KR100715614B1 - Hair setting composition - Google Patents

Abstract

The present invention relates to a hair dressing composition containing a polyalkylene glycol represented by the following formula (1). In more detail, the hair dressing composition according to the present invention contains polyalkylene glycol represented by the following Chemical Formula 1, and can be reshaped without stickiness and can be easily removed with a shampoo.

(Wherein A is methyl or hydrogen, R is hydrogen, methyl, or a mixture thereof, and n is 4 to 800).

Polyalkylene glycol * Hair dressing * Sticky * Hair resetting

Description

Hair setting composition

The present invention relates to a hair dressing composition containing a polyalkylene glycol represented by the following formula (1). In more detail, the hair dressing composition according to the present invention contains polyalkylene glycol represented by the following Chemical Formula 1, and can be reshaped without stickiness and can be easily removed with a shampoo.

[Formula 1]

(Wherein A is methyl or hydrogen, R is hydrogen, methyl, or a mixture thereof, and n is 4 to 800).

Many techniques have been published in the context of hair dressing agents, which are being marketed in a variety of products including gels, mousses, sprays, liquids and waxes. Among the above products, except for wax, which has shown much growth in recent years, mainly the fixed polymer (Fixative Polymer) shows a hair dressing effect. The fixed polymers are largely classified into anionic, cationic, nonionic, and zwitterionic polymers, and are used in various products according to their characteristics. Specifically, the anion polymer is mainly used in aerosol products such as spray or mousse because the acrylate system is fast drying and strong fixing force. Cationic polymers are also called polyquaterniums and are mainly used in conditioning agents or gels. In addition, nonionic polymers include PVP, PVP / VA, and are mainly used in gels and waxes. In addition, the zwitterionic polymers are a betaine acrylate copolymer, and are used in various ways such as mousse, gel, and spray. However, although the fixing polymers have excellent setting and sustaining power, they remain sticky and harden too hard when used, resulting in difficulty in rearrangement and lack of flexibility.

Recently, new fixed polymers have been added to increase the flexibility by attaching functional groups, such as silicone, hydrocarbon, urethane, and amine oxides, to the basic fixed polymer backbone, and form a mixture of two raw materials having rigidity and flexibility. Also sold as.

However, since there is basically a fixed polymer in the raw material, the stickiness cannot be completely removed and the film looks unnatural due to the hardening of the film.

Accordingly, the present inventors have studied to reduce the stickiness and search for a material that can be re-established. As a result, polyalkylene glycol has a film forming ability and shows hairstyling power. It was found that the shampoo can be removed cleanly, to complete the present invention.

Accordingly, an object of the present invention relates to a hair dressing composition containing a polyalkylene glycol represented by the following formula (1).

In order to achieve the above object, the hair dressing composition according to the present invention is characterized in that it contains 5 to 50% by weight of polyalkylene glycol represented by the following formula (1) as the main film forming agent with respect to the total weight of the composition. In addition, the hair dressing composition of the present invention, in the polyalkylene glycol, 10 to 50% by weight of solvent, 1.0 to 10% by weight of polyol, 0.5 to 10% by weight of fixed polymer, 0.1 to 2.0% by weight of thickener, based on the total weight of the composition %, Neutralizer 0.1 to 2.0% by weight and purified water.

[Formula 1]

(Wherein A is methyl or hydrogen, R is hydrogen, methyl, or a mixture thereof, and n is 4 to 800).

Hereinafter, the present invention will be described in more detail.

Hereinafter, the respective components contained in the hair dressing composition according to the present invention will be described in detail.

In the hair dressing composition of the present invention, the polyalkylene glycol contained as the main film forming agent has a film forming ability, has hairstyling power and is non-sticky, so that the film is flexible and can be rearranged. have. In particular, PEG-X (Polyethyleneglycol-X) (55 ≦ X ≦ 350) having an average molecular weight of 3,000 to 20,000 in the polyalkylene glycol is preferable, and X means the number of polymerization of ethylene oxide groups of 55 to 350. It is. Specific examples of the PEG-X (Polyethyleneglycol-X) (55≤X≤350) are PEG-55, PEG-60, PEG-75, PEG-80, PEG-90, PEG-100, PEG-135, PEG- 150, PEG-180, PEG-200, PEG-220, PEG-240, PEG-350 and the like. The PEG-X (55 ≦ X ≦ 350) may be used alone or in combination of two or more, and contains 5 to 50% by weight based on the total weight of the composition. This is because it is a range that effectively gives formulation stability and fixation force.

