JP2001288041A - Hair cosmetic for hair fixing - Google Patents

Abstract

PROBLEM TO BE SOLVED: To provide a hair cosmetic for hair fixing, excellent in usability, good in finish, further good in persistence and refixing properties of the set hair, having good stability with time and capable of providing matted feeling. SOLUTION: This hair cosmetic for hair fixing comprises (A) 1.0-30.0 wt.% solid oil component, (B) 1.0-30.0 wt.% liquid oil component, (C) 0.1-20.0 wt.% fatty acid esters of glycol, (D) 0.01-2.0 wt.% thickener and (E) 30.0-90.0 wt.% water.

Description

DETAILED DESCRIPTION OF THE INVENTION

[0001]

TECHNICAL FIELD The present invention relates to a hair cosmetic for hairdressing. More specifically, the present invention relates to a hair cosmetic for hair styling, such as a cream, using the styling power of a solid oil.

[0002]

2. Description of the Related Art Hairdressing hair cosmetics generally used include hairdressing hair cosmetics such as mousses, hair sprays, gels, and set lotions for setting hair with a set resin;
Hair sticks that mainly use the styling power of solid wax,
There are hair cosmetics for hair styling such as pomade, hair cream and hair wax. In recent years, a high-quality feeling that suppresses hair gloss,
There is a tendency to prefer hair cosmetics for hair styling having a so-called matte feeling. Conventionally, it is known that when a fatty acid glycol is blended with a hair wax, a hair cosmetic for hair styling with less gloss and a matt feeling can be obtained.

[0003] However, conventional hair cosmetics having a matte feeling have poor stability at high temperatures, and have a hardened and hardened hair after styling, and do not have a soft and soft feel. It was not satisfactory, such as the lack of strength. Furthermore, at the time of use, growth is heavy,
There were also problems with usability such as stickiness.

[0004]

SUMMARY OF THE INVENTION The present invention has been made in view of the above circumstances, and has as its object to provide a mat which is excellent in usability and finish, has good set continuity, good hair re-setting properties, and is stable over time. An object of the present invention is to provide a hair cosmetic for hair styling with a feeling.

[0005]

Means for Solving the Problems The present inventors have conducted intensive studies to solve the above-mentioned problems, and as a result, have found that the above-mentioned problems can be solved by blending a thickener with fatty acid glycols. The present invention has been completed.

That is, the present invention provides the following (A):
A hairdressing hair cosmetic comprising the components (B), (C), (D) and (E). (A) Solid oil content: 1.0 to 30.0% by weight (B) Liquid oil content: 1.0 to 30.0% by weight (C) Fatty acid glycols: 0.1 to 20.0% by weight (D) Increase Viscosity: 0.01 to 5.0% by weight (E) Water: 20.0 to 90.0% by weight.

Preferred fatty acid glycols for exhibiting the effects of the present invention include ethylene glycol distearate, polyethylene glycol distearate (degree of polymerization 3), polyethylene glycol stearate (degree of polymerization 2), and polyethylene glycol oleate (degree of polymerization). 2) one or more selected from polyethylene glycol dioleate (degree of polymerization 8) and polyethylene glycol dioleate (degree of polymerization 12), and the thickener is a water-soluble polymer, particularly a carboxyvinyl polymer or It is sodium acrylate.

[0008] In the present invention, the solid oil content is defined as room temperature (2
5 ° C.) means a solid or semi-solid oil, and the liquid oil means a liquid oil at room temperature (25 ° C.). In addition, fatty acid glycols are esters of fatty acids and glycols.

[0009]

DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENTS Hereinafter, embodiments of the present invention will be described in detail.

The solid oil used in the present invention is:
It is a solid oil generally used for cosmetics. Specific examples include, for example, cacao butter, coconut oil, horse fat, hardened coconut oil, palm oil, tallow, sheep tallow, hardened tallow, palm kernel oil, lard, beef bone fat, mokuro kernel oil, hardened oil , Beef leg fat, mokuro, hardened castor oil, etc .; Hexyl laurate, reduced lanolin, jojoba wax, hard lanolin, shellac wax, POE lanolin alcohol ether, POE lanolin alcohol acetate, POE cholesterol ether, POE hydrogenated lanolin alcohol ether and other waxes; polyethylene wax, paraffin wax, ceresin, wax Phosphorus, microcrystalline wax, Runasera, hydrocarbon waxes ozokerite and the like; cetyl alcohol, cetostearyl alcohol, stearyl alcohol, higher alcohols such as behenyl alcohol; monostearyl glycerol ether (batyl alcohol)
Fatty acid glyceryl ethers such as acetoglyceride,
Fatty acid glycerides such as tri-2-heptylundecanoic acid glyceride; Of these, carnauba wax and microcrystalline wax are preferred for exhibiting the effects of the present invention, and it is particularly preferred to combine them in combination. Any one or more of these solid oils can be selected and used.

