KR100611046B1 - The multi-purpose bioceramic coating for shield to water vein, radio wave and activity to energy passage - Google Patents
The multi-purpose bioceramic coating for shield to water vein, radio wave and activity to energy passage Download PDFInfo
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Abstract
본 발명은 친 환경 아크릴바인더와 특이한 구성원소 비율의 천연옥,동(cupper),알루미늄,참숯파우더를 사용한 다기능(multi-purpose)세라믹 코팅재 조성물에 관한 것으로 건축물 실내(바닥,벽체,천정)에 도포시 수맥차단,유해전자파차단,경락활성(經絡活性) 등의 특수 바이오물성 발휘하여 인체의 기능을 활성화하여 신진대사 및 성인병을 예방할수 있는 장점을 지니고 있다The present invention relates to a multi-purpose ceramic coating composition using an environmentally friendly acrylic binder and a specific constituent element ratio of nacre, cupper, aluminum, charcoal powder, and is applied to indoor (floor, wall, ceiling) It has the advantage of being able to prevent the metabolism and adult diseases by activating the functions of the human body by demonstrating special bio properties such as water blocking, harmful electromagnetic interference, and meridian activity
특히 본 발명품은 아주대학교 회전전자파 측정연구팀의 시험결과 수맥차단,유해전자파차단은 물론 경락순환 구동력 시험결과 방사된 회전전자파가 인체에 들어가 인체의 경락(經絡)의 에너지 흐름을 방해하는 에너지를 외부로 몰아내고 그 흐름을 정상화 시켜 인체의 면역활동 및 생체활동을 활성화시켜 건축물의 실내공간에서 발생될수 있는 두통,천식,피부염 등 각종 성인병을 예방할수 있는 장점을 지니고 있다In particular, the present invention was tested by Ajou University Rotational Electromagnetic Measurement Team, and it was found out that the rotating electromagnetic waves radiated as a result of the meridian circulation driving test as well as the harmful electromagnetic wave interception and the blocking of the harmful electromagnetic wave enter the human body and the energy that interferes with the energy flow of the human meridian It has the advantage of preventing various adult diseases such as headache, asthma, and dermatitis which may occur in the indoor space of the building by activating the immune activity and biological activity of the body by normalizing the flow
Description
근간에 의,식,주가 고급화되고 기능이 향상됨에 따라 각종 바이오(bio) 기능을 발휘하는 세라믹(ceramic)코팅재가 개발되고 있는 실정이며 이는 사람과 환경을 동시에 중시하는 현실임을 알수 있다Ceramic coating materials that exhibit various bio functions have been developed as a result of the improvement of ceramics and ceramics, and the improvement of functions, and it can be seen that this is a reality in which people and environment are emphasized at the same time
현재까지 개발되어 사용되고 있는 바이오세라믹 코팅재의 대부분은 각종 건축물내부에 도포하여 인체에 유익한 원적외선,음이온방사,항균,탈취등의 기능을 발휘함으로서 실내공간을 쾌적하고 건강한 공간으로 바꾸어주는 기능을 발휘하지만 명확한 결과를 확인할수 없으며 일률적인 바이오 기능(원적외선,음이온,항균,탈취)에 국한되어 있는 것이 사실이다Most of the bio-ceramic coatings that have been developed and used so far are applied to various buildings to exhibit functions of converting indoor space into a pleasant and healthy space by exercising functions such as far-infrared rays, anion radiation, antibacterial and deodorant useful for human body. The results can not be confirmed and it is confined to uniform biofunctions (far infrared ray, anion, antibacterial, and deodorization)
그이유는 현재 사용되고 있는 제품들이 단순히 바이오 기능을 발휘하는 세라믹 광물(황토,게르마늄,맥반석,일라이트 등)분말을 액상바인더(binder)에 혼합하여 제조한 것으로 발휘되는 기능 및 효과가 거의 유사한 수준을 벗어나자 못하고 있는 현실이다The reason for this is that the products currently being used are produced by mixing ceramic powders (loess, germanium, elvanite, ilite, etc.) powders, which simply exhibit biofunctions, into liquid binders, It is a reality that we can not escape.