The solvent contained in the hair dressing composition of the present invention is a component for dissolving an auxiliary film former, a fragrance component, and controlling a drying rate. Specifically, the solvent includes ethyl alcohol, isopropyl alcohol, acetone, carbitol, and the like. . The solvent may be used alone or in combination of two or more, and contains 10 to 50% by weight based on the total weight of the composition. This is because it is effective for cold temperature stability and drying speed.

The polyol contained in the hair dressing composition of the present invention is a component that serves as a secondary dissolving agent and a plasticizer, and specifically, polyethylene glycol, glycerin, 1,3-butylene glycol, and the like. The polyol is contained in 1.0 to 10% by weight based on the total weight of the composition. This is to make the film soft.

The fixed polymer contained in the hair dressing composition of the present invention is an auxiliary film former component, specifically, a polyvinylpyrrolidone polymer or copolymer, polyvinylpyrrolidone / vinylacetate (polyvinylpyrrolidone / vinylacetate), hydrophilic polyurethane, methacroylethylbetaine / acrylate copolymer, alkylacrylate / alkylamineoxidecopolymer, polyquaternium -11 (polyquaternium-11), octylacrylamide acrylate / butylamine ethyl methacrylate copolymer (Octylacrylamideacrylate / butylamine ethylmetharylate copolymer), polyurethane and acrylate copolymers (Polyurethane & acrylatecopolymer). The fixed polymer may be appropriately selected and used in consideration of usability and stability, and may be used alone or in combination of two or more thereof. The fixation polymer may be contained in 0.5 to 10% by weight relative to the total weight of the composition, because of the initial fixing force.

The thickener contained in the hair dressing composition of the present invention is a component for imparting proper viscosity and stability of the formulation, and specifically, hydroxyethylcellulose, polyquaternium-4, and cellulose gum. ), Carbomer (Carbomer) and the like, the type was selected according to the properties of the film former and the thickener is contained in 0.1 to 2.0% by weight based on the total weight of the composition, because of the stability of the formulation.

The neutralizer contained in the hair dressing composition of the present invention is a component that neutralizes the thickener and the fixed polymer, and specifically, triethanolamine (TriEthanolAmine), aminopropanol, KOH, NaOH, and the like. The neutralizing agent is contained in 0.1 to 2.0% by weight based on the total weight of the composition. This depends on the amount of fixed polymer.

The hair dressing composition according to the present invention may further include an emulsifier, a pH adjusting agent, a preservative, a fragrance, purified water, and the like. The emulsifier is ethoxy federated fat (C _{12 -22)} alcohol _{(Ethoxylated fatty (C 12 -22)} alcohol), PEG- (5 ~ 60) in particular - hardened castor oil (hydrogenated castor oil), fats (C _{12 -22)} and the like acid monoester / diester (Fatty _{(12 -22} C) acid monoester / diester), ethylene (1-30) oxide glycerol (ethylene (1-30) oxideglycerol). The emulsifier is contained in 0.1 to 20% by weight based on the total weight of the composition. The pH adjusting agent is an alpha hydroxy acid (AHA) component such as citric acid, citric acid, lactic acid, glycolic acid, and the like to add a pH of the composition to 4.0 to 8.0. .

The hair dressing composition according to the present invention can be prepared in a formulation of hair gel, mousse, wax, spray, hair liquid and the like.

Hereinafter, the present invention will be described in more detail with reference to Examples, but the present invention is not limited to these Examples.

PEG-X used in the following examples was purchased from the raw material of Clariant, Sasol, Dow Chemical.

[Examples 1-9, Comparative Examples 1-2]

To the composition of Table 1, Examples 1 to 9 and Comparative Examples 1 to 2 were prepared as a hair gel formulation.