The amount of the solid oil is 1.0 to 30.0% by weight based on the total amount of the hair cosmetic for hair styling.
0 to 15.0% by weight. More preferably, 3.0 to 1
2.0% by weight. If the amount is less than 1.0% by weight,
Hair styling is not enough. On the other hand, if it exceeds 30.0% by weight, problems such as spreadability and stickiness arise.

The liquid oil used in the present invention is:
It is a liquid oil component generally used in cosmetics. Specifically, for example, avocado oil, evening primrose oil, camellia oil,
Turtle oil, macadamia nut oil, sunflower oil, almond oil, corn oil, mink oil, olive oil, rapeseed oil, egg yolk oil, sesame oil, persic oil, wheat germ oil, sasanqua oil, castor oil, linseed oil, safflower oil, cottonseed oil, Liquid oils such as eno oil, soybean oil, peanut oil, teaseed oil, kaya oil, rice bran oil, cinnamon oil, Japanese kiri oil, jojoba oil, germ oil; cetyl octanoate, cetyl 2-ethylhexanoate, dimethyloctane Hexyldecyl acid, ethyl laurate, hexyl laurate, isopropyl myristate, 2-hexyldecyl myristate, myristyl myristate, octyl dodecyl myristate, isopropyl palmitate, 2-ethylhexyl palmitate, 2-hexyldecyl palmitate, palmitin Acid 2
-Heptylundecyl, butyl stearate, isocetyl stearate, isocetyl isostearate, decyl oleate, dodecyl oleate, oleyl oleate, myristyl lactate, cetyl lactate, diisostearyl malate, cholesteryl 12-hydroxystearylate,
Castor oil fatty acid methyl ester, N-lauroyl-L-
Glutamic acid-2-octyldodecyl ester, 2-ethylhexyl succinate, diisobutyl adipate, 2-hexyldecyl adipate, di-2-heptylundecyl adipate, diisopropyl sebacate, di-2-ethylhexyl sebacate, di-2 -Ethylene glycol ethylhexanoate, neopentyl glycol dicaprate, neopentyl glycol dioctanoate, acetoglyceride, glycerin di-2-heptylundecanoate,
Glycerin trioctanoate, glycerin tri-2-ethylhexanoate, glycerin trimyristate, glycerin triisopalmitate, glyceride tri-2-heptylundecanoate, trimethylolpropane tri-2-ethylhexanoate, trimethylolpropane triisostearate Ester oils such as pentaneerythritol tetraoctanoate and pentaerythritol tetra-2-ethylhexanoate; hydrocarbon oils such as liquid paraffin, ozokerite, squalene, pristane, polybutene; dimethylpolysiloxane, methylphenylpolysiloxane, diphenylpolysiloxane, etc. Cyclic polysiloxanes such as octamethylcyclotetrasiloxane, decamethylcyclopentasiloxane, and dodecamethylcyclohexanesiloxane Rokisan, amino-modified polysiloxanes, polyether-modified polysiloxane, alkyl-modified polysiloxanes, silicone oils various modified polysiloxanes and fluorine-modified polysiloxanes.
Any one or more of these liquid oils can be selected and used. Of these, hydrocarbon oils, ester oils, and silicone oils are preferred for exhibiting the effects of the present invention.

The amount of the liquid oil is 1.0 to 30.0% by weight based on the total amount of the hair cosmetic, and preferably 5.
0 to 20.0% by weight. If the compounding amount is less than 1.0% by weight, there is a problem of usability such as growth. On the other hand, if it exceeds 30.0% by weight, a sticky feel is produced.

