing skin irritation, eliminating or minimizing the amount of an alkalizing agent used and inhibiting hair swelling due to high pH. A hair coloring composition comprising an oxidation dye selected from m-aminophenol, resorcine, p-phenylenediamine and p-aminophenol, a chelating agent, antioxidant, emulsifier, a thickening agent, a solubilizing agent, preservative, solvent, a flavoring agent, a pH regulating agent, humectant, stabilizer, an alkalizing agent, a hair protecting agent selected from methylpolysiloxane emulsion, dimethicone/dimethylconol(gum 20%), henna extract, urea, DL panthenol, polyquaternium-7, hydroxyethylcellulose, hydrolyzed silk and polyquaternium-10, and oxidant further comprises 0.01-10 wt.% of the ink extract of Cephalopoda and has pH 6.5-7.2.

Description

두족류의 먹물추출물을 포함한 염모제 조성물{HAIR COLORING COMPOSITION COMPRISING CEPHALOPODA INK EXTRACTS}Hair dye composition including cephalopod ink extract {HAIR COLORING COMPOSITION COMPRISING CEPHALOPODA INK EXTRACTS}

도 1은 두족류의 먹물추출물을 포함한 염모제 조성물의 제조 공정도,1 is a manufacturing process diagram of the hair dye composition containing cephalopod ink extract,

도 2는 산화제를 포함한 염모제 조성물의 제조 공정도이다. 2 is a manufacturing process chart of a hair dye composition including an oxidizing agent.

본 발명은, 염모제 조성물에 관한 것으로서, 특히 두족류의 먹물추출물을 포함하여 염색 안정성을 향상시키고, 모발손상방지 효과를 가지며, 새치머리, 흰머리 및 탈색된 모발의 색상을 자연스러운 원래의 모발색상으로 염색할 수 있도록 개선시킨 두족류의 먹물추출물을 포함한 염모제 조성물에 관한 것이다.The present invention relates to a hair dye composition, in particular to improve the dyeing stability, including cephalophytic ink extracts, have a hair damage prevention effect, and to color the color of the hair, gray hair and bleached hair to the natural original hair color It relates to a hair dye composition comprising cephalophytic extract extracted to improve.

일반적으로 염모제는 염색효과의 차이에 따라 일시적 염모제, 반영구적 염모제, 영구적 염모제로 구분할 수 있다.Generally, hair dyes can be classified into temporary hair dyes, semi-permanent hair dyes, and permanent hair dyes according to the difference in dyeing effect.

이중에서도, 상기 영구적 염모제는 색소가 모표피를 침투하여 모피질 안에 색소 분자를 침전시키도록 만들어져 있고, 침투와 산화제의 추가작용에 의해 상기 염모제는 탈색과 착색이 가능하다. Among these, the permanent hair dye is made so that the pigment penetrates the cuticle and precipitates pigment molecules in the cortex, and the hair dye can be discolored and colored by the addition of the penetration and the oxidizing agent.

상기 영구적 염모제로는 사용되는 염료에 따라 식물성염모제, 금속염모제 및 산화염모제 등으로 나눌 수 있으며, 종래 사용되고 있는 대부분의 모발염모제는 산화염모제 중에서도 알칼리성 산화염모제이다. The permanent hair dye may be divided into vegetable hair dyes, metal hair dyes, and oxidation hair dyes according to the dyes used. Most of the hair dyes conventionally used are alkaline hair dyes among the hair dyes.

상기 알칼리성 산화염모제는 알칼리제가 포함되어 있기 때문에 PH를 높여주어 모발을 팽윤시켜 염료의 모발침착을 촉진할 수 있고, 산화제의 주성분인 과산화수소로 하여금 모발 내의 멜라닌 색소를 빨리 파괴하도록 촉매역할을 하는 장점을 가지고 있기 때문에 널리 사용되고 있다.Since the alkaline oxidation hair dye contains an alkali agent, the pH may be increased to swell the hair to promote hair deposition of the dye, and hydrogen peroxide, which is a main component of the oxidant, serves as a catalyst to quickly destroy melanin pigment in the hair. It is widely used because it has.

그러나, 상기의 알칼리제는 연약한 피부를 가진 사람에 있어서는 피부트러블이나 알레르기를 유발하게 되는 문제점이 있었다. However, the above alkaline agents have a problem of causing skin problems or allergies in people with fragile skin.

또한, 상기의 알칼리제는 PH를 높여주어 모발을 팽윤시키기 때문에 모발의 윤기 및 광택을 감소시키고, 모발성분을 용해시켜 모발이 심하게 손상되는 경우가 있어 부자연스러운 색이 되거나 머릿결을 상하게 하는 문제점이 있었다.In addition, the alkali agent increases the pH, thereby swelling the hair, thereby reducing the gloss and gloss of the hair, and dissolving the hair component, which may severely damage the hair, resulting in an unnatural color or damaging hair.

따라서, 본 발명의 목적은, 천연물질인 두족류의 먹물추출물을 첨가함으로써, 화학적 염료에 의한 모발손상을 줄여주고, 두피의 자극을 감소시켜 염색 후에 발생할 수 있는 두피에 대한 피부트러블이나 알레르기 등 알칼리제에 의한 부작용을 최소화할 수 있는 염색제 조성물을 제공하는데 있다.Therefore, an object of the present invention, by adding the cephalophytic extract of the natural substance, to reduce the hair damage caused by chemical dyes, to reduce the irritation of the scalp to the alkaline agents such as skin problems or allergies to the scalp that can occur after dyeing It is to provide a dye composition that can minimize the side effects caused by.

또한, 약산성에서 약알칼리성을 띠는 조성물들의 혼합만으로 PH를 중성으로 조절하고, 알칼리제를 사용하지 않거나 사용하더라도 그 사용량을 최소화시킴으로써, 높은 PH에 의한 모발의 팽윤현상 없이 염색이 가능하여 모발의 손상을 감소시키고, 모발의 색상을 좀더 자연스럽게 표현할 수 있는 염모제 조성물을 제공하는데 있다.In addition, by adjusting the pH to neutral by mixing only weakly acidic and alkaline compositions, and minimizing the amount of use even when no alkaline agent is used, it is possible to dye hair without high swelling of the hair due to high PH, thereby preventing hair damage. It is to provide a hair dye composition that can reduce and more naturally express the color of the hair.

상기 목적은, 본 발명에 따라, 산화염료, 킬레이트제, 산화방지제, 유화제, 증점제, 가용화제, 보존제, 용제, 착향제, PH조절제, 보습제, 안정제, 알칼리제, 모발보호제, 산화제를 포함하는 염모제 조성물에 있어서, 두족류(頭足類)의 먹물추출물을 추가적으로 포함하는 것을 특징으로 하는 염모제 조성물에 의해 달성된다.The above object is, according to the present invention, a hair dye composition comprising an oxidizing dye, a chelating agent, an antioxidant, an emulsifier, a thickener, a solubilizer, a preservative, a solvent, a flavoring agent, a PH regulator, a humectant, a stabilizer, an alkali agent, a hair protector, and an oxidizing agent. In the above, it is achieved by a hair dye composition characterized in that it further comprises a cephalopod ink extract.

바람직하게는, 상기 염모제 조성물은 상기 먹물추출물을 조성물 전체 중량대비 0.01 내지 10중량% 포함할 수 있다.Preferably, the hair dye composition may include 0.01 to 10% by weight of the ink extract from the total weight of the composition.

더욱 바람직하게는, 상기 염모제 조성물은 상기 먹물추출물을 조성물 전체 중량대비 0.1 내지 3중량% 포함할 수 있다.More preferably, the hair dye composition may include 0.1 to 3% by weight of the ink extract relative to the total weight of the composition.

또한, 상기 산화염료는 m-Aminophenol을 0.7~1.2중량%, Resorcine을 0.8~1.4중량%, p-Phenylenediamine을 1.6~2중량% 포함할 수 있다.In addition, the oxidized dye may include 0.7-1.2% by weight of m-Aminophenol, 0.8-1.4% by weight of Resorcine, 1.6-2% by weight of p-Phenylenediamine.

또한, 상기 산화염료는 m-Aminophenol을 0.05~0.3중량%, Resorcine을 0.6~1.2중량%, p-Phenylenediamine을 1~1.8중량%, p-Aminophenol을 0.2~0.25중량% 포함하며, 상기 알칼리제는 3.3~3.7중량%의 MEA(90%)인 것을 특징으로 한다.In addition, the oxidation dye is 0.05-0.3% by weight of m-Aminophenol, 0.6-1.2% by weight of Resorcine, 1-1.8% by weight of p-Phenylenediamine, 0.2-0.25% by weight of p-Aminophenol, the alkali is 3.3 It is characterized by a 3.7% by weight of MEA (90%).

또한, 상기 산화염료는 m-Aminophenol을 0.09~0.17중량%, Resorcine을 0.4~0.8중량%, p-Phenylenediamine을 0.1~0.5중량%, p-Aminophenol을 0.7~1.1중량% 포함하며, 상기 알칼리제는 3.8~4.2중량%의 MEA(90%)인 것을 특징으로 한다.In addition, the oxidation dye is 0.09 to 0.17% by weight of m-Aminophenol, 0.4 to 0.8% by weight of Resorcine, 0.1 to 0.5% by weight of p-Phenylenediamine, 0.7 to 1.1% by weight of p-Aminophenol, the alkali is 3.8 And 4.2% by weight of MEA (90%).

또한, 상기 모발보호제는 Methylpolysiloxane emulsion을 7~9중량%, Dimethicone/Dimethylconol(Gum20%)을 3~5중량%, Henna추출물을 0.04~0.06중량% 포 함하는 것을 특징으로 한다.In addition, the hair protectant is characterized in that 7 to 9% by weight of Methylpolysiloxane emulsion, 3 to 5% by weight of Dimethicone / Dimethylconol (Gum 20%), 0.04 to 0.06% by weight of Henna extract.

