KR100729506B1 - Liquid aromatic and deodorant agent composition dividing into multi layers and volatilization apparatus using the above composition - Google Patents

Abstract

The present invention relates to a liquid phase divided into a multi-layer for decomposing and controlling the volatilization concentration of two or more different fragrances and deodorants individually, and to a volatilization mechanism for volatilization thereof. A low specific gravity first solvent, a high specific gravity second solvent such as water, a third solvent which is not mixed with the first solvent and the second solvent and has an intermediate specific gravity thereof, Two or more kinds of volatilized substances are dissolved in each of the first solvent and the second solvent.

Volatilization, aroma, deodorization, volatilization mechanism, multilayer structure, salting out, liquid paraffin, normal butanol

Description

Liquid aromatic and deodorant agent composition dividing into multi layers and volatilization apparatus using the above composition}

1 is a cross-sectional view schematically showing a volatilization mechanism for volatilization of a liquid direction, deodorant composition divided into a multi-layer according to the present invention.

※ Explanation of code for main part of drawing

1: container 2: first wick

3: first volatilization plate 4: second volatility plate

5: second wick 6: wick bulkhead

7: first liquid layer 8: second liquid layer

9: 3rd liquid layer

The present invention relates to a liquid phase divided into multiple layers, deodorant compositions and volatilization mechanisms for volatilization thereof. More specifically, the present invention relates to a liquid phase divided into a multi-layered fragrance for decomposing and controlling volatilization concentrations of two or more different fragrances and deodorants, and a volatilization mechanism for volatilization thereof.

Conventional liquid fragrances are incorporated into the aqueous solution layer in an emulsified or solubilized state to naturally volatilize using a wick and volatilized plate or 3-methoxy-3-methyl-1-butanol (3-MMB; 3-methoxy-3- Dissolve the fragrance in organic solvents such as methyl-1-butanol), propylene glycol (PG; propylene glycol), di (propylene glycol) butylether (DPM; Di (propylene glycol) butylether), and isoparaffin, Or vaporized by attachment to a fan for ventilation purposes.

However, when emulsifying or solubilizing the fragrance in the aqueous solution layer, the volatilization of the fragrance is more effective than the gel or bead type, and it is possible to manufacture a product having a large capacity.However, a prescription is complicated because a surfactant or the like must be used to stabilize the fragrance. When the surfactant is used, the surfactant itself is an organic substance having a large molecular weight and thus does not volatilize. Therefore, the surfactant itself remains in the wick, which hinders volatilization of the contents or remains as a residue in the container until the end, which is a characteristic of the liquid perfume contained in a transparent container. It was difficult to produce a product with a decorative effect.

When the fragrance is dispersed in an organic solvent and volatilized using a heating plate, the fragrance is effectively volatilized to give a satisfactory scent, but there are many limitations in applying water-soluble other additives such as deodorant substances.

Therefore, it is possible to manufacture in a simple way by using a simple prescription, which does not need to use a surfactant for the stabilization of fragrance, to maximize the visual effect of the appearance such as color and to manufacture a multifunctional product with added deodorant substances, etc. For this purpose, a multi-layer liquid phase based on an organic solvent layer and an aqueous solution layer is required.

Since the conventional two-layer liquid perfume uses the difference between the oily phase and the aqueous phase, it is not easy to form a liquid phase of three or more layers by adding a third substance. In addition, when glycerin, silicone oil, etc. are used, a multilayer liquid phase can be obtained, but since volatility is not good, it cannot use it as a fragrance | flavor.

In addition, in the case of a volatilization apparatus including one wick and one volatilization plate, which is used in a conventional fragrance deodorant product, application of a unique volatilization structure is not possible because volatilization of the liquid phase divided into multiple layers and the deodorant composition cannot be effectively volatilized. need.

The object of the present invention is that the formulation is simple because it does not need to use a surfactant to form a stable liquid phase, the visual effect of the appearance is excellent, the liquid phase divided into a multi-layer that can control the amount of volatilization by separating the aromatic layer and the deodorant layer Fragrance, deodorant composition.

The liquid fragrance and deodorant composition divided into a multilayer according to the present invention is not mixed with a low specific gravity first solvent such as liquid paraffin, a high specific gravity second solvent such as water, the first solvent and the second solvent, A third solvent having an intermediate specific gravity thereof is included, and is formed by dissolving two or more kinds of volatile substances such as an aromatic substance and a deodorant substance in each of the first solvent and the second solvent.                     

The composition may further include a solvent which is not mixed with the first solvent, the second solvent or the third solvent, and which can form a layer separately.