The fatty acid glycols used in the present invention are esters obtained from fatty acids and glycols as described above, and include diesters and monoesters depending on the degree of esterification of the fatty acids. Among these,
Esters of either ethylene glycol or polyethylene glycol, that is, mono- or diesters composed of fatty acid and polyethylene glycol or fatty acid and ethylene glycol are preferred. Among them, diesters composed of fatty acids and polyethylene glycol or fatty acids and ethylene glycol are preferred. These may be used alone or in combination of two or more. The fatty acid constituting the monoester or the diester has 12 to 2 carbon atoms.
Two linear or branched, saturated or unsaturated fatty acids are preferred. The degree of polymerization of polyethylene glycol is 2 to 20.
Is preferred.

Specific examples of the monoester or diester of the present invention include, for example, ethylene glycol dioleate, ethylene glycol distearate,
Diesters of fatty acids and ethylene glycol such as ethylene glycol dipalmitate, ethylene glycol dibehenate, ethylene glycol diisostearate,
Polyethylene glycol distearate (degree of polymerization 3)
(Hereinafter, polyethylene glycol (degree of polymerization: 3)
It is expressed as -3, and the number is changed depending on the degree of polymerization. ), PEG-20 distearate, PEG-8 diisostearate, PEG-8 dioleate, PEG-12 dioleate, PEG-2 dimyristate, PEG-2 dilaurate and diesters comprising polyethylene glycol and Monoester consisting of fatty acids such as ethylene glycol oleate and ethylene glycol isostearate and ethylene glycol, PEG-2 stearate, PEG-2 oleate, P behenate
And monoesters composed of fatty acids such as EG-8 and polyethylene glycol. Among these, ethylene glycol distearate, PEG-3 distearate, PEG-8 dioleate, PEG-12 dioleate, PEG-2 stearate, and PEG-2 oleate are preferred.

The amount of the fatty acid glycol is 0.1 to 20.0% by weight, preferably 1 to 15% by weight, based on the total amount of the hair cosmetic. More preferably, 5 to 12
% By weight. If the amount is less than 0.1% by weight, it is difficult to obtain a matte feeling, and the hair styling power also deteriorates. Meanwhile, 2
If the content exceeds 0.0% by weight, the finish of spreadability, sticky usability and fluffiness will be insufficient. In addition, the stability is deteriorated.

The thickener used in the present invention is a thickener generally used in cosmetics, and includes polysaccharides,
Examples include water-soluble polymers such as natural polymers, semi-synthetic polymers, and synthetic polymers, and inorganic water-swellable clay minerals. Specifically, for example, polysaccharides include starch, glycogen, hyaluronic acid, chondroitin, guar gum, locust bingham, quince seed, galactan, arabic gum, tragacanth gum, xanthan gum, dextran, succinoglucan, chondroitin sulfate, mucoitin sulfate , Pullulan and the like. Examples of natural polymers include gum arabic, tragacanth gum, galactan, guar gum, carob gum, karaya gum, carrageenan, pectin, agar, quince seed (quince), alge colloid (brown algae extract), starch (rice, corn, potato, wheat). Glycyrrhizic acid, collagen, casein, albumin, gelatin and the like. Examples of the semi-synthetic polymer include starch-based polymers such as carboxymethyl starch and methylhydroxypropyl starch, methylcellulose, ethylcellulose, methylhydroxypropylcellulose, hydroxyethylcellulose, sodium cellulose sulfate, hydroxypropylcellulose, and sodium carboxymethylcellulose (CMC). And alginate polymers such as sodium alginate and propylene glycol alginate.
As the synthetic polymer, for example, polyvinyl alcohol,
Vinyl-based polymers such as polyvinyl methyl ether, polyvinylpyrrolidone, carboxyvinyl polymer (Carbopol; manufactured by Goodrich), polyethylene glycol 2
Polyoxyethylene polymers such as 0000, 40,000 and 60,000, polyoxyethylene polyoxypropylene copolymer copolymer polymers, and acrylic polymers such as sodium polyacrylate, polyethyl acrylate and polyacrylamide Polymers, polyethyleneimines, cationic polymers, and the like are included. Examples of the inorganic water-swellable clay mineral include bentonite, A1Mg silicate (Vegum), laponite, hectorite, and silicic anhydride. These thickeners can be used arbitrarily as one kind or two or more kinds.

Of these, water-soluble polymers, particularly carboxyvinyl polymers and sodium polyacrylate, are preferred from the viewpoint of usability and stability.