본 발명은 특이한 구성원소를 지닌 천연옥,동(cupper),알루미늄,참숯파우더(powder)를 환경친화형 바인더에 혼합,분산하여 제조한 것으로 기본적인 바이오 기능이외의 특수한 기능 즉, 바닥에 도포시 지하밑을 흐르는 수맥을 차단하며 유해전자파를 차단시키는 기능 및 인체의 경락을 활성화하는 기능을 발휘하는 특수 바이오(bio)세라믹 코팅재로서 수맥 및 유해전자파가 흐르는 곳에서 수면 및 생활을 하게되면 인체의 경락이 활성화 되지못하여 두통,천식,알레르기성 피부염을 앓게되거나 이유없는 성인병이 발생된다는 사실은 오래전부터 알려지고 있는 사실이다The present invention is produced by mixing and dispersing natural oak, cupper, aluminum and charcoal powder having a specific constitutional element in an environmentally friendly binder. It has a special function other than the basic biofunction, namely, It is a special bio ceramic coating that blocks the harmful electromagnetic waves and activates the meridians of the human body by blocking the flowing sludge. When you sleep and live in a place where water and harmful electromagnetic waves flow, the meridians of the human body are activated It has long been known that headache, asthma, allergic dermatitis, or adult illness without cause is caused
따라서 본제품은 특수 기능성 바이오 세라믹 코팅재로서 기존 제품과의 차이점은Therefore, this product is a special functional bioceramic coating material.
1.환경친화적인 저(低)V.O.C(휘발성 유기화합물)아크릴 바인더의 사용1. Use of Environmentally Friendly Low V.O.C (Volatile Organic Compound) Acrylic Binder
2.특이한 구성원소 함유량을 지닌 천연옥 파우더의 사용2. Use of natural wood powder with a specific constituent element content
3.동(cupper),알루미늄(aluminium)파우더 및 참숯파우더의 사용 및 적절한 배합비율3. Use of cupper, aluminum powder and charcoal powder, and proper mixing ratio
4.수맥차단,유해전자파차단,경락(經絡)활성 등의 일반 바이오세라믹 코팅재가 발휘하기 힘든 특수한 기능발휘 등을 들수 있다4. Special function that general bio-ceramics coating materials such as water-blockage, harmful electromagnetic interference, and meridian activity are difficult to exhibit
본 발명은 친환경적인 저V.O.C의 바인더 조성물을 제공하는 것을 목적으로 한다. 또한 수맥차단, 유해전자파차단, 경락활성 등의 다양한 기능을 수행할 수 있는 바이오 세라믹 코팅제를 제공하는 것을 또 다른 목적으로 한다.It is an object of the present invention to provide an environmentally friendly low V.O.C binder composition. It is another object of the present invention to provide a bioceramics coating agent capable of performing various functions such as water blocking, harmful electromagnetic wave shielding, and meridian activity.
본 발명은 아크릴모노머로서 메틸 메타 아크릴레이트(Methyl meta acrylate) 30내지 40중량부와 2-에틸 헥실 아크릴레이트(2-Ethyl hexyl acrylate) 5내지10중량부, 계면활성제로서 도데실벤젠설포네이트(Dodecyl benzene sulfonate) 0.01 내지 0.5 중량부, 알카리성 부여제로 2-아미노-메틸-1-프로패놀 (2-amino-methyl-1-propanal) 0.5 내지 2 중량부, 내부가소제로서 디이소부틸 글루타레이트(Diisobuthyl glutarate)와 디이소 부틸 아디페이트(Diisso buthyl adiphate)와 디이소부틸숙시네이트(Diiso buthyl succinate)를 중량비 1:1:1로 혼합하여 0.5 내지 3중량부를 포함하여 구성되는 것을 특징으로 하는 친환경 바인더 조성물을 기술적 요지로 한다.
바람직한 실시예에 의하면 중합개시제로서 티비에치피오(TBHPO, Terciary butyl hydro peroxide)를 0.005 내지 0.03 중량부를 더 첨가하여 미반응 모노머를 제거하게 되는 것을 특징으로 한다.