The second solvent is characterized in that the electrolyte solution in which the electrolyte is dissolved.

As the third solvent, normal propanol is preferable.

Liquid aroma divided into a multi-layer according to the present invention, a method for producing a deodorant composition is mixed with a low specific gravity first solvent such as liquid paraffin, a high specific gravity second solvent such as water, the first solvent and the second solvent In the manufacture of a liquid aroma, deodorant composition comprising a third solvent having a specific gravity thereof, and containing two or more kinds of volatile substances such as fragrance and deodorant, (1) 2 to the first solvent A first solution preparation step of preparing a first solution by dissolving any one or more volatilized substances; (2) a second solution preparation step of preparing a second solution by dissolving a volatile material different from the volatile material dissolved in the first solvent among two or more volatile materials in the second solvent; (3) a first political step of leaving the second solution having a high specific gravity in a container capable of containing the composition; (4) a second political step of allowing the third solvent, which is not mixed with the first solvent and the second solvent, to have a specific gravity therebetween, to remain on the second solution; And (5) a third political step of allowing the first solution to remain on the third solvent.

After the third political step of (5), may further include a stationary step of further mixing the solvents that are not mixed with the first solution, the second solution or the third solvent and can form a separate layer.

The second solution preparation step of (2) may be prepared by dissolving an electrolyte in water in the second solvent.                     

Liquid direction divided into a multi-layer according to the present invention, deodorant composition volatilization mechanism, a direction for forming at least three layers, a container containing the deodorant composition, at least two or more heating plates located on the top of the container, At least two wicks connected to the heating plates and extending to the bottom of the container, and the wick partition such that any one of the wicks does not come into contact with the solution or solvents constituting the layers other than the lowest layer of the composition It is made, including.

Liquid direction divided into multiple layers according to the present invention, deodorant composition volatilizer, the direction to form at least three layers, the container containing the deodorant composition, at least two or more heating plates located on the top of the container, the heating plate At least two wicks connected to the floor and extending to the bottom of the container, and a wick partition which prevents any one of the wicks from contacting the solution or solvents constituting the layers other than the lowest layer of the composition. In the container of the volatilization mechanism which contains, the low specific gravity 1 solvent, such as liquid paraffin, the high specific gravity 2 solvent, such as water, and the said 1st solvent and the 2nd solvent which are not mixed, The agent which has the specific gravity in the middle It includes three solvents and is divided into multilayers formed by dissolving two or more kinds of volatile substances such as aromatic substances and deodorizing substances in each of the first and second solvents. It is made to stand the direction of the liquid, deodorant compositions.

Hereinafter, exemplary embodiments of the present invention will be described in detail with reference to the accompanying drawings.

The liquid direction and deodorant composition divided into a multilayer according to the present invention is not mixed with a low specific gravity first solvent such as liquid paraffin, a high specific gravity second solvent such as water, the first solvent and the second solvent, It comprises a third solvent having a specific gravity of the intermediate, characterized in that it is made by dissolving two or more kinds of volatile substances such as fragrance substance, deodorant substance in each of the first solvent and the second solvent.

The first solvent was selected in consideration of physical and chemical properties such as specific gravity and polarity in order to select a solvent having good volatility and forming a layer without mixing or dissolving with a second solvent such as water. . Liquid paraffin as a preferred organic solvent is a non-polar organic solvent composed of only hydrocarbon, and is excellent in safety and volatility, widely used in household goods and industrial use, and also excellent in solubility in fragrances such as limonene and α-pinene, which are nonpolar organic materials. In the embodiment according to the present invention, liquid paraffin is used as trade name ISOPAR-G of Exxon Chemical Co., Ltd. having good volatility.

Preferably, the second solvent may be water or the like. This second solvent is particularly advantageous for dissolving polar substances.

The composition may further include solvents that are not mixed with the first solvent, the second solvent, or the third solvent, and may form a separate layer, thereby forming a multilayer structure of three or more layers.