The compounding amount of the thickener is from 0.01 to 5.0% by weight based on the total amount of the hair cosmetic for hair styling, and preferably from 0.05 to 5.0, which is excellent in matte feeling, non-stickiness and good spreadability.
2.0% by weight. More preferably, 0.1 to 1.0
% By weight. If the amount is less than 0.01% by weight, the spreadability, sticky usability and fluffy finish will not be sufficient. In addition, the stability is deteriorated. On the other hand, when the content exceeds 5.0% by weight, it is difficult to obtain a matte feeling, and the hair styling power also deteriorates.

The amount of water used in the present invention is 20.0 to 90.0% by weight based on the total amount of the hair cosmetic. Preferably it is 40.0 to 80.0% by weight. 20.
If it is less than 0% by weight, the finish is hard, the spread during use is poor, and the stability is poor. On the other hand, if it is more than 90.0% by weight, sufficient hair styling power cannot be obtained.

The hair cosmetic for hair styling of the present invention may contain other components usually used in cosmetics and pharmaceuticals, in addition to the above-mentioned components, as long as the effects of the present invention are not impaired. Examples include surfactants, humectants, powder components, ultraviolet absorbers, sequestering agents, lower alcohols, amino acids, antioxidants, preservatives, drugs, fragrances, and the like.

Examples of the surfactant include fatty acid soaps such as sodium stearate and sodium palmitate;
-Anionic surfactants such as N-acyl glutamates such as monosodium lauroyl glutamate, disodium N-stearoyl glutamate;

Sorbitan monoisostearate, sorbitan monopalmitate, sorbitan sesquioleate,
Sorbitan fatty acid esters such as sorbitan trioleate, diglycerol tetra-2-ethylhexylate sorbitan, glycerin polyglycerin fatty acids such as mono-cottonseed oil fatty acid glycerin, glycerin sesquioleate, glyceryl monostearate, propylene glycol monostearate, etc. Lipophilic nonionic surfactants such as propylene glycol fatty acid esters, hydrogenated castor oil derivatives and glycerin alkyl ethers;

POE-sorbitan monostearate, P
POE sorbitan fatty acid esters such as OE-sorbitan monooleate, POE-sorbit monolaurate,
POE sorbitol fatty acid esters such as POE-sorbitol monostearate, POE glycerin fatty acid esters such as POE-glycerin monoisostearate, POE-glycerin triisostearate, POE monooleate, POE distearate, ethylene glycol cysteate, etc. POE fatty ethers, POE stearyl ether, POE alkyl ethers such as POE2-octyldodecyl ether, POE cholestanol ether, and POE such as POE dinonyl phenyl ether
E alkylphenyl ethers, pluronics such as pluronics, POE.POP2-decyltetradecyl ether, POE.POP hydrogenated lanolin, POE.P
POE / POP alkyl ethers such as OP glycerin ether, tetra POE / tetra PO such as tetronic
P ethylenediamine condensates, POE hydrogenated castor oil, P
POE castor oil hardened castor oil derivatives such as OE hardened castor oil triisostearate, POE hardened castor oil maleic acid, POE beeswax lanolin derivatives such as POE sorbitol beeswax, alkanolamides such as coconut oil fatty acid diethanolamide, POE propylene glycol fatty acid Hydrophilic nonionic surfactants such as esters and sucrose fatty acid esters;

Cationic surfactants such as alkyltrimethylammonium salts such as stearyltrimethylammonium chloride, alkylpyridinium salts such as cetylpyridinium chloride, alkylquaternary ammonium salts, alkyldimethylbenzylammonium salts, dialkylmorphonium salts and benzalkonium chloride Agent;

Imidazoline amphoteric surfactants such as 2-cocoyl-2-imidazolinium hydroxide-1-carboxyethyloxy disodium salt and betaine compounds such as lauryl dimethylaminoacetate betaine, alkyl betaine, amido betaine and sulfo betaine And amphoteric surfactants such as surfactants.

As humectants, for example, glycerin,
Polyhydric alcohols such as 1,3-butylene glycol, dipropylene glycol, and propylene glycol are exemplified. The compounding amount is 0.1% of the total amount of the hair cosmetic for hair styling.
~ 65.0% by weight is preferred.

[0028]

The present invention will be described more specifically below with reference to examples. The compounding amount is% by weight. Prior to the description of Examples, evaluation methods and evaluation criteria used in each Example and Comparative Example will be described.

