CN106317999A - Desulfurized gypsum putty releasing negative oxygen ions - Google Patents

Desulfurized gypsum putty releasing negative oxygen ions Download PDF

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Publication number
CN106317999A
CN106317999A CN201610665509.7A CN201610665509A CN106317999A CN 106317999 A CN106317999 A CN 106317999A CN 201610665509 A CN201610665509 A CN 201610665509A CN 106317999 A CN106317999 A CN 106317999A
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Prior art keywords
parts
negative oxygen
desulfurated plaster
oxygen ion
powder
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CN201610665509.7A
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CN106317999B (en
Inventor
魏永强
陈强
李太胜
乔媛
李景山
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Shandong Hano Bao Jia new Mstar Technology Ltd
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Shandong Hannuo Baojia Energy Polytron Technologies Inc
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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/34Filling pastes

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Medicinal Preparation (AREA)
  • Adhesives Or Adhesive Processes (AREA)
  • Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)

Abstract

The invention provides desulfurized gypsum putty releasing negative oxygen ions. The desulfurized gypsum putty is prepared from, by weight, 40-60 parts of desulfurized gypsum, 10-30 parts of sand, 10-30 parts of talcum powder, 10-20 parts of tourmaline powder, 0.2-0.5 part of composite retarder, 0.2-0.5 part of hydroxypropyl methyl cellulose, 0.1-0.5 part of water repellent, 0.01-0.1 part of starch ether and 1-2 parts of rubber powder. The tourmaline powder is added into a desulfurized gypsum base material, the negative oxygen ions can be generated, indoor air can be purified, the life of people is prolonged, the applicable temperature range is wide, constructivity is good, hardening is fast, and bonding strength is high.