또한, 상기 모발보호제는 Hydroxylethylcellulose를 0.4~0.6중량%, Polyquaternium-10을 0.9~1.2중량%, Urea를 2.9~3.2중량%, DL Panthenol을 0.4~0.6중량%, Polyquaternium-7을 3.8~4.3중량%, Hydrolyzed silk를 2.7~3.3중량%, Henna추출물을 0.03~0.07중량%, 보습제는 Propylene Glycol을 1.7~2.2중량%, Glycerine을 1.8~2.3중량% 포함하는 것을 특징으로 한다.In addition, the hair protector is 0.4 to 0.6% by weight of Hydroxylethylcellulose, 0.9 to 1.2% by weight of Polyquaternium-10, 2.9 to 3.2% by weight of Urea, 0.4 to 0.6% by weight of DL Panthenol, 3.8 to 4.3% by weight of Polyquaternium-7 Hydrolyzed silk, 2.7 ~ 3.3% by weight, Henna extract 0.03 ~ 0.07% by weight, humectant is characterized in that it comprises 1.7 ~ 2.2% by weight of propylene glycol, 1.8 ~ 2.3% by weight of glycine.

한편, 상기 염모제 조성물의 PH는 6.5 내지 7.2인 것을 특징으로 한다.On the other hand, the pH of the hair dye composition is characterized in that 6.5 to 7.2.

이하, 본 발명을 상세히 설명하기로 한다.Hereinafter, the present invention will be described in detail.

본 발명에 따른 염모제 조성물은 상기와 같은 두족류의 먹물추출물을 포함하는 것을 특징으로 한다. Hair dye composition according to the invention is characterized in that it comprises a cephalophytic extract as described above.

상기 먹물추출물은 두족류의 먹물로부터 추출한 성분이며, 상기 먹물에 대해 설명하면 다음과 같다.The ink extract is a component extracted from the cephalopod ink, the following description of the ink.

상기 먹물은 두족류에 속하는 오징어, 문어 및 낙지류에서만 볼 수 있는 특유한 기관인 먹즙낭에서 분비되는 검은색의 액체로서, 주성분은 멜라닌(melanin)색소이다.The ink is a black liquid secreted from the saccharin, a peculiar organ that can only be seen in cephalopods, octopus and octopus belonging to the cephalopod, the main component is melanin (melanin) pigment.

이와같은 상기 두족류의 먹물에는 강력한 항종양 활성을 지닌 일렉신 등의 뮤코 다당류가 포함되어 항암작용 이외에도 항균작용, 방부작용, 위액분비 촉진작용이 우수하며, 여성의 생리불순 해소에도 탁월한 효능을 지닌 것으로 나타났다. Such cephalopods include mucopolysaccharides such as elexin, which has a strong antitumor activity, and are excellent in antibacterial, antiseptic, and gastric juice secretion in addition to anticancer activity, and have excellent efficacy in relieving menstrual irregularities in women. appear.

실제로 두족류의 먹물추출물을 복수암 세포에 투여한 결과 암세포 성장률이 40~55%까지 억제되었다는 연구결과가 보고되었다.In fact, the study showed that cancer cell growth was inhibited by 40-55% when cephalopods were administered to ascites cancer cells.

또한, 충치균을 없애는 강력한 항균작용을 지니는 것으로 보고되었으며, 어촌에서는 두족류의 먹물을 치질치료에 사용하기도 했다.In addition, it has been reported to have a strong antimicrobial action to eliminate the decay bacteria, and in the fishing village was also used cephalopods in the treatment of hemorrhoids.

상기 두족류의 먹물추출물은 유멜라닌(eumelanin), 페오멜라닌(Pheomelanin)과 같은 모발의 멜라닌(melanin)과 유사한 분자구조를 가지고 있는 물질이기 때문에 화학적 염료에 비해 모발손상이나 두피의 자극을 감소시켜줄 뿐만아니라, 항균, 항염작용이 있기 때문에 염색 후에 올 수 있는 두피에 대한 피부트러블이나 알레르기를 최소화할 수 있는 작용을 한다. The cephalopod ink extract has a molecular structure similar to that of the melanin of the hair, such as eumelanin and pheomelanin, and thus reduces hair damage or irritation of the scalp compared to chemical dyes. Because it has antibacterial and anti-inflammatory properties, it works to minimize skin troubles and allergies to the scalp that can come after dyeing.

전술한 두족류의 먹물추출물은 다양한 방법으로 추출될 수 있지만, 하기와 같은 방법을 사용할 수 있다.Although the above-mentioned cephalopod ink extract can be extracted by various methods, the following method can be used.

예를들어, 두족류의 먹즙낭을 채취해, 증류수로 세척한 후 먹즙낭으로부터 액체 상태의 먹물을 수거한다.For example, cephalopod sacs are collected, washed with distilled water, and liquid ink is collected from the sacs.

상기 먹물을 원심분리하여 추출물을 수거한 다음 24시간 동안 8M 우레아(Urea)에서 추출물을 교반시켜 분해한다.The ink is collected by centrifugation and the extract is then decomposed by stirring the extract in 8M urea (Urea) for 24 hours.

상기 추출물 현탁액을 원심탈수시킨 후, 증류수로 세척한다.The extract suspension is centrifuged and washed with distilled water.

침전되어 덩어리를 이루고 있는 펠릿(pellet)을 50% N,N-디메틸포름아미드(dimethylformamide) 수용액으로 세척한 다음, 아세톤으로 세척 후 공기건조하게 되면 분말형태의 유효성분인 두족류의 먹물추출물을 얻을 수 있다.Precipitated pellets, which form precipitates, are washed with 50% N, N-dimethylformamide solution, washed with acetone, and then air-dried to obtain cephalopods, which are powdered active ingredients. have.

상기 먹물추출물은 추후에 모발보호제, 착향제 등과 같이 투입되어 염모제 조성물로 사용된다.The ink extract is later added as a hair protector, flavoring agent and the like to be used as a hair dye composition.

또한, 상기 산화염료는 산화되어 발색하는 색원물질로서 m-Aminophenol, Resorcine, p-Phenylenediamine, p-Aminophenol 등이 될 수 있다.In addition, the oxidized dye may be m-Aminophenol, Resorcine, p-Phenylenediamine, p-Aminophenol and the like as a color source material that is oxidized color.

또한, 상기 킬레이트제는 수용성의 금속킬레이트를 생성하는 금속이온봉쇄제이며, turpinal-SL, EDTA-2Na 등을 포함한다.In addition, the chelating agent is a metal ion blocking agent for producing a water-soluble metal chelate, and includes turpinal-SL, EDTA-2Na and the like.

또한, 상기 산화방지제는 지방의 산화반응을 일으키는 산소의 제거 등 여러가지 화학반응을 진행하여 지방의 산패를 막아 주는 역할을 하며, Ammonium Thioglycolate, Sodium Sulfite 등을 포함한다.In addition, the antioxidant is responsible for preventing the rancidity of fat by performing various chemical reactions, such as the removal of oxygen causing the oxidation of fat, include Ammonium Thioglycolate, Sodium Sulfite.

또한, 상기 유화제는 유화가 쉽고, 안정되도록 하기 위해 사용하는 계면활성제로서, Grape Seed Oil, Liquid Paraffin, Iso Propyl Myristate, Crodafos CS 20 Acid, Vaselin, PEG 75 Lanoline, Pola Wax NF, Glyceryl stearate/PEG100Stearate, Cetrimonium Chloride, Steartrimonium chloride(50%) 등이 될 수 있다.In addition, the emulsifier is a surfactant used to make the emulsion easy and stable, Grape Seed Oil, Liquid Paraffin, Iso Propyl Myristate, Crodafos CS 20 Acid, Vaselin, PEG 75 Lanoline, Pola Wax NF, Glyceryl stearate / PEG100Stearate, Cetrimonium Chloride, Steartrimonium chloride (50%).

또한, 상기 증점제는 염모제의 점도를 증가시키기 위해 첨가하는 물질로서 Cetearyl Alcohol을 포함하며, 상기 가용화제는 물에 불용성인 물질이 계면활성제의 존재 하에 균일하게 용해하도록 해주는 역할을 하고, Emalex NP-12 등을 포함한다. In addition, the thickener includes Cetearyl Alcohol as a material added to increase the viscosity of the hair dye, the solubilizer serves to make the material insoluble in water uniformly dissolved in the presence of a surfactant, Emalex NP-12 And the like.

또한, 상기 보존제는 염색제의 변질을 방지하는 역할을 하며, Methyl Paraben, Propyl Paraben, Methylchlroisothiazolinone/Methylisothiazolinone 등을 포함한다.In addition, the preservative serves to prevent the deterioration of the dye, and includes Methyl Paraben, Propyl Paraben, Methylchlroisothiazolinone / Methylisothiazolinone and the like.

또한, 상기 용제는 구성물을 용해시키는 물질로서 정제수 등이 될 수 있고, 상기 착향제는 화학물질의 냄새를 방지해주는 역할을 한다.In addition, the solvent may be purified water as a substance for dissolving the constituents, and the flavoring agent serves to prevent the smell of chemicals.

여기서, 본 발명에 사용된 착향제인 HP75623은 한빛향료회사의 상품명이다.Here, HP75623 which is a flavoring agent used in the present invention is a trade name of Hanbit perfume company.

또한, 상기 PH조절제는 과산화수소를 안정화시키기 위해 PH를 4.0부근으로 조절해주며, Phosphoric acid 등이 될 수 있다.In addition, the PH regulator is to adjust the pH to 4.0 in order to stabilize the hydrogen peroxide, may be Phosphoric acid and the like.