The third solvent may be a lower alcohol having 1 to 4 carbon atoms. In order to prevent the volatile substance dissolved in the second solvent and the volatile substance dissolved in the first solvent from mixing with each other between the second solvent and the first solvent, the first solvent and the second solvent are not mixed with each other. A third solvent having a specific gravity of is used. Specifically, in order to add a layer between the aqueous solution layer and the liquid paraffin layer, it is necessary to select a material whose specific gravity is between water and liquid paraffin and does not mix with water or liquid paraffin. Lower alcohols having 1 to 4 carbon atoms, preferably alcohols having a low molecular weight such as ethanol and propanol may be used. These lower alcohols are often used as solvents because of their good volatility, low specific odors and the ability to dissolve fragrances. Usually, the higher the molecular weight of the alcohol, the better the layer with the aqueous electrolyte solution, but the admixture between the specific odor and the liquid paraffin also increases, so be careful in the selection. Ethanol can be separated from the aqueous solution containing an appropriate amount of salts, but the stable state is not good, it is recommended to use more than propanol. Ethanol having a low molecular weight is easily mixed with water due to its strong polarity, but has a problem of being mixed with an oil-soluble solvent because butanol having a relatively high molecular weight increases hydrophobicity. That is, in the case of more than butanol, there is a problem that the liquid paraffin and the layer separation does not occur. Normal propanol or isopropanol may be considered as the third solvent as the lower alcohol, and normal propanol may be preferably used to form a layer separated from the aqueous electrolyte solution and liquid paraffin.

The second solvent is characterized in that the electrolyte solution in which the electrolyte is dissolved. This involves using the principle of salting out for the separation of alcohols and aqueous solutions. Aqueous solutions containing an appropriate amount of salts are also layered with ethanol which mixes well with water. As the salts, sodium chloride, calcium chloride and potassium chloride can be used. In the embodiment according to the present invention, sodium chloride was used to separate the layers in small amounts.

Liquid aroma divided into a multi-layer according to the present invention, a method for producing a deodorant composition is mixed with a low specific gravity first solvent such as liquid paraffin, a high specific gravity second solvent such as water, the first solvent and the second solvent In the manufacture of a liquid aroma, deodorant composition comprising a third solvent having a specific gravity thereof, and containing two or more kinds of volatile substances such as fragrance and deodorant, (1) 2 to the first solvent A first solution preparation step of preparing a first solution by dissolving any one or more volatilized substances; (2) a second solution preparation step of preparing a second solution by dissolving a volatile material different from the volatile material dissolved in the first solvent among two or more volatile materials in the second solvent; (3) a first political step of allowing the second solution having a high specific gravity to remain in the container 1 capable of accommodating the composition; (4) a second political step of allowing the third solvent, which is not mixed with the first solvent and the second solvent, to have a specific gravity therebetween, to remain on the second solution; And (5) a third political step of allowing the first solution to remain on the third solvent.

In the first solution preparation step of (1), a first solution is prepared by dissolving any one of two or more volatile materials in the first solvent, and preparing a material having the lowest specific gravity layer.

In the second solution preparation step of (2), a second solution is prepared by dissolving a volatile material different from the volatile material dissolved in the first solvent among two or more volatile materials in a solvent having a higher specific gravity than the first solvent. Step to create. In this second solution preparation step, it is particularly preferable to dissolve the electrolyte in the second solvent in order to prevent the second solution from mixing with the third solvent and the second solution. For manufacturing convenience, the electrolyte is dissolved in water and filled. The second liquid layer 8 and the first liquid layer 7 are separated from each other by using normal propanol as an alcohol having appropriate hydrophobicity and hydrophilicity as the second solution, the first solution, and the third solvent in which an appropriate concentration of electrolyte is dissolved. It can be stably separated.

Thereafter, the second solution having a high specific gravity is settled in the container 1 capable of accommodating the composition in the first political step in the order of high specific gravity, and is not mixed with the first solvent and the second solvent thereon. After leaving a third solvent having a specific gravity in the middle on the second solution, the first solution is left on the third solvent to obtain a liquid odor and deodorant composition divided into a multilayer of at least three layers or more. can do. The liquid fragrance and deodorant composition thus prepared are very advantageous for the application of deodorant substances having different chemical properties from those of fragrances or fragrances, which have complicated application methods due to various chemical properties. In the case of terpine-based fragrances such as limonene, it is insoluble in strong alcohols, but soluble in nonpolar solvents such as liquid paraffin. Polar substances such as phenyl ethyl alcohol and cinnamic aldehydes, on the other hand, are slightly dissolved in highly polar alcohols or in some cases water. Liquid fragrance and deodorant composition according to the present invention is a non-polar organic solvent, liquid paraffin, normal propanol and water having both hydrophilicity and hydrophobicity as a main component, so that the fragrance can be uniformly volatilized without using a surfactant and stabilized fragrance You don't have to. Therefore, the present invention does not use a surfactant, so the prescription has a simple advantage.