[Usability and Finish] (Evaluation Method) A use test was conducted by a specialized panel of 20 persons, and the evaluation points given by each person were totaled. Evaluation items and evaluation points are as follows. (Evaluation items and evaluation points) Spread: The spread is light, and hair is easy to hand. Stickiness: No stickiness to hands. Hair styling power: A natural hair styling power with a natural hair flow is obtained and it lasts. Hair reshaping: Hair can be easily reshaped by hand. Fluffy feeling: Hair does not harden and has a soft fluffy feeling. Matte feeling: Hair does not shine and has a matte feeling. (Evaluation point) 5 points: Very good. 4 points: good. 3 points: Normal. 2 points: bad. 1 point: very bad. (Evaluation criteria) A: The total score is 90 points or more. ：: The total score is 70 or more and less than 90 points. □: The total score is 50 or more and less than 70 points. Δ: The total score is 30 or more and less than 50. X: The total score is less than 30 points.

[Stability] (Evaluation method) Each sample was stored at each temperature condition of 50 ° C.
The viscosity and change in appearance after 4 weeks were evaluated according to the following evaluation methods. (Evaluation criteria) ○: There is no deterioration such as separation. Δ: Deterioration, such as slight separation. ×: Deterioration such as separation occurred.

A creamy hairdressing composition having the composition shown in Tables 1 to 4 was prepared. Tables 1 to 4 also show the results of evaluation according to the above evaluation methods and evaluation criteria.

[0032]

[Table 1] ―――――――――――――――――――――――――――――――――――― Example Comparative Example Ingredients ―――― ― ――――――――――― 1 2 1 2 3 4 ―――――――――――――――――――――――――――――――― ―――― (1) Microcrystalline wax 8.0 8.0 8.0 8.0 8.0 8.0 (2) Carnauba wax 5.0 5.0 5.0 5.0 5.0 5.0 (3) Liquid paraffin 10.0 10.0 10.0 10.0 10.0 10.0 (4) Tetraoctanoic acid 3.0 3.0 3.0 3.0 3.0 3.0 Penta Erislit (5) Distearic acid 10.0 10.0 10.0---Ethylene glycol (6) Stearic acid 4.5 4.5 4.5 4.5 4.5 4.5 (7) POE (60) hydrogenated castor oil 3.0 3.0 3.0 3.0 3.0 3.0 (8) Carboxyvinyl polymer 0.2- ― 0.2 ― ― (9) Sodium polyacrylate ― 0.2 ― ― 0.2 ― (10) Water residue residue residue Remainder Remainder Remainder (11) Triethanolamine 0.2 0.2 0.2 0.2 0.2 0.2 ―――――――――――――――――――――――――――――――― ― Loose ◎ ◎ × ○ ○ ○ Sticky ◎ ◎ △ ○ ○ ○ Hair styling ○ ○ ○ △ △ △ Hair re-dressing ○ ○ ○ △ △ △ Fluffy ○ ○ × ○ ○ △ Matte ◎ ◎ ○ × × × Stability ○ ○ △ ○ ○ ○ ―――――――――――――――――――――――――――――――――――

[Production method] (1) to (7) were carried out at 80 ° C to 90 ° C.
The mixture was stirred and dissolved at ℃ to make an oil phase, and (8) to (10) were
The mixture is stirred and dissolved at 0 ° C to 80 ° C to obtain an aqueous phase. After the oil phase was added to the water phase to emulsify, (11) was added for neutralization, degassing, cooling and filling.

As can be seen from Table 1, Examples 1 and 2 in which ethylene glycol distearate and carboxyvinyl polymer or sodium polyacrylate were blended,
The matte feeling was excellent, the usability and the finish were good, the durability of the set, the hair re-shaping properties were good, and the stability was good. On the other hand, Comparative Example 1 except for the carboxyvinyl polymer and sodium polyacrylate had a matte feeling, but had poor stability, poor usability, and poor finish. In Comparative Examples 2 and 3, which did not contain ethylene glycol distearate, no matte feeling was obtained, and the finish, the durability of the set, and the hair re-shaping property were poor. In Comparative Example 4, which did not contain any of ethylene glycol distearate, carboxyvinyl polymer, and sodium polyacrylate, there was no matte feeling, and the finish, the durability of the set, and the re-shaping property were poor.