또한, 상기 보습제는 염색모나 손상모에서 손실된 수분을 충분히 공급하여 모발이 더욱 촉촉하도록 유지시켜주는 역할을 하며, Propylene Glycol, Glycerine 등이 될 수 있다.In addition, the moisturizer serves to keep the hair more moist by supplying enough moisture lost from dyed hair or damaged hair, and may be Propylene Glycol, Glycerine, and the like.

또한, 상기 안정제는 산화방지제, 산화염료가 보존 중에 약화 되지 않도록 사용되는 환원제로서, Phenacetin, Sodium Phosphate dibasic 등이 될 수 있다.In addition, the stabilizer is an antioxidant, a reducing agent used to prevent the oxidation dye is not weakened during storage, may be Phenacetin, Sodium Phosphate dibasic and the like.

또한, 상기 알칼리제는 모발을 팽윤시켜 모발로의 염료분자 침투를 용이하게 해주는 역할을 하며, MEA(Monoethanolamine) 등이 될 수 있다.In addition, the alkali agent serves to facilitate the penetration of dye molecules into the hair by swelling the hair, may be MEA (Monoethanolamine).

또한, 상기 모발보호제는 모발표면에 염료가 고착되는 것을 도와주고, 모발에 발수성의 박막을 형성하여 수세 및 일광에 따른 염료의 탈색을 느리게 하여 모발표면에 우수한 컨디셔닝 효과를 주어 모발의 손상을 방지할 뿐만 아니라 에멀젼의 안정화에도 도움을 준다.In addition, the hair protector helps to fix the dye on the hair surface, and to form a water-repellent thin film on the hair to slow the discoloration of the dye due to water washing and sunlight to give excellent conditioning effect to the hair surface to prevent hair damage It also helps stabilize the emulsion.

여기서, 상기 모발보호제로는 Methylpolysiloxane emulsion, Dimethicone/Dimethylconol, Henna추출물, Urea, DL Panthenol, polyquaternium-7, Hydroxyethylcellulose, Hydrolyzed silk, Polyquaternium-10 등이 될 수 있다.Here, the hair protectant may be Methylpolysiloxane emulsion, Dimethicone / Dimethylconol, Henna extract, Urea, DL Panthenol, polyquaternium-7, Hydroxyethylcellulose, Hydrolyzed silk, Polyquaternium-10 and the like.

상기 산화제는 모피질층에 있는 멜라닌 색소를 파괴시키면서 염료가 들어갈 수 있는 공간을 만들어 주어 원하고자 하는 색상을 착색시켜주는 역할을 하며, 과산화수소 등이 될 수 있다.The oxidant serves to color the desired color by destroying the melanin pigment in the cortical layer to create a space for the dye to enter, and may be hydrogen peroxide.

한편, 본 발명에 따른 염모제 조성물은 상기 먹물추출물을 조성물 전체 중량대비 0.01 내지 10중량% 포함하는 것이 바람직하다.On the other hand, the hair dye composition according to the present invention preferably comprises from 0.01 to 10% by weight of the ink extract relative to the total weight of the composition.

여기서, 상기 먹물추출물은 0.01중량% 미만에서는 효과를 발휘할 수 없으며, 10중량%를 초과하게 되면 염모제 성분에 영향을 주게 된다. Here, the ink extract is not able to exert an effect at less than 0.01% by weight, if it exceeds 10% by weight will affect the hair dye components.

따라서, 상기 먹물추출물이 0.01 내지 10중량% 포함되었을 때 염모제 성분에 영향을 주지 않으면서, 좋은 효과를 발휘할 수 있었다.Therefore, when the ink extract contained 0.01 to 10% by weight, it was possible to exert a good effect without affecting the hair dye component.

더욱 바람직하게는, 상기 염모제 조성물이 상기 먹물추출물을 조성물 전체 중량대비 0.1 내지 3중량% 포함할 때 가장 좋은 효과를 발휘할 수 있었다.More preferably, the hair dye composition may exhibit the best effect when the ink extract contains 0.1 to 3% by weight based on the total weight of the composition.

한편, 본 발명에 따른 염모제 조성물의 색상이 블랙일 경우에 조성물의 전체 중량대비로 하여 두족류의 먹물추출물은 0.01∼10중량%, 산화염료로는 m-Aminophenol 0.7~1.2중량%, Resorcine 0.8~1.4중량%, p-Phenylenediamine 1.6~2중량%, 용제로는 정제수 68~74중량%, 킬레이트제로는 Turpinal-SL 0.08∼0.12중량%, 산화방지제로는 Ammonium Thioglycolate 0.7∼0.78중량%, Sodium Sulfite 0.2∼0.4중량%, 보존제로는 Methyl paraben 0.08∼0.13중량%, Propyl Paraben 0.08∼0.12중량%, 유화제로는 Grape Seed Oil 0.08∼1.5중량%, Liquid Paraffin 4.5~5.4중량%, Iso Propyl Myristate 1.8~2.3중량%, Crodafos CS 20 acid 2.5~3.3중량%, Vaselin 3.5~4.4중량%, 증점제로는 Cetearyl Alcohol 6.8~7.4중량%, 착향제로는 HP75623 0.28~0.32중량%를 포함하는 것을 특징으로 한다.On the other hand, when the color of the hair dye composition according to the present invention is black, 0.01 to 10% by weight of cephalopods extract, m-Aminophenol 0.7 to 1.2% by weight, Resorcine 0.8 to 1.4 Wt%, p-Phenylenediamine 1.6 ~ 2 wt%, 68 ~ 74 wt% purified water as solvent, 0.08 ~ 0.12 wt% Turpinal-SL as chelating agent, 0.7 ~ 0.78 wt% Ammonium Thioglycolate as antioxidant, 0.2 ~ Sodium Sulfite 0.2 ~ 0.4 wt%, Methyl paraben 0.08 ~ 0.13 wt% as preservative, Propyl Paraben 0.08 ~ 0.12 wt%, 0.08 ~ 1.5 wt% Grape Seed Oil, 4.5 ~ 5.4 wt% Liquid Paraffin, 1.8 ~ 2.3 wt% Iso Propyl Myristate %, 2.5 ~ 3.3% by weight of Crodafos CS 20 acid, 3.5 ~ 4.4% by weight of Vaselin, 6.8 ~ 7.4% by weight of Cetearyl Alcohol, 0.28 ~ 0.32% by weight of HP75623 as a flavoring agent.

또한, 본 발명에 따른 염모제 조성물의 색상이 다크브라운일 경우 조성물의 전체 중량대비로 하여 두족류의 먹물추출물은 0.01∼10중량%, 산화염료로는 m-Aminophenol 0.05~0.3중량%, Resorcine 0.6~1.2중량%, p-Phenylenediamine 1~1.8중량%, p-Aminophenol 0.2~0.25중량%, 알칼리제로는 MEA(90%) 3.3~3.7중량%, 용제로는 정제수 68~74중량%, 킬레이트제로는 Turpinal-SL 0.08∼0.12중량%, 산화방지제로는 Ammonium Thioglycolate 0.7∼0.78중량%, Sodium Sulfite 0.2∼0.4중량%, 보존제로는 Methyl paraben 0.08∼0.13중량%, Propyl Paraben 0.08∼0.12중량%, 유화제로는 Grape Seed Oil 0.08∼1.4중량%, Liquid Paraffin 4.7~5.3중량%, Iso Propyl Myristate 1.8~2.2중량%, Crodafos CS 20 acid 2.8~3.3중량%, Vaselin 3.7~4.4중량%, 증점제로는 Cetearyl Alcohol 6.8~7.4중량%, 착향제로는 HP75623 0.28~0.32중량%를 포함하는 것을 특징으로 한다.In addition, when the color of the hair dye composition according to the present invention is dark brown compared to the total weight of the composition, cephalopod ink extract is 0.01 to 10% by weight, m-Aminophenol 0.05 to 0.3% by weight, oxidizing dye 0.6 ~ 1.2 Weight%, p-Phenylenediamine 1-1.8%, p-Aminophenol 0.2-0.25% by weight, 3.3-3.7% by weight MEA (90%) as alkaline agent, 68-74% by weight purified water as solvent, Turpinal- as chelating agent SL 0.08 ~ 0.12% by weight, Ammonium Thioglycolate 0.7 ~ 0.78% by weight, Sodium Sulfite 0.2 ~ 0.4% by weight, Methyl paraben 0.08 ~ 0.13% by weight, Propyl Paraben 0.08 ~ 0.12% by weight, Grape as emulsifier Seed Oil 0.08 ~ 1.4 wt%, Liquid Paraffin 4.7 ~ 5.3 wt%, Iso Propyl Myristate 1.8 ~ 2.2 wt%, Crodafos CS 20 acid 2.8 ~ 3.3 wt%, Vaselin 3.7 ~ 4.4 wt%, Cetearyl Alcohol 6.8 ~ 7.4 as thickener By weight, the flavoring agent is characterized in that it comprises 0.28 ~ 0.32% by weight HP75623.