PEG-X (for X = 20, 32, 55, 60, 75, 90, 100, 150, 180, 240, 350) Component (content; wt%) Example 1 Example 2 Example 3 Example 4 Example 5 Example 6 Example 7 Example 8 Example 9 Comparative Example 1 Comparative Example 2 Purified water EDTA-2Na PEG-55 PEG-60 PEG-75 PEG-90 PEG-100 PEG-150 PEG-180 PEG-240 PEG-350 PEG-20 PEG-32 P G Carbomer Ethyl Alcohol Tween 60 DM Flavor TEA PVP K30 Citric Acid Remaining amount 0.1 10----------5.0 0.5 15 1.0 0.2 0.2 0.48 2.0 0.1 Remaining amount 0.1-10---------5.0 0.5 15 1.0 0.2 0.2 0.48 2.0 0.1 Remaining amount 0.1--10--------5.0 0.5 15 1.0 0.2 0.2 0.48 2.0 0.1 Remaining amount 0.1---10-------5.0 0.5 15 1.0 0.2 0.2 0.48 2.0 0.1 Remaining amount 0.1----10------5.0 0.5 15 1.0 0.2 0.2 0.48 2.0 0.1 Remaining amount 0.1-----10-----5.0 0.5 15 1.0 0.2 0.2 0.48 2.0 0.1 Remaining amount 0.1------10----5.0 0.5 15 1.0 0.2 0.2 0.48 2.0 0.1 Remaining amount 0.1-------10---5.0 0.5 15 1.0 0.2 0.2 0.48 2.0 0.1 Remaining amount 0.1--------10--5.0 0.5 15 1.0 0.2 0.2 0.48 2.0 0.1 Remaining amount 0.1--------10-5.0 0.5 15 1.0 0.2 0.2 0.48 2.0 0.1 Remaining amount 0.1----------10 5.0 0.5 15 1.0 0.2 0.2 0.48 2.0 0.1

[Test Example 1]

Ten panelists were allowed to use the hair gels of Examples 1 to 9 and Comparative Examples 1 to 2 for one month, and the satisfaction with setting force, stickiness, and body strength was evaluated by the values of 1, 3, 5, 7, and 9 It was. In addition, the availability of the formulations was investigated. The results are shown in Tables 2 to 5 below.

Satisfaction with setting power panel Example Comparative example One 2 3 4 5 6 7 8 9 One 2 end 5 5 5 5 7 7 7 9 9 3 3 I 5 5 5 5 7 9 9 9 9 3 3 All 5 5 7 7 7 7 7 7 7 3 3 la 5 5 5 5 5 7 9 9 9 3 3 hemp 3 5 5 7 7 7 7 9 9 3 3 bar 5 5 7 7 7 7 9 9 9 3 3 four 5 7 7 7 7 7 9 9 9 3 3 Ah 5 7 7 7 7 7 7 7 9 3 3 character 5 5 7 7 7 9 9 9 9 3 5 car 7 5 5 5 5 7 7 9 9 5 5 Average 5.0 5.4 6.0 6.2 6.6 7.4 8.0 8.6 8.8 3.2 3.4

Satisfaction with Stickiness panel Example Comparative example One 2 3 4 5 6 7 8 9 One 2 end 7 7 7 7 7 5 5 5 5 7 7 I 7 7 7 7 7 7 5 5 5 9 9 All 7 9 7 7 7 5 5 5 5 9 9 la 9 9 9 7 7 7 7 5 5 9 9 hemp 7 7 7 7 5 5 5 5 5 9 7 bar 9 9 9 7 7 7 5 5 5 9 9 four 7 7 7 7 5 5 5 5 5 9 9 Ah 9 7 7 7 7 7 5 5 5 9 9 character 7 7 7 7 7 7 5 5 5 9 9 car 9 7 7 5 5 5 5 5 5 9 9 Average 7.8 7.6 7.4 6.8 6.4 6.0 5.2 5.0 5.0 8.8 8.6

Satisfaction with cleaning power panel Example Comparative example One 2 3 4 5 6 7 8 9 One 2 end 9 9 7 7 7 7 5 5 5 9 9 I 9 7 7 7 7 5 5 5 5 9 9 All 9 9 9 7 7 7 7 5 5 9 9 la 9 7 7 7 7 5 5 5 5 9 9 hemp 9 9 7 7 7 5 5 5 3 9 9 bar 7 7 7 5 5 5 5 5 5 9 9 four 9 9 9 7 7 5 5 5 5 9 9 Ah 9 7 7 7 5 5 5 5 5 9 9 character 9 9 9 7 7 5 5 5 5 9 9 car 9 9 9 7 7 5 5 5 3 9 9 Average 8.8 8.2 7.8 6.8 6.6 5.4 5.2 5.0 4.6 9.0 9.0

availability panel Example Comparative example One 2 3 4 5 6 7 8 9 One 2 end X X O O O O O X X X X I O X O O O O O X X X X All O O O O X X X O O O O la O X X O O O O X X O O hemp O O O O X X X O O X O bar X O O O O O X O O X X four O O O O O X X O O X X Ah X X X X O O O X X X X character X O O O O O X O O X X car X X X X O O O X X X X Average 5 5 7 8 8 7 5 5 5 2 3

According to Test Example 1 via hair gel containing PEG-X (for X = 20, 32, 55, 60, 75, 90, 100, 150, 180, 240, 350), Comparative Example 1 and Comparative Example 2 In the case of the satisfaction with the stickiness and washing power was high, but the satisfaction with the setting power was considerably low, it was confirmed that it is difficult to use as a hair dressing agent.

