KR100515764B1 - Face cleansing agent - Google Patents
Face cleansing agent Download PDFInfo
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- KR100515764B1 KR100515764B1 KR10-2002-0064026A KR20020064026A KR100515764B1 KR 100515764 B1 KR100515764 B1 KR 100515764B1 KR 20020064026 A KR20020064026 A KR 20020064026A KR 100515764 B1 KR100515764 B1 KR 100515764B1
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- whitening
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
- A61K8/0216—Solid or semisolid forms
- A61K8/022—Powders; Compacted Powders
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/67—Vitamins
- A61K8/676—Ascorbic acid, i.e. vitamin C
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/96—Cosmetics or similar toiletry preparations characterised by the composition containing materials, or derivatives thereof of undetermined constitution
- A61K8/97—Cosmetics or similar toiletry preparations characterised by the composition containing materials, or derivatives thereof of undetermined constitution from algae, fungi, lichens or plants; from derivatives thereof
- A61K8/9728—Fungi, e.g. yeasts
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/96—Cosmetics or similar toiletry preparations characterised by the composition containing materials, or derivatives thereof of undetermined constitution
- A61K8/97—Cosmetics or similar toiletry preparations characterised by the composition containing materials, or derivatives thereof of undetermined constitution from algae, fungi, lichens or plants; from derivatives thereof
- A61K8/9783—Angiosperms [Magnoliophyta]
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q19/00—Preparations for care of the skin
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q19/00—Preparations for care of the skin
- A61Q19/02—Preparations for care of the skin for chemically bleaching or whitening the skin
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q19/00—Preparations for care of the skin
- A61Q19/10—Washing or bathing preparations
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/20—Chemical, physico-chemical or functional or structural properties of the composition as a whole
- A61K2800/28—Rubbing or scrubbing compositions; Peeling or abrasive compositions; Containing exfoliants
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
- A61K2800/60—Particulates further characterized by their structure or composition
- A61K2800/61—Surface treated
- A61K2800/62—Coated
- A61K2800/622—Coated by organic compounds
Abstract
본 발명은 피부의 각질을 미세하게 제거시키면서, 미백 효과가 있는 각질제거 및 미백세정제로서, 각질제거에 사용되어지고 있는 실리카 또는 산화아연에 알파하이드록시산을 코팅한 분체와 미백효능이 잘 알려진 백봉령, 백강잠, 율무, 아스코르브산과 소염작용이 있는 감초, 녹차 및 수용성 수지, 향을 분말 상태로 만든 세정제이다.The present invention is an exfoliating and whitening cleanser having a whitening effect while finely removing the dead skin of the skin, and powders coated with alpha hydroxy acid on silica or zinc oxide that are used for exfoliation, and the whitening effect of Baekbong Ryeong It is a cleanser made of powdered powder, white nap, yulmu, ascorbic acid and anti-inflammatory licorice, green tea and water-soluble resin.
Description
본 발명은 피부를 손상시키지 않으면서 피부의 제일 바깥층 즉, 표피 중에서도 제일 밖에 있는 각질층만을 신속하게 제거하며, 또한 미백작용을 원활하게 하여 더욱 효과적으로 각질제거 및 미백작용을 하는 피부세정제이다.The present invention is a skin cleanser that quickly removes only the outermost layer of the skin, that is, the outermost stratum corneum among the epidermis without damaging the skin, and also smoothes the whitening function and more effectively exfoliates and whitens the skin.