[0035]

[Table 2] ――――――――――――――――――――――――――――――――― Comparative Example Example Comparative Example Ingredients ――― ――――――――――――――――― 5 3 4 5 6 6 ―――――――――――――――――――――――――――― ――――――― Microcrystalline wax 8.0 8.0 8.0 8.0 8.0 8.0 Carnauba wax 5.0 5.0 5.0 5.0 5.0 5.0 Liquid paraffin 10.0 10.0 10.0 10.0 10.0 10.0 Tetraoctanoic acid 3.0 3.0 3.0 3.0 3.0 3.0 Pentaerythrit distearic acid 10.0 10.0 10.0 10.0 10.0 10.0 Ethylene glycol stearic acid 4.5 4.5 4.5 4.5 4.5 4.5 POE (60) hydrogenated castor oil 3.0 3.0 3.0 3.0 3.0 3.0 Carboxyvinyl polymer 0.005 0.01 0.05 2.0 5.0 10.0 Water Residue Residue Residue Residue Residue Triethanolamine 0.2 0.2 0.2 0.2 0.2 0.2 0.2- ―――――――――――――――― ――――――――――――――――― No stretch × ○ ◎ ◎ ○ ○ Sticky △ ○ ◎ ◎ ○ ○ Hair styling ○ ○ ○ ○ ○ × Hair re-dressing ○ ○ ○ ○ ○ × Fluffy feeling × ○ ○ ○ ○ ○ Matte feeling ○ ○ ◎ ◎ ○ × Stability △ ○ ○ ○ ○ ○ ―――――――――――――――――――――――――――― ―――――――

[Preparation method] Preparation was carried out in the same manner as in Table 1.

As can be seen from Table 2, Examples 3 to 5 containing 0.01 to 5.0% by weight of the carboxyvinyl polymer were used.
6 is excellent in matte feeling, good in usability and finish, good in set persistence, good in styling, and in terms of stability,
It was good. In particular, in the range of 0.05 to 2.0% by weight, the matte feeling, the spreadability, and the stickiness were excellent. On the other hand, Comparative Example 5 in which 0.005% by weight was blended was heavy, sticky, and finished without fluffy feeling. Also, the stability was poor. Also, 10.0
In Comparative Example 6 in which the weight% was blended, the mat feeling was insufficient, and the hair styling power and the hair re-shaping property were also poor.

[0038]

[Table 3] ―――――――――――――――――――――――――――――――――― Comparative Example Example Comparative Example ― ――――――――――――――――― 7 7 8 9 10 8 ――――――――――――――――――――――――――― ――――――――― Microcrystalline wax 8.0 8.0 8.0 8.0 8.0 8.0 Carnauba wax 5.0 5.0 5.0 5.0 5.0 5.0 Liquid paraffin 10.0 10.0 10.0 10.0 10.0 10.0 Tetraoctanoic acid 3.0 3.0 3.0 3.0 3.0 3.0 Pentaerythrit distearic acid 0.01 0.1 1.0 15.0 20.0 30.0 Ethylene glycol stearic acid 4.5 4.5 4.5 4.5 4.5 4.5 POE (60) hydrogenated castor oil 3.0 3.0 3.0 3.0 3.0 3.0 Carboxyvinyl polymer 0.2 0.2 0.2 0.2 0.2 0.2 Water Residue Residue Residue Residue Residue Triethanolamine 0.2 0.2 0.2 0.2 0.2 0.2 ―――――――――――――――――― ――――――――――――――――― No stretch ○ ○ ◎ ◎ ○ × Sticky ○ ○ ◎ ◎ ○ × Hair styling △ △ ○ ○ ○ ○ Hair re-dressing △ ○ ○ ○ ○ ○ Fluffy feeling ○ ○ ○ ○ ○ × Matte feeling × ○ ◎ ◎ ○ ○ Stability ○ ○ ○ ○ ○ × ―――――――――――――――――――――――――――― ―――――――

[Preparation method] Prepared in the same manner as in Table 1.