또한, 본 발명에 따른 염모제 조성물의 색상이 라이트브라운일 경우 조성물의 전체 중량대비로 하여 두족류의 먹물추출물은 0.01∼10중량%, 산화염료로는 m-Aminophenol 0.09~0.17중량%, Resorcine 0.4~0.8중량%, p-Phenylenediamine 0.1~0.5중량%, p-Aminophenol 0.7~1.1중량%, 알칼리제로는 MEA(90%) 3.8~4.2중량%, 용제로는 정제수 68~74중량%, 킬레이트제로는 Turpinal-SL 0.08∼0.12중량%, 산화방지제로는 Ammonium Thioglycolate 0.7∼0.78중량%, Sodium Sulfite 0.2∼0.4중량%, 보존제로는 Methyl paraben 0.08∼0.13중량%, Propyl Paraben 0.08∼0.12중량%, 유화제로는 Grape Seed Oil 0.08∼1.4중량%, Liquid Paraffin 4.7~5.3중량%, Iso Propyl Myristate 1.8~2.2중량%, Crodafos CS 20 acid 2.8~3.3중량%, Vaselin 3.7~4.4중량%, 증점제로는 Cetearyl Alcohol 6.8~7.4중량%, 착향제로는 HP75623 0.28~0.32중량%를 포함하는 것을 특징으로 한다.In addition, when the color of the hair dye composition according to the present invention is light brown compared to the total weight of the composition, cephalopod ink extract is 0.01 to 10% by weight, m-Aminophenol 0.09 to 0.17% by weight, Resorcine 0.4 to 0.8 Weight%, p-Phenylenediamine 0.1 ~ 0.5% by weight, p-Aminophenol 0.7 ~ 1.1% by weight, 3.8 ~ 4.2% by weight MEA (90%) as alkaline agent, 68 ~ 74% by weight purified water as solvent, Turpinal- as chelating agent SL 0.08 ~ 0.12% by weight, Ammonium Thioglycolate 0.7 ~ 0.78% by weight, Sodium Sulfite 0.2 ~ 0.4% by weight, Methyl paraben 0.08 ~ 0.13% by weight, Propyl Paraben 0.08 ~ 0.12% by weight, Grape as emulsifier Seed Oil 0.08 ~ 1.4 wt%, Liquid Paraffin 4.7 ~ 5.3 wt%, Iso Propyl Myristate 1.8 ~ 2.2 wt%, Crodafos CS 20 acid 2.8 ~ 3.3 wt%, Vaselin 3.7 ~ 4.4 wt%, Cetearyl Alcohol 6.8 ~ 7.4 as thickener By weight, the flavoring agent is characterized in that it comprises 0.28 ~ 0.32% by weight HP75623.

또한, 본 발명에 따른 염모제 조성물의 색상이 제1 내츄럴일 경우 조성물의 전체 중량대비로 하여 두족류의 먹물추출물은 0.01∼10중량%, 용제로는 정제수 52~58중량%, 킬레이트제로는 EDTA-2Na 0.03~0.06중량%, 보존제로는 Methyl Paraben 0.08∼0.13중량%, Propyl Paraben 0.08∼0.12중량%, 유화제로는 PEG 75Lanoline 5.8~6.2중량%, Pola Wax NF 0.9~1.2중량%, Grape Seed Oil 0.08∼1.4중량%, Glyceryl stearate/PEG100Stearate 2.2~2.7중량%, Vaselin 5.5~6.3중량%, Liquid Paraffin KF-70 5.8~6.2중량%, Iso Propyl Myristate 3.7~4.2중량%, Cetrimonium Chloride 3.8~4.2중량%, Crodafos CS 20 acid 2.7~3.3중량%, PEG 75Lanoline 5.8~6.2중량%, 증점제로는 Cetearyl Alcohol 1.8~2.3중량%, 착향제로는 HP75623 0.25~0.33중량%, 모발보호제로는 Henna추출물 0.03~0.07중량%, Methylpolysiloxane emulsion 7.5~8.3중량%, Dimethicone/Dimethiconol(Gum20%) 3.7~4.2중량%를 포함하는 것을 특징으로 한다.In addition, when the color of the hair dye composition according to the present invention is the first natural, the cephalopod ink extract is 0.01 to 10% by weight, the solvent is 52 to 58% by weight, and the chelating agent is EDTA-2Na, based on the total weight of the composition. 0.03 ~ 0.06% by weight, Methyl Paraben 0.08 ~ 0.13% by weight, Propyl Paraben 0.08 ~ 0.12% by weight, 5.8 ~ 6.2% by weight PEG 75Lanoline, 0.9 ~ 1.2% by weight Pola Wax NF, 0.08 ~ 0.01% by Grape Seed Oil 1.4 wt%, Glyceryl stearate / PEG100Stearate 2.2-2.7 wt%, Vaselin 5.5-6.3 wt%, Liquid Paraffin KF-70 5.8-6.2 wt%, Iso Propyl Myristate 3.7-4.2 wt%, Cetrimonium Chloride 3.8-4.2 wt%, Crodafos CS 20 acid 2.7 ~ 3.3 wt%, PEG 75Lanoline 5.8 ~ 6.2 wt%, Thickener Cetearyl Alcohol 1.8 ~ 2.3 wt%, Flavoring agent HP75623 0.25 ~ 0.33 wt%, Hair protector Henna extract 0.03 ~ 0.07 wt%, Methylpolysiloxane emulsion 7.5 ~ 8.3 wt%, Dimethicone / Dimethiconol (Gum20%) It is characterized in that it comprises 3.7 ~ 4.2 wt%.

또한, 본 발명에 따른 염모제 조성물의 색상이 제2 내츄럴일 경우 조성물의 전체 중량대비로 하여 두족류의 먹물추출물은 0.01~10중량%, 용제로는 정제수 79~85중량%, 보습제로는 Propylene Glycol 1.7~2.2중량%, Glycerine 1.8~2.3중량%, 모발보호제로는 Hydroxyethylcellulose 0.4~0.6중량%, Polyquaternium-10 0.9~1.2중량%, Urea 2.9~3.2중량%, DL Panthenol 0.4~0.6중량%, Polyquaternium-7 3.8~4.3중량%, Hydrolyzed silk 2.7~3.3중량%, Henna추출물 0.03~0.07중량%, 착향제로는 HP75623 0.25~0.33중량%, 보존제로는 Methylchlroisothiazolinone/Methylisothiazolinone 0.03~0.06중량%를 포함하는 것을 특징으로 한다.In addition, when the color of the hair dye composition according to the present invention is the second natural, the cephalopod ink extract is 0.01 to 10% by weight, the solvent is 79 to 85% by weight, and the moisturizer is Propylene Glycol 1.7. ~ 2.2% by weight, Glycerine 1.8 ~ 2.3% by weight, 0.4 ~ 0.6% by weight of Hydroxyethylcellulose, 0.9 ~ 1.2% by weight of Polyquaternium-10, 2.9-3.2% by weight of Urea, 0.4 ~ 0.6% by weight of DL Panthenol, Polyquaternium-7 3.8-4.3 wt%, 2.7-3.3 wt% Hydrolyzed silk, 0.03-0.07 wt% Henna extract, HP75623 0.25-0.33 wt% as flavoring agent, Methylchlroisothiazolinone / Methylisothiazolinone 0.03-0.06 wt% .

한편, 상기 염모제 조성물의 PH는 6.5 내지 7.2인 것을 특징으로 한다.On the other hand, the pH of the hair dye composition is characterized in that 6.5 to 7.2.

여기서, 상기 염모제 조성물은 약산성에서 약알칼리성을 띠는 조성물들의 혼합만으로 PH를 중성으로 조절하고, 알칼리제를 사용하지 않거나 사용하더라도 그 사용량을 최소화시킴으로써, 높은 PH에 의한 모발의 팽윤현상 없이 염색이 가능하여 모발의 손상을 감소시키고, 모발의 색상을 좀더 자연스럽게 표현할 수 있도록 한다.Here, the hair dye composition can be dyed without high swelling of the hair due to high pH by controlling the pH to neutral by mixing only weakly acidic to weakly alkaline compositions and minimizing the amount of use even when the alkaline agent is not used or used. It reduces the damage to your hair and allows you to express your hair's color more naturally.

이하, 구체적인 실시예를 통하여 본 발명을 더욱 상세히 설명하기로 한다.Hereinafter, the present invention will be described in more detail with reference to specific examples.

설명에 앞서, 이들 실시예는 단지 본 발명을 예시하기 위한 것이며, 본 발명의 보호범위가 이들 실시예에 의해 한정되는 것이 아님을 미리 밝혀둔다.Prior to the description, these examples are merely to illustrate the present invention, and it is noted that the protection scope of the present invention is not limited by these examples.

[제 1 실시예] 염모제 조성물의 색상이 블랙일 경우[Example 1] When the color of the hair dye composition is black

본 발명에 따른 염모제 조성물의 색상이 블랙일 경우에 하기 표 1에 나타난 성분을 사용하여 염모제 조성물을 제조하였다. 상기 염모제 조성물은 두족류의 먹물추출물을 0.01 내지 10중량% 포함하는 것이 바람직하다. When the color of the hair dye composition according to the present invention is black, a hair dye composition was prepared using the ingredients shown in Table 1 below. The hair dye composition preferably comprises 0.01 to 10% by weight of cephalophytic ink extract.

여기서, 상기 먹물추출물은 0.01중량% 미만에서는 효과를 발휘할 수 없으며, 10중량%를 초과하게 되면 염모제 성분에 영향을 주게 된다. 따라서, 0.01 내지 10중량%를 포함시켰을 때 염모제 성분에 영향을 주지않으면서 가장 좋은 효과를 발휘 할 수 있었다.Here, the ink extract is not able to exert an effect at less than 0.01% by weight, if it exceeds 10% by weight will affect the hair dye components. Therefore, when included 0.01 to 10% by weight was able to exert the best effect without affecting the hair dye component.

또한, 상기 염모제 조성물은 알칼리제를 포함하지 않는 것을 특징으로 한다.In addition, the hair dye composition is characterized in that it does not contain an alkali agent.

여기서, 상기 염모제 조성물의 색상이 블랙일 경우 블랙색상 자체는 밝게 표현이 되지 않아도 되기 때문에 알칼리제를 포함하지 않는 것을 특징으로 한다.Here, when the color of the hair dye composition is black, since the black color itself does not need to be expressed brightly, it is characterized by not including an alkali agent.

도 1을 참조하면, 표 1의 조성에 따라 두족류의 먹물추출물을 함유하는 염모제 조성물을 다음과 같은 방법으로 제조하였다.Referring to Figure 1, according to the composition of Table 1 was prepared a hair dye composition containing cephalophytic ink extract in the following method.