또한 상기 조성물 30내지 40중량부에 천연옥 파우더 20내지 40중량부와 동파우더 5내지 10중량부와 알루미늄 파우더 10내지 15중량부와 참숯 2내지 5중량부를 투입하여 제조하는 것을 특징으로 하는 수맥차단,유해전자파차단,경락활성 등의 다(多)기능 바이오세라믹 코팅재 조성물을 또 다른 기술적 요지로 한다.
아래에 실시예를 통하여 본 발명을 상세히 설명한다The present invention relates to a thermosetting resin composition comprising 30 to 40 parts by weight of methyl methacrylate as an acrylic monomer and 5 to 10 parts by weight of 2-ethyl hexyl acrylate as a monomer and dodecylbenzenesulfonate (Dodecyl benzene sulfonate as an internal plasticizer, 0.5 to 2 parts by weight of 2-amino-methyl-1-propanal as an alkali-imparting agent, 0.1 to 2 parts by weight of diisobutyl glutarate and 0.5 to 3 parts by weight of diisobutyl adipate and Diiso buthyl succinate in a weight ratio of 1: 1: 1. 2. The eco-friendly binder composition according to claim 1, wherein the diisobutyl adipate is diisobutyl adipate. As a technical point.
According to a preferred embodiment of the present invention, 0.005 to 0.03 part by weight of terbary butyl hydroperoxide (TBHPO) is further added as a polymerization initiator to remove unreacted monomers.
And 20 to 40 parts by weight of natural wood powder, 5 to 10 parts by weight of copper powder, 10 to 15 parts by weight of aluminum powder and 2 to 5 parts by weight of charcoal are added to 30 to 40 parts by weight of the composition. A multi-functional bio-ceramic coating composition such as harmful electromagnetic interference, meridian activity and the like is another technical point.
Hereinafter, the present invention will be described in detail with reference to examples
실시예Example
1. 〈친환경 바인더의 제조〉1. <Preparation of Eco-friendly Binder>
제조탱크에 아크릴모노머로서 Methyl meta acrylate 30-40중량부, 2-Ethyl hexyl acrylate 5-10중량부, 계면활성제로서 Dodecyl benzene sulfonate 0.01-0.5중량부를 넣어 80℃에서 3-4시간동안 반응시킨후 동온도에서 1-2시간 숙성시킨다30 to 40 parts by weight of Methyl meta acrylate as an acrylic monomer, 5-10 parts by weight of 2-ethyl hexyl acrylate and 0.01-0.5 parts by weight of Dodecyl benzene sulfonate as a surfactant were reacted at 80 ° C for 3-4 hours, Mature for 1-2 hours at temperature
다음에 방부제 0.01-0.1중량부,알카리성 부여제로서 2-amino-methyl-1-propanol 0.5-2중량부를 넣어 40-50℃에서 30분간 교반시킨후 내부가소제로서 Diisobuthyl glutarate, Diisso buthyl adiphate, Diiso buthyl succinate의 혼합물(중량비 1:1:1)을 0.5-3중량부를 넣고 40-50℃ 에서 30분간 반응시킨다Then, 0.5 to 2 parts by weight of 2-amino-methyl-1-propanol was added as an alkali-imparting agent, and the mixture was stirred at 40 to 50 ° C for 30 minutes. Diisobutyl glutarate, Diisso buthyl adiphate, Diiso buthyl succinate (weight ratio 1: 1: 1) was added, and the mixture was reacted at 40-50 ° C for 30 minutes
일반적으로 아크릴에멀젼 제조시 알카리성 부여제로서 암모니아(ammonia)를 사용하고 있으나 취기가 독하며 가소성부여제로서 Texanol을 사용하고 있으나 이는 V.O.C(휘발성 유기화합물)에 해당되며 인체에 유해하며 환경을 오염시킨다Generally, ammonia (ammonia) is used as an alkali-imparting agent in the production of acrylic emulsion. However, Texanol is used as a plasticizing agent, but it is V.O.C (volatile organic compound), harmful to human body and pollutes the environment