Description

A kind of desulfurated plaster putty of releasing negative oxygen ion
Technical field:
The present invention relates to the desulfurated plaster putty of a kind of releasing negative oxygen ion.
Background technology:
Desulfurated plaster, as the second largest solid waste of thermal power plant after flyash, has higher Development volue.Strengthen Resource analysis to desulfurated plaster, widens its application, improves its utilization rate, is not only and thermal power plant is realized flue gas desulfurization The strong promotion of target, also complies with China simultaneously and accelerates development recycling economy and the requirement built a conservation-minded society.Desulfurated plaster Purposes more, owing to desulfurated plaster is different from the physics of general Gypsum Fibrosum, possibly together with silicon dioxide in desulfurated plaster, oxidation Sodium, calcium carbonate, calcium sulfite, limestone, calcium chloride, magnesium chloride etc..Compared with other Gypsum Fibrosum, desulfurated plaster has can be again Raw, granularity is little, stable components, and objectionable impurities content is few, purity high.So the base material that desulfurated plaster is used as putty has Natural advantage.But existing desulfurated plaster putty function is the most single, does not use all characteristics of desulfurated plaster, it is impossible to Play its good function vector.
Summary of the invention:
The purpose of the present invention is aiming at the disadvantages mentioned above that prior art exists, and adds electrically in desulfurated plaster base material Stone powder, it is possible to producing negative oxygen ion, purify the air of a room, make people's life lengthening, Applicable temperature is in extensive range, and application property is good, hard Change fast, adhesive strength height.Solve problems of the prior art.
The present invention solves that above-mentioned technical problem be the technical scheme is that
The desulfurated plaster putty of a kind of releasing negative oxygen ion, is made up of the raw material of following parts by weight: desulfurated plaster 40-60 Part, sand 10-30 part, Pulvis Talci 10-30 part, tourmaline powder 10-20 part, compound retarder 0.2-0.5 part, hydroxypropyl methyl fibre Dimension element 0.2-0.5 part, hydrophober 0.1-0.5, starch ether 0.01-0.1 part, rubber powder 1-2 part.
Preferably, it is made up of the raw material of following parts by weight: desulfurated plaster 50 parts, sand 20 parts, Pulvis Talci 20 parts, electrically Stone powder 15 parts, compound retarder 0.35 part, hydroxypropyl methyl cellulose 0.35 part, hydrophober 0.3, starch ether 0.05 part, rubber powder 1.5 part.
Preferably, the germanite powder of 2-8 part parts by weight is also included.
Preferably, the particle diameter of described sand is 70-140 mesh.
Preferably, the particle diameter of described tourmaline powder and germanite powder is 1200-1300 mesh.
Preferably, described talcous particle diameter is 300-350 mesh.
Preferably, the viscosity of described hydroxypropyl methyl cellulose is 6-8 ten thousand.
Preferably, described desulfurated plaster is the waste residue semi-hydrated gypsum through calcining of smoke-gas wet desulfurization generation.
Preferably, described compound retarder is made up of the raw material of following parts by weight: citric acid 20-40 part, boric acid 20-40 Part, tartaric acid 5-15 part, sodium citrate 20-40 part.
Preferably, described compound retarder is made up of the raw material of following parts by weight: citric acid 30 parts, boric acid 30 parts, wine Stone acid 10 parts, sodium citrate 30 parts.
Desulfurated plaster is for utilizing thermal power plant two water desulfurized gesso of flue gas to calcine 1.5-2.5h through 150-170 degree, through dehydration Half water desulfurated plaster obtained by process.
Sand, Pulvis Talci are filler, improve gypsum putty intensity and application property;
Tourmaline: excite releasing negative oxygen ion.
Compound retarder: play deferred action.
Hydroxypropyl methyl cellulose: increase construction workability, make that brushing is smooth, water conservation.
Rubber powder: increase putty pliability, resistance to water, prevent dry linting.
Hydrophober: increase putty resistance to water.
Starch ether: anti-sag.
Germanite powder: with tourmaline reciprocal action, excite releasing negative oxygen ion.
Compared with prior art, the invention have the advantage that in desulfurated plaster base material, add tourmaline powder and germanite, energy Enough producing negative oxygen ion, negative oxygen ion can not only facilitate human body synthesis and vitamin storage, and the physiology of strengthening and human activin is lived Dynamic, therefore it is otherwise known as " air vitamin ", because it is as the vitamin of food, to human body and the life of other biological Activity has highly important impact, the most electronegative microgranule to make oxygen content in blood increase, beneficially blood oxygen conveying, suction Receive and utilize, there is promotion human metabolism, improving human body immunity, strengthening human body flesh energy, regulating human body function balance Effect;Increasing compound retarder, hydroxypropyl methyl cellulose in component, Applicable temperature is in extensive range;Connecting inner contains Hydrophober, starch ether and rubber powder, application property is good, hardening is fast, adhesive strength is high.
Detailed description of the invention:
For the technical characterstic of this programme can be clearly described, below by detailed description of the invention, the present invention is explained in detail State.