먼저 제조기기의 세척상태를 확인하고(S1), 용제, 금속봉쇄제, 보존제, 산화방지제를 제조탱크에 투입 후 85℃로 유지하면서 호모 및 패들믹서로 혼합하여 용해한다(S2). 상기 혼합물에 별도로 산화염료들을 계량하여 85℃에서 투입하고, 호모를 이용하여 완전용해시킨다(S3). 상기 산화염료 혼합물의 용해를 확인한 후, 별도의 유상용해조에서 85℃로 교반 용해시킨 유화제, 보존제, 증점제 등의 혼합물을 제조탱크에 투입하고 85℃에서 교반 용해시킨다(진공, 5분간 Homo-2500RPM, Paddle-35RPM으로 교반유지)(S4). 상기 혼합물을 패들믹서로 교반하면서, 45℃까지 냉각 후(S5) 착향제, 먹물추출물, Henna 추출물, 모발보호제 등을 투입해 교반한다(진공, 4분간 Homo-2500RPM, Paddle-35RPM으로 교반유지)(S6). 상기 혼합물의 점도 및 면상태를 확인하고(S7), 상기 혼합물을 저장탱크로 이동 후 질소를 채워줌으로써 산화를 방지한다. First, check the washing state of the manufacturing equipment (S1), and then dissolve the solvent, metal blocker, preservative, antioxidant by mixing with a homo and paddle mixer while maintaining at 85 ℃ after adding to the production tank (S2). Oxidative dyes were separately weighed into the mixture and added at 85 ° C., and completely dissolved using a homogeneous (S3). After confirming the dissolution of the oxidized dye mixture, a mixture of emulsifiers, preservatives, thickeners and the like, which were stirred and dissolved at 85 ° C. in a separate oil bath, was added to the production tank and stirred and dissolved at 85 ° C. (vacuum, Homo-2500RPM, Stirring with Paddle-35RPM) (S4). While stirring the mixture with a paddle mixer, the mixture is cooled to 45 ° C. (S5), and then flavored, ink extract, Henna extract, and hair protectant are added and stirred (vacuum, 4 minutes of Homo-2500RPM and paddle-35RPM to be kept agitated). (S6). Check the viscosity and surface state of the mixture (S7), and the mixture is moved to a storage tank to prevent oxidation by filling with nitrogen.

도 2을 참조하면, 표 6의 조성에 따라 산화제를 포함하는 염모제 조성물을 다음과 같은 방법으로 제조하였다.Referring to Figure 2, according to the composition of Table 6 to prepare a hair dye composition comprising an oxidizing agent in the following method.

먼저 제조기기의 세척상태를 확인하고(S11), 용제, 금속봉쇄제, PH조절제를 제조탱크에 투입 후 80℃로 유지하면서 호모 및 패들믹서로 혼합하여 용해한다(S12). 상기 혼합물에 유화제, 안정제, 증점제 등을 별도의 유상용해조에서 80℃로 교반용해하여(S13) 제조탱크에 투입하고 호모를 이용하여 완전용해시킨다(S14). (3분간 Homo-2000RPM, Paddle-30RPM으로 교반유지). 상기 혼합물을 패들믹서로 교반하면서, 45℃까지 냉각 후(S15) H2O2(35%), 착향제, PH조절제 등을 순차적으로 투입해 교반한다(S16). 상기 혼합물의 점도 및 면상태를 확인함으로써 산화제를 포함하는 염모제 조성물을 제조하였다(S17).First, check the washing state of the manufacturing equipment (S11), and then dissolve by mixing with a homo and paddle mixer while maintaining the solvent, metal blocker, PH regulator in the manufacturing tank at 80 ℃ (S12). The emulsifier, stabilizer, thickener and the like are stirred and dissolved in a separate oily bath at 80 ° C. (S13), and then put into a manufacturing tank and completely dissolved using a homogeneous (S14). (Keep stirring at Homo-2000RPM, Paddle-30RPM for 3 minutes). While stirring the mixture with a paddle mixer, after cooling to 45 ℃ (S15) H2O2 (35%), a flavoring agent, a pH regulator, etc. are sequentially added and stirred (S16). The hair dye composition including the oxidant was prepared by checking the viscosity and the state of the mixture (S17).

[표1] 블랙색상[Table 1] Black Color

구 분 division 성 분 별Classification 함량(중량%)Content (% by weight) 용제solvent 정제수Purified water 72.372.3 킬레이트제Chelating agents Turpinal-SLTurpinal-SL 0.10.1 산화방지제Antioxidant Ammonium ThioglycolateAmmonium thioglycolate 0.750.75 산화방지제Antioxidant Sodium SulfiteSodium Sulfite 0.30.3 보존제Preservative Methyl ParabenMethyl Paraben 0.10.1 보존제Preservative Propyl ParabenPropyl paraben 0.10.1 산화염료Oxidation Dye m-Aminophenolm-Aminophenol 0.90.9 산화염료Oxidation Dye ResorcineResorcine 1.01.0 산화염료Oxidation Dye p-Phenylenediaminep-Phenylenediamine 1.851.85 유화제Emulsifier Grape seed oilGrape seed oil 1One 유화제Emulsifier Liquid ParaffinLiquid paraffin 55 유화제Emulsifier Iso Propyl MyristateIso propyl myristate 22 유화제Emulsifier Crodafos CS 20 acidCrodafos CS 20 acid 33 유화제Emulsifier VaselinVaselin 44 증점제Thickener Cetearyl AlcoholCetearyl alcohol 7.27.2 착향제Flavor HP75623HP75623 0.30.3 유효성분Active ingredient 두족류의 먹물추출물Cephalopod Extract 0.10.1

(총 100%기준)(100% total)

[제 2 실시예] 염모제 조성물의 색상이 다크브라운일 경우[Example 2] When the color of the hair dye composition is dark brown

본 발명에 따른 염모제 조성물의 색상이 다크브라운일 경우 하기 표 2에 나타난 성분을 사용하여 염모제 조성물을 제조하였다. 상기 염모제 조성물은 제 1 실시예에서와 동일하게 두족류의 먹물추출물을 0.01 내지 10중량% 포함하는 것이 바람직하다. When the color of the hair dye composition according to the present invention is dark brown, a hair dye composition was prepared using the ingredients shown in Table 2 below. It is preferable that the hair dye composition contains 0.01 to 10% by weight of cephalopod ink extract as in the first embodiment.

여기서, 상기 먹물추출물은 0.01중량% 미만에서는 효과를 발휘할 수 없으며, 10중량%를 초과하게 되면 염모제 성분에 영향을 주게 된다. 따라서, 0.01 내지 10중량%를 포함시켰을 때 염모제 성분에 영향을 주지않으면서 가장 좋은 효과를 발휘할 수 있었다.Here, the ink extract is not able to exert an effect at less than 0.01% by weight, if it exceeds 10% by weight will affect the hair dye components. Therefore, when included 0.01 to 10% by weight it was possible to exert the best effect without affecting the hair dye component.

또한, 상기 염모제 조성물은 알칼리제인 Monoethanolamine(90%)을 3.3~3.7중량% 포함하는 것을 특징으로 한다.In addition, the hair dye composition is characterized in that it comprises 3.3 ~ 3.7% by weight of an alkaline monoethanolamine (90%).

여기서, 상기 염모제 조성물의 색상이 다크브라운일 경우 모발에 있는 멜라닌 색소를 파괴하여 밝게 만들어 주어야 하므로 알칼리제를 포함할 수 있다.Here, when the color of the hair dye composition is dark brown, an alkaline agent may be included since the melanin pigment in the hair needs to be made bright.

도 1을 참조하면, 표 2의 조성에 따라 두족류의 먹물추출물을 포함하는 염모제 조성물을 제 1 실시예의 방법으로 제조하였다.Referring to Figure 1, according to the composition of Table 2 was prepared a hair dye composition comprising cephalophytic ink extract by the method of the first embodiment.

[표2] 다크브라운색상[Table 2] Dark brown color

구 분division 성 분 별 Classification 함량(중량%)Content (% by weight) 용제solvent 정제수 Purified water 70.0370.03 킬레이트제Chelating agents Turpinal-SL Turpinal-SL 0.10.1 산화방지제Antioxidant Ammonium ThioglycolateAmmonium thioglycolate 0.750.75 산화방지제Antioxidant Sodium SulfiteSodium Sulfite 0.30.3 보존제Preservative Methyl ParabenMethyl Paraben 0.10.1 보존제Preservative Propyl ParabenPropyl paraben 0.10.1 산화염료Oxidation Dye m-Aminophenolm-Aminophenol 0.10.1 산화염료Oxidation Dye ResorcineResorcine 0.80.8 산화염료Oxidation Dye p-Pheylenediaminep-Pheylenediamine 1.41.4 산화염료Oxidation Dye p-Aminophenolp-Aminophenol 0.220.22 유화제Emulsifier Grape Seed OilGrape Seed Oil 1One 유화제Emulsifier Cradafos CS 20 AcidCradafos CS 20 Acid 33 유화제Emulsifier VaselinVaselin 44 유화제Emulsifier Liquid ParaffinLiquid paraffin 55 유화제Emulsifier Iso Propyl MyristateIso propyl myristate 22 증점제Thickener Cetearyl AlcoholCetearyl alcohol 7.27.2 알칼리제Alkali Monoethanolamine(90%)Monoethanolamine (90%) 3.53.5 착향제Flavor HP75623HP75623 0.30.3 유효성분Active ingredient 두족류의 먹물추출물Cephalopod Extract 0.10.1

(총 100%기준)(100% total)

[제 3 실시예] 염모제 조성물의 색상이 라이트브라운일 경우[Example 3] When the color of the hair dye composition is light brown

본 발명에 따른 염모제 조성물의 색상이 라이트브라운일 경우 하기 표 3에 나타난 성분을 사용하여 염모제 조성물을 제조하였다. 상기 염모제 조성물은 제 1 실시예에서와 동일하게 두족류의 먹물추출물을 0.01 내지 10중량% 함유하는 것이 바람직하다. When the color of the hair dye composition according to the present invention is light brown, a hair dye composition was prepared using the ingredients shown in Table 3 below. It is preferable that the hair dye composition contains 0.01 to 10% by weight of cephalopod ink extract as in the first embodiment.