As can be seen from Table 3, Examples 7 to 10 in which ethylene glycol distearate was blended in an amount of 0.1 to 20.0% by weight had excellent matt feeling, good usability, good finish, long lasting set, The hair reshaping property was good, and the stability was also good. In particular, in the range of 1.0 to 15.0% by weight, the matte feeling was excellent, and the spreadability and stickiness were also excellent. On the other hand, Comparative Example 7, in which 0.01% by weight was blended,
The matte feeling was insufficient, and the hair styling ability and re-styling properties were poor. In Comparative Example 8 in which 30.0% by weight was blended, the spread was heavy, and the stickiness and finish were not fluffy. Also, the stability was poor.

[0041]

[Table 4] ―――――――――――――――――――――――――――――――――― Example Ingredients ―――――― ――――――――――――――― 11 12 13 14 15 16 ――――――――――――――――――――――――――――― ――――――― Microcrystalline wax 8.0 8.0 8.0 8.0 8.0 8.0 Carnauba wax 5.0 5.0 5.0 5.0 5.0 5.0 Liquid paraffin 10.0 10.0 10.0 10.0 10.0 10.0 Tetraoctanoic acid 3.0 3.0 3.0 3.0 3.0 3.0 Pentaerythrit Ethylene glycol oleate 10.0 ― ― ― ― ― PEG-3 distearate ― 10.0 ― ― ― ― PEG-2 stearate ― ― 10.0 ― ― ― PEG-2 oleate ― ― ― 10.0 ― ― PEG-8 dioleate ― ― ― ― 10.0 ― PEG dioleate −12 ― ― ― ― ― 10.0 Stearic acid 4.5 4.5 4.5 4.5 4.5 4.5 POE ( 0) Hardened castor oil 3.0 3.0 3.0 3.0 3.0 3.0 Carboxyvinyl polymer 0.2 0.2 0.2 0.2 0.2 0.2 Water Residue Residue Residue Residue Residue Triethanolamine 0.2 0.2 0.2 0.2 0.2 0.2 ―――――――――――――― ――――――――――――――――――――― Spread ○ ◎ ◎ ◎ ◎ ◎ Sticky ○ ◎ ◎ ◎ ◎ ◎ Hair styling ○ ○ ○ ○ ○ ○ Re-shaping ○ ○ ○ ○ ○ ○ Fluffy feeling ○ ○ ○ ○ ○ ○ Matte feeling ○ ◎ ◎ ◎ ◎ ◎ Stability ○ ○ ○ ○ ○ ○ ―――――――――――――――――――――――― ―――――――――――

[Preparation method] Prepared in the same manner as in Table 1.

As can be seen from Table 3, Examples 11 to 16 in which various fatty acid glycols were blended were all excellent in matte feeling, good in usability and finish, long lasting of the set,
The hair reshaping property was good, and the stability was also good. In particular, PEG-3 distearate, P stearate
EG-2, PEG-2 oleate, PEG dioleate
-8, PEG-12 dioleate was excellent.

Hereinafter, examples of the present invention produced according to a conventional method will be described. All of these examples were excellent in matte feeling, good in usability and finish, good in set persistence, good in hair re-shaping, and good in stability.

Example 17 Cream Hairdressing Carnauba Wax 5.0% by Weight Microcrystalline Wax 8.0 Stearyl Alcohol 2.0 Liquid Paraffin 10.0 Methylphenyl Polysiloxane 5.0 5.0 Pentaerythritol Tetraoctanoate 3.0 Ethylene Distearate Glycol 12.0 POE (60) hydrogenated castor oil 3.0 Stearic acid 4.5 Isostearic acid 1.0 Carboxyvinyl polymer 1.0 Propylene glycol 8.0 Triethanolamine 1.1 Ion-exchanged water Residual antioxidant Proper preservative Agent appropriate amount fragrance appropriate amount

Example 18 Cream Hairdressing Carnauba Wax 2.0% by Weight Paraffin Wax 3.0 Stearic Acid 2.0 Liquid Paraffin 5.0 Dimethyl Polysiloxane 3.0 2-Ethylhexyl Sebacate 2.0 POE Glyceryl Isostearate 1.5 Glycerin monostearate 1.5 Propylene glycol 10.0 Caustic soda 0.2 Carboxyvinyl polymer 0.2 Polyethylene glycol 20,000 0.05 Sodium polyacrylate 0.1 PEG-2 stearate 0.5 Oleic acid PEG-2 0.5 Ethylene glycol distearate 10.0 Ion-exchanged water Residual perfume Appropriate amount