The desulfurated plaster putty of a kind of releasing negative oxygen ion, is made up of the raw material of following parts by weight: desulfurated plaster 40-60 Part, sand 10-30 part, Pulvis Talci 10-30 part, tourmaline powder 10-20 part, compound retarder 0.2-0.5 part, hydroxypropyl methyl fibre Dimension element 0.2-0.5 part, hydrophober 0.1-0.5, starch ether 0.01-0.1 part, rubber powder 1-2 part.
Also include the germanite powder of 2-8 part parts by weight.Germanite contains substantial amounts of organic germanium and famous and precious jade powder, Margarita 45 kinds of mineral useful to human body such as powder, wheat Alumen, Chinese medicine material, magnesium, ferrum, calcium, carbon, potassium, sodium, chlorophyll, and through 1350 Under celsius temperature, crystallization forms.And germanite interacts with tourmaline, it is possible to excite produce very many negative oxygen from Son.
The particle diameter of described sand is 70-140 mesh.Sand commonly uses building materials, low price as one, it is possible to effectively improve Gypsum putty intensity and application property.
The particle diameter of described tourmaline powder and germanite powder is 1200-1300 mesh.Use ultra-fine grain diameter, it is possible to make it in putty Uniform, increase its specific surface area, utilize it to produce negative oxygen ion to greatest extent.
Described talcous particle diameter is 300-350 mesh.Pulvis Talci, tourmaline powder, germanite powder use different grains with sand Footpath coordinates, it is possible to increase its workability, owing to tourmaline powder and germanite powder use the thinnest microgranule, and can be as far as possible Make tourmaline powder and germanite powder be distributed in desulfurated plaster putty, it addition, Pulvis Talci can also to promote that tourmaline powder produces negative Oxonium ion.
The viscosity of described hydroxypropyl methyl cellulose is 6-8 ten thousand.Hydroxypropyl methyl cellulose is dissolved in water, and safety non-toxic can Make food additive, empty calory, skin, mucosa are contacted non-stimulated, and its Acceptable Daily Intake 25mg/kg (FAO/WHO 1985), endanger minimum.It has preferable peptizaiton, pacifies agent as suspending cement etc., and flow improver, it is right also to improve The splicing power of substrate, it is improved a lot by these as the workability of putty.
Described desulfurated plaster is the waste residue semi-hydrated gypsum through calcining of smoke-gas wet desulfurization generation.
Described compound retarder is made up of the raw material of following parts by weight: citric acid 20-40 part, boric acid 20-40 part, winestone Acid 5-15 part, sodium citrate 20-40 part.The purpose mixing people's retarder in commerical ready-mixed concrete is hard in order to extend the aquation of cement The change time, make fresh concrete can keep plasticity in a long time, thus regulate the setting time of fresh concrete.Fructus Citri Limoniae Acid, boric acid, tartaric acid and sodium citrate are harmless.
Described compound retarder is made up of the raw material of following parts by weight: citric acid 30 parts, boric acid 30 parts, tartaric acid 10 Part, sodium citrate 30 parts.
Embodiment 1:
Raw material is: desulfurated plaster 40 kilograms, sand 10 kilograms, Pulvis Talci 10 kilograms, tourmaline powder 10 kilograms, compound slow setting Agent 0.2 kilogram, hydroxypropyl methyl cellulose 0.2 kilogram, hydrophober 0.1, starch ether 0.01 kilogram, rubber powder 1 kilogram;The grain of sand Footpath be 70 mesh, the particle diameter of tourmaline powder be that 1200 mesh, talcous particle diameter are 300 mesh, state the viscosity of hydroxypropyl methyl cellulose It is 80,000;The weight ratio of citric acid, boric acid, tartaric acid and the sodium citrate of each component of compound retarder is, 20:20:5:20.
Above-mentioned each component is weighed the raw material of above-mentioned quality, then carries out weighing, mixes, stirs and remember product, Being denoted as No. 1 product, adding water according to the 30-35% of powder quality during use is stirred until homogeneous.According to " JG/T 298-2010 builds Indoor putty ", measure the physical property of putty.It is then shut off door and window, after 15 minutes, utilizes negative oxygen ion detector to detect room The content of interior negative oxygen ion.
Embodiment 2:
Raw material is: desulfurated plaster 60 kilograms, sand 30 kilograms, Pulvis Talci 30 kilograms, tourmaline powder 20 kilograms, compound slow setting Agent 0.5 kilogram, hydroxypropyl methyl cellulose 0.5 kilogram, hydrophober 0.5, starch ether 0.1 kilogram, rubber powder 2 kilograms;The grain of sand Footpath be 140 mesh, the particle diameter of tourmaline powder be that 1300 mesh, talcous particle diameter are 350 mesh, state the viscosity of hydroxypropyl methyl cellulose It is 80,000;The weight ratio of citric acid, boric acid, tartaric acid and the sodium citrate of each component of compound retarder is, 40:40:15:40.
Above-mentioned each component is weighed the raw material of above-mentioned quality, then carries out weighing, mixes, stirs and remember product, Being denoted as No. 2 products, adding water according to the 30-35% of powder quality during use is stirred until homogeneous.According to " JG/T 298-2010 builds Indoor putty ", measure the physical property of putty.It is then shut off door and window, after 15 minutes, utilizes negative oxygen ion detector to detect room The content of interior negative oxygen ion.
Embodiment 3:
Raw material is: desulfurated plaster 50 kilograms, sand 20 kilograms, Pulvis Talci 20 kilograms, tourmaline powder 15 kilograms, compound slow setting Agent 0.35 kilogram, hydroxypropyl methyl cellulose 0.35 kilogram, hydrophober 0.3, starch ether 0.05 kilogram, rubber powder 1.5 kilograms;Sand Particle diameter be 100 mesh, the particle diameter of tourmaline powder be that 1250 mesh, talcous particle diameter are 325 mesh, state hydroxypropyl methyl cellulose Viscosity is 70,000;The weight ratio of citric acid, boric acid, tartaric acid and the sodium citrate of each component of compound retarder is, 30:30:10: 30。