여기서, 상기 먹물추출물은 0.01중량% 미만에서는 효과를 발휘할 수 없으며, 10중량%를 초과하게 되면 염모제 성분에 영향을 주게 된다. 따라서, 0.01 내지 10중량%를 포함시켰을 때 염모제 성분에 영향을 주지않으면서 가장 좋은 효과를 발휘할 수 있었다.Here, the ink extract is not able to exert an effect at less than 0.01% by weight, if it exceeds 10% by weight will affect the hair dye components. Therefore, when included 0.01 to 10% by weight it was possible to exert the best effect without affecting the hair dye component.

또한, 상기 염모제 조성물은 알칼리제인 Monoethanolamine(90%)을 3.8~4.2중 량% 포함하는 것을 특징으로 한다.In addition, the hair dye composition is characterized in that it comprises 3.8 ~ 4.2% by weight of the alkali agent Monoethanolamine (90%).

여기서, 상기 염모제 조성물의 색상이 라이트브라운일 경우 모발에 있는 멜라닌 색소를 파괴하여 밝게 만들어 주어야 하므로 알칼리제를 포함할 수 있다.Here, when the color of the hair dye composition is light brown, an alkaline agent may be included since the melanin pigment in the hair must be made bright.

도 1을 참조하면, 표 3의 조성에 따라 두족류의 먹물추출물을 포함하는 염모제 조성물을 제 1 실시예의 방법으로 제조하였다.Referring to Figure 1, according to the composition of Table 3 was prepared a hair dye composition comprising cephalophytic ink extract by the method of the first embodiment.

[표3] 라이트브라운색상[Table 3] Light Brown Color

구 분division 성 분 별Classification 함량(중량%)Content (% by weight) 용제solvent 정제수Purified water 70.1270.12 킬레이트제Chelating agents Turpinal-SL Turpinal-SL 0.10.1 산화방지제Antioxidant Ammonium ThioglycolateAmmonium thioglycolate 0.750.75 산화방지제Antioxidant Sodium SulfiteSodium Sulfite 0.30.3 보존제Preservative Methyl ParabenMethyl Paraben 0.10.1 보존제Preservative Propyl ParabenPropyl paraben 0.10.1 산화염료Oxidation Dye m-Aminophenolm-Aminophenol 0.130.13 산화염료Oxidation Dye ResorcineResorcine 0.60.6 산화염료Oxidation Dye p-Phenylendiaminep-Phenylendiamine 0.30.3 산화염료Oxidation Dye p-Aminophenolp-Aminophenol 0.90.9 유화제Emulsifier Grape Seed OilGrape Seed Oil 1One 유화제Emulsifier Cradafos CS 20 AcidCradafos CS 20 Acid 33 유화제Emulsifier VaselinVaselin 44 유화제Emulsifier Liquid ParaffinLiquid paraffin 55 유화제Emulsifier Iso Propyl MyristateIso propyl myristate 22 증점제Thickener Cetearyl AlcoholCetearyl alcohol 7.27.2 알칼리제Alkali Monoethanolamine(90%)Monoethanolamine (90%) 44 착향제Flavor HP75623HP75623 0.30.3 유효성분Active ingredient 두족류의 먹물추출물Cephalopod Extract 0.10.1

(총 100%기준)(100% total)

[제 4 실시예] 염모제 조성물의 색상이 제1 내츄럴일 경우[Example 4] When the color of the hair dye composition is the first natural

본 발명에 따른 염모제 조성물의 색상이 제1 내츄럴일 경우에 하기 표 4에 나타난 성분을 사용하여 염모제 조성물을 제조하였다. 상기 염모제 조성물은 제 1 실시예에서와 동일하게 두족류의 먹물추출물을 0.01 내지 10중량% 포함하는 것이 바람직하다. When the color of the hair dye composition according to the present invention is the first natural, a hair dye composition was prepared using the ingredients shown in Table 4 below. It is preferable that the hair dye composition contains 0.01 to 10% by weight of cephalopod ink extract as in the first embodiment.

여기서, 상기 먹물추출물은 0.01중량% 미만에서는 효과를 발휘할 수 없으며, 10중량%를 초과하게 되면 염모제 성분에 영향을 주게 된다. 따라서, 0.01 내지 10중량%를 포함시켰을 때 염모제 성분에 영향을 주지 않으면서 가장 좋은 효과를 발휘할 수 있었다.Here, the ink extract is not able to exert an effect at less than 0.01% by weight, if it exceeds 10% by weight will affect the hair dye components. Therefore, when included 0.01 to 10% by weight, the best effect could be exhibited without affecting the hair dye component.

또한, 상기 염모제 조성물은 알칼리제를 포함하지 않는 것을 특징으로 한다.In addition, the hair dye composition is characterized in that it does not contain an alkali agent.

여기서, 상기 염모제 조성물의 색상이 제1 내츄럴일 경우 상기 염모제 조성물은 기존의 염색된 색상을 유지하면서 모발에 영양을 공급하고, 보습효과를 향상시키는 등의 트리트먼트 효과를 주기 위해 사용하는 것으로서 무색으로 표현되기 때문에 알칼리제를 포함하지 않는 것을 특징으로 한다.Here, when the color of the hair dye composition is the first natural, the hair dye composition is colorless as it is used to give nutritional treatment to hair and improve moisturizing effect while maintaining the existing dyed color. Since it is expressed, it does not contain an alkali chemicals.

도 1을 참조하면, 표 4의 조성에 따라 두족류의 먹물추출물을 포함하는 염모제 조성물을 제 1 실시예의 방법으로 제조하였다.Referring to Figure 1, according to the composition of Table 4 was prepared a hair dye composition comprising a cephalopod ink extract by the method of the first embodiment.

[표4] 제1 내츄럴색상[Table 4] First Natural Color

구 분division 성 분 별Classification 함량(중량%)Content (% by weight) 용제solvent 정제수Purified water 54.854.8 킬레이트제Chelating agents EDTA-2NaEDTA-2Na 0.050.05 보존제Preservative Methyl ParabenMethyl Paraben 0.10.1 보존제Preservative Propyl ParabenPropyl paraben 0.10.1 유화제Emulsifier PEG 75LanolinePEG 75Lanoline 66 유화제Emulsifier Pola Wax NFPola Wax NF 1One 유화제Emulsifier Grape Seed OilGrape Seed Oil 1One 유화제Emulsifier Glyceryl stearate/PEG100StearateGlyceryl stearate / PEG100Stearate 2.52.5 유화제Emulsifier VaselinVaselin 66 유화제Emulsifier Liquid Paraffin KF-70Liquid Paraffin KF-70 66 유화제Emulsifier Iso Propyl MyristateIso propyl myristate 44 유화제Emulsifier Cetrimonium ChlorideCetrimonium Chloride 44 모발보호제Hair protectant Methylpolysiloxane emulsionMethylpolysiloxane emulsion 88 모발보호제Hair protectant Dimethicone/Dimethylconol(Gum20%)Dimethicone / Dimethylconol (Gum20%) 44 모발보호제Hair protectant Henna 추출물Henna Extract 0.050.05 증점제Thickener Cetearyl AlcoholCetearyl alcohol 22 착향제Flavor HP75623HP75623 0.30.3 유효성분Active ingredient 두족류의 먹물추출물Cephalopod Extract 0.10.1

(총 100%기준)(100% total)

[제 5 실시예] 염모제 조성물의 색상이 제2 내츄럴일 경우[Example 5] When the color of the hair dye composition is the second natural

본 발명에 따른 염모제 조성물의 색상이 제2 내츄럴일 경우에 하기 표 5에 나타난 성분을 사용하여 염모제 조성물을 제조하였다. 상기 염모제 조성물은 제 1 실시예에서와 동일하게 두족류의 먹물추출물을 0.01 내지 10중량% 포함하는 것이 바람직하다. When the color of the hair dye composition according to the present invention is the second natural, the hair dye composition was prepared using the ingredients shown in Table 5 below. It is preferable that the hair dye composition contains 0.01 to 10% by weight of cephalopod ink extract as in the first embodiment.

여기서, 상기 먹물추출물은 0.01중량% 미만에서는 효과를 발휘할 수 없으며, 10중량%를 초과하게 되면 염모제 성분에 영향을 주게 된다. 따라서, 0.01 내지 10중량%를 포함시켰을 때 염모제 성분에 영향을 주지않으면서 가장 좋은 효과를 발휘할 수 있었다.Here, the ink extract is not able to exert an effect at less than 0.01% by weight, if it exceeds 10% by weight will affect the hair dye components. Therefore, when included 0.01 to 10% by weight it was possible to exert the best effect without affecting the hair dye component.

또한, 상기 염모제 조성물은 알칼리제를 포함하지 않는 것을 특징으로 한다.In addition, the hair dye composition is characterized in that it does not contain an alkali agent.

여기서, 상기 염모제 조성물의 색상이 제2 내츄럴일 경우 상기 염모제 조성 물은 기존의 염색된 색상을 유지하면서 모발에 영양을 공급하고, 보습효과를 향상시키는 등의 트리트먼트 효과를 주기 위해 사용하는 것으로서 무색으로 표현되기 때문에 알칼리제를 포함하지 않는 것을 특징으로 한다.Here, when the color of the hair dye composition is the second natural color, the hair dye composition is colorless as it is used to give nutrition to hair and improve moisturizing effect while maintaining the existing dyed color. Since it is represented by, it does not contain an alkali agent.