As deodorant as a volatile substance, organic extracts such as organic acids and flavonoids are generally used, and generally, they are soluble in water or alcohol. In the case of a fragrance using an organic solvent, the addition of the deodorant is limited, but in the case of the liquid aroma divided into a multilayer according to the present invention including alcohol and water, in the case of the deodorant composition, the application of the deodorant as well as the fragrance is very easy. . In the case of the fragrance deodorant which contains the fragrance and the deodorant material, the fragrance and the deodorant may be reduced due to the action of the fragrance and the deodorant. It is a good way to realize the proper function of each raw material because the component to be dissolved is specialized and the contact is reduced.

Since the liquid direction and deodorant composition divided into a multilayer according to the present invention is a liquid having a multi-layered structure, an active ingredient of insecticide / insecticide function can be added to liquid paraffin and normal propanol to prepare an application as an insecticide deodorant.

In addition, when using a pigment in the liquid direction of the multi-layered structure, deodorant composition, even if one pigment is used, there is an advantage that various effects can be obtained according to the difference in solubility. In the case of the water-soluble pigment, it does not stay in the liquid paraffin layer which is the first liquid layer 7, but stays in a proper ratio in the normal propanol layer and the second liquid layer 8, which are the third solvent. In this case, a color difference occurs depending on the difference between the solvent properties and the pigment content, thereby producing a visual decorative effect. In some cases, oil-soluble pigments and water-soluble pigments may be used together to emphasize visual effects.

After the third policing step (5) may further include a stationary step of further mixing the solvents that are not mixed with the first solution, the second solution or the third solvent and can form a separate layer, 3 It is also possible to further form a multilayer structure of more than a layer.

In addition, as shown in FIG. 1, the liquid direction divided into the multilayer which concerns on this invention, the deodorant composition volatilization mechanism, the direction which forms at least three layers, the container 1 which accommodates a deodorant composition, and the said container 1 At least two heating plates located at the top of the), at least two wicks connected to the heating plates and extending to the bottom of the container 1, and one of the wicks It comprises a wick partition 6 to avoid contact with the solutions or solvents that make up the layers except the lowermost layer.

In general, three or more wicks are required for the effective volatilization of the liquid phase, deodorant composition of the multi-layer structure of three or more layers. However, when volatilizing the first liquid layer 7 and the third liquid layer 9 together through a volatilization plate using a volatilization structure as shown in FIG. 1, the composition divided into three layers into two wicks is effectively volatilized. You can.

Both wicks 2 and 5 used must reach the bottom of the container 1 for complete volatilization of the composition. In addition, while the first wick 2 is in contact with all the layers of the composition having a multi-layered structure, the second wick 5 is not in contact with the solutions or solvents constituting the layers except the lowermost layer of the composition. It is preferable to be surrounded by the wick partition 6 to avoid. If possible, it is better to use the wick bulkhead 6 completely overlaid on the second wick 5, but a separate wick bulkhead having a length that can pass through the three-layered liquid while surrounding the wick even when using a wick without a shell. It is also possible to use (6). In order to increase the appearance preference, a capillary wick may be used as the second wick 5.

By adjusting the area of the first volatilization plate 3 and the second volatility plate 4, the volatilization amount and volatilization rate of the first liquid layer 7 and the third liquid layer 9, the volatilization amount of the second liquid layer 8, and The speed of volatilization can be adjusted simply. In the case where the product is emphasized in aroma performance, the area of the first volatilization plate 3 may be increased while increasing the amount of the first liquid layer 7 and the third liquid layer 9 in which the fragrance is dissolved, and in the case of the product in which the deodorizing performance is emphasized, The area of the second volatilization plate 4 may be increased while increasing the amount of the second liquid layer 8.

In addition, the liquid direction divided into the multilayer according to the present invention, the deodorant composition volatilizer, the direction of forming at least three layers, the container (1) for accommodating the deodorant composition, and at least two located at the upper end of the container (1) At least two heating plates, at least two wicks connected to the heating plates and extending to the bottom of the container 1, and a solution in which any one of the wicks forms layers other than the lowest layer of the composition. Or a first solvent having a low specific gravity such as liquid paraffin, a second specific solvent having a high specific gravity such as water, and the like in the container 1 of the volatilization mechanism including the wick partition 6 which does not come into contact with the solvents. It is not mixed with a solvent and a second solvent, and includes a third solvent having an intermediate specific gravity thereof, and is formed by dissolving two or more kinds of volatile substances such as aroma and deodorant in each of the first solvent and the second solvent. To stand the direction of the liquid, deodorant composition to be separated by a multi-layer features a true.

By the configuration as described above, it is excellent in the visual effect of the appearance, it can provide a three-layer liquid odor deodorant product that can control the amount of volatilization by separating the odor layer and the odor layer.

Hereinafter, preferred embodiments and comparative examples of the present invention will be described.                     