Above-mentioned each component is weighed the raw material of above-mentioned quality, then carries out weighing, mixes, stirs and remember product, Being denoted as No. 3 products, adding water according to the 30-35% of powder quality during use is stirred until homogeneous.According to " JG/T 298-2010 builds Indoor putty ", measure the physical property of putty.It is then shut off door and window, after 15 minutes, utilizes negative oxygen ion detector to detect room The content of interior negative oxygen ion.
Embodiment 4:
Raw material is: desulfurated plaster 40 kilograms, sand 10 kilograms, Pulvis Talci 10 kilograms, tourmaline powder 10 kilograms, compound slow setting Agent 0.2 kilogram, hydroxypropyl methyl cellulose 0.2 kilogram, hydrophober 0.1, starch ether 0.01 kilogram, rubber powder 1 kilogram, germanite powder 2 Kilogram;The particle diameter of sand be 70 mesh, the particle diameter of tourmaline powder be 1200 mesh, the particle diameter of germanite be 1200 mesh, talcous particle diameter Be 300 mesh, the viscosity of stating hydroxypropyl methyl cellulose be 80,000;The citric acid of each component of compound retarder, boric acid, tartaric acid and The weight ratio of sodium citrate is, 20:20:5:20.
Above-mentioned each component is weighed the raw material of above-mentioned quality, then carries out weighing, mixes, stirs and remember product, Being denoted as No. 4 products, adding water according to the 30-35% of powder quality during use is stirred until homogeneous.According to " JG/T 298-2010 builds Indoor putty ", measure the physical property of putty.It is then shut off door and window, after 15 minutes, utilizes negative oxygen ion detector to detect room The content of interior negative oxygen ion.
Embodiment 5:
Raw material is: desulfurated plaster 60 kilograms, sand 30 kilograms, Pulvis Talci 30 kilograms, tourmaline powder 20 kilograms, compound slow setting Agent 0.5 kilogram, hydroxypropyl methyl cellulose 0.5 kilogram, hydrophober 0.5 kilogram, starch ether 0.1 kilogram, rubber powder 2 kilograms, germanite 5 kilograms of powder;The particle diameter of sand be 140 mesh, the particle diameter of tourmaline powder be 1300 mesh, the particle diameter of germanite be 1300 mesh, talcous The viscosity that particle diameter is 350 mesh, state hydroxypropyl methyl cellulose is 80,000;The citric acid of each component of compound retarder, boric acid, winestone The weight ratio of acid and sodium citrate is, 40:40:15:40.
Above-mentioned each component is weighed the raw material of above-mentioned quality, then carries out weighing, mixes, stirs and remember product, Being denoted as No. 5 products, adding water according to the 30-35% of powder quality during use is stirred until homogeneous.According to " JG/T 298-2010 builds Indoor putty ", measure the physical property of putty.It is then shut off door and window, after 15 minutes, utilizes negative oxygen ion detector to detect room The content of interior negative oxygen ion.
Embodiment 6:
Raw material is: desulfurated plaster 50 kilograms, sand 20 kilograms, Pulvis Talci 20 kilograms, tourmaline powder 15 kilograms, compound slow setting Agent 0.35 kilogram, hydroxypropyl methyl cellulose 0.35 kilogram, hydrophober 0.3, starch ether 0.05 kilogram, rubber powder 1.5 kilograms, germanite 8 kilograms of powder;The particle diameter of sand be 100 mesh, the particle diameter of tourmaline powder be 1250 mesh, the particle diameter of germanite be 1250 mesh, talcous The viscosity that particle diameter is 325 mesh, state hydroxypropyl methyl cellulose is 70,000;The citric acid of each component of compound retarder, boric acid, winestone The weight ratio of acid and sodium citrate is, 30:30:10:30.
Above-mentioned each component is weighed the raw material of above-mentioned quality, then carries out weighing, mixes, stirs and remember product, Being denoted as No. 6 products, adding water according to the 30-35% of powder quality during use is stirred until homogeneous.According to " JG/T 298-2010 builds Indoor putty ", measure the physical property of putty.It is then shut off door and window, after 15 minutes, utilizes negative oxygen ion detector to detect room The content of interior negative oxygen ion.
Quality index and negative oxygen ion that the said goods records according to " JG/T 298-2010 architecture indoor putty " contain Measure as shown in the table:
In the case of without tourmaline powder and germanite powder, according to above-mentioned steps, record 110/m of negative oxygen ion content3, dry The dry time is 6h.The above results indicates that the present invention is hardened soon, adhesive strength is high, can produce the advantage of negative oxygen ion, and The strongest mutual facilitation is there is between germanite powder and tourmaline powder.The present invention is ensureing in the case of putty practicality, Germanite powder and coordinates by the setting of particle diameter with tourmaline powder so that it is given play to the advantage of extraordinary generation negative oxygen ion, right Healthy of great advantage in user.
Above-mentioned detailed description of the invention cannot function as limiting the scope of the invention, for the technology people of the art For Yuan, any alternate modification being made embodiment of the present invention or conversion all fall within protection scope of the present invention.
The present invention does not describes part in detail, is the known technology of those skilled in the art of the present technique.