미인이 되기 위한 노력은 고대로부터 끊임없이 이어져 내려오는데, 현재의 화장품은 효능을 증가시키기 위하여 많은 것을 새로 개발하고 또 화장품에 첨가를 하고 있지만, 실험에 의해서가 아닌 체험에 의해서 고대로마시대 때부터 많이 이용되고 있는 방법중의 하나가 우유로 목욕을 하면 피부가 고와지고, 포도주와 레몬 쥬스를 적신 압박붕대를 얼굴전체에 감싸는 미용법도 행하여 졌다는데 이러한 우유나 과일을 이용한 미용법이 과학적으로 입증되기 시작한 것은 20세기에 들어서 이다. 이러한 우유와 과일 속에 함유되어진 알파 하이드록시산이라는 물질에 피부의 필링 효과가 밝혀지고 있다. 필링(Peeling)이란 말 그대로 껍질을 벗긴다는 뜻인데 피부에 무리한 자극을 주지 않으면서 부작용이 없이 각질을 떼어내는 것을 말하는데, 피부에 필링이 필요한 이유는 피부세포의 기저 층에서 생겨난 세포가 약 28일을 경과하면 각질층에 이르러 각화현상으로 떨어져 나가는데 이러한 현상이 원활해야 피부는 윤기가 있고 건강하게 된다. 그러나 나이가 들면 피부의 신진대사가 저하되고 죽은 각질세포가 쌓여 거칠고 칙칙한 피부가 되기 때문에 불필요한 각질을 제거하고 피부표면을 매끈하게 하기 위해서 필링제가 사용된다. Efforts to be a beautiful woman have been continued from ancient times. Currently, many cosmetic products have been newly developed and added to cosmetic products to increase their efficacy, but they have been used since ancient Roman times by experience, not by experiment. One of the methods used is to bathe in milk, and the skin is hardened, and a beauty treatment method that covers the entire face with a pressure bandage moistened with wine and lemon juice has been performed. It is entering the century. The peeling effect of the skin on the substance called alpha hydroxy acid contained in the milk and fruit is revealed. Peeling means peeling, which means peeling off dead skin cells without causing any irritation to the skin without causing any irritation. The reason why peeling is necessary for the skin is that the cells from the base layer of skin cells are about 28 days old. After passing through the stratum corneum and fall off keratin phenomenon, this phenomenon is smooth, the skin is shiny and healthy. However, as the body ages, the metabolism of the skin decreases and dead keratinocytes accumulate and become rough and dull skin, and peeling agents are used to remove unnecessary keratin and smooth the skin surface.
본 발명에서 이루고자하는 기술적 과제는 기존 알파하이드록시산을 사용하는 화장품류는 피부에 바르고 있어 잔류물이 잔존하여 피부의 트러블이 일어날 우려가 있는데 본 발명품은 짧은 시간 안에 피부의 각질을 제거하며 효율적으로 미백작용을 하기 위해서 실리카나 산화아연이라는 분체를 지지체로 하여 알파하이드록시산이 코팅이 되어져 있으므로 발명품을 물과 섞어 피부를 문지르듯 세정을 하면 분체인 지지체에 의해 보다 효율적으로 피부에 밀착이 되므로 신속하게 작용을 한 후 세정에 의해 제거가 되므로 피부의 트러블이 극소화하며 각질을 신속하게 제거할 수 있는 목적이 있다.The technical problem to be achieved in the present invention is that the existing cosmetics using alpha hydroxy acid is applied to the skin, there is a risk that the residue may occur due to the residual residue of the present invention, the present invention removes dead skin cells in a short time and efficiently Alpha hydroxy acid is coated with a powder of silica or zinc oxide as a support for whitening. Therefore, if you mix the invention with water and wash it like rubbing your skin, it will adhere to your skin more efficiently by the powder support. Since it is removed by washing after doing so, the trouble of the skin is minimized and the purpose of removing keratin quickly is provided.
본 발명은 무기물 필링제로 사용되어지는 실리카나 산화아연 50 ~ 600 mesh인 분체에 알파 하이드록시산(Alpha Hydroxy Acid)을 코팅한 박피제의 사용으로 보다 효율적이고 단시간 내에 피부의 각질을 제거하는 발명품이다.The present invention is an invention that removes keratin of skin in a more efficient and short time by using a dermabrasion agent coated with alpha hydroxy acid (Alpha Hydroxy Acid) on the powder of silica or zinc oxide 50 ~ 600 mesh used as an inorganic peeling agent. .