The following examples are intended to illustrate the invention and should not be understood as limiting the scope of the invention.

Example 1

To prepare a deodorant composition of the liquid phase divided into a multilayer according to a conventional method as the composition of Table 1 below.

ingredient Content (% by weight) Liquid paraffin 25 Normal-propanol 30 10% aqueous sodium chloride solution 40 Floral Spices 5 Aqueous dye B-4.01% Some

As a result, three-layer liquid perfumes with different colors were prepared regardless of the order of addition of the solvents.

Comparative Example 1

To prepare a deodorant composition of the liquid phase divided into a multilayer according to a conventional method as the composition of Table 2 below.

ingredient Content (% by weight) Liquid paraffin 25 Isopropanol 30 10% aqueous sodium chloride solution 40 Floral Spices 5 Aqueous dye B-4.01% Some

As a result, isopropanol and an aqueous sodium chloride solution were mixed to prepare a two-layer liquid perfume.

Comparative Example 2

To prepare a deodorant composition of the liquid phase divided into a multilayer according to a conventional method as the composition of Table 3 below.

ingredient Content (% by weight) Liquid paraffin 25 Normal Butanol 30 10% aqueous sodium chloride solution 40 Floral Spices 5 Aqueous dye B-4.01% Some

As a result, normal butanol and liquid paraffin were mixed to prepare a two-layer liquid perfume.

Therefore, according to the present invention, since it is not necessary to use a surfactant in order to form a stable liquid phase, the formulation is simple, the visual effect of the appearance is excellent, and divided into a multi-layer which can control the amount of volatilization by separating the aromatic layer and the deodorizing layer Aroma of the liquid, there is an effect that can provide a deodorant composition.

Although the present invention has been described in detail only with respect to the described embodiments, it will be apparent to those skilled in the art that various modifications and variations are possible within the technical scope of the present invention, and such modifications and modifications are within the scope of the appended claims.

Claims (9)

It comprises a non-polar solvent consisting of only hydrocarbon, water, and normal propanol not mixed with the non-polar solvent and water, characterized in that it is made by dissolving two or more volatiles selected from aromatic or deodorant in each of the non-polar solvent and water Liquid direction or deodorant composition divided into multilayers. delete The method of claim 1, The water is an aromatic or deodorant composition of the multi-layered liquid, characterized in that the electrolyte solution in which the electrolyte selected from the group consisting of sodium chloride, calcium chloride and magnesium chloride dissolved. delete In the preparation of a liquid aromatic or deodorant composition comprising a non-polar solvent consisting of only hydrocarbon, water, and normal propanol not mixed with the non-polar solvent and water, and containing two or more volatile substances selected from the aromatic or deodorant , (1) preparing a first solution by dissolving any volatilized substance of two or more kinds of volatilized substances in a non-polar solvent consisting of only hydrocarbon; (2) a second solution preparation step of preparing a second solution by dissolving a volatile material different from a volatile material dissolved in a non-polar solvent consisting of only hydrocarbon among two or more volatile materials in water; (3) a first political step of leaving the second solution having a high specific gravity in a container capable of containing the composition; (4) a second political step of allowing normal propanol not mixed with the nonpolar solvent and water to stand on the second solution; And (5) a third political step of placing the first solution on the normal propanol; Method of producing a liquid aroma or deodorant composition divided into a multi-layer characterized in that consisting of. delete The method of claim 5, In the second solution preparation step of (2), water is an electrolyte selected from the group consisting of sodium chloride, calcium chloride and magnesium chloride is dissolved, the method of producing a liquid or deodorant composition of the liquid divided into multiple layers. A container containing a direction or deodorant composition forming at least three layers, at least two or more heating plates located on top of the container, and at least two or more wicks connected to the heating plates and extending to the bottom of the container And a wick partition which comprises one of the wicks so as not to come into contact with a solution or solvents constituting the layers other than the lowest layer of the composition. Voluntary Organization. A container containing a direction or deodorant composition forming at least three layers, at least two or more heating plates located on top of the container, and at least two or more wicks connected to the heating plates and extending to the bottom of the container And a non-polar solvent consisting of hydrocarbon, water only in the container of the volatilization mechanism including a wick which prevents any one of the wicks from contacting the solution or the solvents constituting the layers other than the lowest layer of the composition. , And a liquid fragrance or deodorant composition divided into a multilayer comprising normal propanol which is not mixed with the non-polar solvent and water, and dissolved by dissolving at least two kinds of volatiles selected from aromatic or deodorant in each of the non-polar solvent and water. Divided into multi-layer characterized in that Group is direction or deodorant composition vaporization of the liquid phase.

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