다음에 미반응 모노머를 제거하기 위하여 TBHPO(Terciary Buthyl Hydro Peroxide)를 0.005-0.03중량부를 넣어 40-50℃에서 20-30분간 교반시킨후 친환경 수지물을 제조한다Next, 0.005-0.03 parts by weight of TBHPO (Tereric Buthyl Hydro Peroxide) is added to remove the unreacted monomer and stirred at 40-50 ° C for 20-30 minutes to prepare an environmentally friendly resin
이렇게 제조한 수지물은 환경부에서 지정한 V.O.C(휘발성 유기화합물)물질 함유량이 검사결과 0 ppm으로 측정되었다(검사방법 KSM 0031)The content of V.O.C (Volatile Organic Compound) substance designated by the Ministry of Environment was measured at 0 ppm in the resin thus prepared (Test Method KSM 0031)
2.〈다기능 세라믹 코팅재의 제조〉2. < Preparation of Multifunctional Ceramic Coating Material >
상기의 친환경 바인더 30-40중량부에 천연옥 파우더(300-400메쉬)20-40중량부,동(cupper)파우더 5-10중량부,알루미늄 파우더10-15중량부,참숯 2-5중량부,물 10-30중량부,분산제 0.05-2중량부,소포제 0.01-0.5중량부,침강방지제 1-3중량부를 넣고 10-30분간 1,000-2,000rpm으로 분산시킨후 소포제0.01-0.2중량부를 넣고 100-300rpm으로 10-20분간 저속교반 시킨다 이렇게 저속교반 시키는 이유는 양호한 소포(defoaming)효과를 얻을수 있으며 제품제조 완료시 기포가 없는 균일한 액상상태의 제품을 얻을수 있기 때문이다20-40 parts by weight of natural wood powder (300-400 mesh), 5-10 parts by weight of cupper powder, 10-15 parts by weight of aluminum powder, 2-5 parts by weight of charcoal, 10-30 parts by weight of water, 0.05-2 parts by weight of a dispersing agent, 0.01-0.5 parts by weight of an antifoaming agent and 1-3 parts by weight of an anti-settling agent are dispersed at 1,000-2,000 rpm for 10-30 minutes, 0.01-0.2 parts by weight of a defoaming agent, 300 rpm for 10 to 20 minutes. The reason for stirring at such a low speed is that a good defoaming effect can be obtained and a uniform liquid phase product without bubbles can be obtained when the product is manufactured
다음에 방부제 0.1-0.5중량부, 동결안정제 0.2-1중량부,알카리성 부여제로서 2-amono-methyl -1-propanol 0.1-0.5중량부를 넣어 500-1,000rpm으로 10-15분간 교반후 물 10-30부를 넣어 300-500rpm으로 10-15분 교반후 본 발명품을 제조한다Then, 0.1-0.5 parts by weight of a preservative, 0.2-1 parts by weight of a freezing stabilizer and 0.1-0.5 parts by weight of 2-amono-methyl-1-propanol as an alkali-imparting agent were added thereto. The mixture was stirred at 500-1,000 rpm for 10-15 minutes, 30 parts, and the mixture was stirred at 300-500 rpm for 10-15 minutes to prepare the present invention
본 발명에 사용된 천연옥 파우더의 성분조성비율은 다음과 같으며 이러한 조성비율의 천연옥이 많은 시험결과 가장 우수한 결과를 나타내었다The composition ratio of the natural wood powder used in the present invention is as follows.
발명에 사용된 천연옥 조성비율The percentage of the natural wood composition used in the invention
. Mgo : 38%. Mgo: 38%
. Sio2 : 52%. SiO2: 52%
. CaO : 1.0%. CaO: 1.0%
. Al2O3 : 7.8%. Al2O3: 7.8%
. K2O : 0.2%. K2O: 0.2%
또한 본 발명에 사용된 동(cupper),알루미늄,참숯의 투입량에 따라서도 제품의 물성에 큰 차이를 나타내게 되며 알루미늄 및 참숯의 함량이 많으면 제품의 점도가 높아 사용상 어려움이 있으며 제품의 가격이 상승되는 문제점이 있다Also, depending on the amount of copper, aluminum, and charcoal used in the present invention, the physical properties of the product are greatly different. When the content of aluminum and charcoal is high, the viscosity of the product is high and the product is difficult to use. There is a problem.