알파 하이드록시산은 피부에 여러 가지의 효과를 주는 것으로 공지되어있다. 그중 하나가 농도와 사용기간에 따라 다소 차이는 있지만, 피부 외부의 케라틴성 각질 조직 층을 제거하고 박피에 효과가 있고 새 피부 층의 재생을 자극하여 피부가 상당히 좋아 보이게 하는 효과가 있다. 이러한 알파 하이드록시산은 자연에서 생성되는 산으로 우유나 식물의 당분에서 추출된다. 예를 들어, 글리콜릭산(Glycolic Acid)은 사탕수수에서 생성되어지고, 락틱산(Lactic Acid, 젓산)은 우유에서, 탈타릭산(Tartaric Acid)은 포도에서, 시트릭산(Citric Acid, 구연산)은 레몬과에서, 말릭산(Malic Acid)은 사과에서 생성, 추출되어진다. 그래서 이러한 산이 과일에서 발견되므로 과일산이라고도 한다.Alpha hydroxy acids are known to have various effects on the skin. One of them is somewhat different depending on the concentration and the duration of use, but it removes the keratinous keratinous layer outside the skin, is effective in exfoliation and stimulates the renewal of the new skin layer, making the skin look quite good. These alpha hydroxy acids are naturally occurring acids that are extracted from milk or plant sugars. For example, glycolic acid is produced from sugar cane, lactic acid is derived from milk, tartaric acid is derived from grapes, and citric acid is citric In the family, malic acid is produced and extracted from apples. Therefore, because these acids are found in fruits, they are also called fruit acids.
본 발명에서 사용되는 코팅 방법으로는 알파 하이드록시산, 예를 들면 락틱산을 상온에서 에틸에테르나 에탄올등 쉽게 용해시킬 수 있는 유기용제에 녹여서 실리카나 산화아연 50 ~ 600 mesh인 분체를 넣고 1-2시간 교반을 한 후에, 용제를 감압 제거하여 코팅분체를 만들 수 있다.As a coating method used in the present invention, alpha hydroxy acid, for example, lactic acid is dissolved in an organic solvent which can be easily dissolved at room temperature, such as ethyl ether or ethanol, and then a powder of silica or zinc oxide 50 to 600 mesh is added. After stirring for 2 hours, the solvent may be removed under reduced pressure to form a coating powder.
본 발명에서 사용되어진 코팅분체는 산성을 나타내므로 드물게 피부에 따라 미약하게나마 자극을 줄 수가 있는데, 이러한 자극은 감초나 녹차의 소염작용에 의해서 피부 트러블을 극소화 시킨다. 이때의 감초나 녹차도 50 ~ 600 mesh의 분체를 사용한다.Since the coating powder used in the present invention shows acidity, it may rarely give a slight irritation depending on the skin, and this stimulation minimizes skin troubles by the anti-inflammatory action of licorice or green tea. At this time, licorice and green tea also use powder of 50 ~ 600 mesh.
본 발명에 사용되어진 미백원료는 한방재료로 잘 알려진 백봉령, 백강잠 및 율무를 50 ~ 600 mesh로 곱게 분말화 시킨 분체를 사용하고 또한 티로신으로부터 생성되는 흑갈색 색소인 멜라닌의 형성억제 작용으로 미백의 효능이 잘 알려진 아스코르브산 (비타민 C)을 사용한다.The whitening raw material used in the present invention is powdered finely powdered Baekryong, Baekjam and Yulmu into 50 ~ 600 mesh, which are well-known as herbal ingredients, and the effect of whitening is suppressed by the action of inhibiting the formation of melanin, a dark brown pigment produced from tyrosine. Use the well-known ascorbic acid (vitamin C).