Example 19 Cream Hairdressing Liquid Liquid Paraffin 15.0% by weight Glycerin tri-2-ethylhexanoate 2.0 Vaseline 10.0 Stearyl alcohol 1.0 Ceresin 1.0 Carboxyvinyl polymer 0.1 Glycerin 0 Polyoxyethylene hydrogenated castor oil 3.0 Caustic soda 0.1 Deionized water Residue Ethylene glycol distearate 5.0

Example 20 Pomade Hair Styling Glycerin 50.0% by weight Propylene glycol 3.0 Ethanol 10.0 Carboxyvinyl polymer 0.5 Bentonite 0.05 Hydroxypropylcellulose 0.1 Polyoxyethylene octyldodecyl ether 1.0 Beeswax 1.0 liquid paraffin 2.0 caustic soda 0.1 edetate 0.1 methyl paraben 0.1 ion exchange water residue ethylene glycol distearate 5.0 PEG-8 dioleate 2.0 PEG-12 dioleate 1.0

Example 21 Gel Hairdressing Liquid Paraffin 5.0% by weight Dimethylpolysiloxane 3.0 Highly polymerized methylpolysiloxane 7.0 Microcrystalline wax 2.0 1,3-butylene glycol 5.0 Ethanol 10.0 Fatty acid polyoxyethylene glyceryl 1.0 Polyoxyethylene nonyl phenyl ether 2.0 Carboxyvinyl polymer 0.1 Xanthan gum 0.2 Polyvinylpyrrolidone 0.4 Ethyl cellulose 0.3 Methyl paraben 0.1 Ion exchange water Residue Ethylene glycol distearate 5. 0 PEG-3 distearate 2.0 Ethylene glycol oleate 3.0

Example 22 Cream Hairdressing Carnauba Wax 5.0% by Weight Microcrystalline Wax 8.0 Stearyl Alcohol 2.0 Liquid Paraffin 10.0 Methylphenyl Polysiloxane 5.0 5.0 Pentaerythritol Tetraoctanoate 3.0 Ethylene Distearate Glycol 12.0 POE (60) hydrogenated castor oil 3.0 Stearic acid 4.5 Isostearic acid 1.0 Sodium polyacrylate 1.0 Propylene glycol 8.0 Triethanolamine 1.1 Ion-exchanged water Residual antioxidant Appropriate amount Preservatives qs perfume qs

[0051]

As described in detail above, according to the present invention,
Natural, soft, fluffy finish with light stretchiness and non-greasy usability, long lasting set, good re-shaping, stable over time, matte hair cosmetic Is provided.

 ────────────────────────────────────────────────── ─── Continuing on the front page (72) Inventor Hiromi Ueda 1050 Nippa-cho, Kohoku-ku, Yokohama-shi, Kanagawa Prefecture F-term in Shiseido Daiichi Research Center (reference) 4C083 AA082 AA122 AB032 AB051 AB442 AC012 AC022 AC072 AC102 AC122 AC182 AC242 AC262 AC352 AC391 AC392 AC401 AC402 AC422 AC432 AC482 AC532 AC542 AD042 AD072 AD091 AD092 AD152 AD262 AD282 AD352 BB12 BB13 BB36 CC32 DD22 DD27 DD31 DD41 EE06 EE07 EE28 FF05

Claims (4)

[Claims] 1. A hairdressing hair cosmetic comprising the following components (A), (B), (C), (D) and (E). (A) Solid oil content: 1.0 to 30.0% by weight (B) Liquid oil content: 1.0 to 30.0% by weight (C) Fatty acid glycols: 0.1 to 20.0% by weight (D) Increase Viscosity: 0.01 to 5.0% by weight (E) Water: 20.0 to 90.0% by weight 2. Fatty acid glycols include ethylene glycol distearate, polyethylene glycol distearate (degree of polymerization 3), polyethylene glycol stearate (degree of polymerization 2), polyethylene glycol oleate (degree of polymerization 2), polyethylene glycol dioleate ( The hair cosmetic according to claim 1, which is one or more selected from the group consisting of a polymerization degree of 8) and polyethylene glycol dioleate (polymerization degree of 12). 3. The method according to claim 1, wherein the thickener is a water-soluble polymer.
The hair cosmetic for hairdressing according to the above. 4. The hair cosmetic for hairdressing according to claim 3, wherein the water-soluble polymer is a carboxyvinyl polymer or sodium polyacrylate.