도 1을 참조하면, 표 5의 조성에 따라 두족류의 먹물추출물을 포함하는 염모제 조성물을 제 1 실시예의 방법으로 제조하였다.
[표5] 제2 내츄럴색상
구 분 성 분 별 함량(중량%) 용제 정제수 83.05 보존제 Methylchlroisothiazolinone/Methylisothiazolinone 0.05 가용화제 Emalex NP-12 0.6 보습제 Propylene Glycol 2 보습제 Glycerine 2 모발보호제 Urea 3 모발보호제 DL Panthenol 0.5 모발보호제 Polyquaternium-7 4 모발보호제 Hydroxyethylcellulose 0.5 모발보호제 Polyquaternium-10 1 모발보호제 Hydrolyzed silk 3 모발보호제 Henna 추출물 0.05 착향제 HP75623 0.15 유효성분 두족류의 먹물추출물 0.1
(총 100%기준)
[표6] 산화제
Referring to Figure 1, according to the composition of Table 5 was prepared a hair dye composition comprising cephalophytic ink extract by the method of the first embodiment.
[Table 5] Second Natural Color
division Classification Content (% by weight) solvent Purified water 83.05 Preservative Methylchlroisothiazolinone / Methylisothiazolinone 0.05 Solubilizer Emalex NP-12 0.6 Moisturizer Propylene glycol 2 Moisturizer Glycerin 2 Hair protectant Urea 3 Hair protectant DL Panthenol 0.5 Hair protectant Polyquaternium-7 4 Hair protectant Hydroxyethylcellulose 0.5 Hair protectant Polyquaternium-10 One Hair protectant Hydrolyzed silk 3 Hair protectant Henna Extract 0.05 Flavor HP75623 0.15 Active ingredient Cephalopod Extract 0.1
(100% total)
[Table 6] Oxidizer

삭제delete

삭제delete

삭제delete

삭제delete

구 분division 성 분 별Classification 함량(중량%)Content (% by weight) 용제solvent 정제수Purified water 76.7576.75 주성분chief ingredient H2O2(35%)H2O2 (35%) 88 킬레이트제Chelating agents EDTA-2Na EDTA-2Na 0.20.2 안정제stabilizator PhenacetinPhenacetin 0.080.08 안정제stabilizator Sodium Phosphate dibasicSodium Phosphate dibasic 2.52.5 PH조절제PH regulator Phosphoric AcidPhosphoric Acid 0.170.17 유화제Emulsifier Miconium STAC80Miconium STAC80 0.50.5 유화제Emulsifier PEG 75LanolinePEG 75Lanoline 1One 유화제Emulsifier Liquid ParaffinLiquid paraffin 6.56.5 유화제Emulsifier Pola Wax NFPola Wax NF 0.80.8 유화제Emulsifier Glyceryl stearate/PEG100StearateGlyceryl stearate / PEG100Stearate 0.70.7 점증제 Thickener Cetearyl AlcoholCetearyl alcohol 2.52.5 착향제Flavor HP75623HP75623 0.30.3

(총 100%기준)(100% total)

전술한 바와 같이, 본 발명에 따르면, 두족류의 먹물추출물을 첨가함으로써, 염색 후에 올 수 있는 모발손상과 두피에 대한 피부트러블 및 알레르기를 최소화할 수 있는 효과를 발휘할 수 있다.As described above, according to the present invention, by adding the cephalopod ink extract, it is possible to exert the effect of minimizing the skin trouble and allergy to the scalp and hair damage that may come after dyeing.

또한, 약산성에서 약알칼리성을 띠는 조성물들의 혼합만으로 PH를 중성으로 조절하고, 알칼리제를 사용하지 않거나 사용하더라도 그 사용량을 최소화함으로써, In addition, by adjusting the pH to neutral only by mixing the weakly alkaline composition, and by using or not using an alkaline agent to minimize the amount of use,

높은 PH에 의한 모발의 팽윤현상 없이 염색이 가능하도록 하여 모발의 손상을 감소시켜 모발의 색상을 좀더 자연스럽게 표현할 수 있는 효과를 발휘할 수 있다. It is possible to dye without hair swelling phenomenon due to high PH, thereby reducing the damage of the hair can be more effective to express the color of the hair more naturally.

Claims (9)

m-Aminophenol, Resorcine, p-Phenylenediamine 및 p-Aminophenol 중 어느 하나를 포함하는 산화염료와, 킬레이트제와, 산화방지제와, 유화제와, 증점제와, 가용화제와, 보존제와, 용제와, 착향제와, PH조절제와, 보습제와, 안정제와, 알칼리제와, Methylpolysiloxane emulsion, Dimethicone/Dimethylconol(Gum20%), Henna추출물, Urea, DL Panthenol, polyquaternium-7, Hydroxyethylcellulose, Hydrolyzed silk 및 Polyquaternium-10 중 어느 하나를 포함하는 모발보호제와, 산화제로 이루어진 염모제 조성물에 있어서,oxidizing dyes containing any one of m-Aminophenol, Resorcine, p-Phenylenediamine and p-Aminophenol, chelating agent, antioxidant, emulsifier, thickener, solubilizer, preservative, solvent, flavoring agent, , PH regulator, moisturizer, stabilizer, alkali agent, Methylpolysiloxane emulsion, Dimethicone / Dimethylconol (Gum20%), Henna extract, Urea, DL Panthenol, polyquaternium-7, Hydroxyethylcellulose, Hydrolyzed silk and Polyquaternium-10 In the hair dye composition comprising a hair protector and an oxidizing agent, 두족류(頭足類)의 먹물추출물을 추가적으로 포함하는 것을 특징으로 하는 염모제 조성물.Hair dye composition, characterized in that it further comprises a cephalopod ink extract. 제 1항에 있어서,The method of claim 1, 상기 염모제 조성물은 상기 먹물추출물을 조성물 전체 중량대비 0.01 내지 10중량% 함유하는 것을 특징으로 하는 염모제 조성물.The hair dye composition is a hair dye composition, characterized in that containing the ink extract from 0.01 to 10% by weight relative to the total weight of the composition. 제 2항에 있어서,The method of claim 2, 상기 염모제 조성물은 상기 먹물추출물을 조성물 전체 중량대비 0.1 내지 3중량% 함유하는 것을 특징으로 하는 염모제 조성물.The hair dye composition is a hair dye composition, characterized in that containing 0.1 to 3% by weight of the ink extract relative to the total weight of the composition. 제 1항에 있어서,The method of claim 1, 상기 산화염료는 m-Aminophenol을 0.7~1.2중량%, Resorcine을 0.8~1.4중량%, p-Phenylenediamine을 1.6~2중량% 포함하는 것을 특징으로 하는 염모제 조성물. The oxidation dye is a hair dye composition, characterized in that 0.7-1.2% by weight of m-Aminophenol, 0.8-1.4% by weight of Resorcine, 1.6-2% by weight of p-Phenylenediamine. 제 1항에 있어서,The method of claim 1, 상기 산화염료는 m-Aminophenol을 0.05~0.3중량%, Resorcine을 0.6~1.2중량%, p-Phenylenediamine을 1~1.8중량%, p-Aminophenol을 0.2~0.25중량% 포함하며, 상기 알칼리제는 3.3~3.7중량%의 MEA(90%)인 것을 특징으로 하는 염모제 조성물.The oxidizing dye contains 0.05-0.3% by weight of m-Aminophenol, 0.6-1.2% by weight of Resorcine, 1-1.8% by weight of p-Phenylenediamine, 0.2-0.25% by weight of p-Aminophenol, 3.3-3.7 A hair dye composition, characterized in that the weight percent MEA (90%). 제 1항에 있어서,The method of claim 1, 상기 산화염료는 m-Aminophenol을 0.09~0.17중량%, Resorcine을 0.4~0.8중량%, p-Phenylenediamine을 0.1~0.5중량%, p-Aminophenol을 0.7~1.1중량% 포함하며, 상기 알칼리제는 3.8~4.2중량%의 MEA(90%)인 것을 특징으로 하는 염모제 조성물.The oxidizing dye contains 0.09 to 0.17% by weight of m-Aminophenol, 0.4 to 0.8% by weight of Resorcine, 0.1 to 0.5% by weight of p-Phenylenediamine, 0.7 to 1.1% by weight of p-Aminophenol, and the alkaline agent is 3.8 to 4.2. A hair dye composition, characterized in that the weight percent MEA (90%). 제 1항에 있어서,The method of claim 1, 상기 모발보호제는 Methylpolysiloxane emulsion을 7~9중량%, Dimethicone/Dimethylconol(Gum20%)을 3~5중량%, Henna추출물을 0.04~0.06중량% 포함하는 것을 특징으로 하는 염모제 조성물.The hair protectant is 7 to 9% by weight of Methylpolysiloxane emulsion, Dimethicone / Dimethylconol (Gum20%) 3 to 5% by weight, Henna extract 0.04 to 0.06% by weight comprising a hair dye composition. 제 1항에 있어서,The method of claim 1, 상기 모발보호제는 Hydroxylethylcellulose를 0.4~0.6중량%, Polyquaternium-10을 0.9~1.2중량%, Urea를 2.9~3.2중량%, DL Panthenol을 0.4~0.6중량%, Polyquaternium-7을 3.8~4.3중량%, Hydrolyzed silk를 2.7~3.3중량%, Henna 추출물을 0.03~0.07중량%, 보습제는 Propylene Glycol을 1.7~2.2중량%, Glycerine을 1.8~2.3중량% 포함하는 것을 특징으로 하는 염모제 조성물.The hair protectant is 0.4 to 0.6% by weight of Hydroxylethylcellulose, 0.9 to 1.2% by weight of Polyquaternium-10, 2.9 to 3.2% by weight of Urea, 0.4 to 0.6% by weight of DL Panthenol, 3.8 to 4.3% by weight of Polyquaternium-7, Hydrolyzed A hair dye composition comprising 2.7 to 3.3% by weight of silk, 0.03 to 0.07% by weight of Henna extract, 1.7 to 2.2% by weight of propylene glycol, and 1.8 to 2.3% by weight of glycerin. 제 1항 내지 제 3항 중 어느 한 항에 있어서,The method according to any one of claims 1 to 3, 상기 염모제 조성물의 PH는 6.5 내지 7.2인 것을 특징으로 하는 염모제 조성물.The pH of the hair dye composition is a hair dye composition, characterized in that 6.5 to 7.2.
KR1020060077500A 2006-08-17 2006-08-17 Hair coloring composition comprising cephalopoda ink extracts KR100755525B1 (en)