삭제delete
본 발명에서 사용되어진 수용성 수지는 본 발명품의 조성물이 물이나 우유 등의 물질과 혼합하였을 때 분체들의 점도가 미약하여 피부 접착력이 약해져 사용감이 떨어지는데 이를 개선하기 위해서 적당한 점도를 유지시켜 피부에 밀착도를 높이는 용도로 사용되어지는데, 수용성수지인 소디움카르복시메틸셀룰로즈분체, 아라빅검 분체 또는 글루코스 분체등의 수용성 수지가 사용되어진다.The water-soluble resin used in the present invention, when the composition of the present invention is mixed with a substance such as water or milk, the viscosity of the powder is weak and the skin adhesion is weakened to reduce the feeling of use to maintain a suitable viscosity to improve the adhesion to the skin to improve Although it is used for the purpose, water-soluble resin, such as sodium carboxymethylcellulose powder, arabic gum powder, or glucose powder which is a water-soluble resin, is used.
아스코르브산은 비타민 C 라고도 하는데, 1928년 헝가리의 A. 센트죄르지가 소의 부신피질에서 최초로 분리하였다고 알려져 있는데, 천연에서는 녹차, 레몬, 시금치, 양배추 등의 식물에 많이 포함되어 있으며 동물체 내에서는 부신피질 속에 많이 들어 있다고 한다. 토끼나 쥐 등의 대부분의 포유류는 아스코르브산을 글루코오스로부터 합성할 수 있으나, 사람과 원숭이는 체내 합성이 불가능하여 음식물 등을 통해서 반드시 외부에서 섭취를 해야하는 물질이다.Ascorbic acid, also known as vitamin C, was first identified in Hungary in 1928 by A. Centumerzi, which was first isolated from bovine adrenal cortex, which is naturally found in plants such as green tea, lemon, spinach and cabbage. It is said to be contained. Most mammals, such as rabbits and mice, can synthesize ascorbic acid from glucose, but humans and monkeys cannot synthesize it in the body and must be consumed externally through food.
아스코르브산은 화학식은 C6H8O6 이고 상온에서 결정형 고체이다. 이러한 건조된 아스코르브산은 공기중에서 상당히 안정한 물질로 알려져 있는데, 수용액이나 기타 용매에 용해되어있을 때는 매우 불안정하여 수일에서 수주일이 지나면 쉽게 변화가 되는 물질로 알려져 있다. 본 발명에서는 건조된 분체에 건조된 아스코르브산을 사용하므로 사용자가 물이나 기타 액체에 섞어서 사용하기 직전까지 상당히 양호한 안정성을 확보할 수 있다.Ascorbic acid has the formula C6H8O6 and is a crystalline solid at room temperature. The dried ascorbic acid is known to be a material that is quite stable in air, and is very unstable when dissolved in an aqueous solution or other solvent, and is known to change easily after several days to several weeks. In the present invention, dried ascorbic acid is used in the dried powder, so that the user can secure a fairly good stability until just before mixing with water or other liquid.
본 발명에 사용되어진 유기산의 산도가 너무 낮아 pH 3이하가 되면 피부자극이 심하게 나타나는 경우가 있는데, 본 발명품에서는 칼슘카보네이트 (Calcium carbonate)를 사용하여 산도를 약산성으로 되게 하여 피부자극을 최소화 시킨다.When the acidity of the organic acid used in the present invention is too low or less than pH 3, there may be severe skin irritation. In the present invention, calcium carbonate is used to minimize acidity by making acidity weakly acidic.
본 발명에 따른 조성물을 아래의 실시예로 설명을 하며, 이들 실시예로 본 발명을 제한하고자 하는 것은 아니다.The compositions according to the invention are described in the following examples, which are not intended to limit the invention.