상술한 바와 같이 본 발명은 친환경,저V.O.C 타입의 아크릴에멀젼 수지와 특이한 구성원소 비율의 천연옥 파우더,동(cupper)파우더,알루미늄파우더,참숯파우더의 혼합물을 사용하여 제조한 새로운 형태의 다기능 바이오 세라믹 코팅재로서 기존제품들이 나타내고 있는 원적외선,음이온방사,항균,탈취기능 외에 수맥차단,유해전자파차단,경락활성등의 특수 바이오기능을 발휘하는 특징을 지니고 있으며 아주대학교 회전전자파 측정연구팀의 시험결과 우수한 물성을 나타내는 것으로 확인되었으며 특히 경락순환구동력시험은 본 발명품에서 방사된 회전전자파가 인체에 들어가 경락의 에너지 흐름을 방해하는 에너지를 외부로 몰아내고 그 흐름릉 정상화시켜 인체의 면역활동 및 생체활동을 활성화 시키는 작업을 계속적으로 반복하고 있음을 나타내었음As described above, the present invention provides a new type of multifunctional bioceramic coating material made of a mixture of an environmentally friendly, low VOC type acrylic emulsion resin and a specific constituent element ratio of natural wood powder, cupper powder, aluminum powder and charcoal powder It has the characteristics of showing the special bio functions such as water blocking, harmful electromagnetic wave shielding and meridian activity besides the far infrared rays, anion radiation, antibacterial and deodorizing functions that the existing products show, and the test result of Ajou University Rotational Electromagnetic Measurement Team In particular, the meridian circulation driving force test is a test to determine whether or not the rotating electromagnetic wave radiated from the present invention enters the human body and drives the energy that hinders the energy flow of the meridian to the outside and normalizes the flow path to activate the immune activity and the biological activity of the human body Repeatedly repeated.
따라서 본 발명품을 각종 건축물의 실내에 도포시 일반적인 바이오 기능(원적외선,음이온방사,항균,탈취)은 물론 본 발명의 주 기능인 수맥차단,유해전자파차단 및 경락활성 등의 기능을 발휘하여 인체의 기능을 활성화 시키고 신진대사를 촉진하는 효과를 발휘하는 장점을 지니고 있음Therefore, when the present invention is applied to the interior of various buildings, the functions of the human body such as the main function of the present invention, such as water blocking, harmful electromagnetic wave interception and meridian activity, as well as general bio function (far infrared ray, anion radiation, antibacterial and deodorization) It has the advantage of activating and stimulating metabolism.
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR19980030413A (en) * | 1996-10-29 | 1998-07-25 | 김고정 | Manufacturing method of building interior paint to let far infrared rays radiate |
| KR20010027635A (en) * | 1999-09-14 | 2001-04-06 | 김고정 | composition of mineral stone paints |
| JP2002146144A (en) | 2000-11-13 | 2002-05-22 | Nippon Shokubai Co Ltd | (meth)acrylic ester-based resin composition |
| JP2003292886A (en) | 2002-04-02 | 2003-10-15 | Nippon Paint Co Ltd | Urethane paint composition |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR19980030413A (en) * | 1996-10-29 | 1998-07-25 | 김고정 | Manufacturing method of building interior paint to let far infrared rays radiate |
| KR20010027635A (en) * | 1999-09-14 | 2001-04-06 | 김고정 | composition of mineral stone paints |
| JP2002146144A (en) | 2000-11-13 | 2002-05-22 | Nippon Shokubai Co Ltd | (meth)acrylic ester-based resin composition |
| JP2003292886A (en) | 2002-04-02 | 2003-10-15 | Nippon Paint Co Ltd | Urethane paint composition |
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