Claims (10)

1. the desulfurated plaster putty of a releasing negative oxygen ion, it is characterised in that: it is made up of the raw material of following parts by weight: desulfurization Gypsum Fibrosum 40-60 part, sand 10-30 part, Pulvis Talci 10-30 part, tourmaline powder 10-20 part, compound retarder 0.2-0.5 part, hydroxyl Propyl methocel 0.2-0.5 part, hydrophober 0.1-0.5, starch ether 0.01-0.1 part, rubber powder 1-2 part.
The desulfurated plaster putty of a kind of releasing negative oxygen ion the most according to claim 1, it is characterised in that: by following weight The raw material composition of number: desulfurated plaster 50 parts, sand 20 parts, Pulvis Talci 20 parts, tourmaline powder 15 parts, compound retarder 0.35 Part, hydroxypropyl methyl cellulose 0.35 part, hydrophober 0.3, starch ether 0.05 part, rubber powder 1.5 parts.
The desulfurated plaster putty of a kind of releasing negative oxygen ion the most according to claim 1, it is characterised in that: also include 2-8 The germanite powder of part parts by weight.
The desulfurated plaster putty of a kind of releasing negative oxygen ion the most according to claim 1, it is characterised in that: described sand Particle diameter is 70-140 mesh.
The desulfurated plaster putty of a kind of releasing negative oxygen ion the most according to claim 4, it is characterised in that: described tourmaline The particle diameter of powder and germanite powder is 1200-1300 mesh.
The desulfurated plaster putty of a kind of releasing negative oxygen ion the most according to claim 1, it is characterised in that: described Pulvis Talci Particle diameter be 300-350 mesh.
The desulfurated plaster putty of a kind of releasing negative oxygen ion the most according to claim 1, it is characterised in that: described hydroxypropyl The viscosity of methylcellulose is 6-8 ten thousand.
The desulfurated plaster putty of a kind of releasing negative oxygen ion the most according to claim 1, it is characterised in that: described desulfurization stone Cream is the waste residue semi-hydrated gypsum through calcining of smoke-gas wet desulfurization generation.
The desulfurated plaster putty of a kind of releasing negative oxygen ion the most according to claim 1, it is characterised in that: described compound slow Solidifying agent is made up of the raw material of following parts by weight: citric acid 20-40 part, boric acid 20-40 part, tartaric acid 5-15 part, sodium citrate 20-40 part.
The desulfurated plaster putty of a kind of releasing negative oxygen ion the most according to claim 1, it is characterised in that: described compound Retarder is made up of the raw material of following parts by weight: citric acid 30 parts, boric acid 30 parts, 10 parts of tartaric acid, sodium citrate 30 parts.
CN201610665509.7A 2016-08-12 2016-08-12 A kind of desulfurated plaster putty of releasing negative oxygen ion Active CN106317999B (en)