일반적 제조방법은 무기물 분체와 유기용제 그리고 알파하이드록시산을 반응용기에 넣고 온도를 20 ~ 80℃를 유지하며 교반하여 무기물 분체가 충분히 코팅이 되게한 후에 10 ~ 60℃까지 온도를 내리고 상압 또는 감압증류하여 유기용제를 제거하여 코팅분체를 만든다. 여기에 백봉령 분체, 백강잠 분체, 율무 분체, 감초 분체, 녹차 분체와 아스코르브산 분체, 수용성 수지인 소디움카르복시메틸셀룰로즈 또는 아라빅검 분체, 방부제로서 솔빈산칼륨 그리고 통상의 향을 넣고 상온에서 교반을 시켜 충분히 혼합이 되게 만든다.In general manufacturing method, the inorganic powder, the organic solvent, and the alpha hydroxy acid are put in the reaction vessel, and the temperature is kept at 20 to 80 ° C., and the mixture is stirred so that the inorganic powder is sufficiently coated. Distillation removes the organic solvent to form a coating powder. Baekbongyeong powder, Baeksi sleep powder, Yulmu powder, licorice powder, green tea powder, ascorbic acid powder, sodium carboxymethylcellulose or arabic gum powder, which is a water-soluble resin, potassium sorbate as an antiseptic agent, and common flavor, and stirred at room temperature. Make it blend.
실시예 1Example 1
코팅분체 제조법으로 실리카(평균 300 mesh) 100g을 에틸에테르 500g에 넣고, 여기에 락틱산 30g을 넣고 교반을 30분간 한 후에 40℃에서 에틸에테르를 감압증류제거하여 분체를 만든다.100 g of silica (average 300 mesh) was added to 500 g of ethyl ether, and 30 g of lactic acid was added thereto. After stirring for 30 minutes, ethyl ether was distilled off under reduced pressure at 40 ° C. to obtain a powder.
실시예 2Example 2
식물 및 백강잠 분말제조 방법으로는 각각의 백봉령, 백강잠, 율무, 감초, 녹차를 고속분쇄기로 분쇄하여 200 mesh 망으로 분말을 채로 쳐서 만들거나 전부를 각각의 비율대로 넣고 분쇄한 후에 200 mesh 망의 채로 쳐서 분말을 얻어낸다.The method of manufacturing plant and white sieving powder is made by crushing each Baeknyeongyeong, white sieze, yulmu, licorice, and green tea with a high speed grinder, and then sieving the powder with 200 mesh net, or crushing all of them at their respective ratios and then grinding them with 200 mesh net To obtain the powder.
실시예 3Example 3
실리카 분체, 락틱산, 소디움카르복시메틸셀룰로즈, 백봉령, 백강잠, 율무, 감초, 아스코르브산등을 원료로 사용한 예Example using silica powder, lactic acid, sodium carboxymethyl cellulose, Baekbongryeong, Baekjap, Yulmu, licorice, ascorbic acid, etc. as raw materials
본 발명품의 성능을 실제 시험해 보기 위하여 만 30세 보통피부, 만 34세 건성피부, 만 22세 여드름이 돋아나 있는 지성피부의 여성을 대상으로 각 시료를 소정량 취하여 물이나 우유 등을 섞어서 얼굴에 마사지하면서 시료 각각의 효과를 일주일 동안 시험해 보았다. 그 결과, 시료1의 경우는 3가지 피부에 마사지 후 세안시 피부가 매끈거리고 부드러웠으며 미백효과가 있었으며 화장이 잘 받는 느낌을 받을 수 있었다. 시료2의 경우는 건성피부에서 마사지를 오래한 경우 얼굴이 조금 붉어지고 약간 자극적이었으나, 여드름의 지성피부에서는 여드름 자국이 상당히 옅어지는 효과가 있었지만 그다지 미백효과는 보이지 않았다. 시료3의 경우는 오래도록 마사지하여도 피부자극이 거의 없었으며 미백효과를 보았다. 시료4의 경우도 시료1의 경우처럼 양호한 결과가 나왔다. 본 실시예에 의한 시험결과 본 발명에 따른 범위 내에서 각 성분이 혼합될 경우 우수한 성능을 보임을 확인할 수 있었다. In order to actually test the performance of the present invention, a certain amount of each sample is taken from a woman of 30 years of normal skin, 34 years of dry skin, and 22 years of age for oily skin with acne. The effect of each sample was tested for a week while massaging. As a result, in the case of sample 1, the skin was smooth and soft at the time of facial cleansing after massage on the three skins, and there was a whitening effect and the makeup was well received. In the case of sample 2, after a long massage on dry skin, the face was slightly red and slightly irritating, but in acne oily skin, acne marks were significantly lightened, but there was no whitening effect. In the case of sample 3, even after long massage, there was almost no skin irritation and whitening effect. Sample 4 also had good results as in Sample 1. As a result of the test according to the present embodiment, it could be confirmed that excellent performance was obtained when each component was mixed within the range according to the present invention.