On the other hand, in the case of Examples 1 to 9 have a very high satisfaction with the setting force has the optimum effect as a hair dressing agent, and also improve the disadvantages of stickiness, it is possible to re-finish without stickiness and has the effect of washing well in shampoo I could confirm it.

Examples 10 to 18 and Comparative Examples 3 to 4

To the composition of Table 6, Examples 10-18, Comparative Examples 3-4 was prepared as a hair liquid formulation.

PEG-X (for X = 20, 32, 55, 60, 75, 90, 100, 150, 180, 240, 350) Component (Content; Weight%) Example 10 Example 11 Example 12 Example 13 Example 14 Example 15 Example 16 Example 17 Example 18 Comparative Example 3 Comparative Example 4 Purified water EDTA-2Na PEG-55 PEG-60 PEG-75 PEG-90 PEG-100 PEG-150 PEG-180 PEG-240 PEG-350 PEG-20 PEG-32 P G Ethyl Alcohol Tween 60 DM Flavor PVP K30 Citric Acid Remaining amount 0.1 10----------5.0 30 1.0 0.05 0.2 2.0 0.2 Remaining 0.1-10---------5.0 30 1.0 0.05 0.2 2.0 0.2 Remaining amount 0.1--10--------5.0 30 1.0 0.05 0.2 2.0 0.2 Remaining 0.1---10-------5.0 30 1.0 0.05 0.2 2.0 0.2 Remaining amount 0.1----10------5.0 30 1.0 0.05 0.2 2.0 0.2 Remaining amount 0.1-----10-----5.0 30 1.0 0.05 0.2 2.0 0.2 Remaining amount 0.1------10----5.0 30 1.0 0.05 0.2 2.0 0.2 Remaining amount 0.1------10---5.0 30 1.0 0.05 0.2 2.0 0.2 Remaining amount 0.1--------10--5.0 30 1.0 0.05 0.2 2.0 0.2 Remaining amount 0.1---------10-5.0 30 1.0 0.05 0.2 2.0 0.2 Remaining amount 0.1----------10 5.0 30 1.0 0.05 0.2 2.0 0.2

[Test Example 2]

10 panelists in the same manner as in Test Example 1 to the satisfaction of the setting force, stickiness and fine force for the following Examples 10-18 and Comparative Examples 3-4 to the numerical values of 1, 3, 5, 7, and 9 It was. In addition, the availability of the formulations was investigated. The results are shown in Tables 7 to 10 below.

Satisfaction with setting power panel Example Comparative example 10 11 12 13 14 15 16 17 18 3 4 end 5 5 5 5 5 7 7 9 9 3 3 I 5 5 5 5 7 9 9 9 9 3 3 All 5 5 7 7 7 7 7 7 9 3 3 la 5 5 5 5 5 7 9 9 9 3 3 hemp 3 5 5 5 7 7 7 9 9 3 3 bar 5 5 7 7 7 7 9 9 9 3 3 four 5 7 7 7 7 7 9 9 9 3 3 Ah 5 5 7 7 7 7 7 7 9 3 3 character 5 5 7 7 7 7 7 9 9 3 5 car 5 5 5 5 5 7 7 9 9 5 5 Average 5.0 5.2 6.0 6.0 6.4 7.2 7.8 8.6 9.0 3.2 3.4

Satisfaction with Stickiness panel Example Comparative example 10 11 12 13 14 15 16 17 18 3 4 end 7 7 7 7 7 5 5 5 5 7 7 I 7 7 7 7 7 7 5 5 5 9 9 All 7 9 7 7 7 5 5 5 5 9 9 la 7 9 9 7 7 7 7 3 5 9 9 hemp 7 7 7 7 5 5 5 5 3 9 7 bar 9 9 9 7 7 7 5 5 5 9 9 four 7 7 7 7 5 5 5 5 5 9 9 Ah 9 7 7 7 7 7 5 7 5 9 9 character 7 7 7 7 7 7 7 5 5 9 9 car 9 9 7 5 5 5 5 5 5 9 9 Average 7.6 7.8 7.4 6.8 6.4 6.0 5.4 5.0 4.8 8.8 8.6