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Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108624108A (en) * 2018-04-26 2018-10-09 德施普科技发展温州有限公司 A kind of modified desulfurated plaster putty powder for exterior wall and preparation method thereof
CN109294312A (en) * 2018-05-15 2019-02-01 优高雅健康科技(深圳)有限公司 The gypsum base powder of lacquer putty for use on for increasing anion can be lured
CN109517424A (en) * 2018-12-12 2019-03-26 湖南大迈新材科技有限公司 Metope gypsum leveling putty and preparation method thereof
CN109810556A (en) * 2019-03-05 2019-05-28 浙江志强涂料有限公司 One pack system gypsum base water proof putty and its construction method
CN115286343A (en) * 2022-08-16 2022-11-04 湖南科技大学 Regenerated fiber gypsum board with negative oxygen ion slow release function and preparation method thereof

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CN101037557A (en) * 2007-04-25 2007-09-19 上海大学 Method for preparing powder wall mastic with desullfurization gypsum
CN101705027A (en) * 2009-12-04 2010-05-12 毕家新 Putty powder used for walls in house
CN101734896A (en) * 2008-11-10 2010-06-16 河南省翔宇建材科技有限公司 Formula of putty coated on gypsum inner wall
CN102910874A (en) * 2012-11-13 2013-02-06 辽宁啄木鸟漆业发展有限公司 Negative ion putty powder

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101037557A (en) * 2007-04-25 2007-09-19 上海大学 Method for preparing powder wall mastic with desullfurization gypsum
CN101734896A (en) * 2008-11-10 2010-06-16 河南省翔宇建材科技有限公司 Formula of putty coated on gypsum inner wall
CN101705027A (en) * 2009-12-04 2010-05-12 毕家新 Putty powder used for walls in house
CN102910874A (en) * 2012-11-13 2013-02-06 辽宁啄木鸟漆业发展有限公司 Negative ion putty powder

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108624108A (en) * 2018-04-26 2018-10-09 德施普科技发展温州有限公司 A kind of modified desulfurated plaster putty powder for exterior wall and preparation method thereof
CN109294312A (en) * 2018-05-15 2019-02-01 优高雅健康科技(深圳)有限公司 The gypsum base powder of lacquer putty for use on for increasing anion can be lured
CN109294312B (en) * 2018-05-15 2021-04-20 优高雅健康科技(深圳)有限公司 Gypsum-based putty powder capable of inducing and increasing negative ions
CN109517424A (en) * 2018-12-12 2019-03-26 湖南大迈新材科技有限公司 Metope gypsum leveling putty and preparation method thereof
CN109810556A (en) * 2019-03-05 2019-05-28 浙江志强涂料有限公司 One pack system gypsum base water proof putty and its construction method
CN115286343A (en) * 2022-08-16 2022-11-04 湖南科技大学 Regenerated fiber gypsum board with negative oxygen ion slow release function and preparation method thereof

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Effective date of registration: 20191218

Address after: 251600 Shanghe County, Ji'nan, Shandong Province, south of the village of Hou Jia, 316 of the provincial road south.

Patentee after: Shandong Hano Bao Jia new Mstar Technology Ltd

Address before: Xinluo Avenue high tech Zone of Ji'nan City, Shandong province 250101 1166 orsus building 2-2420

Patentee before: Shandong hannuo Baojia energy Polytron Technologies Inc