위에 기재한 바와 같이, 본 발명에 따르는 피부각질제거 및 미백세정제의 경우 피부의 제일 바깥층 즉, 표피 중에서도 제일 밖에 있는 각질층만을 얇게 벗겨내므로 피부의 노폐물 제거능력이 뛰어나 영양분의 침투가 용이하고 화장을 들뜨지 않고 잘 받게 하는 이점이 있다. 또한 미백효과가 우수하며 살균력이 있어 여드름이나 염증을 감소시켜주는 효과가 있다. As described above, in the case of the exfoliating and whitening cleanser according to the present invention, only the outermost layer of the skin, ie, the outermost layer of the epidermis, is peeled off thinly, so the skin is easily removed from waste products, and the nutrients are easily penetrated and the makeup is applied. There is an advantage of not being excited. In addition, the whitening effect is excellent and has the bactericidal power to reduce acne and inflammation.
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KR101172114B1 (en) * | 2008-11-17 | 2012-08-10 | (주)아모레퍼시픽 | Skin whitening cosmetic composition containing natural crop powders as exfoliation surface skin cells |
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KR100659490B1 (en) * | 2004-03-29 | 2006-12-20 | 주식회사 비트로젠 | Cosmetic composition for hair care, preparing method |
KR100861654B1 (en) | 2008-06-24 | 2008-10-02 | 김득수 | Manufacturing method for massage pack composition |
KR102230822B1 (en) * | 2019-07-09 | 2021-03-19 | 한남대학교 산학협력단 | An exfoliating cosmetic composition comprising surface modified natural cellulose |
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KR970025601A (en) * | 1995-11-03 | 1997-06-24 | 김덕록 | Whitening cosmetic composition |
JP2001019630A (en) * | 1999-07-07 | 2001-01-23 | Kao Corp | Cosmetic |
KR20010014048A (en) * | 1997-06-20 | 2001-02-26 | 마리 케이 인코퍼레이션 | Cosmetic composition containing a whitening agent and an exfoliant |
KR20030008000A (en) * | 2001-07-12 | 2003-01-24 | 신원의 | massage cream using a natural products and method for manufacturing thereof |
KR20030086187A (en) * | 2002-05-02 | 2003-11-07 | 최상숙 | Antiageing cosmetics containing natural extracts |
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KR970025601A (en) * | 1995-11-03 | 1997-06-24 | 김덕록 | Whitening cosmetic composition |
KR20010014048A (en) * | 1997-06-20 | 2001-02-26 | 마리 케이 인코퍼레이션 | Cosmetic composition containing a whitening agent and an exfoliant |
JP2001019630A (en) * | 1999-07-07 | 2001-01-23 | Kao Corp | Cosmetic |
KR20030008000A (en) * | 2001-07-12 | 2003-01-24 | 신원의 | massage cream using a natural products and method for manufacturing thereof |
KR20030086187A (en) * | 2002-05-02 | 2003-11-07 | 최상숙 | Antiageing cosmetics containing natural extracts |
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KR101172114B1 (en) * | 2008-11-17 | 2012-08-10 | (주)아모레퍼시픽 | Skin whitening cosmetic composition containing natural crop powders as exfoliation surface skin cells |
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