Satisfaction with cleaning power panel Example Comparative example 10 11 12 13 14 15 16 17 18 3 4 end 9 9 7 7 7 7 5 5 5 9 9 I 9 7 7 7 7 5 5 5 5 9 9 All 9 9 9 7 7 7 7 5 5 9 9 la 9 7 7 7 7 5 5 5 5 9 9 hemp 9 9 7 7 7 7 5 5 3 9 9 bar 7 7 7 5 5 5 5 5 5 9 9 four 9 9 9 7 7 5 5 5 5 9 9 Ah 9 7 7 7 5 5 5 5 5 9 9 character 9 9 9 7 7 5 5 5 5 9 9 car 9 9 9 9 7 5 5 3 3 9 9 Average 8.8 8.2 7.8 7.0 6.6 5.6 5.2 4.8 4.6 9.0 9.0

availability panel Example Comparative example 10 11 12 13 14 15 16 17 18 3 4 end X X O O O O O X X X X I O X O O O O O X X X X All O O O O X X X O O O O la O X X O O O O X X O O hemp O O O O X X X O O O O bar X O O O O X X O O X X four O O O O O O X O O X X Ah X X X X O O O X X X X character X O O O O O X O O X X car X X X X O O O X X X X Average 5 5 7 8 8 7 5 5 5 3 3

According to Test Example 2 via Hair Liquid containing PEG-X (for X = 20, 32, 55, 60, 75, 90, 100, 150, 180, 240, 350), Comparative Example 3 and Comparative Example 4 In the case of the satisfaction with the stickiness and washing power was high, but the satisfaction with the setting power was considerably low, it was confirmed that it is difficult to use as a hair dressing agent.

On the other hand, in the case of Examples 10 to 18, the satisfaction with the setting force is considerably high and has the optimal effect as a hair dressing agent, and also improves the disadvantages of stickiness and can be re-adhesive without stickiness and has the effect of being washed well in the shampoo. I could confirm it.

As described above, the hair dressing composition according to the present invention contains polyalkylene glycol and can be easily reshaped without being sticky and can be easily removed with a shampoo, such as hair gel, mousse, wax, spray, hair liquid, and the like. It can be prepared in a variety of formulations.

Claims (8)

5-50% by weight of polyalkylene glycol represented by the following Chemical Formula 1, 10-50% by weight of solvent, 1.0-10% by weight of polyol, 0.5-10% by weight of fixed polymer, thickener 0.1 As a hair dressing composition characterized by containing -2.0 wt%, a neutralizing agent 0.1-2.0 wt% and purified water; The solvent is at least one member selected from the group consisting of ethyl alcohol, isopropyl alcohol, acetone, and carbitol; The polyol is at least one member selected from the group consisting of polyethylene glycol, glycerin, and 1,3-butylene glycol; The fixed polymer may be a polyvinylpyrrolidone polymer or copolymer (polyvinylpyrrolidone polymer or copolymer), polyvinylpyrrolidone / vinylacetate, hydrophilic polyurethane, methacroylethylbetaine / acrylic Latex copolymer (Methacroylethylbetaine / acrylate copolymer), Alkylacrylate / alkylamine oxide copolymer (Alkylacrylate / alkylamineoxide copolymer), Polyquaternium-11, Octylacrylamide acrylate / Butylamine ethyl methacrylate copolymer (Octylacrylamideacrylate / butylamineethylmetharylate copolymer), at least one member selected from the group consisting of polyurethane and acrylate copolymers (Polyurethane &acrylatecopolymer); The thickener is at least one selected from the group consisting of hydroxyethylcellulose, polyquaternium-4, cellulose gum, and carbomer; The neutralizing agent is a hair dressing composition, characterized in that at least one selected from the group consisting of triethanolamine (TriEthanolAmine), aminopropanol, KOH and NaOH: [Formula 1]

Wherein A is methyl or hydrogen, R is hydrogen, methyl, or a mixture thereof, and n is 4-800. The method of claim 1, wherein the polyalkylene glycol is PEG (Polyethyleneglycol, hereinafter equal to) -X (55≤X≤350) having an average molecular weight in the range of 3,000-20,000, PEG-55, PEG-60, PEG-75, At least one member selected from the group consisting of PEG-80, PEG-90, PEG-100, PEG-135, PEG-150, PEG-180, PEG-200, PEG-220, PEG-240, and PEG-350 Hair-styling composition made into. delete delete delete delete The hair dressing composition according to claim 1 or 2, wherein the composition has excellent hair setting power and improved stickiness. The hair dressing composition of claim 1 or 2, wherein the composition is a hair gel, mousse, wax, spray, or hair liquid formulation.