Priority Applications (2)

Application Number Priority Date Filing Date Title
KR1020060077500A KR100755525B1 (en) 2006-08-17 2006-08-17 Hair coloring composition comprising cephalopoda ink extracts
PCT/KR2007/003944 WO2008020730A1 (en) 2006-08-17 2007-08-17 Hair dye composition containing cephalopod ink extract

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
KR1020060077500A KR100755525B1 (en) 2006-08-17 2006-08-17 Hair coloring composition comprising cephalopoda ink extracts

Publications (1)

Publication Number Publication Date
KR100755525B1 true KR100755525B1 (en) 2007-09-05

Family

ID=38736527

Family Applications (1)

Application Number Title Priority Date Filing Date
KR1020060077500A KR100755525B1 (en) 2006-08-17 2006-08-17 Hair coloring composition comprising cephalopoda ink extracts

Country Status (2)

Country Link
KR (1) KR100755525B1 (en)
WO (1) WO2008020730A1 (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR100834891B1 (en) 2007-05-25 2008-06-03 이원기 Hair treatment composition including ink extracts of cephalopoda
KR20220033782A (en) * 2020-09-10 2022-03-17 주식회사 엔에프씨 A Nanoliposome Structure Containing Squid Ink and Hair Dye Composition using the Same

Families Citing this family (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CA2737394A1 (en) * 2008-09-16 2010-03-25 Perachem Limited Hair treatment methods
DE102009002880A1 (en) * 2009-05-06 2010-11-18 Henkel Ag & Co. Kgaa Scalp-soothing hair dye / wellmittel
GB2471135A (en) * 2009-06-19 2010-12-22 H D S Ltd Hair dye composition and use in reducing contact allergy
EP2422762A1 (en) 2010-08-24 2012-02-29 KPSS-Kao Professional Salon Services GmbH Stable oxidative colouring composition for keratin fibers
US8591872B2 (en) 2011-12-30 2013-11-26 L'oreal Composition and process for reducing the curl and frizziness of hair
US8506651B2 (en) 2011-12-30 2013-08-13 L'oreal S.A. Process for altering the appearance of hair using a composition containing dyes and non-hydroxide bases
US8556994B2 (en) 2011-12-30 2013-10-15 L'oreal Process for altering the appearance of hair using a composition containing direct dyes and non-hydroxide bases
US8343238B1 (en) 2011-12-30 2013-01-01 L'oreal Sa. Process for altering the appearance of hair using a composition containing dyes and non-hydroxide bases
US10596100B2 (en) 2012-12-19 2020-03-24 L'oreal Cosmetic compositions containing an alkoxysilane and a silsesquioxane resin
US10245221B2 (en) 2015-05-07 2019-04-02 Celeb LLC Stabilized color depositing shampoo
US9889080B2 (en) 2015-05-07 2018-02-13 Celeb LLC Color depositing shampoo
CN109939061B (en) * 2019-05-14 2020-11-27 连云港诗碧曼生物科技有限公司 Safe and non-irritant white hair blackening essence and preparation method thereof

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR20050009395A (en) * 2003-07-16 2005-01-25 엘지전자 주식회사 structure for installation braket for loading engine in projection television

Family Cites Families (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH059395A (en) * 1990-12-19 1993-01-19 Ain Kk Cuttlefish ink powder and formation thereof
JPH0543811A (en) * 1991-08-12 1993-02-23 Ain Kk Cuttlefish ink powder and forming method therefor
JP3696473B2 (en) * 2000-03-16 2005-09-21 花王株式会社 Keratinous fiber dyeing composition
FR2807647B1 (en) * 2000-04-12 2005-08-26 Oreal KERATIN FIBER OXIDATION DYEING COMPOSITION AND METHOD USING THE SAME

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR20050009395A (en) * 2003-07-16 2005-01-25 엘지전자 주식회사 structure for installation braket for loading engine in projection television

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR100834891B1 (en) 2007-05-25 2008-06-03 이원기 Hair treatment composition including ink extracts of cephalopoda
KR20220033782A (en) * 2020-09-10 2022-03-17 주식회사 엔에프씨 A Nanoliposome Structure Containing Squid Ink and Hair Dye Composition using the Same
KR102439800B1 (en) 2020-09-10 2022-09-02 주식회사 엔에프씨 A Nanoliposome Structure Containing Squid Ink and Hair Dye Composition using the Same

Also Published As

Publication number Publication date
WO2008020730A1 (en) 2008-02-21

Similar Documents

Publication Publication Date Title
KR100755525B1 (en) Hair coloring composition comprising cephalopoda ink extracts
US6497892B2 (en) Cosmetic and skin protective compositions
US6641845B1 (en) Skin whitening composition comprising bearberry and tetrahydrocurcumin
KR100625180B1 (en) Composition for hair color and preparation method thereof
JP4827856B2 (en) Destaining agent composition
JP2014024766A (en) External preparation with unstable dye being stably admixed, for coloring skin and hair
KR101045328B1 (en) Hair dye composition
KR102174707B1 (en) Sulfate-free cosmetic composition for improving condition of hair or scalp
JP2014234346A (en) Hair treatment agent
EP1959920A1 (en) Use of rooibos extract for protecting hair colour
JP3345174B2 (en) Hair treatment agent
KR20080070334A (en) Composition for scalp-care before haircoloring
KR101636807B1 (en) Composition for the anti-irritation effect on the scalp containing natural ingredients for hair colorants
KR20100084040A (en) Hair dye composition
KR19990006295A (en) Use of Sulfite and Metabisulfite, in particular in dermatology, for the preparation of cosmetic or pharmaceutical compositions with melanogenesis-inhibiting or decolorizing activity
KR101292828B1 (en) Hair dye containing snail mucus extract and preparation method therof
KR100965630B1 (en) Dyeing Composition for Hair with hardwood charcoal and aloe extracts
KR20090054113A (en) Cuttlefish ink hairdye
KR101415991B1 (en) Hair dye composition for the oxidative dyeing containing Camellia sinensis powder
JPH10130129A (en) Hair dyeing composition
KR101851306B1 (en) Oxidative Hair Dye Composition Comprising Carbonated Water
KR102016584B1 (en) Composition for Hairdye Containing Extracts of Cornus Controversa Hemsl
KR100862646B1 (en) Composition of hair color and method for preparing thereof
JPH11180854A (en) Skin preparation for external use
KR101826006B1 (en) Hair cosmetic composition containing natural dyeing material

Legal Events

Date Code Title Description
A201 Request for examination
A302 Request for accelerated examination
E902 Notification of reason for refusal
E902 Notification of reason for refusal
E701 Decision to grant or registration of patent right
N231 Notification of change of applicant
GRNT Written decision to grant
J206 Request for trial to confirm the scope of a patent right
J204 Request for invalidation trial [patent]
J204 Request for invalidation trial [patent]
J301 Trial decision

Free format text: TRIAL NUMBER: 2007100002959; TRIAL DECISION FOR CONFIRMATION OF THE SCOPE OF RIGHT_DEFENSIVE REQUESTED 20071024

Effective date: 20080911

Free format text: TRIAL DECISION FOR CONFIRMATION OF THE SCOPE OF RIGHT_DEFENSIVE REQUESTED 20071024

Effective date: 20080911

J2X1 Appeal (before the patent court)

Free format text: CONFIRMATION OF THE SCOPE OF RIGHT_DEFENSIVE

J121 Written withdrawal of request for trial
J301 Trial decision

Free format text: TRIAL NUMBER: 2007100002980; TRIAL DECISION FOR INVALIDATION REQUESTED 20071026

Effective date: 20090123

Free format text: TRIAL DECISION FOR INVALIDATION REQUESTED 20071026

Effective date: 20090123

J2X1 Appeal (before the patent court)

Free format text: TRIAL NUMBER: 2009200001675; INVALIDATION

Free format text: INVALIDATION

J302 Written judgement (patent court)

Free format text: TRIAL NUMBER: 2009200001675; JUDGMENT (PATENT COURT) FOR INVALIDATION REQUESTED 20090305

Effective date: 20090909

Free format text: JUDGMENT (PATENT COURT) FOR INVALIDATION REQUESTED 20090305

Effective date: 20090909

J302 Written judgement (patent court)

Free format text: TRIAL NUMBER: 2008200011934; JUDGMENT (PATENT COURT) FOR CONFIRMATION OF THE SCOPE OF RIGHT_DEFENSIVE REQUESTED 20081018

Effective date: 20091112

Free format text: JUDGMENT (PATENT COURT) FOR CONFIRMATION OF THE SCOPE OF RIGHT_DEFENSIVE REQUESTED 20081018

Effective date: 20091112

FPAY Annual fee payment

Payment date: 20120827

Year of fee payment: 6

FPAY Annual fee payment

Payment date: 20130829

Year of fee payment: 7

FPAY Annual fee payment

Payment date: 20140819

Year of fee payment: 8

FPAY Annual fee payment

Payment date: 20150611

Year of fee payment: 9

FPAY Annual fee payment

Payment date: 20160706

Year of fee payment: 10

FPAY Annual fee payment

Payment date: 20170612

Year of fee payment: 11

FPAY Annual fee payment

Payment date: 20180613

Year of fee payment: 12

FPAY Annual fee payment

Payment date: 20190627

Year of fee payment: 13